Matter Matter Anything that has _____ and takes up ____. Matter is made of atoms. Atoms are the basic UNIT of matter. Circle the word or phrase that describes an example of matter. Proton lava air light electrons Bria concepts catsup water vapor thoughts atom your breath ideas heat quark Mira decisions a vacuum motion something (empty space) without mass molecule something that takes up space mixture Atoms are made of protons, neutrons and electrons. The word atom derives from the Greek (ατομοζ) for indivisible. PROTON A __________ charged particle found in the ______________. NEUTRON A particle in the ________________ with ____ charge (neutral). It has the ______________ mass as a proton. ELECTRON A ________________ charged particle found ___________________ the nucleus in a region called the _______________ ______________. http://phrenopolis.com/perspective/atom/ (scale of proton vs electron) NUCLEUS The center of an atom containing the _______________ and _________________. ELECTRON CLOUD The region surrounding the nucleus of an atom where _____________ are found. The Bohr model of the atom Each “ring” is called a _________. These are also called stationary states. http://www.upscale.utoronto.ca/GeneralInterest/Har rison/BohrModel/Flash/BohrModel.html (animated Bohr model) Element song= http://www.privatehand.com/flash/elements.html Helium Lithium Beryllium Boron 2 protons, 2 neutrons and 3 protons, 4 neutrons and 4 protons, 5 neutrons and 5 protons, 6 neutrons and 2 electrons 3 electrons 4 electrons 5 electrons Valence Shell The valence shell is the outermost shell of an atom. Shells #1 holds - 2 electrons max, #2 -8 electrons max #3 -18 electrons max http://www.ndt-ed.org/EducationResources/HighSchool/Electricity/valenceshell.htm Electron Shells Electrons are arranged around the Nucleus in SHELLS. For simplicity they can be thought of like miniplanets orbiting a central sun, but it is closer to the truth to think of them as "clouds" of electric charge around the Nucleus. The shells are numbered outward from the Nucleus. The maximum number of electrons found in each shell can be calculated by: where "n" is the number of the shell. Maximum Shell Number Number of Electrons in the Shell 1 2x1=2 2 2x4=8 3 2 x 9 = 18 4 2 x 16 = 32 5 2 x 25 = 50 The Octet Rule: In general, atoms are most stable when they have 8 electrons in their outer-most shell. (Octet means 8.) The exception is the first shell which is most stable with TWO electrons. If you know the Atomic Number and Mass Number of an element and the maximum number of electrons in each electron shell you can draw a diagram of the element. For example: Sodium has an Atomic Number of 11 and an Mass Number of 23 ie This means an atom of Sodium has 11 Protons and therefore 11 electrons. Since the number of Protons + Neutrons is 23 and there are 11 Protons there must be 12 Neutrons. From the table above the electrons are arranged as: First Shell = 2, Second Shell = 8, Third Shell = 1 (Giving a total of 11.) Shells, More Accurately…………..2,8,8,18,18,32 As atomic number increases so too does the number of electrons in a neutral atom of the element. The valence electrons are largely responsible for its chemical behavior. If elements having the same number of valence electrons are grouped together the elements in each group or family will have similar chemical properties. The first short period contains only two elements. These elements fill the K shell. It ends with helium which contains a full K shell consisting of two electrons. 2 The second short period contains eight elements beginning with lithium and ending with neon. Neon has a complete L shell of eight electrons. 8 The third short period contains eight elements beginning with sodium. It ends with argon, which contains eight electrons in the M shell. 8 The fourth period contains eighteen elements beginning with potassium. It includes a series of elements from scandium through copper. These elements are known as transition elements. 18 They are building the M shell from eight to eighteen electrons. Before this series begins though two electrons enter the outermost N shell. After the series the N shell then builds up to eight electrons ending with krypton. The fifth period is just like the fourth period in which the O shell takes two electrons then the N shell builds to eighteen electrons before the O shell continues out to eight electrons ending with xenon. 18 The sixth period contains 32 elements. It too has a transition series beginning with lanthanum and ending with gold, in which the O shell fills to eighteen electrons. 32 Note however that this series is split after lanthanum with a series of fourteen elements. In these elements the N shell (third from the outside) is filling from eighteen to 32 electrons. These are referred to as the inner transition series, lanthanum series or the rare earth elements. It begins with cerium and ends with lutetium. http://www.corrosionsource.com/handbook/periodic/e_shells.htm Following lutetium the transition series from hafnium to gold completes by building the O shell to eighteen electrons. The outer P shell then continues to build to eight electrons ending with radon. The seventh period is incomplete. The first two elements, francium and radium fill the Q shell with two electrons. Then the P and O shells fill in the same way as the sixth period. This produces the actinide series. ATOMIC MASS/WEIGHT The number of protons and neutrons found in the nucleus of an atom. Particle Location Charge Mass Neutron Nucleus None 1.008665 amu Proton Nucleus +1 1.007277 amu Electron Shells around the nucleus -1 0.0005486 amu QUARKS Six "flavours" quarks: up, down, bottom, top, strange, and charm Elements A material is an element if all its atoms are the same. Something is not an element if it contains different types of atoms. Elements differ by the number of protons they contain. This number tends to equal the same number of electrons. PERIODIC TABLE 1869 “The BIG DADDY” OF THE PERIODIC TABLE If he was a rapper, he would have been called Heavy D. Dmitri Ivanovich Mendeleev (1834-1907) Mendeleev’s first sketch of a periodic table of the elements Lithium reaction http://www.youtube.com/watch?v=wY0afMI4Jgc&annotatio n_id=annotation_780828&feature=iv Synthetic elements are created using particle accelerators. A particle accelerator (or atom smasheris a device that uses electric fields to propel electrically-charged particles to high speeds and to contain them. A new particle accelerator, the Large Hadron Collider near Geneva, Switzerland. (Credit: CERN). 27-kilometer Particle Accelerator http://news.yahoo.com/s/ap/20091123/ap_on_sc/eu_sci_big_bang _machine It has massive magnets cooled 1.9 degrees Kelvin (that's cold) . Fermilab Aerial photo of the Tevatron at Fermilab. The main accelerator is the ring above; the one below (about one-third the diameter, despite appearances) is for preliminary acceleration, beam cooling and storage, etc. http://en.wikipedia.org/wiki/Particle_accelerator http://gemologyproject.com/wiki/index.php?title Click table contents=The_Chemistry_of_Gemstones http://elements.wlonk.com (picture and word table) Rows called PERIODS; arranged by atomic number = #protons horizontal Columns called FAMILIES; grouped by similar properties vertical Element Symbols Hydrogen Copper Carbon Nitrogen Chlorine Iron Silicon Sulfur OxygenCalcium Top Elements in Top Elements in Earth Crust our Body Oxygen 65% Oxygen 47% Carbon 18% Hydrogen 10% Silicon 28% Aluminum 8% Top Elements in the Top Elements in Oceans Atmosphere Nitrogen 78% Oxygen 86% Oxygen Hydrogen 10% 21% Argon <1% Chlorine Human Body Elements by % Element Percent by mass Oxygen 65 Carbon 18 Hydrogen 10 Nitrogen 3 Calcium 1.5 2% Phosphor us 1.2 Potassium 0.2 Sulfur 0.2 Chlorine 0.2 Sodium 0.1 EARTH’S CRUST ELEMENTS The 8 most common elements in Earth’s crust (by mass): 46.6% Oxygen (O) 27.7% Silicon (Si) 8.1% Aluminum (Al) 5.0% Iron (Fe) 3.6% Calcium (Ca) 2.8% Sodium (Na) 2.6% Potassium (K) 2.1% Magnesium (Mg) EARTH’S ATMOSPHERE ELEMENTS Components of (volume) dry air Nitrogen 78.0842% Oxygen 20.9463% Argon 0.9342% Elements in the Oceans Oxygen 85.84% Hydrogen 10.82 Chlorine 1.94 Sodium 1.08 Phases of Matter The key word to notice is physical. Things only move from one phase to another by physical means. Solid: A solid is matter in which the molecules are very close together and cannot move around. Examples of solids include rocks, wood, and ice (frozen water). Liquid: A liquid is matter in which the molecules are close together and move around slowly. Examples of liquids include drinking water, mercury at room temperature, and lava (molten rock). Gas: A gas is matter in which the molecules are widely separated, move around freely, and move at high speeds. Examples of gases include the gases we breathe (nitrogen, oxygen, and others), the helium in balloons, and steam (water vapor). Plasma: A plasma is a gas that is composed of free-floating ions (atoms stripped of some electrons - positively charged) and free electrons (negatively charged). A plasma conducts electrical currents. Plasma was discovered by William Crookes in 1879. There are many different types of plasmas. There is plasma in stars (including our Sun), and the solar wind in our Solar System is made of plasma. http://www.enchantedlearning.com/physics/Phasesofmatter.shtml http://www.miamisci.org/af/sln/phases/index.html MIXTURE A type of matter made up of substances that are physically combined. EX: tossed salad, sugar ice tea COMPOUND A type of matter made up of elements chemically combined. EX: salt, water, carbon dioxide PHYSICAL PROPERTY The properties that can be observed without changing the chemical makeup/characteristics. EX: color, luster, malleability, brittleness, odor, taste, density, texture, hardness, electrical conductivity, heat conductivity, boiling melting and freezing point. PHYSICAL CHANGE (no new substance) Occurs when the physical properties of a substance changes but no new substance is formed. Mixtures may be formed or separated through physical changes. 1. A change that affects the appearance of a substance, but does not affect the composition or chemical properties. 2. Molecules are unchanged. 3. Original substance is still there with only new physical properties. 4. No new substance is formed. Examples : evaporating, melting, freezing, sublimating OR: Sharpening a pencil Cut up an apple Grinding a rock into powder Dissolving sugar in water Drying your clothes Breaking glass DENSITY The amount of matter (stuff) in a given volume (space). It is a physical property of all matter. Amount of mass compared to amount of space taken up (volume). M/V Mass Volume e Volume is the amount of space an object takes up. Can be measured using: graduated cylinder Ruler/meter stick (LxWxH) Units of density are: g/mL or g/cm It is concept 3 an important regarding buoyancy. http://www.karlyoder.com/flash_density.html (virtual density lab) The SI unit for density is: kilograms per cubic meter (kg/m³) or g/mL or g/cm3 http://www.world-builders.org/lessons/less/les1/weight_mass.html Densities of Substances Substances Density (kg/m3) Solids Substances Density (kg/m3) Liquids Aluminum 2.70 x 10 3 Water (4oC) 1.00 x 10 3 Iron and Steel 7.8 x 10 3 Blood, plasma 1.03 x 10 3 Copper 8.9 x 10 3 Blood, whole 1.05 x 10 3 Lead 11.3 x 10 3 Sea water 1.025 x 10 3 Gold 19.3 x 10 3 Mercury 13.6 x 10 3 Concrete 2.3 x 10 3 Alcohol, ethyl 0.79 x 10 3 Granite 2.7 x 10 3 Wood (typical) 0.3 ~ 0.9 x 10 3 Glass, common 2.4~2.8 x 10 3 Gases Ice 0.917 x 10 3 Air 1.29 Bone 1.7~2.0 x 10 3 Helium 0.179 Carbon dioxide 1.98 Gasoline Water (steam 100oC) 0.68 x 10 3 0.598 http://www.angelfire.com/nc3/pweb/charts/density.htm Chemical Property: a description of how the matter reacts with other substances. Example: flammable, reacts with air, reacts with water, does not react CHEMICAL CHANGE Compounds may be formed or broken down through chemical changes. The following may occur during a chemical change: heat or light is produced gas is produced (bubbling) a change of color a solid is formed(precipitate) 1. Change in matter in which one substance is _____________________into another substance. 2. Molecules ________________. 3. Original substance is _____________. 4. An entirely ___________substance is formed with new physical and new chemical properties. Chemical Change Examples: Rusting or corrosion of any metal (tarnish, metals reacting with air) Digestion Respiration(animals)/Photosynthesis(plants) Burning anything A battery producing electricity Spoiling of food or cooking food CHEMICAL CHANGE (cont.) Rotting Plant material Growth Acids and Bases reacting Metals reacting in water Law of Conservation of Matter (Mass) Matter (mass) is not created nor destroyed in an ordinary chemical reaction. COMPOUNDS Compound* *Molecule Matter that is made up of two or more elements (atoms) _________________________combined and cannot be separated by physical means. The molecule is the smallest unit of a ____________________. Compound Facts: The elements that make up a compound are combined. chemically A compound has different the elements that make it up. chemical properties than Energy is always used/applied when a compound is broken up or put together. It takes another chemical reaction to change/create new a compound. The ratio of the elements that make up a compound are always the same for that compound. Example: water is always atom. 2hydrogen atoms and 1oxygen Parts of a compound: compound formula(david) compound name CO2 = carbon dioxide subscript _________ (how many atoms are present)* *When there is no subscript written, it is assumed that the subscript is 1 A chemical equation uses chemical formulas of elements and compounds to represent a chemical change. Parts of a Chemical Equation coefficient 2Na + Cl2 reactants Yields(energy applied) 2NaCl products subscript Balanced equations…. Or not? Remember ….. reactant + reactant 1. S8 + O2 product SO3 2. FeCl3 + NaOH 3. HCl + CaCO3 Fe(OH)3 + NaCl CaCl2 + H2O +CO2 4. C12H22O11 + O2 5. CO2 + H2O What is the chemical name for the following compounds? Word bank: Sugar Salt rust water 1. H2O _______________________ 2. NaCl ______________________ 3. Fe2O3 _______________________ hydrogen peroxide carbon dioxide 4. CO2 _________________________ 5. H2O2 ________________________ 6. C12H22O11 ____________________ COMPOUNDS OR ELEMENTS? C=compound E= element Use your periodic table to determine if the following is an element or compound. _____1. carbon _____2. carbon dioxide _____3. oxygen _____4. fluorine _____5. sodium fluoride _____6. hydrogen _____7. vinegar _____8. sodium _____9. chlorine ____10. sodium chloride ____11. baking soda ____12. sugar ____13. lithium ____14. rust True or False: _____ 1. Compounds are made up of only one type of atom. _____ 2. Compounds can be found on the periodic table. _____ 3. Subscripts are used in compounds to determine the number of elements in the compound. _____ 4. You can separate a compound by a physical change. _____ 5. It takes a chemical change to form a compound. _____ 6. The proportions of the elements that make up a compound can change and you would still have the same compound. Venn Diagram: Compare Elements to Compounds Make up your own riddle: Pick a compound that you already know, or choose one from the list and come up with a four line poem that rhymes, The students will try to guess what compound you are talking about. 1. NaCl 2. CaCO3 3. N2O 4. MgSO4 5. FeS2 6. CH4 7. CaSO4 8. SiO2 9. KNO3 10. NaHCO3 11. CaSO4 12. NaF 13. H2O 14. Na2B3O7 15. H4Mg3Si2O9 16. HC2H3O2 17. NH4OH 18. CO 19. CO2 20. C12H22O11 (salt) (chalk or marble) (nitrous oxide or laughing gas) (Epsom salt) (iron sulfide – fools gold) (methane) (plaster of paris) (quartz or sand) (saltpeter – used to make gun powder)) (baking soda) (gypsum) (sodium fluoride) (water) (borax) (talc) (vinegar) (ammonia) (carbon monoxide) (carbon dioxide, dry ice) (sugar) Compare Contrast Elements Compounds . . Chemical Reactions Reactants # of atoms here Product = So, it’s balanced! # of atoms here Solubility- mixing of two or more substances together in solution. Simply defined, it is a measure of how much solute will dissolve into the solvent. Not all substances will dissolve in all solvents. Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a liquid solvent to form a homogeneous solution. Solvent-the greater amount Solute-the lesser amount Miscibility- the property of liquids to mix in all proportions, forming a homogeneous solution. Solubility of a substance strongly depends on the used solvent as well as on temperature and pressure. Solubility increases with temperature(energy) increase. Decreases with temperature (energy) decrease. Similar concept for pressure. A solution is said to be SATURATED if no more solute can dissolve in the solvent. ISOTOPES The number of protons determines what the element the atom is. However, it is possible for an element to exist in more than one form by having greater or fewer neutrons in the nucleus. The different forms of the same element are known as isotopes of an element. Most elements have a few stable isotopes and a few unstable isotopes. For example: Carbon exists in 15 isotopes with the most common forms being the stable C-12,C-13 and the unstable or radioactive C-14. Fission In 1905, in his theory of Special Relativity, Einstein proposed that mass and energy were indeed equivalent. They are linked by the immortal formula E = mc2, where E = energy, m = mass, and c = the speed of light (300,000 kms-1). Thus, a certain quantity of energy is equivalent to a certain mass. However, even a small amount of mass is equivalent to a massive quantity of energy. So, one can see that the mass of the nucleus, and the energy required to bind it are just different types of the same thing. For each atom, the mass and binding energy are inversely proportional; that is, if you increase one, the other must be decreased to minimise energy expenditure. OR http://www.users.bigpond.com/sinclair/fission/Fission2.html Thus, there are two ways of splitting the atom (scission): either by increasing its energy, or by increasing its mass. However, the energy needed to split an atom is enormous, and this is not a practical possibility. The usual result when a nucleus becomes excited (extra energy added) is that gamma or beta rays are released to reduce energy. In other cases where the nucleus is unstable, alpha or beta particles are released to reduce mass, rather than the atom splitting. An alpha particle is a helium nucleus (4He), and a beta particle is a single electron. By releasing mass, the atom is able to reduce energy, and become stable again. The other method (adding mass) is achieved by bombarding a suitable nucleus with neutrons. Suitable nuclei are those with fissionability parameters close to 1 (e.g. 235U = 0.8). By adding an extra neutron to the nucleus, mass is increased, and binding energy is consequently reduced to conserve energy. When the binding energy is reduced, the electrostatic repulsion within the nucleus is greater than the binding energy, and the nucleus splits apart. Top: Expected results: alpha particles passing through the plum pudding model of the atom undisturbed. Bottom: Observed results: a small portion of the particles were deflected, indicating a small, concentrated positive charge. The Geiger–Marsden experiment (also called the Gold foil experiment or the Rutherford experiment) was an experiment to probe the structure of the atom performed by Hans Geiger and Ernest Marsden in 1909, under the direction of Ernest Rutherford at the Physical Laboratories of the University of Manchester. The unexpected results of the experiment demonstrated for the first time the existence of the atomic nucleus, leading to the downfall of the plum pudding model of the atom, and the development of the Rutherford (or planetary) model. A beam of alpha particles, generated by the radioactive decay of radium, was directed normally onto a sheet of very thin gold foil. The gold foil was surrounded by a circular sheet of zinc sulfide (ZnS) which was used as a detector: the ZnS sheet would light up when hit with alpha particles. Under the prevailing plum pudding model, the alpha particles should all have been deflected by, at most, a few degrees; measuring the pattern of scattered particles was expected to provide information about the distribution of charge within the atom. However they observed that a very small percentage of particles were deflected through angles much larger than 90 degrees. According to Rutherford: It was quite the most incredible event that has ever happened to me in my life. It was almost as incredible as if you fired a 15-inch shell at a piece of tissue paper and it came back and hit you. On consideration, I realized that this scattering backward must be the result of a single collision, and when I made calculations I saw that it was impossible to get anything of that order of magnitude unless you took a system in which the greater part of the mass of the atom was concentrated in a minute nucleus. It was then that I had the idea of an atom with a minute massive centre, carrying a charge