INTRODUCTION Significant mineral deposits of iron, nickel, aluminium and clays develop by residual concentration in different environments with certain specific evolutions. Among them bauxite and laterite are principle ore deposits. In 1807 a Surgeon, Francis Buchanan of British East India Company, firstly introduced word “laterite” (Buchanan, 1807). He observed reddish-brown colored weathered material in a few places in South India, particularly in wet and tropical conditions. This material was rich in secondary oxides and hydroxides of iron and aluminium that he called “laterite”/brick material. Mineralogically, laterite consists predominantly of mineral assemblages of goethite (Fe2O3. H2O), boehmite {AlO(OH)}, gibbsite {Al(OH)3}, hematite (Fe2O3), aluminium hydroxides, kaolinite and quartz. Another significant mineral bauxite that forms residual deposit was firstly termed by Pierre Berthier in 1821 and was named after the village Les Baux in southern France, where it was first found, enriched with alumina. Laterites and bauxites are produced in tropical soils by weathering, which enriches iron (laterites) and alumina (bauxites) as well as trace elements such as nickel, gold, phosphorus, and niobium to ore grade. Laterites and bauxites can be redeposited into sedimentary sequences, and remain as ores if not transported far and diluted with other materials. The age of redeposited laterites and bauxites, and of bauxitic and lateritic paleosols, can be established from the geologic age of overlying rocks, an approach especially effective in paleosols within sequences of isotopically datable volcanic rocks (Gregory J. Retallack, 2010). The Yilgarn Craton is one of the world's principal mineral provinces, with considerable resources of gold, nickel, bauxite and iron ore, as well as lesser amounts of a wide range of other commodities. As such, it is a major target for exploration. However, as most of the Craton has been exposed to sub-aerial conditions since at least the Late Proterozoic, it has had a long history of weathering and erosion under a wide variety of climatic conditions, resulting in a widespread and complex regolith cover. This diverse and extensive regolith poses considerable difficulties for exploration as well as opportunities in terms of different sample media and the formation of resources within the regolith itself. 1 INTRODUCTION The development of appropriate geochemical exploration procedures has been the subject of considerable research by government, university and industry for nearly 50 years (Anand and Butt, 2010). Although „bauxite‟ is an ore of aluminium, but petrologically, it has been considered as rock with mineral assemblage of gibbsite, boehmite and diaspore. It is a member of lateritic family it is characterized by a particular enrichment of free aluminium-hydroxide. Bauxite is a mixture of mono-aluminium and trialuminium hydrates, with the impurities of titanium, calcium and iron oxides. Genetically, laterite/bauxite cap parent rocks like basalts, syenites, granites, arkoses, marl, shale and arkosic sandstones and exposed in the form of regoliths. Most suitable environment for the formation of laterite/bauxite is freely drained and strongly leached. Another common loci for bauxite is Karst topography, where it occurs in caves and solution cavities in limestone. Besides being a primary material for extraction of aluminium it‟s also used in making refractories, abrasives, chemicals and cement. It is also used as a fluxing material in steel melting and in Ferro-alloy industries in place of fluorspar and as absorbent in refining kerosene. Most of the Indian bauxite deposits are under the capping of laterite over a variety of rock types. They are the product of sub aerial weathering and laterisation of variety of rocks, although the important deposit of Madhya Pradesh, Chhattisgarh, Maharashtra, Gujarat, Bihar and Karnataka are distributed on Deccan Trap lava flows. (IBM, 1987) & they classified Indian bauxite in three major types: Continuous: Regular deposits with consistency in grades and thickness; Lenticular: Fairly extensive deposits with sharp grade fluctuations; and Pocket deposits of inconsistent grades and erratic nature. Indian bauxite resources are confined to peninsular shield excepting the occurrences in Jammu in the Extra Peninsular region. In the Peninsular region about 85% of the total reserve is associated with „high level‟ laterite occurring along the eastern and western coasts of which nearly 74% of the reserve is restricted to east coast. About 10% of the total reserves occur amidst inland 2 INTRODUCTION plateaux. The major bauxite deposits of India are generally associated with laterite occurs as cappings and blankets on the plateaus of high elevation between 700 m to 2100 m above MSL in parts of Orissa, Andhra Pradesh, Bihar, Madhya Pradesh, Maharashtra, Karnataka and Tamil Nadu. In contrast, there are coastal and „low level‟ bauxite deposits found along the coastal tracts of Gujarat, Karnataka and Kerala (after GSI, 1994). The important bauxite deposits occur with the „high level‟ laterites in the following four regions of dissected table lands, viz.; (1) The Eastern Ghats Orissa and Andhra Pradesh (East Coast Bauxite Belt) (2) Plateaus bordering Bihar and Madhya Pradesh (3) Maikala range of Madhya Pradesh (Amarkantak deposits) (4) The Western Ghats Besides these smaller and isolated bauxite deposits also occur at : (i) Shevaroy hills, Kolli hills and Kodaikanal in Nilgiri-Palni hill ranges of Tamil Nadu (ii) Seoni, Kaimur and Malwa plateaus and Kaskal –Bailadila range of Madhya Pradesh (iii) Vindhyan plateau bordering Uttar Pradesh and Madhya Pradesh (iv) Kharagpur hills in Mongher district, Bihar (v) Kumbla in Kerala (vi) Bauxite in Jammu, J & K State. 1.1 STUDY AREA AND ITS APPROACH The area of study Mainpat Plateau falls in Surguja district in Chhattisgarh state, India (Fig. 1.1). It is located in Survey of India toposheet numbers 64 N/1, N/5 and N/6 lying between longitudes E83°08‟ to 83°25‟ and latitudes N22°41‟ to 22°55‟. The plateau is located about 45 km SSE of Ambikapur, the District Headquarter of the Surguja. Area is conveniently approachable in all seasons by well connected by road, from District Headquarter (45 km) and that reaches upto the top of the plateau. The nearest rail head is Bishrampur (SE Railway) situated at a distance of 65 km from the study area and nearest air ports is Raipur (Chhattisgarh) and Ranchi (Jharkhand). Sitapur is the main townships and tehshil headquarter 28 km from the study area. 3 INTRODUCTION FIGURE -1.1 MAP SHOWING STUDY AREA (MAINPAT PLATEAU) IN SURGUJA DISTRICT, CHHATTISGARH. (Map not to scale) 1.2 OBJECTIVE OF STUDY The bauxite deposits are not uncommon in India. Bauxite capping occurs on many litho-units. Among them Vindhyans and Deccan traps are particularly underlains the deposits of bauxite. Bauxite reserves in the Chhattisgarh-Madhya Pradesh state are of the order of 277.76 million tonnes which is approximately 4 INTRODUCTION 9.14% of the country‟s total reserves. In Chhattisgarh Bilaspur, Surguja, Raigarh, Korba, Jashpur, Kanker, Kawardha and Bastar districts are major locations and the reserve is about 96 million tonnes (CG, DGM-2003-04). Laterite cappings cover a total area of more than 1500 sq. km. In undivided M.P., following areas account for more than 80% of the total reserve: i) Extension of Bihar plateau region into the districts of Surguja, Raigarh and Bilaspur. ii) The plateau region forming the Maikala Hill range (Amarkantak deposit) in the districts of Shahdol, Bilaspur, Rajnandgaon, Mandla and Balaghat. Rest of the bauxite reserve occurs in Keskal and Bailadila ranges in Bastar. In the Mainpat area, Directorate of Geology & Mining (DGM), Chhattisgarh has established reserves of 33 million tonnes of bauxite. In this plateau bauxite deposits occur at flat top hills at an elevation 1000 m to 1160 m above MSL in the form of laterite cappings over Deccan Trap basalt. Bauxite occurs as discontinuous lenticular and tabular bodies persisting down to a depth of 10 – 12 m from surface. Gibbsite is the main constituent mineral. The bauxite is having high TiO2 upto 17%. Out of this much of ore reserves of the area are to be determined in the study area. Available literature reveals that an extensive research work must be carried out to explore the geology, structure, chemistry and setup of the formation of bauxite. Thus author took this challenge for his doctoral research. 1.3 PREVIOUS WORK Lot of work has been carried out in India and abroad, in an effort to determine the economic use of bauxite. Fox (1923), Bardossy and Aleva (1990) did extensive work on bauxites. Velton (1972) carried out a detailed work on geochemistry and mineralogy of the different bauxite deposits of the world. A large number of scientific publications are available on Indian laterites and bauxites. Major bauxite deposits of India were explored and studied mainly by workers of Geological Survey of India (GSI) among them Roy Choudhary 5 INTRODUCTION (1958), Roy Choudhary et al. (1964 and 1968) are pioneer workers, who Indian presented a detailed report on Amarkantak bauxite deposits near, Phutkapahar (Madhya Pradesh) and Ranchi-Lohardaga lateritic bauxite (Bihar). Bauxite derived from sub aerial weathering of Deccan trap basalt particularly in Madhya Pradesh, Chhattisgarh, Maharastra and Gujarat have been attempted by many workers Fox (1923); Sinor (1923); Chatterjee (1951); Murthy (1952); Roy Choudhary et al. (1964, 1968). However, on the basis of structural, mineralogical and lithological evidences Ghosh and Dutta (1978) have shown that Phutkapahar bauxite deposit of Madhya Pradesh was derived from the Gondwana sandstone. Though the topic is still on debate where many workers considered its origin from Deccan trap or basalt. Another significant contribution received from various schools of thoughts about the bauxite originated from Vindhyans of Central India. Many workers (Swarup, 1973; Murthy et al., 1981; Rao, 1981; Mehta, 1984; Kalsotra et al., 1986) have described the origin of these deposits by weathering of Vindhyan shale or sandstone but it was not yet fully proved. Balasubramaniam (1978) and Sahastrabudhe (1978) carried out a detailed study on Western Ghat bauxite deposits. A detailed account on the discovery of Eastern Ghat bauxite and its resource evolution in the province (Andhra Pradesh and Orissa) has been prepared by Geological survey of India (1977). These deposits are found on khondalite (quartz-garnet-sillimanite-gneiss). Khondalite is an acidic rock containing about 80-85% silica in the form of fine grained quartz (Raman, 1976, 1978, 1981; Rao and Raman, 1979; Raman et al., 1980; Nandi and Slukin, 1983). This discovery has shifted attention of many geologists from basic to acidic rocks as new source of bauxite. Eastern Ghat deposits are known for their large reserve, which is estimated to be higher than 2100 million tones. The derivation of bauxite from the charnokitic rocks (hypersthene granite) is also known from the Shevaroy hills in Tamil Nadu. These deposits are fairly silica rich and overlie the charnokites (Balasubramaniam and Nagarajan, 1978). 6 INTRODUCTION Ray Choudhary (1958), Agrawal et al. (1974), Khan & Pandaya (2000), Mainkar & Minj (2003), Dhekaware & Chouhan (2005) and Kankane & Sai (2005) are some of the pioneer workers in this field who worked on the proposed study area for exploration purposes. The exploration at Mainpat was carried out by Directorate of Geology and Mining of Chhattisgarh to categories the ore and its quantity. Agrawal, Vaidya and Jain (1974) worked on exploration of bauxite of Barima and Khandraja blocks Mainpat plateau. Khan and Pandaya (2000) reported on prospecting of metal grade bauxite in Barima area, Mainpat plateau. Mainkar and Minj (2003) worked on survey and demarcation of bauxite pockets in Jaspur and Surguja District. Kankane and Sai (2005) worked on rapid survey for demarcation of Bauxite deposit in Mainpat area. Dhekaware & Chouhan (2005) reported on prospecting of bauxite in Bijlhwa area Mainpat plateau. 1.4 PHYSIOGRAPHY AND DRAINAGE The high-lands of Surguja district have peculiar 'pat formations' – highlands with small tablelands. The Mainpat, Jarang, Jonka, Jamira and the Lahsun are the major pats of the district. The average height of area is above 600 metres (2,000 ft). Some of peaks are – Mailan 1,226 metres (4,022 ft), Jam 1,166 metres (3,825 ft), Parta Gharsa 1,159 metres (3,802 ft), Kanda Dara 1,149 metres (3,770 ft), Chutai 1,131 metres (3,711 ft), and Karo 1,105 metres (3,625 ft). There are number of other peaks. North–west Surguja is hilly in nature and moving westwards, three distinct steps may be marked out: the first from Shrinagar on the east to the low-lands of Patna and Khargawan, the second from thence to the uplands around Sonhat and the third beyond Sonhat to above a height of 1,033 metres (3,389 ft). Central Surguja is a low basin through which the Rihand and it's tributaries flow. The Mainpat Plateau exhibits an even flat topped topography. The northern part of the area is Kamleswarpur (1116m) and western part of the area is Parpatiya (1158m). The average height of the plateau is 1050m MSL. The major rivers/nala i.e. Manchari nala, Magarda nala, Ghungata nala and Ghagi nala flowing 7 INTRODUCTION northernly, play an important role in draining the area and showing the Dendritic drainage pattern. All the nalas flows from the area and are tributaries of Mand and Barnai Rivers. Detailed geomorphology and drainage has been discussed in the later chapters. 1.5 FLORA & FAUNA The Mainpat plateau tops are generally monotonously free from vegetation but for a few grooves of Sarai occur along with spreaded shrubs. A dense evergreen shrub 1-3m height with reddish dark, blabrous leaves 12 cm to 15 cm long, lanccolate margin toothed, petioles 1.25 to 2.550 cm long flowers in short long axillary‟s spikes and corolla bilabiate is white with purple stamens abundantly present in bauxite bearing area. The local name is Siktapushi where as the botanical name of this shrub is “Justicia adhatota Linn.” (Patel et al., 2005). The rest area covered by brown and whitish soil and being used for cultivation. Hilly slope terrains are very much covered with different floral species. The important floral species are Sarai, Sal (Shore arobusta), Teak, Mahua (Madhulika latifolia), Tendu (Diospyros melanoxylon), Amla (Emblica officivalis), Mango (Mangiferapyros indica), Jamun (Eugenia jambolana), Saja (Terminalia tomentosa) and Bel (Aegle marmeto). The faunal species are Elephant, monkey (Semnipithecus entellus), Indian wolf (Cannislupus), rabbit and bear (Melasus). 1.6 CLIMATE According to Trewartha's classification the Surguja falls in AW (AW denotes Tropical Swanah region) class which is based on temperature and vegetation. The chief feature of this climate is long dry period. However, on the basis of vegetation type, the climate of the area is deciduous to Semiarid. During summer temperature ranges from 150C to 450C while in winter season temperature fall down to 90C and rainy season starts from middle of June and ends by middle of September. Average rainfall during the year ranges from 150 cm to 200 cm. 8 INTRODUCTION 1.7 SCOPE OF THE STUDY The present work covers following: To study geological, geomorphological and tectonic set up of Mainpat bauxite deposit. To study the development of laterite profile. To study configuration of bauxite plateau and morphology of ore body. Mineralogical variations, transformation of minerals in the laterite profiles. Detail geochemical study of laterite profile. Importance and use of bauxite/laterite. Genetic aspect of these bauxite deposits. 1.8 RELEVANCE OF THE STUDY Since enough literature is not available to explain the geology, structure and mineralogenic aspects of Mainpat plateau. Further the Central Indian shear zone and its significance to mineralisation have not worked out. During the course of this work it enlarged to prepare a model which explains the genetic aspects of bauxite in relation to shear zone and hence, the model will be identical for exploration of similar bauxite deposits in adjoining area. Geomorphological factors will also be attempted to understand the bauxite formation. Detailed geochemical studies of laterite profile of this area will provide data regarding mineralisation in the area. Author is on the opinion that a complete account of genesis of Bauxite of Mainpat plateau may be prepared after this research work. 1.9 LIMITATIONS & CONSTRAINTS Due to unavailability of enough literature on the Mainpat Plateau Bauxite deposit author put lot of time for field work. Plateau has steep slope and escarpments and author does not have any training on mountaineering and hence complete and précised profile of escarpment was not attempted. Since author also faced lot of problems regarding local language, fooding habits, convince, remoteness of the study area, etc. Naxallite due to some political causes also suffered research work at some movements. 9