1. Principles of Chemistry Revision – PARTICLES Draw a representation of the particles in a solid, liquid and gas. Name the transitions KEY WORDS: Particle Kinetic theory Solid Liquid Gas Attraction Complete the table to compare AND explain the properties Solid Liquid Gas Define diffusion. Give an example How do particles move? Attraction between particles Arrangement of particles Shape Compressibility 1 2. Principles of Chemistry Revision – Atomic Structure Draw the symbol for sodium include its atomic mass and atomic number (what do they tell us?) What are the charges and masses of electrons, protons and neutrons? Where are electrons and neutrons and protons found in an atom? What is an electron ‘shell’? How many electrons can be found in each ‘shell’? Draw the electronic configuration for sodium, oxygen and argon How many atoms of which elements are there in: C2H5OH ? What is an alloy? Give two examples and how they are useful Define Isotope: Give an example: KEY WORDS: Electron Proton Neutron Shell Electronic Configuration Orbit What is a radioactive isotope? 3 3. Principles of Chemistry Revision – CHEMICAL BONDING 1 Describe how sodium and chlorine bond; Use a dot cross diagram to show how sodium and chlorine bond Describe the structure of metals and metallic bonding List the properties of metals Complete the table to show and explain the properties of ionic compounds Property Ionic quality Explanation Hardness Melting/boili ng point Solubility Conductivity Malleability KEY WORDS: Electron Proton Neutron Shell Electronic Configuration Covalent/Ionic/Metallic 4 4. Principles of Chemistry Revision – CHEMICAL BONDING 2 Make a diagram to explain how a giant lattice is formed for an ionic structure Diamonds and Graphite are both made of carbon. Make a table of their differences KEY WORDS: Electron Sharing Inter molecular Covalent/Ionic/ Metallic Attraction 5 5. Principles of Chemistry Revision – STOICHIOMETRY What is Ar? What is a mole? What is Mr? What equation links mole with mass? What is the Mr of C2H5OH? What equation links mole with concentration of solution? What is Avogadro’s number? Write the formula of: Magnesium oxide: What is percentage yield and what is the equation to calculate it? H2 + O2 H2O N2 + H2 NH3 S8 + O2 SO3 N2 + O2 N2O HgO Hg + O2 CO2 + H2O C6H12O6 + O2 Zn + HCl ZnCl2 + H2 SiCl4 + H2O H4SiO4 + HCl Na + H2O NaOH + H2 H3PO4 H4P2O7 + H2O C10H16 + Cl2 C + HCl Calculate what volume of hydrogen gas is formed at RTP when 5.7g of magnesium is added to excess sulfuric acid.. Sodium chloride: Potassium phosphide: Balance these equations: Calculate the empirical formula for a compound containing: Na 0.167 g, C 0.0435 g, O 0.174 g KEY WORDS: Calcium fluoride: Reversible Haber Process Relative Atomic Mass Relative Formula Mass Isotope Moles 6 6. Physical Chemistry Revision – ELECTROLYSIS 1 What is electrolysis? What does OILRIG stand for? What do we call the substance that is broken down during electrolysis Describe the movement of ions and electrons at each electrode when potassium iodide is electrolysed How is the electrolysis of used to purify copper? [Draw a diagram to help] What is the positive electrode called? What is the negative electrode called? Label a diagram showing the electrolysis of Lead (II) bromide What happens when a solution containing potassium iodide is electrolysed? What 3 products are made when we electrolyse brine? Give a use for each? KEY WORDS: What ions are formed? Electrolysis Cathode Anode Oxidation Reduction 7 7. Physical Chemistry Revision – ELECTROLYSIS 2 & REDOX What is electroplating and what is it used for? Oxidation can be defined in two ways, they are: What is a reducing agent? What is an oxidising agent? Reduction can be defined in two ways, they are: Describe the process used to extract aluminium from its ore. Give the conditions. Include equations. A diagram could be useful. Write the symbol equation for the displacement of copper from copper(II) oxide by zinc. What are oxidation states? How are they shown in chemical names, give an example? Rewrite this as an ionic equation What do changes in oxidation state represent? Give 3 uses of aluminium and the properties that make it useful Rewrite this as two half equations KEY WORDS: Redox Electron Oxidation Reduction Agent Ion 8 8. Physical Chemistry Revision– ENERGY & REACTIONS 1 What are exothermic reactions? Define Enthalpy change (its symbol?) Give an example and explain why it is exothermic? Define activation energy What are bond energy values? Why are they average values? What are bond energy values? Why are they average values? What are endothermic reactions? Draw fully labelled energy profile diagrams for exo and endo thermic reactions. Explain how to calculate bond energy for a reaction: Give an example and explain why it is endothermic KEY WORDS: Collision Theory Catalyst Activation Energy Rate of Reaction Concentration Temperature Bond Energy values (J/mol) H−H F-F H−F O−H C−H 432 154 565 467 413 Cl−Cl 239 C−O 358 C=C 614 C≡O 1072 C=O 745 C−C 347 C=O 799 C−Cl 339 O=O 495 9 9. Physical Chemistry Revision – ENERGY CALCULATIONS 2 We calculated the energy used when burning fuels using the following calculation: Energy released = mass of water X specific heat X rise in heated capacity of water temperature This is sometimes written as: Use the bond energy values on the previous page to calculate the enthalpy change for each of these reactions: 1. H2(g) + F2(g) → 2HF(g) 𝑄 = 𝑚𝑐∆𝑇 We also need to know the amount of energy released per gram or per mole to compare the efficiency of the fuels: 1𝑔 Energy released per gram (kJ/g) = energy released X 2. CH4(g) + 2O2(g) → CO2(g) + 2H2O (g) 3. CO(g) + 2H2(g) → CH3OH(l) 4. 2H2(g) + O2(g) → 2H2O(g) 5. 2H2O(g) → 2H2(g) + O2(g) 𝑐ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑓𝑢𝑒𝑙 Energy released per mole (kJ/mol) = energy released X 𝑅𝐴𝑀 𝑜𝑓 𝑓𝑢𝑒𝑙 𝑐ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑓𝑢𝑒𝑙 Use these equations to show which fuel is more efficient: 0.2 g of fuel A heats 50g of water from 16°C to 41°C 0.46 g of fuel B heats 50g of water from 21°C to 57°C 0.13 g of fuel C heats 35ml of water from 21°C to 46°C KEY WORDS: Energy release Activation Energy energy transfer Catalyst Solutions Bond breaking Exothermic Bond making Endothermic Bond energy 10 10. Physical Chemistry Revision – RATES OF REACTION What do we mean by ‘rate of reaction’? Explain the effect of concentration on the rate of reaction Explain the effect of temperature on the rate of reaction [think about: kinetic energy & number of collisions] What 4 factors affect the rate of a reaction? What must happen for a reaction to occur? Draw diagrams to represent it? Draw diagrams to represent it: What is the smallest amount of energy that must be overcome for a reaction to occur? How does surface area affect rate of reaction? Low concn High concn What do catalysts do? Low temp High temp KEY WORDS: Give two examples of catalysed reactions Collision Theory Catalyst Activation Energy Rate of Reaction Concentration Temperature 11 11. Physical Chemistry Revision – REVERSIBLE REACTIONS What is a reversible reaction? What is the symbol for a reversible reaction? What can you say about energy in a reversible reaction? [Think: exo and endothermic] What happens to the equilibrium when the concentration of products is increased? Why? What is a dynamic equilibrium? If the forward reaction of an equilibrium is exothermic and the temperature of the system is increased, what would happen to the equilibrium why? What is the Haber process? State Le Chatelier’s principle What are the raw materials? For the Haber process, what would happen to the equilibrium if the pressure was reduced why? What is the reaction equation? KEY WORDS: What conditions are required? Collision Theory Catalyst Activation Energy Rate of Reaction Concentration Temperature How does a catalyst affect the equilibrium? Why? 12 12. Physical Chemistry Revision – ACIDS, ALKALIS & SALTS What is a base? Write a general equation for an acid reacting with a metal and two examples: What is produced when an acid and an alkali react? What type of reaction is this called? What is an alkali? How can this reaction be simplified using just the ions involved? What ions make something alkali? Define Acid: Write a general equation for an acid reacting with a base and two examples: What ions make something acidic? What is a precipitation reaction? How can we make ammonium hydroxide? What is the pH scale? What happens when we add nitric acid to it? Describe 2 uses for acids and alkalis in the ‘real world’ KEY WORDS: Acid Base Alkali pH scale Indicator Precipitate 13 13. Inorganic Chemistry Revision – THE PERIODIC TABLE State how each of these scientists aided in the development of the modern periodic table: Newland: Describe how the modern periodic table is arranged: Mendeleev: What are rows called in the P. table? Create a key for the colours displayed on the periodic table above: What are columns called? Group 1 – the alkali metals: Describe the properties: Give some group 1 compounds and their uses Describe their reactions with air Describe their reactions with water Describe Group 1 reactions with chlorine KEY WORDS: Reactivity Reactive metals Non-metals Melting point Boiling point Alkali metals 14. Inorganic Chemistry Revision – THE PERIODIC TABLE Group 7 – the Halogens Describe the properties: Describe their reactions with Metals Give some group 1 compounds and their uses: Describe their reactions with water Write ionic equations for the halogen displacement reactions Describe what the halogen displacement reactions are and why they occur: KEY WORDS: Transition metals Describe the properties: Noble gases – group 8/0 Describe the properties and electron structure: What is unique about trans metals oxidation states and how does this affect them? Give some uses of noble gases: Reactivity Reactive metals Non-metals Melting point Boiling point Halogens Nobel gases 16 15. Inorganic Chemistry Revision – METALS Put these metals in their order of reactivity Carbon, Calcium, aluminium, Magnesium, potassium, lead, gold, Copper, Iron, zinc, silver, sodium Write a general equation and two examples for each below: Heating metal nitrate Complete the displacement equation below and then make your own : Copper Oxide + Carbon _______________ + _______________ Heating metal carbonate What is an ore? How is steel made? Include equations Heating metal hydroxides How is iron extracted? Include equations Give 2 uses of: Aluminium Copper Draw a diagram to show metallic bonding KEY WORDS: DISPLACEMENT ORE BLAST FURNACE ALLOY Steel Metallic bonding 17 16. Inorganic Chemistry Revision – SULFUR AND CARBONATES Describe the steps of the contact process. Include equations. You could use a diagram. Write equations to show how sulfuric acid reacts with alkalis, bases, carbonates and glucose: Describe some uses of: Quicklime Limestone Slaked lime What is sulfuric acid used for? What are the conditions for industrial thermal decomposition of limestone KEY WORDS: DISPLACEMENT ORE BLAST FURNACE ALLOY Steel Metallic bonding 18 17. Inorganic Chemistry Revision – AIR & WATER What are the layers of the Earth? What is the chemical test for water? Sketch the water cycle Complete the table to show the atmosphere of Earth today Gas % How is water cleaned for drinking? Others (inc. Argon) Describe the Nitrogen cycle How are humans disrupting/ effecting the nitrogen cycle? What is the carbon cycle? Briefly describe the steps What are NPK fertilisers? What are the three key processes of the C cycle? Give the equations KEY WORDS: ATMOSPHERE CARBON CYCLE Nitrates Nitrifying bacteria Decomposers Precipitation 19 18. Inorganic Chemistry Revision – POLLUTION Complete the table to show the source of pollutants in the air Pollutant Sketch a diagram to show global warming Source Carbon monoxide Sulfur dioxide Nitrogen oxides Lead compounds Describe how acid rain forms. Include equations. Describe some techniques used to reduce pollutants in the air What are CFCs? Why are they important to pollution chemistry? Describe methods used to prevent rusting. KEY WORDS: ATMOSPHERE CARBON CYCLE Nitrates Nitrifying bacteria Decomposers Precipitation 20 19. Organic Chemistry Revision – CRUDE OIL & FUELS Name the process by which we separate crude oil into useful components: What are fossil fuels? Give the name of 8 fractions of crude oil and their uses Fraction Use Num. of C What property does this process rely on? How does it work? What are hydrocarbons? Write a general equation for combustion and incomplete combustion Describe how these properties change further up the fractionating column: Boiling point Molecule size Viscosity What does ‘cracking’ mean? Ease of burning Smokiness of flame Strength of intermolecular forces Why is cracking important? KEY WORDS: Write an equation with an example of a cracking reaction ALKANE ALKENE SATURATED FRACTIONAL DISTILLATION COMBUSTION 21 20. Organic Chemistry Revision – ALKANES AND ALKENES What does it mean if a molecule is saturated or unsaturated? What is a homologous series? Describe the, use, procedure and outcome of the bromine test Complete the table to summarise alkanes and alkenes: ALKANES Saturated or unsaturated ALKENES Define Isomer Define Structural isomerism Reactivity General formula Uses Draw and name 2 isomers of C6H14 Name the first 5 Draw an example KEY WORDS: CRACKING POLYMERISATION PLASTIC POLYMER MONOMER FERMENTATION BIODEGRADABLE 22 21. Organic Chemistry Revision – ORGANIC CHEMISTRY Alcohols: What is the functional group and general formula? Carboxylic acids: What is the functional group and general formula? Draw 2 structural isomers of butanol Draw and name the structure of the first 3 members: Esters: Describe how esters are made: Give two uses of esters: Draw and name three esters Briefly state the some of the uses of alcohol: Describe how carb, acids are made, include an equation: Describe the conditions and procedure of producing ethanol by Fermentation: Describe the reaction of carboxylic acid with carbonates: Briefly describe the issues of using ethanol as a fuel Hydration: KEY WORDS: Alcohol Functional group Homologous series Carboxylic acid Esters Combustion Oxidation Ethanol 23 22. Organic Chemistry Revision – POLYMERS Define monomer and polymer What is ‘condensation polymerisation’? List 3 problems with plastics: Draw an amide link and state what it is formed from: Give examples of two naturally occurring polymers and their monomers: Draw an ester link and state what it is formed from: Describe and explain how addition polymers form. You could use a diagram How are biodegradable plastics made? What are the problems with them? KEY WORDS: CRACKING POLYMERISATION PLASTIC POLYMER MONOMER FERMENTATION BIODEGRADABLE 24 23. Principles of Chemistry Revision – EXPERIMENTAL TECHNIQUES What is the range of a measuring implement? What is the function of paper chromatography? What is the interval? Describe the steps involved in paper chromatography: What instrument and unit do you use to measure: Describe the steps used to purify a solid. You could use a labelled diagram. Describe the steps used to purify an impure liquid. You could use a labelled diagram. Time: Mass: What is a Retention Factor and how do you calculate it? Temperature: Volume of liquids: What is the simplest test of purity? KEY WORDS: Desalination Distillation Soluble Solvent Chromatogram 2 24. Physical Chemistry Revision – ANALYSIS AND SYNTHESIS Fill in the table to show your understanding of flame tests: Fill in the flow chart to show your understanding of positive ion tests: Metal ion Colour of precipitate Further tests required Metal ion Copper Cu2+ Lithium (Li+) Reddish-brown Sodium (Na+) Iron Fe2+ Lilac Magnesium Mg2+ Insoluble in excess NaOH, red flame test Aluminium Al3+ Flame colour White Describe how to carryout a titration: Red Barium (Ba2+) Fill in the table to show your understanding of negative ion tests: Anion Test Observation CO2 gas produced Colour precipitate: Chloride Bromide Iodide Halide State the different types of chemical analysis that can be carried out: Sulphate KEY WORDS: Flame test Sodium hydroxide Carbonates Halides Sulphates Titration White precipitate End point Concentration Chemical analysis Equilibrium Pressure Energy Haber process 14