Earth Science Weathering, Erosion & Soil Name: Lab # 17 - TEMPERATURE AND CHEMICAL WEATHERING Introduction: Whether it’s the granite of a New Hampshire mountain breaking down into sand and clay or the limestone of Kentucky decomposing to form rich soil, all chemical weathering processes involve water. What effect does the temperature of the water have on the rate at which chemical weathering occurs? As you know, carbonic acid is a weak acid that forms when carbon dioxide dissolves naturally in rain, in streams, or in groundwater. A common chemical weathering process is the reaction between carbonate rocks, such as limestone and marble, with carbonic acid. In this lab activity, you will observe a model of t his reaction. By changing the temperature of the water, you can model the effect of the temperature on the rate of the reaction between carbonate rocks and carbonic acid. Objectives: ☺ ☺ ☺ ☺ Materials: To Model a chemical weathering process To graph the data from the model and to interpret the graph To predict what will happen when the model is modified To compare the observed data with the theoretical data Each group will need the following materials for the lab; 5 – 250 mL beakers 5 thermometers 5 effervescent antacid tablets Hot water (40o – 50oC) Ice water Graph paper Procedures: PART 1 1. Arrange 5 beakers in a row. Assign each beaker a number from 1 to 5. Place a thermometer in each beaker. Each beaker should contain about 200 mL of water. The water temperature in each beaker will need to be adjusted to match the following temperatures (use ice or hot water as necessary to make adjustments). Beaker 1 Beaker 2 Beaker 3 Beaker 4 Beaker 5 0o – 10oC 10o – 20oC 20o – 30oC 30o – 40oC 40o – 50oC F:\Documents\Earth Science\Rocks, Minerals & Soil\Sur face Processes & Landscape Development\ES Lab Temp and Chemical Weathering.doc 1 2. Begin with Beaker 1. Remove any pieces of ice from the water. Check to be sure that the water is within the correct temperature range and that the thermometer has stopped changing. Read the temperature of the water in Beaker 1 to the nearest 0 .5 degree and record it in DATA TABLE A: Actual Data. Remove the thermometer from the beaker and set it aside in a safe place. 3. READ THIS ENTIRE STEP BEFORE CONTINUING! Drop one of the antacid tablets into beaker 1. Start the stop watch at the instant the tablet enters the water. Stop the stopwatch when the last piece of the tablet dissolves. NOTE: It is not necessary to wait for all of the bubbling to stop; wait only for all pieces of the tablet to disappear. 5. Read the time on the stopwatch and record it to the nearest 1.0 second on DATA TABLE A. 6. Repeat steps 3 and 4 for each of the remaining beakers. 7. Using your data from DATA TABLE A, plot a graph for the 5 trials. Label the X-axis Temperature (0C) and the Y-axis Time (seconds). Connect the 5 points with a smooth curve. Label the curve Observed Data. 8. Answer questions 1 – 6 in the Analysis and Conclusions. PART 2 1. Copy ONLY your Beaker 1 data from DATA TABLE A to DATA TABLE B. The remaining values in Data Table B will need to be calculated. 2. For the temperature values, add 10 o C to the reading for Beaker 1 and record that as the temperature for Beaker 2. In the same way, continue to add 10 oC to each temperature reading for Beakers 3, 4 and 5 and record in the table. 3. For the time values on DATA TABLE B, divide the time for Beaker 1 in half to obtain the time for Beaker 2 and so on. When you divide the values, round off each result to the nearest whole second. EXAMPLE: Beaker 2 Time = Beaker 1 Time ÷ 2 Beaker 2 Time = 25 Seconds ÷ 2 Beaker 2 Time = 12.5 Seconds Record 13 seconds for Beaker 2 4. Using the same graph as before, plot the e values from Data Table B. Connect the points with a smooth curve. Label the curve Theoretical Data. 5. Answer question #7 in the Analysis and Conclusions. F:\Documents\Earth Science\Rocks, Minerals & Soil\Sur face Processes & Landscape Development\ES Lab Temp and Chemical Weathering.doc 2 DATA TABLE A: Observed Data Beaker Number Temperature (0C) Time (seconds) 1 2 3 4 5 DATA TABLE B: Theoretical Data Beaker Number Temperature (0C) Time (seconds) 1 2 3 4 5 F:\Documents\Earth Science\Rocks, Minerals & Soil\Sur face Processes & Landscape Development\ES Lab Temp and Chemical Weathering.doc 3 ANALYSIS and CONCLUSIONS: Answer using your knowledge of weathering & erosion and the graph completed in this lab. [1 point each] 1. In which beaker did the reaction occur most slowly? In which beaker did the reaction occur most rapidly? State the relationship between temperature and the rate of the reaction. 2. Based upon your observations, what do you think the relationship is between the temperature and the rate of natural chemical weathering? 3. Look at the temperatures you recorded. Are all of these temperatures likely to occur on Earth’s surface? Explain. 4. How would the rate of the reaction have been different if the tablets had been ground into a powder before they were dropped into the water? Why? 5. Look at the calculated values in Data Table B. (a) On your graph, is the line for the theoretical data above, below, or the same as your line for the actual data? 6. What does this mean about the rate of the reaction you observed compared with the theoretical rate of reaction? 7. Which factor has the least effect on the weathering of a rock? A) composition of the rock B) exposure of the rock to the atmosphere C) the number of fossils found in the rock D) climatic conditions F:\Documents\Earth Science\Rocks, Minerals & Soil\Sur face Processes & Landscape Development\ES Lab Temp and Chemical Weathering.doc 4 8. Four quartz samples of equal size and shape were placed in a stream. Which of the four quartz samples below has most likely been transported farthest in the stream? 9. The diagram below shows an outcrop of different layers of sandstone in a region receiving heavy rainfall. Which sandstone layer appears to be the least resistant to weathering? (1) A (2) B (3) C (4) D 10. Slightly acidic groundwater seeps through cracks and openings in limestone bedrock producing caves. State whether the type of weathering that produces these caves is mainly chemical or physical, and identify one characteristic of limestone that allows this type of weathering to occur. F:\Documents\Earth Science\Rocks, Minerals & Soil\Sur face Processes & Landscape Development\ES Lab Temp and Chemical Weathering.doc 5