Introduction EN113 Engineering Materials & Properties Dr. S. K. Ales, PhD BE & MTech (PNGUT, PG), PNGUT; ME (SAU CN); PhD (AUT, NZ) Department of Mechanical Engineering PNG University of Technology * 1 Today’s Lecture ■ ■ Administrative issues (syllabus, etc.) Introduction to materials engineering 2 Important Information ■ Meeting time and place ■ ■ Textbook (recommended) ■ ■ CT208 (tutorials/Assignments/Tests) W.D. Callister, Materials Science and Engineering: An Introduction, 9th ed. Prerequisites ■ Earlier versions of W.D. Callister, Materials Science and Engineering: An Introduction 3 1Attendance : Course Requirements 1. You are expected and required to attend all classes of this course. Since this course is too difficult to study by yourself , it is particularly important for you to be in class to benefit from all that your fellow students and instructor have to offer. 2. You can leave messages for me at steve.korokan@pnguot.ac.pg 3. Grading Guidelines: (1) 2 x Assignments : weight 10% ; (2) 2 x Tests : weight 20%; (3) 3 x Laboratory: weight 20% ; (4)Final examination : weight 50% . EN113 Final Subject outline will be issued soon. * 4 Lectures Time: See your time table Location: DH/RKLT Activities: • Present new material • Announce reading and homework • Take quizzes and midterms* *Make-ups given only for emergencies. *Discuss potential conflicts beforehand. * 5 Recitations Instructor: tba Times and Places: ___. ___. ___. ___. X:XXa _____ m XXX X:XXp _____ m XXX X:XXp _____ m XXX X:XXa _____ XXX Purpose: m • Discuss homework, quizzes, exams • Hand back graded quizzes, exams • Discuss concepts from lecture Recitations start next week. Try to attend your registered recitation. If*necessary, attend an alternate recitation. 6 Laboratory Instructor/Lab Assistant: tba Location: M6 Materials Science & Engineering lab Purpose: To learn more about materials by relating lecture material with observations. Also to learn to properly formulate and write engineering reports and proposals. * 7 Teaching Assistants Roles Nam e_____ _____ _____ _____ _____ Office _____ _____ XXX _____ XXX _____ XXX _____ XXX XXX Tel. X-XXX X-XXX X-XXX X-XXX X-XXX X E-mai l _____ _____ _____ _____ _____ Teaching Assistants will • participate in recitation sessions, • have office hours to help you with course material and problem sets. * 8 Office Hours *Contact lab assistants for special arrangements Activities: • Discuss homework, quizzes, exams • Discuss lectures, book • Pick up missed handouts * 9 Course Materials Required textbook: • Materials Science and Engineering: An Introduction, W.D. Callister, Jr. and D.G. Rethwisch, 9th edition, John Wiley and Sons, Inc. (2010). References: All earlier versions by W.D. Callister and D.G. Rethwisch Google class ID: c27rywg Link: https://classroom.google.com/c/NDY1OTgwNTMzNjIx?cjc=c27rywg * 10 Overall Aim Course Objective... Introduce fundamental concepts in Materials Science & Engineering You will learn about: • material structure • how structure dictates properties • how processing can change structure This course will help you to: • use materials properly • realize new design opportunities with materials * 11 Chapter 1 - Introduction ■ What is materials science? Why should we know about it? ■ Materials drive our society ■ ■ ■ ■ ■ Stone Age Bronze Age Iron Age Now? ■ ■ * Silicon Age? Polymer Age? 12 Development of Materials in history * 13 Components of Materials Engineering ■ ■ ■ Materials science is the study of the relationships between the structures and properties of materials Materials engineering is the design or engineering of a material to produce the desired properties Components of materials engineering: 14 Metals, Ceramics & Polymers Familiar objects made of metals and metal alloys (from left to right): silverware (fork and knife), scissors, coins, a gear, a wedding ring, and a nut and bolt. Adapted from Callister Fig. 1.9 9E Common objects made of ceramic materials: scissors, a china teacup, a building brick, a floor tile, and a glass vase. Adapted from Callister Fig. 1.10 9E * Several common objects made of polymeric materials: plastic tableware (spoon, fork, and knife), billiard balls, a bicycle helmet, two dice, a lawn mower wheel (plastic hub and rubber tire), and a plastic milk carton. Adapted from Callister Fig. 1.11 9E 15 Application Example – Hip Implant ■ With age or certain illnesses joints deteriorate. Particularly those with large loads (such as hip). * Adapted from Fig. 22.25, Callister 7e. 16 Application Example – Hip Implant ■ Requirements mechanical strength (many cycles) good lubricity biocompatibility ■ ■ ■ * Adapted from Fig. 22.24, Callister 7e. 17 Application Example – Hip Implant * Adapted from Fig. 22.26, Callister 7e. 18 Hip Implant ■ Key problems to overcome ■ fixation agent to hold acetabular cup ■ cup lubrication material ■ femoral stem – fixing agent (“glue”) ■ must avoid any debris in cup Ball Acetabular Cup and Liner Femoral Stem * Adapted from chapter-opening photograph, Chapter 22, Callister 7e. 19 Structure, Processing, & Properties • Properties depend on structure ex: hardness vs structure of steel (d) Hardness (BHN) 600 500 400 30 μm (c) (b) (a) 4 μm 300 200 100 0.0 1 30 μm 0. 1 30 μm Data obtained from Figs. 10.30(a) and 10.32 with 4 wt% C composition, and from Fig. 11.14 and associated discussion, Callister & Rethwisch 8e. Micrographs adapted from (a) Fig. 10.19; (b) Fig. 9.30;(c) Fig. 10.33; and (d) Fig. 10.21, Callister & Rethwisch 8e. 1 10 100 1000 Cooling Rate (ºC/s) • Processing can change structure ex: structure vs cooling rate of steel * 20 Types of Materials • Metals: – Strong, ductile – High thermal & electrical conductivity – Opaque, reflective. • Polymers/plastics: Covalent bonding 🡪 sharing of e’s – Soft, ductile, low strength, low density – Thermal & electrical insulators – Optically translucent or transparent. • Ceramics: ionic bonding (refractory) – compounds of metallic & non-metallic elements (oxides, carbides, nitrides, sulfides) – Brittle, glassy, elastic – Non-conducting (insulators) * 21 The Materials Selection Process 1. Pick Application Determine required Properties Properties: mechanical, electrical, thermal, magnetic, optical, deteriorative. 2. Propertie Identify candidate Material(s) s Material: structure, composition. 3. Material Identify required Processing Processing: changes structure and overall shape ex: casting, sintering, vapor deposition, doping forming, joining, annealing. * 22 Example: Selection Criteria for Beverage Container ■ ■ ■ ■ ■ ■ * provide a barrier to the passage of carbon dioxide, which is under pressure in the container; be nontoxic, unreactive with the beverage, and, preferably be recyclable; be relatively strong, and capable of surviving a drop from a height of several feet when containing the beverage; be inexpensive and the cost to fabricate the final shape should be relatively low; if optically transparent, retain its optical clarity; capable of being produced having different colors and/or able to be adorned with decorative labels. 23 Example: Aluminum alloy is relatively strong (but easily dented), is a very good barrier to the diffusion of carbon dioxide, is easily recycled, beverages are cooled rapidly, and labels may be painted onto its surface, however they are opaque and expensive to produce. Glass is impervious to the passage of carbon dioxide, is a relatively inexpensive material, may be recycled, but it cracks and fractures easily, and glass bottles are relatively heavy * Plastic is relatively strong, may be made optically transparent ,is inexpensive and lightweight, and is recyclable, it is not as impervious to the passage of carbon dioxide as aluminum and glass 24 Electrical • Electrical Resistivity of Copper: 6 4 3 (10-8 Ohm-m) Resistivity, ρ 5 2 1 0 Cu + 3.32 i t%N a i %N t a Ni 16 . % t 2 + 12 a . Cu 1 u+ C med i r o f %N t de a 1.12 + Cu Cu ” e r “Pu -20 0 -10 0 0 Adapted from Fig. 18.8, Callister & Rethwisch 8e. (Fig. 18.8 adapted from: J.O. Linde, Ann Physik 5, 219 (1932); and C.A. Wert and R.M. Thomson, Physics of Solids, 2nd edition, McGraw-Hill Company, New York, 1970.) T (ºC) • Adding “impurity” atoms to Cu increases resistivity. • Deforming Cu increases resistivity. * 25 Thermal -- Silica fiber insulation offers low heat conduction. Adapted from chapter-opening photograph, Chapter 17, Callister & Rethwisch 3e. (Courtesy of Lockheed Missiles and Space Company, Inc.) * 100 μm • Thermal Conductivity of Copper: -- It decreases when you add zinc! Thermal Conductivity (W/m-K) • Space Shuttle Tiles: Adapted from Fig. 19.4W, Callister 6e. (Courtesy of Lockheed Aerospace Ceramics Systems, Sunnyvale, CA) (Note: "W" denotes fig. is on CD-ROM.) 40 0 30 0 20 0 10 0 0 0 1 2 3 4 Composition (wt% 0 0 0 0 Adapted from Fig. 19.4, Callister & Rethwisch Zinc) 8e. (Fig. 19.4 is adapted from Metals Handbook: Properties and Selection: Nonferrous alloys and Pure Metals, Vol. 2, 9th ed., H. Baker, (Managing Editor), American Society for Metals, 1979, p. 315.) 26 Magnetic • Magnetic Storage: vs. Composition: -- Adding 3 atomic % Si makes Fe a better recording medium! Magnetization -- Recording medium is magnetized by recording head. • Magnetic Permeability Fe+3%Si Fe Magnetic Adapted from C.R. Barrett, W.D. Field Fig. 20.23, Callister & Rethwisch 8e. Nix, and A.S. Tetelman, The Principles of Engineering Materials, Fig. 1-7(a), p. 9, 1973. Electronically reproduced by permission of Pearson Education, Inc., Upper Saddle River, New Jersey. * 27 Optical • Transmittance: -- Aluminum oxide may be transparent, translucent, or opaque depending on the material structure. single crystal polycrystal: low porosity polycrystal: high porosity Adapted from Fig. 1.2, Callister & Rethwisch 8e. (Specimen preparation, P.A. Lessing; photo by S. Tanner.) * 28 Deteriorative -- causes cracks! • Heat treatment: slows crack speed in salt water! crack speed (m/s) • Stress & Saltwater... 1 8 0 1 -1 0 0 Adapted from chapter-opening photograph, Chapter 16, Callister & Rethwisch 3e. (from Marine Corrosion, Causes, and Prevention, John Wiley and Sons, Inc., 1975.) “as-is ”“held at 160ºC for 1 hr before Alloy 7178 tested in testing” saturated aqueous NaCl solution at 23ºC increasing load Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation and Fracture Mechanics of Engineering Materials" (4th ed.), p. 505, John Wiley and Sons, 1996. (Original source: Markus O. Speidel, Brown Boveri Co.) -- material: 4 μm 7150-T651 Al "alloy" (Zn,Cu,Mg,Zr) * Adapted from Fig. 11.26, Callister & Rethwisch 8e. (Provided courtesy of G.H. Narayanan and A.G. Miller, Boeing Commercial Airplane Company.) 29 Advanced Materials ▪ Semiconductors have intermediate properties between metals (conductors) and ceramics/Polymers. For example, integrated circuitry that have totally revolutionised the electronics and computer industries ▪ Biomaterials are employed in components implanted into the human body to replace diseased or damaged body parts. These materials must not produce toxic substances and must be compatible with body tissues (i.e., must not cause adverse biological reactions). All of the preceding materials—metals, ceramics, polymers, composites, and semiconductors— may be used as biomaterials. ▪ Smart (or intelligent) materials are a group of new and state-of-the-art materials now being developed that will have a significant influence on many of our technologies * 30 Advanced Materials ▪ Nanomaterials are those that have structural features on the order of a nanometer, some of which may be designed on the atomic/molecular level). They can be metal, ceramic, polymer or composites. * 31 Summary Course Goals: • Use the right material for the job. • Understand the relation between properties, structure, and processing. • Recognize new design opportunities offered by materials selection. * 32 Homework Problem 1.1: Select one or more of the following modern items or devices and conduct an Internet search in order to determine what specific material(s) is (are) used and what specific properties this (these) material(s) possess(es) in order for the device/item to function properly. Finally, write a short essay in which you report your findings: a)Cell phone b)PCB (Printed Circuit Boad) (c)digital camera batteries d)Cell phone displays e)Solar cells (f)Wind turbine blades g)Automobile engine blocks (other than cast iron) h)Automobile bodies (other than steel alloys) •Space telescope mirrors •Military body armor a)Sports equipment b)Soccer balls/Basketballs (c)Ski poles d)Ski boots * 33