Page:of 8 Automatic Zoom Actual Size Page Fit Page Width 50% 75% 100% 125% 150% 200% 300% 400% 2018 Name: Kendall Hill Date: April 21 , 2020 Student Exploration: Chemical Changes Vocabulary : acid, base, catalyst, chemical change , coefficient, conservation of matter , decomposition, dissolve, double replacement, endothermic , exothermic, indicator, ion, physical change, product, reactant, single replacement, subscript, synthesis Prior Knowledge Q uestion s (Do th ese BEFORE using the Gizmo.) 1. A student mixes baking soda and vinegar in a glass . The results are shown at left . Do you think any new substances are being created in this mixture ? If so, how do you know? When these two substances are combined they form two chemical reactions b ecause one is a base and one is an acid. At the end of the reactions, the bubbles that are shown in the image are made of carbon dioxide gas. 2. Suppose this was done on top of a balance. Do you think the mass would change as the reaction proceeded? I think the mass would remain the same as the reaction proceeds as long as the amounts are the same. 3. What do you think would happen to the mass if the reaction took place inside a sealed plastic bag? The mass would be contained and compressed if the reactio n were to occur inside a sealed plastic bag because it was limited room to react in. Gizmo Warm up A chemical change , (or chemical reaction ) occurs when one or more substances, called reactants , are transformed into different substances, or products . In the Chemical Changes Gizmo, you will look for evidence of chemical changes by looking at changes you can see, touch, or smell. To begin, check that Reactant 1 is Sodium and Reactant 2 is Water . Sodium is a metal so soft you can cut it with a knife. 1. Click Play ( ). What do you observe? 2018 Some type of reaction occurs making a sizzle noise and the water changes pigmentation to a clear/glassy color. (releases/forms a vapor too) 2. Do you think a chemical reaction has taken place? Explain. Sodium metal reacts rapidly with water to form a colorless solution of sodium hydroxide (NaOH) and hydrogen gas (H 2 ). The resulting solution is basic because of the dissolved hydroxide. The reaction is exothermic. Activity A: Observing chemical changes Get the Gizm o ready : Click Reset ( ) . Check that the reactants are still S odium and W ater . Turn on the Label reactants checkbox. Introduction: It is important to distinguish chemical changes , in which new substances are formed , from physical changes , which do not create new substances. In this activity, you will look at many kinds of evidence that chemists use to see if a chemical change has taken place. Question: What kinds of evidence indicate a chemical change has taken place? 1. Observe : Some chemical reaction s release heat, and others absorb heat. In an exothermic reaction, heat is released and the temperature of the system rises. In an endothermic reaction, heat is absorbed and the temperature of the system decreases. In the Gizmo, drag the Thermometer into the flask of water. A. What is the starting temperature? 21 C B. Click Play , and wait for the reaction to end. What is the final temperature? 59C C. Was this reaction exothermic or endothermic ? Exothermic (temp rises) 2. Observe : Two families of chemicals are acids and bases . Acids and bases can be detected by an indicator , which is a substance that changes color in the presence of an acid or a base. Phenol red is an indicator that is yellow in an acid, orange in a neutral soluti on, and pink in a base. A. Click Reset . Drag the Phenol red next to the flask of water. What does the indicator show? “Start pH: Neutral” B. Click Play , and wait for the reaction to end . What does the indicator show now? “End pH: Basic” 3. Observe : Click Reset . Select the Gas collection setup. Chemists use this apparatus to collect any gases produced in the reaction. From the reaction flask, gases travel through a long tube and into a cylinder of water. As gases bubble into the cylinder, the water is displaced (removed) until the cylinder is filled with gas. 2018 Click Play and observe the cylinder. Was any gas produced in the reaction? How do you know? Yes, gas was produced when the reaction occurred because it was visible and audible. (Activity A continued on next page) Activity A (continued from previous page) 4. Analyze : One way to test what kind of gas is in the cylinder is to use a glowing splint .A glowing splint is a wooden stick that has been lit on fire and then blown out, resulting in a glowing, red h ot tip. The table shows how a glowing splint reacts to some common gases: Gas : Carbon dioxide (CO 2 ) or ammonia (NH 3 ) Oxygen (O 2 ) Hydrogen (H 2 ) Splint reaction: Goes out Burns brightly Small explosion and “pop” sound A. Drag the glowing splint next to the cylinder, and observe. What do you see? I see that the glowing splint causes a small explosion. B. Based on the table above, what gas do you think was produced in this reaction? The gas produced was Hydrogen (H 2 ) according to the table. 5. Interpret : Turn on Show chemical equation . A chemical equation is a shorthand way to describe a chemical reaction. Symbols represent the elements: H for hydrogen, O for oxygen, and Na for sodium. The reactants are to the left of the arrow , and the products are to the right. For example, the equation H 2 +O 2 →H 2 O shows that the reactants hydrogen and oxygen combine to form the product H 2 O, or water. A. Look at the reaction shown in the Gizmo. What are the reactants in this reaction? Sodium (Na) and Water (H 2 0) are the reactants . (Na+H 2 O) B. What are the products in this reaction? NaOH+ H 2 These symbols represent sodium hydroxide and hydrogen gas. Sodium hydroxide is a strong base. (C hemicals that contain the hydroxide ion (OH – ) are bases. ) C. How do the products of the reaction relate to the phenol red test and the splint test? The products of the reaction relate to these tests based off the fact there are bases and acids. 2018 Activity B: Conservation of matter Get the Gizmo ready : Click Reset . Select Hydrogen peroxide for Reactant 1 and Potassium iodide for Reactant 2 . Goal: How does the mass change (or not change) during a chemical reaction? 1. Review : In this reaction, hydrogen peroxide is added to a potassium iodide solution. Click Play and observe the reaction. A. What do you observe? As the liquids mix, there is some type of gas released , sizzling/fizzing, and the color of the liquid change s. B. What evidence do you see that a chemical reaction is taking place? There is a change in t he physical appearance and gas is released possibly. C. Replay the reaction and use the available tools ( Thermometer , Phenol red , and Glowing splint .) What do these tools indicate? (Note: You will need to switch to the Gas collection setup to use the splint.) Thermometer: Start: 21C & Current: 83C Phenol red: Start & End pH: Neutral Glowing splint: Glowing splint ignites. 2. Record : Click Reset , and change back to the Normal setup . Notice the mass shown on the electronic balance. A. What is the starting mass for this reaction? 336.6 g B. Click Play . What is the mass when the reaction has finished? 335.2 g C. How does the mass change in this reaction? The mass number decreases in this reaction because the liquid is transformed into a gas a nd releases into the air causing the mass to change. 3. Record : Click Reset , and select the Gas collection setup. Notice that this setup is heavier than the normal setup, but the amounts of reactants is the same. A. What is the starting mass for this reaction? 2386.6 g B. How do you think the mass will change during the reaction? I think the mass might remain the same throughout the reaction. 2018 C. Click Play . What is the mass when the reaction has finished? 2386.6 g (Activity B continued on next page) Activity B (continued from previous page) 4. Explain : Why do you think that mass was lost when the reaction was done in the normal setup, but stayed the same when the reaction was done in the gas collection setup? I thi nk the mass might have stayed the same in the gas collection setup because the reaction was balanced but in the normal setup it wasn’t and the gas had to be released. A fundamental law of chemistry is conservation of ma tter . This law states that, in a chemical reaction, matter can neither be created nor destroyed. That means that, as long as nothing escapes from the system, the total mass measured at the start of the reaction will be the same as the total mass at the end of the reaction. 5. Compare : Tur n on Show chemical equation . The small numbers, called subscripts , show how many of each atom there are in the molecule. For example, the molecule H 2 O contains two hydrogen atoms and one oxygen atom. (Notice that, in this reaction, the potassium iodide (KI ) acts as a catalyst . A catalyst is a substance that helps a reaction happen but does not change during the reaction.) Count the total number of hydrogen and oxygen atoms on the left and right sides of the equation: Left side: H : 2 O : 2 Right side: H : 2 O : 3 What do you notice? That there was an additional oxygen atom produced. 6. Turn on Show balanced equation . A balanced equation shows how many molecules of each substance take part in the reaction. The coefficients are the big numbers that tell you how many molecules there are. For example, “2H 2 O” means there are two water molecules and a total of four hydrogen and two oxygen atoms. Carefully count the total number of hydrogen and oxygen atoms on the left and right sides of the balanced equation: Left side: H : 4 O : 4 Right side: H : 4 O : 4 A. What do you notice? Both sides are balanced out and equivalent in the equation. 2018 B. How does the balanced equation relate to the law of conservation of matter? It relates because nothing is created nor destroyed from this reaction which is demonstrated by the numbers remaining the same before and after the reaction. Activity C: Types of reactions Get the Gizmo ready : Click Reset . Select Normal setup . Select Sodium for Reactant 1 and Chlorine for Reactant 2 . Goal: Explore, observe, and classify a variety of chemical reactions . 1. Observe : In this reaction, a small piece of sodium is added to a flask co ntaining poisonous chlorine gas which has a yellowish color , and sand. Water is added to start the reaction. A. Click Play . What happens ? A flame is ignited and then burn s out. B. Try the experiment with the Thermometer . Is the reaction exothermic or endothermic? Exothermic; heat is released and the temp rises C. Run the experiment one more time, this time watching the mass. What do you notice? The mass increases by the end of the reaction. D. Repeat the experiment, this time in the Closed system . How does the mass change during the reaction now? The mass chang es during the reaction but concludes as the same mass as before. 2. Challenge : Turn on Show chemical equation . In this reaction, solid sodium reacts with chlorine gas to form solid sodium chloride (NaCl), also known as table salt. How does this explain the normal setup increase in mass during the reaction? When the new substance is created it explains the increase in mass because it adds to the original mass. 3. Observe : Select Ammonium nitrate for Reactant 1 and Water for Reactant 2 . Add the Thermometer to the flask and click Play . A. What do you observe ? The temperature decreases by 8. B. Is this process exothermic or endothermic? Endothermic 2018 C. What is the equation for this process ? NH 4 NO 3 +H 2 O NH 4 + + NO 3 – +H 2 O In this example, ammonium nitrate (NH 4 NO 3 ) dissolves in water, producing ammonium (NH 4 + ) and nitrate (NO 3 – ) ions. Chemists do not all agree about whether this is a n example of a physica l change or a chemical change. (Activity C continued on next page) Activity C (continued from previous page) 4. Classify : There are manytypes of chemical reactions. Four are described below: Synthesis : Two or more reactants combine to form a single product. For example, 2H 2 +O 2 → 2H 2 O. (Synthesis reactions are also called combination reactions.) Decomposition : One reactant breaks down to form two or more products. For example, 2KCl → 2K + Cl 2 . Single replacement : An element reacts with a compound to form another element and compound. For example, Zn + 2HC l → ZnCl 2 +H 2 . Double replacement : Two compounds react to form two different compounds. For example, FeS + 2HCl → FeCl 2 +H 2 S. Using the Gizmo, find an example of each type of reaction. Synthesis: Na + Cl 2 NaCl 2 Decomposition: H 2 O 2 H 2 O+O 2 Single replacement: Na + H 2 O NaOH + H 2 Double replacement: AgNO 3 + HCl AgCl + HNO 3 5. Explore : Find an example of each of the following in the Gizmo: A. An example of no chemical reaction occurring: Sodium & Kerosene (N a+C 12 H 26 Na + C 12 H 26 ) B. A reaction that produces an acid: Silver Nitrate & Hydrochloric acid (AgNO 3 + HCl AgCl + HNO 3 ) C. A reaction that produces a base: Calcium chloride & Sodium hydroxide (CaCl 2 + 2NaOH Ca(OH) 2 + 2NaCl) D. A reaction that uses a catalyst: Hydrogen peroxide & Potassium iodide (2H 2 O 2 2H 2 O+O 2; Catalyst: KI) 2018 6. Demonstrate learning : Choose an interesting reaction in the Gizmo. Use the available tools to make observations, and use what you have learned so far to draw conclusions about the reaction. Describe your findings below. (If necessary, continue on a secon d sheet of paper.) Reaction: Reactant 1: Ammonium nitrate & Reactant 2: Potassium hydroxide Findings: Results in Normal setup Data Before Reaction After Reaction Mass 317.2 g 315.1 g Temperature 21C 31C Phenol red pH Basic Neutral Smell Strong ammonia smell Strong ammonia smell In conclusion, it takes multiple elements/substances to form a chemical reaction. The chemicals can react by releasing and producing matter effecting the mass. There can even be heat involved and makes an endothermic or exothermic reaction. You may test your chemicals by monitoring the temperature and pH levels.