Chemical reactions Gives out a great amount of energy – wydziela dużą ilość energii Dependence on fossil fuels – zależność od paliw kopalnych Combustion engine - silnik spalinowy Bi-fuel engine – silnik dwupaliwowy Put in place - wprowadzony Poses its own problems - stwarza własne problemy Stored safely – przechowywany bezpiecznie Forcing - zmuszanie, wymuszanie, narzucanie Reliable fuels - niezawodne paliwa Immensely - niezmiernie Commitment - zaangażowanie Reap the benefits – czerpanie korzyści Non-polluting - niezanieczyszczanie Prospect - perspektywa Hydrogen fuel cell car - samochody na wodorowe ogniwa paliwowe Filling stations – stacje paliwa Crystal lattice – sieć krystaliczna Vast – ogromny, rozległy Devastatingly damaging – zatrważająco szkodliwy 4.1 Chemical reactions and equations. Interconnecting reactions – reakcje łączenia Chemistry deals with how substances react with each other. Physical changes: The substances present remain chemically the same: no new substances are formed. Are often easy to reverse. Any mixtures produced are usually easy to separate. Water exists under different conditions of temp. Or pressure – one form can change into another if those conditions change. Dissolving sugar in ethanol or water – it produces a solution, but the substances can easily be separated again by distillation Chemical change: Exothermic change – energy is given out in the form of heat and light. Example – chemiluminescence, burning magnesium, the condensation of steam to water Endothermic change – energy is taken in in form of heat from surrounding. Example – the addition of concentrated sulfuric acid to water, reaction between nitrogen and oxygen. The new substances are made during the reaction Many reations (not all) are difficult to reverse More exothermic than endothermic reactions. 4.2 Equations for chemical reactions. Word equations – type of equation which links together the names of the substance that react (the reactants) with those of the new substances formed (the products). This type gives us some information. Balanced symbol equations: Law of conservation of mass – the total mass of all the products of a chemical reation is equal to the total mass of all the reactants. During a chemical reaction, the atoms of one element are not changed into those of another element. Balanced equation – the numbers of each type of atom are the same on both the reactant side and the product side of the equation. Writing balanced equations: You cannot change the fromulae of the substances themselves when balancing equations. These are fixed by the nature of the atoms and their bonding. 4.3 Types of chemical reaction. Synthesis reactions - (direct combination) occur where two or more substances react together to form just one product. They are usually exothermic. There is one synthesis reaction, which is endothermic namely photosynthesis (photochemical reaction) Spontaneous - spontaniczny Vigorous - energiczny Chlorophyll – chlorofil Decomposition reactions – have just one reactant, which breaks down to give two or more simpler products. Thermal decomposition – decomposition caused by heat energy. Neutralisation reactions – involve acids. When acid react with bases or alkalis, their acidity is destroyed. They are neutralised and a salt is produced. Precipitation reactions – involve the formation of an insoluble product. Precipitation – the sudden formation of solid, either when two solutions are mixed or when a gas is bubbled into a solution. Limewater test – badanie wody wapiennej Displacement reactions – occurs because a more reactive element will displace a less reactive one from a solution of one of its compounds. The halogens can be placed in order of reactivity using displacement reactions. Combustion – the reaction of a substance with oxygen causing the release of energy. The reaction is exothermic and often involves a flame. Burning – combustion in which a flame is produced. Fuels - substances such as methane, which undergo combustion readily and give out a large amount of energy. Digestation – during that, food i broken down into simpler substances. Respiration – exothermic reaction. If a substance gains oxygen during a reaction, it is oxidised. If a substance loses oxygen during a reaction, it is reduced. Reducing agent – an element or compound that will remove oxygen from other substances. The commonest reducing agents are hydrogen, carbon and carbon monoxide. Oxidising agent – a substance that will add oxygen to another substance. The commonest oxidising agent are oxygen, hydrogen peroxide, potassium manganate vii and potassium dichromate vi. Examples of oxidation reactions: Corrosion – if a metal is reactive, its sufrace may be attacked by air, water or other things. When iron or steel slowly corrodes in damp air, the product is a brown, flaky rust. Rusting weakens structures such as car bodies. Rancidity – when the fats and oils in butter and margarine oxidised, they become rancid. Manufactures add antioxidants to fatty foods and oils to prevent oxidation. Keeping foods in refrigerator can slow down the oxidation process, storage in airtight containers.