Matter and Its Properties ✘ Chemistry is the branch of science concerned with the substances of which matter is composed, the investigation of their properties and reactions, and the use of such reactions to form new substances. ✘ Chemistry is the science and study of matter, including its properties, composition as well as reactivity. ✘ Chemistry relates to everything that can be sense from the minute elements to complex structures ✘ The atom and molecules are the basic unit or components of Chemistry. ✘ Atom - are the basic units of matter and the defining structure of elements. ✘ Molecules - a group of two or more atoms that form the smallest identifiable unit. ✘ Matter is made of particles that give its mass and volume. The arrangement and attraction between these particles result in different phases of matter. ✘ Matter can exist as solid, liquid or gas. How can you differentiate one from another? Three Phases of Matter Solid • Liquid Gas retains a fixed volume and shape rigid - particles locked into place • • • not easily compressible little free space between particles • • not easily compressible little free space between particles • • compressible lots of free space between particles • • does not flow easily rigid - particles cannot move/slide past one another • • flows easily particles can move/slide past one another • • flows easily particles can move past one another • • assumes the shape of the part • of the container which it occupies • particles can move/slide past one another assumes the shape and volume of its container particles can move past one another Physical Properties ✘ ✘ Physical Properties is a characteristic of matter that is not associated with a change in its chemical composition. Familiar examples of physical properties include density, color, hardness, melting and boiling points, and electrical conductivity. Chemical Properties ✘ ✘ Describe a material’s possibility to undergo chemical change in its chemical composition. Examples of chemical properties include flammability, toxicity, oxidation states, chemical stability, salt formation, and types of chemical bonds a material forms. Intensive and Extensive Properties ✘ Physical properties of matter can further be classified as intensive and extensive. Intensive Property ✘ ✘ are substance-specific properties that do not depend on the amount of the substance. Other intensive properties include color, luster, malleability, conductivity, hardness, melting point, freezing point, and boiling point of the material. Examples of Intensive Properties include: ✘ ✘ ✘ ✘ ✘ ✘ Density Specific Gravity Specific Heat Temperature Hardness Refractive Index ✘ ✘ ✘ ✘ ✘ ✘ ✘ Boiling Point Concentration Pressure Specific Volume Chemical Potential Color Molality Extensive Property ✘ are properties that do not depend on the amount of substance or material. Whenever the amount of the substance changes, the substance’s extensive properties also change. Extensive and Intensive properties Extensive Properties Weight, volume, length, mass Intensive Properties Density, color, luster, malleability, conductivity, hardness, melting point, freezing point, boiling point Classification of Matter Classification of Matter ✘ Matter takes any forms. But isn’t it confusing if you label everything as matter? ✘ Classification according composition will make a clear distinction among materials. Pure Substances and Mixtures ✘ ✘ ✘ ✘ Matter, whether it is solid, liquid or gas, is classified as a pure substance or a mixture. If the components of matter can be separated by physical means, then that is a mixture. Anything that cannot be broken down through physical means is a pure substance. A pure substance can be classified as an element or a compound. Pure Substances and Mixtures ✘ If a pure substance can be broken down into simpler forms using chemical means, you are dealing with a compound. ✘ If it cannot be simplified, then it is an element. Comparison between Substances and Mixtures Criteria Substances Mixtures 1. Melting temperature range Sharp Wide 2. Boiling temperature range Constant Varying Homogeneous Heterogeneous 4. Distilling property Cannot be distilled Can be distilled 5. Separation into components or constituents By chemical means By mechanical means (physical) 3. Physical Appearance Mixtures ✘ Mixtures are forms of matter with no definite properties and are not combined chemically. This means that the materials in a mixture retain their characteristics, or they have no uniform composition. Mixtures ✘ Homogeneous Mixture is a mixture that has uniform composition. (i.e dextrose or glucose solution) Mixtures ✘ Heterogeneous Mixture has at least two different phases of matter or visible components. Elements and Compounds ✘ An element, the simplest pure substance that make up matter, is made up only one kind of atom. An element cannot be broken down into a simpler type of matter by either physical or chemical means. ✘ An atom, which means indivisible particle, is the basic unit of an element. Elements and Compounds ✘ ✘ A compound, on the other hand, is made up of two or three more different kinds of atoms chemically combined. Elements can be classified into three according to their properties: metals, non-metals, and metalloids. Each type has its own characteristics and uses. Differences in the properties of metals, nonmetals, metalloids Metals Good electrical conductors and heat conductors. Malleable- can be shaped into thin sheets. Ductile- can be stretched into a wire Possess metallic luster Opaque as thin sheets Solid at room temperature (except Hg) Nonmetals Poor conductors of heat and electricity Brittles (in solids only) Nonductile Do not possess metallic luster Transparent as a thin sheet Solids, liquids, or gases at room temperature Metalloids Intermediate between metal and non-metal Can be shiny or dull Excellent semiconductors Elements and Compounds ✘ When elements chemically combine in a fixed proportion, you call the product a compound. An example of compound is water. Water is made up of the chemical combination of hydrogen and oxygen, resulting H2O. H2 + O2 = 2H2O Common compounds at home Common Name Chemical Name Chemical Formula Table salt Sodium chloride NaCl Sugar Sucrose C12H22O11 Vinegar Acetic acid CH3COOH Baking soda Sodium bicarbonate NaHCO3 Ethyl alcohol Ethanol C2H6O Separation of Mixtures 1. Chromatography ✘ ✘ is the separation of a mixture by passing it in solution or suspension or as a vapor (as in gas chromatography) through a medium in which the components move at different rates. Thin-layer chromatography is a special type of chromatography used for separating and identifying mixtures that are or can be colored, especially 2. Distillation ✘ ✘ is an effective method to separate mixtures comprised of two or more pure liquids. Distillation is a purification process where the components of a liquid mixture are vaporized and then condensed and isolated. In simple distillation, a mixture is heated and the most volatile component vaporizes at the lowest temperature. Distillation ✘ The vapor passes through a cooled tube (a condenser), where it condenses back into its liquid state. The condensate that is collected is called distillate. 3. Evaporation ✘ ✘ ✘ is a technique used to separate out homogenous mixtures where there is one or more dissolved solids. This method drives off the liquid components from the solid components. The process typically involves heating the mixture until no more liquid remains, Prior to using this method, the mixture should only contain one liquid component, unless it is not important to isolate the liquid components. Evaporation ✘ ✘ This method is suitable to separate a soluble solid from a liquid. In many parts of the world, table salt is obtained from the evaporation of sea water. The heat for the process comes from the sun. 4. Filtration ✘ ✘ is a separation method used to separate out pure substances in mixtures comprised of particles some of which are large enough in size to be captured with a porous material. Particle size can vary considerably, given the type of mixture. Filtration ✘ ✘ For instance, stream water is a mixture that contains naturally occurring biological organisms like bacteria, viruses, and protozoans. Some water filters can filter out bacteria, the length of which is on the order of 1 micron. Other mixtures, like soil, have relatively large particle sizes, which can be filtered through something like a coffee filter. 5. Decantation ✘ ✘ ✘ is defined as the separation process in which two immiscible liquids are separated. This is done by pouring out the clear upper layer of liquid. Separation of a mixture of oil from water is an example of decantation. 6. Sedimentation ✘ is the tendency for particles in suspension to settle out of the fluid in which they are entrained and come to rest against a barrier. ARIGATOUU