Heat flow in welding Subjects of Interest • Heat sources • Heat source and melting efficiency • Analysis of heat flow in welding • Effects of welding parameter • Weld thermal simulator Suranaree University of Technology Sep-Dec 2007 Objectives • This chapter provides information of heat flow during welding, which can strongly affect phase transformation, microstructure, and properties of the welds. • Students are required to indicate heat source and power density used in different welding methods, which affect the melting efficiency. Suranaree University of Technology Sep-Dec 2007 Welding heat sources Electrical sources Mechanical sources • Arc welding • Resistance welding • Electroslag Heat intensity ~ 106-108 Wm-2 • Friction (stir) welding Heat intensity ~ 104-106 Wm-2 • Ultrasonic welding (15-75 KHz) • Explosion welding (EXW) Chemical sources Other sources • Oxyfuel gas welding • Thermit welding Heat intensity ~ 106-108 Wm-2 • Diffusion welding High energy sources • Laser beam welding • Electron beam welding Heat intensity ~ 1010-1012 Wm-2 Suranaree University of Technology Sep-Dec 2007 Welding Arc Characteristics • A welding arc consists of a sustained electrical discharge through a high temperature, conducting plasma, producing (ionic gas or plasma sufficient thermal energy as to be useful for the joining of metal by with electric current fusion. passing through) • Gaseous conductor changes electrical energy into heat. • Arc produces sources of heat + radiation (careful required proper protection) http://en.wikipedia.org bell shaped arc Welding arc Suranaree University of Technology Gas metal arc welding Sep-Dec 2007 Emission of electron at cathode Emission of electrons at cathode occurs when an amount of energy required to remove the electron from a material (liquid or solid). This amount of energy per electron is called ‘work function’. (analogous to ionization potential) Material Work function, eV Al 3.8-4.3 Cu 1.1-1.7 Fe 3.5-4 Mg 3.1-3.7 W 4.3-5.3 BaO, SrO 0.95 Thoria 2.5 CsO 0.75 Al2O3 <2.5 Suranaree University of Technology Emission occurs mainly by two processes; 1) Cold cathode At low pressure, high voltage conditions, positive ions are accelerated toward the cathode and bombard the cathode with relatively high energy. 2) Thermal emission At high temperature some electrons acquire enough thermal energy to overcome the work function and become free electrons. Sep-Dec 2007 Plasma formation www.fronius.com States of matter Solid Melting • Plasma consists of ionized state of a gas composed of nearly equal numbers of electrons and ions, which can react to electric or magnetic fields. Liquid Vaporization Gas (neutral atoms/molecules) Ionization Plasma • Electrons, which support most of the current conduction, flow from cathode terminal (-) to anode terminal (+). (negative charges • Neutral plasma can be established and positive ions) by thermal means by collision process, which requires the attainment of equilibrium temperature according to ionization potential of the materials. Suranaree University of Technology Sep-Dec 2007 Ionization potential Energy Element/Compound Ionization Potential (Volts or eV) He 24.6 Ar 15.8 H2 15.4 N2 15.6 O2 12.1 CO2 13.8 CO 14.1 C 11.3 Si 8.2 Fe 7.9 Ni 7.6 Na 5.1 K 4.3 Cs 3.9 Ionization potential, Vi, required to strip an electron from an outer shell of and atom or M+. Plasma temperature = Ionization potential x 1000 K Suranaree University of Technology Sep-Dec 2007 Power in arc •The electrical power is dissipated in three regions of the arc: anode, cathode and plasma column. Cathode - •The area at cathode and anode has strong effects on arc configuration, the flow of the heat energy to the terminal affecting shape and depth of the fusion zone. Arc area is mainly divided into three zones; Pc Power (Parc) Heat 1) Anode Pa = IE a 2) Cathode Pa Anode + Energy dissipation in the arc Pc = IE c 3) Plasma arc column Parc = I (dE arc / dl )l Suranaree University of Technology Note: Most heat goes to the anode/cathode and most is lost radially from the arc Sep-Dec 2007 Temperature in the arc and heat loss www.geocities.com • The arc temperature ~ 5000-30,000 K depending on the nature of plasma and current. • The arc temperature is determined by measuring the spectral radiation emitted. Heat losses in the arc • Energy losses by heat conduction and convection, radiation and diffusion. • In Ar gas, radiation loss ~ 20% while in other welding gas, radiation loss <10%. Plasma temperature contour in the arc Temp Radiation loss Heat loss Note: The use of fluxing reduces radiation lost Suranaree University of Technology Sep-Dec 2007 Polarity There are three different types of current used in arc welding 1) Direct-Current Electrode Negative (DCEN) 2) Direct-Current Electrode Positive (DCEP) 3) Alternating current (AC) Suranaree University of Technology Sep-Dec 2007 Direct-Current Electrode Negative (DCEN) • Also called straight polarity. • Electrons are emitted from the negative tungsten electrode and accelerated while travelling through the arc. • Most commonly used in GTAW. • Relatively narrow and deep weld pool is produced due to high energy. • DCEN in GMAW makes the arc unstable and causes excessive spatter, large droplet size of metal and the arcs forces the droplets away from the workpiece. This is due to a low rate of electron emission from the negative electrode. Suranaree University of Technology Sep-Dec 2007 Direct-Current Electrode Positive (DCEP) • Also called reverse polarity. • The electrode is connected to the positive terminal of the power source, therefore the heating affect is now at the tungsten electrode rather than the workpiece. shallow weld for welding thin sheets. • At low current in Ar, the size of the droplet ~ the size of the electrode Globular transfer. • The droplet size is inversely proportional to the current and the droplets are released at the rate of a few per second. • At above the critical current the droplets are released at the rate of hundreds per second (spray mode). • Positive irons clean off the oxide surface. Suranaree University of Technology Sep-Dec 2007 Surface cleaning action DCEP can be employed to clean the surface of the workpiece by knocking off oxide films by the positive ions of the shielding gas. Ex: cleaning of Al2O3 oxide film (Tm ~2054oC) on aluminium to make melting of the metal underneath the oxide film easier. Surface cleaning action in GTAW with DC electrode positive. Suranaree University of Technology Sep-Dec 2007 Alternating Current (AC) • Reasonably good penetration and oxide cleaning action can be both obtained. • Often used for welding aluminium alloys. Suranaree University of Technology Sep-Dec 2007 Heat source efficiency In the case of arc welding, having a constant voltage E and a constant current I, the arc efficiency can be expressed as; η= Where Qt weld Qt weld Q = = Qno min al t weld EIt weld EI Eq.2 Q is the rate of heat transfer Qnominal is the heat input tweld is the welding time In cases of electron beam and laser beam welding, Qnominal is the power heat source of the electron beam and laser beam respectively. The term, heat input per unit length of weld often refers to Qno min al EI , or V V Where Qnominal or EI V Qnominal / V Suranaree University of Technology Eq.3 is the heat input is the welding speed is heat input per unit length of weld Sep-Dec 2007 Heat source efficiency measurement • Heat source efficiency can be measured using a calorimeter (by measuring the heat transfer from the heat source to the workpiece and then to the calorimeter). • The temperature rise in the cooling water (Tout-Tin) can be measured using thermocouples or thermistors. Heat transfer from the workpiece to the calorimeter is given by Eq.4 α α 0 0 Qt weld = ∫ WC (Tout − Tin )dt ≈ WC ∫ (Tout − Tin )dt Where W C Tout Tin t is the mass flow rate of water is the specific heat of water is the outlet water temperature is the inlet water temperature is time Suranaree University of Technology Note: This integral corresponds to the shaded area, and can be used to calculated the arc efficiency η. Sep-Dec 2007 Heat source efficiency measurement • The arc efficiency can also be measured using Seebeck envelope calorimeter. This technique utilises thermocouple junctions for sensing temperature difference. • The heat transfer from the workpiece to the calorimeter can be determined by measuring the temperature different ∆T and hence gradient across a gradient layer of material of known thermal conductivity k and thickness L. α Qt weld = A∫ k 0 Where A ∆T/L ∆T dt L Eq.5 is the area for heat flow is temperature gradient Layer of temperature gradient for heat source efficiency measurement. Note: this type of calorimeter is used to determine the arc efficiencies in PAW, GMAW, and SAW. Suranaree University of Technology Sep-Dec 2007 Heat source efficiency measurement • In GMAW the arc, metal droplets, and the cathode heating contribute to the efficiency of the heat source. • Lu and Kou used a combination of three calorimeters to estimate the amounts of heat transfer from the arc, filler metal droplets and the cathode heating to the workpiece in GMAW of aluminium. (a) Measured results, (b) breakdown of power inputs. (a) Heat transfer from metal droplets (b) Total heat inputs (c) Heat inputs from arc and metal droplets. Suranaree University of Technology Sep-Dec 2007 Heat source efficiency in various welding processes LBW Heat source efficiency is low because of the high reflectivity. PAW Heat source efficiency is much higher than LBW (no reflectivity). SAW EBW Heat source efficiencies in several welding processes. Suranaree University of Technology Heat source efficiency is higher than GTAW or SMAW since the arc is covered with thermally insulating blanket of molten slag and granular flux. Heat source efficiency is high due to the keyhole acting like a black body trapping the energy from electron beam. Sep-Dec 2007 Melting efficiency Aweld = Afiller +Abase Melting efficiency is the ability of the heat source to melt the base metal (as well as the filler metal). Cross section of weld The melting efficiency of the arc ηm can be defined as follows Where V Hbase Hfiller tweld ηm = ( AbaseVt weld ) H base + ( A filler Vt weld ) H filler ηEIt weld Eq.7 V is the welding speed ηm is the energy required to raise a unit volume of tweld base metal to the melting point and melt it. is the energy required to raise a unit volume of filler metal to the melting point and melt it. is the welding time. Note: the quantity inside the parentheses represents the volume of material melted while the denominator represents the heat transfer from the heat source to the workpiece. Suranaree University of Technology Sep-Dec 2007 Melting efficiency (a) shallow welds of lower melting efficiency, (b) (b) deeper weld of higher melting efficiency. Low heat input Low welding speed High heat input High welding speed Aweld = Afiller +Abase Suranaree University of Technology Sep-Dec 2007 Power density distribution of heat source Power density distribution is influenced by 1) Electrode tip angle 2) Electrode tip geometry Sharp electrode • Arc diameter • Power density distribution Blunter electrode • Arc diameter • Power density distribution Effect of electrode tip angle on shape and power density distribution of gas-tungsten arc. Suranaree University of Technology Sep-Dec 2007 Effect of electrode tip angle on shape of gas tungsten arc and power density Conical angle of electrode tip Suranaree University of Technology The arc becomes more constricted Sep-Dec 2007 Analysis of heat flow in welding Heat or temperature distribution occurring during welding greatly affect microstructure of the weld, hence, the weld properties •The temperature-distance profile shows that the heat source travels along the weld in the direction A-A’ at a constant speed. • As the heat source moves on, the cooling rates around the weld are very high. • A more intense heat source will give a steeper profile and the HAZ, which will be confined to a narrower region. Temperature distribution round a typical weld Suranaree University of Technology Sep-Dec 2007 Effect of temperature gradient on weld microstructure The temperature gradients in the liquid weld material are substantially higher than in most casting processes. This leads to high solidification rates which produce a finer dendritic structure than that observed in most castings. Microstructures occurring in a weld and its HAZ. Suranaree University of Technology Sep-Dec 2007 Effect of welding parameters • Effect of heat input Q and welding speed V on the weld pool. • Effect of heat input on cooling rate. • Effect of the power density distribution of the heat source on the weld shape. • Heat sink effect of workpiece. Suranaree University of Technology Sep-Dec 2007 Effect of heat input and welding speed on the weld pool • The shape and size of the weld pool is significantly affected by heat input Q and the welding speed V. Heat input Welding speed The weld pool becomes more elongated. Note: the cross indicates the position of the electrode. Suranaree University of Technology Sep-Dec 2007 Effect of heat input on cooling rate The cooling rate in ESW (high Q/V) is much smaller than that in arc welding. Heat input per unit length EI/V Cooling rate Suranaree University of Technology Sep-Dec 2007 Effect of power density distribution on weld shape Power density Weld penetration Suranaree University of Technology Sep-Dec 2007 Heat sink effect of the workpiece • The cooling rate increases with the thickness of the workpiece due to the heat sink effect. • Thicker workpiece acts as a better heat sink to cool the weld down. Brass with a higher melting point than that of aluminium is used as a heat sink to increase the cooling rate in aluminium welding. Blass heat sink is clamped behind aluminium to be welded. Suranaree University of Technology Sep-Dec 2007 References • Kou, S., Welding metallurgy, 2nd edition, 2003, John Willey and Sons, Inc., USA, ISBN 0-471-43491-4. • Gourd, L.M., Principles of welding technology, 3rd edition, 1995, Edward Arnold, ISBN 0 340 61399 8. Suranaree University of Technology Sep-Dec 2007