110 close book 2 : 45 60 open book 3:45 MCQ 50 Multiple response 1-2 Drag and drop 3-4 No mark 30 Api 510 65-85 (78) Api 572 10-16 (12) Api 576 8-10 (10) Api 578 1-2 (2) Api 571 20-25 (22) Api 577 5-8 (6) Asme sec viii 12-20 (18) Asme sec V 12-18 (16) Asme sec ix 4-6 (6) AMINE STRESS CORROSION CRACKING Definition Caused by action of tensile stress in amine environment mostly use to remove H2S and CO2 from gases or liquid hydrocarbons. Cause Non PWHT welds Prevention PWHT and use of SS cladding or better alloy. Affected Materials Carbon Steel and low alloy steels Safe Materials / Safe Conditions Hight temperature increases amine stress corrosion cracking but found in low amine solutions like MEA at room temperatures as well. Mostly associated with lean amine services as rich amine services mostly form iron sulfide layer that protects. But concentration of amine doesn’t effect on crack propagation. Effective & Non-Effective NDE WFMT, ACFM, angle beam UT (SWUT & PAUT), ET, Acoustic emission testing (AET) are effective PT can be used but shouldn’t be only mean because it is not effective for tight cracks as are filled with oxide. RT is also not very effective finding fine tight crack. Morphology Intergranular and oxide filled with some branching mostly on welds or heat affected zones Related Mechanisms Caustic SCC, Alkaline SCC, wet H2S, ammonia SCC, carbonate SCC, ATMOSPHERIC CORROSION Definition Mostly occurs because of moisture in environment. Cause Unpainted surfaces, Coating damage, Downwind from towers, Marine environments (20 mpy), industrial environments containing acid fumes (5 -10 mpy), inland with moderate moisture (1-3 mpy), dry rural (<1 mpy) Prevention Proper painting/coating Affected Materials CS, low alloy steel and Copper Alloyed Aluminum Safe Materials / Safe Conditions Proper painting/coating Effective & Non-Effective NDE VT, UT, RT (profile), ECT BRITTLE FRACTURE Definition Sudden rapid fracture under stress with no evidence of ductility Cause Low material fracture toughness Size shape and stress concentration Residual stress application Prevention Controlled pressure, temp environments Affected Materials Carbon steel, low alloy steel and 400 series SS Safe Materials / Safe Conditions Fully killed, fine grain austenitic steel with grain structure finer than 6 Austenitic SS (300 series) Controlled pressure, temp environments Effective & Non-Effective NDE Routine inspection isn’t very effective. PT, MT and UT for preexisting cracks or cracking in service. Morphology Straight non branching cracks showing no evidence of plastic deformation. Fracture surface if undamaged may show chevron markings. Cleavage with limited intergranular cracking Related Mechanism Temper embrittlement, strain age embrittlement, Titanium hydriding, sigma embrittlement CAUSTIC CORROSION Definition Localized corrosion due to the concentration of caustic (alkaline) solutions such as NaOH and KOH, and/or corrosive salts from those solutions, that usually occurs under evaporative or high heat transfer conditions Cause Caustic (KOH, NaOH) Prevention In steam generating equipment by proper design minimizing caustic concentration by proper flooding of water. Proper burner management to minimize hot spots. Caustic injection facilities should be designed to allow proper mixing and adequate dilution of caustic. Affected Materials CS, Low alloy steel and 400 series SS 300 series usually resistant to caustic until passivity is damaged which can occurs at 160 F – 210 F depending upon concentration. In high-solution-strength caustic, temperatures above about 170 °F (75 °C), with the temperature limit depending on the caustic concentration, will cause general corrosion of carbon steel. Morphology Caustic gouging is typically characterized by localized metal loss that may appear as grooves in a boiler tube or locally thinned areas under insulating deposits Effective & Non-Effective NDE UT, Angle Beam (SWUT, PAUT) , RT within limits of technique CAUSTIC STRESS CORROSION CRACKING Definition Caustic SCC is characterized by surface-initiated cracks that occur in piping and equipment exposed to caustic (alkaline hydroxide solutions) at elevated temperature, primarily adjacent to non-PWHT’d welds Cause Caustic Solution in non PWHT areas Prevention PWHT A heat treatment at 1150 °F (620 °C) minimum with a minimum holding time of 1 hr is considered an effective stress relieving heat treatment for carbon steel. 300 series SS offer little advantage in resistance to cracking over carbon steel. Nickel-based alloys are more resistant to cracking and may be required at higher temperatures and/or caustic concentrations. However, caustic SCC of these alloys has been observed at high temperatures that promote the formation of molten caustic in the absence of free water [604 °F (318 °C), at atmospheric pressure]. This damage has sometimes been referred to as molten caustic cracking. Steam out of non-PWHT’d carbon steel piping and equipment should be avoided Affected Materials Carbon steel, low-alloy steels, and 300 series SS are susceptible. Duplex stainless steels are also susceptible but have shown improved resistance compared to the 300 series SS. Nickel-based alloys are more resistant. Effective & Non-Effective NDE WMFT, ACFM, ECT, Angle beam UT, AET PT or MT can be effective. (PT may not useful for oxide filled cracks) Morphology The pattern of cracking observed on the steel surface is sometimes described as a spider web of small cracks Cracking in 300 series SS is most often transgranular but can be intergranular even in non-sensitized material. When transgranular, it can be difficult to distinguish from Cl− SCC. Caustic SCC of nickel-based alloys has been observed as either intergranular (Figure 3-15-9) or transgranular CHLORIDE STRESS CORROSION CRACKING Definition Surface initiated cracking of 300 series SS and some nickel-based alloys under the combined action of tensile stress, temperature and aqueous chloride environment. Cause Chloride content, temperature, PH, tensile stresses, presence of oxygen Mostly inorganic chloride CL- ion cause Cl-SCC No practical lower limit exists for prevention. Temperature above 140 F-400 F most concern. Affected Materials Mostly 300 series SS (welds in SS mostly contain ferrite producing duplex structure which is more resistant) Duplex SS are more resistant but still susceptible. Nickle based alloys are highly resistant but still not immune. Safe Materials / Safe Conditions Stainless steel with nickel 8-12 % highly susceptible. Alloys with Nickel content above 35 % are highly resistant And above 45 % nearly immune. Appearance Spider web/ craze cracking, typically branched trans granular, 300 SS maybe intergranular, typically have brittle appearance Effective & Non-Effective NDE VT for advance cracks PT, ECT, Angle beam UT (PAUT, SWUT) is effective RT is not very effective except in advance stage COOLING WATER CORROSION Definition General or localized corrosion of carbon steels and other metals caused by dissolved salts, gases, organic compounds, or microbiological activity in cooling water systems Cooling water corrosion, fouling, and MIC are closely related and should be considered together. Affected Materials Carbon steel, all grades of stainless steel, copper and copper alloys, aluminum and aluminum alloys, titanium, and nickel alloys. Safe Materials / Safe Conditions Low velocities can promote increased corrosion. Velocities should be high enough to minimize fouling and dropout of deposits but not so high as to cause erosion. Generally, velocities below about 3 fps (1 m/s) are likely to result in fouling Process-side inlet temperatures of water-cooled exchangers should be maintained below 140 °F (60 °C). Effective & Non-Effective NDE Remote field testing is commonly used for inspection of ferrous (carbon steel) tubes. RFT has an equal sensitivity to ID and OD indications and can detect and size corrosion and pitting as well as baffle cuts. ECT is the preferred method for non-ferromagnetic materials as it has a higher probability of detecting all types of damage than ultrasonic methods. Internal rotating inspection system IRIS is used when a higher flaw detection and sizing capability is needed (compared to the other methods), but it is slower, and thorough tube cleaning is required prior to inspection. IRIS can be used on both ferrous and nonferrous materials. IRIS is most used on carbon steel tubes. CUI Definition Corrosion of piping, pressure vessels, and structural components resulting from water trapped under insulation or fireproofing Cause Corrosion rates increase with increasing metal temperature up to the point where the water evaporates quickly. Affected Materials Carbon steel, low-alloy steels, 300 series SS, 400 series SS, and duplex stainless steels Safe Materials / Safe Conditions Coating Flame Sprayed aluminum coatings Effective & Non-Effective NDE Profile RT, Infrared thermography, VT, UT, Pit gauge, neutron backscatter (for wet insulation) ERROSION / ERROSION-CORROSION Definition Erosion is the mechanical removal of surface material as the result of relative movement between, or impact from, solids, liquids, vapor, or any combination thereof. Prevention Increase diameter to decrease velocity Affected Materials All metals, but mostly carbon steel and copper alloys in refining Effective & Non-Effective NDE UT, RT HIGH TEMP HYDROGEN ATTACK Definition HTHA results from exposure of steels to hydrogen gas at elevated temp and pressure. Dissociated hydrogen atom reacts with carbon and carbides to form CH4. Affected Materials In order of resistance: welded CS, non-welded CS, CS with PWHT, C-0.5Mo, Mn-0.5Mo, 1Cr-0.5Mo, 1.25 Cr- 0.5 Mo, 2.25Cr-1Mo, 2.25Cr-1Mo-V, 3Cr-1Mo, 5Cr-0.5Mo Safe Materials / Safe Conditions 300 series SS, 5Cr, 9Cr, 12Cr alloys are not susceptible to HTHA Use steels with high chromium and molybdenum content Common design practice is 25 F - 50 F and 25-50 psia Effective & Non-Effective NDE The period where no HTHA detected internally or externally even by NDE is called incubation period. VT (for blisters), TOFD, PAUT, AUBT (AUTOMATED ULTRASONIC BACKSCATTER TESTING) is effective. MT, PT, WMFT not effective at all unless crack has reached the surface. AET is also not proven method. Effected Units Hydrotreaters, hydrocrackers, catalytic reformers, boiler tubes in very high-pressure steam service Appearance Blisters, internal fissuring and cracking HYDROCHOLORIC ACID CORROSION Definition HCL cause both localized and general corrosion. Mostly associated with dew point corrosion in which vapors containing water and hydrogen chloride condenses. Cause HCL, vapors containing water and hydrogen chloride. Prevention Upgrading carbon steels to nickel based alloys or titanium will reduce the impact. Water wash & Caustic injection is effective. Ammonia, neutralizing amines and filming amines can be injected. Affected Materials / Units All common materials used in refineries. Carbon steel and low alloy steel when exposed to HCL with ph below 4.5. 300 SS & 400 SS also get affected. Alloy 400, titanium and nickel-based alloys show some resistance to dilute HCL. Oxidizing agent increase corrosion for 400 series and alloy B-2. Titanium performs well in oxidizing conditions but fails in dry HCL conditions. Safe Materials / Safe Conditions 20 ppm chloride. Note: don’t confuse for hydrotest chloride requirement which is 50 ppm Effective & Non-Effective NDE Effective NDE includes: VT (look for orange yellow discoloration). UT mapping, AUT (automated UT), RT MECHANICAL FATIGUE Definition Mechanical form of degradation when component exposed to cyclic stresses for extended period. Cause Vibrations, water hammer, unstable fluid flow, vibrational load synchronize with natural or harmonic frequency. Usually initiates on key holes on shafts, mechanical notches, tool markings, grinding marking, lips on drilled hole, thread root notches and corrosion. Prevention Good design, stiffeners and dampers Affected Materials All engineering alloys (number of cycles may vary metal to metal) 300, 400 series SS aluminum and most non-ferrous metals don’t have endurance limit so eventually fails after 106 𝑡𝑜 107 cycles. Safe Materials / Safe Conditions Titanium, carbon steels and low alloys steels has endurance limit if stress amp is below endurance limit fatigue will not occur regardless of cycles. Ratio of endurance limit to Ultimate tensile Strength (UTS) is between 0.4 and 0.5. Heat treatment is effective. Effective & Non-Effective NDE Effective: UT, MT, Angle beam (PAUT & SWUT: shear wave), compression wave UT for cracking in bolts, vibration monitoring. SOUR WATER CORROSION Definition Corrosion of steel due to acidic sour water containing H2S at a PH between 4.5 to 7.0. Cause acidic sour water (dangerous at lower ph) Prevention Controlled H2S, PH, Chloride, Cyanide, temp, velocity and oxygen concentration. Affected Materials CS Safe Materials / Safe Conditions SS, copper alloys and nickel-based alloys. Effective & Non-Effective NDE UT and RT. SULFIDATION Definition Corrosion of carbon steels and other alloys resulting from their reaction with sulfur compounds in high temp environments. Cause Sulfur compounds with service temp above 450 F should be concern but practical concern is above 500 F. Prevention Higher chromium steel. Above 1193 F select nickel alloy with lower nickel content. Affected Materials All iron-based materials including CS, low alloy Steel, 400 series, 300 series (in order of susceptibility). Above 1193 F alloy containing high nickel can suffer. Susceptibility increase with increase of nickel content. Copper based alloys form sulfide corrosion at lower temp than CS. Safe Materials / Safe Conditions Increasing chromium content increase resistance. 300 series are better resistant at high temps. CS with silicon content above 0.10% good resistant. Effective & Non-Effective NDE Effective: UT, RT, internal VT followed by UT, Appearance / Morphology Mostly uniform but can be localized or high velocity erosion corrosion damage WET H2S DAMAGE Definition 4 types of damage: a) Hydrogen blistering: Hydrogen blisters form bulges primarily on the ID surface of pressure vessels b) Hydrogen induced cracking in this case, when the hydrogen atoms diffuse into the steel, rather than forming blisters, internal separations parallel to the surface of the steel eventually forming a thru-wall leak path. c) Stress oriented hydrogen induced cracking SOHIC results from an array of HIC (separations or cracks) stacked on top of each other. When acted upon by a high stress level (residual or applied), the stacked HIC will connect and create a thru-thickness crack that is perpendicular to the surface. d) Sulfide stress cracking (SSC) SSC is the cracking of a susceptible metal under the combined action of tensile stress and corrosion in the presence of water and H2S Cause A value of 50 ppmw of H2S is often stated as minimum concentration where wet H2S damage can occur. But damage has been found at even 1 ppmw H2S partial pressure above 0.05 psia can cause SSC in steels with tensile strength above 90 ksia and with hardness above 237 HB Found minimum at PH 7 and increase with both increase/decrease of PH from 7. At PH < 4 only small amount of H2S required for damage. Increasing level of ammonia or ammine solution where PH > 7 also susceptible to damage. at pH > 7.6 with 20 ppmw dissolved HCN in the water, as little as 1 ppmw total sulfide content in the water can cause SSC Blistering, HIC, and SOHIC have been found to occur between ambient temperature and 300 °F (150 °C) or higher SSC potential is greatest at about 70 °F (20 °C) and decreases with increasing or decreasing temperature SSC is generally a concern below about 200 °F (95 °C); however, the limiting temperature above which SSC is no longer a concern will depend on the situation, i.e. on the hardness of the steel involved and the severity of other environmental factors such as pH. Hardness is primarily an issue with SSC. Blistering, HIC, and SOHIC damage are not related to steel hardness. Welds in carbon steel should be controlled to produce weld hardness < 200 HB, and they will typically achieve this without any special precautions. Carbon steel welds are not susceptible to SSC unless localized zones of hardness above 237 HB are present In hydroprocessing units, an ammonium bisulfide concentration above 2 % increases the potential for blistering, HIC, and SOHIC Affected Materials Carbon Steel, in case of SSC low alloys steels and martensitic stainless steels (410 series) Effective & Non-Effective NDE Cracks from SOHIC or surface-breaking HIC may be seen visually. However, to enable crack detection at an early stage, WFMT, ECT, or ACFM techniques can be used Angle beam UT techniques including external SWUT and PAUT can be used. These techniques are especially useful for volumetric inspection and crack sizing. Appearance: HB: blisters HIC: Staircase