Arabian Journal for Science and Engineering (2019) 44:417–428 https://doi.org/10.1007/s13369-018-3476-8 RESEARCH ARTICLE - EARTH SCIENCES A Modified Approach for Volumetric Evaluation of Shaly Sand Formations from Conventional Well Logs: A Case Study from the Talhar Shale, Pakistan Muhsan Ehsan1,2 · Hanming Gu1 · Zulfiqar Ahmad3 · Malik Muhammad Akhtar4 · Saiq Shakeel Abbasi1 Received: 4 May 2017 / Accepted: 15 July 2018 / Published online: 4 August 2018 © King Fahd University of Petroleum & Minerals 2018 Abstract In potential shale-gas basins, due to limited data availability, volumetric evaluation of shaly sand formations is a challenging task for researchers, as well as for exploration and production companies, with the use of conventional well logs. This paper is intended to provide a better understanding of volumetric evaluation in unconventional shaly sand formations. Petrophysical parameters derived from conventional well logs play a significant role in the volumetric estimation of shale. The assessment was performed using numerical equations, well log indexes, and cross-plot analysis. Deep and shallow resistivity logs overlap with each other; this phenomenon indicates that the Talhar Shale in Pakistan can be considered to be an unconventional formation. The average values of shale volume, total porosity, effective porosity, and matrix volume are 29, 16, 12, and 59%, respectively. The Talhar Shale is dominantly characterized by intergranular porosity. It has been observed that at low shale volumes (10–20%), porosities (total and effective), and resistivity measurements (deep, shallow, and microlaterolog), well log signatures have close contents with the shale volume. In contrast, for the remainder of the shale volume, there is significant separation of log signatures. Well log indexes indicate significant responses in 10–20% shale volume zones. Keywords Shaly sand formations · Volumetric shaly sand evaluation · Gamma ray logs · Porosity logs · Resistivity logs · Well log indexes 1 Introduction B Muhsan Ehsan muhsanehsan98@hotmail.com Hanming Gu guhanming@263.net Zulfiqar Ahmad fz97@hotmail.com Malik Muhammad Akhtar drmalikma21@gmail.com Saiq Shakeel Abbasi saiqshakeel@gmail.com 1 Institute of Geophysics and Geomatics, China University of Geosciences, No 388 Lumo Road, Wuhan 430074, Hubei, People’s Republic of China 2 Department of Earth and Environmental Sciences, Bahria University, Islamabad, Pakistan 3 Office of Research Innovation and Commercialization (ORIC), University of Wah, Wah Cantt, Pakistan 4 Department of Environmental Sciences, FLSI, Balochistan University of Information Technology, Engineering and Management Sciences (BUITEMS), Quetta, Pakistan Most of the developing countries are in the midst of worst energy crises. Currently, to meet the world’s energy requirements, exploration and production companies and researchers are focusing on unconventional hydrocarbon resources. Previously, data were acquired in potential shalegas basins for conventional oil and gas resources. Geoscientists are now facing challenges to accurately evaluate shale volumetric data, due to their limited availability in these basins. Conventional well logs are being used to estimate and evaluate shale-gas potential. Geoscientists are trying to perform volumetric evaluations of shale by applying theoretical and deterministic or statistical methods. Fortunately, conventional well logs can be utilized for this purpose in the absence of advanced logs and lithologic analysis of core samples. Mainly, the challenges exist due to the lack of knowledge about porosity, matrix volume, and shale content in geological formations [1]. The typical behavior of conventional well logs, i.e., natural gamma ray, neutron porosity, resistivity, 123 418 Arabian Journal for Science and Engineering (2019) 44:417–428 bulk density, and sonic logs, is used to identify shale-gas reservoirs with an integrated approach. Researchers suggest that the trend of these logs in shale-gas-bearing geological formations is helpful in the volumetric evaluation of shale [2–5]. Researchers are mainly focused on shale-gas interpretation models which are developed on the basis of a significant criterion and rules for volumetric evaluation of shale from conventional well logs in the absence or lacking of geochemical and other modern-day logs [6–8]. Cross-plot analyses and numerical equations are helpful for better understanding of formation evaluation [9]. Several types of deterministic linear and nonlinear approaches are applied on well logs data for the estimation of the volume of shale [10–12]. Szabó and Dobróka [13] conducted a study on the regional basis to check the validity of a new multivariate statistical method using nonlinear deterministic methods on different sedimentary basins data sets. Findings of volume of shale using the deterministic method on single well log give accurate and reliable results, but provide the information of only one measured variable. Integrated study of more well logs sensitive to volume of shale using empirical formulas provides more accurate estimation [12–15]. This study entails the latest techniques used for volumetric evaluation of shaly sand formations. Conventional well log data are extensively studied to check the behavior of volume of shale on well logs numerical values and their indexes. Well log indexes can be used to identify thin and low shale volume beds. The estimation of volume associated with different components of the shale-gas reservoir including porosity, volume of shale, and solid rock fraction plays a key role in the evaluation of unconventional hydrocarbon resources. It is mandatory to actively consider all of these parameters when dealing with this kind of reservoir because the porosity system becomes very complex due to the development of natural fractures porosity along with intragranular porosity of host matrix rock. As the sedimentary rocks contain different volumes of shale, porosity, and matrix, the theoretical value of volume falls between 0 and 1. The unit volume of rock is divided into three parts, i.e., effective porosity, shale volume, and matrix volume of rock for the material balance equation. The purpose of this study is to introduce a quick scheme to volumetric evaluation of shale by applying the numerical equations, well log indexes, and cross-plot analyses on conventional well log data in the absence of XRD data and other modern-day logs like nuclear magnetic resonance measurements, and image logs, etc. Techniques are adopted for volumetric evaluation of shale from several conventional well logs for Talhar Shale. This study is a milestone for researchers and exploration and production companies, which are working in potential shale-gas basins, to achieve a better understanding of hydrocarbons structures of shaly sand formations with the available conventional well logs 123 data. The present study demonstrates an efficient approach to the volumetric evaluation of unconventional shaly sand formations by conventional well logging data. 2 Geological Settings The Southern Lower Indus Basin is geographically located in the Sindh province (SE) of Pakistan. It is extended approximately between 24 and 28◦ N and 66◦ E to the southern boundary of Pakistan as illustrated in Fig. 1a. In a broader view, it is a north–south trending sedimentary basin. Its width is approximately 250 km and remained relatively stable during Mesozoic [18]. Major oil and gas wells are drilled in the western side of basin because tectonic subsurface structures are favorable for the accumulation of hydrocarbons in the strata of Mesozoic. Normal faulting which formed horst and graben geometry was observed [19,20]. In the study area, major oil and gas production is extracted from Mesozoic to Cenozoic sedimentary rocks. The contribution of Mesozoic is more significant and almost 76% of production in the Southern Lower Indus Basin comes from Mesozoic rocks, while only 24% from Cenozoic rocks [21]. Current research focuses on volumetric evaluation of shale in Mesozoic sedimentary formation. By William [22], the name Goru Formation of Cretaceous age was introduced. Lower Goru Formation is distributed in the entire Indus Basin as described in Fig. 1b. Based on lithological information, the Goru Formation has been divided into Lower Goru and Upper Goru formations. Cretaceous petroleum plays a significant role from hydrocarbon exploration point of view. Lower Goru Formation is a sandstone reservoir sealed by shale of Upper Goru Formation and charged by underlying shale of Sembar Formation [23]. Oil and Gas Development Company Limited (OGDCL), Pakistan and Union Texas Pakistan (UTP) have divided Lower Goru Formation into further units, based on its lithology. The main units include Upper Sand, Basal Sand, Talhar Shale, and Massive Sand [24]. In this study, the main target is Talhar Shale which is around 79 m thick. The wireline log data of Hakeem Daho well are used in the present study. The Government of Pakistan (GOP) started a project with the help of USA to evaluate the unconventional hydrocarbon potential in its territory [25]. According to the Energy Information Administration (EIA) report, Pakistan has estimated shale-gas potential about 105 trillion cubic feet (TCF) and 9 billion barrels of oil shale [26]. E&P companies are trying to explore the shale-gas potential of the study area, and their main target is Talhar Shale. In a recent study, Talhar Shale is considered as potential shale-gas candidate in Southern Lower Indus Basin, Pakistan. Possibly, hydraulic fracturing will be used to produce shale gas. Talhar Shale possesses low Arabian Journal for Science and Engineering (2019) 44:417–428 419 Fig. 1 a Basins Architecture of Pakistan after [16], b Lower Goru Formation distribution map in which study area is mentioned after [17] permeability which provides one of the strong evidence of the presence of shale gas [27–29]. Table 1 Classification of formation in the process of evaluation of shale according to the volume of shale [35] Classification 3 Methodology The volume of shale (Vsh ) is a key parameter in the process of conventional formation evaluation because of its impact on various petrophysical parameters interpretation results [30]. Generally, in shale gases, a correlation between gamma ray index and (Vsh ). Occasionally, natural gamma ray (NGR) log gives higher values of (Vsh ) due to the presence of uranium (U) content of non-shale origin. High U content shifts the NGRmin and NGRmax , which gives ambiguous results. To eliminate the effect of U content in calculations, a computed gamma ray (CGR) log was used. CGR serves better comparison to NGR in the estimation of (Vsh ). Various field studies have proved that estimation of the volume of shale using well logs data is being improved with CGR instead of NGR, for a better reservoir description and accurate estimation of percentage of shale [10,31–34]. On the basis of volume, shale is classified into three types: clean sand, shaly sand, and shale. The volume of shale, less than 10%, is called clean sand, 10% < Vsh < 33% shaly sand, while Vsh > 33% refers to shale as shown in Table 1 [35]. Volume of shale (%) Clean sand Vsh < 10 Shaly sand 10 < Vsh < 33 Shale Vsh > 33 Al-Ruwaili [36] proposed a model, which is based on well logs data for shaly sand formations evaluation, and it facilitates to understand the basic components of shaly sand formations. Passey et al. [37] developed a systematic model for evaluation of shale. A systematic model for material balance Eq. 1 using both concepts of Al-Ruwaili [36] and Passey et al. [37] is illustrated in Fig. 2. Vsh + φE + Vma = 100 (1) The major parts of bulk volume of shaly sand formation includes the volume of shale (Vsh ), total porosity (φT ), effective porosity (φE ), and volume of the matrix (Vma ). It has been divided into three parts for the material balance equation in the process of volumetric evaluation of shale. Firstly, (Vsh ) is the sum of volume of clay and non-clay minerals, dry 123 420 Arabian Journal for Science and Engineering (2019) 44:417–428 Fig. 2 General systematic bulk volume of shaly sand formations . Modified after [36,37] clay, clay bound water, and organic matter. Secondly, φE is the sum of hydrocarbons and free water; basically, it is pore space volume, and thirdly, Vma is the summation of specific type of volume of particles (quartz etc) excluding (Vsh ). The theoretical bulk volume of shaly sand formation is expressed as 0–100%. Empirical formulas have been used for NGR, CGR, and Gamma Ray Sonic (GRS) logs to estimate the volume of shale with both the applied linear and nonlinear approaches. Gamma ray index (IGR ) is calculated from well log by using Eq. 4. The values of NGRmax and NGRmin are taken from well log [38]. A relationship between IGR and (Vsh ) is a quantitative indication of shale content in the geological formations [39]. Poupon and Gaymard [40] introduced linear Eqs. 2 and 3, while Steiber [41], Larionov [42], and Clavier et al. [43] used nonlinear Eqs. 4–6, respectively, for the estimation of Vsh . Percentage error in shale volume is computed by using Eq. 7. IGR GRlog − GRmin = GRmax − GRmin (2) where IGR = gamma ray index, GRlog = gamma ray log values, GRmax = gamma ray maximum values, and GRmin = gamma ray minimum values IGR = Vsh Error (%) = Vsh by XRD − Vsh by GR ∗ 100 Vsh by XRD Total porosity (φT ) can be obtained from any porosity log in shaly formation [44]. Therefore, a combination of three logs comprising bulk density, sonic, and neutron porosity logs that are called as φNDS has been used for total porosity to reduce the effect of a single log to achieve better results [38]. Hence, φNDS is equal to the total porosity (φT ). φN = neutron porosity from well log φD = ρma − ρb ρma − ρf (8) (9) where φD = density-derived porosity, ρma = matrix density, ρf = fluid density and ρb = bulk density values from log φS = tlog − tm tf − tm (10) where φS = sonic-derived porosity, tm = matrix transit time, tf = fluid transit time, and tlog = sonic transit time from log φNDS = φN + φD + φS 3 (11) (3) φNDS = φT 0.5∗ IGR Vsh = 1.5 − IGR (7) (4) Lower Goru is of Cretaceous age; therefore, we used and applied rock older than Tertiary using Eqs. 5 and 6. (12) Hill et al. [45] introduced empirical Eq. 13 to compute effective porosity using total porosity and shale volume. φE = φT (1 − Vsh ) (13) Vsh = 0.33(22IGR − 1.0) (5) The volume of the matrix is computed using material balance Eq. 1 by computing shale volume and effective porosity. Hence, the volume of the matrix is computed using Eq. 14. 1 2 Vsh = 1.7 − 3.38 − (IGR + 0.7)2 (6) Vma = 100 − (φE + Vsh ) 123 (14) Arabian Journal for Science and Engineering (2019) 44:417–428 421 Empirical Eq. 15 is used to compute well logs index. Ix = xlog − xmin xmax − xmin (15) where x = any well log, I x = index of log, xmin = minimum log value, and xmax = maximum log value 4 Volumetric Shale Evaluation Results The results of the volumetric shale evaluation are described below. 4.1 Shale Volume An essential step to be taken in the process of formation evaluation is estimation of the amount of shale present in the geological formation because it is mandatory to calculate effective porosity and fluid content [46,47]. To accurately estimate the volume of shale (Vsh ), numerical equations are used for well logs. In this study, three logs, NGR, CGR, and GRSL, are used to estimate the volume of shale. The results of these logs are given in Table 2. We accepted (Vsh ), which is 29.25% computed using CGR and applied Steiber [41] empirical equation as it is very close to the results of the volume of shale calculated by XRD. The (Vsh ) calculated by XRD data is 30% in Talhar Shale [29]. It is common practice to use the natural gamma ray (NGR) log, which is a total contribution from all three elements, uranium (U), potassium (K), and thorium (TH), as indicator of shale content. The presence of highly radioactive black organic shale in the geological formation showed a significant difference than the X-ray diffraction data. This causes an overestimation of the volume of shale [47]. Therefore, computed gamma ray (CGR) log is used whose results appear to be compatible with X-ray diffraction results. Estimation of volume of shale using CGR is considered to be better than NGR and GRSL. GRSL overestimated the volume of shale as compared to NGR and CGR logs. It is noticed that linear approach, Larionov, and Clavier et al. overestimated the volume of shale. The display of (Vsh ) calculated using CGR log and applied linear and nonlinear approaches is illustrated in Fig. 3a. The display of accepted volume of shale (%) is illustrated in Fig. 3b. The results of the classification of shale are illustrated in Fig. 3c, where depth (m) is plotted on x-axis and volume of shale (%) on the y-axis. Talhar Shale is classified into three types, as shown in Fig. 3c based on the volume of shale values. The classification of shale by volume curve is constructed using MATLAB. Shaly sand is present at 2992–2996 and 3024–3048 m depth (m) intervals while shale and clean sand on small depth (m) intervals. The volume of shale frequency distribution is illustrated in Fig. 3d. The maximum data points are located at shaly sand zone and its contribution is 65%, while the contributions of shale and clean sand are 29 and 6%, respectively. On the basis of this classification, we are able to conclude that Talhar Shale is a shaly sand formation. 4.2 Porosities and Volume of Matrix A combination of neutron porosity logs with one or more porosity logs gives accurate porosity estimation and better results in the process of shaly sand formations evaluation. Density is also a porosity log, which is helpful for geologists to detect the gas-bearing zones. Neutron porosity and bulk density logs are reliable and ubiquitous logs for the evaluation of shaly sand formations. Sonic-derived porosity is, sometimes, overestimated due to the presence of shale with high density. Hence, a combination of all porosity logs is used to calculate total porosity [35,38,48]. Total porosity is a function of the neutron, density, and sonic porosities. Neutron porosity is taken directly from well log, while density and sonic are calculated from numerical equations. Porosity logs are affected by various shale contents in geological formations. The interval (2982–3012 m) indicates the high values due to the high values of the volume of shale. Rest of the interval (3012–3061 m) of porosity logs has medium range values, and neutron, sonic, and total porosity are closely compatible. Contrary to that, densityderived porosity indicates low values because it is affected by matrix density. The average total porosity in Talhar Shale is 16.52%. The output plots of all porosities are illustrated in Fig. 4. Effective porosity is computed from Eq. 15 after the computation of total porosity and volume of shale. The average effective porosity in Talhar Shale is 11.54%. The average volume of the matrix computed using Eq. 16 is 59.21% in Talhar Shale. 5 Relationship Between Porosities, Sonic, Resistivity Measurements with Shale Volume The key parameter in this study is the volume of shale because it is a function of porosities, sonic, and resistivity measurements. In the present study, a relationship between the volume of shale with porosities, sonic, and resistivity logs and their indexes has been extensively studied to check the behavior of these logs and their indexes against the volume of shale values. The results are discussed further in the coming sections. 123 422 Arabian Journal for Science and Engineering (2019) 44:417–428 Fig. 3 a Volume of shale display which is computed by using CGR and applied linear and nonlinear approaches. b Accepted volume of shale display. c Classification of Talhar Shale by using accepted volume of shale with marked zones. d Accepted volume of shale frequency distribution Fig. 4 Output plot of neutron, sonic, density, and total porosities in which depth (m) is plotted on x-axis and porosities (%) values on y-axis 123 Arabian Journal for Science and Engineering (2019) 44:417–428 423 Table 2 Results of volume of shale (%) by linear and nonlinear methods with percentage (%) error Well logs Linear approach Nonlinear approach Gamma ray index by Eq. 5 Steiber [41] by Eq. 6 Larionov [42] by Eq. 7 Clavier et al. [43] by Eq. 8 NGR error (%) 51.28 − 70.93 (Rejected) 28.80 4.03 (Rejected) 34.68 − 15.6 (Rejected) 34.04 − 13.47 (Rejected) CGR error (%) 51.93 − 73.1 (Rejected) 29.25 2.5 (Accepted) 35.54 − 18.4 (Rejected) 34.56 − 15.2 (Rejected) GRSL error (%) 53.73 − 79.1 (Rejected) 30.99 − 3.3 (Rejected) 37.92 − 26.2 (Rejected) 36.39 − 21.2 (Rejected) 5.1 Porosities and Shale Volume Relationships between the total and effective porosities with shale volume have been studied. Total porosity is directly proportional to shale volume, while effective porosity is inversely proportional. The curves separation between total porosity and effective porosity appears to be prominent in shale zone. At shaly sand zone where shale volume is 10– 20%, they have shown close compatibility with volume of shale at depth interval 3026–3045 m as illustrated in Fig. 5a. An increase in the volume of bound water present in the shale results in the increase of shale volume as well as total porosity. Effective porosity is a shale-free porosity that will decrease with the increase of shale volume [49]. Consequently, only with porosity values, it is difficult to find out low shale volume zone in well logs interpretation. To resolve this problem, we introduced and applied total and effective porosities index technique. The output plot of these indexes with shale volume is shown in Fig. 5b. The effective porosity index indicates significant response on low shale volume zone on thin beds; consequently, very high values are encountered. Therefore, low shale volume zones can be easily identified, which are inversely proportional to shale volume. Total porosity index is directly proportional to shale volume. It is therefore concluded that porosity indexes can identify low shale volume zone. Porosity indexes give a much better response as compared to porosity logs in low shale volume zone. 5.2 Sonic Log and Shale Volume Sonic log plays a significant role in porosity analysis. Geoscientists used sonic log in hydrocarbons exploration as well as for well log interpretation. Sonic log numerical values are directly proportional to the shale volume as illustrated in Fig. 5c. The sonic log indicates sharp change similar to shale volume. The sonic index is directly proportional to shale volume. It has prominent separation at low shale volume 10–20%. The value for total porosity (φT ) was derived from combining the readings of porosity logs [49,50]. The φS − φT cross-plot is dependent on the porosity parameters φN , φD , φS and deduced from density, neutron porosity, and sonic logs which are used for the estimation of the type of reservoir porosity (primary or secondary) in a particular zones [41]. The cross-plot of total porosity–sonic porosity is illustrated in Fig. 5d, which indicates the dominance of the high intergranular porosity (primary porosity) with lower secondary porosity type. High porosity zone in cross-plot indicates shale or gas effect present in Talhar Shale. 5.3 Resistivity and Shale Volume The resistivity logs are directly proportional to the shale volume in unconventional formations. The resistivity logs values are plotted with the shale volume as illustrated in Fig. 6a. At depth interval 3026-3045 m, all resistivity logs have close contents with the shale volume, while at high shale volume, it indicates separation, as illustrated in Fig. 6a. Microlaterolog has strong responses on thin beds as compared to deep and shallow resistivity logs. Resistivity log indexes are plotted with shale volume to check the response on the shale volume as illustrated in Fig. 6b. Resistivity log indexes are also directly proportional to the shale volume. In thin beds, microlaterolog index response is more prominent as compared to deep and shallow resistivity log indexes. At low shale volume 10–20%, indexes responses are more significant as compared to logs responses. Microlaterolog index is the most important to detect thin as well as low shale volume beds in geological formations. 6 Conclusions Conventional well logs can successfully be utilized in the volumetric evaluation of shale (in terms of volume, total porosity, effective porosity, and matrix volume). Natural gamma ray, porosity, and resistivity logs have played a vital role in this study. The proposed method is successfully applied on the Talhar Shale, and also it can be considered 123 424 Arabian Journal for Science and Engineering (2019) 44:417–428 Fig. 5 a Output plot of effective and total porosities with accepted volume of shale; b output plot of effective and total porosities indexes with accepted volume of shale; c display of sonic log and sonic index with accepted volume of shale; d total porosity versus sonic porosity crossplot with color-coded by effective porosity which indicates prominent intergranular porosity in Talhar Shale as a comprehensive interpretation of the conventional well log data in the volumetric evaluation of shale. The numerical character of all well logs provides very useful information during volumetric shale evaluation. Natural gamma ray, porosity, and resistivity logs are function of shale volume. The best estimation of the shale volume is computed using computed gamma ray (CGR) log with Stieber nonlinear approach, which is calibrated with XRD with 2.5% error which validates our findings. The maximum data cluster is located on shaly sand zone (65%), which indicates that Talhar Shale is a shaly sand formation. In a nutshell, we conclude that the extensive study of well logs numerical character and their indexes have shown significant responses as compared to their well logs numerical character, on low shale volume (10–20%) zone. Therefore, low shale volume zone should be identified by well log indexes instead of well logs. Microlaterolog gives the best indication of thin beds as compared to the shallow and deep resistivity logs. It is inferred that along with well logs interpretation, numerical equations and deterministic methods and well log indexes can also be used to extract valuable information from the conventional well log data. 123 7 Appendix In this section, conventional well logs application is described in the process of volumetric shaly sand evaluation. Arabian Journal for Science and Engineering (2019) 44:417–428 425 Fig. 6 a Display of resistivity logs with accepted volume of shale, b display of resistivity log indexes with accepted volume of shale To understand the subsurface structure and characteristics, in terms of petrophysical, “Wireline Logs” are utilized. Wireline logs do not directly measure petrophysical properties; they measure “Log Properties” of geological formations like bulk density, sonic, and resistivity [51]. In the absence of XRD and other modern logs data, researchers are trying a volumetric evaluation of shale by using theoretical and numerical approach, which is applied to conventional well log data. The basic tool is conventional well log data, to investigate and evaluate subsurface geological formations of hydrocarbons structures [52,53]. Conventional well logs: NGR [API] is natural gamma ray log, CGR [API] is computed gamma ray log, GRSL [API] is gamma ray sonic log, DT [µs/ft] is sonic log, CNCF [%] is neutron porosity log, ZDEN [g/cm3 ] is bulk density log, RMLL [ohm-m] is microlaterolog, RS [ohm-m] is shallow resistivity log, and RD [ohm-m] is deep resistivity log, which was run at the depth interval of 2982–3061 m (79 m thick) in Talhar Shale, as illustrated in Fig. 7. Schlumberger made data acquisition in 2002. The data were acquired from Directorate General Petroleum Concession (DGPC), Pakistan. mation of the volume of shale, we utilized NGR which is a weighted sum of thorium (TH), potassium (K), and uranium (U), as described in Eq. 16. Computed gamma ray (CGR) is the sum of thorium and potassium, which is calculated in API unit, shown in Eq. 17. We also used gamma ray sonic (GRSL) to calculate the volume of shale in our study. Then, we compared the results with XRD data volume of shale and chose the best one among them called accepted volume of shale. NGR(API) = 4∗ T H (ppm) + 8∗ U (ppm) + 16∗ K (%) (16) CGR(API) = 4∗ T H (ppm) + 16∗ K (%) (17) where the weights 4, 8, and 16 were chosen on the basis of total gamma ray count for natural gamma ray spectrometry apparatus to compute NGR and CGR by a simple formula. 7.2 Porosity Logs 7.1 Natural Gamma Ray Natural gamma ray spectrometry (NGS) apparatus is capable of measuring the natural radioactivity of the geological formations by measuring TH, K, and U concentrations [10]. Natural gamma ray measures the natural radioactivity in geological formations; its values are directly proportional to the volume of shale content [54]. In general, the concentrations of naturally occurring elements are high in shale as compared to other sedimentary rocks. Sedimentary rocks are composed of quartz sand, silt, and shale, so higher values indicate the shale content [55]. In the conventional method for the esti- Porosity is measured as a percent of total rock volume. It is categorized into effective porosity (φE ) and total porosity (φT ) in the process of evaluation of geological formations. Total porosity bulk volume is mainly composed of hydrocarbons, non-clay water (free water), and clay bound water. Effective porosity (a shale-free porosity) bulk volume is mainly composed of hydrocarbons and non-clay water. The main difference between φT and φE is the volume of free water that is present in geological formations. Effective porosity has a significant role in geological formations that contain commercial hydrocarbons (oil and gas) deposits 123 426 Arabian Journal for Science and Engineering (2019) 44:417–428 Fig. 7 Conventional well logs data displayed from left to right, CGR [API] computed gamma ray, GRSL [API] gamma ray sonic, NGR [API] natural gamma ray, DT [μs/ft] sonic, ZDEN [g/cm3 ] bulk density, CNCF [%] neutron porosity, RS [ohm-m] shallow resistivity, RMLL [ohm-m] microlaterolog and RD [ohm-m] deep resistivity logs, respectively because in this type of porosity fluids can be moved and recovered [56,57]. The geological formation has a variable density value; due to this phenomena, the effect of shale on porosity logs is also variable. Hence, it is crucial to check the behavior of all available porosity logs for the volumetric evaluation of shale. The porosity logs include neutron porosity, bulk density, and sonic. These are used for formation evaluation. Neutron porosity log is used principally for determination of porosity of geological formations; it is a function of hydrogen content in geological formations, while in shaly sand intervals it is a function of both shale and liquid fills. 7.2.1 Primary and Secondary Porosity 123 Neutron and density logs are responses to pores of all sizes in geological formations. However, it has been observed by field studies that sonic log is used to measure interparticle (intergranular and intercrystalline) porosity. Porosity is derived from the sonic log by using Wyllie et al. [58] equation. The cross-plot between sonic derived porosity and total porosity provides information about primary porosity (intergranular) and secondary porosity. The cross-plot of total porosity–sonic-derived porosity depends on the porosity parameters (φN , φD , φS , and φT ), which are deduced from neutron, density, sonic logs, and their combinations, respectively. Secondary porosity usually does not exceed as Arabian Journal for Science and Engineering (2019) 44:417–428 427 Table 3 A summary of phenomenological interpretation of conventional well logs modified after [33] Descriptor Measurement Shaly sand/shale Natural gamma ray (NGR) Vsh ↑ → Porosity (φ) Bulk density φ↑ → ρb ↓ Resistivity Functional behavior NGR ↑ Neutron φ↑ → φn ↑ Sonic (DT) φ↑ → DT ↑ Deep resistivity (RD) Vsh ↑ → Shallow resistivity (RS) Vsh ↑ → RS ↑ Microlaterolog (RMLL) Vsh ↑ → RMLL ↑ RD ↑ Where ρb = bulk density, φn = neutron porosity and Vsh = volume of shale compared to primary porosity. Data points located in intergranular zone indicate shale or gas effect [41,50,59]. 7.3 Resistivity Logs The resistivity logs are used to measure the formation resistivity; the presence of hydrocarbon raises the resistivity values. Resistivity has an inverse relationship with porosity. In our study, three types of resistivity logs are utilized, which include deep resistivity, shallow resistivity, and microlaterolog. Deep and shallow resistivity logs are used to evaluate the productivity of the geological formations. The presence of shale content in geological formations has an adverse effect on resistivity logs. The effect is related to the content of shale volume. Deep resistivity and shallow resistivity logs overlap each other in tight sandstone, shale, and shaly sand beds. Geoscientists used microlaterolog for best estimation and the correlation between thin beds and reservoir analysis of the geological formations [54,57]. A summary of phenomenological interpretation of conventional well logs is given in Table 3. Acknowledgements I thank Directorate General Petroleum Concession (DGPC), Pakistan, for providing data for this research. 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