Chemistry Journal 7.02 Enthalpy Values Driving Questions: How do scientists calculate enthalpy for physical and chemical changes, and how does that help distinguish between endothermic and exothermic changes? Key Ideas and Terms Notes FQ: How is specific heat capacity related to temperature? What is specific heat capacity? the quantity of heat required to raise the temperature of one gram of a substance by one degree Celsius Why is specific heat capacity an intensive property? It is an intensive property because the amount of the substance does not change its specific heat capacity. How does a change in mass affect how much thermal energy is needed to change the temperature of a substance? However, a difference in mass does impact how much thermal energy must be absorbed before a change in temperature occurs. For instance, when the same amount of heat is applied, an ocean will take a lot longer to change temperature than a small lake. Video: Specific Heat Capacity What units of measurement are used to measure specific heat capacity? It is measured in joules per gram degrees Celsius. It can also be measured in joules per gram Kelvin. What is the formula for specific heat capacity? It can be calculated using the following formula—specific heat, or C, equals heat generated by the temperature change, or Q, divided by the mass of substance times the change in temperature. Does low specific heat equal lower melting point? Explain why or why not. Yes FQ: How are energy transfers calculated using a temperature change? How do chemists calculate energy transfers in an The energy transfer of an unknown sample can be calculated using the specific heat capacity of the sample, the temperature change observed during the reaction, and the mass of the sample. unknown sample? Video: Calculating Enthalpy What is the equation to calculate enthalpy? Show how to use the enthalpy equation from the video example. q equals m times c times delta T Describe each variable of the enthalpy equation. How is change of temperature determined for the enthalpy equation? A flask containing 855 grams of water was heated over a Bunsen burner. If the temperature of the water was raised from 21.0 to 85.0 degrees Celsius, how much heat (in joules) did the water absorb? Describe the steps. The specific heat capacity of liquid water is 4.184 J/g ⁰ C. When using the specific heat capacity equation to calculate enthalpy, the change in temperature (△T) can be determined by subtracting the initial temperature of a substance from the final temperature. Use the common specific heat capacities table to help you solve the practice problems below. Be sure to include a copy of the table to your chemistry journal. A frying pan with 5 grams of vegetable oil is heated on a stove top. If the temperature of the oil increases from 25.0 °C to 95.0 °C, how much energy does the oil absorb? Calculate the number of joules released when 72.5 grams of water at 95.0 °C cools to a final temperature of 28.0 °C. How does enthalpy change during phase changes? FQ: How is the heat of reaction calculated for a chemical reaction? What is the heat of reaction? the change in the enthalpy of a chemical reaction that occurs at a constant pressure What is the equation to calculate the heat of reaction? What is the total enthalpy change of a reaction? The total enthalpy change in a reaction is a combination of the energy used to break bonds in the reactants and the energy released when bonds are formed in the products. How does △H become positive or negative? Endothermic Exothermic How can enthalpy change be used as a conversion factor to determine heat of reaction? The enthalpy change of a reaction or process is usually expressed in kilojoules per mole (kJ/mol) in a thermochemical equation. What is a a balanced chemical equation that shows the enthalpy change in a thermochemical reaction? reaction The chemical reaction and enthalpy change for burning methane (CH4) is given below. If 38.5 grams of methane are burned, how many kilojoules of energy are transferred, and is this reaction endothermic or exothermic? CH4 + O2 → CO2 + 2H2O △H = −890.0 kJ/mol During an endothermic reaction, H for the reactants was −200 kJ/mol. What range of values could the H for the products be for this reaction? The combustion of isooctane fuel (C8H18) has an enthalpy change of −5,460 kJ/mol. How many kilojoules of energy are released when 350.0 grams of isooctane are burned? Be sure to record any extra helpful notes, vocabulary terms, and practice sample problems.