CHEE 3101 Heat Transfer MINISTRY OF MANPOWER DIRECTORATE OF TECHNOLOGICAL EDUCATION HIGHER COLLEGE OF TECHNOLOGY ENGINEERING DEPARTMENT MECHANICAL ENGINEERING SECTION Specialization: Chemical Engineering Level : Advanced Diploma Course Name : Heat Transfer Course Code : CHEE 3101 Student Name Student ID No. Chemical Engineering :: ::::For Internal circulation Only:::: Page 0 CHEE 3101 Heat Transfer CHAPTER 1 Fundamentals of Heat Transfer (Outcomes 1) 1.1 Introduction The present standard of living is made possible by the energy available in the form of heat from various sources like fuels. The process by which this energy is converted for everyday use is studied under thermodynamics, leaving out the rate at which the energy is transferred. In all applications, the rate at which energy is transferred as heat plays an important role. The design of all equipment involving heat transfer requires the estimate of the rate of heat transfer. There is no need to list the various equipment where heat transfer rate influences their operation. The driving potential or the force which causes the transfer of energy as heat is the difference in temperature between systems. Other such transport processes are the transfer of momentum, mass and electrical energy. In addition to the temperature difference, physical parameters like geometry, material properties like conductivity, flow parameters like flow velocity also influence the rate of heat transfer. The aim of this text is to introduce the various rate equations and methods of determination of the rate of heat transfer across system boundaries under different situations. 1.2 Thermodynamics • • • • Energy can be transferred between a system and its surroundings. A system interacts with its surroundings by exchanging work and heat Deals with equilibrium states (Ideal conditions). Does not give information about: – Rates at which energy is transferred – Mechanisms through with energy is transferred – Factors affecting the energy transfer – Real time problems & applications Chemical Engineering :: ::::For Internal circulation Only:::: Page 1 CHEE 3101 Heat Transfer In this chapter we will learn What is heat transfer How is heat transferred Relevance and importance 1.3 Thermodynamics Vs Heat transfer Thermodynamics tells about • how much heat is transferred • how much work is done • final state of the system Heat transfer tells about • how heat is transferred (different modes of transfer) • At what rate heat is transferred • Temperature distribution inside the body Heat transfer deals about study of thermal energy transfer that is induced by a temperature difference (or gradient) 1.4 Modes of heat transfer • Conduction heat transfer: Occurs when a temperature gradient exists through a solid or a stationary fluid (liquid or gas). • Convection heat transfer: Occurs within a moving fluid, or between a solid surface and a moving fluid, when they are at different temperatures. • Thermal radiation: Heat transfer between two surfaces (that are not in contact), often in the absence of an intervening medium. Chemical Engineering :: ::::For Internal circulation Only:::: Page 2 CHEE 3101 Heat Transfer 1.4.1 Conduction Transfer of energy from the more energetic to less energetic particles of a substance by contact of particles of matter. Mechanisms of conduction: Lattice Vibration Particle collisions Lattice Vibration: Particle collision (observed in matters having lot of free electrons) • Conduction through electron collisions is more effective than conduction through lattice vibration • Metals (particle collision) are good conductors of heat (Eg: Copper) as they have lot of free electrons. Chemical Engineering :: ::::For Internal circulation Only:::: Page 3 CHEE 3101 Heat Transfer • Ceramic materials, inert gases etc., doesn’t exhibit good conducting nature as they have very less free electrons. These materials are called Insulators. Conduction expressed by Fourier’s law of heat conduction as written below Fig. Heat conduction through a large plane wall of thickness Δx and area A 𝐴𝑟𝑒𝑎 𝑋 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 𝑑𝑖𝑓𝑓𝑒𝑟𝑒𝑛𝑐𝑒 Rate of heat conduction α 𝑇ℎ𝑖𝑐𝑘𝑛𝑒𝑠𝑠 𝑇1−𝑇2 ΔT dT 𝑄̇ conduction = k A = - kA = - kA Δx Δx dx Heat flux is the heat transfer per unit time per unit area, and is equal to 𝑄̇ q′̇ = 𝑨 Where, • • dT dx is the temperature gradient (oC/m) k is the thermal conductivity(W/moC or W/moK) • A is the area which is normal to the direction of heat transfer.(m2) Chemical Engineering :: ::::For Internal circulation Only:::: Page 4 CHEE 3101 Heat Transfer 1.4.2 Convection Energy transfer by random molecular motion (as in conduction) plus bulk (macroscopic) motion of the fluid. Relative motion between the surfaces is essential for convection. Typical convective scenario: 1. Hot surface heats the surrounding fluid (at the interface) 2. The interfacial fluid gets heated and becomes warmer. 3. A fluid movement gets created which replaces the warmer fluid (at the interface) with cooler fluid (in the main stream), which can draw more heat away from the surface. Based on the nature of the fluid movement creation, convection is classified as: o Natural (free) convection: flow induced by buoyancy forces, arising from density differences arising from temperature variations in the fluid o Forced convection: flow movement caused by external means like fan, blower etc. Natural Convection: In this case, the fluid movement is created by the warm fluid itself. The density of fluid (at the interface) decrease as it is heated; thus, hot fluids become lighter than cool fluids. Warm fluid surrounding a hot object rises, and is replaced by cooler fluid resulting in the self-induced fluid movement. Eg: Boiling of water in a kettle Chemical Engineering :: ::::For Internal circulation Only:::: Page 5 CHEE 3101 Heat Transfer Forced Convection: In this case, the fluid movement is created by an external agent like a fan or blower. Eg: Forced convection is what makes a windy, winter day feel much colder than a calm day with same temperature. The heat loss from your body is increased due to the constant replenishment of cold air by the wind. Natural wind and fans are the two most common sources of forced convection. Convective effect is predominantly felt in forced convection rather than free convection Convection is expressed by Newton’s law of cooling as 𝑄̇ = h As (Ts - T∞) Where, • h is the convection heat transfer coefficient (W/m2.oC or W/m2.oK) • As is the surface area through which convection heat transfer takes place (m2) • Ts is the surface temperature (oC) • T∞ is the temperature of the fluid sufficiently far from the surface (oC) 1.4.3 Radiation Radiation is the energy emitted by matter in the form of electromagnetic waves (or photons) as a result of the changes in the electronic configurations of the atoms or molecules. Unlike conduction and convection, the transfer of energy by radiation does not require the presence of an intervening medium. In fact, energy transfer by radiation is fastest (at the speed of light) and it suffers no attenuation in a vacuum. Chemical Engineering :: ::::For Internal circulation Only:::: Page 6 CHEE 3101 Heat Transfer Any body maintain above absolute zero kelvin temperature can emit radiation. This is how the energy of the sun reaches the earth. The maximum rate of radiation that can be emitted from a surface at an absolute temperature Ts (in K or R) is given by Stefan–Boltzmann law as 𝑄̇ = σ As Ts4 where σ = 5.67 X 10-8 W/m2·K4 is the Stefan–Boltzmann constant. The idealized surface that emits radiation at this maximum rate is called a blackbody, and the radiation emitted by a blackbody is called blackbody radiation. Emissive power E is the rate at which energy is released per unit area (W/m2) (radiation emitted from the surface) Irradiation G is the rate of incident radiation per unit area (W/m2) of the surface (radiation absorbed by the surface), originating from its surroundings. ****************** Chemical Engineering :: ::::For Internal circulation Only:::: Page 7 on n CHEE 3101 Heat Transfer CHAPTER 2 (Outcomes: 2, 3, and 4) Heat Conduction Equation Distinguish between steady and unsteady heat transfer. Realize the significance of Fourier’s law, thermal conductivity and heat transfer coefficients in solving heat transfer problems. Calculate temperature distribution and heat transfer rates by conduction through solids, in flat slabs/plates, in pipes, in cylinders- as single body or in series. 2.1 Steady versus Unsteady (Transient) Heat Transfer Heat transfer problems are often classified as being steady (also called steady state) or transient (also called unsteady). The term steady implies no change with time at any point within the medium, while transient implies variation with time or time dependence. Therefore, the temperature or heat flux remains unchanged with time during steady heat transfer through a medium at any location, although both quantities may vary from one location to another (Fig. 2-1). For example, heat transfer through the walls of a house will be steady when the conditions inside the house and the outdoors remain constant for several hours. But even in this case, the temperatures on the inner and outer surfaces of the wall will be different unless the temperatures inside and outside the house are the same. The cooling of an apple in a refrigerator, on the other hand, is a transient heat transfer process since the temperature at any fixed point within the apple will change with time during cooling. During transient heat transfer, the temperature normally varies with time as well as position. As a special Case, the temperature of the medium changes uniformly with time but not with position. Such heat transfer systems are called lumped systems. A small metal object such as a thermocouple junction or a thin copper wire, for example, can be analyzed as a lumped system during a heating or cooling process. Most heat transfer problems encountered in practice are transient in nature, but they are Chemical Engineering :: ::::For Internal circulation Only:::: Page 8 CHEE 3101 Heat Transfer usually analyzed under some presumed steady conditions since steady processes are easier to analyze, and they provide the answers to our questions. Fig.2-1 Steady and Transient Heat Conduction in Plane Wall 2.2.0 Different coordinate systems The Various distances and angles involved when describing the location of a point in different coordinate systems as shown below in the figure. Fig.2-2 Different Coordinates System Chemical Engineering :: ::::For Internal circulation Only:::: Page 9 CHEE 3101 Heat Transfer 2.2.1 Multidimensional Heat Transfer A Heat transfer problems are also classified as being: one-dimensional two dimensional three-dimensional In the most general case, heat transfer through a medium is three-dimensional. However, some problems can be classified as two- or one-dimensional depending on the relative magnitudes of heat transfer rates in different directions and the level of accuracy desired. One-dimensional if the temperature in the medium varies in one direction only and thus heat is transferred in one direction, and the variation of temperature and thus heat transfer in other directions are negligible or zero. Two-dimensional if the temperature in a medium, in some cases, varies mainly in two primary directions, and the variation of temperature in the third direction (and thus heat transfer in that direction) is negligible. Fig. 2-3 Fig. 2-4 Chemical Engineering :: ::::For Internal circulation Only:::: Page 10 CHEE 3101 Heat Transfer The rate of heat conduction through a medium in a specified direction (say, in the x-direction) is expressed by Fourier’s law of heat conduction for one-dimensional heat conduction as: (Eqn. 2-1) Heat is conducted in the direction of decreasing temperature, and thus the temperature gradient is negative when heat is conducted in the positive x -direction. Fig. 2-5 The heat flux vector at a point P on the surface of figure must be perpendicular to the surface, and it must point in the direction of decreasing temperature If n is the normal of the isothermal surface at point P, the rate of heat conduction at that point can be expressed by Fourier’s law as (Eqn. 2-2) Fig. 2-6 Chemical Engineering :: ::::For Internal circulation Only:::: Page 11 CHEE 3101 Heat Transfer 2.3 Heat generation A medium through which heat is conducted may involve the conversion of electrical, nuclear, or chemical energy into heat (or thermal) energy. In heat conduction analysis, such conversion processes are characterized as heat generation. For example when electric current passes through wire it generate heat, likewise a large amount of heat is generated in the fuel elements of nuclear reactor, another source of heat generation in a medium is exothermic chemical reactions that may occur throughout the medium. Note that heat generation is a volumetric phenomenon. Therefore, the rate of heat generation in a medium is usually specified per unit volume and is denoted by 𝑔̇ , whose unit is W/m3. The total rate of heat generation in a medium of volume V can be determined from 𝐺̇ = ∫𝑣 𝑔̇ 𝑑𝑣 (Eqn.2-3) In the special case of uniform heat generation, as in the case of electric resistance heating throughout a homogeneous material, the relation in Eqn. 2.3 reduces to 𝐺̇ = 𝑔̇ 𝑉 (Eqn.2-4) where 𝑔̇ is the constant rate of heat generation per unit volume. Example: 2.1. The resistance wire of a 1200-W hair dryer is 80 cm long and has a diameter of 0.3 cm. Determine the rate of heat generation in the wire per unit volume, in W/cm3, and the heat flux on the outer surface of the wire as a result of this heat generation. Solution: Power consumed by the resistance wire of a hair dryer is given. The heat generation and the heat flux are to be determined. Assumptions: Heat is generated uniformly in the resistance wire. Chemical Engineering :: ::::For Internal circulation Only:::: Page 12 CHEE 3101 Heat Transfer Analysis : A 1200-W hair dryer will convert electrical energy into heat in the wire at a rate of 1200 W. Therefore, the rate of heat generation in a resistance wire is equal to the power consumption of a resistance heater. Then the rate of heat generation in the wire per unit volume is determined by dividing the total rate of heat generation by the volume of the wire, Similarly, heat flux on the outer surface of the wire as a result of this heat generation is determined by dividing the total rate of heat generation by the surface area of the wire, 2.4 Thermal conductivity As discussed earlier, the heat conduction is the transmission of energy by molecular action. Thermal conductivity is the property of a particular substance and it can be defined as the rate of heat transfer through a substance (i.e., material) per unit area per unit temperature difference. Higher the thermal conductivity more easily will be the heat conduction through the substance and it indicates that the substance is good conductor, and low value indicates that the substance is poor heat conductor or good insulator. It can be realized that the thermal conductivity of a substance would be dependent on the chemical composition, phase (gas, liquid, or solid), crystalline structure (if solid), temperature, pressure, and its homogeneity. The general notation of thermal conductivity is ‘k’ and the unit is W/moC or W/moK. Chemical Engineering :: ::::For Internal circulation Only:::: Page 13 CHEE 3101 Heat Transfer Table-2.1: Thermal conductivity of various substances [8] Table-2.2: Thermal conductivity of mercury at three different phases [8] Chemical Engineering :: ::::For Internal circulation Only:::: Page 14 CHEE 3101 Heat Transfer The general results of the careful analysis of the Table-2.1 and 2.2 are as follows, Thermal conductivity depends on the chemical composition of the substance. Thermal conductivity of the liquids is more than the gasses and the metals have the highest. Thermal conductivity of the gases and liquids increases with the increase in temperature. Thermal conductivity of the metal decreases with the increase in temperature. Thermal conductivity is affected by the phase change. 2.5 Thermal diffusivity/ specific heat/ heat capacity Now we know that the thermal conductivity facilitates the heat to propagate through the material due to the temperature gradient. Similarly, specific heat is the capacity of heat stored by a material due to variation in temperature. Thus the specific heat (unit: kJ/kg·oC) is defined as the amount of thermal energy required to raise the temperature of a unit amount of material by 1oC. The product ρCp, which is frequently encountered in heat transfer analysis, is called the heat capacity of a material. Both the specific heat C p and the heat capacity ρCp represent the heat storage capability of a material. But Cp expresses it per unit mass whereas ρCp expresses it per unit volume, as can be noticed from their units J/kg · °C and J/m3 · °C, respectively. Another material property that appears in the transient heat conduction analysis is the thermal diffusivity, which represents how fast heat diffuses through a material and is defined as α= Heat conducted / Heat stored = k /ρCp (Eqn.2.5) Note that the thermal conductivity k represents how well a material conducts heat, and the heat capacity ρCp represents how much energy a material stores per unit volume. Therefore, the thermal diffusivity of a material can be viewed as the ratio of the heat conducted through the material to the heat stored per unit volume. A material that has a high thermal conductivity or a low heat capacity will obviously Chemical Engineering :: ::::For Internal circulation Only:::: Page 15 CHEE 3101 Heat Transfer have a large thermal diffusivity. The larger the thermal diffusivity, the faster the propagation of heat into the medium. A small value of thermal diffusivity means that heat is mostly absorbed by the material and a small amount of heat will be conducted further. You may be aware that any flow whether it is electricity flow, fluid flow, or heat flow needs a driving force. The flow is proportional to the driving force and for various kinds of flows the driving force is shown in the table 2.3. Table 2.3. Various flows and their driving forces Thus the heat flow per unit area per unit time (heat flux, the following relation, ) can be represented by Where, proportionality constant k is the thermal conductivity of the material, T is the temperature and x is the distance in the direction of heat flow. This is known as Fourier’s law of conduction. The term steady-state conduction is defined as the condition which prevails in a heat conducting body when temperatures at fixed points do not change with time. The term one-dimensional is applied to a heat conduction problem when only one coordinate is required to describe the distribution of temperature within the body. 2Such a situation hardly exists in real engineering problems. However, by Chemical Engineering :: ::::For Internal circulation Only:::: Page 16 CHEE 3101 Heat Transfer considering one-dimensional assumption the real problem is solved fairly upto the accuracy of practical engineering interest. 2.6 One Dimensional Steady-State Conduction through Constant Area A simple case of steady-state, one-dimensional heat conduction can be considered through a flat wall as shown in the fig.2.1. Fig.2-7: Steady-state conduction through a slab (constant area) The flat wall of thickness dx is separated by two regions, the one region is at high temperature (T1 ) and the other one is at temperature T2 . The wall is very large in comparison of the thickness so that the heat losses from the edges are negligible. Consider there is no generation or accumulation of the heat in the wall and the external surfaces of the wall are at isothermal temperatures T1 and T2 . The area of the surface through which the heat transfer takes place is A. Then the eqn.2.7 can be written as, The negative sign shows that the heat flux is from the higher temperature surface to the lower temperature surface and is the rate of heat transfer through the wall. Chemical Engineering :: ::::For Internal circulation Only:::: Page 17 CHEE 3101 Heat Transfer 𝑞̇ = −kA 𝑇2 −𝑇1 𝑥2 −𝑥1 (𝑜𝑟) 𝑞̇ = 𝑇1 −𝑇2 𝑥 −𝑥 ( 2𝑘𝐴 1 ) (𝑜𝑟) 𝑞̇ = 𝑇1 −𝑇2 ( 𝐿 ) 𝑘𝐴 (2-11) Where, L = dx = thickness of the slab 𝑞̇ = ∆𝑇 (2-12) 𝑅𝑡ℎ Now if we consider a plane wall made up of three different layers of materials having different thermal conductivities and thicknesses of the layers, the analysis of the conduction can be done as follows. Consider the area (A) of the heat conduction (fig.2-8) is constant and at steady state the rate of heat transfer from layer-1 will be equal to the rate of heat transfer from layer-2. Similarly, the rate of heat transfer through layer-2 will be equal to the rate of heat transfer through layer-3. If we know the surface temperatures of the wall are maintained at T1 and T2 as shown in the fig.2.2, the temperature of the interface of layer1 and layer 2 is assumed to be at T' and the interface of layer-2 and layer-3 as T". Fig.2.8: Heat conduction through three different layers The rate of heat transfer through layer-1 to layer-2 will be, Chemical Engineering :: ::::For Internal circulation Only:::: Page 18 CHEE 3101 Heat Transfer and, The rate of heat transfer through layer 2 to layer 3 will be, and, The rate of heat transfer through layer 3 to the other side of the wall, On adding the above three equations, 2.7 Thermal Resistance Network with Film Contact Resistance Now consider steady one-dimensional heat flow through a plane wall of thickness L, area A, and thermal conductivity k that is exposed to convection on both sides to fluids at temperatures T∞1 and T∞2 with heat transfer coefficients h1 and h2, respectively, as shown in Fig.. Assuming T∞2 ≤ T∞1, the variation of temperature will be as shown in the figure. Note that the temperature varies linearly in the wall, and asymptotically approaches T1 and T2 in the fluids as we move away from the wall. Under steady conditions we have Chemical Engineering :: ::::For Internal circulation Only:::: Page 19 CHEE 3101 Heat Transfer It is sometimes convenient to express heat transfer through a medium in an analogous manner to Newton’s law of cooling as (Eqn.2.18) Where U is the overall heat transfer coefficient. (unit: W/m2. 0C (or) W/m2. 0K) 2.7.1 The Thermal Resistance Network for Heat Transfer Through A Two-Layer Plane Wall Subjected to Convection On Both Sides. The surface temperature of the wall can be determined as described above using the thermal resistance concept, but by taking the surface at which the temperature Chemical Engineering :: ::::For Internal circulation Only:::: Page 20 CHEE 3101 Heat Transfer is to be determined as one of the terminal surfaces. For example, once Q · is evaluated, the surface temperature T1 can be determined from (Eqn. 2.19) 2.8 Thermal Resistance (Electrical Analogy): Physical systems are said to be analogous if that obey the same mathematical equation. The above relations can be put into the form of Ohm’s law: V=IRelec Chemical Engineering :: ::::For Internal circulation Only:::: Page 21 CHEE 3101 Heat Transfer Using this terminology it is common to speak of a thermal resistance: A thermal resistance may also be associated with heat transfer by convection at a surface. From Newton’s law of cooling, (Eqn. 2.20) The thermal resistance for convection is then (Eqn. 2.21) The unit of the various parameters used above is summarized as follows, __________________________ Chemical Engineering :: ::::For Internal circulation Only:::: Page 22 CHEE 3101 Heat Transfer Example 2.2 The two sides of a wall (2 mm thick, with a cross-sectional area of 0.2 m2) are maintained at 30oC and 90oC. The thermal conductivity of the wall material is 1.28 W/(m·oC). Find out the rate of heat transfer through the wall? Assumptions 1.Steady-state one-dimensional conduction 2. Thermal conductivity is constant for the temperature range of interest 3. The heat loss through the edge side surface is insignificant 4. The layers are in perfect thermal contact Chemical Engineering :: ::::For Internal circulation Only:::: Page 23 CHEE 3101 Heat Transfer Example 2.3 One side of a 1 cm thick stainless steel wall (k 1 = 19 W/moC) is maintained at 180oC and the other side is insulated with a layer of 4 cm fiberglass (k 2 = 0.04 W/moC). The outside of the fiberglass is maintained at 60o C and the heat loss through then wall is 300 W. Determine the area of the wall. Chemical Engineering :: ::::For Internal circulation Only:::: Page 24 CHEE 3101 Heat Transfer The previous discussion showed the resistances of different layers. Now to understand the concept of equivalent resistance, we will consider the geometry of a composite as shown in fig.2-9a. The wall is composed of seven different layers indicated by 1 to 7. The interface temperatures of the composite are T1 to T5 as shown in the fig.2-9a. The equivalent electrical circuit of the above composite is shown in the fig 2-9b below, Fig.2-9. (a) Composite wall, and (b) equivalent electrical circuit The equivalent resistance of the wall will be, Chemical Engineering :: ::::For Internal circulation Only:::: Page 25 CHEE 3101 Heat Transfer where, Therefore, at steady state the rate of heat transfer through the composite can be represented by, Where, R is the equivalent resistance. -----------------------------------------------------Example: 2.3 Consider a composite wall containing 5-different materials as shown in the fig.210. Calculate the rate of heat flow through the composite from the following data? Assumptions: 1. Steady-state one-dimensional conduction. 2. Thermal conductivity is constant for the temperature range of interest. 3. The heat loss through the edge side surface is insignificant. 4. The layers are in perfect thermal contact. 5. Area in the direction of heat flow is 1 m2. Chemical Engineering :: ::::For Internal circulation Only:::: Page 26 CHEE 3101 Heat Transfer Fig. 2-10 (a) composite, (b) corresponding electrical circuit The height of the first layer is 4 m (h1 = h2 + h3 ). Chemical Engineering :: ::::For Internal circulation Only:::: Page 27 CHEE 3101 Heat Transfer 2.9 Thermal contact resistance In the previous discussion, it was assumed that the different layers of the composite have perfect contact between any two layers. Therefore, the temperatures of the layers were taken same at the plane of contact. However, in reality it rarely happens, and the contacting surfaces are not in perfect contact or touch as shown in the fig.2-11 (a). It is because as we know that due to the roughness of the surface, the solid surfaces are not perfectly smooth. Thus when the solid surfaces are contacted the discrete points of the surfaces are in contact and the voids are generally filled with the air. Therefore, the heat transfer across the composite is due to the parallel effect of conduction at solid contact points and by convection or probably by radiation (for high temperature) through the entrapped air. Thus an apparent temperature drop may be assumed to occur between the two solid surfaces as shown in the fig.2-11b. If TI and TII are the theoretical temperature of the plane interface, then the thermal contact resistance may be defined as, Fig.2-11. (a) Contacting surfaces of two solids are not in perfect contact, (b) temperature drop due to imperfect contact Chemical Engineering :: ::::For Internal circulation Only:::: Page 28 CHEE 3101 Heat Transfer where Rc represents the thermal contact resistance. 2.10 Steady-state heat conduction through a variable area It was observed in the previous discussion that for the given plane wall the area for heat transfer was constant along the heat flow direction. The plane solid wall was one of the geometries but if we take some other geometry (tapered plane, cylindrical body, spherical body etc.) in which the area changes in the direction of heat flow. 2.10.1 One Dimensional Steady State Heat Conduction in Cylinders and Spheres Consider a hollow cylinder as shown in the fig.2.9a. The inner and outer radius is represented by ri and ro , whereas Ti and To (Ti > To ) represent the uniform temperature of the inner and outer wall, respectively. Fig. 2-12. (a) Hollow cylinder, (b) equivalent electrical circuit Chemical Engineering :: ::::For Internal circulation Only:::: Page 29 CHEE 3101 Heat Transfer Consider a very thin hollow cylinder of thickness dr in the main geometry (fig.212a) at a radial distance r. If ‘dr’ is small enough with respect to r, then the area of the inner and outer surface of the thin cylinder may be considered to be of same area. In other words, for very small ‘dr’ with respect to r, the lines of heat flow may be considered parallel through the differential element in radial outward direction. We may ignore the heat flow through the ends if the cylinder is sufficiently large. We may thus eliminate any dependence of the temperature on the axial coordinate and for one dimensional steady state heat conduction, the rate of heat transfer for the thin cylinder, (Where, A= surface area of cylinder) Where dT is the temperature difference between the inner and outer surface of the thin cylinder considered above and k is the thermal conductivity of the cylinder. On re arranging, To get the heat flow through the thick wall cylinder, the above equation can be integrated between the limits, On solving, Note: Rcylinder = (ro –ri)/(2𝝅Lk) Chemical Engineering :: ::::For Internal circulation Only:::: (2.26) Page 30 CHEE 3101 Heat Transfer We can repeat the analysis above for a spherical layer by taking A = 4πr2 and the result can be expressed as Note: Rsphere = (ro –ri)/(4𝝅krori) (2.28) Now consider steady one-dimensional heat flow through a cylindrical or spherical layer that is exposed to convection on both sides to fluids at temperatures T1 and T2 with heat transfer coefficients h1 and h2, respectively, as shown in Fig. The thermal resistance network in this case consists of one conduction and two convection resistances in series, just like the one for the plane wall, and the rate of heat transfer under steady conditions can be expressed as Where, For cylindrical layer: (2.29) Chemical Engineering :: ::::For Internal circulation Only:::: Page 31 CHEE 3101 Heat Transfer For spherical layer: (2.30) Note that A in the convection resistance relation Rconv = 1/hA is the surface area at which convection occurs. It is equal to A = 2πrL for a cylindrical surface and A = 4πr 2 for a spherical surface of radius r. Also note that the thermal resistances are in series, and thus the total thermal resistance is determined by simply adding the individual resistances, just like the electrical resistances connected in series. 2.10.2 Multi Layered Cylinders and Spheres Steady heat transfer through multilayered cylindrical or spherical shells can be handled just like multilayered plane walls discussed earlier by simply adding an additional resistance in series for each additional layer. For example, the steady heat transfer rate through the three-layered composite cylinder of length L shown in Fig. with convection on both sides can be expressed as Chemical Engineering :: ::::For Internal circulation Only:::: Page 32 CHEE 3101 Heat Transfer (2.31) where A1 = 2πr1L and A4 = 2πr4L. The above Equation can also be used for a threelayered spherical shell by replacing the thermal resistances of cylindrical layers by the corresponding spherical ones. The ratio T/R across any layer is equal to Q, which remains constant in one-dimensional steady conduction. Chemical Engineering :: ::::For Internal circulation Only:::: Page 33 CHEE 3101 Heat Transfer 2.11 One Dimensional Heat Conduction Equation. Consider heat conduction through a large plane wall such as the wall of a house, the glass of a single pane window, the metal plate at the bottom of a pressing iron, a cast iron steam pipe, a cylindrical nuclear fuel element, an electrical resistance wire, the wall of a spherical container, or a spherical metal ball that is being quenched or tempered. Heat conduction in these and much other geometry can be approximated as being onedimensional since heat conduction through these geometries will be dominant in one direction and negligible in other directions. Below we will develop the one dimensional heat conduction equation in rectangular, cylindrical, and spherical coordinates. Heat Conduction Equation in a Large Plane Wall Consider a thin element of thickness x in a large plane wall, as shown in Figure, Assume the density of the wall is , the specific heat is C, and the area of the wall normal to the direction of heat transfer is A. An energy balance on this thin element during a small time interval t can be expressed as (Eqn.2.32) Chemical Engineering :: ::::For Internal circulation Only:::: Page 34 CHEE 3101 Heat Transfer But the change in the energy content of the element and the rate of heat generation within the element can be expressed as By solving, knowing k-thermal conductivity, α-thermal diffusivity=k/ρC, we have (Eqn.2.33) (Eqn.2.34) (Eqn. 2.35) 2.11.1 Boundary Conditions-Initial Conditions – (Plane Wall) The description of a heat transfer problem in a medium is not complete without a full description of the thermal conditions at the bounding surfaces of the medium. Boundary conditions: The mathematical expressions of the thermal conditions at the boundaries. Chemical Engineering :: ::::For Internal circulation Only:::: Page 35 CHEE 3101 Heat Transfer From a mathematical point of view, solving a differential equation is essentially a process of removing derivatives, or an integration process, and thus the solution of a differential equation typically involves arbitrary constants The temperature at any point on the wall at a specified time depends on the condition of the geometry at the beginning of the heat conduction process. Such a condition, which is usually specified at time t = 0, is called the initial condition, which is a mathematical expression for the temperature distribution of the medium initially. The general solution of a typical To describe a heat transfer problem differential equation involves arbitrary completely, two boundary conditions must be constants, and thus an infinite number of given for each direction along which heat transfer is significant. solutions. Specified Temperature Boundary Condition One of the easiest ways to specify the thermal conditions on a surface is to specify the temperature. For one-dimensional heat transfer through a plane wall of thickness L, the specified temperature boundary conditions can be expressed as T(0, t) = T1 ; T(L, t) = T2, where T1 and T2 are the specified temperatures at Chemical Engineering :: ::::For Internal circulation Only:::: Page 36 CHEE 3101 Heat Transfer surfaces at x = 0 and x = L, The specified temperatures can be constant, which is the case for steady heat conduction, or may vary with time. Specified Heat Flux Boundary Condition The heat flux in the positive x-direction anywhere in the medium, including the boundaries, can be expressed by (Eqn. 2.36) For a plate of thickness L subjected to heat flux of 50 W/m2 into the medium from both sides, for example, the specified heat flux boundary conditions can be expressed as Chemical Engineering :: ::::For Internal circulation Only:::: Page 37 CHEE 3101 Heat Transfer Special Case: Insulated Boundary A well-insulated surface can be modeled as a surface with a specified heat flux of zero. Then the boundary condition on a perfectly insulated surface (at x = 0, for example) can be expressed as (Eqn. 2.37) On an insulated surface, the first derivative of temperature with respect to the space variable (the temperature gradient) in the direction normal to the insulated surface is zero. Another Special Case: Thermal Symmetry The two surfaces of a large hot plate of thickness L suspended vertically in air is subjected to the same thermal conditions, and thus the temperature distribution in one half of the plate is the same as that in the other half. That is, the heat transfer problem in this plate possesses thermal symmetry about the center plane at x = L/2. Therefore, the center plane can be viewed as an insulated surface, and the thermal condition at this plane of symmetry can be expressed as (Eqn. 2.38) Chemical Engineering :: ::::For Internal circulation Only:::: Page 38 CHEE 3101 Heat Transfer which resembles the insulation or zero heat flux boundary condition. 2.11.2 The solution procedure for solving heat conduction problems can be summarized as (1) formulate the problem by obtaining the applicable differential equation in its simplest form and specifying the boundary conditions, (2) Obtain the general solution of the differential equation, and (3) apply the boundary conditions and determine the arbitrary constants in the general solution --------------------------------------------------------- Example: 2.4. Consider a large plane wall of thickness L = 0.2 m, thermal conductivity k = 1.2 W/moK, and surface area A = 15 m2. The two sides of the wall are maintained at constant temperatures of T1 = 120°C and T2 = 50°C, respectively. Determine (a) the variation of temperature within the wall and the value of temperature at x = 0.1 m and (b) the rate of heat conduction through the wall under steady conditions. Assumptions 1 Heat conduction is steady. 2 Heat conduction is one-dimensional since the wall is large relative to its thickness and the thermal conditions on both sides are uniform. 3 Thermal conductivity is constant. 4 There is no heat generation. Analysis (a) Taking the direction normal to the surface of the wall to be the xdirection, the differential equation for this problem can be expressed as Chemical Engineering :: ::::For Internal circulation Only:::: Page 39 CHEE 3101 Heat Transfer With boundary conditions T(0) = T1 = 120°C T(L) = T2 = 50°C Integrating the differential equation once with respect to x yields where C1 is an arbitrary constant. Integrating one more time, we obtain T(x) = C1x + C2 This is the general solution of the differential equation. The first boundary condition can be interpreted as in the general solution, re-place all the x's by zero and T(x) by T1. T(0) = C1 x 0 + C2 C2 = T1 The second boundary condition can be interpreted as in the general solution, replace all the x's by L and T(x) by T2. That is, Substituting the C1 and C2 expressions into the general solution, we obtain Substituting the given information, the value of the temperature at x = 0.1 m is determined to be (b) The rate of heat conduction anywhere in the wall is determined from Fourier's law to be Chemical Engineering :: ::::For Internal circulation Only:::: Page 40 CHEE 3101 Heat Transfer The numerical value of the rate of heat conduction through the wall is deter-mined by substituting the given values to be Example: 2.5 Consider a 0.8-m-high and 1.5-m-wide double-pane window consisting of two 4mm-thick layers of glass (k = 0.78 W/m.°C) separated by a 10-mm-wide stagnant air space (k = 0.026 W/m.°C). Determine the steady rate of heat transfer through this double-pane window and the temperature of its inner surface for a day during which the room is maintained at 20°C while the temperature of the outdoors is 10°C. Take the convection heat transfer coefficients on the inner and outer surfaces of the window to be h1 = 10 W/m2.°C and h2= 40 W/m2.°C, which includes the effects of radiation. Chemical Engineering :: ::::For Internal circulation Only:::: Page 41 CHEE 3101 Heat Transfer 2.12 One Dimensional General Heat Conduction Equation in a Long Cylinder Chemical Engineering :: ::::For Internal circulation Only:::: Page 42 CHEE 3101 Heat Transfer (Eqn. 2.39) 2.13 Heat Conduction Equation in a Sphere Chemical Engineering :: ::::For Internal circulation Only:::: Page 43 CHEE 3101 Heat Transfer (Eqn. 2.40) Example: 2.6 A 3-m internal diameter spherical tank made of 2-cm-thick stainless steel (k = 15 W/m · °C) is used to store iced water at T1 = 0°C. The tank is located in a room whose temperature is T2 = 22°C. The walls of the room are also at 22°C. The outer surface of the tank is black and heat transfer between the outer surface of the tank and the surroundings is by natural convection and radiation. The convection heat transfer coefficients at the inner and the outer surfaces of the tank are h 1 = 80 W/m2 °C and h2 = 10 W/m2 °C, respectively. Determine (a) the rate of heat transfer to the iced water in the tank and (b) the amount of ice at 0°C that melts during a 24-h period. Chemical Engineering :: ::::For Internal circulation Only:::: Page 44 CHEE 3101 Heat Transfer Chemical Engineering :: ::::For Internal circulation Only:::: Page 45 CHEE 3101 Heat Transfer Chemical Engineering :: ::::For Internal circulation Only:::: Page 46 CHEE 3101 Heat Transfer Example: 2.7 Steam at T1 =320°C flows in a cast iron pipe (k = 80 W/m.°C) whose inner and outer diameters are D1 =5 cm and D2 = 5.5 cm, respectively. The pipe is covered with 3-cm-thick glass wool insulation with k =0.05 W/m.°C. Heat is lost to the surroundings at T2 = 5°C by natural convection and radiation, with a combined heat transfer coefficient of h2 = 18 W/m2.°C. Taking the heat transfer coefficient inside the pipe to be h1 = 60 W/m2 · °C, determine the rate of heat loss from the steam per unit length of the pipe. Also determine the temperature drops across the pipe shell and the insulation. Chemical Engineering :: ::::For Internal circulation Only:::: Page 47 CHEE 3101 Heat Transfer That is, the temperatures between the inner and the outer surfaces of the pipe differ by 0.02°C, whereas the temperatures between the inner and the outer surfaces of the insulation differ by 284°C. 2.14 CRITICAL RADIUS OF INSULATION Adding more insulation to a wall or to the attic always decreases heat transfer. The thicker the insulation, the lower the heat transfer rate. This is expected, since the heat transfer area A is constant, and adding insulation always increases the thermal resistance of the wall without increasing the convection resistance. Adding insulation to a cylindrical pipe or a spherical shell, however, is a different matter. The additional insulation increases the conduction resistance of the insulation layer Chemical Engineering :: ::::For Internal circulation Only:::: Page 48 CHEE 3101 Heat Transfer but decreases the convection resistance of the surface because of the increase in the outer surface area for convection. Consider a cylindrical pipe of outer radius r1 whose outer surface temperature T1 is maintained constant (Fig). The pipe is now insulated with a material whose thermal conductivity is k and outer radius is r2. Heat is lost from the pipe to the surrounding medium at temperature T, with a convection heat transfer coefficient h. The rate of heat transfer from the insulated pipe to the surrounding air can be expressed as The variation of Q with the outer radius of the insulation r2 The value of r2 at which Q reaches a maximum is determined from the requirement that dQ/dr2 = 0 (zero slope). Performing the differentiation and solving for r2 yields the critical radius of insulation for a cylindrical body to be Chemical Engineering :: ::::For Internal circulation Only:::: Page 49 CHEE 3101 Heat Transfer Note that the critical radius of insulation depends on the thermal conductivity of the insulation k and the external convection heat transfer coefficient h. The rate of heat transfer from the cylinder increases with the addition of insulation for r 2 rcr, reaches a maximum when r2 = rcr, and starts to decrease for r2 rcr. Thus, insulating the pipe may actually increase the rate of heat transfer from the pipe instead of decreasing it when r2 rcr. In a similar manner that the critical radius of insulation for a spherical shell is The effectiveness of insulation is often given in terms of its R-value, the thermal resistance of the material per unit surface area, expressed as Where L is the thickness and k is the thermal conductivity of the material. Example: 2.7 Calculate the critical radius of insulation for the pipe which is used for transport hot water, consider the lowest possible value of h=5 W/m2°C for the case of natural convection of gases. The thermal conductivity of common insulating materials which is used for insulation is about 0.05 W/m°C. Given : h=5 W/m2°C ; k=0.05 W/m °C The value of the critical radius, rc = kins/h = 0.05/5 = 0.01 m Chemical Engineering :: ::::For Internal circulation Only:::: Page 50 CHEE 3101 Heat Transfer Example: 2.8 A 3-mm-diameter and 5-m-long electric wire is tightly wrapped with a 2-mm thick plastic cover whose thermal conductivity is k = 0.15 W/m.°C. Electrical measurements indicate that a current of 10 A passes through the wire and there is a voltage drop of 8 V along the wire. If the insulated wire is exposed to a medium at T = 30°C with a heat transfer coefficient of h = 12 W/m2.°C, determine the temperature at the interface of the wire and the plastic cover in steady operation. Also determine whether doubling the thickness of the plastic cover will increase or decrease this interface temperature. In steady operation, the rate of heat transfer becomes equal to the heat generated within the wire, which is determined to be The values of the two thermal resistances are determined to be Chemical Engineering :: ::::For Internal circulation Only:::: Page 51 CHEE 3101 Heat Transfer and therefore the total resistance to be Then the interface temperature can be determined from Note that we did not involve the electrical wire directly in the thermal resistance network, since the wire involves heat generation. To answer the second part of the question, we need to know the critical radius of insulation of the plastic cover. It is determined to be This is larger than the radius of the plastic cover. Therefore, increasing the thickness of the plastic cover will enhance heat transfer until the outer radius of the cover reaches 12.5 mm. As a result, the rate of heat transfer Q̇ will increase when the interface temperature T1 is held constant, or T1 will decrease when Q̇ is held constant, which is the case here. Chemical Engineering :: ::::For Internal circulation Only:::: Page 52 CHEE 3101 Heat Transfer Assignment Questions: Q1. Thermal conductivity of water __________ with rise in temperature (A) (B) (C) (D) Increases remains same decreases may increase or decrease depending upon temperature Q2. Heat transfer takes place according to the statement of, (A) Zeroth Law of Thermodynamics (B) First Law of Thermodynamics (C) Second Law of Thermodynamics (D) Third Law of Thermodynamics Q3. For a current carrying metallic ball of 20 mm diameter exposed to air (h=25 W/m2K), maximum heat distribution occurs when the thickness of the insulation (K=0.5 W/mK) is: (A)10 mm (B) 20 mm (C) 30 mm (D) 40 mm Q4. For a current carrying metallic rod of 20 mm diameter exposed to air (h=25 W/m2K), maximum heat distribution occurs when the thickness of the insulation (K=0.5 W/mK) is: (A) 10 mm (B) 20 mm (C) 30 mm (D) 40 mm Q5. Heat is lost through a brick wall (k=0.72W/moK), which is 4m long, 3m wide, and 25cm thick at a rate of 500W. If the inner surface of the wall is at 22 oC, the temperature at the mid plane of the wall is (A) 0oC (B) 11oC Chemical Engineering :: (C) 14.8oC (D) 22oC ::::For Internal circulation Only:::: Page 53 CHEE 3101 Heat Transfer Q6. Consider the following: 1. Water 2.Wood 3. Air 4. Mercury Which of the following options correspond to the order of correct thermal conductivity at room temperature? (A)4>1>3>2 (B) 4>1>2>3 C) 1>4>3>2 (D) 1>4>2>3 Q7. It is proposed to coat a 1mm diameter wire with enamel paint (k=0.1 W/mK) to increase heat transfer with air. If the air side heat transfer coefficient is 100 W/m2K, the optimum thickness of enamel paint should be (A) 0.25 mm (B) 0.5 mm (C) 1 mm (D) 2 mm Q8. A 2-kW electric resistance heater submerged in 30-kg water is turned on and kept on for 10 min. During the process, 400 kJ of heat is lost from the water. The temperature rise of water is (A) 5.6°C (B) 6.4°C (C) 13.6°C (D) 23.3°C Q11. A furnace is made of a red brick wall of thickness 0.5 m and conductivity 0.7 W/mK. For the same heat loss and the temperature drop, this can be replaced by a layer of diatomite earth of conductivity of 0.14 W/mK and thickness should be: (A) 0.5 m (B) 0.1 m (C) 0.2 m (D) 0.4 m Q9. A gas filled tube has 2 mm inside diameter and 25 cm length. The gas is heated by an electrical wire of diameter 50 cm located along the axis of the tube. Current and voltage drop across the heating element are 0.5 amps and 4 volts, respectively. If the measured wire and inside tube wall temperatures are 175oC and 150oC respectively, find the thermal conductivity of the gas filling tube. (A) 0.12 W/moK (B) 0.15 W/moK Chemical Engineering :: (C) 0.17 W/moK ::::For Internal circulation Only:::: (D) 0.19 W/moK Page 54 CHEE 3101 Heat Transfer Q10. Electric current is passed through a copper ball 1 mm in diameter. The ball is submerged in liquid water at atmospheric pressure, and the current is increased until the water boils. For this situation h=5000W/m2 oC. How much electric power must be supplied to the wire to maintain the ball at 114oC? (A) 0.2199W (B) 21.99W (C) 25.64W (D) 0.2564 W Q12. Determine the correctness or otherwise of the following Assertion [a] and the Reason [r]. Assertion [a]: in case of insulating electrical wire the optimum thickness should be below critical thickness. Reason [r]: upto critical radius increment of conductive resistance is the predominant effect than decrement of convective resistance. (A) Both [a] and [r] are true and [r] is the correct reason for [a]. (B) Both [a] and [r] are true but [r] is NOT the correct reason for [a]. (C) [a] is true but [r] is false. (D) [a] is false but [r] is true. Q13. Determine the correctness or otherwise of the following Assertion [a] and the Reason [r]. Assertion [a]: in case of gases thermal conductivity increases with temperature. Reason [r]: in fluids conduction is due to Lattice vibrations & motion of free electrons. (A) (B) (C) (D) Both [a] and [r] are true and [r] is the correct reason for [a]. Both [a] and [r] are true but [r] is NOT the correct reason for [a]. [a] is true but [r] is false. [a] is false but [r] is true. Chemical Engineering :: ::::For Internal circulation Only:::: Page 55 CHEE 3101 Heat Transfer Q14. Match the following : (Group1) Temperature distribution along plane walls in series: (Group2) WALL MATERIAL (P) SLAB1 - (T) Copper (Q) SLAB2 - (U) Silver (R) SLAB3 - (V) Aluminium (S) SLAB4 - (W) Stainless steel (A) P-U,Q-V,R-W,S-T (B) P-T,Q-W,R-V,S-U (C) P-W,Q-U,R-T,S-V (D) P-V,Q-T,R-U,S-W Q15. A furnace wall is of three layers, first layer of insulation brick of 12 cm thickness of conductivity 0.6 W/mK. The face is exposed to gases at 870°C with a convection coefficient of 110 W/m2K. This layer is backed by a 10 cm layer of firebrick of conductivity 0.8 W/mK. There is a contact resistance between the layers of 2.6 × 10 –4 m2 °C/W. The third layer is the plate backing of 10 mm thickness of conductivity 49 W/mK. The contact resistance between the second and third layers is 1.5 × 10–4 m2 °C/W. The plate is exposed to air at 30°C with a convection coefficient of 15 W/m 2K. Determine the heat flow, the surface temperatures and the overall heat transfer coefficient. [Answer: T1 = 850.97°C; T2 = 432.40°C; T3 = 431.86°C; T4= 170.26°C T5 = 169.95°C; T6 = 169.52°C] Q16. A composite wall is made up of 3 layers of thicknesses 25 cm, 10 cm and 15 cm with thermal conductivities of 1.7, kB and 9.5 W/mK. The outside surface is exposed to air at 20°C with convection coefficient of 15 W/m2K and the inside is exposed to gases at 1200°C with a convection coefficient of 28 W/m2K and the inside surface is at 1080°C. Determine the unknown thermal conductivity, all surface temperatures, resistances of each layer and the overall heat transfer coefficient per unit area. [Answer: kB=1.163 W/moC; U=2.85 W/m2oC; T1 = 585.9°C; T2 = 297°C; T3 = 243.95°C] Chemical Engineering :: ::::For Internal circulation Only:::: Page 56 CHEE 3101 Heat Transfer Q15. A pipe carrying steam at 230°C has an internal diameter of 12 cm and the pipe thickness is 7.5 mm. The conductivity of the pipe material is 49 W/mK and the convective heat transfer coefficient on the inside is 85 W/m2K. The pipe is insulated by two layers of insulation one of 5 cm thickness of conductivity 0.15 W/mK and over it another 5 cm thickness of conductivity 0.48 W/mK. The outside is exposed to air at 35°C with a convection coefficient of 18 W/m2K. Determine the heat loss for 5 m length. Also determine the interface temperatures and the overall heat transfer coefficient based on inside and outside areas. [Answer: T1 = 222.3°C; T2 = 222.2°C; T3 = 77.04°C; T4 = 48.03°C] Q16. Derive the unidirectional temperature distribution equation for plane wall, hollow cylinder and hollow sphere from Laplace equation. Q17. With neat sketch derive the general two dimensional unsteady state heat conduction equation for an isotropic slab with internal heat generation. Simplify the obtained equation to Poisson’s equation, Fourier’s equation and Laplace equation. Q18. Using the general conduction equation for a Cartesian system, derive the expressions for the position and value of maximum temperature for plane wall with internal heat generation having, a. different surface temperature, b. same surface temperature, c. One surface insulated. Chemical Engineering :: ::::For Internal circulation Only:::: Page 57 CHEE 3101 Heat Transfer CHAPTER 3 (outcomes 5, 6, 7 and 12) 3.1 PHYSICAL MECHANISM OF CONVECTION The convection is the mechanism of heat transfer through a fluid in the presence of bulk fluid motion. Convection is classified as natural (or free) and forced convection, depending on how the fluid motion is initiated. In forced convection, the fluid is forced to flow over a surface or in a pipe by external means such as a pump or a fan. In natural convection, any fluid motion is caused by natural means such as the buoyancy effect, which manifests itself as the rise of warmer fluid and the fall of the cooler fluid. Convection is also classified as external and internal, depending on whether the fluid is forced to flow over a surface or in a channel. 3.2 Internal versus External Flow A fluid flow is classified as being internal and external, depending on whether the fluid is forced to flow in a confined channel or over a surface. The flow of an unbounded fluid over a surface such as a plate, a wire, or a pipe is external flow. The flow in a pipe or duct is internal flow if the fluid is completely bounded by solid surfaces. Water flow in a pipe, for example, is internal flow, and air flow over an exposed pipe during a windy day is external flow (Fig.). The flow of liquids in a pipe is called openchannel flow if the pipe is partially filled with the liquid and there is a free surface. The flow of water in rivers and irrigation ditches are examples for that. Chemical Engineering :: ::::For Internal circulation Only:::: Page 58 CHEE 3101 Heat Transfer 3.3 Laminar versus Turbulent Flow The highly ordered fluid motion characterized by smooth streamlines is called laminar. The flow of high-viscosity fluids such as oils at low velocities is typically laminar. The highly disordered fluid motion that typically occurs at high velocities characterized by velocity fluctuations is called turbulent. The flow of low-viscosity fluids such as air at high velocities is typically turbulent. The flow regime greatly influences the heat transfer rates and the required power for pumping. 3.4 3.4.1 Use of Non Dimensional Numbers in Heat Transfer Analysis Nusselt Number In convection studies, it is common practice to nondimensionalize the governing equations and combines the variables, which group together into dimensionless numbers in order to reduce the number of total variables. It is also common practice to nondimensionalize the heat transfer coefficient h with the Nusselt number, defined as Eq. 3.1 where k is the thermal conductivity of the fluid and Lc is the characteristic length. Significance: the Nusselt number represents the enhancement of heat transfer through a fluid layer as a result of convection relative to conduction across the same fluid layer. The larger the Nusselt number, the more effective the convection. A Nusselt number of Nu = 1 for a fluid layer represents heat transfer across the layer by pure conduction. 3.4.2 Prandtl Number The relative thickness of the velocity and the thermal boundary layers is best described by the dimensionless parameter Prandtl number, defined as Chemical Engineering :: ::::For Internal circulation Only:::: Page 59 CHEE 3101 Heat Transfer Eq. 3.2 The Prandtl numbers of fluids range from less than 0.01 for liquid metals to more than 100,000 for heavy oils. Note that the Prandtl number is in the order of 10 for water. The Prandtl numbers of gases are about 1, which indicates that both momentum and heat dissipate through the fluid at about the same rate. Heat diffuses very quickly in liquid metals (Pr « 1) and very slowly in oils (Pr » 1) relative to momentum. Consequently the thermal boundary layer is much thicker for liquid metals and much thinner for oils relative to the velocity boundary layer. 3.4.3 Reynolds Number The transition from laminar to turbulent flow depends on the surface geometry, surface roughness, free-stream velocity, surface temperature, and type of fluid, among other things. The flow regime depends mainly on the ratio of the inertia forces to viscous forces in the fluid. This ratio is called the Reynolds number, which is a dimensionless quantity, and is expressed for external flow Eq. 3.3 where V is the upstream velocity (equivalent to the free-stream velocity u∞ for a flat plate), Lc is the characteristic length of the geometry, and = /ρ is the kinematic viscosity of the fluid. For a flat plate, the characteristic length is the distance x from the leading edge. Note that kinematic viscosity has the unit m2/s, which is identical to the unit of thermal diffusivity, and can be viewed as viscous diffusivity or diffusivity for momentum. Chemical Engineering :: ::::For Internal circulation Only:::: Page 60 CHEE 3101 Heat Transfer At large Reynolds numbers, the inertia forces, which are proportional to the density and the velocity of the fluid, are large relative to the viscous forces, and results rapid fluctuations of the fluid, called as Turbulent flow. At small Reynolds numbers, however, the viscous forces are large enough to overcome the inertia forces and to keep the fluid “in line.” Thus the flow is laminar. The Reynolds number at which the flow becomes turbulent is called the critical Reynolds number. (flow over plate Recritical = 5 105). 3.4.4 Schmidt Number (Sc) – defined as the ratio of the molecular diffusivity of momentum to the molecular diffusivity of mass. Sc DAB μ – Dynamic viscosity; DAB Eq. 3.4 γ – Kinematic viscosity; DAB – Diffusion coefficient 3.5 Flow over a flat plate Heat Transfer from flat surfaces – Flow over a flat plate (External flow) i) Mean film temperature, – Plate surface temperature – Fluid temperature All the thermo physical properties of the fluid (like density, viscosity, specific heat, thermal conductivity) should be taken corresponding to mean film temperature ii) Criteria for flow type Re < 5 x 105 Laminar flow Re > 5 x 105 Turbulent flow Chemical Engineering :: ::::For Internal circulation Only:::: Page 61 CHEE 3101 Heat Transfer 3.5.1 For flat plate laminar flow: 1. Local Nusselt number, Nux = 0.332 (Re)0.5 (Pr)0.333 2. Local heat transfer coefficient, hx = (Nux k / L) 3. Average heat transfer coefficient, h = 2hx 4. Heat transfer rate, Q = h A (Tw-Tα) 5. Velocity boundary layer thickness, = hx 5 x Re0.5 6. Thermal boundary layer thickness, = Tx hx Pr 0.333 7. Local friction coefficient, Cfx = 0.664 (Re)-0.5 8. Average friction coefficient, C fL 1.328(Re) 0.5 3.5.2 For flat plate Turbulent flow: 1. Local Nusselt number, Nux = 0.0296 (Re)0.8 (Pr)0.333 2. Local heat transfer coefficient, hx = (Nux k / L) 3. Average heat transfer coefficient, h = 1.25 hx 4. Heat transfer rate, Q = h A (Tw-Tα) 5. Velocity boundary layer thickness, 6. Thermal boundary layer thickness, hx 0.381 x Re0.2 Tx hx 7. Local friction coefficient, Cfx = 0.592 (Re)-0.2 Cfx = 0.37 (log10 Re)-2.584 for for Re > 5 x 105 & Re < 107 Re > 107 & Re < 109 Note: The flow is fully turbulent right from the leading edge of the plate 3.5.3 For flat plate Combined flow 1. Average Nusselt number, Nu = Pr0.333 [0.037(Re)0.8 – 371] 2. Average heat transfer coefficient, h = (Nu k / L) Chemical Engineering :: ::::For Internal circulation Only:::: Page 62 CHEE 3101 Heat Transfer 3. Heat transfer rate, Q = h A (Tw-Tα) 4. Average friction coefficient, C fL 0.074(Re) 0.2 1742(Re) 1.0 Note: The flow is laminar at the start and becomes turbulent as it flows over the plate Example 3.1 Air at 20oC, at a pressure of 1 bar is flowing over a flat plate at a velocity of 3 m/s. If the plate is maintained at 60oC, calculate the heat rate transfer per unit width of the plate taking the length of the plate along the flow of air is 2 m. Given: Fluid Temperature, Tά = 20o C ; Pressure, P = 1 bar; Plate surface temperature = 60o C; Velocity, U = 3m/s; Width, W = 1m; Length, L = 2m To find: Heat transfer rate per unit width (Q̇ /W) Solution: o Film Temp, Tf = (Tw+ Tά) /2 Tf = 40 C o Properties of air at 40 C (From table); 3 ρ = 1.128 kg/m ; k = 0.02756 W/moK; Re = (UL/γ) = 3.5377 x 10 5 -6 2 γ = 16.96 x 10 m /s; Re < 5 x 10 5 Pr = 0.699 Laminar flow For a flat plate laminar flow, Local Nux = 0.332 (Re) Nux = 175.27 Local hx = (Nux k / L) 0.5 (Pr) 0.333 2 hx = 2.415 W/m K Chemical Engineering :: ::::For Internal circulation Only:::: Page 63 CHEE 3101 Heat Transfer Heat transfer rate, Q̇ = h A (Tw – Tά) Q̇ = h (LW) (Tw – Tά) (Q̇ /W) = h L (Tw – Tά) Average h = 2 hx (for laminar flow) 2 h = 4.83 W/m K (𝐐̇ /W) = 386.4 W/m Example 3.2 Air at 20oC, at atmospheric pressure flows over a flat plate of at a velocity of 3 m/s. If the plate is 1m wide and is at 80oC, calculate the following at x=300mm i) Hydrodynamic boundary layer thickness, ii) Thermal boundary layer thickness, iii) Local friction coefficient, iv) Average friction coefficient, v) Local heat transfer coefficient, vi) Average heat transfer coefficient, vii) Heat transfer rate. Given: Fluid Temperature, Tά = 20o C ; Distance, x = 0.3 m ; Velocity, U = 3m/s; Plate surface temperature = 80o C; Width, W = 1m To find: i) δhx ii) δTx, iii) Cfx, iv) CfL, iv) hx, v) h, vi) Q̇ Solution: Film Temp, Tf = (Tw+ Tά) /2 Tf = 50o C Properties of air at 50o C (From table); ρ = 1.093 kg/m3; k = 0.02826 W/mK; Rex = (Ux/γ) = 0.501 x 105 Chemical Engineering :: γ = 17.95 x 10-6 m2/s; Re < 5 x 105 Pr = 0.698 Laminar flow ::::For Internal circulation Only:::: Page 64 CHEE 3101 Heat Transfer Example: 3.3 Air at 20oC is flowing over a flat plate of 1 m long, 0.5 m wide at a velocity of 100 m/s. The flow over the whole length of the plate is made turbulent. Calculate the following i) Thickness of the boundary layer, ii) Mean value of the heat transfer coefficient Given: Fluid Temperature, Tά = 20o C; Length, L = 1m; Velocity, U = 100 m/s ; Width = 0.5 m The flow is turbulent over the entire length To find: i) δ, ii) h Solution: Film Temp, Tf = (Tw+ Tά) /2 Tf = 20o C Properties of air at 20o C (from table); ρ = 1.205 kg/m3; k = 0.02593 W/mK; γ = 15.06 x 10-6 m2/s; Pr = 0.703 Rex = (UL/γ) = 6.64 x 106 Re > 5 x 105 Turbulent flow No check is required for combined flow as the problem clearly tells that it is fully turbulent flow For a flat plate turbulent flow, Local Nux = 0.0296 (Re)0.8 (Pr)0.333; where Re = 1.23 x 106 Nux = 7552 Local hx = (Nux k / L) hx = 195.8 W/m2K Average h = 1.25 hx (for turbulent flow) hturbulent = 244.75 W/m2K Chemical Engineering :: ::::For Internal circulation Only:::: Page 65 CHEE 3101 Heat Transfer Boundary layer thickness δ = 0.37 χ (Re)-0.2 δhx = 0.0159 m Boundary layer thickness = 0.0159 m Average heat transfer coefficient = 244.75 W/m2K 3.6 Heat Transfer from circular surfaces – (External flow) Two regions Boundary layer region near the surface Inviscid region away from the surface Pressure gradient along the cylinder is responsible for the development of a separated flow region on the backside of the cylinder Separation of flow affects the drag force on a curved surface to great extent Chemical Engineering :: ::::For Internal circulation Only:::: Page 66 CHEE 3101 Heat Transfer 3.6.1 Heat Transfer from circular surfaces – Flow over a cylinder (External flow) i) Mean film temperature, All the thermo physical properties of the fluid (like density, viscosity, specific heat, thermal conductivity) should be taken corresponding to mean film temperature Tf Tw T 2 Tw – Plate surface temperature ii) Reynolds number, Re Tα – Fluid temperature UD iii) Nusselt number, Nu = C (Re)m (Pr)0.333 ReD C m 0.4 – 4.0 0.989 0.330 4.1 – 40.0 0.911 0.385 40.1 – 4000 0.683 0.466 4001 – 40,000 0.193 0.618 40,001 – 400,000 0.0266 0.805 iv) Average heat transfer coefficient, h = (Nu k /D) v) Heat transfer rate, Q̇ = h A (Tw- T∞); Chemical Engineering :: Where A = π DL ::::For Internal circulation Only:::: Page 67 CHEE 3101 Heat Transfer 3.6.2 Heat Transfer from circular surfaces – Flow over a sphere (External flow) i) Nusselt number, Nu = 0.37 (Re)0.6 for, 17 < Re < 70,000 ii) Average heat transfer coefficient, h = (Nu k /D) iii) Heat transfer rate, Q̇ = h A (Tw- T∞); Where A = 4π r2 Example 3.4 Air at 15oC, 30 km/h flows over a cylinder of 400 mm diameter and 1500 mm height with surface temperature of 45oC. Calculate the heat loss. To find: Heat loss (Q̇) Given: Fluid Temperature, T∞ = 15o C; Velocity, U=30 km/h=8.33 m/s; Diameter, D = 0.4 m; Plate surface temperature, Tw = 45o C; Length L = 1.5 m Properties of air at 30o C (from table), ρ = 1.165 kg/m3; k = 0.02675 W/mK; γ = 16 x 10-6 m2/s; Pr = 0.701 Re = (UD/γ) = 2.08 x 105 Average Nu = C (Re)m (Pr)0.333 Re = 2.08 x 105 Corresponding ‘C’ value is 0.0266 and ‘m’ value is 0.805. (from table) Nu = 451.3 Average h = (Nu k / D) h = 30.18 W/m2K Heat loss, Q̇ = h A (Tw – T∞) Chemical Engineering :: ::::For Internal circulation Only:::: Page 68 CHEE 3101 Heat Transfer Q̇ = h (π D L) (Tw – T∞) 𝐐̇ = 1706.6 W 3.7 Heat Transfer from circular surfaces – Flow through a cylinder (Internal flow) Retardation of fluid flow near the walls causes Boundary layer development (Shown by dotted line in the fig) Thickness of the BL is limited to radius of the pipe since the flow is within a confined passage BL from the pipe walls meet at the centre of the pipe and the entire flow region acquires the same pattern of the flow Once the BL thickness becomes equal to the radius of the pipe there will be no further changes in the velocity distribution. This invariant velocity profile distribution is called fully developed velocity profile i.e Poiseulle flow Chemical Engineering :: ::::For Internal circulation Only:::: Page 69 CHEE 3101 Heat Transfer i) Mean film temperature, Tmo Tf Tmo Tmi 2 Tmi – Fluid outlet temperature – Fluid inlet temperature All the thermo physical properties of the fluid (like density, viscosity, specific heat, thermal conductivity) should be taken corresponding to mean film temperature ii) Reynolds number, UD Re Criteria for flow type Re < 2300 - Laminar flow Re > 2300 - Turbulent flow Laminar Flow: Nu = 3.66 Turbulent Flow: Nu = 0.023 (Re)0.8 (Pr)n (Dittus-Boelter equation) n = 0.4 – Heating process n = 0.3 – Cooling process Equivalent diameter for rectangular section Dh (or) De =(4A / P) = [4LW/2(L+W)] Where A – Area in m2, P – Perimeter in m, L – Length in m, W – Width in m. Equivalent diameter for hollow cylinder (annular spaces) 4 Do2 Di2 4 Dh (or) De = (4A / P) = Do Di Chemical Engineering :: ::::For Internal circulation Only:::: Page 70 CHEE 3101 Heat Transfer Where Do – Outer diameter in m, Di – Inner diameter in m Heat transfer Q̇ = h A (Tw - Tm) where A = π D L (m2) Tm – Mean temperature oC, = Tmi – Inlet temperature oC, Tmo Tmi 2 Tmo – Outlet temperature oC. Tw – Tube wall temperature oC Q̇ = m Cp(Tmo - Tmi) Mass flow rate m = ρ x A x U (kg/s) where ρ – Density in kg/ m3 , A – Area, (π/4)D2 in m2 , U – Velocity in m/s. Example 3.5 Water flows inside a tube of 20 mm diameter and 3 m long flows at a velocity of 0.03 m/s. The water gets heated from 40o C to 120o C while passing through the tube. The tube wall is maintained at constant temperature of 160 o C. Find heat transfer rate Given: Diameter, D = 0.020 m; Length, L = 3 m; Velocity, U = 0.03 m/s; Inner temperature of water, Tmi = 40o C; Outer temperature of water, Tmo = 120o C Wall temperature, Tw = 160o C To find: Heat transfer rate (Q̇) Chemical Engineering :: ::::For Internal circulation Only:::: Page 71 CHEE 3101 Heat Transfer Solution: Bulk mean Temp, Tm = (Tmi+T mo) / 2 = 80oC Properties of water at 80oC (from table) ρ = 974 kg/m3; γ = 0.364 x 10-6 m2/s; Pr = 2.22; k = 0.6687 W/ mK Re = (UD/γ) = 1648.35 Since Re < 2300, flow is laminar. For laminar flow, Nu = 3.66 Average heat transfer coefficient, h = Nu k / D h =122.39 W/m2K Heat transfer rate, Q̇= h A (Tw - Tm) = h πDL (Tw-Tm) 𝐐̇ = 1845.29 W Example 3.6 Water at 50o C enters 50 mm diameter and 4 m long tube with a velocity of 0.8 m/s. The tube wall is maintained at a constant temperature of 90 o C. Determine the heat transfer coefficient and the total amount of heat transferred if exit water temperature is 70o C. Given: Diameter, D = 0.05 m; Length, L = 4 m; Inner temperature, Tmi = 50o C; Velocity, U = 0.8 m/s Exit temperature, Tmo = 70o C Tube wall temperature, Tw = 90o C To find: i) Heat transfer coefficient ( h ), ii) Heat transfer rate (Q̇) Solution: Chemical Engineering :: ::::For Internal circulation Only:::: Page 72 CHEE 3101 Heat Transfer Bulk mean Temp, Tm = (Tmi+T mo) / 2 = 60o C Properties of water at 60o C ( from table), ρ = 985 kg/m3; γ = 0.478 x 10-6 m2/s; Pr = 3.020; k = 0.6513 W/mK Re = (UD/γ) = 8.36 x 104 Turbulent flow So, Nu =0.023(Re)0.8(Pr)n The process involved is heating, hence n = 0.4 Nu = 310 Heat transfer coefficient, h = Nu k / D = 4039.3 W/m2K Heat transfer, Q̇ = h A (Tw-Tm)= h πDL (Tw-Tm) = 76,139 W Example 3.7 Air at 15o C, 35 m/s, flows through a hollow cylinder of 4 cm inner diameter and 6 cm outer diameter and leaves at 45o C. Tube wall is maintained at 60o C. Calculate the heat transfer coefficient between the air and the inner tube. Given: Inlet temperature, Tmi = 15o C ; Inner Diameter, Di = 0.04 m Velocity, U = 35 m / s ; Exit temperature, Tmo = 45o C; Outer Diameter, Do = 0.06 m; Wall temp, Tw = 60o C To find: Heat transfer coefficient (h) Solution: Mean Temp, Tm = (Tmi+T mo) / 2 = 30o C Properties of air at 30o C (from table) Chemical Engineering :: ::::For Internal circulation Only:::: Page 73 CHEE 3101 Heat Transfer ρ = 1.165 kg/m3; γ = 16 x 10-6 m2/s; Pr = 0.701; k = 0.02675 W/mK Hydraulic or Equivalent diameter De = 4A/P = (4(π/4)[Do2 – Di2])/(π )[Do + Di]) = 0.02 m ReDe = (U De /γ) = 43750 Since Re > 2300, flow is turbulent. For turbulent flow, general equation, Nu =0.023(Re)0.8(Pr)n This is heating process, so n=0.4 Nu = 102.9 Heat transfer coefficient, h = Nu k / De h = 137.7 W/m2K Chemical Engineering :: ::::For Internal circulation Only:::: Page 74 CHEE 3101 Heat Transfer Assignment Questions: Q1. Air at 25oC, flows over a flat plate maintained at 135oCat a speed of 5 m/s. The plate is 3 m long and 1.5 m wide. Calculate the local heat transfer coefficient at x=0.5 m and the heat transferred from the first 0.5 m of the plate. [ Answer : hx=0.5 = 6.14 W/m2K; Q̇avg uptox=0.5 = 1013.9 W] Q2. Air at 30oC, 0.2 m/s flows across a 120 W spherical electric bulb at 130 oC. Find the heat transfer rate and power lost due to convection if bulb diameter is 70 mm. [Answer: Q̇= 12.22 W; % heat lost = 10.18 %] Q3. Water at 30o C, 20 m/s flows through a straight tube of 60 mm diameter. The tube surface is maintained at 70o C and outlet temperature of water is 50o C. Find the heat transfer coefficient from the tube surface to the water, heat transferred and the tube length. [ Answer: h = 43726.59 W/m2K; Q̇= 4.69 x 106 W; L = 18.96 m] Q4. Air at 30o C, 6 m/s flows in a rectangular section of size 300 x 800 mm. Calculate the heat leakage per meter length per unit temperature difference. [Answer: (Q̇ / L ΔT) = 39.79 W] Q5. Air at 333 K, 1bar pressure, flow through 12 cm diameter tube. The surface temperature of the tube is maintained at 400 K and mass flow rate is 75 kg/hr. Calculate the heat transfer rate for 1.5 m length of the tube. [Answer: Q̇ = 300.82 W] Chemical Engineering :: ::::For Internal circulation Only:::: Page 75 CHEE 3101 Heat Transfer 3.8 Boiling and Condensation • In the previous chapter, Fluid was considered as a homogenous single phase system • In many situations, fluid changes its phase during convective heat transfer. • Boiling & condensation are such convective heat transfer processes that are associated with change in phase of liquid. Boiling • The change of phase from liquid to vapour state is known as boiling. Condensation • The change of phase from vapour to vapour state is known as condensation. Applications of Phase change heat transfer • Thermal and nuclear power plant. • Refrigerating & Air-conditioning systems. • Process of heating & cooling • Heating of metal in furnaces 3.8a. Boiling Heat Transfer • Change of phase from liquid to vapour state • Possible only when the temperature of heating surface (Tw) exceeds the saturation temperature of liquid (Tsat) at given pressure. • According to convection law, Q = h A ( Tw – Tsat ) = h A (ΔT) Where, ΔT – is known as excess temperature Chemical Engineering :: ::::For Internal circulation Only:::: Page 76 CHEE 3101 Heat Transfer 3.8a.1 Pool Boiling • If heat is added to a liquid from a submerged solid surface, the boiling process is referred as pool boiling. • The liquid above the hot surface is essentially stagnant and its motion (as well as heat transfer) near the surface is due to i) Free convection ii) Mixing induced by bubble growth & detachment Typical boiling curve for water at 1 atm pressure. Chemical Engineering :: ::::For Internal circulation Only:::: Page 77 CHEE 3101 Heat Transfer Boiling Curve Interface evaporation (Region I) • Evaporation process with no bubble formation. • Excess temperature ΔT is very small (5oC). • Liquid near the surface is super heated slightly and evaporation takes place at the liquid surface. • The liquid above the hot surface is essentially stagnant and its motion (as well as heat transfer) near the surface is due to (i) Free convection (ii) Mixing induced by bubble growth and detachment Nucleate Boiling (Region II & III) • Starts at region II. • As excess temperature is further increased, bubbles are formed more rapidly and rapid evaporation takes place. This is indicated in region III. • Nucleate boiling exists upto ΔT = 50oC. • The maximum flux, known as critical flux occurs at point A Film boiling (Region IV, V and VI) • Region IV – vapour film formed is not stable and collapses & reforms rapidly. • With further increase in ΔT, the vapour film is stabilized as indicated in region V. • The surface temperature required to maintain a stable film is high and under these conditions a sizable amount of heat is lost by the surface due to radiation. This is indicated in region VI. Chemical Engineering :: ::::For Internal circulation Only:::: Page 78 CHEE 3101 Heat Transfer Inference from the boiling curve Rapid increase in heat transfer rates is associated with small values of the excess temperature in nucleate boiling region. 3.8a.2 Flow or Forced convection boiling • Flow boiling or forced convection boiling may occur when a fluid is forced through a pipe or over a surface which is maintained at a temperature higher than the saturation temperature of the fluid. • Occurs in water tube boilers involving forced convection 3.8b. Condensation The change of phase from vapour to liquid state is known as condensation Modes of condensation There are two modes of condensation 3.8b.1 Filmwise condensation: The liquid condensate wets the solid surface, spreads out and forms a continuous film over the entire surface is known as filmwise condensation. Film condensation occurs when a vapour is free from impurities. 3.8b.2 Dropwise condensation: In dropwise condensation, the vapour condenses into small liquid droplets of various sizes which fall down the surface in a random fashion. Heat transfer rates in dropwise condensation may be as much as 10 times higher than in filmwise condensation. Chemical Engineering :: ::::For Internal circulation Only:::: Page 79 CHEE 3101 Heat Transfer CHAPTER 4 (outcomes 8, 9, 10 and 11) RADIATION HEAT TRANSFER 4.1 Concepts: • Any surfaces at all temperatures (but above absolute zero temperature) emit thermal radiation. • In addition to emitting radiation, the surfaces of a body has the capacity for absorbing all or part of the radiation emitted by surrounding surfaces and falling on it. • A surface emits radiation in all directions encompassed by a hemisphere. - We shall be concerned only with situations involving radiation exchange between surfaces, in which the space between the surfaces is a vacuum or is occupied by a gas which does not participate in the radiation exchange in any way. Chemical Engineering :: ::::For Internal circulation Only:::: Page 80 CHEE 3101 Heat Transfer 4.1.1 Definition The heat transfer from one body to another without any transmitting medium is known as radiation Electromagnetic wave phenomenon Propagates at the speed of light 4.1.2 Emission properties The rate of emission of radiation by a body depends upon the following factors: Wavelength or frequency of radiation Temperature of the surface Nature of the surface 4.1.3 Emissive power - The emissive power is defined as the total amount of radiation emitted by a body per unit time and unit area. It is expressed in W/m2 - Monochromatic emissive power is the energy emitted at a given wavelength per unit time per unit area in all directions. 4.1.4 Concept of Black body Black body is an ideal surface having the following properties Absorbs all incident radiation, regardless of wavelength and direction Emits the maximum energy for a given temperature and wavelength 4.1.5 Concept of Gray body If a body absorbs a definite percentage of incident radiation irrespective of their wavelength, the body is known as gray body. The emissive power of a gray body is always less than that of the black body. Chemical Engineering :: ::::For Internal circulation Only:::: Page 81 CHEE 3101 Heat Transfer 4.2 Absorption, Reflection and Transmission Energy balance yields, Q = Qa + Qr + Qt Dividing the above equation by Q, 1 = (Qa /Q) + (Qr /Q) + (Qt /Q) (or) 1 = α + ρ + τ Absorptivity (α) = Radiation absorbed / Incident radiation Reflectivity (ρ) = Radiation reflected / Incident radiation Transmissivity (τ) = Radiation transmitted / Incident radiation Note: Transmissivity and Emissivity are different 4.2.1 Emissivity It is defined as the ability of the surface of a body to radiate heat. It is also defined as the ratio of the emissive power of any body (gray body) to the emissive power of a black body of equal temperature. Emissivity, ε = E / Eb Chemical Engineering :: ::::For Internal circulation Only:::: Page 82 CHEE 3101 Heat Transfer 4.3 Laws of Radiation 4.3.1 Planck’s Distribution Law The relationship between the monochromatic emissive power of a black body and wave length of a radiation at a particular temperature is given by the following expression, by Planck Ebλ = (c1 λ-5) / (exp(c2/ λT) - 1) where Ebλ = Monochromatic emissive power W/m2 λ = Wavelength – m c1 = 0.374 x 10-15 W m2 c2 = 14.4 x 10-3 mK 4.3.2 Wien’s Displacement Law The Wien’s law gives the relationship between temperature and wavelength corresponding to the maximum spectral emissive power of the black body at that temperature λmax T = 2898 µmK => λmax T = 2.9 x 10-3 mK [since µ = 10-6 m] 4.3.3 Stefan – Boltzmann Law The emissive power of a black body is proportional to the fourth power of absolute temperature Eb α T4 Eb = σ T4 where Eb = Emissive power – W/m2 σ = Steffan – Boltzmann constant = 5.67 x 10-8 W/m2K4 T = Absolute Temperature – K Chemical Engineering :: ::::For Internal circulation Only:::: Page 83 CHEE 3101 Heat Transfer 4.3.4 Kirchoff’s Law Of Radiation This law states that the ratio of total emissive power to the absorptivity is constant for all surfaces which are in thermal equilibrium with the surroundings. This can be written as E1 / α1 = E2 / α2 = E3 / α3 ……… It also states that the emissivity of the body is always equal to its absorptivity when the body remains in thermal equilibrium with its surroundings. α1 = ε1 ; α2 = ε2 and so on. Example: 4.1 A black body at 3000 K emits radiation. Calculate the following, a) b) c) d) Monochromatic emissive power at 1 µm wave length, Wave length at which emission is maximum. Total emissive power, Calculate the total emissive of the furnace if it is assumed as a real surface having emissivity equal to 0.85 Given: Surface temperature, T = 3000 K To find: a. b. c. d. Monochromatic emissive power Ebλ at λ = 1 µ = 1 x 10-6 m Maximum Wave length, (λmax ) Total emissive power, Eb Emissive power of real surface at ε = 0.85 Chemical Engineering :: ::::For Internal circulation Only:::: Page 84 CHEE 3101 Heat Transfer Solution: a. Monochromatic emissive power: From Planck’s distribution law, Ebλ = (c1 λ-5) / (exp(c2/ λT) - 1) where c1 = 0.374 x 10-15 W m2 c2 = 14.4 x 10-3 mK λ = 1 x 10-6 m [Given] => Ebλ = 3.10 x 1012 W/m2 b. Maximum Wave length, (λmax ) : From Wien’s law, λmax T = 2.9 x 10-3 mK => λmax = 0.966 x 10-6 m c. Total emissive power, Eb : From Steffan - Boltzmann law, Eb = σ T4 W/m2 => Where σ = Steffan Boltzmann constant = 5.67 x 10-8 W/m2 K4 Eb = 4.59 x 106 W/m2 d. Total emissive power of a real surface : (Eb)real = ε σ T4 where ε – Emissivity = 0.85 (Eb)real = 3.90 x 106 W/m2 Chemical Engineering :: ::::For Internal circulation Only:::: Page 85 CHEE 3101 Heat Transfer 4.4 Radiation – Gray body heat exchange formulae Heat exchange between 2 large parallel plate is given by: Q12 = σ A (T14 – T24) Where emissivity, 1 1 σ 1 1 2 1 = Steffan Boltzmann constant = 5.67 x 10-8 W/m2 K4 ε1 = Emissivity of surface 1 ε2 = Emissivity of surface 2 T1 = Temperature of surface 1 – in K T2 = Temperature of surface 2 – in K Heat exchange between 2 large concentric cylinder (or) sphere is given by : Q12 = A1 σ (T14 – T24) where 1 1 A 1 1 1 1 A2 2 For cylinder, Area, A = 2 π r L For sphere, Area, A = 4 π r2 Chemical Engineering :: ::::For Internal circulation Only:::: Page 86 CHEE 3101 Heat Transfer Example: 4.2 Calculate the net radiant interchange per sq.m, for two large planes at a temperature of 900 K and 400 K respectively. Assume that the emissivity of hot plane is 0.9 and that of cold plane is 0.7. Given: Hot plane temperature, T1 = 900 K Cold plane temperature, T2 = 400 K Emissivity of hot plane, ε1 = 0.9 Emissivity of cold plane, ε2 = 0.7 To find; Net radiant heat exchange per square meter. Solution: The heat exchange between two large parallel plate is given by Q = where σ = = σ A (T14 – T24) (1) = 1 / ((1/ ε1) + (1/ ε2) – 1) = 0.649 Steffan Boltzmann constant 5.67 x 10-8 W/m2 K4 Equation ( 1 ) => Q / A = 23.20 x 103 W/m2 = 23.20 kW/m2 Chemical Engineering :: ::::For Internal circulation Only:::: Page 87 CHEE 3101 Heat Transfer Example: 4.3 Calculate the heat exchange by radiation between the surfaces of two long cylinders having radii 120 mm and 60 mm respectively. The axis of the cylinders is parallel to each other. The inner cylinder is maintained at a temperature of 130 o C and emissivity of 0.6. Outer cylinder is maintained at a temperature of 30 o C and emissivity of 0.5. Given: r1 = 60 mm = 0.060 m r2 = 120 mm = 0.12 m T1 = 130 + 273 = 403 K T2 = 30 + 273 = 303 K ε1 = 0.6 ε2 = 0.5 To find: Heat exchange, (Q) Solution: The heat exchange between two large concentric cylinder is given by Q12 = σ A (T14 – T24) ( 1) = 1 / ((1/ ε1) + (A1/A2)((1/ ε2) – 1)) = 0.46 Equation ( 1 ) => Chemical Engineering :: [since A = π D L and L1 / L2 =1] Q12 = 176.47 W ::::For Internal circulation Only:::: Page 88 CHEE 3101 Heat Transfer Assignment Questions: Q1. Estimate the net radiant heat exchange per square meter between two large plates at a temperature of 550o C and 320o C. Assume that emissivity of hot plate is 0.8 and cold plate is 0.6 [Answer: Q / A = 9880.6 W/m2 = 9.88 kW/m2] Q2. Liquid oxygen is stored in double walled spherical vessel. Inner wall temperature is – 160o C and outer wall temperature is 30o C. Inner diameter of sphere is 20 cm and outer diameter is 32 cm. Calculate the following. a. Heat transfer if emissivity of spherical surface is 0.05 b. Rate of evaporation of liquid oxygen if its latent heat is 200 kJ/kg. [Answer: Q12 = - 2.12 W; m = 1 x 10-5 kg/s] Q3. A pipe of outside diameter 30 cm having emissivity 0.6 and at a temperature of 600 K runs centrally in a brick duct of 40 cm side square section having emissivity 0.8 and at a temperature of 300 K. Calculate the heat exchange per metre length. [Answer: Q12 = 3569.2 W] ********************* Chemical Engineering :: ::::For Internal circulation Only:::: Page 89 CHEE 3101 Heat Transfer CHAPTER 5 HEAT EXCHANGERS (Outcomes 13 to 16) 5.1 Definition A heat exchanger is defined as an equipment which transfers the heat from a hot fluid to a cold fluid. 5.1.1 Types of heat exchangers: Criteria for classification of heat exchangers: (i) Nature of heat exchange process (ii) Relative direction of fluid motion (iii) Design and constructional features (iv) Physical state of fluids I. Nature of heat exchange process: a) Direct contact heat exchangers or Open heat exchangers Examples: Cooling towers, Direct contact feed heaters b) Indirect contact heat exchangers. Examples: IC engines, gas turbines, Air pre heaters, Economizers. II. Relative direction of fluid motion: a. Parallel flow heat exchanger – Fluids move in same direction b. Counter flow heat exchanger – Fluids move in opposite direction c. Cross flow heat exchanger – Fluids make right angle to each other III. Design and constructional features: a. Concentric tubes b. Shell and tube (most widely used) Chemical Engineering :: ::::For Internal circulation Only:::: Page 90 CHEE 3101 Heat Transfer c. Multiple shell and tube passes d. Compact heat exchangers IV. Physical state of fluids: a. Condensers b. Evaporators. 5.1.2 Applications • Automobiles (Radiators, Air preheater, Exhaust gas heat removal) • Gas turbines • Cooling towers • Industrial Furnaces (Economizers) # As discussed above, heat exchangers are manufactured in a variety of types, The simplest being the double-pipe heat exchanger. One fluid in a double-pipe heat exchanger flows through the smaller pipe while the other fluid flows through the annular space between the two pipes. Two types of flow arrangement are possible in a double-pipe heat exchanger: (1) parallel flow, and (2) counter flow. In a parallel-flow type, both the hot and cold fluids enter the heat exchanger at the same end and move in the same direction, whereas in a counter-flow type, the hot and cold fluids enter the heat exchanger at opposite ends and flow in opposite directions. Chemical Engineering :: ::::For Internal circulation Only:::: Page 91 CHEE 3101 Heat Transfer Temperature variation in a heat exchanger Parallel flow Counter flow 5.2 Introduction to LMTD • Temperature difference between the hot and cold fluids in a heat exchanger varies from point to point • In addition various modes of heat transfer are involved • Hence, based on the concept of appropriate mean temperature difference, also called logarithmic mean temperature difference, the total heat transfer rate in the heat exchanger is expressed as Chemical Engineering :: ::::For Internal circulation Only:::: Page 92 CHEE 3101 Heat Transfer Q = UA (∆T)lm where U – Overall heat transfer co-efficient, W/m2K A – Area, m2 (∆T)lm – Logarithmic mean temperature difference. FOR PARALLE FLOW (∆T) lm =[(Th1 – Tc1) – (Th2 – Tc2)] / ln ((Th1 – Tc1) / (Th2 – Tc2)) FOR COUNTER FLOW (∆T) lm = [(Th1 – Tc2) – (Th2 – Tc1)] / ln ((Th1 – Tc2) / (Th2 – Tc1)) Heat lost by hot fluid = Heat gained by cold fluid Qh = Qc Q = mhCph(Th1 – Th2) = mcCpc(Tc2 – Tc1) Where mh – Mass flow rate of hot fluid mc – Mass flow rate of cold fluid Cph – Specific heat of hot fluid Cpc – Specific heat of cold fluid Surface area of cylindrical tube A = π Di L Where, Di – Inner diameter Chemical Engineering :: ::::For Internal circulation Only:::: Page 93 CHEE 3101 Heat Transfer In case of evaporators / Condensers Q = m x hfg Where , hfg – Latent heat (J/kg K) Example 5.1 In a double pipe heat exchanger, hot fluid with a specific heat of 2300 J/kg enters at 380oC and leaves at 300oC. Cold fluid enters at 25oC and leaves at 210oC. Calculate the heat exchanger area required for (i) Counter flow (ii) Parallel flow. Take overall heat transfer coefficient as 750 W/m2 K and mass flow rate of hot fluid is 1 kg/s. Given: Mass flow rate of hot fluid, mh = 1 kg/sec Entry temperature of cold fluid, Tc1 = 25o C Exit temperature of cold fluid, Tc2 = 210o C Specific heat of oil (Hot fluid), Cph = 2300 J/kg K Entry temperature of hot fluid, Th1 = 380o C Exit temperature of hot fluid, Th2 = 300o C Overall heat transfer co-efficient, U = 750 W/m2K To find: Heat exchanger area (A) for (i) Counter flow (ii) Parallel flow Chemical Engineering :: ::::For Internal circulation Only:::: Page 94 CHEE 3101 Heat Transfer Solution: We know that, Heat transfer, Q = mcCpc(Tc2 – Tc1) = mh Cph(Th1 – Th2) => Q = mhCph(Th1 – Th2) [Since Specific heat & flow rate of hot fluid is known] Q = 184 x 103 W We know that, Heat transfer, Q = UA (∆T) lm (1) (i) For counter flow (∆T) lm = [(Th1 – Tc2) – (Th2 – Tc1)] / ln ((Th1 – Tc2) / (Th2 – Tc1)) = 218.3o C Substitute (∆T) lm, Q and U values in Equation (1), (1) Q = UA (∆T) lm A = Q/U (∆T)lm = 1.12 m2 (ii) For parallel flow (∆T) lm =[(Th1 – Tc1) – (Th2 – Tc2)] / ln ((Th1 – Tc1) / (Th2 – Tc2)) = 191.3o C Substitute (∆T) lm, Q and U values in Equation (1), (1) Q = UA (∆T) lm A = Q/U (∆T) lm = 1.27 m2 Area required for Counter flow = 1.12 m2 Area required for Parallel flow = 1.27 m2 Inference: Counter flow heat exchanger is more effective compared to parallel flow heat exchanger Chemical Engineering :: ::::For Internal circulation Only:::: Page 95 CHEE 3101 Heat Transfer 5.3 Cross Flow Heat Exchangers In compact heat exchangers, the two fluids move perpendicular to each other, and such a flow configuration is called cross-flow. The cross-flow is further classified as unmixed and mixed flow, depending on the flow configuration, as shown in Figure. In (a) the cross-flow is said to be unmixed since the plate fins force the fluid to flow through a particular inter fin spacing and prevent it from moving in the transverse direction (i.e., parallel to the tubes). The cross-flow in (b) is said to be mixed since the fluid now is free to move in the transverse direction. Both fluids are unmixed in a car radiator. The presence of mixing in the fluid can have a significant effect on the heat transfer characteristics of the heat exchanger. Other common type of heat exchangers in industrial applications is the shell-andtube heat exchangers. Shell-and-tube heat exchangers contain a large number of tubes (sometimes several hundred) packed in a shell with their axes parallel to that of the shell. Heat transfer takes place as one fluid flows inside the tubes while the other fluid flows outside the tubes through the shell. Baffles are commonly placed Chemical Engineering :: ::::For Internal circulation Only:::: Page 96 CHEE 3101 Heat Transfer in the shell to force the shell-side fluid to flow across the shell to enhance heat transfer and to maintain uniform spacing between the tubes. Despite their widespread use, shell and- tube heat exchangers are not suitable for use in automotive and aircraft applications because of their relatively large size and weight. Note that the tubes in a shell-and-tube heat exchanger open to some large flow areas called headers at both ends of the shell, where the tube-side fluid accumulates before entering the tubes and after leaving them. Fig. The schematic of a shell-and-tube heat exchanger (Shell & tube Condenser). Shell-and-tube heat exchangers are further classified according to the number of shell and tube passes involved. Heat exchangers in which all the tubes make one U-turn in the shell, for example, are called one-shell-pass and two tube-passes heat exchangers. Likewise, a heat exchanger that involves two passes in the shell and four passes in the tubes is called a two-shell-passes and four-tube-passes heat exchanger Chemical Engineering :: ::::For Internal circulation Only:::: Page 97 CHEE 3101 Heat Transfer 5.4 Fouling of a heat exchanger Surface of the heat exchangers do not remain clean after it has been in use for some time. Surface becomes fouled with scales or deposits which in turns affects the value of heat transfer coefficient (U). This fouling effect is taken care by introducing an additional thermal resistance called the fouling resistance or fouling factor (Rf) . U outer 1 r 1 r r r 1 R fo o ln o o R fi o ho k ri ri ri hi Chemical Engineering :: ::::For Internal circulation Only:::: Page 98 CHEE 3101 Heat Transfer Causes for fouling 1. Presence of inherent salt & scales in the fluids used in the heat exchangers 2. Condensation of inorganic vapor components 3. Usage of flue gas which contains ash & effluents with it 4. Chemical reaction resulting from the fluids & the heat exchanger components 5. Usage of low melting matter 5.5 The effectiveness–NTU method Usually, a heat exchanger can be designed by the LMTD method when the inlet and outlet temperatures of both fluids are known. However, when the inlet and outlet temperatures of the fluids are not known and if the problem is to determine the inlet or exit temperature of heat exchanger, effectiveness – NTU method is used. The plot between effectiveness and NTU for various values of (Cmin/Cmax) is available in the chart for different heat exchangers Number of Transfer units (NTU) NTU Where UA Cmin U = Overall heat transfer coefficient A = Heat exchanger area Cmin = minimum heat Capacity Heat capacity, C = m x Cp Effectiveness of a heat exchanger Chemical Engineering :: ::::For Internal circulation Only:::: Page 99 CHEE 3101 Heat Transfer Ratio of actual heat transfer to the maximum possible heat transfer Effectiven ess, Actual heat transfer Q Max possible heat transfer Qmax Where, Q = mcCpc(Tc2 – Tc1) = mhCph(Th1 – Th2) Qmax = Cmin (Th1 – Tc1) Cmin = minimum heat capacity Chemical Engineering :: ::::For Internal circulation Only:::: Page 100 CHEE 3101 Heat Transfer Effectiveness Vs NTU Chart Chemical Engineering :: ::::For Internal circulation Only:::: Page 101 CHEE 3101 Heat Transfer Example 5.2 A parallel flow heat exchanger is used to cool 4.2 kg/min of hot liquid of specific heat 3.5 kJ/kg K at 130oC. A cooling water of specific heat 4.18 kJ/kg K is used for cooling purpose at a temperature of 15oC. The mass flow rate of cooling water is 17 kg/min. calculate the following. a. Outlet temperature of hot liquid b. Outlet temperature of water c. Effectiveness of heat exchanger. Take Overall heat transfer co-efficient as 1100 W/m2K. Heat exchanger area is 0.30 m2 Given: Mass flow rate of hot fluid, mh= 4.2 kg/min = 0.07 kg/s Specific heat of hot fluid, Cph = 3.5 kJ/kg K = 3.5 x 103 J/kg K Inlet temperature of hot fluid, Th1 = 130o C Mass flow rate of cooling water, mc= 17 kg/min = 0.28 kg/s Specific heat of water, Cpc = 4.18 kJ/kg K = 4.18 x 103 J/kg K Inlet temperature of cooling water, Tc1 = 15o C Overall heat transfer co-efficient, U = 1100 W/m2K Area, A = 0.30 m2 To find: a. Outlet temperature of liquid (Th2) b. Outlet temperature of water (Tc2) c. Effectiveness of heat exchanger (ε). Solution: Capacity rate of hot liquid, Ch = mh x Cph = 245 W/K Capacity rate of water, Chemical Engineering :: Cc = mc x Cpc = 1170.4 W/K ::::For Internal circulation Only:::: (1) (2) Page 102 CHEE 3101 Heat Transfer From (1) and (2), Cmin = 245 W/K; Cmax = 1170.4 W/K (3) => Cmin / Cmax = 0.209 Number of transfer units, NTU = UA / Cmin => (4) NTU = 1.34 To find effectiveness ε, refer data chart for parallel flow heat exchanger From graph, Xaxis NTU =1.34 Curve Cmin / Cmax = 0.209 Corresponding Yaxis value is 64% i.e., Effectiveness, ε = 0.64 Maximum possible heat transfer Qmax = Cmin (Th1 – Tc1) = 28175 W Actual heat transfer rate Q = ε x Qmax = 18032 W We know that, Heat transfer, Q = mc Cpc (Tc2 – Tc1) => 18032 = 1170.4 Tc2 - 17556 Tc2 = 30.40o C => Outlet temperature of cold water, Tc2= 30.40o C We know that, Heat transfer, Q = mh Cph (Th1 – Th2) => => 18032 = 31850 – 245 Th2 Th2 = 56.4o C Outlet temperature of hot liquid, Th2 = 56.4o C ---------------------------------------------------------Chemical Engineering :: ::::For Internal circulation Only:::: Page 103 CHEE 3101 Heat Transfer Assignment Questions: Q1. Water flows at the rate of 65 kg/min through a double pipe, counter flow heat exchanger. Water is heated from 50oC to 75oC by oil flowing through the tube. The specific heat of the oil is 1.780 kJ/kg K. The oil enters at 115 oC and leaves at 70o C. The overall heat transfer co-efficient is 340 W/m2K. Calculate the following 1. Heat exchanger area 2. Rate of heat transfer [Answer: Q = 113 x 103 W; A = 11.54 m2] Q2. A counter flow double pipe heat exchanger is used to cool the engine oil from 150oC to 55oC with water, available at 23oC as the cooling medium. The specific heat of oil is 2125 J/kg K. The flow rate of cooling water through the inner tube of 0.4 m diameter is 2.2 kg/s. The flow rate of oil through the outer tube of 0.75 m diameter is 2.4 kg/s. If the value of the overall heat transfer co-efficient is 240 W/m2K, how long must the heat exchanger be to meet its cooling requirement? [Answer: L = 31.9 m] Q3. Saturated steam at 126oC is condensing on the outer tube surface of a single pass heat exchanger. The heat exchanger heats 1050 kg/h of water from 20 oC to 95oC. The overall heat transfer co-efficient is 1800 W/m2K. Calculate the following 1. Area of heat exchanger 2. Rate of condensation of steam. Take hfg = 2185 kJ/kg [Answer: Rate of condensation of steam, mh = 0.0416 kg/s; A = 0.828 m2] Q4. In a counter flow heat exchanger, water is heated from 20 o C to 80o C by oil with a specific heat of 2.5 kJ/kg-K and mass flow rate of 0.5 kg/s. The oil is cooled Chemical Engineering :: ::::For Internal circulation Only:::: Page 104 CHEE 3101 Heat Transfer from 110o C to 40o C. If the overall heat transfer co-efficient is 1400 W/m2K, find the following by using NTU method. a. Mass flow rate of water b. Effectiveness of heat exchanger b. Surface area. [Answer: Mass flow rate of water, mc = 0.348 kg/s Effectiveness, ε = 0.77 Surface area, A = 3.03 m2] ************************** Chemical Engineering :: ::::For Internal circulation Only:::: Page 105 CHEE 3101 Heat Transfer Chemical Engineering :: ::::For Internal circulation Only:::: Page 106 CHEE 3101 Heat Transfer Chemical Engineering :: ::::For Internal circulation Only:::: Page 107 CHEE 3101 Heat Transfer References: 1. Yunus A.Cengel, “Heat Transfer” 2nd Edition Reprint, McGraw Hill Higher Education, 2002. 2. P S Ghoshdastidar, “Heat Transfer” 2nd Edition, Oxford University Press, 2005. 3. J. P. Holman, “Heat Transfer” 8th International Edition, McGraw Hill Higher Education INC, 1997. 4. D S Kumar, “Heat and Mass Transfer”, Laxmi Publications, 2000. 5. Ozisik M.N, “Heat Transfer”, McGraw-Hill Book Co., 1994. 6. Nag P.K, “ Heat Transfer”, Tata McGraw-Hill, New Delhi, 2002. 7. C.P Kothandaraman, “Heat and Mass Transfer Data Book”, New Age international (P) limited, publishers, New Delhi,2012. 8. NPTEL (National Programme on Technology Enhanced Learning) nptel.ac.in. Chemical Engineering :: ::::For Internal circulation Only:::: Page 108