Philippine Journal of Science 150 (4): 611-623, August 2021 ISSN 0031 - 7683 Date Received: 18 Jan 2021 Waste Profile and Waste-to-Energy Conversion Potential of Medical, Hazardous Industrial, and Electronic Residual Wastes in Metro Manila, Philippines Ferdinand Manegdeg1,4,5, Analiza Rollon2,4,5, Eduardo Magdaluyo Jr.3, Florencio Ballesteros Jr.2,5, Louernie de Sales-Papa5, Eligia Clemente3,5, Emma Macapinlac2, Roderaid Ibanez1, and Rinlee Butch Cervera3,4,5* 1Department of Mechanical Engineering 2Department of Chemical Engineering 3Department of Mining, Metallurgical, and Materials Engineering 4Energy Engineering Program 5Environmental Engineering Program College of Engineering, University of the Philippines Diliman Quezon City 1101 Philippines Waste disposal is an important issue that needs to be addressed, not only for health and environmental reasons but also for its social and economic impacts. Three important waste streams that contribute to the growing amount of wastes generated come from medical, industrial, and electronic residual wastes. These residual wastes are usually just being dumped or disposed of in sanitary landfills. Apart from finding solutions to these environmental waste problems, these wastes can be a possible source of energy that can support our energy sustainability. In this study, three different waste streams, medical, industrial, and electronic wastes in Metro Manila – the capital region in the Philippines – were profiled and investigated for their potential as waste-to-energy (WTE) feeds. The daily generation, types of wastes, and heating values were studied. The total generated daily waste for medical wastes, hazardous industrial wastes, and residual electronic wastes that have a potential for WTE was about 143,834 kg/d or about 52,500 tons/yr. Its total energy potential was about 4,727 GJ/d. These large amounts of residual WTE feeds can potentially support daily energy needs, as well as mitigate problems associated with the typical disposal of these hazardous and residual wastes. Keywords: electronic waste, industrial waste, medical waste, waste disposal, waste-to-energy INTRODUCTION Environmental problems and socio-economic impacts due to mismanaged wastes are some of the big issues and concerns, especially in developing countries. As a consequence, littered and illegally dumped solid wastes *Corresponding Author: rmcervera@up.edu.ph become increasingly visible in streets, private and public lands, rivers, lakes, beaches, coastal areas, and even offshores. Mismanaged solid wastes may have been causing declining health, contamination of soil and water due to degradation of illegally dumped solid waste, and declining tourism due to visible littered wastes (Rushton 2003). One of the reasons for mismanaged solid wastes 611 Philippine Journal of Science Vol. 150 No. 4, August 2021 is the lack of solid waste disposal facilities. Apart from environmental concerns, in the Philippines – for example – the increasing demand for energy and energy security is also one of the important issues that the Philippine government needs to address. Hence, there is a crucial need to manage and build facilities that can reduce wastes volume and at the same time taking advantage to utilizing the energy from waste to generate electricity that can support the energy supply. WTE is considered as one of the sustainable means of waste management and promising technologies for future renewable energy sources (Kothari et al. 2010; Kumar and Samadder 2017; Eddine and Sallah 2012). Common WTE technologies such as incineration, pyrolysis, and gasification typically utilize municipal solid wastes as raw material feed (Kumar and Samadder 2017; Tan et al. 2015; Agaton et al. 2020). Moreover, wastes feed such as agricultural or biomass wastes are also considered as potential renewable energy feed sources (Kothari et al. 2010). However, in order to realize and sustain further this WTE as a future renewable energy source, other potential wastes are needed. Apart from municipal solid wastes, other major wastes that have potential as WTE feed sources are those coming from medical facilities, hazardous wastes from industries, and different residual electronic wastes. Most of the residual wastes from these waste streams, after segregation and treatment, usually just end up in storage facilities – or worst – in landfills. For medical wastes, for example, the global wastes generated surge and increase manifolds during the COVID-19 pandemic, which adds up to our waste problems (Sarkodie and Owusu 2020; Klemes et al. 2020). Hazardous industrial wastes, on the other hand, such as paints and used oils and grease after treatment just end up also in storage facilities or in landfills. Moreover, for electronic wastes – after segregating and recovering the recyclable materials – the residual electronic wastes also are just being disposed of in landfills. These three different wastes streams – instead of adding to environmental waste problems – may have potential benefits as a WTE feed, which can help not only in managing these wastes but also to provide alternative source and energy supply support. There are various reports on the waste management, treatment, or disposal technologies for medical wastes (Zhao et al. 2009; Cai and Du 2020; Caniato et al. 2016; Khan et al. 2019; Hong et al. 2018; Jang et al. 2006; Nema and Ganeshprasad 2002); however, only very limited reports were published on the potential of medical waste for WTE so far (Bujak 2009; Singh and Khosla 2017; Manegdeg et al. 2020). Bujak (2009) reported the energy efficiency of an incinerator for medical waste; however, no detailed profiling and elementary composition of medical wastes were provided, and the study was focus mainly on the experimental analysis of useful energy flux 612 Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines and coefficient of energy efficiency of an incinerator for medical waste combustion from a certain hospital facility. Similarly, Singh and Khosla (2017) reported and focus their study on the comparative performance of materials of medical waste incinerators. The profile of medical waste and compositional study were also not reported. Manegdeg et al. (2020) reported medical waste characterization and electricity generation using pyrolyzer-rankine cycle; however, the scope of the study was only limited to specialty hospitals in one particular city. On the other hand, there are also very limited reports for the WTE potential of hazardous industrial wastes (Eddine and Sallah 2012; Lupa et al. 2011). Eddine and Sallah (2012) reported the use of commercial and industrial waste in energy recovery systems in the UK; however, no waste profiling was done and only reported the energy generation potential taken from waste samples at waste management sites. And for residual electronic wastes as potential feed for WTE, there are none published yet up to date to the best of our knowledge. In this study, waste profiling and characterization of medical, hazardous industrial, and electronic wastes were conducted in Metropolitan Manila, Philippines. The waste generation and profile for each of these waste streams were investigated and its potential as feed for WTE. MATERIALS AND METHODS Medical Wastes Analysis and Characterization In this study, guided by the categories from the Department of Health (DOH) Memorandum No. 2012-0012 and the 2019 National Health Facility Registry listing in the Philippines, the total number per medical facility category was first obtained. There are five major medical facility categories – namely, general hospitals, specialty hospitals, stand-alone facilities, rural health centers, and barangay health centers. Within the database of the category, the selection of the sampling sites had been randomized, with certain consideration that the samples had been dispersed throughout the metropolis. This was to ensure that representation of a wide distribution of populations and various districts will be presented in the study. In this report, only general hospitals and those specialty hospitals were considered. Rural health centers and barangay health centers were also investigated; however, initial studies from these facilities showed varying and very minimal daily wastes. Stand-alone facilities such as dialysis centers and dental clinics were also excluded. For the sampling sites, different hospitals were first classified in accordance to DOH Memorandum No. 2012-0012, which classifies medical facilities under various categories – each based on their general function, bed capacity, service Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines Philippine Journal of Science Vol. 150 No. 4, August 2021 capabilities, and training hospitals. According to functional capacity, general hospitals may be classified based on their bed capacities, which are ranked from Level 1 to Level 4 hospitals. These levels account for their capacity to treat patients based on their needs – from simple to complex treatments. Specialty hospitals are sub-categories also considered in the functional capacity category. Waste profiling from the randomized different hospital sites was conducted during the pre-COVID-19 pandemic between November 2019 up to February 2020. Three hospitals for Levels 1 and 2, three hospitals for Levels 3 and 4, and four specialty hospitals were considered as the sampling sites wherein the last three specialty hospitals were taken with reference to our previous study (Manegdeg et al. 2020). These hospitals account for about 6% of the total general and specialty hospitals in Metropolitan Manila. The data collection involved sending a request to a particular hospital and meeting with a pollution control officer to discuss pertinent data and outcomes for the data collection in their facility. Appropriate health protocols were observed during the collection of waste materials by wearing proper personal protective equipment. Daily gathering of data on the general and infectious wastes was done and lasted for eight days. On both waste types, all bags of the same waste type generated within the day were weighed to obtain the total weight. Total generated waste per day in a facility was obtained from the hospital waste data weighed every day after collection, and then the daily average was taken for the eight-day generation. To identify the individual weights per waste material, three bags of the total bag number per day of the general waste types from all the hospitals were segregated and weighed according to the waste material. This method was applied due to the constraints and protocol of the hospitals involved. On the other hand, for infectious waste – due to health hazards – only the estimation was done on the types and quantity via visual inspection of the waste bag. The weight of the waste bag was determined using a weighing balance. Further verification on the reliability of this approach was done through laboratory weighing of clean samples and multiplied by the respective number of the samples during the inspection, including some correction factor to account for other matters such as dirt, moisture, and among others that added up to the actual weight. Heating values of general medical waste were compared from literature values (Sharuddin 2016; Erdincler and Visilind 1993) and those medical wastes that were infectious were obtained using a bomb calorimeter by using a representative clean waste material sample since literature values are not available. Industrial Wastes Analysis and Characterization For hazardous wastes, only the collection of secondary data was conducted due to legal and safety restrictions in handling these kinds of wastes. The hazardous waste types were based on Chapter 2 (Classification of Hazardous Waste) of the Department of Environment and Natural Resources (DENR) Administrative Order (DAO) No. 2010-22. This list classifies hazardous wastes into 56 types based on a combination of industry source, main constituents, and the kind of medium the waste is contained in. The final list of waste types, as shown in Table 1, was selected using the inclusion and exclusion Table 1. Hazardous waste types for WTE (DENR–EMB DAO 2013-22). Class Description Waste number F. Inks/ Dyes/ Pigments/ Paint/ Resins/ Latex/ Adhesives/ Organic sludge Solvent-based Includes all solvent-based wastes that also meet one or more of the subcategories F601 Inorganic pigments Includes all wastewater treatment sludge from the production of inorganic pigments F602 Includes all grease wastes generated from establishments such as industrial, commercial, and institutional facilities H802 Used industrial oil, including sludge I101 Vegetable oil, including sludge I102 Tallow I103 Oil-contaminated materials I104 Expired pharmaceuticals and drugs stocked at producers’ and retailers’ facilities that contain hazardous constituents harmful to the environment such as antibiotics, veterinary and phytopharmaceuticals, among others M503 H. Organic wastes Grease wastes I. Oil Used or waste oil M. Miscellaneous wastes Pharmaceuticals and drugs 613 Philippine Journal of Science Vol. 150 No. 4, August 2021 criteria. Inclusion criteria for hazardous waste types are those hazardous wastes that have prior literature to support their use in waste to energy technologies while those excluded are hazardous waste types such as medical and hospital wastes, electronic wastes, hazardous wastes that do not have clearly defined constituents, hazardous wastes that have known chlorinated components, and hazardous wastes that have constituents belonging to the DENR Priority Chemicals List. Based in DAO 2013-22, also known as the Revised Procedures and Standards for the Management of Hazardous Waste (Revising DAO 2004-36) – which provided a procedural manual for the technical requirements and standards for generators of, transporters of, and TSD (treatment, storage, and disposal) facilities for hazardous waste under Section 2 on the classification of all hazardous wastes – the following types viable for waste to energy conversion were considered. Due to the dangers that hazardous wastes pose to human health, actual waste accounting in industrial settings was not done. Instead, self-monitoring report (SMR) data – which contain the quarterly generation of hazardous waste in Metro Manila from the 1st quarter of 2017 to the 4th quarter of 2019 – were obtained from the Environmental Management Bureau (EMB). The average yearly generation was used in subsequent analyses. Hazardous waste types that have not been used in WTE applications based on prior literature were not included. The calorific value of the selected waste types was taken from known literature values for a specific industrial waste material (Muniz 2003; Trabelsi 2018; El-Mekkawi 2020; Balcik-Canbolat 2017; Barişçi and Salim Öncel 2014; Filippis 2012). Electronic Wastes Analysis and Characterization For electronic wastes (e-wastes), there are basically two facilities that handled these wastes: 1) TSD facilities and 2) junk shops. According to Metro Manila Solid Waste Management Report, a lot of junk shops are not registered with the local government unit (LGU) (Varey et al. 2003). Given this amount of undocumented junk shops, the profiled junk shops in the metropolis were only limited to those which are registered with their respective LGUs. On the other hand, for TSD facilities, the DENR lists a total of 24 TSD facilities in Metro Manila as of January 2020. Of these 24, only two are facilities that handle both classifications of hazardous wastes that are from electronics wastes. To sample the junk shops in Metropolitan Manila, the metropolis was first divided into quadrants – namely, north, east, west, and south quadrants – which was based on the Oplan Metro Yakal Plus of the Metro Manila Disaster Risk Reduction and Management Council (Varey et al. 2003). In this study, a combination of sampling techniques 614 Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines was used in the selection of junk shops. Proportionate stratified sampling was initially done with a sampling percentage of about 3%. Then, to finally determine the respondents, convenience sampling was employed on the junk shops within the quadrants or the strata. Proportionate stratified sampling was chosen to proportionate the size of the number of junk shops in the quadrants when viewed against the total number of junk shops. It also provides better precision than a simple random sample of the same size. Convenience sampling was then chosen due to the concealing of information by some LGUs on the junk shops in their cities or municipalities, thus restricting the use of proportionate stratified random sampling. The data gathering of this research started with the application of the sampling procedures to the profiled e-waste handling facilities to determine which of the facilities will be considered sampling sites. The chosen facilities were then contacted or visited on-site to request the facility to take part in the study. The communication between the researchers and the sampling sites included the rationale (purpose, objectives, significance of the study, scope, and limitations) and the general methodology of the research. Once the facility agreed on taking part in the study, the people who are in charge or are knowledgeable with the facilities’ electronic waste management were first interviewed about the specifics of the facilities’ e-waste flow. The involved personnel was asked about the processes involved in the facilities’ daily operations, from the reception of the electronics up to its waste disposal, which involved the residual wastes. The facilities then accomplished the eight-day residual waste data collection forms. Data gathering was facilitated by using two data collection forms that allowed the researchers to evaluate the performance of the facilities in gathering e-waste materials from sources through their waste collection schemes prior to and during the eight-day data gathering period. The first form allows the researchers to obtain information pertaining to the operation of the sample facilities. This includes the usual waste stream flow of e-waste materials, as well as cash flow from buying and selling of dismantled products. The second form focuses on obtaining relevant information related to the inflow and outflow of pertinent materials or appliances, as well as the outflow of residual waste materials being collected by waste collectors for dumping to landfills. Similar to medical waste, the daily generated waste was averaged from the eight-day data collection. The characterization of the electronic residual wastes started with the segregation by material or component type and the identification of the specific e-waste it was originally from. The residual samples were also weighed to determine their weight relative to that of their e-waste source. The material type of the residuals was then identified, and heating values were taken using a bomb calorimeter. Philippine Journal of Science Vol. 150 No. 4, August 2021 RESULTS AND DISCUSSION Medical Waste Generation and Waste Profile Medical waste is defined as any waste material in solid or liquid form generated or produced by diagnosis, treatment, or immunization of human beings or animals, medical research, pathological testing, and waste from minor or scattered sources (DOH 2012). The waste management manuals given by the DOH discussed types of healthcare wastes (HCWs) produced by the medical facilities and guidelines to proceed with its handling, treatment, and storage. There are several categories or types of HCWs such as: 1) non-hazardous or general, 2) infectious, 3) sharps, 4) pathological and anatomical, 5) pharmaceutical, 6) chemical, and 7) radioactive wastes. Among these types of medical wastes, the focus was on the medical waste generation for general and infectious wastes. General wastes are comparable to domestic wastes. This type of waste does not pose a special handling problem or hazard to human health or to the environment. General wastes can include both recyclable and non-recyclable materials. Such materials for recyclables involve paper and plastic products while non-recyclable wastes include wastes such as polystyrene (PS) based materials. Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines Materials are considered infectious wastes if they have pathogens and have enough to cause diseases. These may include but are not limited to the following: clinical laboratory instruments and materials containing bodily fluids or those in contact during clinical procedures such as catheters and tubing. Figure 1a shows an example of the HCW handling for infectious waste and non-biodegradable general waste, as stated in the DOH Healthcare Waste Management Manual (DOH 2012). For infectious medical wastes, the flowchart shows that treatment of these waste can either be done on-site or off-site; however, these wastes still ends up and disposed of after treatment. On the other hand, for non-biodegradable and non-recyclable general waste, these wastes are directly collected, transported, and disposed of in landfills. The waste profiles of general and infectious wastes before the COVID-19 pandemic are shown in Figures 1b and c. Figure 1b shows that there were ten general waste material types found on medical facilities – namely, the low-density polyethylene (LDPE) plastics, textiles, plastic cups, cans, PS, glass, polyethylene terephthalate (PET) plastics, high-density polyethylene (HDPE) plastics, papers, and rubber. Based on the chart, Figure 1. Medical waste stream and waste profile: a) flowchart of infectious and general (non-biodegradable and non-recyclable) wastes; b) daily general waste; c) daily infectious waste. 615 Philippine Journal of Science Vol. 150 No. 4, August 2021 the top four types of general waste generated from medical facilities are the PETs (34.9%), papers (22.5%), cans (12.2%), and LDPE plastics (10.4%). Other waste materials gathered from these facilities were commonly used materials such as rubber, glass, PS, and textiles. On the other hand, for infectious medical wastes, only an estimation of infectious waste material composition was done in the study as infectious waste materials are dangerous even when exercising caution. For this study, estimation was done by peeking through the waste container. Figure 1c shows the waste composition generated for infectious wastes. From these estimations, diaper, gloves, and masks comprised the highest contribution in the amount of infectious wastes generated. For the WTE feed, only combustible waste materials were included in the calculation for the total generated daily waste for energy potential, thus excluding non-combustible wastes such as glasses and cans. The total generated daily combustible medical wastes in Metropolitan Manila were about 41,174 kg/d and about 33,732 kg/d for general and infectious medical wastes, respectively, with a total of about 74,906 kg/d. This total medical wastes generated per day was obtained based on the average gathered data from the hospitals. In general, the total medical waste characterization was based on all waste sources gathered from the hospitals to get the total composition of the waste stream. Although hospitals differ in function and capacity, the majority of the Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines general wastes or material types generated were similar, but the amount of the wastes generated varied depending on how large the hospital was. Moreover, the production of infectious wastes can vary between general and specialty hospitals due to function. Hazardous Industrial Waste Generation and Waste Profile Metropolitan Manila has the highest number of manufacturing industries in the Philippines. At 19,291 facilities, the capital region hosts 17% of the country’s total number of factories and manufacturing plants (PSA 2018). The government categorizes establishments based on the number of employees. There are currently four categories – namely, micro, small, medium, and large enterprises – which correspond to establishments having 1–9, 10–99, 100–199, and more than 200 employees, respectively. These industries are the main source of hazardous industrial wastes. Figure 2 shows the flowchart of the collection, transport, treatment, and disposal of hazardous wastes based on the TSD facility category. Category A covers facilities that perform onsite treatment and disposal of hazardous wastes. These facilities also employ treatment methods from Categories B–E and G. Category B covers facilities that utilize thermal methods transforming the physical and chemical characteristics of the hazardous wastes prior to disposal. Category C covers facilities that collect hazardous waste for final disposal to sanitary landfill Figure 2. Collection, transport, treatment, and disposal of hazardous wastes based on the TSD facility category. 616 Philippine Journal of Science Vol. 150 No. 4, August 2021 or surface impoundments. Category D covers facilities that employ the recycling and reprocessing of hazardous wastes. It includes recovery of materials such as used oil, solvents, metals, etc. It also reprocesses materials for fuel to energy. Category E covers facilities that conduct chemical treatment methods such as encapsulation and immobilization transforming the physical and chemical characteristics of hazardous wastes prior to disposal. Category F covers facilities that store hazardous wastes prior to thermal or chemical treatment, disposal, or export. Category G covers facilities that conduct the draining of PCB oil and dismantling of PCB-containing equipment prior to treatment and disposal (DAO 2013-22). For the hazardous industrial wastes, eight types were considered from the 56 hazardous waste types excluding the medical and electronic wastes and based on the following screening criteria: hazardous wastes that do not have clearly defined constituents, those that have known chlorinated components, and those that have constituents belonging to the DENR Priority Chemicals List. The hazardous industrial wastes profile is shown in Figure 3. The data from this figure were gathered and analyzed based on the SMRs submitted to DENR by Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines the industrial plants and from the Philippine Statistics Authority (PSA). The bulk of the average daily generated waste from the studied industrial wastes was attributed to I101 (61.6%), which are wastes coming from petroleum refining operations and manufacturing plant wastes such as used industrial diesel and lubricants. The total industrial hazardous wastes generated from these types of wastes were about 59,300 kg/d. Electronic Wastes Generation and Waste Profile E-wastes or waste electrical and electronic equipment is defined as any end-of-life equipment that is dependent on electrical currents or electromagnetic fields in order to work properly (Grant et al. 2013). There are basically three domestic sources of e-wastes: households, institutions, and industries (Yoshida et al. 2016) that are handled by the two major sectors of e-waste handling facilities: the TSD facilities and junk shops. The general e-waste management and disposal flow is shown in Figure 4. TSD facilities typically cater to private individuals, businesses, and companies. They usually handle industrial e-waste as well as e-waste coming from institutions. These Figure 3. Hazardous industrial wastes profile. The total generated hazardous industrial waste that has potential as energy feed is about 59,342 kg/d. 617 Philippine Journal of Science Vol. 150 No. 4, August 2021 Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines Figure 4. General E-waste disposal management. entities contract TSD facilities to collect, treat, and dispose of their waste safely. Since they do not entertain walk-in waste collection and trading like other facilities such as junk shops, e-waste inflow is not regular but rather on a job-order basis. After dismantling electronic equipment, salvaged metal and plastic components are shipped off to private melting companies. TSD facilities dispose of their residual waste in the general waste collection care of the local government. Junk shops, on the other hand, mainly handle household e-wastes coming from local residential areas. Junk shops with higher buying capital may participate in auctions done by companies, which puts them in competition with TSDs. E-waste may be sourced by members of the community, also known as dismantlers, that collect waste door-to-door. However, due to the relatively small volume of e-wastes brought by dismantlers daily, the junk shops accumulate scraps and e-wastes prior to selling to the consolidators. Metal and plastic components, on the other hand, are taken by private melting companies; electronic parts are auctioned off to private buyers while residual waste is transported to landfills. This, of course, may not always be the case since some e-waste still directly makes it to landfills, which calls for more stringent policymaking. Illustrated in Figure 4 is the general waste flow for both facilities. The figure indicates the sources of e-waste (blue), the handling facilities (red), actions done (yellow), and products. From the flowchart, TSD facilities and junk shops are the facilities that process e-waste. Essentially, TSDs are the facilities where hazardous wastes are transported, 618 stored, treated, recycled, reprocessed, or disposed of (DAO 92-29), while junk shops are defined as the buyers of the scraps coming from dismantlers (Yoshida et al. 2016). Electronics in e-waste handling facilities are dismantled and different components are sorted. In this study, e-waste components are classified as either recyclable or residual. Recyclable components are those plastic and metal components that are sold to recycling and smelting companies. These also include electronic components that are typically repaired and reused by private buyers. Anything that could not be repurposed or recycled is considered a residual component of e-waste. For the purpose of waste to energy conversion, only the residual components of e-waste are considered. TSDs and junk shops reported an average amount of 103.06 kg of e-waste per day per facility, which composed of recyclable and residual components weighing 81.62 kg and 21.60 kg, respectively, as shown in Figure 5a. Daily e-waste collection was estimated at 120,168 kg – made of 95,052.86 kg of recyclable components and 25,115.10 kg of residual components. This amounts to at least a total of about 43,880 metric tons of e-wastes – made of 34,709 metric tons of recyclable components and 9,171 metric tons of residual components – each year in Metro Manila alone. Since TSDs mainly handle e-waste from institutions and industries while junk shops handle those coming from households, it is expected that the type of e-waste they collect would differ. However, due to recent developments where a private recycling group having similar practices to junk shops has just been established as a TSD facility Philippine Journal of Science Vol. 150 No. 4, August 2021 in Metro Manila, the waste types are not so different. Illustrated in Figure 5c are the different types of e-waste in kg in a typical e-waste handling facility in a day. It can be seen that refrigerators, air conditioning units, and old box-type television sets make up the most of e-waste collected based on weight with each being collected at about 21.95, 13.51, and 13.47 kg/d, respectively. Each e-waste type was dismantled and the residual components were determined. From the dismantled e-waste, as shown in Figure 5a, 79.1% are recyclable while 20.9% are those residual e-wastes that will be disposed of and end up in landfills. On the other hand, the residual components of the different e-waste types can be classified according to material type, which was found to be materials made up mostly of polyurethane, ABS, PVC, and non-combustibles. From the 21.6 kg of residual e-waste collected every day in each facility, 58.2% are not combustible as these are main components made from glass. The remaining 9.0 kg that is combustible may be valuable for energy conversion Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines purposes. Taking out the non-combustible components, the composition of a possible feedstock coming from a daily influx of e-waste for a single waste to energy conversion facility is composed of 79.5% of polyurethane, 11.5% ABS, and 9.0% of PVC, as seen in Figure 5b. Heat Maps and Energy Potential of Medical, Industrial, and Electronic Wastes Figure 6 shows the daily waste generation heat maps in Metro Manila for medical, hazardous industrial waste, and residual e-wastes. Quezon City, which is the largest city in Metropolitan Manila, showed the highest amount of daily generated wastes among the other cities. Based on these heat maps, a possible potential WTE facility can be built. Table 2 revealed the daily generated wastes for the three waste streams, potential combustible waste compositions, and their energy potential. The total energy potential for each waste stream was calculated by multiplying the Figure 5. E-waste profiles: a) average weight (kg) of residual and recyclable components of each e-waste handling facility per day; b) composition of the daily average residual wastes; c) average total weight (kg) of different types of e-waste per day per facility. 619 Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines Philippine Journal of Science Vol. 150 No. 4, August 2021 Figure 6. Heat maps of daily generated wastes in Metropolitan Manila, which have the potential for WTE: a) medical, b) hazardous industrial, and c) residual e-wastes. Table 2. Daily generated wastes profile and energy potential of medical, hazardous industrial, and residual electronic wastes. Waste stream Total waste generated in Metro Manila (kg/d) Component composition/ material type (weight %) Average calorific value, HHV (MJ/kg) Total energy potential, GJ/d (Metro Manila) General medical waste 41,174 LDPE (12.2%); PP (11.6%); PS (9.2%); PET (40.3%); HDPE (0.1%); paper (26.6%) 29.3 1,208 Infectious medical waste 33,732 Diaper (46.4%); syringe (1.9%); storage aids (7.1%); mask (10.9%); gloves (18.3%); dressing (15.4%); 23.6 788 Residual electronic waste 9,585 Polyurethane (87.4%); UBS (12.6%) 25.5 244 Hazardous industrial waste 59,342 F601 (3.6%); F602 (4.2%); H802 (11.5%); I101 (61.6%); I102 (5.9%); I103 (0.01%); I104 (3.8%); M503 (9.2%); 41.9 2,487 Total 143,834 – – 4,727 average calorific value with the total waste generated. The generated daily wastes in Metropolitan Manila for medical, industrial, and residual electronic wastes that have a potential for WTE were about 143,834 kg/d (143 tons), which has an energy potential of about 4,727 GJ/d. This is approximately comparable to about 127 m3 of fuel 620 gasoline or 160,000 kg of charcoal for such daily energy potential (i.e. gasoline with 46.4 MJ/kg HHV, charcoal with about 29.6 MJ/kg HHV). From this energy-fromwaste potential, an estimation of its electricity generation potential by conventional pyrolysis is about 45 MW/d. With this electricity generation potential, if modular WTE Philippine Journal of Science Vol. 150 No. 4, August 2021 Manegdeg et al.: Profile and Energy Conversion Potential of Wastes in Metro Manila, Philippines can be built, this can already help and support some of the electricity needs in the metropolis. The appropriate and viable type of WTE technologies that can utilize these waste feeds – considering as well potential hazards and mitigation measures, and the details of the electricity generation potential (e.g. pyrolysis) – will be reported elsewhere. In addition, financial and economic feasibility and socio-economic impacts for a WTE technology will be reported and discussed in a different paper. Thus, with the efforts and push for non-coal energy generation, such potential energy-from-waste can be viable support to existing renewable energy sources in addition to helping solve the lack of disposal facilities – as well as problems associated with the generated wastes coming from medical, hazardous industrial, and residual electronic wastes. Since waste streams from medical wastes, hazardous industrial wastes, and residual electronic waste – will be almost similar to other cities. Except for the generated amount of these wastes depending on the number of facilities or industries in a particular city, the waste profiling and the feasibility of utilizing these wastes into useful energy can be a source of reference information and other cities may consider the WTE technology as a means for waste disposal and energy source. in sanitary landfills, can already add to about 52,500 tons annually. The total daily energy potential of the three waste streams was about 4,727 GJ/d. Future study may include the formulation of enabling policies and the environment in order to realize WTE as alternative waste disposal and potential of medical, hazardous industrial, and residual electronic wastes for WTE. In this study, the following are recommended for waste profiling and future studies of the three investigated waste streams: 1) inclusion of smaller health facilities, such as barangay and rural health centers, and other standalone facilities such as dental clinics can be investigated since the scope in this study was limited to the hospital facilities as they produce the most significant amount of wastes; 2) for e-waste, due to informal economy nature of junkshop facilities, only registered junkshops were considered as unregistered junkshops may increase the daily residual e-waste generated and subject for further investigation; and 3) direct investigation can be pursued for waste generation by industrial facilities that produce hazardous wastes. The analysis may be able to further characterize their residual output to accurately check what waste materials are being produced in certain industries and their potential for WTE. AGATON CB, GUNO CS, VILLANUEVA RO, VILLANUEVA RO. 2020. Economic analysis of waste-to-energy investment in the Philippines: a real options approach. Applied Energy 275: 115265. CONCLUSION The waste profiles and WTE potentials of medical, hazardous industrial, and residual electronic wastes in Metro Manila, Philippines were investigated. The generated daily residual wastes for medical wastes composed of general and infectious wastes were about 74,906 kg, hazardous industrial wastes were about 59,342 kg, and residual electronic wastes were about 9,585 kg. These residual wastes, if just being dumped or disposed of ACKNOWLEDGMENTS This project is financially supported by the Philippine Senate Committee on Energy and the Energy Research Fund of the Office of the Vice-President for Academic Affairs, University of the Philippines Diliman. 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