Review Questions: Acids, Bases and Salts 1. How does the Arrhenius Theory define an acid and a base? a. Acid- Any substance that releases hydrogen ions (H+1) to solution b. Base- Any substance that releases hydroxide ions (OH-1) to solution 2. How does the Bronsted-Lowry Theory define an acid and a base? a. Acid- A proton donor or any positive ion (since they have more protons than electrons) b. Base- A proton acceptor or any negative ion (since they have more electrons than protons) 3. How does the Lewis Theory define an acid and a base? a. Acid- An electron pair acceptor (substance attracted to a pair of electrons) b. Base- An electron pair donor (substance with a non-metal that has at least one pair of electrons) 3. What is the molecular formula of the hydronium ion? 4. List some of the common physical and chemical characteristics of acids. Sour or tart taste Corrosive to metals releasing hydrogen gas pH of less than 7 Neutralize bases to form a salt and water Have a texture similar to water Changes the color of indicators: Phenolphthalein turns clear Litmus paper turns pink - 53 - 5. List some of the common physical and chemical characteristics of bases. Have a bitter taste pH of greater than 7 Neutralize acids to form a salt and water Have a texture similar to oil (slippery to the touch) Changes the color of indicators: Phenolphthalein turns pink Litmus paper turns blue 6. What is the definition of a binary acid? An acid that contains hydrogen and one other nonmetal element HCl, H2S, H3P, etc. Name using both a prefix of HYDRO - and suffix of –IC ACID 7. What is the definition of a polyatomic acid? An acid that contains hydrogen and more than one nonmetal element H2SO4 , H3PO4 , H2CO3 , etc. Name using ONLY a suffix of –OUS ACID or –IC ACID (no prefix) 8. Name the following acids given their chemical formulas. a. HF Hydrofluoric acid Binary acid: prefix (hydro) and suffix (-ic acid) b. H3PO4 Phosphoric acid Polyatomic acid with an –ate ion; suffix (-ic acid) c. H2SO3 Sulfurous acid Polyatomic acid with an –ite ion; suffix (-ous acid) d. H2CO3 Carbonic acid Polyatomic acid with an –ate ion; suffix (-ic acid) e. HBr Hydrobromic acid Binary acid: prefix (hydro) and suffix (-ic acid) f. HNO3 Nitric acid Polyatomic acid with an –ate ion; suffix (-ic acid) g. HIO2 Iodous acid Polyatomic acid with an –ite ion; suffix (-ous acid) h. HBrO3 Bromic acid i. H2S Hydrosulfuric acid Polyatomic acid with an –ate ion; suffix (-ic acid) Binary acid: prefix (hydro) and suffix (-ic acid) - 54 - 9. Write the correct chemical formula for the following acids. a. Hydrochloric acid HCl (has a hydro prefix and -ic acid suffix) Binary acid b. Acetic acid HC2H3O2 (acid with an –ic suffix) Polyatomic with –ate ion c. Sulfuric acid H2SO4 (acid with an –ic suffix) Polyatomic with –ate ion d. Phosphorous acid H3PO3 (acid with an –ous suffix) Polyatomic with –ite ion e. Hydroiodic acid f. Nitrous acid (has a hydro prefix and –ic acid suffix) HI Binary acid (acid with an –ous suffix) Polyatomic with –ite ion HNO2 (acid with an –ic suffix) Polyatomic with –ate ion g. Iodic acid HIO3 h. Bromous acid HBrO2 (acid with an –ous suffix) Polyatomic with –ite ion i. Oxalic acid (acid with an –ic suffix) Polyatomic with –ate ion H2C2O4 10. Name the following bases given their chemical formulas. a. KOH Potassium Hydroxide b. Mg(OH)2 Magnesium Hydroxide c. Al(OH)3 Aluminum Hydroxide d. Fe(OH)2 Iron (II) Hydroxide (two OH-1 ions needed so Fe has a +2 charge 11. Write the correct chemical formula for the following bases. a. Lithium hydroxide LiOH b. Barium hydroxide Ba(OH)2 c. Copper (I) hydroxide CuOH d. Zinc hydroxide e. Sodium hydroxide Zn(OH)2 NaOH - 55 - 12. What is a conjugate base? What remains or is produced after an acid has released or given away a hydrogen ion. 13. What is a conjugate acid? What is produced after a base has accepted or taken a hydrogen ion. 14. In the following reactions, identify the acid, the base, the conjugate acid, and the conjugate base. a. H3PO4 + OH-1 H2PO4-1 + H2O b. NO2-1 + H3O+1 HNO2 + H2O c. NH4+1 + H3O+1 + H2O NH3 15. What is the conjugate acid of HSO4-1 ? 16. What is an amphiprotic substance? A substance that can act as either an acid or a base. - 56 - 17. What is the definition of a salt? A compound that releases + and – ions into a solution that are NOT H+1 or OH-1 This is a physical process. 18. What is dissociation as it applies to salts? The process by which the + and – ions of a salt separate from each other when dissolved in water 19. What is ionization? The formation of ions when neutral molecules like acids and bases react with water. This is a chemical process 20. Explain the difference between electrolytes and nonelectrolytes. a. Electrolytes- Substances that form ions in solution allowing an electric current to flow through the solution b. Nonelectrolytes- Substances that DO NOT form ions in solution 21. What is the difference between a strong electrolyte and a weak electrolyte? a. Strong electrolyte- Those that ionize almost 100%, releasing lots of ions into solution. b. Weak electrolyte- Those that ionize very little, releasing very few ions into solution 22. Classify the following acids as either strong acids or weak acids by writing the word strong or weak below each molecular formula. HCl H2CO3 H2O H2SO4 H3PO4 Strong Weak Weak Strong Weak - 57 - 23. Classify the following bases as either strong bases or weak bases by writing the word strong or weak below each molecular formula. NaOH Ca(OH)2 Strong Strong CuOH Fe(OH)3 Weak Weak KOH Strong 24. How are most salts produced? By reacting an acid with a base; by a neutralization reaction. 25. Describe the type of salt produced when the following acids and bases react with each other. a. Strong acid with a weak base- Acidic salt b. Strong acid with a strong base- Neutral salt c. Weak acid with a strong base- Basic salt 26. What is the pH scale? A relative scale that represents the level of acidity of a solution by the measurement of the hydrogen ion concentration of a solution. 27. What is the mathematical formula used to calculate the pH of a solution? pH = - log [H+1] 28. Calculate the pH of each of the following solutions given the hydrogen ion concentration. a. [H+1] = 1 x 10-4 4 b. [H+1] = 1 x 10-8 8 c. [H+1] = 1 x 10-6 6 29. Calculate the hydrogen ion concentration of the following solutions given the pH value of the solution. a. pH = 3 1 x 10-3 b. pH = 7 1 x 10-7 c. pH = 9 1 x 10-9 - 58 - 30. What is the pH of a solution with a hydrogen ion concentration of 5 x 10-4? pH = - log [5 x 10-4] = 3.3 31. What is a chemical indicator? A substance that changes color at different pH values. 32. What will be the color of the following indicators in an acidic and basic solution? Indicator Color in an acidic solution Color in a basic solution Phenolphthalein Clear Pink Litmus Pink Blue 33. What is a buffer? A mixture of substances that resists changes in pH when small amounts of acids or bases are added. - 59 - - 60 -