Example 3: Annotated student work Internal Assessment: Environmental Systems & Societies Research Question To what extent has the corrosive nature of acid rain affected the buildings in Lahore? Word count: 2003 Environmental systems and societies 1 Example 3: Annotated student work Table of Contents Contents page not needed. Introduction .................................................................................................................................3 Research Question .......................................................................................................................3 Hypothesis ...................................................................................................................................3 Procedure ....................................................................................................................................4 Graphical Presentation of results ................................................................................................5 Calculations .................................................................................................................................5 Discussion ....................................................................................................................................6 Conclusion ...................................................................................................................................8 Evaluation ....................................................................................................................................8 Solution ........................................................................................................................................9 Bibliography ...............................................................................................................................10 Environmental systems and societies 2 Example 3: Annotated student work Introduction Acid rain is a serious problem in our environment. Acid rain is composed of both dry and wet deposition from the environment which contains very high amounts of sulphuric and nitric acids. These chemicals that cause acid rain can be caused because of both natural causes and human activities. The natural sources that can cause high levels of nitric and sulphuric acids are volcanic eruptions and decaying vegetations. However, these natural disasters do not occur that often, so it can be said that the major cause for high amounts of sulphur dioxides and nitrogen oxides in the atmosphere is combustion of fossil fuels. Acid rain can cause a lot of damage. The direct effects of acid rain are on aquatic organisms, it can also create an indirect toxic effect on fish by increased solubility of metals. Another effect of acid rain is its corrosive effect on buildings. The extent to which buildings are effected by acid rain will be assessed in this report. Since my city is Lahore and most of the ancient or recent buildings are mostly made from Limestone, Marble, Granite and Brick. Small sized rocks of these materials are used for construction of Environmental issue is outlined. More discussion should be given for the context of the research question. The link to the chosen location is provided but the element of acid rain impacts on the building materials for Lahore could be more detailed. buildings. Research Question To what extent has the corrosive nature of acid rain affected the buildings in Lahore? A reasonable and focused research question Hypothesis Among the given construction materials; limestone, brick, granite and marble, limestone will be the one to be the most effected by acid rain and will bear the most damage. Variable Identification Independent Variable; Type of selected construction material; granite, brick, limestone and marble. Dependent Variable: The remaining weight of construction materials after being submerged in vinegar. Controlled Variable: • Acidity of vinegar in which the construction materials are to be submerged. • Amount of vinegar used. • The duration of time experiment was conducted • The primary weight of construction material No justification given for the choice of vinegar rather than rain/acid rain. Apparatus • Weighing scale (digital) • Piece of cloth Environmental systems and societies 3 Example 3: Annotated student work • Sand paper • Chisel • Hammer • Measuring cylinders • Containers/Beakers Materials • 200 grams of marble • 200 grams of brick • 200 grams of granite • 200 grams of limestone • 3200 ml of vinegar Procedure 1. To perform the experiment, four most used materials in Pakistan's buildings; brick, granite, marble and limestone were selected. All the pieces of construction material were cleaned One data set per treatment so not enough data is collected. Gives some justification for building material choices. and it was made sure that all of them were of equal weight, which is 200g. If one of the piece was not the decided weight of 200g it was reduced to it through using a chisel and a hammer or a sand paper. The weights were then recorded. This mentions sampling strategy but misses parts. How were they cleaned? Was the volume/shape the same? The measuring cylinders are used to measure exactly 800ml of vinegar and poured into four containers along with either one of the selected construction materials. The vinegar is used to imitate the properties of acid rain because of its pH value. Normal run has a ph value of 5.0 which is slightly acidic. However, after combining the nitrogen and sulphuric oxides form automobiles etc. the pH value decreases and becomes about 4.0 Therefore, vinegar is perfect to imitate acid rain because of its low pH value. No value for vinegar pH is given; the reason for using vinegar is weak. Everyday for the next five days, the pieces of the selected construction materials were removed from the vinegar, cleaned and weighed using a digital weighing scale and the results were recorded in the following table. Environmental systems and societies This is not clear enough to follow. 4 Example 3: Annotated student work Data table of construction material submerged in vinegar The raw data is fine; the raw data is then graphed. Weight of the selected construction materials submerged in vinegar (grams ) Construction material Start Day 1 Day 2 Day 3 Day 4 Day 5 Marble 200 171 154 139 125 110 Limestone 200 166 142 123 111 89 Brick 200 194 188 181 174 167.5 Granite 200 200 199 198 196 194.6 Calculations Mean Marble: (200+171+154+139+125+110)/6=149.8 This is a significant error for the data collected and the research question. Limestone:(200+166+142+123+111+89)/6=138.5 Brick:(200+194+188+181+174+167.5)/6=184.1 Granite:(200+200+199+198+196+194.6)/6=197.5 Environmental systems and societies 5 Example 3: Annotated student work Marble σ = √[∑ (x-149.8) 2÷6] σ = √∑ [ ((200-149.8) 2 + (171 - 149.8)2 + (154 - 149.8) 2 + (139 - 149.8) 2 + (125 149.8) 2 +(110 - 149.8)2) ÷ 6] σ = 32.5 Limestone σ = √[∑ (x - 138.5) 2÷6] σ = √ [ (200-138.5) 2 + (166-138.5)2 + (142-138.5) 2 + (123-138.5) 2 + (111-138.5) 2 + (89-138.5)2) ÷ 6 ] σ = 39.9 Brick σ = √[∑ (x-184.1) 2÷6] σ = √ [ (200-184.1) 2 + (194-184.1)2 + (188-184.1) 2 + (181-184.1) 2 + (174-184.1) 2 + (167.5-184.1)2)÷ 6] σ = 12.2 Granite σ = √ [∑ (x-197.5) 2÷ 6] σ =√[ ((200-197.5) 2 + (200-197.5)2 + (199-197.5) 2 + (198-197.5) 2 + (196-197.5) 2 + (194.6-197.5)2) ÷ 6] σ = 2.21 Discussion This is also the conclusion/analysis section. With every passing day in the experiment, I noticed that the weight of every type of construction material (under experiment conditions) was decreasing constantly. I then deemed it important to calculate the mean and standard deviation to know which type of construction material is most affected by acid rain. Environmental systems and societies This does not help answer the research question. 6 Example 3: Annotated student work Marble This type of construction material came in mediocre level in terms of being affected by acid rain. The weight of marble piece reduced by 29 grams on the very first day, this is significant. On the second day, the weight of marble further dropped by 17 grams. The next day the weight loss of the marble piece was recorded to be 15 grams. A the end of the 5 days the remaining weight of the marble piece was 110 grams which was a reduction from 200 grams. so, a total of 90 grams were lost from the marble piece at an average rate of 15 grams/day. The standard deviation is Analysis calculated to get an estimate of the intensity of the affect of acid rain on the selected construction materials. Because the standard deviation measures how concentrated the data are around a mean, the less concentrated the bigger the standard deviation. The value of standard deviation of marble is calculated to be 32.5. Comparing it to the standard deviation of other selected construction materials, this value is fairly high. This means that the value are less concentrated and it can be concluded that acid rain will cause relatively more damage to marble. Limestone This does not help the validity claims and is not a correct statement. Limestone is one of the most commonly used construction materials in Pakistan and hence Lahore because of its availability. The first day its weight dropped by 34 grams, which was the highest weight drops of the day. The next day its weight dropped by 24 grams more. The next day the limestone piece loss weight by a further 19 grams. At the end of the five days, the weight of limestone was 99 grams which is a staggering 111 grams less than our initial weight of 200 grams of limestone. The standard deviation of the weight of limestone is calculated to be 39.9 grams which, in true sense is a very low value indicating the data being spread shortly with a small range of values. However, this interpretation is completely wrong if this value is looked at from a comparative perspective. Out of all the construction materials selected, limestone has the highest standard deviation value which means that its data is spread widely over a large This is a not a good way to try to consider validity of the data. The student has carried forward the misunderstanding of the mass loss and the incorrect calculation of the mean. Then they try to use this information to consider validity. number of values. In other words the weight of limestone is the most concentrated which indicates that it has borne the most damage from the vinegar mixture out of all the selected construction materials. Brick Brick is undoubtedly the most common construction material used in Pakistan. So it is important that it is irresponsive to acid rain in terms of damage. In this experiment, on the first day, the piece of brick only lost 6 grams of weight the next day the brick again lost only 6 grams of weight. For the next two days, the brick kept on losing 7 grams of weight and at the end of the five days, the weight of the brick was 167.5 grams which means that only 32.5 grams of weight were loss Environmental systems and societies 7 Example 3: Annotated student work by the brick in those five days. The standard deviation of brick has a low value of 12.2 which denotes that relative to marble and limestone brick has a lower chance of being damaged by acid rain. Granite The standard deviation does not indicate the chance of damage occurring due to acid rain. Granite is another igneous rock which is commonly used i the construction. Granite is identified as being one of the most durable rocks and construction materials. Through this experiment it was seen that on the first day the weight of granite was exactly the same. The next day it had lost a weight of as less as 1 gram. On the third day only 1 gram was lost again. On the fourth day, 2 grams were lost and on the last day of the experiment 2.4 grams were lost. In the duration of the experiment, only 5.4 grams were lost by granite. The standard deviation of granite is also the lowest and has the value of 2.2 grams only. This means that the weight of granite is the least concentrated around the its mean weight loss, the values are not spread widely which means that granite is not affected much by acid rain. Conclusion This is mainly the discussion. Lahore is known for the buildings and architecture in inhabits rooting all the way back to the Mughal era. With the change in population, technological advancements and human activities, pollution has given rise to acid rain which can cause harm to many living organisms as well as buildings. Through this research I investigated the effect of acid rain on four of the frequently used construction materials which are; marble, limestone brick and granite. Vinegar, due to its A link back to the environmental issue but it is descriptive only. low pH value, was used to imitate acid rain. The experiment was performed was submerging each of the pieces of construction materials (which had equal weights) in to equal quantity of vinegar for five days. To decipher the effects the differences in the weight loss of the construction materials were compared. The hypothesis that limestone amongst all the selected construction materials would suffer the most damage by the vinegar and hence the acid rain was proven to be true as it lost 111 grams of weight out of the initial 200 grams, it had reduced to almost half the initial weight. A conclusion is reached from the data. The validity of the data is not considered. Evaluation This experiment uses vinegar to imitate the properties of acid rain because of its low pH value, however the amount of acid and hence the acidity of actual acid rain may differ causing the Environmental systems and societies 8 Example 3: Annotated student work affect on the the selected construction materials to be different. Other factors like time also influence the affect of acid rain on construction. This experiment was conducted for only five days but actual rain can either take place for different duration of time depending on the weather conditions and pollution levels of the area. Evaluation basics identified. My hypothesis that limestone will be most damaged by acid rain was proven to be true,however, The effect of acid rain on limestone also depends how pure limestone was some A few further considerations are considered. naturally have less than 5% non-carbonate impurities which means they are stronger and more resistant to acid rain damage and vice versa. Similarly, according to this experiment, granite is identified to be the most strong construction material leading us to a conclusion that it should be used for construction more often. However, other problems of granite such as flaking, peeling and efflorescence(appearance of a whitish deposit layer caused by soluble salts or moisture) etc. should also he considered. Solution As mentioned at the start of the report, there are various reasons why acid rain may take place. these reasons can be either natural (i.e. volcanic eruptions) or manmade activities. Though it is impossible to control the natural factors, we can control our activities that cause pollution and give rise to acid rain. One of the most important reasons for pollution is energy production because it creates huge amounts of pollution so we should conserve as much energy as possible. This can be done A solution is stated. through simple gestures like turning off the lights, television and other electronic equipment when they are not in use. We should also try to limit the use of air conditioners as much as possible, and whilst using them the thermostat should be adjusted to higher values. Another way to reduce pollution is to limit the use of personal cars by taking public transport such as buses or trains. We should also try to walk small distances or use bicycles when possible. Environmental systems and societies A range of applications for the solution is mentioned but no evaluation is done. 9 Example 3: Annotated student work Bibliography • "Granite: Characteristics, Uses And Problems." GSA Home. N.p., 13 July 2016. Web. 08 Jan. 2017. <https://www.gsa.gov/portal/content/111938> • "Limestone." Geology. N.p., n.d. Web. 11 Jan. 2017. <http://geology.com/rocks/limestone.shtml> • "How Does Acid Precipitation Affect Marble and Limestone Buildings? [USGS]." How Does Acid Precipitation Affect Marble and Limestone Buildings? [USGS]. N.p., n.d. Web. 14 Jan. 2017. <https://pubs.usgs.gov/gip/acidrain/5.html> Environmental systems and societies 10