No.20150129 Material Safety Data Sheet IDENTITY(As Used on Label and List) RESIN FLUX CORED WIRE SOLDER “SUPER ROSIN 60GXB3 ” 1. Chemical Product and Company Identification Product Name : Resin Flux Cored Wire Solder “SUPER ROSIN 60GXB3” Manufacturer's Name : ISHIKAWA METAL CO., LTD. Address : 7-21, Chikko hamadera nishimachi, Nishi-ku, Sakai-city, Osaka, 592-8352, Japan Telephone Number : +81-72-268-1155 Fax Number : +81-72-268-1159 2. Composition/Information on Ingredients The product is preparation of A, B and C. Component A B C Chemical Name Sn(Tin) Pb(Lead) Activated Rosin Mass% 58.2% 38.8% 2.85% CAS No. 7440-31-5 7439-92-1 8050-09-7 3. Hazards Identification Emergency Overview Emergency overview: Component Lead is harmful by inhalation and if swallowed. Danger of cumulative effects. May cause harm to the unborn child. Possible risk of impaired fertility. Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. Air sensitive. Potential health effects: (Primary route of exposure) Inhalation : Soldering fumes can respiratory irritation, kidney and liver damage. Oxides of nitrogen may be produced which are poisonous. Overheating may produce lead fumes leading to lead poisoning. Eye contact : Can cause severe irritation and abrasion. Skin contact: May cause irritation, dermatitis. Ingestion : May cause kidney and liver damage, lead poisoning. 4. First Aid Measures Inhalation : Lay in fresh air and call a physician. Eye contact : Flush eye well with plenty running water for 15 minutes. Including under eyelids. Skin contact: Wash with soap and water. Ingestion : Wash mouth and call a physician. 5. Fire Fighting Measures Flammable properties: No information available Extinguishing media: Dry chemical, carbon dioxide, chemical form or sand. Fire fighting instructions: Use self-contained breathing apparatus and full protective clothing for fires in enclosed areas. 1/3 60GXB3 No.20150129 6. Accidental Release Measures Sweep up, then place into a suitable container for disposal. If molten metal spilled, steam explosion which can be occurred. 7. Handling and Storage Handling: Heating (more than 350℃) can release harmful fume. Do not have any food, drink or smoke during soldering. eating or smoking after handling solder. Storage: Store indoors prevent from direct sun shine. Wash hands before 8. Exposure Controls/Personal Protection Engineering controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Personal protective equipment: Use protective gloves, safety glasses or goggles, and suitable working wear. Exposure guidelines: Pb: 0.05 mg/m 3 (OSHA PEL,TWA) Pb: 0.05 mg/m 3 (ACGIH TLV-TWA) 3 Pb: 150 mg/m (FRANCE PEL-TWA) Pb: 0.1 mg/m 3 (GERMANY PEL-TWA) Pb: 0.05 mg/m 3 (POLAND PEL-TWA) 3 Sn: 2 mg/m (OSHA PEL,TWA) Sn: 2 mg/m 3 (ACGIH TLV-TWA) Rosin: Reduce to expose as low as possible. Thermal decomposition products, as resin acid – colophony, are sensitizer (ACGIH) 9. Physical and Chemical Properties Appearance/Color : Silvery gray, solid metal wire Odor : Odorless Boiling Point : Sn: 2270℃, Pb: 1751℃, Rosin: approx.200℃ Melting Point : Alloys: 183℃~190℃, Rosin: approx.70℃ Specific Gravity : Alloys: approx.8.5 (H 2 O=1 at 20℃) Solubility in Water : Insoluble 10. Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Strong oxidants. Incompatibilities with other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Lead/lead oxides, Tin/tin oxides Hazardous Polymerization: Has not been reported. 11. Toxicological Information Inhalation Effects: Soldering fumes can respiratory irritation, kidney and liver damage. Oxides of nitrogen may be produced which are poisonous. Skin Effects: May cause irritation, dermatitis. Eyes Effects: Can cause severe irritation and abrasion. 2/3 60GXB3 No.20150129 Ingestion Effects: May cause kidney and liver damage as lead poisoning. 12. Ecological Information Ecotoxicity: Fish toxicity for Lead(Pb): LC50(28day) 13. Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations. Do not dump this material into sewers, on the ground or into any body of water. Contact supplier or a licensed chemical waste disposal contractor for treatment, packaging, and disposal requirements. 14. Transport Information US DOT Hazard Class : Not regulated US DOT ID number : Not applicable Keep away from direct sunlight and contact with water. Avoid overturn, fall-down and any other damage on loading and transporting. 15. Regulatory Information European/International Regulations: European Labeling in Accordance with EC Directives for Lead(Pb). Hazard Symbols: T Toxic N Dangerous for the environment Risk Phrases : R 20/22 Harmful by inhalation and if swallowed. R 33 Danger of cumulative effects. R 61 May cause harm to the unborn child. R 62 Possible risk of impaired fertility. R 50/53 Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. Safety Phrases : S 53 Avoid exposure–obtain special instructions before use. S 45 In case of accident or if you feel unwell, seek medical advice immediately. S 60 This material and/or its container must be disposed of as hazardous waste. S 61 Avoid release to the environment. Refer to special instructions/Safety data sheets. Please refer to any other national measures that may be relevant. 16. Other Information MSDS Creation Date : Jan. 29, 2015 Revision #0 Date : This information is furnished without warranty, express or implied, except that it is accurate to the best knowledge of ISHIKAWA METAL CO., LTD. It relates only to the specific material designated herein, and does not relate to use in combination with any other material or in any process. ISHIKAWA METAL CO., LTD. assumes no legal responsibility for use of or reliance upon this information. 3/3 60GXB3