THE CHEMICAL PHENOMENA A chemical phenomenon is any manifestation of the process of transformation of matter that can be perceived by our senses. The term is used as a synonym of chemical reaction and of chemical change. Actually, the three concepts are inter-related in such a way that they are inter- dependent. CHEMICAL PHENOMENA CAN BE TWO TYPES: NATURAL AND ANTHROPOGENIC. Chemical reaction: Process of transformation that depend on the chemical properties of matter Chemical change: Change in structure and properties of matter as a consequence of the chemical reaction Chemical phenomenon: Manifestation of the chemical change NATURAL CHEMICAL PHENOMENA NATURAL CHEMICAL PHENOMENA Life in the planet is a dynamic process in which a myriad of chemical reactions that sustain life and maintain the natural balance between the living beings, take place constantly. Natural balance refers to the relationship between living beings with the environment and between themselves. These are the so-called natural chemical phenomena, some of them so nromal that we dont even wonder how they take place Ex: Cellular respiration (human and plants) Humans: inhale oxygen and exhale carbón monoxide (respiration) plants;: absorb carbón dioxide and reléase oxygen (photosynthesis) NATURAL CHEMICAL PROCESSES – EXAMPLES F E R M E N TAT I O N Biochemical process by which an organic substance transforms into another; ussually a simpler one, by the action of a microorganism called ferment. Milk (not refrigerated) sour Alcoholic beverages from the fermentation of fruits NATURAL CHEMICAL PROCESSES – EXAMPLES CORROSION Deterioration of a material caused by some chemical agents from its environment Ex: formation of rust in ferrous materials by the action of oxygen and the humidity of the atmosphere. NATURAL CHEMICAL PROCESSES – EXAMPLES COMBUSTION Is the chemical reaction that is produced between oxygen and a combustible material, accompanied by the reléase of energy and regularly, it manifests as incandescence or flame. Like the combustion of gasoline, of natural gas, of Wood or paper, among other materials, especially of an organic nature. ¿? According to scientific theory, the formation of the first living organism in the planet occured starting from a series of chemical reactions between substances that were found in the primitive atmosphere and under the action of solar energy; therefore, we may consider this process as the natural chemical phenomenon by excellence. ANTHROPOGENIC CHEMICAL PHENOMENA ANTHROPOGENIC CHEMICAL PHENOMENA Usually, the term is applied to describe the diverse types of contamination in the planet, as a consequence of the actions that human perform in the search for attaining better and more comfortable life conditions, which has contributed to a very pronounced technological advance in the previous century, that is, they are are contaminant chemical phenomena. Their origin may be urban industrial, agricultural and from livestock or from maritime navigation. ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F T H E AT M O S P H E R E Atmospheric contaminants are classified in two types: primary and secondary PRIMARY CONTAMINANTS Those emitted directly into the atmosphere by the sources that originate them. Among the most important are those that emanate from processes that imply combustion reactions in industries and vehicles with internal combustion motors; the main ones are: Carbon dioxide and monoxide Nitrogen oxides Sulfur dioxide Hydrocarbons The ones emitted by cars, trucks ,industrial chimneys, ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F T H E AT M O S P H E R E Atmospheric contaminants are classified in two types: primary and secondary SECONDARY CONTAMINANTS Those that have the their origin in the atmosphere by reaction between two or more primary contaminats, or among them, and the normal constituents of air. These reactions are favored by extreme environmental conditions such as elevated temperatures resulting from the heat produced in the combustion of gasoline and other combustibles in motor vehicles. The oxides of nitrogen, the hydrocarbons and oxygen react among them in the presence of ultraviolet radiation from the sun rays, generating the appearance of oxides in the atmosphere which, in turn, provoke a series of reactions that produce other contaminants, one of them, o z o n e , which in turn reacts with hydrocarbons, which transform into toxic products, such as aldehydes and acetones, among others. Oxidants associated to a strong insolation. ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F WAT E R Occurs by the presence of contaminating substances, whose sources can be of urban, industrial, agricultural, livestock and maritime navigation origin. CONTAMINATION BY URBAN DUMPING From domestic activities and are of organic origin, mainly of non-degradable material such as types of soaps and detergents, as well as edible oils. ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F WAT E R Occurs by the presence of contaminating substances, whose sources can be of urban, industrial, agricultural, livestock and maritime navigation origin. CONTAMINATION OF INDUSTRIAL ORIGIN Depending on the type of industry Examples: mercury, lead and arsenic generated by the mining and steel industry . Chrome and inorganic solvents come from the textile industry. Paint industries also generate paper and chemicals. ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F WAT E R Occurs by the presence of contaminating substances, whose sources can be of urban, industrial, agricultural, livestock and maritime navigation origin. AGRICULTURAL AND LIVESTOCK INDUSTRY CONTAMINANTS This type of activity generates contaminants by the agricultural use of pesticides and fertilizers; also by organic residues of animals and plants. Livestock activity contaminates by cow manure, urine and the cleaning products used in abundance. The presence of nitrates in the water of the wells, derived from human and animal excrements are a source of microbial contamination. ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F W AT E R Occurs by the presence of contaminating substances, whose sources can be of urban, industrial, agricultural, livestock and maritime navigation origin. MARITIME NAVIGATION The contamination of the seas is a cause of concern due to its grave impact on the lives of diverse marine species. It is mainly caused by hydrocarbons proceeding from oil spilled by oil tankers and other means of maritime transport. The damage they cause are severe since they affect the fauna and fishing, as well as the near coasts. Its effects are felt for a long time. ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F T H E G R O U N D The ground is the superficial part of the Earth’s crust and is a nature resource necessary for life. Its nature is determined by the interaction of physical, chemical and biological factors. The main contaminants in the country are the agrochemicals used for preservation of the crops, mainly fertilizers and pesticides. ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F T H E G R O U N D The fertilizers provide nutrients to favor the development and quality of the crops. The problem presents when quantities beyond the ground´s capacity for absorption are applied; at that moment, they change from beneficial to contaminants, since the excess of nitrates and phosphates which are the main components, transform the ground in the medium through which severe problems of contamination of waters are produced. Another severe problem is when this excess infiltrates from the subsoil towards subterranean waters. When consumed by humans, this water transforms the nitrates into nitrites by the action of some bacteria that exist in the stomach and urinary bladder; the nitrites convert into certain compounds called nitrosamines, that affect the stomach and liver with carcinogenic effects. ANTHROPOGENIC CHEMICAL PHENOMENA EXAMPLES C O N TA M I N AT I O N O F T H E G R O U N D Pesticides have always been used in agriculture to combat the great threat that plagues signify. However, pesticides are contaminants because they affect the soil and other species due to substances that form its chemical composition. Most pesticides contain organ chlorinated and organophosphate compounds, if these are insecticides. In herbicides, are found derivatives of heterocyclic organic compounds and of urea which are high toxicity substances. Fungicides of older use contain cooper and sulfur compounds, and currently, organometallics are found, which are organic compounds with atoms of varied metals. OZONE LAYER THE OZONE LAYER is a belt of the naturally occurring gas "ozone." It sits 9.3 to 18.6 miles (15 to 30 kilometers) above Earth, and serves as a shield from the harmful ultraviolet B (UVB) radiation emitted by the sun. Ozone is a highly reactive molecule that contains three oxygen atoms. It is constantly being formed and broken down in the high atmosphere, 6.2 to 31 miles (10 to 50 kilometers) above Earth, in the region called the stratosphere. Today, there is widespread concern that the ozone layer is deteriorating due to the release of pollution containing the chemicals chlorine and bromine. Such deterioration allows large amounts of ultraviolet B rays to reach Earth, which can cause skin cancer and cataracts in humans and harm animals as well. Extra ultraviolet B radiation reaching Earth also inhibits the reproductive cycle of phytoplankton, single-celled organisms such as algae that make up the bottom rung of the food chain. Biologists fear that reductions in phytoplankton populations will in turn lower the populations of other animals. Researchers also have documented changes in the reproductive rates of young fish, shrimp, and crabs as well as frogs and salamanders exposed to excess ultraviolet B. Chlorofluorocarbons (CFCs), chemicals found mainly in spray aerosols heavily used by industrialized nations for much of the past 50 years, are the primary culprits in ozone layer breakdown. When CFCs reach the upper atmosphere, they are exposed to ultraviolet rays, which causes them to break down into substances that include chlorine. The chlorine reacts with the oxygen atoms in ozone and rips apart the ozone molecule. One atom of chlorine can destroy more than a hundred thousand ozone molecules, according to the the U.S. Environmental Protection Agency. The ozone layer above the Antarctic has been particularly impacted by pollution since the mid-1980s. This region’s low temperatures speed up the conversion of CFCs to chlorine. In the southern spring and summer, when the sun shines for long periods of the day, chlorine reacts with ultraviolet rays, destroying ozone on a massive scale, up to 65 percent. This is what some people erroneously refer to as the "ozone hole." In other regions, the ozone layer has deteriorated by about 20 percent. MARIO MOLINA n 1995, Mario Molina received a Nobel prize in chemistry for his work in atmospheric chemistry and the effect of chlorofluorocarbons (CFCs) on the depletion of the ozone layer. He shared the Nobel Prize with F. Sherwood Rowland and Paul Crutzen. This was the first time a Nobel Prize for research into the impact of man-made objects on the environment was awarded. The discoveries led to an international environmental treaty, which bans the production of industrial chemicals that reduce the ozone layer. Dr. Molina was named one of the top 20 Hispanics in Technology, 1998. Today, Dr. Molina is one of the world's most knowledgeable experts on pollution and the effects of chemical pollution on the environment.