00 Cover_Layout 1 12/16/14 6:57 AM Page cvr1 Plastics Engineering JANUARY 2015 www.4spe.org ■ www.plasticsengineering.org ■ Global Resin Trends 2015: An Expert Roundtable Global Resin Trends 2015: An Expert Roundtable PE PE ■ Academic-Industry Partnerships: Three Examples ■ You Want a Raise? ■ PET Bottle and Film PE/PP Recycling ■ Polymer Degradation: What Can Go Wrong ■ Join SPE’s “Race” at NPE2015 PE/PP 00 Cover_Layout 1 12/16/14 6:57 AM Page cvr2 Speed + Strength • • • • • • Strength of a structural adhesive Speed of an instant adhesive High impact and vibration resistance Temperature resistance up to 300°F Gap filling up to 0.2" Suitable for a variety of substrates, including metals, most plastics and rubbers WWW.HENKELNA.COM/4090 1.800.LOCTITE (562.8483). 01 contents_editorial 12/16/14 7:00 AM Page 1 CONTENTS VolUME 71 ■ NUMbER 1 ■ JANUARY 2015 2 From SPE Join sPE’s “Race” at NPE2015 Industry News ................................48 COVER STORY 6 14 18 Global Resin Trends 2015: An Expert Roundtable Edited By Michael Tolinski look for some big moves in polyolefins over the next few years Academic-Industry Partnerships: Preparing Tomorrow’s Plastics Professionals By Nancy D. Lamontagne three examples show how collaboration is helping students enter the industry You Want a Raise? By Dennis Gros it’s a complicated issue in today’s plastics industry GLOBAL LOOK 22 30 DEPARTMENTS Willing & Label By John Standish the impact of labels & adhesives on PEt recycling is significant A Look at Plastic Film Recycling By American Chemistry Council it’s growing, with lots of future opportunities Industry Patents ............................54 By Dr. Roger Corneliussen Upcoming Industry Events ..........58 Energy-Saving Tip ..........................59 By Dr. Robin Kent Market Place ..................................60 Editorial Index ................................62 Advertiser Index ............................64 About the cover: A few global polyolefin production and export trends are reflected by this graphic; learn more about future trends from the experts in our “roundtable” cover story. Plastics Engineering JANUARY 2015 !$ INSIDE SPI 44 ! !$ ■ & # $& How to Measure Color By Ron Beck Proper analysis is key for plastic parts that require accurate, consistent coloration ■ *** %! '( ' # # 40 Plastic Failure Through Molecular Degradation By Jeffrey Jansen Multiple mechanisms can attack polymers—here’s what can go wrong '# & # ' ■ " 0# )'(&, &(# &' %' & + "%! ' ■ $) ■ ■ #( $((! , !# ' # !" $!," & & ( $# ( # $ &$# ■ $# -' . / ( *** '% $& 34 ! '# & # ' CONSULTANT’S CORNER INSIDE SPI News about the state of the plastics industry and more, from sPi: the Plastics industry trade Association www.4spe.org www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 1 02-05 From SPE_046854 IndustryNews.QXD 12/16/14 7:01 AM Page 2 FROM SPE Join SPE’s “Race” at NPE2015 O n Day 2 of nPE2015, don’t be surprised to see a lot of green shirts hurrying around the show floor. the people wearing them will be running in the Plastics racetM, a fun and exciting event with a down-to-earth purpose. the high-profile race is expected to draw several hundred race participants and involve the support of up to 100 of the show’s near-2,000 exhibitors, whose booths will serve as waypoint destinations for the “racers” during the event. as part of sPE’s “next generation” initiative, the Plastics race is just one of an ongoing series of programs and activities designed to attract qualified students and young professionals to careers in the plastics industry. Dr. Jaime gómez, sPE’s Vice President of communications and secretary explains, “like any organization, the society of Plastics Engineers needs a constant influx of young and enthusiastic professionals to replace the ranks of our more senior members as they approach retirement. Our next generation initiative is geared to help us sustain our numbers and even grow our ranks.” Unlike last year’s race (at antEc® las Vegas), where race teams ventured up the Vegas strip to solve dozens of plastics-related riddles, this year’s Plastics race has been completely re-formatted to be run on the show floor at nPE2015, throughout its expansive Orlando county convention center venue. at nPE2015, the Plastics race will take the form of an appdriven, smart-phone-based question hunt in which soon-to-graduate engineering students and talented young plastics professionals compete for nearly $12,000 in prizes by answering questions they can only access by visiting exhibiting sponsors’ booths. Each four-person team will plot its own course from one sponsor location to the next. at each waypoint they will use their smart phones to scan a Qr code prominently displayed in the sponsor’s booth, verifying their visit. they then select a category (e.g., polymer science, processing, materials, equipment, etc.) and difficulty (easy, medium, or hard) to reveal the question to be posed. if exhibiting sponsors wish to personally engage race par- “Racers” on the hunt at ANTEC® 2014. 2 | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 02-05 From SPE_046854 IndustryNews.QXD 12/16/14 7:02 AM Page 3 02-05 From SPE_046854 IndustryNews.QXD 12/16/14 9:45 AM Page 4 Join SPE’s “Race” at NPE2015 At NPE2015, participants in The Plastics Race will use a smart-phone app to answer questions. ticipants, they may choose to pose a separate “Exhibitor Bonus” question about their company, its markets, technologies, products, or services, prompting the racers’ inquiry and discussion. Through each team’s smart phone app, booths visited and answers submitted will be monitored at “Race Control,” The Plastics Race’s on-site nerve center. At the completion of the race, points will be totaled, winners determined, and prizes awarded at a reception following the race. Gómez explains, “While only one team can win first place, everyone wins by participating in The Plastics Race. All participants win by having 4 At NPE2015, The Plastics Race will take the form of an appdriven, smart-phonebased question hunt in which soon-tograduate engineering students and talented young plastics professionals compete for nearly $12,000 in prizes by answering questions they can only access by visiting exhibiting sponsors’ booths. the opportunity to meet people, make new contacts, expand their knowledge, cultivate existing connections, network with associates, uncover employment possibilities, discover new companies, and learn about many of the new and existing products and technologies on display at NPE2015. “And exhibiting sponsors win as well, whether they are new to the industry or a well-established name, whether their booths are large or small, or whether they’re in a prime location or ‘far off the beaten track.’ By actively funneling dozens and dozens of racers to their booths over the sixhour duration of the race, all 100 Jaime Gómez exhibiting sponsors will ‘stand out from the crowd’ at NPE as they stir curiosity and draw the attention of nearby show-goers, while demonstrating their endorsement of SPE and the upcoming generation of plastics industry professionals that its programs and activities are designed to support.” For more information on how to join the 2015 Plastics Race, whether as a race participant or exhibiting sponsor (or to read more about last year’s race), visit www.4spe.org/antec/tpr. | PlASTiCS ENGiNEERiNG | JANUARY 2015 | www.4spe.org | www.plasticsengineering.org 02-05 From SPE_046854 IndustryNews.QXD 12/16/14 7:03 AM Page 5 2TQFWEVKQPGHƂEKGPE[EQWPVUA broad perspective is essential: every day, some 3.5 billion high-quality plastic parts are produced on ALLROUNDER machines – so the WVOQUVRTQFWEVKQPGHƂEKGPE[KUTGSWKTGF+H[QWCTGUGGMKPIVQRTQFWEGVJCVGHƂEKGPVN[YGCTGVJG TKIJVEJQKEG9GGPUWTG[QWTGEQPQOKEUWEEGUU#4$74)HQTGHƂEKGPVKPLGEVKQPOQNFKPI ARBURG, Inc. 4QEMYGNN4QCF Newington, CT 06111 Tel.: +1 (860) 667 6500 Fax: +1 (860) 667 6522 e-mail: usa@arburg.com #4$74) 6GEJPQNQI[ %GPVGT /KFYGUV /KNNGPPKWO &TKXG 'NIKP +. 6GN #4$74)6GEJPQNQI[%GPVGT%CNKHQTPKC&QRRNGT4QCF+TXKPG%#6GN www.arburg.us 2015 23-27, ) March (Level 2 ll a H West 9 States $QQVJ United o, FL Orland COVER STORY Global Resin Trends 2015: An Expert Roundtable Look for some big moves in polyolefins over the next few years PE PE PE/PP PE/PP By Michael Tolinski 6 | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 06-13 Cover Story_046854 IndustryNews.QXD 12/16/14 2:33 PM Page 7 G iven all the attention on new sources of resin feedstock (i.e., shale gas), there’s a strong need for some expert comment to put current (and future) resin trends into context. Below, four experts in the areas of polyolefin supply and demand respond to some timely questions, offering some long-range views—plus explanations about why things might not turn out as some people expect. this year’s “Roundtable” features responses from: • chris Bezaire, senior vice president, Polyethylene Business, for Nova chemicals. Bezaire joined Nova in 1994. Prior to his appointment to the management team, he served as vice president for Business and technology integration. • Kent Furst, manager, Polymers & Materials Group, for the Freedonia Group, inc. Furst has written over 50 studies since joining Freedonia in 2005 and is currently involved in research on the polyethylene, fluoropolymer, and graphite industries and markets. • Edward J. Holland, president and cEO of M. Holland company. Ed Holland has spent his entire career at M. Holland co., beginning as a sales representative in 1976 and moving up to president and cEO in 1994. During his tenure, the company has grown from a small regional plastics distributor to one of the top four distributors in North America. • Robin Waters, director, Polyolefins North America, for iHs. Waters joined iHs in september 2012, bringing 30 years of industry experience at DuPont and Basell Polyolefins (now lyondellBasell) in roles ranging from product and sales management to strategic planning and commercial management. Global Supply Patterns Plastics Engineering: It’s a complex question, but overall, how have geographic polyolefin resin supply patterns changed over the last few years? Waters: the last few years have seen significant supply buildup from the Middle East and china. the Middle East has become by far the largest exporting region for polyolefins, while china continues to look to reduce its dependence on imported resin. Over the next five years, we will see accelerated growth in the global supply of three key “building blocks”: ethylene, propylene, and methanol. the supply of these feedstocks is changing around the world. china is investing in coal- and methanol-toolefins technologies; North America is tapping cheap domestic ethane from natural gas…. For polyethylene a key theme will be the unprecedented investments in new plants in N. America; iHs expects to see some 50% increase in PE capacity over the next five years. this significant increase in capacity will, in turn, lead N. America to become a World polyethylene production by region, 2003–2023 (millions of metric tons) (chart courtesy of the The Freedonia Group, from the company’s October 2014 report, “World Polyethylene”). www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENGiNEERiNG | 7 06-13 Cover Story_046854 IndustryNews.QXD 12/16/14 2:33 PM Page 8 Global Resin Trends _______________________________________________________ _ significant net exporter of PE. at the same time the Middle East continues to increase supply, albeit at a slower pace, while growth in china continues to outpace all regions. the continued supply growth from these three regions will lead to significant shifts in trade and also place pressure on higher-cost regions, affecting operating rates and in some cases resulting in asset rationalizations. export into the global market, and expect to be able to continue this in the future, even as supply growth begins to outpace demand growth. Polyethylene Prices: Whys & Wherefores PE: Considering the North American production of shale gas, why have polyethylene prices not really fallen over past couple years (as of November 2014)? Robin Waters Furst: the answer is pretty simple: basic supply and demand. Even though shale gas has dramatically reduced production costs for ethylene and polyethylene in n. america, new production capacity has not yet come online. so polyethylene producers have been able to maintain current prices and enjoy the increased profitability from cheap feedstocks. in fact, most producers have been able to raise polyethylene prices since operating rates have been so high. driven by supply and demand than cost. Even with the addition of new capacity starting in 2015, the global supply/demand balance will still be the main driver of polyethylene pricing. any polymer pricing reductions solely based on capacity additions are likely to be more tempered and short term. Holland: While shale gas does deliver lower-cost feedstocks to the U.s. petrochemicals market, the infrastructure to deliver product is still being put in place. Only a limited amount of producers have been able to introduce shale gas feeds into their operations and complete their conversions. in the meantime, driven by strong demand and operational issues that have led to significant downtime, the n. american polyethylene market has been operating at very high utilization rates. thus the current market has been more Bezaire: Polyethylene is a globally traded product with the price floor set by producers with high costs, not by those with low costs. While the production of shale gas provides n. american ethane-based producers with production costs that are among the lowest in the world, the ethylene and polyethylene price floor is set by high-cost naphtha-based producers globally, and so shale gas does not directly impact the price of polyethylene. in addition, based on the n. american cost advantage, producers have the ability to 8 Waters: the fundamental basis for polyethylene prices remaining high is based the fact that global demand cannot be satisfied solely from low-cost regions like the Middle East and n. america but also requires supply from producers at the upper end of the production cost curve. thus there is a global price-setting mechanism for polyethylene, an easily transportable product. Producers in lower-cost regions therefore are able to take prices essentially set by higher-cost competitors. this brings into discussion the cyclic nature of the chemical industry where high margins attract investments in what is a very capital intensive industry—a process we are seeing played out here in n. america. Lower PE Prices to Come? PE: When will we really start to notice the effects of shale gas production on polyethylene and polypropylene prices? Or, why should we not expect to notice an effect on prices? Bezaire: We don’t expect shale gas production or future polyethylene supply growth to (materially) affect polyethylene prices, because the price floor is set by the relatively high production costs of naphtha-based producers around the world. as an example, polyethylene prices in the Middle East are not significantly different than polyethylene prices around the world—even though their ethane-based operations have the lowest cost structure in the world. Furst: Unfortunately, i don’t think we’ll see a dramatic decline in prices— processors will not be able to party like | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 06-13 Cover Story_046854 IndustryNews.QXD 12/16/14 2:33 PM Page 9 _________________________________________________________________________ it’s 1999. Again, supply and demand are at work here—Freedonia’s research has found that the global market should be able to absorb all the polyethylene capacity increases that have been announced in N. America. Even though capacity growth seems excessive, declining production in Europe and flat growth in South America will provide ample export opportunities for N. American resin. So I doubt there will be the kind of overcapacity and intense competition that leads to lower prices. The more likely scenario is slower increases in polyethylene prices, below inflation. impressive rates due to its value in use, and we expect that trend to continue. Waters: For polyethylene prices, we could start to see the effect of shale gas as early as late 2015 as the anticipation of new capacities becomes more imminent with the completion of Braskem IDESA project in Mexico. However, it is more likely that the full effect won’t be seen until 2017/2018 time frame, as expected capacity builds in N. America result in significant exports leaving the region. An important consideration in this development is how much capacity South America, North America’s preferred export region, will be able to absorb…. To evaluate that situation one must consider not only what if any new capacity will be built in S. America, but also what other regions, such as the Middle East, will be competing for share in the region. IHS currently projects that N. American prices will become much more competitive compared to other regions—not the case today… and, along with more competitive energy costs overall, see improved competitiveness in the processing community, particularly for those applications that benefit from what we refer to as “supply chain intensity,” i.e., applications requiring attributes such as short lead times, high value-in- Plastics Engineering: What could be the effects of plastics product bans, like California’s bag ban, on resin supplies and price patterns? At what point could a plastic product ban, even nationwide bans, influence resin production patterns and prices? PE: Are there signs that commodity resin users are doing more switching between resin types because of anticipated natural gas production trends or volatility? Bezaire: We continue to see interest among some polypropylene converters in switching to polyethylene due to the perceived lower volatility in Bag Ban Effects? Chris Bezaire use, high service requirements, and more rigid specifications. For polypropylene, the effect on prices differs somewhat given the nature of its feedstock supply. For certain, N. America benefits from low-cost propane, and this is driving projects for on-purpose production of propylene in N. America. The question is how much of a role will polypropylene play in monetizing the propane and propylene; IHS believe polypropylene projects will emerge, but, as the value chain is less integrated than that for ethylene and polyethylene, the capacity growth is not expected to have as dramatic effect on N. America net trade as that for polyethylene. For this reason IHS believes that, while N. American polypropylene prices will moderate relative to other regions, the impact will be less than that for polyethylene. That being given, polypropylene continues to grow at Furst: According to Freedonia, U.S. demand for retail plastic bags was about 1.7 billion pounds in 2013. Assuming California is 13% of U.S. demand (same as its share of GDP), the state’s bag ban would impact 230 million pounds of PE resin. That’s a lot of resin, but it’s less than 1% of the 29 billion pounds of polyethylene consumed in the USA overall, so it is unlikely to have an effect on prices. Even a nationwide bag ban would have a limited effect. For plastic product bans to really impact resin production and prices, they would have to target a much larger portion of overall resin demand, such as PET beverage bottles or EPS foam containers, which is unlikely. However, there is certainly the threat of “death by a thousand cuts,” where numerous bans of a limited scope lead companies to voluntarily abandon a particular plastic product. www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlASTICS ENGINEERING | 9 06-13 Cover Story_046854 IndustryNews.QXD 12/16/14 2:33 PM Page 10 Global Resin Trends _______________________________________________________ _ ing global economic uncertainty and the resultant growth outlooks. another fallout of lower oil prices, if sustained for any period, could be a slowdown in the extraction and development of shale gas and oil in n. america. this, in turn, could give pause to the U.s. petrochemical expansions announced but as yet unbuilt. Ed Holland polyethylene pricing, and where polyethylene offers equivalent or even improved performance in their applications. Oil’s Influence PE: What about the price of oil? How might continuing low oil prices impact resin prices in 2015? Holland: One major impact of lower oil prices is to make heavy-feedstockderived product more competitive in the global market. a second and more unpredictable result is the geopolitical effect that lower oil prices will have on the economies and subsequent stability and policies of countries like russia, Venezuela, nigeria, iraq, and others whose government budgets are only sustainable at oil prices over $80 per barrel. Unrest in these already volatile countries can have the effect of increas- 10 Waters: it’s important to realize that, on a global basis, polyethylene capacity exceeds demand to the point that global operating rates average in the mid-80% range. so lower oil prices will result in lower prices, beginning with those producers whose costs are more directly associated with the higher-cost crude-based feed stocks, namely naphtha, and especially those located within large demand regions, for example china, where capacity utilization is already challenged by lower-cost exporting regions, namely the Middle East. lower oil prices may, however, lead to marginally improved margins for local, naphtha-based producers, incentivizing them to run at higher rates. the combination of lower costs and, perhaps higher production from producers on the upper end of the cost curve leads to increased price pressure for the producers in low-cost exporting regions to maintain full production rates, which we would expect them to do given the attractive margins that still exist despite lower crude. at some point the lower export prices needed to maintain position in export markets reach a point where domestic prices are influenced and respond; how much and when can be debated. Other Influences PE: What are some less-often talked-about influences on resin prices that will be relevant in 2015? Kent Furst Holland: the health of the overall global market, especially in the presumed high growth chinese and indian economies, is always an overlay to any discussion of future pricing influences. recent stimulation of the chinese market through the lowering of interest rates has raised concern of the ability to sustain the aggressive growth targets expected of the chinese consumer market. the chinese have proven predictions of their inability to sustain growth wrong in the past, but it is worthy of close attention. another influence in 2015 could be the strength of the U.s. dollar. if predictions of an even stronger dollar in 2015 come true, it will improve the prospects for resin and finished goods imports to n. america and negatively impact the U.s. export market. in resin markets, this has the capability to be magnified if oil prices remain at levels below $80 per barrel and heavy- | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 06-13 Cover Story_046854 IndustryNews.QXD 12/16/14 2:33 PM Page 11 Better Fit, Improved Cosmetics At Ashland, we are collaborating with the transportation industry to find new solutions to meet industry regulations and customer needs. It’s what we call “Good Chemistry”. The use of composites is increasing in automotive and heavy truck applications to address the need for lightweight, corrosion-resistant parts. To ensure outstanding fit and finish in those parts, Ashland offers a complete line of Low Profile Additives (LPAs). These LPAs help provide excellent dimensional stability and control of short and long term waviness; resulting in parts with smooth, flat surface profiles. Whether it is a zero shrink structural application or a Class A painted part, there is an Ashland LPA that fits your need. Ashland LPAs are one of many solutions in our transportation portfolio which enable our customers to produce outstanding, lighter parts. Our commitment to the transportation industry is as solid as our products themselves. To learn more about Ashland’s transportation solutions, visit ashland.com/ transportation. ® Registered trademark, Ashland or its subsidiaries, registered in various countries ™ Trademark, Ashland or its subsidiaries, registered in various countries © 2014, Ashland AD-13032 With good chemistry great things happen.™ 06-13 Cover Story_046854 IndustryNews.QXD 12/16/14 2:33 PM Page 12 Global Resin Trends _______________________________________________________ _ feedstock-dependent international producers are able to better compete in the U.S. market. Waters: We can’t ignore the global economy and its impact going into 2015. In 2014 we saw positive economic news regarding the USA, for example, but growing concerns regarding emerging economies, as well as continued conflicts that continue to raise concerns over sustained global growth. We need to continue to understand and anticipate the impact events in other regions have on prices here in N. America. Of course we also need to continue to sort out the impact of any prolonged period of low crude which, if played out as many expect, will lead to shifts not really contemplated for much of the past couple of years. Of particular interest would be the impact on capital spending in N. America, which could see delays if the assumed cost advantage for natural gas vs. crude is viewed less favorably. All of these topics are intertwined and mean perhaps a more complicated picture compared to a year ago. Bio-Based Resins: Priced Out? Plastics Engineering: Are there any signs that bio-based polymer prices are becoming competitive with conventionally produced resins? If so, which bioresins and why? Furst: Low-cost natural gas has had a significant negative effect on the biobased plastics industry. However, this has less to do with price than it does with investment, business focus, and margins. Braskem, Dow Chemical, and Mitsui have all shelved plans to build biobased polyethylene capacity in Brazil not necessarily because the economics were bad, but because their investment focus turned to gas-based polyethylene. Even if biobased polyethylene is at price parity, gas-based polyethylene is an established technology which is a sure bet in terms of profitability. Other biobased plastics have had enormous difficultly in achieving price parity, and a number of high-profile companies have gone out of business. The most successful has been NatureWorks’ PLA, which is not only price competitive with polystyrene and PET, but has also gained wide acceptance among plastic processors and brand owners in the USA, Europe, and Asia. Holland: With notable positive development efforts—Braskem’s production and marketing of sugarcane-derived ethanol and LDPE and Invista’s pursuit of sugar-based nylon intermediates—bio-based polymers are not as yet having a significant effect on overall business activity in the polymers market. In order to thrive, bio-based raw materials must first become readily available at competitive prices and in large quantities. The trend to bio-based feedstocks and their resultant polymers that exhibit all the properties and recyclability of their oil- and gas-based competitors is a positive development for these products. However, it’s been proven over and over again that these resins must be cost-competitive to be successful, and, as of yet, cost parity with established feedstock derivatives has not been achieved. Aggressive end-user efforts to adopt bio-based, sustainable products into their supply chain are needed to drive the success of those innovative producers that have committed significant capital investment to these products. Stay connected with the global plastics industry,, strengthen your professional networks by making new contacts, participate in discussions, or simply share your own news. Visit us on the web at www.4spe.org Follow us on Facebook, LinkedIn and Twitter. 12 | PLASTICS ENgINEErINg | JANUArY 2015 | www.4spe.org | www.plasticsengineering.org 06-13 Cover Story_046854 IndustryNews.QXD 12/16/14 2:33 PM Page 13 NPE2015 You Y ou make ma gr great eat things. Together, we make great things happen. Two-thirds T wo-thirds of all buyers worldwide are willing to pay more for consumer products that are manufactured in an environmentally responsible way*. Sustainable manufacturing is not just the latest trend; it is the future of the consumer products industry industry.. Discover the technology technology,, processes, and people you need to manufacture goods that meet the demands of increasingly eco-friendly market. *2013 Aspirational Consumer Index See how plastics can produce results for you. Register for free today at www www.npeguestpass.org/PE4 .npeguestpass.org/PE4 NPE2015: THE INTERNA INTERNATIONAL TIONAL PLASTICS SHOWCASE March 23-27, 2015 Orange County Convention Center Orlando, Florida USA www.npe.org www.npe.org 14-17 Lamontagne_046854 IndustryNews.QXD 12/16/14 7:05 AM Page 14 Academic-Industry Partnerships: Preparing Tomorrow’s Plastics Professionals Three examples in the USA show how collaboration can be stepping-stones into the industry for new generations of students By Nancy D. Lamontagne P reparing tomorrow’s plastics professionals starts today. Collaborations between academic institutions and the plastics industry are helping to give plastics engineering students the real-world experience they’ll need to be future innovators and problem solvers. Whether companies donate equipment or participate in research collaborations, industry partners gain brand exposure with future purchasers or employees, and benefit from fresh ideas coming from the lab. “Partnerships with industry are critical for plastics engi- neering programs,” says Robert Malloy, chairman of the University of Massachusetts–Lowell (UMass Lowell) Plastics Engineering Department. “We could not survive or be as effective without strong industry connections.” Keeping Education Relevant The UMass Lowell Plastics Engineering Dept. depends upon industry leaders to provide the advice and guidance that keeps the program relevant to industry needs. Many man- UMass Lowell student Azadeh Farahanchi is pursuing her doctorate degree in Plastics Engineering under the mentorship of Prof. Robert Malloy, the department’s chair (photo by Joson Images for UMass Lowell). 14 | PLasTiCs EnginEERing | JanUaRY 2015 | www.4spe.org | www.plasticsengineering.org 14-17 Lamontagne_046854 IndustryNews.QXD 12/16/14 7:05 AM Page 15 ufacturing, hardware, and software companies sponsor labs and donate or consign equipment for labs, providing stateof-the-art equipment for student training. corporate partners established some of the department’s more than 50 endowed scholarships, which help ensure talented engineering students can complete their education program. “Our job as plastics educators is to ensure that the plastics industry has an adequate supply of trained plastics engineers,” says Malloy. “We could not do this effectively without the great industry support we receive.” About 95% of the UMass lowell plastics engineering students complete one or more co-ops as an undergraduate. “students get a better feel for the aspects of the industry they like, and it helps them with their career path,” says Malloy. “We also feel the employers benefit, as the students bring a good skill set with them.” Meanwhile, UMass lowell has had a partnership with Moldflow simulation software since even before Autodesk acquired the company in 2008. Moldflow established an endowed scholarship, funded the renovation of the Moldflow computer lab, and provided simulation software for the lab. since then, Autodesk upgraded the lab and contributed supplying additional funds to the scholarship endowment. the newly renovated lab provides students with access to the full suite of Autodesk software technovel, a Japanese-based, multi-screw extruder manufacturer, placed both twin- and quad-screw compounding lines in UMass lowell’s new Mark and Elisia saab Emerging technologies and innovation center. the state-of-the-art, ultra-high speed compounding extruders operate at screw speeds as high as 4,500 rpm. “this investment by technovel is very significant and gives our students the opportunity to work with equipment that is as sophisticated as any equipment they will encounter in industry,” says Malloy. One of the newest collaborations for UMass lowell involves a new Plastics sustainability Research lab sponsored by sPi: the Plastics industry trade Association. the lab will have a variety of equipment for mechanically recycling plastic materials, which sPi is procuring from its member companies. After being displayed in the “Zero Waste Zone” at NPE2015 in Orlando, Florida, the equipment will be shipped to UMass lowell, where students will learn how to use it. “We hope that this lab will help our students and graduates have a much better understanding of recycling processes and hopefully will work to enhance recycling rates for plastics,” says Malloy. “this lab will also give us an additional plastics recycling research capability that we have not really had in the past.” Malloy sees a bright future for industry partnerships. “i repeatedly hear from employers that they are concerned about their aging workforce and are seeking new and young plastics engineering talent. Having a presence on campus is becoming almost a requirement if companies want the best and brightest graduates.” Graduate students at the University of Akron use an electromagnetic processing line in the school’s National Polymer Innovation Center. It can orient nanoparticles and polymer phases to produce functional films with enhanced properties in the thickness (“z”) direction for capacitors, fuel cell membranes, and ultra-high density information storage devices. “We Learn, and They Learn” the University of Akron in Ohio partners with industry in many ways. For example, its National Polymer innovation center offers a place for companies to work with the university on a smaller scale to develop new processes. this exchange also gives the students who work in the center important insight into product development. “companies come to us sometimes because of our expertise, sometimes because of our equipment, or they might have an idea of what they want and just need to work with someone on it,” says Eric Amis, dean of the college of Polymer science and Polymer Engineering. “We learn, and they learn.” the center’s unique equipment includes a very advanced roll-to-roll film processing line. companies can try out products on the line with the idea that they might build a similar line, for example. “A lot of new products are tied to changes in processing characteristics, and this equipment allows companies to try out a lot of formulations or processing parameters,” says Robert Weiss, chair of the Department of Polymer Engineering. “that is a big advantage.” www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 15 14-17 Lamontagne_046854 IndustryNews.QXD 12/16/14 7:05 AM Page 16 Academic-Industry Partnerships ________________________________ amis says the college of Polymer science and Polymer Engineering’s educational foundation is in synthesis, processing, measuring, and modeling, but the specific topics that it focuses on are of immediate importance. right now, hot topics include functional materials as well as biomaterials. For example, Prof. Matthew Becker at akron was recently awarded $3 million from the Ohio third Frontier initiative to collaborate with PolyOne, lubrizol corp., sns nanoFiber, Viscus Biologics, and austen Bioinnovation institute to accelerate the development of biomaterials and get them out of the lab and into real-world applications. the collaborators will contribute matching funds and will focus on the development of novel polymers, X-ray shielding materials, protective coatings for medical devices and catheters, and antimicrobial materials for wound healing. Ohio third Frontier provides funding to Ohio companies and institutions to create new technology-based products, companies, industries, and jobs. like many academic institutions, the University of akron places a lot of emphasis on developing intellectual property that can be licensed or used to launch spin-off companies. “akron has been doing well with this, and the students are an important part of the teams who talk to the industry partners about how to implement technology,” says coleen Pugh, chair of the Polymer science Department. companies also come to akron to increase their technology portfolio. For example, Premix, which is now owned by the composites group, came for help in expanding their sustainable materials. “We developed a joint iP agreement with the company,” explains Pugh. “the students worked on projects that will increase their sustainable materials offerings, including scaling up materials.” internships are another way that students get a chance to learn what it’s like to work in industry. this experience can help them decide on an academic or industry career path. some of the University’s graduate students work for two days per week for one year, and students have also had internships at PolyOne and Omnova solutions inc. Gaining Industry Experience For students in the Plastics Engineering technology and rubber Engineering technology programs at Ferris state University in Michigan, internships play a central part of their education. they’re required to take part in an internship, typically during the summers after their freshman and junior years. companies providing these internships have included nike, Ford Motor co., general Motors, chrysler, and many tier One automotive suppliers as well as major material suppliers. 16 Prof. Robert Speirs of Ferris State University teaches students how to operate a vacuum tank for tube extrusion. “For the freshmen, our goal is for them to gain exposure to the industry and get an understanding of what goes on there, as well as what their interests are in terms of a technical career,” explains robert speirs, professor and program coordinator of the Plastics Engineering Program. “Many companies put them into a project environment where they are guaranteed success, and often a mentoring system is used to ensure the students have someone with them a majority of the time.” When the students enter their second internship, they tend to drive projects such as cost-savings exercises, implementation projects, or quality or materials control programs, and they often save the company some significant money towards the end of their tenure. companies frequently view this second internship as an extended interview, and thus many of the students leave with a career opportunity. Fifty to sixty percent of Ferris state students in the program receive a job offer in this way. speirs says that recent improvements in the economy are making companies more aggressive in recruiting students for internships. “Many are including housing as part of their recruiting package, even though the internships are paid,” says speirs. One reason for this change is that hiring has been low since 2008-2009, so companies are dealing with an aging workforce. they need to hire talented young employees who can move up into leadership positions over the next 10 to 15 years. | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 14-17 Lamontagne_046854 IndustryNews.QXD 12/16/14 7:05 AM Page 17 The University of Akron’s multipurpose hybrid roll-to-roll film manufacturing line can produce transparent conductive films by depositing conductive nanofibers onto cast polymer liquid, which subsequently solidifies. the Plastics and Rubber Engineering technology programs are relatively expensive to run, and thus they rely on industry assistance in the form of materials and machine donations. “industry assistance is very important to keeping us in operation and helps keep us modern,” explains speirs. “the students learn to use this equipment, and when they graduate and… get the opportunity to specify instruments, they will lean towards manufacturers they know.” For example, Bekum America corp., KraussMaffei, Maplan Rubber Machinery, and AEc all provide equipment to the Ferris state programs, and a variety of materials suppliers provide materials that students use in the laboratories. companies also provide important insight into today’s trends through guest lecturers and other interactions with students. www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 17 18-21 Gros_046854 IndustryNews.QXD 12/16/14 7:08 AM Page 18 You Want a Raise? That’s a complicated issue in the plastics industry of today… By Dennis Gros President, Gros Executive Recruiters, Franklin, Tennessee, USA I n the midst of this renaissance of American manufacturing, plastic companies will have engineers, quality experts, sales personnel, and tech-savvy workers at the top of their hiring list in 2015. And the number of jobs will exceed the number of people who can step in and perform immediately. So if you’re in one of those professions, that’s good news, right? It’s a matter of supply and demand—and a great time for a pay raise! Not so fast, plastics professional. Let’s take a closer look at the factors that affect the dollars and sense of your paycheck. 18 Why They Need You Now Here are the reasons your job opportunities will bloom in 2015: • Expansion. It’s not that the American economy is amazingly robust. Rather, it’s the rest of the world that is doing so poorly. So by comparison, the USA is the best location globally for manufacturing over the next few years. U.S. manufacturers are proving they can compete on quality and price with the best in the world. To be | PLASTIcS ENGINEERING | JANUARY 2015 | www.4spe.org | www.plasticsengineering.org 18-21 Gros_046854 IndustryNews.QXD 12/16/14 7:08 AM Page 19 sure, nearly all economists are predicting good economic growth in 2015. For plastics companies specifically, the supply of North American gas is plentiful and low in cost—giving U.s. plastics companies a boost both domestically and in export markets. • Machines replace hands. the trend of replacing line workers with machines (automation/robotics) also will continue. therefore, hiring requirements will be for people who think and do, not just people who do. • Replacing retirees. More work in the plastics industry requires more people, but there aren’t enough experienced sophomores to fill the jobs as the senior workers retire. At this time, workers age 55-64 represent more than 20% of the overall workforce, and sometimes as high as 40% in skilled trades. if you are one of the few with plastics experience, expect to be in demand. Not enough young workers are embracing work in the plastics industry, or manufacturing in general, to close the gap. A Step Back in Time “How’s business?” At meetings and conferences, that’s the question you can expect to hear right after, “Hi, how are you doing?” the answer is almost always couched in two frames of reference—pre-recession and post-recession—such as, “i’m doing 10% better than in 2007.” (Rarely do they detail the metrics of red ink in 2009 and 2010.) As time goes by, the memory doesn’t hurt so much, but it’s ever-present. it’s likely that plastic companies will approach hiring with utmost caution in 2015, because profitability, while good, remains a tenuous proposition, affected by costs beyond control from: • healthcare insurance for employees, • costs of resin and other commodities, and • costs of regulatory compliance. Which Brings Us to your Paycheck… You can slice it anyway you want, but the reality is that paychecks in the plastics industry are barely keeping up with inflation. According to the federal government’s U.s. inflation calculator, you would need to earn 14.7% more today than you did in 2007 just to keep up with inflation—and that’s exactly where plastics industry salaries are today. But that is largely due to the unprecedented 11% jump in average salaries in 2013. i don’t expect an 11% increase again because financial realities and corporate profits don’t support it; 2013 was a catch-up year. As a result, American workers, including those in the plastics industry, are facing a break-even paycheck. All of us are paying higher prices for gasoline, utilities, insurance, food, and taxes, and there’s little financial wherewithal to move ourselves forward. there’s also no leftover money in worker paychecks to ensure their futures once they leave the workplace. Here’s one example of how to look at workplace pay for managers and employees in the plastics industry. in 2007— just a year prior to the economic downturn—business was good. Employers were placing recruiting assignments with our firm for process engineers at a target compensation of about $85,000. today, employers are placing recruiting assignments for the same position at about the same target compensation. company owners shouldn’t be accused of hoarding profits. in plastics, the margin on every order is extremely tight because economic advantages are being smothered by a weak economy. so until the business environment improves and employers feel more secure in boosting wages to outstrip inflation, actual pay will be an issue. Hot Job Titles it pays to be in an industry that pays. to find the most fertile market in plastics, look at your product, but don’t stop there. look at your customer’s product, and its demand in the marketplace. When you’re working within a profitable market niche, your boss has greater latitude to offer pay increases. Automotive: car sales are up, and so is the need for plastic components. Just like their dealers, car manufacturers have earned their reputation as skilled negotiators. there’s only a tiny margin of profitability in each piece, but when you’re making millions around the clock, cash flow is good and overall profitability is not bad. Plastic manufacturers making parts for the auto industry will be hiring quality engineers and managers, automation engineers, and process engineers. Building products: With construction markets expected to have a second straight solid year in 2015, companies will need workers to meet the growing demand for energy-efficient plastic building products, creating demand for sales, marketing, and computer-savvy manufacturing workers and design engineers. Packaging: No area of plastics is hotter than this, as plastics continue to make inroads because of their advantages in providing strong durable packaging at a lower cost and their ability to meet the sustainability needs of consumer product goods and medical companies. in highest demand: workers who can meet the challenging design characteristics with both their software skills and knowledge of materials. Medical: the medical components market is simply booming as medical device manufacturers continue to innovate to bring lower-cost, higher-quality products that provide better health-care results. their thirst for plastics products is insatiable because they provide better performance at lower www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 19 18-21 Gros_046854 IndustryNews.QXD 12/16/14 10:01 AM Page 20 You Want a Raise?_______________________________________________ costs. that’s driving the demand for engineers and material experts who can design products that give companies an edge in the marketplace. Final Thoughts as professional recruiters, we are rich in job inquiries now, but we also see that companies are reluctant to pull the trigger and invest money in not just a salary, but relocation costs, overhead, and benefits. Why? it’s the economy. Wage increases need to begin outpacing inflation. and for that to happen, we need our elected representatives in Washington, D.c., to generate an economic environment that fosters real growth. We need regulations and policies that help businesses compete globally and which do not serve as a barrier to growth and innovation. 20 About the Author: Dennis Gros is founder and president of Gros Executive Recruiters (grosrecruiters.com). He founded the forerunner of Gros Executive Recruiters in 1989 and moved operations to the Nashville, Tennessee, area two years later. The firm has placed an aggregate of more than $45 million in new employee starting salaries. Gros is a former chapter president for the Society of Plastics Engineers, and the firm is an active member of SPI: The Plastics Industry Trade Association. | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 18-21 Gros_046854 IndustryNews.QXD 12/16/14 7:53 AM Page 21 From: The Recruiter To: The Employer F What is your most di!cult hiring challenge?" Finding qualified candidates! Evaluating candidates during the interview! or every year of the Gros Executive Recruiters salary survey, we ask this question: “What’s your most difficult hiring challenge?” And every year, you reply overwhelmingly with one voice: “Finding Qualified Candidates.” In 2014, this answer garnered 70% of 455 responses. The challenge of attracting the best workers is more than an issue of attractive pay. As an industry, we need to compete with the information technology industries for the brightest minds. And for that, we need to shine. We need glamour. Young people are picking the hottest new companies with the latest and greatest capabilities. If your equipment and your technologies are not cutting-edge, don’t expect to attract top-notch talent. The obstacles facing management include the need to conceptualize the job. That is, re-think and re-define the job function, because many of the archived job descriptions don’t fit current circumstances. You need to prove to them and show them—both before and during the hiring process—that you have those leading-edge technologies because the traditional image of manufacturing is dirty, dingy, dark, and dusty. That image is your enemy. If your equipment and systems aren’t contemporary and lead- Meeting salary and/or benefit expectations! Expressing your company’s vision and goals! Enticing the candidate to relocate to your city! Other! ing-edge, it’s almost impossible to attract the top minds that are needed to generate ideas, products, and processes that will keep your company moving forward. So your capital investments actually pay for themselves twice: on the production floor and in the Human Resources office. Just like in your production process, outdated equipment leads to a downward spiral in the qualifications of your new hires. Employers also should understand that twenty-somethings are motivated by accomplishment. They want the excitement, the adrenaline high of contributing to the organization and bringing a new product to the marketplace. They want the psychological reward of discovering, creating, and building the products that make a positive impact on other people’s lives. In a tangible form, you can demonstrate that opportunity. I wish you a successful hunting expedition! www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlASTICS ENGINEERING | 21 22-29 Global Look_046854 IndustryNews.QXD 12/16/14 7:24 AM Page 22 GLOBAL LOOK Willing & Label The impact of labels and adhesives on PET container recycling is significant By John Standish technical Director, association of Postconsumer Plastic recyclers, Washington, D.c., Usa i n plastics recycling, we often discuss strategies to efficiently collect and process more resins and packaging types. But as we work to grow and diversify the recycling stream, we shouldn’t lose sight of critical evolutions that have occurred in a longtime standby of our sector: PEt packaging. and when it comes to PEt, one of the most pressing concerns is label technologies. not surprisingly, the type of labels on plastic packaging can greatly affect the recycling process. in recent years, brands and packaging stakeholders have begun employing new methods of creating and displaying their labels in an effort to reduce costs and make products stand out on the shelf in front of consumers. the association of Postconsumer Plastic recyclers (aPr) and other concerned industry players have worked hard to determine how different labeling systems are affecting the plastics recycling process. What follows is a rundown of the findings to date and suggestions on how label technology and recycling can move forward together. 22 PET bottles (and their labels) await the next step in the recycling process | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 22-29 Global Look_046854 IndustryNews.QXD 12/16/14 7:24 AM Page 23 • Left: A typical wrap-around label for a PET bottle, where a thin line of hot-melt adhesive is used to fix the label in place. Center: A concept for Avery Dennison's sleeve-label technology which allows the PET bottle to show through; this style of label allows NIR automated sorters to clearly see the PET behind the label. Right: The “Bris Bottle” is Spear’s first commercial application for their label technology, in which the pressure-sensitive label washes off cleanly. (Photos courtesy of the author, Avery Dennison, and Spear, respectively.) A Trio of Approaches there are currently three widely employed label types used for PEt packaging: wrap-around, full-wrap shrink sleeves, and plastic film pressure-sensitive labels. Each one of these label variations demonstrates different levels of performance when recycled, and it’s helpful to understand exactly what each label type entails. the wrap-around label is the most commonly utilized method for beverage containers. the polyolefin film labels are wrapped around the bottle and fixed in place with a small line of hot melt adhesive. in many cases, the printing is done on one film surface and then laminated to a second film so that the ink is sandwiched between the two layers. the APR’s “Design guide for Plastics Recyclability” provides packaging designers valuable information about how packages can be developed to have minimal impact on the recycling process, and the guide details the following as the preferred practice for recyclers working with PEt bottles that have wrap-around labels: • the hot caustic wash water melts and disperses the hot melt adhesive, releasing the label from the bottle. • With the ink laminated between two layers of film, the ink cannot stain the wash water or the PEt flakes. • Because the film is olefin-based, it will float in water, and is readily separated from the PEt that sinks in water. Posing Challenges Full-wrap shrink sleeve labels in use today differ from their wrap-around counterparts because they typically cover a PEt bottle from the closure down to the base of the container. From a recycling point of view, these labels pose challenges for several reasons: sleeved clear PEt bottles are often seen as colored bottles by autosortation equipment and ejected from the recycle stream. • the most widely used label stocks are PEtg or even PVc, which sink in water with the PEt bottle flake and are difficult to separate from the PEt in the widely used sinkfloat process step. • the inks on sleeve labels have traditionally not been designed to have good adhesion in hot caustic wash water and can bleed into the wash water. the APR encourages measuring the recycling impact of shrink sleeve and pressure-sensitive labels (more on these below) using laboratory-scale testing process and evaluation criteria, which are covered in full in the APR “critical guidance Documents.” Avery Dennison and Polysack, two current APR member companies, now offer commercially available labels that meet the strictest test results criteria in the “sleeve label guidance Document.” in addition, American Fuji seal and UPM Raflatac now offer sleeve label materials that are recognized by the APR for meeting critical guidance. testing from the APR and these companies has shown best recycling performance for full-sleeve labels occurs when: • the label floats in water; • ink adhesion on the label is retained during exposure to hot caustic wash water; and • printing on the label covers no more than 75% of the bottle surface area so that NiR (nearinfrared) and color auto-sorters can clearly identify the clear PEt bottle beneath the label. clearly, these types of labels can be fully integrated into the recycling stream, but precautions need to be put in place by manufacturers, and the cooperating companies understand that point. “Finding a label solution that can maintain the integrity of the PEt recycling stream is vital to the practices of www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 23 22-29 Global Look_046854 IndustryNews.QXD 12/16/14 7:24 AM Page 24 GLOBAL LOOK Willing & Label ________________________________________________ Wash water from a sample set of containers that all used paper labels: Some floating material can be seen, largely from closures, and at the bottom of the beaker is paper pulp that sinks with PET flake. A little bit of label makes a lot of pulp. (Photo courtesy of TK.) brands and retailers who want to reduce the environmental impact of their packaging,” says rosalyn Bandy, senior sustainability manager at avery Dennison. “the aPr critical guidance Documents have enabled avery Dennison to supply label constructions that help brands and retailers meet their sustainability goals. it’s not just about having zero impact—it’s about bringing value.” applications, including beverage, personal care, food, and home-cleaning products. they are also widely used on PEt thermoformed packages. adhesives are primarily selected to meet brand-owner needs for adhesion in hot, cold, and wet environments. in most cases, the impact of the adhesive, ink, or label on recycling has not been evaluated. However, spear label and the Kennedy group, also aPr members, are suppliers of pressuresensitive film labels and have employed the “Pressure sensitive label critical guidance Document” to demonstrate that their label technologies meet the strictest test result guidance contained in the protocol. test data demonstrates that these firms’ labels have negligible impact on recycling, in part because they: • release cleanly from the PEt container, leaving no adhesive residue on the bottle; • leverage label stock made from an olefin film that floats and is easily separated from PEt; and • use ink that adheres to the label in the hot caustic wash step and so does not “bleed” into the wash water and create risk of staining the PEt. these stakeholders have vowed to continue to push forward the recyclability side of film pressure labels. “the Kennedy group is committed to developing innovative products that promote recycling and sustainability,” says the Kennedy group’s Pat Kennedy. “With the introduction of PureVue, we’re complementing our family of pressure-sensitive labels with a product that is ideal for environmentally conscious brand owners. Our goal is to work with organizations like the aPr to help brand owners meet their corporate sustainability objectives.” and what about paper pressure-sensitive labels? these products are widely used on PEt thermoforms. as an industry, we want to collect and recycle this packaging type, but the paper labels can have an especially negative impact on PEt recycling. the paper can “pulp” in the wash step and release ink into the wash water. in addition, the adhesives used can be difficult to remove from the PEt surface. the aPr recently created a protocol for evaluating PEt thermoform labels and adhesives for compatibility with recycling to encourage label suppliers to develop labels that have the lowest impact on recycling. there are now a Pressure Pioneers the final label option is the pressuresensitive approach, which can use either a paper or polymer film substrate. the label is printed on one side of the label substrate, and a layer of adhesive is applied on the entire back side of the label to firmly adhere it to the package. Pressure-sensitive labels are used in a variety of PEt packaging 24 Left: Carbonated soft drink bottles that employ wrap-around labels after a PET whole-bottle wash step—the labels are removed by the wash step. Right: Bottles with pressure-sensitive labels after that same whole-bottle wash step—these labels are much more difficult to remove (photo courtesy of TK). | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 22-29 Global Look_046854 IndustryNews.QXD 12/16/14 7:24 AM Page 25 22-29 Global Look_046854 IndustryNews.QXD 12/16/14 7:24 AM Page 26 GLOBAL LOOK Willing & Label ________________________________________________ Continuing Efforts The Kennedy Group’s PureVue pressure-sensitive label (photo courtesy of the Kennedy Group). few sources of paper label stock that perform well in this assessment. Avery Dennison, Green Bay Packaging, UPM Raflatac, and Wausau Coated Products offer this type of paper label. The APR encourages those that produce or specify labels to use the label stocks listed on the APR website (www.plasticsrecycling.org). 26 The packaging industry’s development of new sleeve and pressure-sensitive label innovations seems set to continue. Fortunately, many members of the label value chain have been working closely to better understand and solve the challenges of new labels when it comes to recycling. Sun Chemical and Eastman, for example, are working together to develop an approach to creating a seam on sleeve labels that will allow the label seam to separate when a bottle goes through a whole bottle wash process. At the same time, companies selling auto-sortation equipment are making improvements to equipment and software to better manage labels, and ink suppliers are using APR test methods to develop new label inks. The recycling industry welcomes these innovations and strongly encourages their adoption by brand owners. The APR, meanwhile, will continue efforts to work with the label industry to create solutions for challenges to plastics recycling. Those APR efforts, in fact, are becoming increasingly formalized and effective. The Design Guide and Critical Guidance Document initiatives mentioned earlier are both components of the APR’s Champions for Change Program, which guides package designers and innovators to develop packaging compatible with today’s recycling processes. The program provides stan- dardized laboratory evaluations to assess the impact of a package or package component on recycling. In order to drive packaging innovation and qualify new materials, the APR encourages brand owners to request that suppliers provide data developed through these tests. Companies that meet the strictest test result guidance given in the Critical Guidance Documents are formally recognized. Stakeholders in the PET packaging field are indicating they are paying attention to the recycling industry’s efforts to examine the impacts of label types, and those companies are increasingly becoming a part of the actual research. With that type of cooperation, we can ensure labels and recycling processes evolve together. “Having been involved with the APR and the development of these test methods, we are happy to see the response and success to innovate labels,” says Kristina Hansen, project manager at Plastics Forming Enterprises. “These efforts will raise the quality of the recycling stream.” About the Author: John Standish is technical director of the Association of Postconsumer Plastic Recyclers. He can be reached at john@plasticsrecycling.org. This article was originally published in Resource Recycling and Plastics Recycling Update magazines in 2014. Used with permission. | PlASTICS EnGInEERInG | JAnUARY 2015 | www.4spe.org | www.plasticsengineering.org 22-29 Global Look_046854 IndustryNews.QXD 12/16/14 7:24 AM Page 27 September 8-9, 2015 SAVE THE DATE! SPE is proud to announce ANTEC® Brussels 2015 – a broad-based, high-quality technical conference for the plastics industry. This is the second conference of its kind to be held in Europe; EUROTEC 2013, which took place in Lyon, successfully presented 150 quality papers to attendees from 28 different countries. These presentations covered a wide-range of topics involving polymer converting technologies and applications, product developments, and elite plastics industry innovations. EUROTEC 2013 was the largest technical conference in Europe that year. ANTEC® Brussels 2015 will expand on the success experienced in Lyon. Taking place in Brussels, Belgium on September 8-9, 2015, it will again be the premier event for technical and business information for plastics professionals. The conference will consist of exclusive sessions involving: Composites Automotive Extrusion Innovations 3D and Nanocomposites Trends Technologies in Polymers Printing/Additive Manufacturing Medical And Polymers more! In addition to selected peer-reviewed presentations, the conference will also offer workshops and a compact exhibition, where you can interact with suppliers presenting their newest products. Don’t miss this premier event for the plastics industry! Mark you calendars today! Questions? Contact: Carine Roos croos@4spe.org PH: +32 498.85.07.32 22-29 Global Look_046854 IndustryNews.QXD 12/16/14 7:25 AM Page 28 22-29 Global Look_046854 IndustryNews.QXD 12/16/14 7:26 AM Page 29 www.antec.ws Monday PLENAR PLENARY Y Speaker “The Role of Nanotechnology in Current and Future Space Missions” Michael Michael Meador, Meadorr, NASA N NASA’s A’’s M Manager Game Changing Development Program’s Nanotechnology Project Chief anager of G ame C hanging De velopment P rogram’s Nanot echnology P roject & C hief Glenn Polymers Branch of the NASA G lenn P olymers Br anch Mr. Meador is currently on loan from NASA to the White House Office of S cience & Technology h l as the h Director of the National Nanotechnology Coordination O ffice (NNCO). NEW NEW TECHNOLOGY TECHNOLOGY Forums Monday: “Inno “Innovating vating W Within ithin a Global C Compliance ompliance En Environment” virronment” Presented by speakers from from UL, REACH (ECHA), PolyOne, FAA, FDA Tuesday: “3-D P Printing rinting g With With a Fo FFocus ocus on Mat Material terial erial eria D Development” evelopment” Presented by speakers from Shapeways, Materialise, Arburg, Oak Ridge, Teknor Apex Wednesday: ““Advances Advances in Batteries Battteries eries a and nd Sup Super-Capacitors” err-Capacitors” Presented by speakers from LBNL, University Missouri-Columbia, Exponent, Blue Spark Technolog Technologies, Wildcat Discovery TTechnolog echnologies DIGITAL DIGIT TAL A POSTER Sessions NEW! SPE has moved to all-digital displays ffor or thi this year’s poster sessions. All posters will be presented by students and industry proffessionals on HDT V flat screens in tandem with technical sessions. For complete conference details, visit the website to view the ANTEC® 2015 A Advanced dvanced P Program rogram 30-33 American Chemistry Council_046854 IndustryNews.QXD 12/16/14 8:16 AM Page 30 A Look at Plastic Film Recycling It’s growing, with lots of opportunity for future growth By American Chemistry Council Note: This article continues the series of updates in PE from Plastics Make it Possible®, an initiative sponsored by America’s Plastics Makers™ through the American Chemistry Council. i n 1996, the american Plastics council (the predecessor to today’s Plastics Division of the american chemistry council) commissioned a whitepaper on plastic film. in its paper,1 the environmental consulting firm Headley Pratt noted that, compared to alternatives, commonly used plastic film typically: • uses much less material to package products; • takes less energy to produce; • takes up less space in shipment, storage, and at retail; and • reduces environmental impacts of transportation. these benefits, due primarily to plastic film’s high strength-to-weight ratio, were not really news to manufacturers of plastic film and their customers. What was newsy back then was the whitepaper’s overview of the nascent efforts to establish plastic film recycling programs, which at the time took place predominately at businesses that used large amounts of stretch wrap. companies such as warehouse and distribution centers, bulk mail facilities, and grocery store chains had begun gathering large amounts of film over time and backhauling it to recycling facilities. 30 Early Collection Efforts in all, approximately 190 million pounds (86 million kg) of film were recycled in 1995 out of a production of 11.25 billion pounds (5.1 billion kg), according to the r.W. Beck consulting firm. that added up to a 3% recycling rate. consumer participation in the recycling of plastic film was in even earlier stages than commercial recycling. Due to the flexible nature of plastic bags and wraps, plastic film products typically were not being included in the rapidly growing plastics curbside collection programs. that remains the case today. the supermarket chain giant and the (then) Mobil chemical company initiated some of the original efforts to engage consumers in plastic film recy- cling. in the early 1990s, giant placed collection bins at its 75 stores in the Usa throughout Pennsylvania, Maryland, Virginia, and West Virginia with signs urging consumers to return only grocery bags that were provided by giant. the bags were back-hauled to giant’s distribution center where they were baled and trucked to the trex recycling facility in Winchester, Virginia. trex (at the time owned by Mobil) used the grocery bags along with used stretch wrap to manufacture plastic lumber, which the company continues to do today. the giant program and similar programs proved successful, and this new retail collection system for consumer grocery bags has expanded over time into a widespread collection program at thousands of major retailers across | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 30-33 American Chemistry Council_046854 IndustryNews.QXD 12/16/14 8:16 AM Page 31 the country, including grocery stores, target, Wal-Mart, lowe’s, and others. the program also evolved to collect many other types of consumer film, including bread bags, newspaper bags, dry-cleaning wraps, tyvek®, and flexible product wraps, such as wraps for cases of bottled water. Collection Efforts Today today, there are more than 18,000 store drop-off locations throughout the UsA that collect plastic bags, wraps, and film for recycling. As a result of this expanded collection program and increased commercial recycling, more than one billion pounds (450 million kg) of plastic film were recycled in 2012, according to Moore Recycling Associates—a more than five-fold increase since 1995. the EPA estimates that plastic film was recycled at a nearly 15% rate in 2012, the most recent year for which the agency has figures. interestingly, based on audits of the plastic film bales by Moore Recycling, a majority of film collected for recycling is not from grocery bags, but rather from product wraps and other film packaging. the authors of the 1996 paper pointed out many difficulties associated with plastic film recycling, including: amassing enough volume, storage space, collection infrastructure, contamination, and moisture. While those obstacles remain, many have been overcome over the years through trial and error and pilot projects that enhance recycling efficiencies. One important obstacle remains: consumer awareness of and participation in the recycling of plastic film. A 2014 survey by Plastics Make it Possible® found that while nearly two-thirds of Americans say they recycle on a “regular basis,” only 32% say they have returned plastic shopping bags to stores for recycling. A recently developed labeling program for packaging could help raise awareness and jumpstart the recycling of plastic film, as well as other “How2Recycle” posters like this one are strong reminders that plastic film can and should be recycled. packaging. greenBlue’s sustainable Packaging coalition in 2012 launched the “How2Recycle” label program that provides clear, simple, and nationally harmonized directions for what and where to recycle—right on the package. For the first time, this label literally puts recycling instructions into the hands of consumers, right at the point of disposal. For plastic film packaging, the label informs consumers that clean and dry bags, film, and wraps should be taken to store drop-offs for recycling. greenBlue’s goal is to place the How2Recycle label on the majority of www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 31 30-33 American Chemistry Council_046854 IndustryNews.QXD 12/16/14 8:17 AM Page 32 A Look at Plastic Film Recycling _______________________________ consumer goods by 2016. Many big names are on board including McDonald’s USA, conAgra, Kellogg’s, costco, general Mills, Microsoft, and Estee lauder. Some recent additions to the labeling program could help boost plastic film recycling: • Reynolds consumer Products will print the label primarily on its Hefty brand slider bags. • Kimberly-clark will add the label to its Scott naturals Tube-Free bath tissue flexible film packaging, followed by other Scott naturals packaging and Kimberly-clark products. Hilex Poly, the nation’s largest plastic bag manufacturer, will use the label on a variety of its flexible plastic packaging, including its well-known “Thank You” plastic bag. Wegmans became • And How2Recycle’s first grocery retailer, putting the label and a “Return to Sender” message on all plastic grocery and produce bags. Even though plastic film recycling is growing, substantial increases in consumer and commercial recycling will be needed to reach the higher recycling • rates of plastic containers and other materials. indeed, as the Plastics Division of the American chemistry council noted earlier this year, “[E]xisting infrastructures for collecting commercial film can be greatly expanded to capture significantly more of this material from the increasing number of businesses seeking recovery options for shrink film and transport packaging” (emphasis added). So opportunities exist for both consumers and businesses to increase plastic film recycling. Hopefully both will take advantage of these opportunities. For more information on plastic film recycling, visit www.plasticfilmrecycling.org. Reference 1. plastics.americanchemistry.com/understanding-plastic-film Plastics Make it Possible highlights the many ways plastics inspire innovations that improve our lives, solve big problems, and help us design a safer, more promising future. For more information visit plasticsmakeitpossble.org. So what happens to that billion pounds of plastic film after it has been collected? Recycled polyethylene film is used to make a range of products, such as durable plastic and composite lumber for outdoor decks and fencing, home building products, garden products, crates, pipe, new film packaging, and plastic bags. One example: Trex uses 140,000 recycled plastic bags to make 500 square feet (46.5 m2) of decking—the company is one of the largest plastic film recyclers in the USA. 32 | PlASTicS EnginEERing | JAnUARY 2015 | www.4spe.org | www.plasticsengineering.org 30-33 American Chemistry Council_046854 IndustryNews.QXD 12/16/14 8:17 AM Page 33 34-39 Consultants Corner_046854 IndustryNews.QXD 12/16/14 8:15 AM Page 34 CONSULTANT’S CORNER Plastic Failure Through Molecular Degradation Multiple mechanisms can attack polymer chains—here’s what can go wrong By Jeffrey Jansen the Madison group, Madison, Wisconsin, Usa [Note: The author will be presenting the SPE webinar “Degradation Failure of Plastics” on Feb. 18; see more details near the end of the article in the sidebar.— Ed.] M olecular degradation is a leading cause of plastic component failure, with a study indicating that 17% of plastic failures are associated with a degradation mechanism.1 in generic terms, molecular degradation of a plastic is the deleterious alteration of the molecular structure within the polymer as the result of a chemical reaction. importantly, degradation mechanisms principally involve a permanent reduction in molecular weight as a result of the chemical reaction. there are numerous molecular degradation mechanisms, but the most common are: • thermal oxidation, • ultraviolet radiation, • chain scission, and • hydrolysis. 34 Mechanisms of Degradation the dominant mechanism of molecular degradation and the extent of degradation are dependent on the composition of the plastic resin and the surrounding environmental conditions. significant property reduction can occur within most polymer families as a result of molecular degradation. all forms of degradation represent Figure 1: This nylon water-heater valve degraded through contact with chlorinated water at elevated temperatures. | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 34-39 Consultants Corner_046854 IndustryNews.QXD 12/16/14 8:15 AM Page 35 chemical reactions that result in molecular structural changes that are accompanied by noted decreases in physical properties. The reduction in molecular weight associated with degradation inherently leads to lower ductility due to the accompanying loss of entanglement of the now shortened polymer chains. This reduces the energy required for disentanglement/ slippage to occur and shifts the preferred mechanism from ductile yielding to brittle fracture. The manifestations of molecular degradation can include: • loss of mechanical properties, like – reduction in strength, – embrittlement, – cracking, and – catastrophic failure; • reduction in chemical resistance; • aesthetic changes, like – discoloration, – chalking, – loss of gloss, and – clouding/loss of transparency; evolution of volatiles (including • foul odor generation); and • carbonyl formation (and loss of dielectric properties). Molecular degradation can occur throughout the lifecycle of a plastic component. Regardless of when the degradation occurs, the effects can lead to premature failure of the component. (An example of a failure is shown in Figure 1, and some typical circumstances are listed in Table 1.) Thermal oxidation Thermal oxidation is the degradation of a polymeric material through contact with a chemical oxidizer. Most polymers are subject to oxidation, and it is the most common form of plastic degradation (consider Table 2). Oxidation is a chemical reaction in which oxygen is introduced into the molecular structure of the polymer, creating a form of carbon-oxygen bonds known as carbonyl functionality. It produces a permanent change within the plastic, most often in the form of Table 1: Circumstances Leading to Premature Failure Life Cycle Stage Compounding Drying Processing Processing Storage Installation Service Service Service Condition Exposure to elevated shear-induced heating while additives are incorporated into compound Exposure to elevated temperature for an extended period of time while in the drying hopper Insufficient drying of resin prior to injection molding leading to exposure to water at elevated temperatures Resin remains in the injection molding barrel for a prolonged period of time at temperature beyond recommended Outdoor exposure to sunlight of non-stabilized polymeric components Uncontrolled elevated temperatures used for welding operations Parts exposed to fluorescent lighting Exposure to temperatures higher than anticipated for extended periods Contact with aggressive acidic or basic cleaning chemical agents Result Chain scission Thermal oxidation Hydrolysis Chain scission Photo-oxidation Thermal oxidation Photo-oxidation Thermal oxidation Hydrolysis Table 2: Inherent Resistance to Oxidation of Various Polymers Polypropylene Low Density Polyethylene High Density Polyethylene Nylon Polyacetal Poly(phenylene oxide) Poly(ether ether ketone) Poly(phenylene sulfide) Poly(vinylidene fluoride) Polytetrafluoroethylene molecular weight reduction through shortening of the polymer chains. Oxidation takes place via a multi-step reaction based on free radical formation. Free radicals can be found within plastic formulations as unintentional residual byproducts of polymerization, as formulation additives, or as contaminants. These free radicals react Least Resistant Most Resistant with oxygen to attack the polymer backbone covalent bonds. In most cases, the rate of the degradation mechanism will accelerate with time as the reaction proceeds to autocatalyze. Through thermal oxidation, the polymer chains are cleaved, and the resulting shortened chains are terminated with oxygenated functional www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PLAsTICs ENgINEERINg | 35 34-39 Consultants Corner_046854 IndustryNews.QXD 12/16/14 8:15 AM Page 36 CONSULTANT’S CORNER Plastic Failure Through Molecular Degradation _________________ groups, including carboxylic acids, esters, ketones, and aldehydes. Photo-oxidation Photo-oxidation, commonly referred to as ultraviolet (UV) degradation, is the degradation of a polymeric material through exposure to terrestrial light energy in conjunction with contact with a chemical oxidizer, such as air. Based upon their structure and the functional groups comprising the polymer, some plastics are inherently susceptible to photo-oxidation. given enough light energy input, these susceptible functional groups, known as chromophores, cleave to produce free radicals. Degradation through photo-oxidation is very similar to the thermal oxidation, and is driven by the production of free radicals. Essentially, the exposure to light energy results in the accelerated formation of free radicals, which speeds the initiation of the degradation reaction. Photo-oxidation is a chemical reaction facilitating the incorporation of oxygen into the backbone structure as carbonyl groups, resulting in molecular weight reduction of the polymer. UV energy at short wavelengths is most severe toward polymeric materials, and can break the covalent molecular bonds forming the polymer backbone. the shortest UV wavelengths found within the Earth’s atmosphere are sufficient to produce this degradation. Most often, the chromophore that is susceptible to the UV energy is a functional group within the polymer; however, it can also be associated with an additive within the formulation. Bonds susceptible to photo-oxidation include carbon-nitrogen bonds such as nitrile, amide, and amine; carbon-oxygen bonds such as ether, ester, ketone, and carboxylic 36 acid; carbon-chlorine bonds; oxygenoxygen bonds such as peroxide; and nitrogen-hydrogen such as amide and amine. Degradation damage is generally limited to the surface layer exposed to the UV radiation, to a depth of approximately 150 µm. the depth of the degradation penetration is determined by the extent of oxygen diffusion into the material. However, even damage to this minimal degree can produce a deleterious outcome. the radiation exposure degrades the polymeric material, which results in a brittle surface layer. this degraded layer is then subject to localized shrinkage, producing stresses, or the direct application of stress in the application. this stress, and the accompanying strain, makes the material more prone to further oxidation and results in the initiation of cracks within the surface layer. the cracking subsequently extends into the base material through brittle fracture. Chain scission chain scission is the degradation of a polymeric material in the absence of a chemical agent, in particular without oxygen. as part of chain scission, the molecular structure of the polymer is altered solely based on energy, potentially as exposure to high levels of stress or elevated temperature. the covalent bonds forming the polymer backbone will break down randomly, resulting in rapid decreases in molecular weight. like thermal oxidation, chain scission proceeds via a free radical mechanism. as the polymer backbone chains are broken, carbon-carbon double bonds, known as unsaturation, are formed. the absence of oxygen drives this degradation mechanism. normally, chain scission is caused by exposure to elevated temperatures in combination with high shear stress, and is often associated with processing techniques where air is not present. Hydrolysis Hydrolysis is the degradation of a polymeric material through contact with water, specifically the hydrogen cations (H+) or hydroxyl anions (OH-). Hydrolytic degradation can occur within plastic materials as a result of submersion in water, progression through condensation cycles, or by exposure to steam. it can also result from contact with acids (high H+ concentration) or bases (high OH- concentration), which can dramatically accelerate the process. some polymers are inherently susceptible to hydrolysis, given their molecular structure. specifically, condensation polymers, such as those listed below, form water during the polymerization process, and as such are susceptible to hydrolytic degradation: • polyesters (like poly(butylene terephthalate), poly(ethylene terephthalate), and copolyester resins); • polycarbonate; • nylons (nylon 6, nylon 6/6, nylon 12); • polyurethane (ether-based and ester-based); and • polyacetal (homopolymers and copolymers). like the other types of molecular degradation reviewed here, hydrolysis represents a chemical reaction that results in a permanent change within the molecular structure of the polymer. the hydrolysis mechanism proceeds through the reaction of the polymer with water, resulting in the cleavage of the susceptible functional group, commonly into chemical species that resemble the initial reactants used in | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 34-39 Consultants Corner_046854 IndustryNews.QXD 12/16/14 3:07 PM Page 37 the original polymerization process. With some polymers, water is produced as a byproduct of the hydrolysis reaction, and in these cases the degradation proceeds relatively rapidly. it is important to recognize that hydrolysis is different than water absorption. While water absorption can significantly alter the mechanical properties of a plastic, particularly nylon resins, the effect is transient and reversible. Factors Influencing Degradation the various forms of molecular degradation present some commonalities in regards to the factors that influence the type of degradation and the rate and degree of damage to the material. generalized, the most important parameters affecting the extent of molecular degradation are as follows: • Polymer type: the susceptibility to the specific types of molecular degradation is variable, and based on the polymer structure. • Effectiveness of stabilization additives: the type, loading, and permanence of anti-degradant package used in the plastic formulation. • Temperature: Higher temperatures result in increased reaction rates. • Strength of reactant chemical or radiation: stronger or more concentrated reactive agents will result in faster degradation. • Stress level: Higher levels of stress results in more rapid degradation—internal and external stresses are combined. Figure 2: Reference and failed connectors, shown as received. The failed parts exhibited significant discoloration. Figure 3: Photomicrographs showing features associated with brittle cracking on the transverse fracture surface of the connector (left) and an interconnecting series of cracks on the interior surfaces at both the nipple end (left) and threaded end (right). A Case Illustration What went wrong? A plastic elbow connector used in a food service application failed while in service after approximately six months of use (Figure 2). A series of connectors installed within equipment at the same site had all failed prematurely, while parts at other locations Figure 4: SEM image showing mud cracking, characteristic of severe molecular degradation, on the interior surface of connector. www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 37 34-39 Consultants Corner_046854 IndustryNews.QXD 12/17/14 12:52 PM Page 38 CONSULTANT’S CORNER Plastic Failure Through Molecular Degradation _________________ had performed as expected. as part of normal operation, the systems are cleaned using a variety of commercial products. the elbow connector was stated to be produced from a nylon 6/6 resin. Evaluation Microscopic examination of the failed connector confirmed a catastrophic transverse crack within the nipple end of the elbow. the fracture surface displayed features associated with brittle cracking. inspection of the interior surfaces of the elbow revealed widespread cracking in an intersecting pattern, commonly referred to as mud cracking (Figures 3-4). the exterior surface of the failed part showed significant discoloration in the form of yellowing; however, cracking was not found. the extent and form of the cracking was indicative of molecular degradation of the elbow material initiating from the interior. scanning electron microscopic (sEM) examination revealed further evidence indicating molecular degradation was severe and consistent with chemical attack associated with exposure to an aggressive, incompatible chemical agent Fourier transform infrared spectroscopy (Ftir) was performed on the reference elbow, and the obtained results were consistent with a nylon resin (Figure 5). the interior surface of the failed elbow was also analyzed, and the resulting spectra contained absorption patterns associated with the nylon base material. However, additional absorption bands indicative of carbonyl functionality were also present, consistent with oxidative degradation. Energy dispersive X-ray spectroscopy (EDs) was performed on the base material of the reference connector and the interior surface of the failed part. Both results showed relatively high levels of carbon, oxygen, and nitrogen, as expected for a nylon resin. additionally, the interior surface of the failed part presented a low, but significant level of potassium. Conclusion it was the conclusion of the evaluation that the elbow connector failed as a result of severe molecular degradation of the nylon plastic resin. Degradation was indicated by the significant mud cracking and discoloration, as well as the oxidation indicated by Ftir. the degradation, and subsequently the cracking, initiated on the interior surface of the connector, indicating that the chemical agent responsible for the degradation was contained within the equipment. analysis of the interior surface of the failed part showed the presence of potassium, and because of the lack of other elements, this was thought to represent the presence of potassium hydroxide. given the internal nature of the degradation, the general classes of materials that produce molecular degradation in nylon 6/6, and the presence of potassium, the likely potential source of the deleterious chemical agent was the cleaning products used in conjunction with sanitation of the food service equipment. Reference 1. Figure 5: FTIR results on the failed elbow of the connector showed an absorption band indicative of oxidation. 38 Wright, D. Failure of Plastics and Rubber Products (shawbury, shrewsbury, shropshire, UK: raPra technology ltd., cambridge: 2001), p. 5. About the author: Jeffrey A. Jansen is a senior managing engineer and partner at The Madison Group (www.madisongroup.com; +1 608-231-1907), an | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 34-39 Consultants Corner_046854 IndustryNews.QXD 12/16/14 3:05 PM Page 39 independent plastics engineering and consulting firm. He specializes in failure analysis, material identification and selection, and aging studies for thermoplastic materials, and has been solving polymer-related problems for 23 years, during which he has performed over 1,525 failure investigations. Jansen is a regular presenter for SPE’s webinar series, covering a wide range of topics related to plastics failure, material performance, testing, and polymer technology. SPE webinar: Degradation Failure of Plastics Wednesday, February 18, 2015, 11:00 a.m. EST Plastic materials offer a unique balance of strength and ductility associated with their inherent viscoelastic nature. However, they are susceptible to molecular degradation through a variety of exposures. This degradation can occur during compounding, processing, storage, or while in service. Understanding the nature of degradation can help prevent failure. Thus, topics covered during this webinar will include: • Introduction to plastic molecular degradation, including the various mechanisms • Material susceptibility to degradation • Stabilizers to prevent degradation • Testing to assess the level of degradation For more details or to register, go to www.4spe.org/Events/webinars. aspx. www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlASTIcS ENgINEERINg | 39 40-43 Beck_046854 IndustryNews.QXD 12/16/14 8:15 AM Page 40 How to Measure Color Proper analysis is key for creating plastic parts that require accurate & consistent coloration By Ron Beck R&D Manager, Americhem, Cuyahoga Falls, Ohio, USA A s children, one of the very first concepts you likely learned was that of “color.” As a toddler, you learned to tell red from blue. As you grew older, you began to comprehend that there is far more diversity in colors than you had originally grasped. Sea green and forest green may both be green, you found; yet there is an easily perceptible distinction between the two. For many people, education on the differentiation of colors progresses little after childhood. They may recognize that there is a difference between two shades of a color, but they never learn how to measure this difference. And they are widely alright with this fact, as the ability to visually perceive a difference in color is what matters most to a layperson. For those who make regular decisions regarding the coloration of products, however, the skills to empirically differentiate colors are far more valuable. So how should we measure color? Principles of Examination As is the case with many scientific endeavors, measuring color involves examination followed by analysis. Thorough examination requires clear procedures, responsible methods, and a firm understanding of variability. You need good representative samples with which to work, as well as statistically valid, clean, appropriately preserved standards. Any sample Spectrophotometry is one method for repeatable, accurate color matching. 40 | PlASTiCS EnginEERing | JAnUARY 2015 | www.4spe.org | www.plasticsengineering.org being measured must be statistically representative of the entire batch, free from contamination, the same form as a target, and reproducible within acceptable limits of repeatability. Visual examination Evaluation of color can be—and generally is—done visually, but there is a fundamental issue with this method. Perceptions of color are highly subjective, as visual examination involves many complicating variables—from differences in the eyes and brains of examiners to the conditions of the examining environment. light sources vary in brightness and color rendering ability, for instance, and the properties of an object being examined could shift over time. As a result, consistent judgment is difficult to come by, and repeatability and reproducibility of color measurements determined visually are generally low. If you choose to compare colors visually, know that the methodology you select can affect color measurement outcomes. For instance, if you measure a single sample (imagine a square painted with a sample of a batch of yellow paint) versus a single standard (imagine a square painted with a sample of a batch of yellow paint previously determined to be of acceptable coloration), you may find that your judgment of similarity between the sample and the standard shifts over time, making repeatability difficult. As an alternative, if you choose to compare a single standard against numerous reference batches of a color, these previous batches can provide visual anchors to help you reproduce the same judgments from examination to examination. Instrumental examination the alternative to visual examination is to use specialized instruments to measure color. Instrumental examination allows you to assign quantifiable values to colors, making comparison simpler and eliminating some of the inherent inconsistencies of visual judgment. Remember, however, that a machine is not a human eye, and thus the consistency of instrumental measurement should always be paired with an understanding that regardless of its numerical values, an object’s color could still appear differently depending on who is looking at it and where. While color-identifying instruments are very useful for scientific color measurement, there are a few things to keep in mind when using an instrumental approach. First, know your instrument. An advantage that eyes have over instruments is that you know exactly how to use them. complex instruments, however, could easily have a misadjusted setting that confuses your measurements if you are not intimately familiar with the mechanism’s workings. Ensure that whatever equipment and procedures you use will deliver results within acceptable error tolerances, and that you know how precisely your instrument will measure. Account for angle of viewing and the reflective properties of any gloss or coatings that could confound your measurements as well. ” 40-43 Beck_046854 IndustryNews.QXD 12/16/14 8:15 AM Page 41 If you choose to compare colors visually, know that the methodology you select can affect color measurement outcomes. Principles of Color Analysis ” Once you’ve determined the methodology you will use for color examination and have your measurements, it’s time to analyze your findings. the biggest key for color analysis is to remember that perceptibility is not the same as acceptability. Perceptibility of the difference between color samples is determined by whether they look different to you; acceptability of the variance between the two samples is established by values set in place by tolerances that vary from application to application. In some cases, perceptible variations may be deemed acceptable based on the governing parameters of an agreement, and discarding a batch of materials based on visual analysis alone could be a costly mistake. On other occasions, depending on visual perception of color variance could mean shipping a batch of product that does not meet specifications. to avoid these issues, focus on computing whether the variance between two colors falls within a set tolerance rather than whether you can see a difference. Establishing color tolerances When analyzing the acceptability of a color batch, you will be scrutinizing values that portray nuanced variations between color samples. Instrument readings will convey information such as: • ∆l: the difference in lightness/darkness • ∆A: the difference in red/green values • ∆B: the difference in yellow/blue values • ∆c: the difference in chromaticity • ∆E: the spectral “distance” between the two colors • ∆H: the difference in hues these values are used to determine graphically whether a batch “passes” or “fails” based on specified tolerances. www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstIcs ENgINEERINg | 41 40-43 Beck_046854 IndustryNews.QXD 12/16/14 8:15 AM Page 42 How to Measure Color__________________________________________ there are a number of ways to determine whether a batch falls within an acceptable tolerance, but not all methods of designating a tolerance are equally advisable. One option, for instance, is to create a “pass/fail” box centered upon the color values of the standard against which you are measuring (Figure 1). the box shows the area within which a batch must fall on the graph. if the value is within the box, it is likely to be acceptable, but not in all instances. the box assumes a linear, uniform behavior of color space, which is not an accurate assumption. another method is to use a circle centered upon the color values of the standard to determine whether the spectral distance between the standard and batch is small enough to fit within the circle, and therefore be deemed acceptable (Figure 2). However, as in the option of the square box, it assumes linear, uniform behavior of color space, which is not accurate. the third option is to create an elliptical pass/fail system based on an equation set forth by the color Manufacturing council (Figure 3). this system places a customizable emphasis on hue and chromaticity value, allowing you to determine how much weight is placed on the hue and chromaticity differences of the two colors. the ability to adjust hue and chromaticity ratios in your calculations is important because the area of the color space in which your colors fall can impact how perceptible hue and chromaticity variances will be, and thus it’s beneficial to weigh variance in neutral and high chromaticity colors differently. commonly used ratio values are 2:1 to determine acceptability. Figure 3: An elliptical pass/fail equation-based system places a customizable emphasis on hue and chromaticity Figure 1: A “pass/fail” box, centered upon the color values of a standard, shows the area within which a sample batch value must fall. Figure 2: A circle centered upon the color values of a standard graphically shows the “spectral distance” between the standard and a sample batch. 42 A recommended approach creating an exact match between two colors with no visual difference is both difficult and expensive. Mathematical difference and perceptible difference are two different things, and what really matters is not whether there is variance between two colors, but whether that difference is visually close enough to be acceptable by a customer or consumer. Of the three options, the elliptical pass/fail system gives you the best point of reference when determining a tolerance that accurately reflects whether a batch will meet this criterion. When charting and comparing real-world results of batches that were either accepted or rejected, we find that pass/fail boxes and circles designate as failures a large number of batches that were actually deemed acceptable. if you choose the elliptical pass/fail system, your probability of false negatives and false positives drops dramatically compared to the box or circle systems. the ellipse, accounting for the realities | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 40-43 Beck_046854 IndustryNews.QXD 12/16/14 8:15 AM Page 43 of how we view color in a non-linear, non-uniform space, offers the best chance of saving you time and money. some instruments calculate according to the cMc l:c (color Measurement committee lightness:chroma) equation used to create pass/fail ellipses; in other cases you can run the calculations yourself based on the delta values your instrument reports. For the most part, you can rely on your equipment to do the math. the responsibility to choose the right methodology and tolerance system lies with you, however, so remember your basics. color measurement, to some extent, is a mixture of science and art. this article offers a high-level overview of the subject to help you establish an elementary understanding of color measurement, but there is far more to be said on the topic. Even long-time color measurement veterans often have questions on the appropriate ratios and equipment to use. About the author: Ron Beck joined Americhem in 1976 as a product designer. After over 35 years with the company, Beck has held multiple positions. Currently, Beck specializes in color science, technical statistics, product design, and Six Sigma. Beck’s future goals for Americhem are to implement the company’s vDesign® program and exploit its new capabilities to change the business model for color concentrates, as well as to utilize his Six Sigma Black Belt training to improve plant efficiency. He can be reached at rbeck@americhem.com or +1 330-3543346. Bioplastics Re-Invention of Plastics via Renewable Chemicals !' #2' 1-'#3'& 40 #//05/%' 052 4* %0/('2'/%' 0/ +0-#34+%3 +#.+ -02+&# #/5#28 0/('2'/%' *'.' 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Carteaux SPI President and CEO D omestic demand for plastics industry products grew at a record-breaking pace in 2013, reflecting the value of manufacturing to the U.S. economy, a report released by SPI staff said. The latest figures available show that the U.S. plastics manufacturing industry operates as a $374 billion sector that employs 900,000 men and women with representation in each of our nation’s 50 states. SPI’s 2014 Global Business Trends report indicates that the domestic demand for plastics industry goods grew 6.5%, from $251 billion in 2012 to $267 billion in 2013. The previous high was $262.6 billion in 2006. Surpassing previous consumption levels confirms that the U.S. plastics manufacturing industry is a major player in the world’s economy. And while U.S. exports of raw materials continue to show profitability, thanks in part to increases in shale gas supplies, domestic demand holds the key to a wealth of job growth and economic benefits for firms that invest in the nation’s manufacturing renaissance. The U.S. resin trade surplus has grown in dollar terms, falling off slightly during the 2008-2009 recession, and again in 44 Bill Carteaux 2012-2013, because of strength in the U.S. economy relative to the rest of the world. Meanwhile, the U.S. manufacturing trade balance has improved in part due to “reshoring,” or the return of manufacturing operations that had been “offshored” to other countries. Our country has become more competitive for four main reasons: low wage inflation, a lower-valued dollar, high productivity, and abundant energy. Exports resumed growth in 2013, recording a 2.7% increase across most sectors (resins, plastic products, and molds), excluding machinery. However, machinery sales and exports historically expand on a triennial basis in conjunction with NPE, SPI’s premiere international plastics showcase. (NPE2015 is scheduled for March 23-27, 2015, in Orlando, Florida, USA.) Because of the flourishing domestic market, more production was needed in 2013 to meet the demand. The ratio of industry exports to domestic shipment fell from 22.2% in 2012 to 21.5% in 2013—another sign of an improving U.S. economy. As has been the case in recent years, Mexico and Canada remain the U.S. plastics industry’s largest export markets, with $14.9 billion in exports going to Mexico and $12.5 billion to Canada in 2013. The industry had its largest trade surplus with Mexico in 2013, at $10.8 billion, which is largely attributable to the North American Free Trade Agreement (NAFTA). U.S. plastics companies continue to take advantage of duty-free access | PlASTICS ENGINEErING | JANUArY 2015 | www.4spe.org | www.plasticsengineering.org 44-47 Inside SPI_046854 IndustryNews.QXD 12/16/14 11:45 AM Page 45 to Mexico’s market, and this should serve as an indication of the potential positive trade benefits that await the U.S. should it successfully conclude negotiations on the Trans-Pacific Partnership (TPP) and the Transatlantic Trade and Investment Partnership (TTIP). Analysis of the report also demonstrates the opportunity within the U.S. plastics industry to reshore manufacturing positions. According to the Reshoring Initiative, bringing jobs back to the USA reduces the cost of ownership and improves quality and consistency, among other reasons. The report also provides deep insight into industry-wide trends as well as movements in molds, resins, machinery, and plastic products. Among the key findings in the resin sector, the report states that resin exports have been competitive as feedstock costs have fallen in response to growing shale gas supplies. While U.S. natural gas costs rose 35.4% in 2013, crude oil prices rose only 4%. The price of oil is higher than the price of gas on a weight or Btu basis, therefore the domestic industry, which relies primarily on gas-based feedstocks, continues to have a significant cost advantage over the majority of overseas resin competitors that use crude oil-based feedstocks. Here are few more facts: • The U.S. resin industry had a $20.5 billion surplus in 2013 (it was about the same in 2012). • Resin exports increased 2.2%, while imports increased 5.5%. • Plastics product trends: The estimated value of plastic products contained in exports was $27 billion, and the estimated value contained in imports was $47.6 billion, giving the USA a $20.6 billion deficit in contained plastic product trade. • Mold trends: The U.S. moldmaker market share was 54.7% market share in 2013, compared with 55.5% in 2012. • Machinery trends: The U.S. machinery producers’ market share was 36.6% in 2013, up from 34.5% in 2012. If you’re interested in an analysis of the report, I would invite you to view a replay of the recent webinar, “America’s Competitive Position in a Global Economy,” accessible on our website at www.plasticsindustry.org. Along with Michael Taylor, SPI’s senior director of international affairs and trade, other speakers were Cliff Waldman, director of economic studies at Manufacturers Alliance for Productivity and Innovation (MAPI), and Harry Moser, Reshoring Initiative founder and president. The full report is also available at www.plasticsindustry.org. Plastics Machinery Shipments Continued to Rise in Q3 M arket demand for plastics machinery continued to grow in the third quarter of 2014, according to statistics compiled and reported by SPI: the Plastics Industry Trade Association’s Committee on Equipment Statistics (CES). “The market conditions that drive investment in new industrial equipment have prevailed throughout all of 2014, and I expect these conditions to persist in 2015. These are: low interest rates, and the need for increased productivity in order to meet rising aggregate demand," according to Bill Wood, the plastics market economist who analyzes and reports on the plastics machinery market sector for the CES. Shipments of primary plastics equipment (injection molding, extrusion, and blow molding equipment) for reporting companies totaled $301.4 million in Q3. This is 6% higher than the revised shipments total of $284.3 million in Q2 of this year, and is down only 2% compared with the robust total from Q3 of www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlASTICS ENGINEERING | 45 44-47 Inside SPI_046854 IndustryNews.QXD 12/16/14 8:05 AM Page 46 INSIDE SPI 2013. For the year to date, the total value of primary equipment shipments is up 6% compared with last year. a closer look at the cEs data shows: • the shipments value of injection molding machinery decreased 4% in Q3 of 2014, compared with the total from Q3 of 2013 (for the year to date, shipments of injection molding machinery are up 4%). • the shipments value of singlescrew extruders dropped 14% in Q3, compared with last year (for the year to date, single screw extruder shipments are down 6%). • the value of shipments of twinscrew extruders (which includes both co-rotating and counter-rotating machines) jumped 33% in Q3 (for the year to date, shipments of twin screw extruders are up 35%). • the shipments value of blow molding machines advanced by an estimated 27% in Q3 (for the year to date, shipments of blow molding machinery are up an estimated 25%). the cEs also compiles data on the auxiliary equipment segment (robotics, temperature control, materials handling, etc.) of the plastics machinery industry. new bookings of auxiliary equipment for reporting companies totaled a record-breaking $108.2 million dollars in Q3. this represented a gain of 8% compared with the total from Q3 of 2013. For the year to date, bookings of auxiliary equipment are up 12%. the trend upward in the cEs data on plastics machinery shipments corresponds with the trends in the two major data series compiled by the U.s. 46 government that measure activity levels in the industrial machinery sector. according to the Bureau of Economic analysis, business investment in industrial equipment escalated by 16% (seasonally-adjusted, annualized rate) in Q3 when compared with Q3 of 2013, and for the year to date investment is up 13%. the other important machinery market indicator, compiled by the census Bureau, showed that the total value of new orders of industrial machinery jumped 47% in Q3 when compared with the total from last year, and for the year to date, industrial machinery orders are up a stellar 34%. “From a global perspective, the north american region will be the strongest in terms of total economic activity in the coming months,” says Wood. “With the exception of china and india, the economic activity in most of the other major economic regions of the world will see sluggish or even negative growth. But strong demand in the U.s. helps to sustain the momentum in the global economy in 2015.” the cEs also conducts a quarterly survey of plastics machinery suppliers that asks about present market conditions and expectations for the future. the responses from the Q3 survey indicate that machinery suppliers remain optimistic about the market demand for their products in the coming months. When asked about expectations for future market conditions, 95% of the respondents expect conditions to stay the same or even improve in the coming quarter, and 98% expect them to hold steady or get better during the next 12 months. there is a strong consensus that north america is the global region where the most promising market conditions are expected in the coming year. Expectations for Mexico improved substantially when compared with the responses from last quarter. Expectations for latin america, asia, and Europe were lowered. as for the major end-markets, the respondents to the Q3 survey expect that automotive and medical will remain strong in terms of demand for plastics products and equipment. Expectations for packaging, appliances, and construction improved when compared with the previous quarter. the industry and survey analysis that appears in this media report was contributed by Mountaintop Economics & research, inc. (MEr), a supplier of market analyses and forecasts for decision makers in the plastics industry. MEr founder Bill Wood (billwood@plasticseconomics.com) is a plastics market economist with more than 25 years of experience in industrial market analysis and forecasting. the sPi committee on Equipment statistics collects monthly orders and shipments data from manufacturers of plastic injection molding, extrusion, blow molding, thermoforming, hot runners, and auxiliary equipment. a confidential, third-party fiduciary, VEris consulting, llc, compiles the monthly data and analyzes individual company data for consistency and accuracy. Once this crucial process is completed, VEris aggregates and disseminates reports to participating companies. if this is something you and your company are interested in please contact Katie Masterson at kmasterson@plasticsindustry.org or +1 202-974-5296. | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 44-47 Inside SPI_046854 IndustryNews.QXD 12/16/14 8:14 AM Page 47 JOIN THE R RACE AC E T O FIND YOUR FUTUR IN THE POLY MER & PL ASTICS INDUST REGISTER YOUR TODAY! OD AY REGISTERYOUR YOUR YOURTEAM TEAMT TODAY! TOD A!Y! FIRST TT P PLACE LP ALCE TEAM WINS ACE TEAM FIRST PLACE WINS F FOUR OUR $ $1,500 1$ ,15,05000 AP APPLE PLE GIF GIFT FT TFT C CARDS! ARDS ! ! F OUR AP PELE E GIFT GIF T C ARDS FOUR $1,500 APPLE CARDS! Additional A dditional gif gift ftgif t ccards ds darrds priz prizes es tto ob be aw awarded arded Additional A dditional gift ftar t rccards dand and priz prizes es tto oe b be e aw awarded arded @ TThe Plastics RACE ® Join us ANTEC® 2015 @ NPE for an exciting new t team-centered, Smartphone-based question and answer hunt. Plot your course from one sponsor location to t the next, scan a specialized code posted in the booth and answer a randomly generated question testing your general knowledge in the fields of polymer science, polymer chemistry, plastics engineering and more. Points are totaled at the end of the race, winners d determined and PRIZES ARE AWARDED! Tuesday, March 24, 2015 10:00 am - 4:00 pm • • Network with fellow race participants a and booth personnel Learn about specific products & services from sponsoring companies • Connect with future employers to find o out who is recruiting • Test your knowledge of the polymer a and plastics industries • Race for amazing prizes! Interested in participating as a sponsor? ACT NOW! There are a limited number of sponsorship opportunities available for this event! www.4spe.org/antec/tpr 48-53 Industry News_046854 IndustryNews.QXD 12/16/14 8:04 AM Page 48 Industry nEws Energysafe pigments from Eckart are designed to substantially increase the solar reflectance properties of plastics across a very wide color space. Plastics with Energysafe graphite Black reflect up to 33% of the incident solar energy (that is, they exhibit a total solar reflectance (tsr) of 0.33). tsr-optimized formulations restrict or even eliminate the use of carbon black; for comparison, plastics pigmented with carbon black have a tsr below 5%. Energysafe graphite Black can be used to adjust the darkness or L values of plastics articles. it contributes to decreasing the rate of absorption of sunlight. this effect can lower overall heat build-up, thus leading to plastics with reduced surface temperatures. surfaces of plastic articles with high solar reflectivity will stay cooler under the sun’s powerful radiation. the product opens up immense potential for the realization of “cool plastics” in very dark shades, while high tsr efficiency—corresponding to low near-infrared absorption—results in reduced heat build-up. this cooling effect may be useful for automotive application like vehicle dashboards or other plastics interior parts which are strongly exposed to sunlight. it’s suitable for polyolefins, engineering plastics, and for PVc, and provides new Photo courtesy of Eckart 48 design opportunities for solar reflective plastics in very dark shades. and Energysafe does not require a reflective substrate, the company adds. www.eckart.net Canatu, a manufacturer of zeroreflectance and flexible transparent conductive films and touch sensors, today launched cnB™ in-Mold Film, a stretchable, formable, conductive film optimized for 3-D formed capacitive touch displays and touch surfaces for automobile center consoles and dashboards, home appliance control panels, remote controls, smartwatches, and portable electronic devices. “touch has recently become the dominant user interface for tablets, smartphones, and other consumer products. One of the remaining challenges for product designers is to build touch sensors into formed or backmolded plastic parts,” says Erkki soininen, vice president of marketing and sales at canatu. “this is especially challenging when those parts involve 3-D shaped curved surfaces. canatu now has a solution to this design challenge. cnB in-Mold touch sensors free user-interface designers from the flat-surface paradigm, making responsive touch on 3-D surfaces a reality.” cnB film is stretchable up to and beyond 100% and can be easily formed and back-molded using standard industrial processes such as film insert molding. this means that cnB touch sensors can be produced in almost any shape, from smooth spherical domes to sharp-edged casings with recesses and bulges. With cnB-based touch sensors, mechanical buttons in automotive dashboards, portable and wearable devices, washing machines, clothes dry- Photo courtesy of Canatu ers, dishwashers, ovens, and other appliances can be replaced with a robust water- and dust-proof 3-Dformed touch user interface. www.canatu.com More than 250 high-speed extruders from battenfeld-cincinnati have now been installed on all continents of the world. Whether for thermoforming sheet, industrial sheet, or edge bandings, the high-speed machines excel in the sheet industry by their enormous output combined with low energy consumption and modest space requirements. For ten years now, the german-austrian extruder specialist has achieved market success with a complete series of high-speed extruders. now this pioneer in this special technology is extending its machine portfolio by adding an adiabatic extruder which uses about 10% less specific energy. the high-speed 34D-long single-screw extruders, with a screw diameter of 75 mm, reach outputs of up to 1.8 ton/hr and operate with screw speeds of up to 1,500 rpm. this is how high outputs | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 48-53 Industry News_046854 IndustryNews.QXD 12/16/14 8:04 AM Page 49 automotive awards program for our collaborative efforts in replacing metal to improve production efficiency, reduce weight, and raise performance,” says Kurt schuering, vice president, global Key Accounts. www.polyone.com Photo courtesy of battenfeld-cincinnati can be achieved with a small machine size, and with optimal melt attributes. the extruders are used for PP, Ps, APEt, cPEt, PlA, and PE processing, as well as in Pc sheet lines. Based on extensive field experience and latest findings from laboratory tests, battenfeld-cincinnati has now developed an adiabatic high-speed extruder with virtually optimal energy efficiency. this new process technology has made it possible to reduce energy consumption by yet another 10% compared to previous high-speed models, which already use 25% less energy than conventional extruders with the same output rates. After this high-speed model was presented at the K 2013 for the first time, the pilot machine has now been in production operation for several months. this machine is laid out for a medium output range of 800 kg/hr (900 kg/hr for PP and Ps). in addition to its low energy consumption, the processing machine stands out with an extremely low noise level in operation and a 10% higher specific feed rate. Apart from the advantages already mentioned, the machine‘s heat emission to its environment has also been reduced considerably by the new process technology concept. this significantly improves production con- ditions, especially during the summer months, the company explains. www.battenfeld-cincinnati.com PolyOne was recognized at the sPE Automotive innovation Awards ceremony for its participation in developing an all-plastic temperature sensor, which will be commercially introduced on the 2015 Ford Edge. the sensor directly measures and averages duct air temperatures to control heating and cooling in the vehicle. the new patent-pending sensor, a finalist in the Body interior category, is easier to assemble and weighs 38% less than the current metal design. the sensor’s design eliminates the need for a rubber O-ring, simplifying assembly and blocking duct leakage paths. in addition, the new sensor’s faster response time leads to improved occupant comfort and better fuel economy. PolyOne worked with sensor manufacturer tDK-EPc corp. to define performance and processing parameters, then formulated a specialty polyamide-based material for the application. “We are extremely pleased to once again be recognized by this prestigious Amcor Rigid Plastics, a manufacturer of rigid plastic packaging for food, beverage, spirits, home/personal care, and healthcare industries, has announced the development of unique hot-fill polyethylene terephthalate (PEt) containers which accept metal lug closures—a first for the food packaging industry. the breakthrough technology, called the APEX63tM system, was unveiled at the Private label Manufacturers Association (PlMA) annual trade show Nov. 16-18 in Rosemont, illinois, UsA. the innovative technology allows the fitment of metal lug closures to blowand-trim 24-oz. hot-fill containers, the company explains. For the first time, Photo courtesy of Amcor www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 49 48-53 Industry News_046854 IndustryNews.QXD 12/16/14 8:04 AM Page 50 InduStry newS consumers who are familiar with the look and quality feel of a glass jar with a metal lug closure can now enjoy the same quality and reassurance of the fresh “pop” of a metal lug closure on a lightweight, shatter-proof PEt jar. the a-PEX63 tM system ensures that sealing integrity is maintained and meets the industry average for removal torque (ease of opening). Brand owners can also maintain the same brand equity with the switch from glass to PEt. the patent-pending technology was achieved through the use of advanced design and engineering techniques, according to Bunlim ly, senior marketing manager for amcor rigid Plastics. “this is a major development which firmly positions PEt hot-fill containers in the food packaging industry,” says ly. “We’ve filled an important need for consumers and brand owners who seek the benefits of PEt containers with met- Photo courtesy of Sikora 50 al lug closures, delivering the same quality and freshness associated with glass along with significant performance, manufacturing, and sustainability benefits.” www.amcor.com For continuous quality control in hose and tube extrusion lines, Sikora lump detectors are just as essential as diameter measuring devices. the 2- and 3-axis lump detectors lump 2000 XY and lump 2000 t detect the smallest lumps and neckdowns on the product surface fast, precisely, and with high reliability. By the use of a powerful signal processor, the number, height, depth, and length of the faults are evaluated. the combination of the double sensor technology (differential measuring principle) with infrared light sources ensures reliable fault detection, even under difficult conditions such as dirt or extreme vibration. the lump detector is sturdy, and due to its small dimensions, it can easily be installed in every extrusion line. the setting of tolerance thresholds and the visualization of lumps and neckdowns are realized with sikora’s remote 2000 or a processor system of the Ecocontrol series. alternatively, the lump 2000 devices can be directly integrated with the line control via various customer interfaces such as Profibus or universal field bus modules. www.sikora.net the Kenics™ thermogenizer from Chemineer is a post-extrusion mixing device that provides superior color and additive distribution and uniform tem- Photo courtesy of Chemineer peratures over a broad range of thermoplastics, including nylons, polyethylenes, styrenes, acrylics, cellulosics, and vinyl resins. Mixing is achieved by a stationary, helical Kenics static Mixer element assembly, which induce flow divisions in the melt stream. this flow splitting combines with axial rotation of the stream, thus ensuring the continuous transfer of material back and forth between the wall and the center of the stream. Kenics thermogenizers can be supplied with electrical band heaters and thermocouple ports for wall temperature control. available in 1-, 1½-, 2-, 3-, and 4-inch (2.5-10 cm) diameters, they install easily between the exit of an extruder and the accompanying die. www.chemineer.com Promising more accurate temperature control and long-term reliability, new EsE series Earthsmart™ central chillers from Conair give plastics processors the flexibility to start with one chiller and expand to a plant-wide multiple chiller system operated by a single controller. EsE chillers are available with integrated pumps and fluid reservoir or as a standalone chiller to supply a sepa- | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 48-53 Industry News_046854 IndustryNews.QXD 12/16/14 8:04 AM Page 51 48-53 Industry News_046854 IndustryNews.QXD 12/16/14 8:04 AM Page 52 InduStry nEwS rate pump tank system. Systems can be water cooled, using tower water, or can be installed in a remote-air-cooled condenser configuration. There are 12 different sizes available, from 10 to 160 tons, with a single refrigeration circuit available on units from 10 to 80 tons in capacity, and dual refrigeration circuits available from 20 to 160 tons. Each refrigeration circuit has two Copeland scroll compressors, so the system can stay up and running even if one of the compressors should require maintenance, the company explains. To meet immediate process requirements and allow for future expansion, users can install one or more ESE chillers and then add more modules up to a total of six for cooling capacities up to 960 tons. All units—up to a total of 12 refrigeration circuits—can be connected to a single control interface using twisted-pair wiring, for centralized control of all chiller circuits. www.conairgroup.com A new method of Eco Bio Plastics Midland, Inc. (EBPM), in which cellulosic material and post-industrial waste paper can be used to create bioplastic products, is said to be leading the way to sustainability. The patented technology was first created in Tokyo, Japan, by the Eco Research Institute, one of Asia’s biggest bioplastics manufacturers. A joint venture with the Michigan Molecular Institute, a leader in advanced polymer research, has allowed the resulting earth-friendly composite resin, called Mapka, to become available to customers in North America. 52 Mapka resin is created by dry-grinding various types of cellulose, the most abundant organic material on the planet, down to a mean particle size of 20 microns. It’s then incorporated into plastics as a physical and mechanical property-enhancing filler. Ultimately, these fillers can comprise up to 65% of the total weight of the product and are virtually undetectable to the naked eye. This concept of incorporating a cellulosic material into plastics is not new; however, EBPM’s patented pulverization technology allows the idea to go far beyond traditional composites. “When you compound plastic with organic material, you need that material to be a very fine powder,” says Fukuji Saotome, vice president of EBPM. “We are the only manufacturer in the world with the ability to do that on a large, commercially viable scale.” With the technology, EBPM says it will cater to a large variety of industries looking to reduce their reliance on unsustainable materials, such as plastics, and make their products better for the environment. Materials can be customized to fit customers’ specific application and property requirements. The technology also facilitates closedloop recycling systems for companies with their own scrap paper materials. www.ecobioplastics.com Solvay Specialty Polymers has unveiled an enhanced version of its Lavanta® high-performance polyester for production of light-emitting diodes (LEDs) for televisions and backlight unit applications. The second-generation product—Lavanta 5115 WH 224— reportedly provides significantly Photo courtesy of Solvay improved processability while maintaining its high heat and light stability. “This second-generation material is an important achievement because it exceeds the processing requirements of the LED industry, enabling molders to maximize productivity and achieve greater efficiencies,” says Glenn Cupta, global business development manager for electrical/electronics for Solvay Specialty Polymers. “The enhanced processability is achieved without sacrificing the excellent initial whiteness and whiteness retention of the material.” Cupta notes the growing trend among television manufacturers to use fewer LEDs to reduce cost. This is accomplished by sending higher amperage (current) through the LED, resulting in significantly higher junction temperatures above 100°C (212°F) and greater brightness. Previously used materials are unable to withstand the higher heat and light output, discoloring prematurely in applications such as reflector cups. www.solvay.com | PLASTICS ENGINEERING | JANUARY 2015 | www.4spe.org | www.plasticsengineering.org 48-53 Industry News_046854 IndustryNews.QXD 12/16/14 8:04 AM Page 53 & && >/ &6&29 *335& ! ! .5$1 3.18 $".-# 18 3.1($2 && &" !% $ &" !% !! &" !% #! % &"%-*/& &$&.#&2 <-0#"-*:"4*0/ 05/%4"#-&= /*6&23*49$0..&2$*"- 1"24/&23)*13 40 %&6&-01 1-"34*$3 120'&33*0/"-3 *2*/( 2&/%3 .1/.1 3$ (-5$23,$-3 2423 (- !(+(38 $-$1&8 1$2(-2 3'$1,./+ 23("2 3'$1,.2$32 2 ".,/.2(3$2 !(./+ 23("2 /1(, 18 , "'(-$18 3..+(-& ,.+#(-& $73142(.- 47(+( 1($2 3$23(-& 2$15("$2 , "'(-$2 ,.-(3.1(-& (-2/$"3(.- '$1,.2$3 4! 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(', !, (% '" +)$'(+ *#+)$'(+ -$%#.!(& / 54-57 Patents_046854 IndustryNews.QXD 12/16/14 8:03 AM Page 54 Industry PAtEnts By roger Corneliussen renewable Plasticizers Us Patent 8,802,877 (august 12, 2014), “Process for Modifying Vegetable Oils and Primary Plasticizer for Vinyl Polymers,” Milton sobrosa cordeiro, sergio teixeira, and ariovaldo Fernandes, Jr. (nPc industrias Quimicas ltda., Mogi das cruzes, Brazil). Epoxidized vegetable oils have been used in small proportions as secondary plasticizers and thermo-co-stabilizers in the production of flexible, semi-rigid, and rigid polyvinyl chloride materials. However, the use of epoxidized triglycerides as primary plasticizers results in exudation due to limited compatibility with the polymeric matrix. cordeiro et al. developed compatible plasticizers for vinyl polymers by transesterification of vegetable oils and alcohols, catalyzed by an alcoxide generated by the reaction of an alcohol with an alkaline metal. Controlled release Us Patent 8,808,752 (august 19, 2014), “controlled release articles and Method for Producing the same,” Junji Oshima (Japan Envirochemicals, ltd., Osaka-shi, Osaka, Japan). Micro-encapsulation of antibiotics for preventing microorganism growth enables a slow controlled-release for lasting effects. this is done by interfacial polymerization involving an oil phase and an aqueous phase. this blending of different phases is complicated, leading to increased ingredient 54 and production costs. Oshima developed a simple process by dissolving the hydrophobic antibiotic in a hydrophobic acrylic monomer, dispersing the solution in water and polymerizing the monomer with an oil-soluble initiator. to be successful the antibiotic has a melting temperature less than 80°c. this process is simple, leading to decreased costs at all levels with good performance. the antibiotic is selected from a sterilizer, antibacterial agent, antiseptic, anti-algae, fungicide, herbicide, insecticide, attractant, repellent, rodenticide, etc. having antibiotic activities. non-toxic Flame retardants Us Patent 8,814,998 (august 26, 2014), “Method of Preparation and application for Flame retarding composition,” aziz Khadbai, Joseph roberts sparling, James Burton anderson, and ian Douglas Buchanan (texas, Usa). Many consumer products use combustible materials such as wood, plastics, synthetic wood, and composites requiring flame retardants. However, common flame retardants can be toxic and dangerous to health. Khadbai et al. developed water-soluble coatings of phosphates and borates. such coatings are safe and effective flame retardants and can be applied by coating, painting, dipping, or spraying. an example water solution consists of 69-81 wt% water, 1-20 wt% ammonium polyphosphate, 4-5 wt% sodium borate, 4-5 wt% boric acid, and 0.8-1 wt% hydrogen peroxide. Light-Emitting diodes Us Patent 8,815,414 (august 26, 2014), “Polymer compound and Polymer light Emitting Device using the same,” shigeya Kobayashi, and Hidenobu Kakimoto (sumitomo chemical company, limited, tokyo, Japan). certain polymers can form light-emitting compounds but they have insufficient light emission efficiency (light emission luminance per electric current). Kobayashi and Kakimoto developed lightemitting materials based on substituted benzocyclobutanes these polymers combined hole-transporting material with electron-transporting material, light-emitting material, stabilizer, and antioxidant. cyclobutane is condensed to aromatic rings such as benzene, naphthalene, anthracene, and pyrene and may have different substituents such as alkyl, alkoxy, alkylthio, and aryl groups. a polymer light-emitting device consists of a polymer electron-transporting layer between a cathode and a light-emitting layer, and a polymer hole-transporting layer between an anode and a light-emitting layer, resulting in a maximum outer quantum yield of 1.5 % when a voltage is applied between an anode and a cathode. Polymeric dyes Us Patent 8,816,040 (august 26, 2014), “Polymer Dye,” takaki Kanbara, Junpei Kuwabara, Hikaru Yamada, and nobutaka Fujimoto (Univ. of tsukuba, tsukuba and sumitomo seika chemi- | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 54-57 Patents_046854 IndustryNews.QXD 12/16/14 8:03 AM Page 55 cals co., ltd., Kako-gun, Japan). in many color applications, a metallic luster is desirable without problems of metallic fillers. Metallic problems range from solubility and toxicity, to blocking electromagnetic waves and corrosion. in addition, metals often require expensive and costly plating processes. Kanbara et al. developed a polymer dye with a metallic luster for a variety of colors, without containing any metals. the 2000 to 50,000 number-average molecular weight polymer contains monocyclic heterocyclic groups such as diketopyrrolopyrrole, squalene, or carotene. Reactive Nanoparticles Us Patent 8,816,107 (August 26, 2014),”Functionalised Nanoparticles, their Production and Use,” giovanni Baldi, Alfredo Ricci, Mauro comes Franchini, Daniele Bonacchi, and Marco Bitossi (colorobbia italia s.p.A., sovigliana-Vinci, italy). Nanoparticles are usually not soluble in a hydroalcoholic environment, which is very important for biomedical and pharmacological applications. Baldi et al. found that mono- and di-functional compounds are able to bind with nanoparticles of transition metal oxides and metals, forming stable complexes. the functionalized nanoparticles can be used in processes which require a specific hydrophobic/hydrophilic behavior such as the production of plastics (e.g., polyethylene or polyester) or synthetic fibers (e.g., nylon) and natural fibers (e.g., cotton). Piezoelectric Polymer Us Patent 8,829,121 (september 9, 2014), “Piezoelectric Polymer Material and Method for Producing same,” Mitsunobu Yoshida, shunsuke Fujii, Hitoshi Onishi, Yoshiro tajitsu, taizo Nishimoto, Kazuhiro tanimoto, and Kenichi goto (Mitsui chemicals, inc., Minato-ku, tokyo, and Kansai Univ., suita-shi, Osaka, Japan). in piezoelectric materials, mechanical stress results in electrically charged materials. typical piezoelectric materials are PZt (PbZrO3–PbtiO3-based solid solution), which is a ceramic material. However, since PZt contains lead, toxicity is a problem, reducing potential medical applications. Because piezoelectric polymeric materials are generally electrically inferior to PZt, there is demand for improved polymer piezoelectric materials. Yoshida et al. developed a helical chiral polymer such as polylactic acid with a weight-average molecular weight of 50,000-1,000,000, optical activity, and 20-80% crystallinity, showing enhanced piezoelectricity. this polymer can also be blended with polyvinylidene fluoride for piezoelectric materials. Biodegradable Sorbents Us Patent 8,829,107 (september 9, 2014), “Biodegradable superabsorbent Polymer composition with good Absorption and Retention Properties,” Franck Furno, Harald schmidt, and Nicolaas De Bruin (Evonik Degussa gmbH, Essen, germany). superabsorbent polymers based on acrylic acid or acrylates are not biodegradable and, therefore, not environmentally friendly. Furno, schmidt, and De Bruin developed a biodegradable superabsorbent polymer by adding starch to the monomer mixture during polymerization of the superabsorbent polymer. the starch compound is introduced into the monomer solution as a powder or powder suspension and then polymerized to form a hydrogel. the hydrogel has a water content of 30 to about 80 wt% and is an easily kneadable dough-like mass. the monomers are unsaturated monomers copolymerizable with acrylamides and methacrylamides or vinylamides. Aramid Polymerization Us Patent 8,835,600 (september 16, 2014), “Process of Forming an Aramid copolymer,” Kiu-seung lee (E.i. du Pont de Nemours and co., Wilmington, Delaware, UsA). Forming aramid copolymers is difficult because of the very different reactivity ratios of the reactants. lee developed a method for forming a controlled copolymer composition by mixing two organic (N-methyl-2-pyrrolidone (NMP) or dimethylacetamide) solutions. One of the solutions contains a precise ratio of amino phenyl benzimidazole and paraphenylene diamine dihydrochloride. the other solution with the same solvent contains terephthaloyl dichloride. Polymerization occurs when the two solutions are mixed. Hcl forms a rigid monomer, enabling precise copolymerization to high molecular weights. Food Packaging Us Patent 8,840,826 (september 23, 2014), “Method of Making Multilayer container,” Katsuro sasauchi and Jun Kawata (Nakamoto Packs co., ltd., Osaka, Japan). Most food containers are formed by thermoforming sheet plastics. However, many food products are heated by microwaves to 100°c. Most thermoplastic containers do not have high heat www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 55 54-57 Patents_046854 IndustryNews.QXD 12/16/14 8:03 AM Page 56 Industry PAtEnts resistance and transparency for this situation. sasauchi and Kawata found a suitable thermoformed multilayer sheet consisting of an a-PEt layer and a functional resin layer with oxygen barrier properties and impact resistance. During thermoforming there are two stretching and heat setting processes. Hydrogels Us Patent 8,841,408 (september 23, 2014), “Macromonomers and Hydrogel systems using native chemical ligation, and their Methods of Preparation,” Phillip B Messersmith, Bi-Huang Hu, Jing su (northwestern Univ., Evanston, illinois, Usa). Hydrogels are hydrophilic polymeric networks which can absorb and retain large amounts of water. Hydrogels are useful in controlled release systems for drug delivery, tissue repair, and tissue engineering, and as surgical sealants and adhesives. although great progress in medical applications of hydrogels has been made, it remains challenging to develop cross-linking methods that satisfy the demanding biological and handling requirements for medical treatment. accordingly, there is an unmet need for biocompatible hydrogels capable of deployment by minimally invasive methods and solidification under physiological conditions. Messersmith, Hu, and su developed biocompatible macromonomer hydrogels using a thioester that readily reacts with an n-terminal thiol (cysteine) through transesterification and rearrangement to form an amide bond through a fivemember ring intermediate. 56 Barrier sensors Us Patent 8,845,969 (september 30, 2014), “Material, system, and Method that Provide indication of a Breach,” Mahalaxmi gita Bangera, Michael H. Baym, roy P.Diaz, roderick a. Hyde, Muriel ishikawa; Y., Edward K. Y. Jung, Jordin t. Kare, Erez lieberman, nathan P. Myhrvold, Dennis J. rivet, Michael a. smith, Elizabeth a. sweeney, and lowell l Wood, Jr. (the invention science Fund i, llc., Bellevue, Washington, Usa). Barrier materials are very useful, but if the barrier is broken, the effects can be serious. some signaling system indicating a breach would be helpful. Bangera et al. developed a multilayer film barrier with a barrier layer and a signaling layer for clothing, like gloves. a breach in some way changes sends an electromagnetic signal to a detector. the detector can include a radio frequency identification sensor and/or a radio frequency identification reader. this material may also include a second signaling layer which emits a chemical when broken. the signaling layer is based on optical fibers which changes a signal when broken. the second signaling layer is formed by coating with or dipping into a liquid containing an indicator chemical. Polynorbornene Us Patent 8,835,580 (september 16, 2014), “catalyst for norbornene Monomer Polymerization and Method for Producing norbornene Polymer,” satoshi Fujibe and nobuyuki Kibino (showa Denko K.K., tokyo, Japan). Polynorbornene is one of the cyclic polyolefins that are special in that the crystals are very similar to the amor- phous phase, resulting in strength, stiffness, transparency, and heat resistance. applications include optical films with a low glass transition of 35°c. the addition of polar groups could greatly expand its usefulness and improve its range of properties. although norbornene monomers are polymerized with transition metal catalysts, polar groups deactivate these catalysts, making polymerization of monomers with polar groups impossible. Fujibe and Kibino developed a catalyst for polar norbornene polymerization. the catalyst is based on a transition metal complex containing a π-allyl ( ξ3-allyl) ligand and a bidentate β-ketoimine ligand as a main catalyst, and a norbornene compound in which a methylene chain is introduced between a norbornene skeleton and an ester group. restoring soil Us Patent 8,802,915 (august 12, 2014), “Hydrocarbon Decomposition for soil and Water remediation,” Pedro Murillo gutierrez (chihuahua, Mexico). there are many methods for cleaning hydrocarbon-polluted soil. these methods are usually based on sequestrants, flocculants, or surfactants which extract the hydrocarbons for transport to some other site. But the hydrocarbon pollution is only transfered to another site and not eliminated. Murillo gutierrez developed a dihydroguaiaretic surfactant with a phosphate source. When mixed with the contaminated soil, the surfactant induces a break-up of the hydrocarbons and oxidation into mineral fertilizers at room temperature and atmospheric pressure. the end product is a fertile soil with complete elimination of the pollutant. | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 54-57 Patents_046854 IndustryNews.QXD 12/16/14 8:03 AM Page 57 One Magazine To Do Everything… Plastics Engineering I O R G N E P FOR ADVERTISING OPPORTUNITIES: ROLAND ESPINOSA • 201 748.6819 respinosa@wiley.com 58-59 Events_046854 IndustryNews.QXD 12/16/14 8:03 AM Page 58 UPCOMING INdUstry EVENts sPE CONFErENCEs sPE E-LIVE® WEBINArs OtHEr UPCOMING EVENts Jan. 14, 2015. single-screw Extruder Analysis and troubleshooting (seminar) site: Polymers center of Excellence, charlotte, north carolina, Usa Contact: sue Wojnicki tel.: +1 203-740-5420 Email: swojnicki@4spe.org Website: www.4spe.org/singlescrew Jan. 15, 2015. “Introduction to Plastics” Jan. 28-30, 2015. BioPlastics: reinvention of Plastics via renewable chemicals site: intercontinental, Miami, Florida, Usa Contact: innoPlast solutions, inc. tel.: +1 973-446-9531 Email: info@innoplastsolutions.com Website: www.BioPlastconference.com Feb. 3-5, 2015. thermoset topical Conference site: le Parker Meridien, Palm springs, california, Usa Contact: shelane nunnery tel.: +1 630-247-6733 Email: shelane@gvineme.com Website: www.4spe.org/Events Feb. 22-25, 2015. International Polyolefins Conference site: Hilton Houston north Hotel, Houston, texas, Usa Contact: David Hansen Email: david.hansen47@yahoo.com Website: www.spe-stx.org/conference.php Feb. 23-25, 2015. 9th European Additives & Colors (ACE) Conference site: Meliá sky Hotel, Barcelona, spain Contact: carine roos tel.: +32 498 85 07 32 Email: croos@4spe.org Website: www.4spe.org/Events March 23-25, 2015. ANtEC® Orlando @NPE2015 site: Orange county convention center, Orlando, Florida, Usa Contact: Barbara spain tel.: +1 508-338-2646 Email: bspain@4spe.org Website: www.antec.ws May 5, 2015. 10th Annual AUtO EPCON site: Detroit Marriott troy, Michigan, Usa Contact: sue Wojnicki Email: swojnicki@4spe.org Website: www.4spe.org/Events 58 Feb. 18, 2015. “degradation Failure of Plastics” March 5, 2015. “Plastic Failure Prevention” April 15, 2015. “the Effects of Impact and Other rapid Loading Mechanisms on Plastics” (all webinars begin at 11:00 a.m. U.s. Eastern time, unless otherwise noted) Contact: Barbara spain tel.: +1 508-338-2646 Email: bspain@4spe.org Website: www.4spe.org/Events/webinars.aspx Feb. 4-6, 2015. Plastics news Executive Forum site: Hilton lake las Vegas resort & spa, nevada, Usa Contact: nicole laPointe tel.: +1 313-446-6078 Email: nlapointe@crain.com Website: www.plasticsnews.com sPE MEEtINGs Feb. 5-10, 2015. Plastindia 2015 site: gandhinagar, gujarat, india Contact: Plastindia Foundation tel.: +91 8414499000 Email: chrysolitemedia@gmail.com Website: www.plastindia.org Feb. 9, 2015. Akron section Meeting topic: sabic innovative Materials— structural Foam Molding Processes and Materials site: Hilton Fairlawn, akron, Ohio, Usa Contact: tony Dean tel.: +1 330-929-9916 Email: francis@neo.rr.com Feb. 10-11, 2015. Polymers in Photovoltaics 2015 site: Hotel nikko Düsseldorf, Düsseldorf, germany Contact: Becca Utteridge tel.: +44 (0) 117 314 8111 Email: rju@amiplastics.com Website: www.amiplastics-na.com/events March 9, 2015. Akron section Meeting topic: thogus Molding tour—twopart Molding/Overmolding site: avon lake, cleveland, Ohio, Usa Contact: tony Dean tel.: +1 330-929-9916 Email: francis@neo.rr.com March 9-11, 2015. Masterbatch asia 2015 site: swissotel the stamford, singapore Contact: adele Brown Email: ab@amiplastics.com Website: www.amiplastics-na.com/events April 13, 2015. Akron section Meeting topic: Earth First Plastics— sustainability of Plastics site: Hilton Fairlawn, akron, Ohio, Usa Contact: tony Dean tel.: +1 330-929-9916 Email: francis@neo.rr.com March 18-19, 2015. green Polymer chemistry 2015 site: Maritim Hotel, cologne, germany Contact: Kat langner tel.: +44 (0) 117 314 8111 Email: kl@amiplastics.com Website: www.amiplastics-na.com/events | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 58-59 Events_046854 IndustryNews.QXD 12/16/14 8:03 AM Page 59 March 23-27, 2015. NPE2015 Site: Orange County Convention Center, Orlando, Florida, USA Contact: SPI: The Plastics Industry Trade Assoc. Tel.: +1 202-974-5235 Email: attend@npe.org Website: www.npe.org April 14-16, 2015. Plastic Pipes in Infrastructure Site: Millennium Gloucester Hotel, London, UK Contact: Giulia Esposito Tel.: +44 (0) 117 314 8111 Email: ge@amiplastics.com Website: www.amiplastics-na.com/events April 14-16, 2015. Stretch & Shrink Film 2015 Site: Maritim Hotel, Cologne, Germany Contact: Sabine Prack Tel.: +44 (0) 117 314 8111 Email: sp@amiplastics.com Website: www.amiplastics-na.com/events April 27-29, 2015. Plastic Pouches 2015 Site: Imperial Riding School Renaissance Hotel, Vienna, Austria Contact: Charmaine Russell Tel.: +44 (0) 117 314 8111 Email: cr@amiplastics.com Website: www.amiplastics-na.com/events June 1-4, 2015. Automotive Plastics Conference & Exhibit Site: Adoba Hotel, Dearborn, Michigan, USA Contact: Executive Conference Management Tel.: +1 313-429-3905 Email: ecm@executiveconference.com Website: www.executive-conference.com # 50 site causes but where it does not control the asset. One area of confusion is whether an emission is in Scope 1 or Scope 3. The key issue is whether the site has control of the asset, and actual ownership is less important than control. Carbon Footprinting: The Basics A carbon footprint can be either for a site or for a product. These are very different: A site carbon footprint does not include the embodied energy in raw materials, it relates only to emissions resulting from site activities. A product carbon footprint covers the complete carbon emissions resulting from the production of the product. The site footprint will only be part of the product carbon footprint. Action: • Prepare an initial carbon footprint. You will need it sooner than you think. Carbon footprinting will become an issue for customers as they attempt to reduce their own carbon footprint. Carbon footprinting requires data on all carbon emissions, and there is a three-part classification: • Scope 1: Direct—this covers emissions that a site directly causes, or from a controlled asset. • After preparing an initial carbon footprint, data collection should become part of normal operations. • Scope 2: Indirect (from imported utilities)—this covers emissions from electricity or other imported utilities, e.g., heat or steam. • Start recording and publishing your carbon emissions regularly. • Scope 3: Indirect (other)—this covers emissions that a Dr. Robin Kent — ©Tangram Technology Ltd. (www.tangram.co.uk) Note: Dr. Robin Kent is the author of Energy Management in Plastics Processing, published by Plastics Information Direct, and managing director of Tangram Technology Ltd., consulting engineers specializing in energy management in plastics processing. rkent@tangram.co.uk. www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PLASTICS ENGINEERING | 59 60-64 Classified_editorial 12/16/14 7:55 AM Page 60 MARKET PLACE ■ PROFESSIONAL SERVICES ■ PROFESSIONAL SERVICES ! " " # $ *+ + , () ■ , PROFESSIONAL SERVICES %&! % ' ) ) JSW Twin screw compounding extruder trials available! USA: Japan Steel Works America, Inc. 41135 Vincenti court novi, Mi 48375 Usa Office: 248-536-0288 X103 Email: spaulot@jswcompounding-usa.com Energy management consulting •Energy surveys and reports management and systems •Energy management training •Energy Belgium : JSW Europe GmbH c/o tigro industries nV, Europalaan 37, 3900 Overpelt, Belgium tEl : +49-211-311-6660 E-mail : gion@jsw.de We only deal with plastics processors We survey plastics processing sites for energy efficiency opportunities We provide detailed and costed programmes for energy efficiency improvements We benchmark sites and machines pe@tangram.co.uk, www.tangram.co.uk EXTRUSION TECHNOLOGY CENTER 31 County Route 59, Phoenix, NY 13135 www.sam-na.com • 315-934-4287 • info@sam-na.com Flexible Packaging and Converting Product Development EXTRUSION COATINGS – LAMINATES – CAST FILMS Substrates: Liquid Coatings: Extrusions: 60 Paper, Board, Film, Foil, Nonwoven Water Based Primers & Coatings Up To 11 Layer Coextrusions | Plastics EnginEEring | JanUarY 2015 | www.4spe.org | www.plasticsengineering.org 60-64 Classified_editorial 12/16/14 7:55 AM Page 61 ■ HELP WANTED ■ HELP WANTED QUALITY ENGINEER wanted by a glass mfg co. in Alabaster, AL. Conduct testing & dimensional layouts using mechanical & electrical inspection gages; conduct trial fit & function builds at customers' facilities; evaluate process capability using statistical tools; perform tech'l & statistical investigations & analysis on production, qlty, process & current model eqpmt issues using std problem solving methods; assist in creating necessary documentation for customer initial sample submissions incl APQP, customer docs & any other reqd documentation; prep advanced qlty planning docs & participate in qlty planning activities, incl FMEA's, Process Flow Diagrams, Control Plans, Gage R&R's & capability studies; dvlp, install & operate qlty systems for incoming material, in process parts & finished products. Reqs Bach's deg in Industrial Engg, Industrial Engg Mgmt, Electrical Engg, or closely related field, & 2 yrs of exp. Forward resume to AGC Automotive Alabama, Inc. 101 Total Solutions Way Alabaster, AL 35007 SPE Topical Conferences KNOWLEDGE SPE Topical Conferences focus in depth on the plastics material, process or industry that impacts your job. Generally 2-3 days in length, topical conferences feature speakers who present technical sessions on a theme related to a single subject. They are hosted by SPE Sections, Divisions, and Special Interest Groups; are held year-round in North America, Europe, India and Australia; and often include a tradeshow, allowing you to learn about and experience the latest products and services directly related to your interest area. ■ HELP WANTED MAINTENANCE ELECTRICAL ENGINEER wanted by a glass manufacturing company in Alabaster, AL. Design, develop & maintain electrical components, eqpmt, & systems; evaluate specs & dsgn new electrical eqpmt & design new & modify existing electrical drawings; lead installation & startup of eqpmt to ensure that budget, project schedule, & OSHA regulatory compliances are maintained; assist mechanical engineers, maintenance, & production with any concerns which may need electrical controls. Requires Bachelor's degree in Manufacturing Systems Engineering, Mechanical Engineering, Industrial Engineering, or closely related field, & 2 years of experience. Forward resume to AGC Automotive Alabama, Inc. 101 Total Solutions Way Alabaster, AL 35007 Society of Plastics Engineers CORPORATE SPONSORSHIP PROGRAM The SPE Corporate Sponsorship Program provides you with a variety of ways to maximize your marketing dollars by gaining access to the world’s largest plastics professional network. Contact Tom Conklin at +1 203-740-5453 for details on the following benefits of partnership: Advertising to over 55,000 members and prospects Live webinar featuring your company’s latest innovation Full page ad in Plastics Engineering magazine Presence on SPE’s website homepage and member social network Conferences are held on topics including: Automotive Blow Molding Color & Appearance Extrusion Flexible Packaging Foams Nanotechnology Plastics Environmental Polyolefins Thermoforming Thermoplastic Elastomers Thermosets Vinyl Plastics PARTNER WITH SPE TO LAUNCH YOUR NEW PRODUCT For a complete listing of all upcoming events, visit: www.4spe.org Society of Plastics Engineers www.4spe.org www.plasticsengineering.org | www.4spe.org | JANUARY 2015 | PlAstics ENgiNEERiNg | 61 60-64 Classified_editorial 12/16/14 7:55 AM Page 62 EDITORIAL INDEX Society of Plastics Engineers AEC ......................................................17 Madison Group ..................................34 EDITORIAL STAFF Amcor Rigid Plastics......................49-50 Maplan Rubber Machinery................17 American Chemistry Council ......30, 32 M. Holland Co. ......................................7 Managing Director Russell C. Broome American Fuji Seal ..............................23 Moore Recycling Assocs. ..................31 Assoc. of Postconsumer Mountaintop Economics & Research ..46 Editor-in-Chief Briana Gilmartin Managing Editor Michael Tolinski Plastic Recyclers ............................22-6 Nakamoto Packs Co. ..........................55 Austen BioInnovation ........................16 Northwestern Univ.............................56 Autodesk..............................................15 Nova Chemicals ....................................7 Avery Dennison ..............................23-6 NPC Industrias Quimicas ..................54 battenfeld-cincinnati ......................48-9 Plastics Forming Enterprises ............26 Bekum America ..................................17 PolyOne ........................................16, 49 Art Director Gerry Mercieca Canatu..................................................48 Polysack ..............................................23 2014–2015 EXECUTIVE COMMITTEE Chemineer ..........................................50 Premix/Composites Group................16 Colorobbia Italia ................................55 R.W. Beck ............................................30 President Vijay Boolani Conair ............................................50, 52 Showa Denko K.K. ..............................56 DuPont ................................................55 Sikora ..................................................50 Eastman ..............................................26 Solvay Specialty Polymers ................52 Eckart ..................................................48 Spear Label ......................................23-4 Eco Bio Plastics Midland ....................52 SPI ..............................................15, 44-6 Evonik Degussa GmbH ......................55 SNS NanoFiber....................................16 Ferris State Univ. ..........................16-17 Sumitomo Chemical Co. ....................54 Freedonia Group ..................................7 Sumitomo Seika Chemicals Co. ....54-5 Green Bay Packaging ........................26 Sun Chemical ......................................26 Gros Exec. Recruiters ........................18 Trex ..............................................30, 32 Hilex Poly ............................................32 Univ. of Akron................................15-17 Japan Envirochemicals ......................54 Univ. of Mass.-Lowell....................14-15 IHS ..........................................................7 UPM Raflatac ................................23, 26 Invention Science Fund......................56 Veris Consulting..................................46 Kennedy Group ..............................24-6 Viscus Biologics ..................................16 KraussMaffei ......................................17 Wausau Coated Products ..................26 Lubrizol ................................................16 Contributing Editors Dr. Roger Corneliussen Patrick Toensmeier Dr. Robin Kent CEO, SPE Willem De Vos President-elect Dick Cameron Senior Vice President Scott E. Owens Vice President/Treasurer Dr. Raed AlZubi Vice President Dr. Gregory A. Campbell Vice President Thierry d'Allard Vice President/Secretary Dr. Jaime A. Gómez Vice President Dr. Jeffrey H. Helms Vice President Olivier Crave 2013–2014 President Jon Ratzlaff Plastics Engineering (ISSN 0091-9578) is published monthly, except bimonthly in July/August and November/December, by Wiley Subscription Services, Inc., a Wiley Company, 111 River Street, Hoboken, NJ 07030 USA. The magazine is compiled and edited by the Society of Plastics Engineers, Editorial and Business Office, 6 Berkshire Blvd., Suite 306, Bethel, CT 06801 USA. Telephone +1 203-775-0471, Fax +1 203-775-8490. SPE Home Page: www.4spe.org. Communications should be sent to the Editor. Send address changes and undeliverable copies to the Circulation Manager at the SPE address given above. Send subscription orders and claims for non-receipt to Wiley Subscription Services at the Wiley address given above. SPE members receive the magazine as a benefit of membership. Subscription rate for nonmembers is $151 for 1 year; add $100 per year for subscriptions outside North America. Single-issue price is $20. Plastics Engineering is printed by Dartmouth Printing Co., a Sheridan Group Company. Periodical postage paid at Hoboken, NJ, and additional entry office. Accepted at special postal rates provided in P.M., Sec. 132 122. Copyright 2015 by the Society of Plastics Engineers, Inc. POSTMASTER: Send address changes to Plastics Engineering, 6 Berkshire Blvd., Suite 306, Bethel, CT 06801 USA. Reproduction in whole or in part without written permission is prohibited. Plastics Engineering is indexed by Engineering Information Inc. Neither Wiley Subscription Services, Inc., nor the Society of Plastics Engineers, nor Plastics Engineering is responsible for opinions or statements of facts expressed by contributors or advertisers, either in the articles published in Plastics Engineering or in the technical papers that are presented at the meetings of the Society. Editorials do not necessarily represent the official policy of Wiley Subscription Services, Inc., or the Society. Display and classified advertisements are included as an educational service to readers of Plastics Engineering. Advertising appearing in Plastics Engineering is not to be taken as an endorsement, expressed or implied, of the respective company’s processes, products, or services represented in the ad. Printed in the U.S.A. 62 | PLASTICS ENGINEERING | JANUARY 2015 | www.4spe.org | www.plasticsengineering.org 60-64 Classified_editorial 12/16/14 7:56 AM Page 63 60-64 Classified_editorial 12/16/14 7:57 AM Page 64 ADVERTISERS INDEX Allgrind Plastics www.allgrind.com ................................................................................................................60 AGC Automotive Alabama, Inc. us.agc.com ............................................................................................................................61 ARbuRG www.arburg.us ........................................................................................................................5 Ashland www.ashland.com/transportation ......................................................................................11 branson ultrasonic Corporation bransonultrasonics.com ........................................................................................................39 Henkel www.henkelna.com/4090............................................................................................Cover 2 InnoPlast Solutions BioPlastConference.com/brochure.html ............................................................................43 J.P. Curilla Associates Email: jpcecl@aol.com ..........................................................................................................60 Japan Steel Works www.jswcompounding-usa.com ..........................................................................60, Cover 4 John Anderson & Associates www.plasticsjobsearch.com ................................................................................................60 NPE 2015 www.npeguestpass.org/PE1 ................................................................................................13 Plastic Flow www.plasticflow.com ............................................................................................................60 Plastic Process Equipment, Inc. www.ppe.com • Email: Sales@ppe.com ....................................................................Cover 3 Polyhedron Laboratories, Inc. www.polyhedronlab.com......................................................................................................60 Process & Design Technologies, LLC www.processdesigntech.com ................................................................................................60 Reedy International www.reedyintl.com ................................................................................................................21 Rheo-Plast Assocs. www.rheoplastusa.com ........................................................................................................60 SAM North America, LLC www.sam-na.com ............................................................................................................60 Shepherd Color Co. www.shepherdcolor.com......................................................................................................17 SIkoRA www.sikora.net/purityscanner ..............................................................................................3 SPE ANTEC® orlando www.antec.ws ................................................................................................................28, 29 SPE ANTEC® brussels Email: croos@4spe.org ........................................................................................................27 SPE Apparel www.4spe.org ......................................................................................................................51 SPE Careers www.4spe.org/careers ............................................................................................................32 SPE Corporate Sponsorship Program www.4spe.org/ ......................................................................................................................61 SPE International Polyolefins Conference www.spe-stx.org/conference.php ......................................................................................25 SPE Membership Application www.4spe.org/membership ................................................................................................63 SPE PlastiVan Educational Program www.4spe.org ........................................................................................................................20 SPE Topical Conferences www.4spe.org ........................................................................................................................61 Tangram Technology www.tangram.co.uk ..............................................................................................................60 The Plastics RACE www.4spe.org/antec/tpr ......................................................................................................47 Wiley RoI/PENG Email: respinosa@wiley.com ................................................................................................57 64 ADVERTISING SALES FoR PRINT AND oN LINE DIGITAL ADVERTISING SALES in Plastics Engineering magazine please contact: Global Advertising Director Stephen Jezzard E-mail: sjezzard@wiley.com Sr. Account Manager Print & E Media Advertising Roland Espinosa Tel: 201-748-6819 E-mail: respinosa@wiley.com 111 River Street Hoboken, NJ 07030 USA Society of Plastics Engineers 6 Berkshire Blvd., Suite 306 Bethel, CT 06801 USA www.4spe.org | PlASTiCS ENgiNEERiNg | JANUARY 2015 | www.4spe.org | www.plasticsengineering.org 00 Cover_Layout 1 12/16/14 6:57 AM Page cvr3 YOUR DEPENDABLE SOURCE FOR MOLDING ACCESSORIES The Worlds Largest Variety of Accessories for the Plastics Industry! 95% OF ALL STOCK ORDERS SHIPPED THE SAME DAY! 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