Taraba State Polytecnic Suntai Department of Mechanical Engineering Diploma Two(2) First Semester, 2019/2020 Session Virtual Online Lecture Delivery(V-OLD) Course Title: Thermodynamics Course Code : Mec 213 Course Unit : 3 Course Lecturer : Engr. Kalus Emmanuel Thank God! You are Covid-19 Free Please Observe WHO Protocols Wash Your Hands with soap & Water Use Alcohol Base Hand Sanitizer Wear Your Face Mask Keep Social Distancing ( 2m) Welcome !!! Thermodynamics Lecture One (1) Topic: Definition of Thermodynamics and Thermodymic properties Aim : At the end of this studies students’ should be able to define Thermodynamics and Thermodynamic Properties of a system Learning Objectives : The Objective of this study is for students’ to understand thermodynamic systems and surroundings Specific Objectives are: Define Thermodynamics Describe the terms that are important to the definition above Understand What is a thermodynamic System Understand the three(3) thermodynamic Systems Understand different types of thermodynamic properties of a system Instructional Materials : Lecture Notes, a “Textbook of Engineering Thermodynamics” Fourth Edition by R.K. Rajput, and an Android Phone Definition of Thermodynamics The word “Thermo-dynamic,” derives its etymology from two Greek words “ therme” and “dynamis” meaning heat, and power or action respectively. Therefore, combining the two words gives “ heat Power” or “ heat action ”. therefore we can say that thermodynamics is the science of engineering that study the effects of heat action or heat power on a system or its surroundings or vice versa. Classification of Thermodynamics Thermodynamics that deals with macroscopic properties such as heat, work, internal energy, enthalpy, entropy, Gibbs free energy e.t.c of molecules is called classical thermodynamics. It does not deal with the microscopic properties of molecules. Thermodynamics that deals with microscopic properties of molecules at the scale of 10-9m and considers the behaviors of particles as waves as particles vice versa is called quantum thermodynamics. It does not deal with the macroscopic properties of molecules of a system. Thermodynamics that bridges quantum mechanics and continuum (constant progression of matter with small changes over time) and deals with the probability of individual molecules of a system, there average properties and energy levels is called statistical thermodynamics. So basically, there are three(3) categories of thermodynamics. Description of Terms important to the definition of Thermodynamics It is important to describe some terms that are very important to the definition of thermodynamics. • Thermodynamic system: A quantity of fixed mass under investigation, it is a region containing matter or energy separated by walls or boundaries • Surroundings: everything external to the system. • System boundary: interface separating system and surroundings, it is the closed surface surrounding the system through which energy or mass (matter) can enter or leave a system. • Universe: combination of system and surroundings. For example : 1. Mixture of fuel + Air inside a cylinder = A Thermodynamic system 2. The Piston, exhaust system, cooling system, lubrication system, e.t.c = The thermodynamic surroundings. Thermodynamic Systems and Surroundings A thermodynamic system is a quantity of fixed mass under investigation, what is not in the system is defined as the surroundings. A system can be: Open or closed, depending on whether it can exchange matter or not with its surroundings. Non-isolated or isolated, depending on whether it can exchange energy, or not, with its surroundings, movable or rigid. If the system is open, it cannot be isolated. So in summary Systems can be: • Open System ( Control Volume): Mass and Energy can transfer between the System and the Surroundings • Closed System (Control Mass): Energy can transfer between the System and the Surroundings, but not mass e.g. A closed capped cup of coffee. A thermodynamic system can also be said to be an isolated or non-isolated systems. • Isolated systems : Neither Mass nor Energy can transfer between the System and the Surroundings Non- Isolated Systems : Both open and closed systems are non- isolated systems. Thermodynamic Properties Thermodynamic properties are basically categorized into two. 1. Intensive Properties: Intensive Properties are properties that is independent of the mass of a system. They do not depend on the mass of a system, examples of intensive properties are temperature and pressure. 2. Extensive Properties : Extensive properties are properties that depends on the mass of the system, examples of extensive properties includes mass, volume, energy Both intensive and extensive properties are all thermodynamic variables. A thermodynamic variable are the quantities used to characterize a system that is at equilibrium. Other thermodynamic variables are : volume (V), surface (S), number of particles (N), amount of substance (n) in moles, applied force (F), internal energy (U), magnetization (M), chemical potential, entropy (S), enthalpy (h) etc. ASSIGNMENT 1 Note 1. All students are to request for free thermodynamic steam table from the lecturer for further lectures, this is critical for the next lecture. 2. students should see the course lecturer for the curriculum of the course to enable study ahead in preparation for further lectures. Assignment 1 Now that you have understood what is a thermodynamic system, surroundings, and thermodynamic properties and variables, give an example of a thermodynamic system aside the one mentioned in the lecture, clearly highlighting the system and the surroundings. State also if the system is an open, closed or isolated system( 5 marks), Thank you and good luck