! ! " # $ % # &$ %' % !"## ! " # $ !% ! & $ ' ' ($ ' # % % ) % * % ' $ ' + " % & ' !# $, ( $ - . ! "- ( % . % % % % $ $ $ - - - - // $$$ 0 1"1"#23." 4& )*5/ +) 678%99:::& % 2 ; ) - * & < "-+ % -= -+ % /- >7?:94& )*5/ +) "3 " & 7?:9 AKNOWLEDGEMENT All thanks and glory be to Allah (SWT) for all his blessings that he showered on us from the first day of our lives up to this moment and I pray that may his blessings be with us throughout our lives in this world and here after. I grateful to my supervisor Dr.D.B. Yahaya for sparing his time and effort to go through my work, I wish to also thank the H.O.D and the entire members of staff of the department of Mechanical Engineering, Bayero University Kano for their kindness and assistance throughout my study. I also wish to thank Mall. Mustapha Usaini, General Manager, Pioneer Technical services Ltd Kaduna for assisting me tremendously in the construction part of this research. Finally I wish to everybody who in one way or the other assisted me in carrying out this work. /s DEDICATION This work is dedicated to my beloved father; Alh. Abubakar Garba, Mother; hajiya Aishatu Abubakar, wife: Amina Jamila Usman and my daughters Maryam (Ummi) and Aisha (Siddiqa) s TABLE OF CONTENTS Contents Page No. Acknowledgement----------------------------------------------------------------------- IV Dedication--------------------------------------------------------------------------------- V Table of contents------------------------------------------------------------------------- VI List of figures ----------------------------------------------------------------------------- IX List of tables------------------------------------------------------------------------------ X Abstract----------------------------------------------------------------------------------- XI CHAPTER ONE: INTRODUCTION 1.0 Background of the Study------------------------------------------------------------ 1 1.1 Statement of the Problem------------------------------------------------------------- 1 1.2 Aim of the Study---------------------------------------------------------------------- 1.3 Objectives of the Study--------------------------------------------------------------- 2 1.4 Significance of the Study-------------------------------------------------------------- 2 1.5 Scope of the Study--------------------------------------------------------------------- 3 2 CHAPTER TWO: LITERATURE REVIEW 2.1 Economic Importance of Onions---------------------------------------------------- 4 2.2 Temperature Effects and Metabolic Activity of Onions during Storage------ 5 2.3 Onion – Bulbs Size and Shape------------------------------------------------------- 6 2.4 Methods Employed In the Storage of Onions------------------------------------- 7 2.4.1 High Temperature Storage----------------------------------------------------------- 7 2.4.2 Refrigeration/ Low Temperature Storage------------------------------------------ 7 2.5 9 Refrigeration of Fruits and Vegetable---------------------------------------------s/ 2.5.1 Water Loss of Stored Product------------------------------------------------------ 13 2.5.2 Heat Transfer of Root Product----------------------------------------------------- 16 2.6 Termination of Processing Time and Heat Load during Refrigeration of Foods------------------------------------------------------------------------------- 20 2.7 Thermal Properties of Foods------------------------------------------------------- 25 2.8 Refrigeration and Refrigeration Cycles------------------------------------------- 27 2.8.1 Refrigerator Efficiency-------------------------------------------------------------- 28 2.8.2 The Ideal Vapor Compression Refrigeration Cycle----------------------------- 29 2.8.3 Actual Vapour Compression Refrigeration Cycles------------------------------ 31 2.9 Refrigerants--------------------------------------------------------------------------- 34 2.9.1 Selection of the right refrigerant --------------------------------------------------- 35 CHAPTER THREE 3.1 Design Procedure--------------------------------------------------------------------- 37 3.2 Calculation of Heat Load------------------------------------------------------------ 37 3.3 Determination of the Refrigeration Capacity Required-------------------------- 49 3.4 Selection and Sizing of Refrigerant and Refrigeration Equipment------------- 49 3.4.1 Compressor Power Requirement---------------------------------------------------- 52 3.4.2 Sizing and Selection of Condenser------------------------------------------------- 53 3.4.2 Sizing and Selection of Evaporator------------------------------------------------- 55 3.4.4 Refrigerant Piping--------------------------------------------------------------------- 56 3.4.5 Selection of Expansion Valve-------------------------------------------------------- 56 3.5 Construction, Testing and Cost Analysis------------------------------------------- 56 3.5.1 Physical Description of the Storage System---------------------------------------- 56 3.5.2 Components of the System------------------------------------------------------------ 57 3.6 Testing of the Storage System--------------------------------------------------------- 58 3.7 Cost Analysis --------------------------------------------------------------------------- 66 s// CHAPTER FOUR: DATA PRESENTATION AND ANALYSIS 4.0 Results from Testing Of Storage System-------------------------------------------- 68 4.1 Data Analysis and Inferences--------------------------------------------------------- 70 CHAPTER FIVE: CONCLUSION AND RECOMMENDATION 5.0 Conclusion------------------------------------------------------------------------------ 75 5.1 Recommendation----------------------------------------------------------------------- 75 5.2 Suggestions for Further Studies------------------------------------------------------- 75 Plate 1: Frond view of the constructed storage system---------------------------- 76 Plate II: Side view photograph of the constructed storage system--------------- 77 References------------------------------------------------------------------------------- 78 APPENDICES APPENDIX I: Wet and dry thermometer chart------------------------------------- 82 APPENDIX II: Heat Leakages------------------------------------------------------- 84 Appendix III: Properties of Common Refrigerants-------------------------------- 85 s/// LIST OF FIGURES Figures Page Number Fig. 2.1: Shapes of Onion Bulb---------------------------------------------------------- 6 Fig 2.2: Schematic of a typical vapor Recompression or Mechanical Refrigerator System------------------------------------------------------------ 10 Fig. 2.3: General system for unsteady heat conduction------------------------------ 21 Fig 2.4: Newtonian heating or cooling------------------------------------------------- 21 Fig 2.5: Transient temperature response----------------------------------------------- 23 Fig 2.6: Equivalent thermal circuit for lumped capacitance solid------------------ 23 Fig. 2.7: A Refrigerator------------------------------------------------------------------- 28 Fig. 2.8: Schematic Diagram; Ideal Vapor Compressor Refrigerator Cycle------- 28 Fig. 2.9: T-S Diagram for the Actual Vapor Compression Refrigeration Cycle-- 32 Fig. 3.1a: Pictorial View of the Storage System (closed) ----------------------------- 60 Fig. 3.1b: Pictorial View of the Storage System (opened) ---------------------------- 61 Fig. 3.2(a&b): Sectional view of the storage system showing onion in storage and chemical containers respectively. -------------------------------------------- 62 Fig. 3.3: Sectional view of the storage system showing evaporator---------------- 63 Fig. 3.4a: Back view of the storage system---------------------------------------------- 64 Fig. 3.4b: Air cooled condenser and compressor arrangement------------------------ 64 Fig. 3.5: Automatic expansion valve---------------------------------------------------- 65 Fig. 3.6: Compressor---------------------------------------------------------------------- 65 Fig. 3.7: Air – cooled condenser--------------------------------------------------------- 65 Fig. 3.8: Evaporator----------------------------------------------------------------------- 65 Fig. 4.0: Respiration rate of onions under storage and in normal air--------------- 72 Fig. 4.1: Weight loss measurements for onions in storage and in control---------- 73 Fig. 4.2: Average relative humidity recorded----------------------------------------- 74 /y LIST OF TABLES Tables Table 2.1: Respiration Rates (Co2 Production) of Onions in mg.kg-1h1--------------- 5 Table 2.2: Recommendation Refrigerated Storage Condition for Onion Bulbs------ 8 Table 2.3: Heat of Respiration of Some Fresh Fruits and Vegetables at various Temperatures. ------------------------------------------------------------------ 12 Table 2.4: Coefficients for CO2 production by Commodities [17] ---------------------- 13 Table 2.5: Thermal Conductivity of Some Root Crop Products [18] ---------------- 19 Table 3.1: Frequency Table for Diameters of Onion Bulbs---------------------------- 38 Table 3.2: Summary of Cost Analysis---------------------------------------------------- 66 Table 4.0: Summary of readings obtained during testing of the storage System---- 69 y ABSTRACT This work is a study of a refrigerated and controlled atmosphere onion storage system. In the process of this study a system was constructed for refrigerated onion storage. The system constructed uses a vapour – compression refrigeration unit, to reduce and maintain the temperature inside the system at 1oC and 87% relative humidity. Soda lime and silica gel were used to control moisture and carbon dioxide production rate of onions in storage. Refrigerated unit components were sized and selected based on heat load calculated. The system was tested for a period of four months with 10kg of onion in storage and exact quantity as control. Results obtained shows that carbon dioxide production rate is significantly lower than normal respiration rate of onions exposed to open air, while weight loss of onions in storage was reduce with only 0.3% weight loss after four months, as compared to 1.67% weight loss for onions in open air. It was concluded that combination of refrigeration and controlled atmosphere is a very efficient method of onion storage. y/ CHAPTER ONE 1.0 Introduction Onion (Alliums cepa L) are highly valued World Wide for their flavor and for their Nutritional value in supplying minor constituents such as minerals and trace elements. The bulbs are boiled and used in soups and stews, fried, or eaten raw. They are also preserved in the form of pickles. Onion leaves, especially from the spring onions are also used in salads and soup. Onions are a major crop in the tropics which account for nearly 30% of total global production (1). Nigeria being a tropical country also contributes to this account. According to Natural Resources Institute (NRI) bulleting of 1997, Nigeria which is located on latitude 4 – 140N produced the (Kano red), (Kano White), (Gindin Tasa), (Wuyan Bajimi) and (Wuyan Mokorowa), varieties of onions. Out of these varieties the Kano Red and the Kano White are widely produced in Kano State of Nigeria. Despite the economic viability of onion of the local farmers and people who seal in the wholesale and retail of the crop are faced with high losses of their crop due to poor storage (1). This is Abecause onion is a perishable crop and thus its storage longer than the maximum period of 23 to 30 days (refer to appendix IV) is difficult. Although various storage techniques are employed by the local people traditionally, this project work was carried out in order to develop and construct a system that can be used to store onions for a period longer than the period after which it will perish. 1.1 Statement of the Problem Onion is a Biennial crop and it shows a distinctly marked dormancy between the vegetative and the generative growth period. Therefore onion bulbs are natural storage organs well for long term crop storage (2). The problems in onion storage is mainly due to climatic conditions (especially ϭ temperature) and how to prevent water loss, exclude pathogens i.e. germs that can cause diseases, prevent sprouting i.e. germination during storage, bulb softening, shriveling and weight loss. Therefore a system where the atmosphere or the climatic conditions and the problems above can be controlled will provide an effective storage of onion for a long period. Since according to NRI Bulletin (1978) the Kano Red onion specie is being produced at a rate of 20 to 30 tones per hectare and can only be stored for 23 day to 1 month, this will constitute a great loss if the onions cannot be stored beyond the period. 1.2 Aim of the Study The aim of the study was to develop an onion storage system in which the temperature and relative humidity within the storage area is 10C and 87% respectively, and to slow rate of respiration of onions during storage. 1.3 Objectives of the Study The objectives of this study are: i. To develop a functional refrigeration system for onion storage. ii. To test and determine the efficiency of the storage system. iii. To determine and select size of refrigeration equipment for onion storage system. 1.4 Significance of the Study For the Local farmers and traders of onion, the construction of a storage system that is cheap and accessible to them will be very useful. This will enhance and improve their economic status. In the cause of the study new knowledge encountered will help in reducing loss of onions during storage. Thus the study is highly significant. Ϯ 1.5 Scope of the Study There are different varieties of onions grown all over the world and each type of specie has different physical appearance. Some long, some oval others round etc. also their storage periods (refer to fig. 2.1 and appendix IV). That is the period over which they can be stored without any defects on them. Due to this the Kano red species of onions was selected for this project work. Therefore information and data collected during testing of the storage system for a period beyond reported maximum storage life of 23 days to 1 month was done using Kano red onion specie. ϯ CHAPTER TWO LITERATURE REVIEW 2.1 Economic Importance of Onions Edible onions are important vegetables World Wide. Pre – eminent among them in terms of volume grown and traded is the common onion grown for bulbs. In terms of global weight of vegetables produced, at nearly 28 million tons per annum, only tomatoes and cabbages exceed bulb onions in importance (2). International trade is estimated at about 2 million tons annually, worth about 400 million, U.S. dollars equivalent to about 5.6 billion Naira (2). Onions are a major crop in the tropics, which account for nearly 30% of total global production (1), estimated loss of total crop in tropical countries is high and can reach 20% to 95% (3). Losses between Wholesale and retail of over 9% have been reported for spring onion (4). Although some tropical countries are not importers, export potential of onions is developing in several tropical regions partly because if dried and parked properly the bulbs can be transported for considerable distances without deteriorating. Storage for several months also is possible if suitable bulb temperature can be maintained. Proper storage environment is critical to minimize bulb softening; shriveling, weight loss and development of storage rot decay. Different cultivars have variable storage life. In general poor – keeping cultivars are less pungent (5) and have a low dry matter content (6), a low refractive index (7,8), and high relative rate of water loss and total water loss, especially in period immediately following harvest. Poor storing cultivars also are more susceptible to storage rots. Sprout more readily (9) and benefit more from “curing”. ϰ 2.2 Temperature effects and metabolic activity of Onions during Storage During dormancy at lower and higher temperatures sprouting is depressed. The rate of elongation of sprouts within the bulb and the rate of leaf initiation were much faster at 15oC than 0 or 30oC (2). Therefore, sprout development in onion bulbs unlike most physiological processes, does not increase in rate progressively as temperature increases (2). Once sprouting has occurred in rooted bulbs like onion, sprout growth rate increases progressively with temperature (2). Respiration rates of produce indicate the degree of metabolic activity and provide useful insights in the design of storage systems for environmental and atmospheric control. The rate of post harvest deterioration (Spoilage) of produce generally is proportional to the rate of respiration (10). Bulb onions have a low respiration rate (3 – 4mg Co2. Kg-1. h-1 at 5 0C) (10) and this increases with corresponding increase in temperature. Green onions have higher respiration rates, comparable to leafy vegetables; at the same temperature (refer to table 2.1 below) a low oxygen level in the storage chamber halves the rates respiration (10). Table 2.1: Respiration Rates (Co 2 Production) of Onions (in mg.kg -1h1) (3) Temperature Dry Onions Green Onions 0 oC 4 - 5 oC 10oC 15 - 16 oC 20 - 21oC 3 3–4 7 -8 10 – 11 14 - 198 10 - 32 17 – 39 36 – 62 66 – 115 79 – 178 In storage as time progresses, the rate of respiration increases. If bulbs are wounded, their rate of respiration increases and reaches a maximum after about 12hours (12). The higher respiration level is measurable over the whole storage period (12), if the dry outer skins of onions are removed, the respiration rate of bulbs increases nearly two fold and the rate of water loss also increases. Bulbs with the skin removed also sprout more rapidly than those with intact skins (2). ϱ 2.3 Onion – Bulbs Size and Shape Bulb size and shape are important attributes both for marketing and retention of post harvest quality. Onion bulb shapes can be described by various standard geometrics (refer to fig. 2.1 below). Bulb size affects both sprouting and water loss during storage. Studies have shown that during storage at 110C large bulbs sprouted at a faster rate than small ones, but small onions lose weight more rapidly (12,13). 1. Flat 5. High Globe 2. Thick flat 6. Spindle 3. Flattened globe 7. Cylinder 4. Globe 8. Flat top Fig. 2.1: Shapes of Onion Bulb ϲ 9. High top 2.4 Methods Employed In the Storage of Onions There are various methods used in storage of onions. These methods are numerous, for the purpose of this project work only two methods, whose information are relevant to this work are discussed here. These are: 2.4.1 High Temperature Storage Onions may be stored at high temperatures of over 25°C at a range of relative humidity's (75% to 80%) that are sufficient to minimize water loss [1]. Storage at temperatures of 25 to 30°C has been shown to reduce sprouting and root growth compared to cold storage at 10 to 20°C, however, weight loss, desiccation of bulbs, and rots occurred at high levels of temperature making the system uneconomic for long periods [1, 14]. High-temperature storage of onions can be achieved under both ambient and heated storage conditions. However ventilation must be applied carefully inside the store to achieve the required temperature and humidity levels. 2.4.2 Refrigeration/ Low Temperature Storage Ranges of temperatures and relative humidity have been recommended for storage of onions (refer to table 2.2) below. Most storage facilities use mechanical refrigeration to control storage temperature. This system utilizes the fact that a liquid absorbs heat as it changes to a gas. The most common mechanical refrigeration systems use a refrigerant such as ammonia or a variety of halocarbons i.e. chlorofluorocarbons (CFC's) fluids (sometimes referred to by the trade name 'Freon') whose vapor can be recaptured easily by a compressor and heat exchanger. Fig 2.2 below shows the components of a typical vapor- recompression (or mechanical) refrigeration system. ϳ Table 2.2: Recommendation Refrigerated Storage Condition for Onion Bulbs [11] Temperature Relative Humidity (%) Length of Storage (Month/ Days) -3-0 70-75 6 mo -3 85-90 5-7mo -2 75-85 300 d -3 - (0.6) 75-80 6 mo -1-0 70-80 6 - 8 mo -0.6 78-81 6-7mo 0 75-85 6 mo 0 65-75 - 0 70-75 20 - 24 wk 0 70-75 - 0 65-70 1 -2 mo 0 65-70 6-8 mo 0 - 230 d 0 70 - 75 or 90 - 95 Up to 120 d 0 80-85 30 -35 wk 1-2 80-85 30-35wk 1 87 - 1.1 70 – 75 16-20wk 4 - 170 d 8 - 120 d 12 - About 90 d 20 - 25 d (°C) The refrigerant fluid passes through the expansion valves, where the pressure drops and the liquid evaporates at temperatures low enough to be ϴ effective in removing heat from the storage area. Heat from the material to be cooled is transferred to the room air, which is then forced past the evaporator (cooling coil located in the room). This is usually a finned tube heat exchanger, which transfer the heat from the air to the refrigerant causing it to evaporate. After fully changing to a gas, it is pressurized by the compressor and then passes through a condenser, where it is cooled to a liquid. The condenser is located outside the storage area and releases hot liquid which is stored in the receiver and is metered out as needed for cooling. Onion bulbs freeze below - 3°C, green onions store best at about 0°C and very high humidity greater than 95%. Maximum length of storage at these conditions varies from just a few days to about 3 weeks [15]. Low temperature storage of onions can be achieved under both ambient and refrigerated storage conditions; however, ventilation must be applied carefully inside the store to achieve the required temperature and humidity levels without inducing condensation of water on the surface. 2.5 Refrigeration of Fruits and Vegetable Fruits and vegetables are frequently cooled to preserve pre-harvest freshness, flavor and to extend storage and shelf life. Fruits and vegetables are mostly water, and thus their properties are close in value to those of water [16]. Initially, all of the heat removed from the product comes from the exterior of the products, causing a large temperature gradient within the product during fast cooling. But the mass average temperature of the product at a given time is used in calculations for simplicity. The heat removed from the products accounts for the majority of the refrigeration load and is determined from: Qproduct= mcp(Tinitial – Tfinal) /'t (w).........................................(2.1) ϵ Fig 2.2: Schematic of a Typical vapour Recompression or Mechanical Refrigerator System (11) ϭϬ Where Qproduct = Average rate of heat removal from the fruits and vegetables. m = The total mass of the fruits and vegetables m = The average specific heat produce. Tinital = mass average temperature before cooling. Tfinal = Mass average temperature after cooling. 't = Cooling time. Fresh fruits and vegetables are live products and they continue to respire for days and even weeks after harvesting at varying rates [16]. During respiration a sugar like glucose combines with oxygen to produce carbon IV oxide and water. Heat of respiration is released during this exothermic reaction, which adds to the refrigeration load during cooling of fruits and vegetables. A simplified representation of the process is given as: C6H12O6+6O2 o 6C020 + 6H20 +Heat of respiration The rate of respiration varies strongly with temperature, an increase in temperature results in increased reaction rates but not all reactions have the same rate of change in temperature [16]. The change in respiration rate due to a change in temperature represents the overall effect of temperature on the different chemical reaction of the respiration process. Keeping the product quality throughout a storage period as near as possible to the quality at harvest time requires that the metabolic processes be slowed down as much as possible. This is best achieved by storage at low temperature, provided that no other adverse effects such as cell-membrane damage occur at low temperature. Refrigeration load due to respiration is determined from [16]: Qrespiration = 6mqrespiration (w).......................................(2.2) This is the sum of the mass times the heat of respiration for all the food products stored in the refrigerated space. The heat of respiration for some fruits and vegetables was given as shown in the table below. ϭϭ Table 2.3: Heat of Respiration of Some Fresh Fruits and Vegetables at various Temperatures. [16] Product Heat of Respiration mW/kg 5°C 20°C Apple 13-36 44-167 Straw berries 48-98 303-581 Broccoli 102-475 825-1011 Cabbage 22-87 121-437 Carrots 20-58 64-117 Cherries 28-42 83-95 Lettuce 39-87 169-29 Watermelon * 51-74 Mushrooms 211 782 - 939 10-20 50 Onions In another related publication based on a data from U.S. department of Agriculture, the carbon dioxide production of products can be expressed as a function of temperature, by a least-square regression fit, of the form [17]: ݉మ ൌ ݂ ൬ ͻܶ ͵ʹ൰ ௫ ሺ݉݃݇݃ ିଵ݄ିଵሻ ǥ ǥ ǥ ǥ ǥ ǥ ǥ ǥ ሺʹǤ͵ሻ ͷ Where ݉మ = Is the carbon dioxide production per unit mass of a product ሺ݉݃݇݃ ିଵ݄ ିଵሻ Tm = the mass average temperature (°C) f and x are respiration coefficients given in table 2.4 below. ϭϮ Table 2.4: Coefficients for carbon dioxide production by Commodities [17] Skin Mass Transfer Coefficient Respiration coefficients 2 Ks (g/m .s.mpa) Low Mean High VPL Carrots 31.8 156.0 361.0 0.99 Onions - 0.888 - 0.98 Potatoes - 0.635 - 0.98 0.01709 1.769 9.09 33.6 87.3 0.96 8.591x10-3 1.888 Sugar beets f X 0.05002 1.793 3.668X10 -4 2.538 The rate of heat generation by respiration qresp of equation (2.2) is given by [17] qresp = 10.7 ݉మ (Jkg-lh-l) .................................................(2.4) It should be noted that even at low temperatures the product is still characterized by a low metabolic activity and subsequently heat is still generated. This internal heat generation in the product causes the product temperatures to be slightly higher than the storage -room air temperature. This may not have a large effect on the respiration activity, but it can greatly affect the vapour-pressure difference between the product and the surrounding air, thus influencing the moisture balance of the product. 2.5.1 Water Loss of Stored Product Apart from respiration, another process that the temperature of the product influences is transpiration. Transpiration of root crops is a mass transfer process in which water is lost from the product. It involves the transport of moisture through the outer layers of the product, the evaporation of the moisture from the product surface, and the convective mass transport of the moisture to the surroundings. Moisture loss affects the product quality causing changes in appearance (the surface starts to shrivel), texture and flavor. In addition moisture loss also reduces the mass salable product. The ϭϯ driving force for transpiration is the vapor-pressure difference between the surface of the product and the surrounding air. The basic mathematical model to describe transpiration is given by [18]: mw = kt (ps - pa) (g/kgday)................................................(2.5) Where: kt = The transpiration coefficient. mv = Moisture loss, per unit product Surface. ps = Vapor pressure at the product Surface, and is given by [18] : ళǤఱ ps = ͳͲቀଶǤ଼ହାమయళǤయశቁ .....................................................(2.6) Where T = Temperature at which product is stored Pa = Vapor pressure in the surrounding air, and is given by [18] Pa = Pa ோு ……….....................................................(2.7) ଵ Where RH = Relative humidity at which product is stored. To take into account the skin resistance of the product and the effect of airflow rate the value of kt is evaluated from [18] : ଵ ൌ ଵ ೌ ଵ ೞ ...............................................................(2.8) ka = Convective mass transfer coefficient ks = The skin mass transfer coefficient, which Accounts for the diffusion resistance of the skin towards moisture migration. In model calculations it is convenient to use values of ks that have been obtained experimentally [18] (refer to Table2.4). Values for the convective mass transfer coefficient at the surface are calculated from SherwoodReynolds -Schmidt correlation given as. Sh = ʹǤͲ ͲǤͷͷʹ ܴ݁ Ǥହ ܵܿ 033 ............................................. (2.9) Where Re = is the Reynolds number Sc= Schmidt number Sh = Sherwood number ϭϰ So that Ka can be determined from Sh = k a + ௗ .....................................................(2.10) ఋ Where G = diffusion coefficient of water in air The diffusion coefficient is strictly a function of pressure and temperature and that for water vapor in air Schirmer's equation can be used to determine G [19] Using the equation ଵ ் ଶଷ G = ʹǤʹܺͳͲିଷ ቀ ଵǤ଼ଵ ቁ (m/s2) ...................................(2.11) Where T = water temperature in Kelvin p =ambient pressure in bar d = average diameter of the product. In storage conditions in which natural convection is significant, the airflow rate is caused by internal heat generation and by evaporative cooling resulting from transpiration. A higher fraction of surface permeable to water results in a higher rate of total moisture loss and thus in lower temperature differences and lower air velocities under steady state conditions [18]. This results in a lower temperature, while the total rate of moisture loss appears to be only slightly affected. Diso [19], on convective mass transfer, stated that consider the case of a plane water surface at a temperature Tw with corresponding properties of water concentration Cw, and saturation pressure Psat, and if air flows over the water with concentration C0, partial vapor pressure Pvo and initial Temperature T0 there will be equilibrium at water level. Due to equilibrium water concentration Cw corresponds to the saturation concentration at Tw. Therefore, because of the temperature difference, there is going to be "Sensible heat transfer" and due to the difference in partial pressures there will also be "mass transfer" which will be companied by "Latent heat transfer", and that the different transfers can be characterized as follows: ϭϱ (i) Sensible heat transfer qs is expressed as dq s=h(Tw-Ts)ds (W)...........................................(2.12) Where Ta - Ambient air temperature Tw = Water temperature. (°C) (°C) qs - Sensible heat transfer (W) h = Sensible heat transfer coefficient (W/m2 °C) S = Area of the water surface (m2) (ii) Mass transfer m is expressed as: dm = hcc(Cw -C0)ds (Kg/s).............................................(2.13) hcc = Concentration mass transfer coefficient in m/s Cw and C0 = Respective water and air concentrations expressed in kg/m3 The rate of latent heat transfer qL is expressed as: (iii) dq L = dmLv(Tw) (W) ...........................................(2.14) Where qL = Latent heat transfer. (W) Lv = latent heat of vaporization at the water temperature. (J/kg) m = The rate of evaporation (kg/s) 2.5.2 Heat Transfer of Root Product It has been mentioned that the product temperature influences processes of respiration and transpiration. As a consequence, the temperature history of the product affects the quality of the product after storage. One of the most important steps after harvest is the removal of heat stored in the product. Indeed, at harvest time the product is at a temperature at which the respiration rate is high and the quality degrades rapidly. Heat transfer inside the product can be described by the Fourier equation, a partial differential ϭϲ equation involving the change in heat content as a function of temperature and heat generation [18]. ܲ ܥ ఋ்ು ఋ௧ ൌ ൫݇ ܶ ൯ܹ௦ ……………………. (2.15) With Tp (x, y, z, t) = Tp,ini (x, y, z) at t = t0 Where pp = The product density (kg m-3) c = The specific heat capacity of the product (Kg kg-loC-l) kp = The thermal conductivity of the product (Wm-1oC-1) Tp = The product temperature (°C) Tp.ini = The initial temperature of the product (°C) t= time (s) t0 = Initial time (s) wresp= The volumetric respiration rate (Wm-3) x, y, and z = Cartesian co-ordinates (m) Also ೝೞ Wresp = ଷ ………………………………………. (2.16) Where qresp = specific respiration rate (Jh-1kg-1) In order to obtain the temperature distribution inside the product as a function of time, the boundary condition describing the energy transfer should be specified. The different terms in the boundary condition can be: (i) Heat transfer by radiation absorbed or released to the surroundings. This is expressed as qrad = HV(Ts -Tw)4 ............................................. (2.17) Where qrad = Heat transfer by radiation (J) H = The emissivity of the product. V = Stefan Boltzman constant (Wm-2 C-4) Ts = the surface temperature (°C) ϭϳ Tw (ii) = the surrounding temperature (°C) Heat Lost or Gained by Convection This is expressed as: qconv = h(Ts-Ta).................................................(2.18) Where qconv = heat transfer by convection (J) h = surface heat transfer coefficient (WM-2.0 C-1) Ts= surface temperature of the product (°C) Ta = the ambient (air) temperature (°C) (iii) Heat lost or gained as latent heat of evaporation or condensation This is expressed as qevap = mw(CmTs - CvTa - hfg) ................................. (2.19) Where qevap = heat gained or lost as latent heat of evaporation or condensation. mw = Moisture loss per unit surface (kgs-1 m-2) hfg = Latent heat of Vaporization of water (JKg-1) Cm =Specific heat capacity of the moisture in the product (JKg-1 0C-1). Ts = The surface temperature (°C) Cv = Specific heat capacity of the vapour in the air (J Kg-1 oC-1). Ta = The Ambient air temperature. (°C) (iv) Heat lost or gained by conduction to other units or to the side walls of the container or of the storage room This is expressed as ݍௗ ൌ െ݇ௗ ߜܶௗ ߜ݊ Where ݍௗ ൌHeat lost or gained by conduction (J) ݇ௗ = Wall thermal conductivity (Wm~ ° C" ) ܶ௧ ൌWall temperature ϭϴ n = outward normal The thermal conductivity of some root products is given in the Table below Table 2.5: Thermal Conductivity of Some Root Crop Products [18] S/N Products Water Apparent Temperature Fraction Density (kg (Wet Basis) m-3) (°C) Thermal Conductivity (Wm-1 K-1) 1. Potato 0.763 1127 40.0 °C 0.410 2. Potato 0.763 1117 50.0 °C 0.470 3. Potato 0.835 — 130.0°C 0.641 4. Onion 0.873 970 28.0 °C 0.574 5. Beet 0.895 1530 28.0 °C 0.601 6. Carrot 0.923 — 25.0 °C 0.571 7. Carrot 0.923 — 105.0oC 0.649 The data in the table are based on experiments conducted by Rhaman,[20] It is possible to approximate the values of these properties for a given product if the chemical composition of the product is known, [18] for simple geometry and linear boundary conditions, the analytical solution of the equation (2.15) above is available and can be found in text books on heat transfer [21, 22],In general, root crops are complex shaped products with temperature dependent material properties (pp, Kp, Cp) which are subjected to non-linear or time varying process conditions. No analytical solutions are available for such complicated heat transfer processes [18], and an approximate solution technique becomes mandatory. In practice, a numerical solution of heat equation (2.15) can be obtained by means of finite difference or finite element methods. When considering heat transfer problems with ϭϵ complex shaped products and complex boundary conditions, the finite element method is better and more advised [23,24]. 2.6 Termination of Processing Time and Heat Load During Refrigeration of Foods Rajput [25] mentioned that when a body whose initial temperature is Tj throughout and which is placed suddenly in ambient air or any liquid at a constant temperature ta is considered (refer to fig.2.3) the transient response of the body can lime determined by relating its rate of change of internal energy with convective heat exchange at the surface that is: Q = - pvc ௗ் ௗ௧ = hAs (T-Ta) ................................................ (2.21) Where Q = convective heat exchange p = density of solid kg/m3 v = Volume of the body m3 c = Specific heat capacity of the body h = heat transfer coefficient / unit surface conductance w/m2°C T = Temperature of the body at any time, °C A = Surface area of the body m2 T = ambient temperature, °C t = time in s After re- arranging the equation (2.21) and integrating the result is: න ݀ܶ ݄ܣ௦ ൌ න ݀ݐ ሺܶ െ ܶ ሻ ߩܿݒ ݊ܫሺܶ െ ܶ ሻ ൌ ೞ ఘ௩ The boundary conditions are At t = o, T = ti (initial surface temperature) ? c1 = In (Ti – Ta) Hence In (T-Ta)= ೞ ఘ௩ ݐ In (Ti – Ta) ϮϬ ݐ ܿଵ In (T-Ta) - In (Ti – Ta)=െ ݊ܫቀ ்ି்ೌ ் ି்ೌ ்ି்ೌ ் ି்ೌ ൌ ቁ=െ ఏ ఏ ೞ ఘ௩ ೞ ఘ௩ ݐ ݐ ൌ ݁ ݔቀെ ೞ ఘ௩ ቁ …………………………… (2.22) Where T = final temperature and Ti = initial temperature. Ϯϭ The following points are worth noting. (i) The equation (2.22) above gives the temperature distribution in the body Newtonian heating or cooling and it indicates that temperature rises exponentially with time (refer to fig 2.4). (ii) The quantity ఘ௩ ೞ has the dimensions of time and is called thermal time constant denoted by tth its value is indicative of the rate of response of a system to a sudden change in its environmental temperature i.e. how fast a body will respond to a change in environmental temperature tth can be expressed as tth = ቀ ଵ ೞ ቁ ሺߩܿݒሻ ൌ ܴ௧ ܥ௧ …………………….. (2.23) Where Rth = ቀ ଵ ೞ ቁ= resistance to convective heat transfer Cth=pvc = lumped thermal capacitance of solid. Any increase in the thermal resistance Rth or thermal capacitance Cth will cause a solid to respond slowly to changes in its thermal environment and will increase the required time to attain the thermal equilibrium (T = 0) (refer to fig 2.5). ϮϮ Ϯϯ Figure (2. 6) shows an analogous Electric network for a lumped heat capacity system, in which Cth = pvc Represents the thermal capacity of the system. The value of Cth can be obtained from the following thermal and electrical equations by similarity [25]: Q = (pvc) t = Cth t S = CE Where S = capacitor change C = capacitance of the condenser E = voltage. When the switch is closed, the solid is changed to the temperature T. On opening the switch, the thermal energy stored as Cth is dissipated through the thermal resistance and the temperature of the body decays with time. From this analogy it can be concluded that Resistance-capacitance electrical circuits may be used to determine the transient behavior of thermal systems. ೞ The power on exponential i.e ௩ ݐcan be Arranged in dimensionless form as follows: ೞ ௩ ݐൌቀ ௩ ೞ ቁቀ మೞ ௩ మ ݐቁ ൌ ቀ ఈ௧ ቁ ቀ మ ቁ ………………….(2.24) Where D = ቀ ቁ = thermal diffusivity of the solid. ఘ L = characteristic length = ௩ ೞ = ௨௧௦ௗ ௌ௨௧௦ௗ The values of characteristic length Lc for simple geometric shapes are given below [25]. (i) Flat plate: L = ௩ ೞ = ு ଶு = = Semi thickness ଶ Where L, B, and H are thickness, width, and height of the plate (ii) Cylinder (long): Lc = (iii) Sphere: Lc = య ర గோయ ସగோమ గோమ ଶగோ = ோ ଶ ோ = where R = Radius of the sphere. ଷ Ϯϰ where R = Radius of cylinder (iv) Cube: Lc = య మ Further from the dimension less equation: (i) The non-dimensional factor is called Biot number (Bi ) It gives an indication of the ratio of the internal (conduction) resistance to surface (convection) resistance, when the value of Bi is small; it indicates that the system has a small internal (conduction) Resistance i.e. relatively small temperature gradient or the existence of practically uniform temperature within the system. The convective resistance then predominates and the transient phenomenon is controlled by the convective heat exchange. If Bi < 0.1 the lumped heat capacity approach can be used to advantage, with simple shapes such as plates, cylinders, spheres and cubes; the error associated is around 5% [25]. (ii) The non dimensional factor ఈ௧ మ is called the Fourier number (F0) i.e Fourier number F0 = ఈ௧ మ .....................................................................(2.26) It signifies the degree of penetration of heating or cooling effect through a solid. Hence using non dimensional terms Equation (2.1) takes the form ఏ ఏ 2.7 ൌ ்ି்ೌ ் ି்ೌ ൌ ݁ ி …………………………………… (2.27) Thermal Properties of Foods Refrigeration of foods offers considerable challenge to engineers since the structure and composition of food and their thermal and physical properties vary considerably. Furthermore, the properties of foods also change with time and temperature. Fruits and vegetables offer an additional Ϯϱ challenge since they generate heat during storage as they consume oxygen and give off carbon dioxide, water vapor and other gases [16]. The thermal properties of foods are dominated by their water content. In fact, the specific heat and the latent heat of foods are calculated with reasonable accuracy on the basis of their content alone. The specific heats of foods can be expressed by Siebel's formula as. Cpfresh = 3.35 a + 0.84 (KJ Kg-l °C)........................................(2.28) Cpfrozen = 1.26 a + 0.84 (Kg Kg-l °C).......................................(2.29) Where Cp fresh = specific heat of food before freezing. Cpfrozen = specific heat of food after freezing. a = fraction of water content of the food (a =0.65 if the water content is 65%) While the constant 0.84 KJ Kg-1 °C represents specific heat of the solid (none-water) portion of the food. Siebel' s formulae are based on the specific heats of water and ice at 0 C and 2.10 kJ Kg-1 °C respectively and thus they result in the specific heat values of mater and ice at 0°C for a = 100% (i.e. pure water) therefore Siebel's formulas give the specific heat values at 0°C. However they can be used over a wide range of temperature with reasonable accuracy[16]. The latent heat of a food product during freezing or thawing (the heat of fusion) also depends on its water content and is determined from: hlatent = 334a (KJ/kg).....................................................(2.30) Where a = is the fraction of water content 334 KJ/Kg-1 is the latent heat of water during freezing at 0 oC at atmospheric pressure. Perishable foods are mostly water in content, which turns to ice during freezing therefore; we may expect the food items to freeze at 0°C, which is the freezing point of pure water at atmospheric pressure. But the water in foods is far from being pure, and thus the freezing temperature of food will be somewhat below 0°C, depending on the composition of a Ϯϲ particular food. In general, food products freeze over a range of temperatures instead of a single temperature since the composition of the liquid in the food changes (becomes more concentrated in sugar) and its freezing point drops when some of the liquid water freezes. Therefore, it is often spoken about the average freezing temperature or, for foods like lettuce that are damaged by freezing, the temperature at which freezing begins. The freezing temperature of most foods is between -0.3°C and - 2.8°C. In the absence of the exact data, the freezing temperature can be assumed to be -2°c for meats and -1°C for vegetables and fruits [16]. 2.8 Refrigeration and Refrigeration Cycles Refrigeration is the transfer of heat from a lower temperature region to higher temperature one, and that devices that produce refrigeration are called refrigerators (or heat pumps), and cycles on which they operate are called refrigeration cycles. The working fluids used in the refrigeration cycles are called Refrigerants [16]. Figure2.7 shows a schematic diagram of a refrigerator. Here QL is the magnitude of heat removed from the refrigerated space at temperature TL, QH is the magnitude of heat rejected to the warm space at temperature TH and Wnet,in is the net work input to the refrigerator. QL and QH represent. Magnitudes and thus are positive quantities. Ϯϳ Fig. 2.7: A Refrigerator Fig. 2.8: Schematic Diagram; Ideal Vapour Compressor Refrigerator Cycle Ϯϴ 2.8.1 Refrigerator Efficiency The efficiency of a refrigerator is expressed in terms of the co-efficient of performance (COP) denoted by COPR, The objective of a refrigerator is to remove heat (QL) from the refrigerated space. To accomplish this objective, it requires a work input of W net in. Then the COP of a refrigerator can be expressed as COPr = ௦ௗை௨௧௨௧ ோ௨ௗை௨௧௨௧ ൌ ௧ ௐ௨௧௨௧ ൌ ொಽ ௐǡ This relation can also be expressed in rate form. Refrigerators like heat pumps are cyclic devices and the conservation of energy principle for a cycle device requires that: Wnet,n =QH - QL (KJ) ............................................................ (2.31) This implies therefore that the C.O.P. relation can also be expressed as: COPr = ொಽ ொ ಹషೂಽ ൌ ௧ ௐ௨௧௨௧ ൌ ଵ ೂಹ ೂషభಽ It should be noted that the value of COP& can be greater than unity. That is the amount of heat removed from the refrigerated space can be greater than the amount of work input. This is in contrast to the thermal efficiency, which can never be greater than 1. In fact, one reason for expressing the efficiency of a refrigerator by another term coefficient of performance (COP) - is the desire to avoid the oddity of having efficiencies greater than unity. The cooling capacity of a refrigeration system i.e. the rate of heat removal from the refrigerated space is often expressed in terms of tons of refrigeration. The capacity of a refrigeration system that can freeze 1ton (2000 Ibm) of liquid water into ice at 0°c in 24 hrs is said to be 1ton. One ton of refrigeration is equivalent 211KJ/min (2000 BTU/min). The most frequently used refrigeration cycle is the Vapor Compression Refrigeration in which the refrigerant is vaporized and condensed alternately and is compressed in the vapor phase. There are two different forms of vapor compression refrigeration cycles [17]. i. The Ideal Vapor Compression Refrigeration Cycle, Ϯϵ ii. The actual vapor Compression Refrigeration cycle. 2.8.2 The Ideal Vapor Compression Refrigeration Cycle As earlier mentioned the vapor compression refrigeration cycle is the most widely used cycle for refrigerators, air conditioning systems, and heat pumps. This is as shown in the schematic and the Temperature - Entropy (Ts) diagrams, (refer to figs2.8 and 2.9). 1- 2 Isentropic compression in a compressor 2- 3 Constant pressure heat rejection in a condenser. 3- 4 Throttling in an expansion device 4- 1 Constant pressure heat absorption in an evaporator. In an ideal vapour compression refrigeration cycle, the refrigerant enters the compressor at state I as saturated vapour and is compressed isentropically to the condenser pressure. The temperature of refrigerant increases during this isentropic compression to well above the temperature of the surrounding medium. The refrigerant then enters the condenser as super heated vapour at state 2 and leaves as saturated liquid at state 3 as a result of heat rejection to the surroundings. The temperature of the refrigerant at this state is still above the temperature of the surroundings. The saturated liquid refrigerant at state 3 is throttled to the evaporator pressure by passing it through an expansion valve or capillary tube. The temperature of the refrigerant drops, below the temperature of the refrigerated space, during this process. The refrigerant enters the evaporator at state 4 as a low quality saturated mixture and it completely evaporates by absorbing heat from the refrigerated space. The refrigerant leaves the evaporator as saturated vapour and re-enters the compressor completing the cycle. The authors went on further to explain that all four components associated with the vapour compression refrigerator cycle are steady flow devices, and thus all four processes that make up the cycle can be analyzed as ϯϬ steady flow processes. The kinetic and potential energy changes of the refrigerant are usually small relative to the work and heat transfer terms, and therefore they can be neglected then the steady flow energy equation on a unit mass basis reduces to (qi – qout) + (Win - Wout) = h out – hin ……………………(2.32) The condenser and the evaporator do not involve any work and the compressor can be approximated as adiabatic. Then the C.O.P’s of refrigerators and heat pumps operating on the vapour – compression refrigeration cycle can be express as COPr = ಽ ௐǡ ൌ భ ିర మ ିభ ……………………………. (2.33) Where h1 = h gas h4 = hfluid 2.8.3 Actual Vapour Compression Refrigeration Cycles An actual vapour – compression refrigeration cycle differs from the ideal one in several ways, owing mostly to irreversibility that occurs in various components [17]. Two common sources of irreversibility are fluid friction (causes pressure drops) and heat transfer to or from the surroundings (refer to fig. 2.8 and 2.9). In the ideal cycle the refrigerant leaves the evaporator and enters the compressor as saturated vapour. In practice, however, it may not be possible to control the state of the refrigerant so precisely. Instead, it is easier to design the system so that the refrigerant is slightly superheated at the compressor inlet. This slight over design ensures that the refrigerant is completely vapourised when it enters the compressor. Also the line connecting the evaporator to the compressor is usually very long thus the pressure drop caused by fluid friction and heat transfer from the surroundings to the refrigerant can be very significant. The result of super ϯϭ heating, heat gain in the connecting line and pressure drops in the evaporator and the connecting line is an increase in a specific volume, thus an increase in the power input requirements to the compressor since steady-flow work is proportional to the specific volume. d Fig. 2.9: T-S Diagram for the Actual Vapour Compression Refrigeration Cycle The compression process in the ideal cycle is internally reversible and adiabatic and thus isentropic. The actual compression process, however, will involve frictional effects, which increase the entropy and heat transfer, which may increase or decrease the entropy, depending on the direction. Therefore the entropy of the refrigerant may increase (process 1-2) or decrease (process 1-2) during an actual compression process, depending on which effects dominate. The compression process 1-2 may be even more desirable than the isentropic compression process since the specific volume of the refrigerant and thus the work input requirement are smaller in this case. Therefore the refrigerant should be cooled during the compression process whenever it is practical and economical to do so. In the ideal case the refrigerant is assumed to leave the condenser as saturated liquid at the compressor exit pressure. In actual situations, however, it is unavoidable to have some pressure drop in the condenser as well as in the lines connecting the condenser to the compressor and to the throttling valve. ϯϮ Also, it is not easy to execute the condensation process with such precision that the refrigerant is a saturated liquid at the end and it is undesirable to route the refrigerant to the throttling valve before the refrigerant is completely condensed. Therefore the refrigerant is sub cooled somewhat before it enters the throttling valve. However, since the refrigerant in this case enters the evaporator with a lower enthalpy and thus can absorb more heat from the refrigerated space. The throttling valve and the evaporator are usually located very close to each other, so the pressure drop in the connecting line is small. ϯϯ 2.9 Refrigerants Ethyl ether was the first commercially used refrigerant in vapour compression systems in 1850, followed by ammonia, carbon dioxide, methyl chloride sulphur dioxide, butane, ethane, propane, isobutene, gasoline and chloroflurocarbons, among others [16]. The industrial and heavy commercial sectors were very satisfied with ammonia, and still are, although ammonia is tonic, the advantages of ammonia over other refrigerants are its low cost, higher coefficient of performance (and thus lower energy cost), more favorable thermodynamic and transport properties and thus higher heat transfer co-efficient (requires smaller and lower cost heat exchangers) greater delectability in the event of a leak and no effect on the ozone layer the major drawback of ammonia is its toxicity which makes it unsuitable for domestic use. Ammonia is predominantly used in food refrigeration facilities such as the cooling of fresh fruits, vegetables, meat and fish, Refrigeration of beverages and dairy products such as beer, wine, milk and cheese; freezing of ice cream and other foods; ice production and low temperature refrigeration in the pharmaceutical and other process industries. It is remarkable that the early refrigerants used in the light commercial and house hold factors such as sulphur dioxide, ethyl chloride, and methyl chloride were highly toxic. The wide spread publicity of a few instances of leaks that resulted in serious illness and death in the 1920's caused a public cry to ban or limit the use of these refrigerants creating a need for the development of a safe refrigerant for household use at the request of Frigidaire corporation, general motors research laboratory developed R-21, the first member of the CFC family of refrigerants, within three days in 1928. Out of several CFCS developed, the research team settled on R-12 as the refrigerant most suitable for commercial use and gave the CFC family the trade name "Freon". Commercial production of R-11 and R-12 was started in 1931 by a company jointly formed by General motors and E.I du pont de Numours and ϯϰ G.inc. The Versatility and low cost of CFCS made them the refrigerants of choice. CFCS were also widely used in aerosols, foam insulations and the electronic industry as solvents to clean computer chips. R-11 is used primarily in large capacity chillers serving air conditioning systems in building R-12 is used in domestic refrigerators and freezers, as well as automotive air condition. R-22 is used in window air conditioners of commercial buildings, and large industrial refrigeration systems, and offers strong competition to ammonia. R-502 (a blend of R-115 and R-22) is the dominant refrigerant used in commercial refrigeration systems such as those in super markets because it allows low temperatures at evaporators while operating at single stage compression. The Ozone layer crisis has caused a major stir in the refrigeration and air conditioning industry and has triggered a critical look at the refrigerants in use. It was realized in the mid-1970's that CFCs allow more ultra violate radiation into the earths atmosphere by destroying the protective Ozone layer while preventing the infrared radiation from escaping the earth and thus contributing to the green house effect that causes global warming. As a result the use of some CFCs was banned by international treaties fully halogenated CFCs (such R-11, R-12 and R-115) do the most damage to the Ozone layer. The none fully halogenated refrigerants such as R-22 have about 5 percent of the Ozone depleting capability of R-12. CFCs that are friendly to the Ozone layer that protects the earth from harmful ultraviolet rays and at the same time do not contribute to the green house effect have been developed. Currently R-12 is being replaced by the recently developed chlorine free R134a. 2.9.1 Selection of the Right Refrigerant When designing a refrigeration system, there are several refrigerants from which to choose, such as chlorofluorocarbons (CFCs), Ammonia, hydrocarbons (Propane, ethane, ethylene e.t.c) carbon dioxide, Air (in the air conditioning of aircraft) and even water (in applications above the freezing ϯϱ point) the right choice of refrigerant depends on the situation at hand of these CFCs such as R11, R12, R22, R134a and R502 account for over 90% of the market in the united states [16]. The important parameters that need to be considered in the selection of a refrigerant are the temperatures of the two media (The refrigerated space and the environment) with which the refrigerant exchanges heat. To have heat transfer at a reasonable rate, a temperature difference of 5 to 10°C should be maintained between the refrigerant and the medium with which it is exchanging heat. If a refrigerated space is to be maintained at -10°C, for example the temperature of the refrigerant should remain at about -20°C while it absorbs heat in the evaporator. The lowest pressure in a refrigeration cycle occurs in the evaporator and this pressure should be above atmospheric pressure to prevent any air leakage into the refrigeration system. Therefore a refrigerant should have a saturation pressure of 1atm or higher at -20°C in this particular case. Ammonia and R134a are two such substances. The temperature (and thus the pressure) of the refrigerant on the condenser side depends on the medium to which heat is rejected. Lower temperatures in the condenser (Thus higher C.O.Ps) can be maintained if the refrigerant is cooled by liquid instead of air. Other factors based on which the selection of refrigerant to use should be considered are (i) Cost (ii) Efficiency i.e. C.O.P (iii) Flammability (iv) Compatibility with piping materials (v) Toxicity [26]. ϯϲ CHAPTER THREE 3.1 Design Procedure Review of literature was conducted in the previous chapter. Since the main objective of this project work is to design and construct a refrigeration system for onion storage this chapter will discuss the method that was used in the design and construction of the storage system, based on the information obtained from the previous chapter. The methods employed were as follows: 3.2 Calculation of Heat Load This is the total heat required to be removed from the refrigerated space and was used to determine the size of the refrigeration equipments that was used. This quantity was determined from the sum (1) The total heat of the product (2) The total heat gain and service load. (3) Defrost heat; That is, heat generated as a result of stoppage of operation. In order to determine the quantities the following parameters were defined and determined; these are Ts = Temperature at which the storage area was maintained = 1°C. Tp = Temperature of the product before cooling which was taken generally as room temperature (27°C to 29°C) RH = Relative humidity at which the storage area was maintained = 87% (from table2.2) chapter two. Ks = Skin mass transfer coefficient = 0.888 (from table2.4) f Respiration coefficient = 3.668X10-4 (from table2.4) = x = Another respiration co-efficient = 2.538. (from table2.4) Kp= Thermal conductivity of the product = 0.574 wm-1 K-1 (from table 2.5). Lv = Latent heat of vaporization of water at the product temperature before cooling. ϯϳ pp = Density of the product = 970kg/m-3 (from table2.5) a Water fraction of the product = 0.873(from table2.5). = S = Storage area h1 = Specific enthalpy of the product at room temp (28°C) before cooling this is determined from psychometric chart at RH (87%) = 83 KJ/Kg h2 = Specific enthalpy of the product within the storage area at storage temperature (1°C) and RH (87) = 9KJ/kg. h3 = Sensible heat transfer co-efficient. Cp = The product's average specific heat capacity which is determined using siebel's formula Cp = 3.35a+0.84KJKg-10C Where a = fraction of water content of the product = 0.873. i.e. Cp= 3.35x0.873 + 0.84 = 3.764KJKg-l0C m = Total mass of the onion stored = 50kg. d = Average diameter of product which was determined Statistically using raw data collected. The raw data was collected by measuring the diameter of 50 samples of onions using vernier's caliper in (mm). The average diameter d was determined statistically using grouped data approach thus: Table 3.1: Frequency Table for Diameters of Onion Bulbs Variable Frequency D f 61.00 - 70.50 dm fdm 15 65.75 986.25 71.00 - 80.50 16 75.75 1212.00 81.00 - 90.50 5 85.75 428.75 91.00 - 100.50 4 95.75 383.00 101.00 - 110.50 10 105.75 1057.50 6 50 Summation Therefore Average diameter d = 4067.25 σ ௗ σ ϯϴ = ସǤଶହ ହ = 81.35mm. Using the value of the parameters above the heat load calculation was carried out thus: 1. The Total Heat of the Product This quantity was determined from the sum of; i. Heat of respiration ii. Latent heat which is accompanying mass transfer iii. Sensible heat due to mass transfer between the water inside the onions and the atmosphere inside the storage system iv. Heat removed from the product. (i) Heat of Respiration The refrigeration load due to heat of respiration is given by equation (2.2) as ܳ௦௧ ൌ ݉ݍ௦௧ ሺܹሻ Where m = total mass of product = 50kg. qresp = specific respiration rate and is given by equation (4) as qresp = 10.7 ݉మ (Jkg-1h-1) ݉మ is also given by equation (3) as ݉మ ൌ ݂ ቀ ଽ் ହ ௫ ͵ʹቁ ሺ݉݃݇݃ ିଵ ݄ିଵሻ Where F = 3.668 X 10-4 x = 2.538 Tm = Mass average temperature of the product = 28oC Thus ݉మ ൌ ͵ǤͺିͲͳݔସ ቀ ଽଶ଼ = 26.73݉݃݇݃ିଵ ݄ିଵ = 26.73 x = 7.425 x 10-3 ݉݃݇݃ ିଵି ݏଵ ? qresp = 10.7 x 7.425 x 10-3 = 0.0794ି݃݇ܬଵ ି ݏଵ Hence Qresp = mqresp ϯϵ ହ ଵ ଷ ͵ʹቁ ଶǤହଷ଼ = 50 x 0.079 = 3.972W. (ii) Latent Heat due to Mass Transfer Before calculating the latent and sensible heat due to mass transfer, the rate of mass transfer was determined first and this, as discussed in chapter two, is caused due to transpiration which is given by equation (2.5) as: Mw = kt(Ps – Pa) (g/kgday) Where Ps = Vapour pressure at the product’s surface evaluated from equation (2.6) given as ళǤఱ ps = ͳͲቀଶǤ଼ହାమయళǤయశቁ ళǤఱభ ps = ͳͲቀଶǤ଼ହାమయళǤయశభ ቁ ps = ͳͲଶǤ଼ଵ = 656.15Ua Pa = Vapour pressure in the surrounding Air and is Evaluated from equation (2.7) given as Pa = Pa ோு ଵ RH = Relative humidity at which product is stored = 87% Thus Pa = 656.15 x ଼ ଵ =570.85Pa = 5.7085 x 10-4Mpa While Kt = Transpiration co-efficient and is evaluated from equation (2.8) given as: ଵ ଵ ೌ ൌ ଵ ೞ Where Ks = Skin mass transfer co-efficient ϰϬ Given in table 2.4 as 0.888g/m2s Mpa And Ka = Convection mass transfer co-efficient at the products surface calculated using the Sherwood – Reynolds Schmidt correlation given by equation (2.9) as: Sh = ʹǤͲ ͲǤͷͷʹܴ݁ Ǥହ ܵܿ 033 Since in this system there will be no flow that is no fan within the storage area then Re is considered to be Zero. Thus, the above relationship becomes Sh = 2.0 So that Ka can be evaluated from equation (2.10) given as: Sh = k a + ௗ ఋ d = average diameter of the product = 81.35 x 10-3m as determined statistically above G = diffusion coefficient of water vapour in air which can be determine from Schirmer’s equation (2.11) given as: ଵǤ଼ଵ ଵ ் ଶଷ G = ʹǤʹܺͳͲିହ ቀ ቁ (m/s2) Where T = Water temperature in this case to be taken as average temperature of this product. P = Ambient (total pressure) in bar, in this case taken as 1bar. Thus: ଵ ଷଵ ଵǤ଼ଵ ଵ ଶଷ G = ʹǤʹܺͳͲିହ ቀ ቁ = 2.69 x 10 -5 m2/s) Thus Ka can now be evaluated from 2.0 = Ka + ଼ଵǤଷହ௫ଵషయ ଶǤଽ௫ଵషఱ 2.0 = Ka + 3,024.16 Ka = 3,024.16 - 2.0 ϰϭ = 3,022.16 Therefore Kt can now be evaluated ଵ i.e ଵ ൌ ൌ ଵ ଷǡଶଶǤଵ ଵ Ǥ଼଼଼ Ǥ଼଼଼ାଷǡଶଶǤଵ ଶǡ଼ଷǤ = 1.126 Hence the rate of mass transfer or rate of evaporation Mw = Kt (Ps – Pa) = 1.126 (6.516 x 10-4 – 5.708 x 10 -4) x 3600 x 24 = 4.35g/kgday Now the latent heat accompanying mass transfer can be calculated using equation (2.14) given as qL = mw Lv (Tp) Where mw = Rate of evaporation = 4.35g/kg day Lv = Latent heat of vaporization (at the water temperature) Since Lv is the same with hfg, and this quantity was determined from the difference between h1 and h2 given amongst the parameters defined above. Thus Lv = hfg = h1 – h2 = 83 – 9 = 74KJ/kg Therefore qL = ସǤଷହ௫ଵషయ ଷ௫ଶସ ݔͶͲͳݔଷʹݔͺ 3600 x 24 = 0.104W (iii) Sensible Heat due to the Mass Transfer The sensible heat transfer due to mass transfer is determined from equation (2.13) gives as qs = h 3 (Tp - Ta)S Where Tp = Initial temperature of the product = 28oC Ts = Ambient air temperature of the storage area = 10C as obtained from literature ϰϮ S = Storage surface area which was considered as the water surface area given in standard handbook of engineering calculations as S = (length – thickness of insulation) (Breadth – thickness of insulation) i.e. (60 – 2.5) (50 -2.5) = 57 x 47.5 = 2,731.25cm = 2731.25 x 10 -2m2 h3 = Sensible heat transfer coefficient. This quantity was determined thus in a general sense Nusselt and Sherwood number characterizes heat and mass transfer respectively so if Nu = DRem Prn Sh = DRem Scn Therefore this means that the Sherwood – Reynolds – Schmidt correlations stated above can also be written as: Nu = 2.0 + 0.552 Re0.53 Pr0.33 hence Nu = 2.0 since Sh = 2.0 Since Nusselt number is expressed as Nu = ೞ where h3 = Sensible heat transfer coefficient L = Length along the direction of air movement. In this case taken to be just 1cm above the products in storage. k = Thermal conductivity of the air. In this case, evaluated from steam table at the ambient air temperature of the storage area 1oC, i.e. 273+1 = 274K hence from the table k by interpretation. T(k) ଵషమ ሺௐȀሻ 250 2.227 274 k 275 ଶହିଶହ ଶସିଶହ 2.428 ൌ ଶǤସଶ଼ିଶǤଶଶ ିଶǤଶଶ ϰϯ ଶହ ଶସ ൌ k= Ǥଶଵ ିଶǤଶଶ ሺଶସ௫ǤଶଵሻାହହǤହ ଶହ = 2.419 x 10-2W/mk h3 = ே௨ = Thus ଶǤ௫ଶǤସଵଽ௫ଵషమ ଵ௫ଵషమ ൌ ͶǤͺ͵ͺܹȀ݉ଶ݇ Hence, the sensible heat load qs can now be determined thus, From qs = h (Tp - Ta)S = 4.838 (28 - 1)x 2731 x 10-2 = 3, 567.72W (iv) Heat Removal from the Product The removed from the product is determined from equation (2.1) Qproduct= mcp(Tini – Tfinal) /'t Where m = The total mass of the onions = 50kg Tini=Mass average temperature of the product before cooling=28 oC Tfinal =Final mass average temperature of the product after cooling Cp = Specific heat capacity of the products determined from the expression, equation (2.28) Cp = 3.35a + 0.54(kgkg-1oC) Where a = Fraction of water content of the onions = 0.871 thus Cp = 3.35 x 0.871 + 0.84 = 3.758 x 103JKg-1oC 't = cooling time The cooling time is the time it will take for the product to be cooled from its harvest temperature to the desired storage temperature and this is determined from the Fourier equation (2.15) giving the heat transfer inside the product expressed as: ܲ ܥ ߜܶ ൌ ൫݇ ܶ ൯ܹ௦ ߜݐ ϰϰ With Tp(x,y,z,t) = Tp,ini (X,Y,Z) at t = to Where Wresp = The volumetric respiration rate determined from ೝೞ Wresp = ଷ where qresp = Specific respirations rate computed above as 0.0794JKg-1h-1 Pp= Density of the onion given as 970kgm-3 Therefore Wresp here becomes ଽ௫Ǥଽସ Wresp = ଷ = 0.02Wm-3 Cp = The specific heat capacity of the product computed above as 3.758x103JKg-10C Kp = The thermal conductivity of the onion given as 0.574Wm-1K-1 Tp = The product temperature = Tp,in and Tp,in = Initial temperature of the product = 28oC t = Time Now, simplifying equation (2.15) i.e. ܲܥ ܲ ܥ ఋ்ು ఋ௧ Taking ൌ ݇ ଶܶ ܹ௦ = ఘ ? ൌ ܥଶ ο் ο௧ ఋ்ು ఋ௧ ൌ ఘ ఋ்ು ఋ௧ ൌ ൫݇ܶ ൯ܹ௦ ଶܶ ܹ௦ ൌ ܥଶଶ ܶ ݍ௦ Now the equation ఋ்ು ఋ௧ ൌ ܥଶ ଶܶ ݍ௦ ………………………… (3.1) Is the heat equation which gives the temperature of a body T(x,y,z,t) of homogenous material where C2 is the thermal diffusivity and ଶ ܶ is the laplacian of temperature Tp with respect to Cartesian coordinates x,y,z . οଶ ܶ ൌ ఋ మ ்ು ఋ మ + ఋ మ ்ು ఋ మ ఋ మ ்ು ఋ మ Kreyszig (2002). Equation (3.1) above can further be expressed as: ϰϱ ఋ்ು ο் ൌ ܥଶ ߜ…………………… ݐ.. (3.2) Where ܥଶ ൌ ఘ = thermal diffusivity of the onion This heat equation is analogous to the heat equation solve by Rajput (2005) since the boundary conditions are that Tp(x,y,z,t) = Tp,ini (X,Y,Z) at t = to as in equation (2.27) thus equation (3.2) above becomes: ் ்ǡ ൌ ݁ భ ி Where Bi = Boit number given by equation (2.25) as = 2 And h = h3 = 4838w/m K K = 0.574Wm-1K-1 The shape of the onion is considered to be a sphere therefore the characteristic length of the onion is: Lc = ோ ଷ where R = Radius of the spherical onion = ? Lc = Ǥସହ ଷ ଼ଵǤଷହ௫ଵషయ ଶ = 0.040675m Thus, = 0.035558m Hence Biot number is evaluated as Bi = ସǤ଼ଷ଼௫Ǥଵଷହ Ǥହସ = 0.114 Fo = Fourier number given by equation (2.26) as F0 = Where D = thermal diffusivity = ఋ Ǥହସ ଽ௫ଷǤହ଼௫ଵయ = 1.575 x 10-7 Thus, F0 = ଵǤହହ௫ଵషళ ௫௧ Ǥଵଷହହଷ଼మ = 8.573 x 10-4 t Therefore equation (2.27) was evaluated as: ϰϲ ఈ௧ మ ் ்ǡ ൌ ݁ ିǤଵଵସ௫଼Ǥହଷ௫ଵ ݁ ିǤଵଵସ௫଼Ǥହଷ௫ଵ షర ௧ ଵ షర ௧ ଶ଼ ? ଵ ଶ଼ షర ௧ ݁ ିǤଵଵସ௫଼Ǥହଷ௫ଵ ൌ ൌ ଵ షర షబǤభభరೣఴǤఱళయೣభబ ൌ ʹͺ -4 0.114 x 8.573 x 10 t = In28 = 3.332 T= ଷǤଷଷଶ hence Ǥଵଵସ௫଼Ǥହ଼௫ଵ షర The cooling time 't =34,093.16s = 9.47h this gives the time required to cool the product from 28 oC to 1oC i.e. cooling rate = ଶ଼ ଽǤସ = 2.9oC/h Therefore the heat removed from the product was then calculated as follows: Neglecting Wresp i.e. ܳௗ௨௧ ൌ ହ௫ଷǤହ௫ଵయ ሺଶ଼ିଵሻ ଷସǡଽଷǤଵ = 148.81W Thus The total heat of the product is = Heat of respiration + sensible heat due to mass transfer + latent heat which is accompanying the mass transfer + heat removed from the product i.e. 3.972 + 3.567.72 + 0.104 + 148.81 = 3,720.606W | 3721W (2) Heat Gain and Service Load This is the heat gain into the storage system through the insulated surfaces caused by the difference between the inside and outside temperatures. Also there is a service load, that is, a heat gain caused by the opening and shutting of the storage system’s door, since the onion will be loaded only once a day, it is safe to assume that the ϰϳ service load is a normal one i.e. the door will be opened less than 5 times per hour. For product storage, cooling, heat and service load is determined from [27]: Heat gain and service load = (Total outside area of cooler) (Maximum outside temperature - minimum inside temperature) (a factor from a given table: refer to Appendix II. i.e. Heat and service load Q = A0 (T0 – Ti)K..................................(3.1) Where A0 = Total outside area determined thus 2(60x10 -2xl50x10-2) + 2(50x10-2x150x10-2) + 2(50x10-2x60x10-2) = 1.8 + 1.5 + 0.6 = 3.92 To = outside temperature = 28°C Ti= inside temperature = 1°C Heat leakage factor, since the storage system was measured to be of 2.5cm insulation thickness then the value of the factor for Heat leakage plus normal service load is given as 0.0012KJ°Cm2 from the table (refer to appendix II). Hence, the heat gain and service load 0 = 3.9(28 - l) x 0.012x103 = 1.263w | = 1.264w. (3) Defrost Heat This is the heat generated as a result of stoppage of equipment operation. An assumed figure of 450W [27] is added to the heat load to serve to take care of defrost heat. Total Heat Load After computing all the above heat loads the total heat load or heat to be removed from the cold storage space is therefore the sum of: Total heat of the product + heat gain and service load + Defrost heat. That is 3721W + 1264W + 450W = 5435W ϰϴ 3.3 Determination of the Refrigeration Capacity Required From literature, the cooling capacity of a refrigeration system that is the rate of heat removal from the refrigerated space is often expressed in terms of tons of refrigeration. The capacity of a refrigeration system that can freeze 1 ton of liquid water into ice at 0°C in 24 hours is said to be 1 ton. And 1 ton of refrigeration is equivalent to 211 Kg/min. This is equivalent to 211 x 60 = 12,660KJ/h. Since the heat load calculated above is 5,435 watts, this implies that: 5435 x ଷ x24 = 469,584KJ/day ଵ Assuming that the refrigeration equipment works 18h/day this implies that 469,584 y 18 = 26,088KJ/h required to be removed. Now since, 1 ton of Refrigeration = 12,660 KJ/h Then 26,088KJ /h is ଶǡ଼଼ = 2.0 tons ଵଶǡ Hence 2.0 tons of refrigeration is required for the storage system. 3.4 Selection and Sizing of Refrigerant and Refrigeration Equipments Before sizing and selection of the refrigeration equipment, the refrigerant was first selected because it is based on the properties of the working fluid that the equipments can be sized. The selection of the refrigerant was based on the following main factors. i. Availability ii. Cost iii. Coefficient of performance (C.O.P) The most commonly and cheaply available Refrigerants encountered in the cause of this project work are R12 and R22 commonly known to the local vendors as Freon 12 and Freon 22. Thus the selection of working fluid is between either of the two available refrigerants. In order to select a ϰϵ refrigerant the temperatures of the two media with which the Refrigerant will exchange heat are considered i.e. the temperature of refrigerated space and that of environment (Room air). From literature it has been mentioned that to achieve a reasonable exchange of heat at the refrigerated space and the environment a temperature difference of between 10°C - 20°C between refrigerant and medium must be maintained. Thus selection of refrigerant was carried out as follows: i. Since desired temperature of refrigerated space is 1°C then temperature of the refrigerant at evaporator must be between 10°C - 20°C lower than the desired temperature of 1°C. ii. The temperature of refrigerant at condenser must be at a level such that room air temperature is less than the temperature of saturation of the refrigerant by a difference of between 10°C to 20°C. The application area of a refrigerant is restricted by critical temperature (tfr) and freezing temperature [28]. Above critical point a refrigerant vapour cannot be condensed and beyond freezing point the liquid does not exist. Hence this means that any refrigerant in application must operate within this temperature range. So using figure from table (refer to appendix III) where the properties of common refrigerants was .given by GutiowsJa, (1996), the refrigerant was selected. The notations used in the table above are defined as follows: qv = Volumetric refrigeration effect at to = -15°C and tk = 30°C to = temperature of evaporation tk = temperature of condensation. n = Thermodynamic efficiency C.O.Pc = Theoretical Coefficient of performance for the reversible Ideal cannot cycle. It depends only on the temperatures. This is given as ϱϬ ் C.O.PC = ሺ்ೖି்బ ሻ To = Temperature of evaporation (K) Tk = Temperature of condensation (K) Then Then C.O.Pc = ଶହ଼ ሺଷଷିଶହ଼ሻ ൌ ͷǤ C.O.P = Actual coefficient of performance of the cycle which Depends on the refrigerants properties and working conditions: 30° condensation temperature and - 15°C evaporation temperature. COP = qo = Refrigerating effect = h1 - h 4 ec = compression work COP = = h2 - h1 Thus భ ିర మ ିభ Kn = Exponent of isentrope of saturated vapour for normal temperature. Snv tn = = normal density of saturated vapor (Kg/m3) normal boiling point (°C), tcr = critical temperature (°C), tfr = freezing temperature (°C), Both R12 and R22 are suitable to be applied for the storage system but R12 was selected because: i. Its value of t n is higher than that of R22 and thus more suitable for a system that requires only cooling to 1°C . ii. Its low toxicity percentage in air compared to R22. The refrigerant, R12 selected is used at the following working conditions. Temperature of evaporation (t0) = -15°C Temperature of condensation (tk) = 30°C Hence: The refrigerant will enter the compressor as a superheated vapour at -15°C. Therefore in order to determine compressor power, a temperature of 50°C ϱϭ which is 20°C higher than the condensing temperature of 30°C is chosen. That is the refrigerant will enter the compressor at -15°C it is then compressed and leave at a temperature of 50°c. The refrigerant is then cooled to a temperature of 30°C and then throttled to the evaporator pressure of 1.826 bar. Thus the properties of the refrigerant from table of thermodynamic and transport properties of fluids arranged by Rogers and May hew are obtained as follows: T1 = -15°C P1 = 1.826 bar h1 = 180.97 KJ/Kg T2 = 50°C P2 = 12.19 bar h2 = 206.45 KJ/Kg T3 = 30°C P3 = 7.449bar h3 = 64.59 KJ/Kg h3 (throttling) = h4 = 64.59 KJ/Kg 3.4.1 Compressor Power Requirement The compressor power requirement was calculated from the expression P = m (h2 - h 1) = mW -------------------------- (3.1) Where m = mass flow rate of refrigerant (kg/s). W = h2 - h1= unit work of isentropic compression (KJ/Kg). While m is expressed as: m = ொబ భ ିర ...............................................................(3-2) Where Qo = Refrigeration Capacity i.e amount of heat required to be Removed from the storage area calculated as 5435 W = 5.44KW. Therefore m = ହǤସସ ଵ଼ǤଽିସǤହଽ = 0.05kg/s ϱϮ Hence P = 0.05 (206.45 - 180.97) = 0.05x25.48 = 1.3kW =1.743hp | 2.0 hp This implies that the coefficient of performance of the refrigerator is COP = ொబ ௐ = ହǤସସ ଵǤଷ = 4.18 W Hence a compressor of 1.3kW power was selected. 3.4.2 Sizing and Selection of Condenser The selection of each type of condenser should be based on the data provided by the manufacturer's catalogue [28]. If the working conditions are out of the catalogue range, it is necessary to carryout analytical calculations based on proper formulae for given heat transfer pattern, and that the necessary heat exchange surface area Ak of a condenser is given by a general formula: Ak = m = ொಽ ሺೖ ିο௧ೖ ሻ …………………………………….. (3.4) Where Qk = The amount of heat to be removed during condensation process and is expressed in terms Q0 and COP as Qk = Qo (1 + COP-1)(kW) = 5.44(l +4. 18 -1) = 6.74kW. Uk = Overall heat transfer coefficient of the condenser (W/m2.K), The following heat flux figures were given by Gutkowski [28] for rough estimation of condenser capacity. Shell and tube condensers, 4,500 - 5000W/m2 Evaporative condensers 1,500 - 2500 w/m2 Air cooled condensers 150 - 200 w/m2 ϱϯ Since for the storage system Air cooled was used a heat flux figure of 165 w/m2 [28] was chosen Thus Uk was determined as: Uk = ு௧௨௫ௐȀమ ௗ௦௧்௧௨ = ଵହ = 0.54w/m2 ଷଷ 'tm = Logarithmic mean temperature difference (LMTD) expressed in (oC) as: οݐ ൌ ο௧భ ିο௧మ ο ூοభ మ Where οଵ and ο ଶ are maximum and minimum temperature difference between cooling medium and condensing refrigerant. The cooling medium temperature is Room air temperature taken as 28°C, condensation temperature of refrigerant is 30°C its temperature when entering the condenser is 50°C. This is represented in LMTD graph thus: ϱϰ Fig: Graphical Representation for Determining LMTD οݐ ൌ ͵ʹ െ ʹ ͵ʹ ݊ܫ ʹ = 10.8°C hence the heat exchange area of the condenser is ܣ ൌ Ǥସ = 1.15m2 Ǥହସ௫ଵǤ଼ Thus a condenser with the calculated area was selected. 3.4.3 Sizing and Selection of Evaporator As for condenser the necessary heat exchange surface area of an evaporator is given by a general formula for heat exchangers. ܣ ൌ ொ …………………………………………… (3.5) ο௧ Where U (W/m2. K) is the overall heat transfer coefficient of an evaporator in this case also figures were given by Gutkowski [28] , for R22 at heat flux of 1000 W/m2 and mentions that for ammonia, the values are much bigger than for R22 and for R22 are lower. Dry evaporators 350 W/m2.K Flooded evaporators 450 - 500 W/m2.K Wet evaporators 750 W/m2.k Considering the evaporator used is a dry evaporator a figure of 350 2 W/m was chosen Thus, U = 350W/m2. 'tm = is logarithmic mean temperature difference calculated by means and Qo = heat removed by the evaporator in (W) of the same formula as for condensers. Thus = 10.8°C Therefore ܣ ൌ ହସଷହ ଷହ௫ଵǤ଼ = 1.43m2 ϱϱ = 5435W Therefore an evaporator having heat exchange surface area of 1.43 m2 was then selected. 3.4.4 Refrigerant Piping The selection of return pipe diameter must always be based on the vapor flow resistance. This resistance causes static pressure drop along the flow which must not exceed the corresponding difference in saturation temperature of 2°C [28]. The total pressure drop is the sum of the pressure drop in piping. The pressure drop in the above apparatus is given in the manufacturer's catalogue. The pipes used were selected based on compatibility with compressor and condenser size. 3.4.5 Selection of Expansion Valve The selection of all expansion devices should be strictly based on manufacturer's catalogue with consideration to refrigerant, refrigerant capacity and operating conditions [28]. Based on this statement the automatic expansion valve was selected because of its principle of operation which is based on the difference between atmospheric pressure and pressure of evaporation. The evaporation pressure to open the valve is always pre-set in a factory for a given refrigerant and indicated in the catalogue. 3.5 Construction, Testing and Cost Analysis After the design calculations were conducted and the figures obtained were used to select components, the construction of the storage system was carried out. 3.5.1 Physical Description of the Storage System The storage system is a container of length 60cm (2ft), Breadth 50cm (1ft 20") and height 150cm (4ft 59") the container is fitted with insulation between the inside and outside surfaces of thickness 2.5cm. Onions are stored ϱϲ inside system at the recommended temperature and relative humidity which are 1°C and 87% respectively. In order to achieve and maintain this temperature a vapor-compression refrigeration unit, comprising of compressor, condenser, expansion valve and an evaporator was incorporated to the system size of which was determined from the total heat load calculated. The source of power utilized is electricity. The system is also fitted with two thermometers one giving dry bulb temperature of storage area while the other is giving the wet bulb temperature. The two readings were used to determine the relative humidity of storage area. The system was also fitted with small containers inside the storage area containing soda lime and silica gel. Their purpose is to control respiration rate of onions thereby preventing them from shrinking and loosing their quality. 3.5.2 Components of the System The system can be divided into two main parts namely: i. The storage container ii. The refrigeration unit. i. The Storage Container: An old scrap household refrigerator of dimension 60cmx50cmx 150cm, thickness 2.5cm was used as the storage container. The storage area was divided into five shelves using wooden plates. On both sides of each shelve perforated containers were fitted to the wall in which soda lime and silica gel were placed inside to absorb the carbon dioxide and moisture produced. Wet and dry bulb thermometer was fitted to the door of the container which protrudes through the door and then covered with glass from the outside such that readings can be taken from outside without opening the door. The description of the container is as shown in figure 3.1(a and b). ii. The Refrigeration Unit: This unit comprises of the following components ϱϳ i. The Compressor: This is a 2.0 hp compressor, selected and bought based on figure obtained from design calculations. It was mounted at back and bottom of constructed container. The compressor was powered by electricity. Its description is as shown in fig (3.6). ii. The Condenser: This is also selected based on the figures calculated compatible with the compressor. It was mounted close to compressor with a fan to increase condensing efficiency of the condenser. Its description is as shown in fig (3.7) while installation arrangement of compressor and condenser is as shown in figure (3.4b) iii. Expansion Valve: This is an automatic expansion valve it was selected based on its compatibility with evaporator and above mention components. Its description is as shown in Fig (3.5). iv. Evaporator: This is also selected based on figures calculated compatible with other components. Its description is as shown in fig (3.8). 3.6 Testing of the Storage System After construction the storage system was tested using 10kg of onions which were placed into the middle shelf, after allowing the storage system to reach the storage temperature of 1°C. simultaneously another 10kg of onions were kept outside in open air. This arrangement was monitored for a period of 4 months during which the following information or data were collected each day. i. Mass of onions in control storage and onions in open air and their average value recorded. ii. The dry bulb temperature of storage area was measured three times daily and their average value recorded. ϱϴ iii. The wet bulb temperature of storage area was measured three times daily and their average value is recorded. iv. The relative humidity of the storage area, using the dry and wet bulb temperatures obtained above from wet and dry thermometer chart was measured three times daily and their average value is recorded. v. The carbon dioxide production rate of onions in control and in open air storage using the regression fit given by equation (2.3) ݉మ ൌ ݂ ൬ ௫ ͻܶ ͵ʹ൰ ሺ݉݃݇݃ିଵ݄ିଵሻ ͷ Where Tm = Average dry bulb temperature recorded daily. ϱϵ ϲϬ Fig. 3.1b: Pictorial View of the Storage System ϲϭ Fig. 3.2 (a and b): Sectional View of the Storage System Showing Onion in Storage and Chemical Containers Respectively ϲϮ Section X – X Fig. 3.3: Sectional View of the Storage System Showing Evaporator ϲϯ ϲϰ ϲϱ 3.7 Cost Analysis The cost involved in production of the storage system can be divided into the cost of materials and labor cost. The cost of materials is summarized as shown in the table below: TABLE 3.2: Summary of Cost Analysis S/N Material Description Unit Total Cost Required Cost(N) (N) 1. Pomeka wood sheet (60 x70 x 160)cm 1 sheets 4,500 4,500 2. Insulation material (fiber glass)kg 1kg 200 200 3. Plastic lining sheet (70x80cm) 5 sheets 700 3,500 4. Wet and Dry thermometer (a pair) °C 1 number 1,100 1,100 5. Soda lime 2kg 500 1000 6. Silica gel 1kg 500 1000 7. Compressor (2.0 hp) 1 number 4,500 4,500 8. Condenser (compatible with item 7) 1 number 1,500 1,500 9. Expansion valve (compatible with item 7) 1 number 150 150 10. Evaporator (compatible with item 7) 1 number 4,500 4,500 11. Refrigerant 12 1kg 1,100 1,100 12. ½ inch Nails 1kg 200 200 13. 5mm screws 1kg 100 100 14. 1 inch angle bar (2 x l)cm 1 number 1,500 1,500 15. Electrode (gauge 12) 10 number 10 100 16. 5mm Rivet 1 packet 1,200 1,200 TOTAL 22,260 ϲϲ Quantity 26,150 Labour Cost Labour cost is 10% of total cost of material i.e. ଵ ଵ ʹݔǡͳͷͲ = N2,615:00 Over head Cost is 5% of total cost of materials i.e. ହ ଵ ʹݔǡͳͷͲ = N1,307:50 Therefore the Overall total cost is Cost of material + Labor Cost + Overhead cost. i.e. N26, 150:00+ N2, 615:00+N1, 307.50:00 = N30,072.50 ϲϳ CHAPTER FOUR DATA PRESENTATION AND ANALYSIS 4.0 RESULTS FROM TESTING OF STORAGE SYSTEM: During the testing of the storage system readings within and outside the storage system were measured. The results obtained from these reading were presented, in the table below. Each data presented is aN average value of three days reading. The symbols used in the table below are defined as follows: A = Average mass of onions in control storage (kg) B = Average mass of onions in open air (kg) C - Average dry bulb temperature of storage area. (°C) D = Average wet bulb temperature of storage area (°C) E = Average relative humidity within storage area obtained from wet and dry thermometer chart, (refer to appendix I) Q = Average carbon dioxide production rate of onions in Control using equation (2,3) given as: ݉మ ൌ ݂ ൬ ௫ ͻܶ ͵ʹ൰ ሺ݉݃݇݃ିଵ݄ିଵሻ ͷ Where F And x are respiration co-efficient for onions given in table (2.4) as f = 3.668 x 10-4 and g = 2.538. Tm is the average temperature of the onions in storage and in control. Z = Average carbon dioxide production rate of onions in storage determined using the same formula as above. Tmc = Average temperature of onions in open air. Tms = Average temperature of onions in control storage. ϲϴ Table 4.0: Summary of readings obtained during testing of the storage System Date A B Kg Kg C D E o o % C C Tmc o C Q Tms Mgkg -1h-1 o C Z Loss Loss Mgkg -1h-1 in Wt in Wt for A for B kg kg 1 2.78 0 0 29.79 1 2.78 0 0.001 29.79 1.50 2.97 0 0.001 30 29.79 1.50 2.97 0.001 0.002 30 29.79 1.50 2.97 0.001 0.002 80 30 29.79 1.50 2.97 0.001 0.002 80 30 29.79 1.50 2.97 0.001 0.002 1 80 30 29.79 1.50 2.97 0.001 0.002 1.50 1 80 30 29.79 1.50 2.97 0.001 0.002 1.50 1 80 30 29.79 1.50 2.97 0.001 0.002 9.078 1.50 1 80 30 29.79 1.50 2.97 0.001 0.003 9.075 1.50 1 80 30 29.79 1.50 2.97 0.001 0.003 24/3/06 9.090 9.072 1.50 1 80 30 29.79 1.50 2.97 0.001 0.003 27/3/06 9.089 9.068 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 30/3/06 9.088 9.064 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 2/4/06 9.087 9.060 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 5/4/06 9.086 9.056 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 8/4/06 16/2/06 10.000 10.000 1 0 80 30 29.79 19/2/06 10.000 9.099 1 0 80 30 22/2/06 10.000 9.098 1.50 1 80 30 25/2/06 9.099 9.096 1.50 1 80 28/2/06 9.098 9.096 1.50 1 80 3/3/06 9.097 9.093 1.50 1 6/3/06 9.096 9.090 1.50 1 9/3/06 9.095 9.087 1.50 12/3/06 9.094 9.084 15/3/06 9.093 9.081 18/3/06 9.092 21/3/06 9.091 9.085 9.052 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 11/4/06 9.084 9.048 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 14/4/06 9.083 9.044 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 17/4/06 9.082 9.040 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 20/4/06 9.081 9.036 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 23/4/06 9.080 9.032 1.50 1 80 30 29.79 1.50 2.97 0.001 0.004 26/4/06 9.079 9.028 2.00 1 81 30 29.79 2.00 3.17 0.001 0.004 29/4/06 9.078 9.024 2.00 1 81 30 29.79 2.00 3.17 0.001 0.004 1/5/06 9.019 2.00 1 81 30 29.79 2.00 3.17 0.001 0.005 9.077 ϲϵ 4/5/06 9.076 9.013 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 7/5/06 9.075 9.007 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 10/5/06 9.074 9.001 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 l#/5/06 9.073 9.095 2.00 1 81 #0 29.79 2.00 3.17 0.001 0.006 16/5/06 9.072 9.088 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 19/5/06 9.071 9.082 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 22/5/06 9.070 9.076 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 25/5/06 9.069 9.070 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 28/5/06 9.068 9.064 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 31/5/06 9.066 9.058 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 3/6/06 9.064 9.052 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 6/6/06 9.062 9.036 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 9/6/06 9.060 9.030 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 12/6/06 9.058 9.024 2.00 1 81 30 29.79 2.00 3.17 0.001 0.006 TOTAL 4.1 0.037 0.162 Data Analysis and Inferences From the data presented in the table above two parameters of major interest are carbon dioxide production rate (Respiration rate) of onions in storage and their loss in weight. The data indicated that respiration rates of onions in control storage varies between 2.78mgkg-1h-1 and 3.17mg kg-1 h-1 over the period through which the experiment was conducted at the storage temperature (averagely 1 to 2°C), a comparison of this response to that of normal respiration rate of onions, Fig (4.0) suggests that onions respire much more slowly under control storage condition than when stored in open air. As shown respiration rates of onions has been slowed by about 9 times under control storage system's conditions. Analysis of loss in weight of onions stored in the constructed system and those in open air was carried out thus: Total average loss of weight in onions exposed to open air = 0.162kg. Therefore percentage weight loss was calculated as: ϳϬ ͲǤͳʹ ܺͳͲͲ ൌ ͳǤʹΨ ͳͲ Total average loss of weight in onions in control storage =0.037kg. Therefore percentage weight loss was calculated as: ͲǤͲ͵ ܺͳͲͲ ൌ ͲǤ͵Ψ ͳͲ Weight loss measurement studied in this work was presented in fig. (4.1). It was found that weight loss in onions stored in open air is higher, with a total of 0.162kg loss over the period of storage; constituting about 1.62% monthly, while loss in weight of onions in control storage is lower with a total of 0.037kg loss over the period of storage constituting an average of about 0.37%) monthly. In a similar work, 9% weight was reported [29], on onions stored using combination of refrigerated and controlled atmosphere storage over a period of 7 months after which the onions were considered marketable. Brice [30] also reported that weight loss under cool controlled atmosphere storage is limited to 15% over 7 months compared with 40% typical of onions held under heated forced air ventilated storage in tropical environment. Therefore from results obtained using the storage system constructed it is inferred that for onions stored in the constructed system a forecast of a loss of only 2.59% after seven months is expected, hence an indication of good result from combination of cold and controlled atmosphere storage of onions. Relative humidity in storage system remained constant at 80% with only an increase by 1% percent after 23 days. After which it remains the same throughout the experiment this is as shown in figure (4.2). ϳϭ ϳϮ ϳϯ ϳϰ CHAPTER FIVE CONCLUSION AND RECOMMENDATION 5.0 Conclusion Based on the results obtained and analyzed as shown in the previous chapter, the following conclusions were reached. (1) That with a forecast of 2.59%, approximately 3% weight loss of onions if stored in the constructed system for seven month, about 97% of onions will be available for marketing. (2) That the achievement of the forecast above may depend on the size of the storage system. (3) That a combination of refrigeration and controlled atmosphere is a very efficient method for onion storage. 5.1 Recommendation Following the above conclusion it is therefore recommended that: (1) The storage system's capacity be increased or developed to room sizes to accommodate more onion bulbs. (2) A different and more accurate method of measuring carbon dioxide production rate of onions should be developed and used 5.2 Suggestions for Further Studies The followings are hereby suggested for further studies. (1) Similar storage system should be designed and constructed using absorption refrigeration system or solar energy. (2) Similar storage system should be developed for other crops like Tomatoes, e.t.c. ϳϱ Plate 1: Frond view of the constructed storage system ϳϲ Plate II: Side view photograph of the constructed storage system ϳϳ REFERENCES 1. Thompson A.K., Booth R.H. and Proctor. F.J. (1972) "Onion Storage in the tropics". Tropical Science 14(1): 19-34 2. Brewster J.L. (1994) "Onions and other vegetable Alliums" C.A.B. International Publishers Walling Ford UK. 3. Linus, U.O. and Martin G. (1999) "Economic importance of onion. In CIGR Handbook of Agricultural Engineering 4:127,132,138,346 4. Amuttiratana, D. and Passornsiri W. (1992) "Post harvest losses of vegetable". A workshop held between 17 and 22 October at Pakistan Agricultural Research Council Islamabad 5. Van Kampen J. (1970) "The improvement of available onion varieties" Zaadbelangen 24:135 - 139 6. Woodman R.M and Barnett, H.R. (1937) "The connection between the keeping quality of commercial verities of onions and rates of water loss during storage" Ann. App. Biol 24:219 - 235 7. Fosket, R.L. and Petterson, C.E. (1950) "Relation of dry matter content to storage quality of some onion varieties and hybrids" proc. Amer. Soc. Hort. Sci 55:314. 8. Hanaoka, T and Ito, K (1957) "studies on the keeping quality of onions. In Relation between the characters of the bulb and their spouting during storage. Japanese Hort. Ass. Jour. 26:129-136. ϳϴ 9. Magruder, E. et al (1941) "Storage qualities of principal varieties of American onions U.S. Dept of Agriculture circ. 619. 10. Robinson, IE. et al (1975) "Storage characteristics of some vegetables and soft fruits" Biosource Tech 81:339 11. Oberbanscheidt, B. et al (1996) "Studies on respiratory rates of onions in storage" Gemiise 32:492 - 496. 12. Karmakar, D.V. and Joshi, B.M. (1941) "Investigations on the storage of onions" Indian Journal of Agricultural Science 11:82 - 94. 13. Kapur, N.S. et al (1953) "Cold storage of onions" Indian Journal of Horticulture 10:9-38. 14. Stow IP. (1975) "Effects of humidity of losses of bulb onions" Experimental Agriculture Journal 11:81 - 87 15. Thompson A.K. (1996) "Post harvest technology of fruits and vegetables" Blackwell science publishers London. 16. Cengel, Y.A. and Boles, M.A. (1998) "Thermodynamics; a. Engineering approach", Third edition by McGraw hill companies inc. Princeton Road U.S.A. www.mnhe.com. 17. Becker, R.B. and Frickle, B.A. (1996)( "Simulation of moisture loss and heat loads in refrigerated storage f fruits and vegetables. In refrigeration science and technology proceedings, October 2-4, 1996, Lexington KT. ϳϵ 18. De Baerdmaeker J. et al (1999) "Root crop quality and loses in CIGR Handbook of Agricultural engineering 4:72, 74, 76 19. Diso IS. (2004) "Lecture note on Advance Thermohydraulics" Department of Mechanical Engineering Bayero University Kano Nigeria. 20. 21. Rahman, S. (1995) "Food properties Handbook" CRC Press U.K. Bird, B.B. et al (1960) "Transport Phenomena" John Wiley and Sons Publishers, Wallingford U.K. 22. Ozisick, M.N. (1980) "Heat conduction" John Wiley and sons publishers, New York U.S. A. 23. Scheerlink, N. et al (1996) "Finite element analysis of coupled heat and mass transfer problems with random field material properties". In American society of Agricultural engineers (ASAE) Standards Handbook paper No. 963028 24. Nicholai, B.M. et al (1995) "Finite element analysis of heat conduction in Lasagna during thermal processing" International Journal of Food Science Technology 30:347 - 354 25. Rajput, R.K. (2005) "Heat and Mass transfer" Chand and company limited New Delhi 110055 India 26. Thompson, J.F, (1999) "Cold storage system" In CIGR Handbook of Agricultural Engineering 4:349 ϴϬ 27. Tyler, G.H. and David, S. (1985) "Standard hand book of Engineering calculations" second edition McGraw Hills Book Company New York U.S.A. 28. Gutkowski. R.K. (1996) ''Refrigeration and Air conditioning "Spectrum Books Limited. Ibadan Nigeria. 29. Smittle, DA (1989) "Controlled atmosphere storage of Vidalia onions "In Internationa! controlled atmosphere conference 5th proceeding, wantchees washing U.S.A. Vol. 2 30. Brice, J. et al (1997) "Onion storage in the tropic" In a practical guide to methods of storage and their selection Chatham U.K. National Resource Institute. ϴϭ APPENDIX I DRY AND WET THERMOMETER TABLE Humidity Table in ConUlgrade Humidity Table in Fahrenheit Balance Wet A dry Point Balance Wet A dry Point 0 1 2 3 4 5 6 7 8 9 10 Wet Point 0 1 2 3 4 5 * 6 7 8 9 10 Wet Point 0 80 63 49 37 28 20 13 8 4 46 100 91 84 76 70 64 59 53 49 44 40 1 81 65 51 4030 22 18 11 7 4 47 100 91 84 78 70 64 59 54 49 45 41 2 82 66 53 4233 25 19 14 10 6 48 100 91 85 77 71 65 €0 54 504642 49 100 91 85 77 71 65 61 55 51 46 42 83 67 55 44 35 27 21 16 12 9 50 100 92 85 78 72 66 61 56 52 47 43 4 83 6956 463/30 24 19 14 11 51 100 92 85 78 73 66 62 57 53 48 44 5 84 70 58 4839 32 26 21 17 13 52 100 92 85 78 73 67 62 57 53 49 45 6 84 71 59 4941 34 28 23 19 IS 3 53 100 92 86 79 73 68 63 SB 54 50 46 54 100 92 86 79 74 68 63 58 54 50 46 55 100 92 86 80 74 69 64 59 55 51 47 7 85 72 61 51 43 36 30 25 21 17 56 100 92 86 80 74 69 64 60 56 51 48 8 85 73 62 52 44 37 32 27 23 19 57 100 92 87 80 75 69 85 60 58 52 48 9 86 74 83 54 46 39 33 28 24 21 58 100 93 87 80 75 70 65 61 57 5349 59 100 93 87 81 76 70 66 61 57 53 49 10 86 74 64 5547 41 35 30 26 23 60 100 93 87 81 76 70 66 62 58 54 50 11 67 75 65 5649 42 36 32 28 24 61 100 93 87 81 76 71 67 62 58 54 51 12 87 76 66 57 50 43 38 33 29 28 62 100 93 88 81 77 71 67 63 59 55 51 63 100 93 88 82 77 72 68 63 59 55 52 13 87 76 67 58 51 45 39 34 30 27 64 100 93 88 82 77 72 68 64 60 55 52 14 68 77 68 59 52 46 40 36 32 28 65 100 93 88 82 77 72 68 64 60 56 53 15 88 78 68 6053 47 42 37 33 2$ 66 100 93 88 82 78 73 69 64 60 58 53 67 100 93 88 82 78 73 69 65 61 57 54 68 100 94 88 83 78 73 69 65 62 57 54 69 100 94 89 83 78 74 70 65 62 58 55 16 88 78 69 61 54 48 43 38 34 36 17 89 79 70 6255 49 44 39 35 31 70 100 94 89 83 79 74 70 68 82 58 55 18 89 79 70 6356 50 45 40 36 32 71 100 94 89 83 79 74 70 66 63 58 55 19 89 80 71 6357 51 46 41 37 33 72 100 94 89 83 79 74 71 66 63 59 56 20 89 80 72 64 58 52 47 42 38 34 73 100 94 89 84 79 75 71 67 63 59 56 74 100 94 89 84 80 75 71 87 64 60 57 ϴϮ 75 100 94 89 84 80 75 78 67 64 60 57 21 90 8072 6558 53 47 43 39 35 76 100 94 89 84 80 75 72 68 6461 57 22 90 81 73 66 59 53 48 44 40 36 77 100 94 90 84 80 76 72 68 65 61 58 23 90 81 73 6660 54 49 45 40 37 78 100 94 90 84 80 76 73 88 65 61 5fl 24 90 82 74 67 60 55 50 45 41 38 79 100 04 90 85 80 76 73 68 65 62 58 80 100 94 90 85 81 76 73 89 66 62 58 25 90 82 74 6761 56 50 46 42 38 81 100 94 90 85 81 77 73 69 68 62 59 28 91 82 75 6862 56 51 47 43 39 82 100 94 90 85 81 77 73 69 66 62 59 83 100 94 90 85 81 77 73 69 86 63 59 27 91 83 75 6862 57 52 47 43 40 84 100 85 90 85 81 77 74 70 67 63 60 28 91 83 75 6963 57 52 48 44 40 85 100 95 90 95 82 77 74 70 87 63 6O 29 91 63 76 6963 58 53 49 44 41 86 100 95 90 86 62 78 74 70 87 83 80 30 91 83 76 7064 58 S3 49 45 41 87 100 95 90 88 82 78 74 70 87 64 61 88 100 95 90 86 82 78 74 71 68 64 $1 89 100 95 91 86 62 78 75 71 68 64 61 31 91 83 76 7064 59 54 50 45 41 90 100 95 91 86 82 78 75 71 68 64 62 32 91 84 77 7065 59 54 50 45 42 91 100 95 91 86 83 78 75 71 68 65 62 33 92 84 77 71 65 80 55 51 46 43 92 100 95 91 86 83 78 75 72 68 65 62 34 92 84 77 71 65 60 55 51 46 44 93 100 95 91 86 83 79 75 72 69 65 62 94 100 95 91 87 83 79 75 72 69 65 62 95 100 95 91 87 83 79 76 72 69 66 63 35 92 84 78 71 65 61 56 51 47 44 ϴϯ leakage plus SOURCE: (27) normal service load Heat Heal leakage only 0.216 0.178 1 0.163 0.127 2 0.110 0.079 4 0.090 0.059 6 In 0.077 0.046 8 0.069 0.038 10 0.0012 0.0010 2.5 0.0009 0.0007 3.1 Insulation thickness 15.2 0.0006 0.0005 0.0005 0.0003 10.2 cm Btu and kJ degree temperature difference per ft (m ) of outside surface Heat Leakage Factors APPENDIX II 0.0004 0.0003 20.3 0.0004 0.0002 25.4 ϴϱ -180.0 -160.0 -100.0 R 13 R22 R502 -45.56 -40.8 -81.5 -29.8 23.7 -33.35 82.2 96.0 28.78 112.04 197.78 132.4 1.125 1.195 1.170 1.122 1 .904 1.3 2086.76 2097.5 N.A 1281.7 203.63 2168.7 6.25 4.77 N.A 6.2 5.88 0.8613 0.76 0.81 N.A 0.82 0.89 0.83 NIL NIL NIL NIL NIL Very limited Aluminium plastics except tephlon Magnesium zinc, lead 40 Plastics except tephlon (T) (T) 40 30 Lead tin zinc aluminium natural rubber 20 Zinc natural rubber Copper with its alloys Reactivity with materials (T) (T) 40 (L) 0.25 in air %hr in air % 16-25 Toxic concentration Explosive concentration Appendix III: Properties of Common Refrigerants Refrigeration and air conditioning ppg 15. % hrs - time exposition in hours to refrigerant in (L) - Lethal in %, (T) -Toxic in %, Source: Gutkow -15.1.0 -111.0 R11 R 12 -77.9 R 717 Refrigerants