Date: ______________ Name: ___________________ SCH4U Unit 4 Test – Equilibrium V1x 10K 17T 6C Part A: Multiple Choice (K: 10 Marks) Please place your answers IN ALL CAPS and in pen in the corresponding boxes below. Choose the BEST answer. 1 2 3 4 5 6 7 8 9 10 Part B: Short Answer (T: 17 Marks, C: 6 Marks) Thinking and Inquiry: 1. A mixture of 0.100 M NO and 0.500 M H2, are placed in a container. At equilibrium, there was 0.0238 M of nitrogen in the container. 2NO(g) + 2H2(g) ↔ N2(g) + 2H2O(g) Determine the equilibrium constant for the reaction. (T/I: 4) 2. A 0.100 mol/L solution of methanoic acid (HCHO2) has a pH of 2.38. Calculate the Ka of methanoic acid. (T/I: 4) 1 Date: ______________ Name: ___________________ 3. You place some solid copper(I) bromide CuBr(s) in a beaker of distilled water. You measure the molar solubility to be 2.0 x 10-4 mol/L at 25°C. What is the Ksp? (T/I: 3) 4. Tap water contains the sulfate ion SO42- at about 0.00400 mol/L. If 10 mL of 0.00100 mol/L BaCl2 is added to 90 mL of tap water, will a precipitate form? Ksp of barium sulfate is 1.1 x 10-10. (T/I:6) 2 Date: ______________ Name: ___________________ Communication: 5. For the equilibrium systems: i) 2SO2(g) + O2(g) ↔ 2 SO3(g) + heat (exothermic) ->Temperature decrease ii) CH4(g) + H2O(g) ↔ CO(g) + 3H2(g) -> Pressure increase by volume decrease Predict the direction in which each of the systems would be shifted upon application of the indicated change. Give a brief Le Chatelier explanation for your prediction. (C:2 each) 6. Explain why a saturated solution of AgCl(aq) would produce a precipitate if you added a saturated solution of NaCl(aq). (C:2) 3