Electron Configuration Part 2 Intro- answer the following questions concerning Potassium (K) 1. How many valence electrons does it have? 2. Do a sketch of its atom (Bohr model) showing the electron shells Wave (Quantum) Mechanical Model of the Atom The electron does not have an exact orbit around the nucleus (like Bohr’s model). -atomic orbital is where an electron is 90% likely to be found. Electron configuration Describes the location of electrons in an atom Composed of energy levels, sublevels, and electrons Looks like… For Titanium (Ti): 1s22s22p63s23p64s23d2 Energy level Its the same number as the period The bigger the energy level, the further the electrons are from the nucleus, and the more energy they have. Sublevels Each orbital can only hold 2 electrons (pauli exclusion principle), so each sublevel has a different number of orbitals sublevel s p d f # orbitals Total # electrons Shapes of orbitals There is 1 spherical shaped s orbital, so the s sublevel can hold 2 electrons. There are 3 dumbbell shaped p orbitals so p sublevel can hold 6 electrons There are 5 d orbitals so 10 electrons can fit in the d sublevel There are 7 f orbitals so 14 electrons can fit in the f sublevel) AUFBAU PRINCIPLE- each electron will occupy the LOWEST energy level available So they fill orbital in a certain order… - Notice the number of electrons that fit in a sublevel relates to the block! - color the blocks different colors to see the difference! AUFBAU PRINCIPLE- each electron will occupy the LOWEST energy level available So they fill orbital in a certain order… - notice the d block is one energy level behind - notice the f block is 2 energy levels behind - follow the arrows until you get to your element Using the chart on the last page and your periodic table answer the following questions… 1. How many electrons can be placed in the 2s sublevel? 2. How many electrons can be placed in the 3d sub? 3. A total of eighteen electrons can be placed into the 3rd energy level. Explain WHY. 4. A total of 32 electrons can be placed into the 4th energy level. Explain WHY. Electron Configuration notation - - This method designates the principle energy level, the sublevel, and the number of electrons in each sublevel. For example Fluorine: - 1s22s22p5 Determine the element for each electron configuration in the table: Electron configuration 1s22s1 1s22s22p3 1s22s22p63s23p5 1s22s22p63s23p64s23d6 1s22s22p63s23p64s23d104p2 1s22s22p63s23p64s23d104p65s24d105p4 1s22s22p63s23p64s23d104p65s24d105p66s25d14f9 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f3 Element Refer to the following electron configuration and answer the questions below: 1s22s22p63s23p64s23d5 a. How many total electrons does this element have? b. What element is this? c. How many energy levels are represented? d. How many sublevels are represented? Write the electron configuration for each element: Mg: Au: Mg 1s22s22p63s2 Au 1s22s22p63s23p64s23d104p65s24d105p66s2 4f145d9 PAULI EXCLUSION PRINCIPLE- Because electrons spin, two can occupy one orbital as long as they are spinning oppositely. HUND’S RULE- within a certain sublevel, single electrons are placed one at a time in orbitals with spins of the same direction, and then will double up with electrons spinning the opposite direction. Example of Carbon (6 electrons) Electron configuration for Orbital Box diagrams: - Each arrow represents an electron Ex. Oxygen Atomic number = 8, so 8 electrons. Start with s, then fill up orbitals as you go. ↑↓ ↑↓ ↑↓ ↑ ↑ 1s 2s 2px 2py 2pz Fill in the box diagram for Fluorine 1s 2s 2px 2py 2pz Draw a box diagram for each of these elements: 1. He 2. N 3. Na 4. P Shorthand electron configuration You can use the noble gases to help make electron configuration easier to do. First identify the noble gas (Group 8A) that is right BEFORE the element. Write that noble gas symbol in [brackets] Then write the rest of the configuration. Ex. Na: 1s22s22p63s1 or [Ne]3s1 examples: shorthand electron configuration 1. Mg [Ne]3s2 2. Al [Ne]3s2 3p1 3. Sn [Kr] 5s24d105p2 4. Br [Ar] 4s23d104p5 5. Po [Xe]6s24f145d106p4