CARBON COMPOUNDS 1. SECTION A Diagram 1 shows structural formula of a hydrocarbon. H DIAGRAM 1 a) State a general formula and name the hydrocarbon. General formula : …………………………………….. Name : ……………………………………. [2 marks] b) Draw two isomers of the hydrocarbon. [2 marks] c) (i) Write a chemical equation for the reaction between bromine water and the hydrocarbon. …………………………………………………………………………….....…........………. [1 mark] (ii) State the observation for the reaction at (c)(i). ……………………………………………………...........………………………....……….. [1 mark] d) (i) Name the gas release when the hydrocarbon combust completely. …………………………..…………………………………………………........................... [1 mark] (ii) State a chemical test that can be carried out to confirm the gas release at (d)(i). ........…………………………………………………………………………………............. ....…………………………………………………………………………………............…. [2 marks] 1 2 The diagram 2 shows the conversion process of propanol to other substances. D C3H8 E II C3H6 I III Propanol Propanoic acid Warm ethanoic acid and concentrated sulphuric acid IV Y DIAGRAM 2 (a) (i) Name process I. …………………………………………………............……………………………… [1 mark] (ii) Write a general formula for substance E. ……………………………………...........…………………………………………… [1 mark] (b) (i) Name process II. ………………………………………………………………………………............… [1 mark] (ii) State a catalyst use in process II. ...........………………………………………………………………………………… [1 mark] (c) Explain a chemical test to differenciate substance D and substance E. ......................………………………………………………………………………………… ......................………………………………………………………………………………… ......................………………………………………………………………………………… [2 marks] (d) (i) Name a chemical substance use in process III. ............………………………………………………………………………………… [1 mark] 2 (ii) Based on the answer in (d)(i), state the observation in process III? ………………………………………………………............………………………… [1 mark] (iii) Propanoic acid react with magnesium. Write a chemical equation for the reaction. ………………………………………………………………………………............… [1 mark] (e) (i) Substance Y is the product of process IV. Name substance Y. ..........………………………………………………………………………………… [1 mark] (ii) What is the function of concentrated sulphuric acid in process IV? …………………………………………………………………………...................... [1 mark] 3 The diagram 3 shows the conversion of several organic compound through the reactions I ,II, III and a complete combustion of compound L in oxygen. Compound J C2H6O I III acidified potassium dichromate (VI) Compound K C2H4O2 II Complete combustion Compound L C2H4 Gas X + H2O DIAGRAM 3 (a) (i) Name the homologous series of compound L ………………………………………………………………………....………[1 mark] (ii) Name gas X. …………………………………………………………………………………[1 mark] (iii) Write a chemical equation for the complete combustion of compound L. ..………………………………………………………………………….........[2 markS] (iv) 0.5 mole of compound L is burnt completely to produce gas X. Calculate the volume of gas X produce in the reaction. 3 [1 mol of gas occupied 24 dm3 at room condition.] [2 marks] (b) State the observation of acidified potassium dichromate (VI) solution in reaction III. …………………………………………………………………………………............ [1 mark] (c) Compound J react with compound K to produce compound M. (i) Name compound M. ..................…………………………………………………………………… [1 mark] (ii) Draw a structural formula for compound M. .....……………………………………………………………………………. [1 mark] (iii) State one special characteristic of compound M. ......……………………………………………………………………………. [1 mark] (d) Draw the set up of the apparatus for the reaction II. [2 marks] 4 Diagram 4 shows the reactions for compound X. Compound X, C2H6O Acidified potassium manganate(VII) I Porcelain chips Gas Q II Compound Y, C2H4O2 III Reflux with Compound Z substance X and 4 + water concentrated sulphuric acid DIAGRAM 4 (a) Name compound X. ……………………………………………………………………......……………….. [1 mark] (b) (i) Name gas Q. ....……………………………………………………………………………… [1 mark] (ii) Draw the set up of the apparatus for reaction I. [2 marks] (c) (i) What is the colour changes observed in reaction II. ........………………………………………………………………………….. [1 mark] (ii) Draw a structural formula of compound Y. [ 1 mark ] (d) Reaction III is a reflux of mixtures of substance X, substance Y and concentrated sulphuric acid. (i) What is the function of concentrated sulphuric acid. ………………………………………………………………………..……….. [1 mark] (ii) Write a chemical equation for the reaction. ………………………………………………………………………………. [1 mark] (iii) Name one special characteristic of substance Z. ……………………………………………………………………………….. [1 mark] (iv) Substance X is replaced with buthanol. Name the substance of the product. 5 ………………………………………………………………………………… [1 mark] 6