09/03/2022 Redox reactions Starter: Why do metals tarnish? Metals react with oxygen to form metal oxides in an oxidation reaction. metal + oxygen metal oxide The reactions are oxidation reactions because the metal gains oxygen. Oxygen can be removed from metal oxides in chemical Fill in the Blanks 1. 2. 3. 4. 5. 6. Aluminium + Oxygen Aluminium _______ Iron + ______ Iron oxide ______ + Oxygen Lithium oxide Sodium + Oxygen ______ _______ Copper oxide + Carbon _____ + Carbon dioxide Iron(II)oxide + Carbon Iron + _____ _____ For each one decide whether the metal is oxidised or reduced? Challenge: convert the word equations into symbol equations. 1. 2. 3. 4. 5. 6. Aluminium + oxygen Aluminium oxide Iron + oxygen iron oxide Lithium + oxygen lithium oxide Sodium + oxygen sodium oxide Copper oxide + carbon copper + carbon dioxide Iron(II)oxide + carbon Iron + carbon dioxide Peer Mark /12 • Oxidised • Oxidised • Oxidised • Oxidised • Reduced • Reduced Practical- Burning Magnesium Ribbon • Identify a group (2-3) • One person collect: • tongs and goggles • Bunsen burner, heatproof mat and splint • Light Bunsen from partner • Take a small piece of magnesium ribbon and hold in the hot part of the flame using tongs DO NOT LOOK DIRECTLY AT THE FLAME • Place on heat proof mat when finished • Turn gas off • pack away Equipment Goggles, bunsen burner, heatproof mat, tongs, magnesium ribbon, splint Questions 1. Describe the appearance of the magnesium ribbon before, during and after heating. 2. Write the word equation for the reaction 3. Write the balanced symbol equation 4. Is magnesium oxidised or reduced? Challenge 5. What type of bond is formed Answers Describe the appearance of the magnesium ribbon before, during and after heating. Shiny silver Bright white flame White powder Write the word equation for the reaction Magnesium + Oxygen Magnesium oxide Write the balanced symbol equation 2Mg(s) + O2(g) 2MgO(s) Is magnesium oxidised or reduced? Oxidised Challenge What type of bond is formed Ionic Whiteboard Questions Draw a dot and cross diagram to show arrangement of electrons in magnesium and oxygen atoms (before bonding) Draw a dot and cross diagram to show arrangement of electrons in magnesium and oxygen ions (after bonding) Describe the movement of electrons. 2+ 2- Discuss Is Magnesium oxidised or reduced? Is Oxygen oxidised or reduced? Half equations 2Mg + O2 2MgO Can you rearrange the terms to make the 2 half equations balance (charge and number of ions/atoms) Mg Mg2+ e- O2 O2- e- Extension Lithium + Oxygen Lithium oxide Word equation 2Li + O2 Li2O Balanced symbol equation Li Li+ + eO2 +4e- 2O2- Half equation