Saygo, Joshua Gabriel C. 2CHE-B SAQ 1-1 Show the derivation of the following units, in terms of the seven base SI units: (a) Newtons (N) 𝐹 = 𝑚𝑔 𝐹 =𝑚𝑥 𝑣 𝑡 𝑚 𝐹 = 𝑘𝑔 𝑥 𝑠 ; 𝑭 = 𝒌𝒈 ∗ 𝒎/𝒔𝟐 𝑠 (b) Joules (J) 𝐽𝑜𝑢𝑙𝑒 𝑖𝑠 𝑎 𝑢𝑛𝑖𝑡 𝑜𝑓 𝑤𝑜𝑟𝑘; 𝑤𝑜𝑟𝑘 = 𝑓𝑜𝑟𝑐𝑒 𝑥 𝑑𝑖𝑠𝑝𝑙𝑎𝑐𝑒𝑚𝑒𝑛𝑡 𝑤𝑜𝑟𝑘 = 𝑚𝑔 𝑥 𝑑𝑖𝑠𝑝𝑙𝑎𝑐𝑒𝑚𝑒𝑛𝑡 𝑚 𝑤𝑜𝑟𝑘 = 𝑘𝑔 𝑥 𝑠 𝑥 𝑚 𝑠 𝑱 = 𝒌𝒈 ∗ 𝒎𝟐 /𝒔𝟐 (c) Watts (W) 𝑊𝑎𝑡𝑡 𝑖𝑠 𝑎 𝑢𝑛𝑖𝑡 𝑜𝑓 𝑝𝑜𝑤𝑒𝑟; 𝑝𝑜𝑤𝑒𝑟 = 𝑘𝑔 ∗ 𝑝𝑜𝑤𝑒𝑟 = 𝑤𝑜𝑟𝑘 𝑡𝑖𝑚𝑒 𝑚2 𝑠2 𝑠 𝑾 = 𝒌𝒈 ∗ 𝒎𝟐 /𝒔𝟑 (d) Pascals (Pa) 𝑃𝑎𝑠𝑐𝑎𝑙 𝑖𝑠 𝑎 𝑢𝑛𝑖𝑡 𝑜𝑓 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒; 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑘𝑔 ∗ 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑷𝒂 = 𝑚 𝑠2 𝑚2 𝒌𝒈 𝒎 ∗ 𝒔𝟐 𝑓𝑜𝑟𝑐𝑒 𝑎𝑟𝑒𝑎 Saygo, Joshua Gabriel C. 2CHE-B (e) Volts (V) 𝑚2 (𝑘𝑔 ∗ 3 ) 𝑤𝑜𝑟𝑘 𝑠 𝑉𝑜𝑙𝑡𝑎𝑔𝑒 = ; 𝑉𝑜𝑙𝑡𝑎𝑔𝑒 = 𝑎𝑚𝑝𝑒𝑟𝑒 𝐴 𝑽= 𝒌𝒈 ∗ 𝒎𝟐 𝒔𝟑 ∗ 𝑨 SAQ 1-2 Show the equivalence of the units on either side of the following equations: (a) 𝑃𝑉 = 𝑛𝑅𝑇 (pressure × volume = number of moles × ideal gas constant × temperature) (𝑎𝑡𝑚)(𝐿) = ( 𝑚𝑜𝑙) (0.082 𝐿 ∗ 𝑎𝑡𝑚 ) (𝐾) 𝐾 ∗ 𝑚𝑜𝑙 (b) 𝛥𝐺 = 𝛥𝐻 − 𝑇𝛥𝑆 (change in molar Gibbs energy = change in molar enthalpy – temperature × change in molar entropy) ( 𝑘𝐽 𝑘𝐽 𝑘𝐽 )=( ) − (𝐾) ( ) (𝐾)(𝑚𝑜𝑙) 𝑚𝑜𝑙 𝑚𝑜𝑙 (c) 𝛥𝑝 = ℎ𝜌𝑔 (pressure difference = height × fluid density × acceleration due to gravity) (𝑃𝑎) = (𝑚) ( 𝑘𝑔 𝑚 )( ) 𝑚3 𝑠 2 SAQ 1-3 Use the equivalence of units on either side of an equation to determine the missing symbol in the following equation for the measurement of the surface tension of a fluid via the capillary rise method: 𝛾 = 𝑟𝑔 ? ℎ 2𝑐𝑜𝑠𝜃 (where = surface tension of the fluid, r = radius of the capillary, g = acceleration due to gravity, ? = to be determined, h = height of the liquid rise, = contact angle) 𝑁 𝐹 (𝑚) 𝛾 = 𝑠𝑢𝑟𝑓𝑎𝑐𝑒 𝑡𝑒𝑛𝑠𝑖𝑜𝑛 = 𝐿 (𝑚) Saygo, Joshua Gabriel C. 2CHE-B 𝑚 𝑠 2 = 𝑟𝑔(𝑋)ℎ 𝑚 2 cos 𝜃 𝑚 𝑚 𝑘𝑔 ∗ 2 (𝑚) ( 2 ) (𝑋)(𝑚) 𝑠 = 𝑠 𝑚 2 cos 𝜃 𝑚 𝑘𝑔 ∗ 2 𝑠 = (( 𝑚 )(𝑋))/(𝑚) 𝑚 𝑠2 𝑘𝑔 ∗ 𝑿 = 𝒌𝒈 SAQ 1-4 Calculate the height of a column of water equivalent to 1.00 bar 1.00 𝑏𝑎𝑟 = 1 𝑥 105 𝑃𝑎 = 1 𝑥 105 𝑁/𝑚2 𝑃 = 𝜌𝑔ℎ 1 𝑥 10 5 𝑚 𝑠 2 = 997 𝑘𝑔 𝑥 9.81 𝑚 𝑥 (ℎ) 𝑚2 𝑚3 𝑠2 𝑘𝑔 ∗ ( 1 𝑥 105 𝑘𝑔 ∗ ℎ= (997 𝑚2 𝑚 𝑠2 ) 𝑘𝑔 𝑚 ) (9.81 2 ) 𝑚3 𝑠 𝑚 1 1 𝑚3 1 𝑠2 ℎ = (1 𝑥 10 𝑘𝑔 ∗ 2 ) ( 2 ) ( )( ) 𝑠 𝑚 997 𝑘𝑔 9.81 𝑚 5 𝒉 = 𝟏𝟎. 𝟐𝟐𝟒 𝒎