Subject: STEM Grade: 10 Ionic and covalent Compounds Book reference: Stoichiometry Name: ---------------------------------------------- Date: / / Part A: Molecular Mass Calculation 1. Calculate the molecular mass of Acetic Acid, HC2H3O2. 2. Calculate the formula unit mass of Ammonium Chromate, (NH4)2CrO4. 3. Calculate the molecular mass of glucose, C6H12O6. 2019/2020 Page 1 Part B: Mole calculation Calculate the mass in grams of 1.16 x 1022 molecules of nitrogen gas, N2 Calculate the number of entities in 0.641 g of oxygen gas, O2 Part C: Percent Composition Calculate the percent composition of each element in the following compound: Acetic Acid HC2H3O2 Page 2 Part D: Empirical Formula Calculation Given the following percent compositions, determine the empirical formula of the following compound: 54.5% carbon, 9.15% hydrogen, and 36.3% oxygen Page 3 Part F: Balancing Chemical Equations Balance the following chemical equations (write the chemical formulas in #10 then balance): 1. Fe 2. Al 3. + FeCl3 -----> FeCl2 O2 -----> Al2O3 Na2CO3 + C + N2 4. FeS O2 5. IBr 6. Cl2 7. AgNO3 -----> 8. HClO4 + 9. HCl + + + -----> NH3 + NaCN Fe2O3 + -----> HOH + -----> -----> AgNO2 P4O10 + HCl + -----> Mg(OH)2 -----> CO SO2 NI3 + + NH4Br HClO O2 H3PO4 MgCl2 + Cl2O7 + HOH 10. Sodium hydroxide + Hydrochloric acid -----> sodium chloride + water Page 4 Part G: Single Replacement Reactions Given the following Activity Series: Li > K > Ba > Sr > Ca > Na > Mg > Al > Mn > Zn > Fe > Cd > Co > Ni > Sn > Pb > (H) > Cu > Ag > Hg > Au Given the following Active Metals: Li > K > Ba > Sr > Ca > Na Complete the products of the following reactions, then balance the equation (If no reaction write NR): -----> 1. Cu(s) + Al(NO3)3 (aq) 2. Al(s) + Cu(NO3)2 (aq) -----> 3. Au(s) + 4. Ca(s) 5. Mn(s) H2SO4 (aq) + + H2O (l) H2O (l) -----> -----> -----> Page 5 Part H: Double Replacement Reactions Given the following Solubility Rules for Ionic Compounds: Compounds containing the following ions are generally soluble in water: 1. Alkali metal ions and ammonium ions, Li+, Na+, K+, NH4+ 2. Acetate ion, C2H3O23. Nitrate ion, NO34. Halide ions (X), Cl-, Br-, I- (AgX, Hg2X2, and PbX2 are insoluble exceptions) 5. Sulfate ion, SO4 2- (SrSO4, BaSO4 , and PbSO4 are insoluble exceptions) Compounds containing the following ions are generally insoluble in water: 6. Carbonate ion, CO32- (see rule 1 exceptions which are soluble) 7. Chromate ion CrO42- (see rule 1 exceptions which are soluble) 8. Phosphate ion PO43- (see rule 1 exceptions which are soluble) 9. Sulfide ion, S2- (CaS, SrS, BaS, and rule 1 exceptions are soluble in water) 10. Hydroxide ion, OH- [Ca(OH)2 , Sr(OH)2 , Ba(OH)2 , and rule 1 exceptions are soluble) Complete and balance the following reactions using the above solubility table (write no reaction or NR if both products are soluble or a covalent compounds is not formed) 1. ___ AlCl3 (aq) + ___ K2CO3 (aq) -----> 2. ___ NiSO4 (aq) + ___ Li3PO4 (aq) -----> 3. ___ NaCl (aq) + ___ AgNO3 (aq) -----> 4. ___ H2SO4 (aq) + ___ NaOH (aq) -----> 5. ___ H3PO4 (aq) + ___ Ba(OH)2 (aq) -----> Page 6 Part I: Mole-Mole Stoichiometry Tungsten occurs in the important mineral scheelite (Calcium tungstate), which is converted to tungstic acid. Tungsten is then extracted from tungstic acid by the following (unbalanced) reaction: H2 + H2WO4 W + H2O How moles of hydrogen is needed to prepare 6 moles of elemental tungsten? Phosphoric acid can be made by the following (unbalanced) reaction: H2O + P4O10 H3PO4 How many moles of Phosphoric acid can be prepared from the combination of 5 moles of Tetra-phosphorus dec-oxide with excess water? Page 7 Part N: Multiple Choice Chapters 8,9,10 ____1. Which of the following is equal to one mole of substance? (A) 6.02 x 1023 sodium atoms, Na (B) 6.02 x 1023 chlorine molecules, Cl2 (C) 6.02 x 1023 sodium chloride formula units, NaCl (D) 6.02 x 1023 chloride ions, Cl 1(E) A & B are both correct (F) C & D are both correct (G) all of the above are correct ____2. Which of the following represents 1 mole of ozone gas, O3? (A) 6.02 x 1023 ozone molecules (B) 48.0 g ozone gas (C) 22.4 L ozone gas at STP (D) all of the above (E) none of the above _____3. What is the molecular mass of mercurous nitrate, Hg2(NO3)2 ? (A) 463.2 g/mol (B) 477.2 g/mol (C) 511.2 g/mol (D) 525.2 g/mol (E) 649.2 g/mol (F) none of the above _____4. If 0.125 mol of S combines with 0.250 mol of O, what is the empirical formula of sulfur oxide? (A) SO (B) SO2 (C) SO4 (D) S2O (D) S4O _____ 5. The insulating material Styrofoam is a polymer of styrene. Find the molecular formula of styrene given its percentage composition: 92.25% Carbon, 7.75% hydrogen. The approximate molar mass is 104 g/mol. (A) C1H1 (B) C1H8 (C) C1H12 (D) C8H8 (E) C12H1 Page 8 _____6. What is the term that expresses the simplest whole number ratio of atoms in a molecule, or ions in a formula unit? (A) chemical formula (B) simplest formula (C) molecular formula (D) empirical formula (E) mass ratio composition (F) percentage composition _____7. Which of the following is evidence for a chemical reaction? (A) a gas is detected (B) a precipitate is formed (C) a colour change is observed (D) an energy change is noted (E) both B & C are correct (F) all are correct (G) none of the above _____8. What is the term for a compound that releases hydrogen ions when dissolved in water? (A) acid (B) aqueous acid (C) base (D) aqueous base (E) none of the above ______9. The product(s) of a neutralization reaction is (are) (A) water (B) aqueous acid (C) aqueous base (D) salt (E) aqueous acid and aqueous base (F) aqueous acid and water (G) salt and water (H) aqueous base and water (I) aqueous acid, water, aqueous base (J) none of the above ______10. Ethane, C2H6, burns to give carbon dioxide and water. What is the coefficient of oxygen gas need to balance the reaction: (A) 5 (B) 7 (C) 10 (D) 14 (E) none of the above Page 9 Use the following choice in questions 11-15 to classify each of the following chemical equations (unbalanced): A. B. C. D. E. F. Combination (or synthesis) Decomposition (or analysis) Single replacement Double Replacement Neutralization Combustion _____11. C5H12 + _____12. K + _____13. Al(OH)3 + _____14. Zn HCl _____15. + S CO2 HNO3 KClO3 O2 H2O K2S KCl + Al(NO3)3 ZnCl2 + + + H2O H2 O2 Answwers: 1.g 2. d 11. f 12. a 3. d 13. e 4. b 14.c 5. d 6.d 7.f 8.b 9.g 10.b 15.b Page 10