Physical Science Study of Matter at the Atomic Scale PHYSICS BIOLOGY CHEMISTRY (central science) EARTH SCIENCE ENVIRONMENTAL (APPLIED) ENGINEERING (APPLIED) MEDICINE (APPLIED) Chemistry is the study of CHANGE Chemistry is the study of matter and the changes it undergoes. OBSERVATIONS - the action or process of observing something or someone carefully or in order to gain information. Can be observed using the sense of sight. Can only be observed using special equipment. MACROSCOPIC MICROSCOPIC MACROSCOPIC MICROSCOPIC The macroscopic world is everything observable. The microscopic world deals with the things that our eyes cannot observe. This is where the different laws in Chemistry comes in. A macroscopic property describes characteristics or behavior of a sample which is large enough to see, handle, manipulate, weigh, etc. A microscopic property describes the behavior of a much smaller sample of matter, an atom or molecule for instance. ALCHEMY universal solvent that will turn every metal to gold elixir of life (immortality) MODERN CHEMISTRY discovery of elements experimentation Theories can help us make better predictions. Dmitri Mendeleev's Theory of the Periodic Table predicted several undiscovered elements. Chemistry in Daily Life WHY ONIONS MAKE YOU CRY • Amino acid sulfoxides form sulfenic acids after you slice into an onion. • This gas reacts with the water in your tears to form sulfuric acid. The sulfuric acid burns, stimulating your eyes to release more tears to wash the irritant away. WHY ICE FLOATS • As water cools below 4 degrees C, the hydrogen bonds adjust to hold the negatively charged oxygen atoms apart. • This produces a crystal lattice, which is commonly known as 'ice'. • Ice floats because it is about 9% less dense than liquid water. WHY ICE FLOATS BAKING SODA MAKE FOODS RISE • Baking soda is pure sodium bicarbonate. • When baking soda is combined with moisture and an acidic ingredient, the resulting chemical reaction produces bubbles of carbon dioxide that expand under oven temperatures, causing baked goods to expand or rise. CHEMISTRY OF LOVE • The emotions that you feel are a result of chemical messengers, primarily neurotransmitters. • Researchers say this is due to the dopamine, norepinephrine and phenylethylamine we're releasing. • Dopamine is thought to be the "pleasure chemical," producing a feeling of bliss. • Norepinephrine is similar to adrenaline and produces the racing heart and excitement. USING SUNSCREEN • Sunscreen combines organic and inorganic chemicals to filter the light from the sun so that less of it reaches the deeper layers of your skin. • The reflective particles in sunblocks usually consist of zinc oxide or titanium oxide. Chemists ask questions. Chemistry is full of unanswered questions. One of the first questions people have been asking since ancient times is: “What is the world made of?” Atomic Theory and the Basic Laws of Matter ANCIENT IDEAS ABOUT MATTER Greek philosopher Democritus introduced the idea of the atom as the basic building block matter. atomos = indivisible Aristotle thought that all materials on Earth were not made of atoms, but of the four elements, Earth, Fire, Water, and Air. (Elements are mystical substances). ANCIENT IDEAS ABOUT MATTER Robert Boyle wrote a book called the "Skeptical Chemist”. His book urged chemists to abandon the view that elements are mystical substances. Instead he promoted a philosophy that valued observation and experimentation. Dalton’s Atomic Theory (1808) John Dalton was an English chemist, physicist, and meteorologist. He is best known for proposing the modern atomic theory, and for his research into color blindness, sometimes referred to as Daltonism in his honor. Dalton's atomic theory was the first complete attempt to describe all matter in terms of atoms and their properties. 1 Elements are composed of extremely small particles called atoms. To make diagrams simpler we often draw atoms as circles. - indivisible - indestructible - extremely small - hard spheres The atoms of one element are different from the atoms of all other elements. 2 All atoms of a given element are identical, having the same size, mass and chemical properties. Gold is a yellowish solid, iron is a silvery solid, while mercury is a silvery liquid at room temperature. Law of Conservation of Mass 3 When matter undergoes changes, whether physical or chemical, the atoms are merely rearranged. No atom is created nor destroyed. mass of the reactants = mass of the products The reaction shown is a combustion reaction: a compound reacts with oxygen and produces carbon dioxide and water. Law of Conservation of Mass The reaction shown is for the formation of water: hydrogen and oxygen reacts with each other to produce water. Law of Conservation of Mass 16 X + 8Y 8 X2Y 29 Law of Multiple Proportion 4 In any compound, the ratio of the numbers of atoms of any two of the elements present is either an integer or a simple fraction. Compounds are composed of atoms of more than one element. 2 : 16 2 : 32 1:8 1 : 16 Law of Multiple Proportions Since atoms are indivisible, they will always combine in simple whole number ratios. Therefore, it would not make sense to write a formula such as Na(0.5)Cl(0.5) because you can't have half of an atom! Atomic Structure and Subatomic particles Subatomic Particles Subatomic Particles Atoms, Molecules and Ions ATOMS vs MOLECULES An atom is smallest particle in an element that has the properties of the element. It is not possible to breakdown the atom further. Molecules are formed by the combination of two or more atoms. The atoms are bonded together in a molecule. Atoms and Molecules A heteronuclear diatomic molecule is a combination of two atoms of different kind. diatomic elements HCl CO NaCl A homonuclear diatomic molecules contains only two atoms of the same kind. H2, N2, O2, Br2, F2, Cl2, I2 A polyatomic molecule contains more than two atoms. O3 H2 O NH3 CH4 Atomic number and Mass number Mass number (A) = number of protons + number of neutrons = atomic number (Z) + number of neutrons Atomic number (Z) = number of protons Atomic number and Mass number A p+ e- n 35 17 17 17 A p+ e- n 7 3 3 4 Exercise 1A Use your periodic table to complete the tables below. A p+ e- n A p+ e- n A p+ e- n Isotopes Isotopes are atoms with the same number of protons but that have a different number of neutrons. We can also say that isotopes are elements with the same atomic number but different mass numbers. Isotopes of Carbon Other Common Isotopes and its Uses A Z p+ e- n A Z p+ e- n A Z p+ e- n Examples A Z p+ e- n A Z p+ e- n A Z p+ e- n An ion is an atom, or group of atoms, that has a net positive or negative charge. cation – ion with a positive charge If a neutral atom loses one or more electrons it becomes a cation. Na 11 protons 11 electrons Na+ 11 protons 10 electrons anion – ion with a negative charge If a neutral atom gains one or more electrons it becomes an anion. Cl 17 protons 17 electrons Cl- 17 protons 18 electrons 49 How many protons and electrons are in? protons electrons 13 10 How many protons and electrons are in? protons electrons 34 36 27 13 Al 3+ 78 234Se Exercise 1B Use your periodic table to complete the tables below. H+ A Z p+ e- n O-2 A Z p+ e- n Ca+2 A Z p+ e- n Mg+2 A Z p+ e- n Te-2 A Z p+ e- n Exercise 1 Use your periodic table to complete the table below. Element Atomic # Mass Protons Neutrons Electrons Symbol Iodine 53 127 53 74 54 I1- 35 17 1 1 Hydrogen 35 5 Oxygen Cl10 45 36 B3+ 11 16 8 10 Exercise 2 Directions: Fill in the missing information in the following tables. A. Neutral Elements Element Symbol Zinc Cobalt Tin (11) (1) Co Sn (12) Atomic Number (2) 27 50 (13) Mass Number 65 (5) (8) 85 No. of Protons 30 (6) (9) 37 No. of Neutrons (3) 32 69 (14) No. of Electrons (4) (7) (10) (15) Atomic Number (2) (6) 35 (13) Mass Number (3) 56 (9) 27 No. of Protons (4) 26 (10) (14) No. of Neutrons 7 (7) 45 (15) No. of Electrons 10 24 (11) 10 B. Ions Element Symbol Nitrogen (5) (8) Aluminum (1) Fe2+ Br(12)