Life - Environment Environmental Friendly Technologies for Rural Development LIFE05ENV/GR/000245 FINAL REPORT Technical Issue Covering the project activities from 01.12.2005 to 31.05.2009 Data Project Project location Greece (Lakonia) Project start date 01-12-2005 Project end date 31-05-2009 Total project duration (months) 42 Total budget 2,193,875 € EC contribution 1,096,210 € (%) of total costs 49,97 (%) of eligible costs 49,97 Reporting date: 25.08.2009 Final Report (Technical issue) – LIFE05 ENV/GR/00024 Environmental Friendly Technologies for Rural Development Data Beneficiary Name Beneficiary Prefecture of Laconia Beneficiary representative Dimitrios Liakakos Contact persons P. Koulogeorgiou / V. Papadoulakis Postal address 2nd km National Road Sparta - Gythio, GR-23100 Sparta Visit address 2nd km National Road Sparta - Gythio, GR-23100 Sparta Telephone +30 27310 93859 Fax +30 27310 93805 E-mail grafeio.symvoulou@lakonia.gr / papkal1@otenet.gr Project website www.envifriendly.tuc.gr Data Scientific Responsible Name Beneficiary Technical University of Crete Contact person Prof. Nikolaos Nikolaidis Postal address Department of Environmental Engineering, GR-37132 Chania Telephone +30 28210 37785 Fax +30 28210 37846 E-mail nikolaos.nikolaidis@enveng.tuc.gr URL http://www.herslab.tuc.gr/ Final Report (Technical issue) – LIFE05 ENV/GR/00024 2/313 Environmental Friendly Technologies for Rural Development LIST OF CONTENTS PREFACE ................................................................................................................ 6 1. EXECUTIVE SUMMARY .......................................................................................... 7 2. INTRODUCTION .................................................................................................. 9 3. LIFE – PROJECT FRAMEWORK ............................................................................. 12 3.1 Methodology of work and planning ................................................................. 12 3.2 Presentation of Partnership ............................................................................ 12 3.3 Modifications according to the initial proposal................................................... 13 4. TECHNICAL DEVELOPMENT ................................................................................. 15 4.1 Descrption of the applied methodology and technologies ................................... 15 4.1.1. Methodology ......................................................................................... 15 4.1.2. Technologies......................................................................................... 15 5. PROGRESS RESULTS .......................................................................................... 21 5.1 General description ....................................................................................... 21 5.2 TASK 1 – Development of preliminary management plans and design of selected demonstration technologies................................................................................. 27 5.3 TASK 2 – Monitored natural attenuation and water management ........................ 30 5.3.1. Monitored Natural Attenuation in Evrotas River Basin ................................. 30 5.3.2. Water Management in Evrotas River Basin ................................................ 36 5.3.3. Risk assessment of water management .................................................... 38 5.4 TASK 3 - Drainage canal and river bank management ....................................... 43 5.4.1. Management of Drainage Canals ............................................................. 43 5.4.2. Riparian Zone Restoration ...................................................................... 48 5.5 TASK 4 - Agricultural product waste management ............................................ 52 5.5.1. 5.5.2. 5.5.3. 5.5.4. Use of OMW for irrigation of crops during the summer months .................... OMW subsurface disposal and phytoremediation ....................................... Electrolytic treatment of OMW................................................................. Prototype unit for treatment of Orange Juice wastewater ........................... 52 57 60 64 5.6 TASK 5 - Integration of socio-economic aspects ............................................... 68 5.6.1 Results of the fieldwork research .............................................................. 68 5.6.2 Report on socio-economic impacts (Integral Planning for Sustainable Development) ................................................................................................ 73 5.7 TASK 6 - Development of integrated watershed management plans .................... 80 5.7.1. 5.7.2. 5.7.3. 5.7.4. 7.5.5. 7.5.6. Agricultural Development ....................................................................... Drinking Water Supply ........................................................................... Irrigation.............................................................................................. Pollution Control .................................................................................... Coordinated response to floods and droughts ............................................ Biodiversity protection and restoration of river ecosystems ......................... 80 83 83 84 86 86 5.8 TASK 7 - Evaluation of social acceptance and dissemination of results................. 91 5.8.1. Dissemination Strategy Plan ................................................................... 91 5.8.2 Observatory for Local Development .......................................................... 96 5.8.3 Open Farms and Mapping Trails ............................................................... 96 5.9 TASK 8 – Project Management ....................................................................... 99 5.9.1. Steering Committee and Advisory Board meetings ..................................... 99 5.9.2. Reporting to EC .................................................................................... 103 Final Report (Technical issue) – LIFE05 ENV/GR/00024 3/313 Environmental Friendly Technologies for Rural Development 6. DISSEMINATION ACTIVITIES & DELIVERABLES .................................................... 105 6.1. Dissemination activities ............................................................................... 105 6.2 Deliverables (last phase) .............................................................................. 105 6.3 List of project deliverables and milestones ...................................................... 106 7. EVALUATION & CONCLUSIONS ........................................................................... 107 8. AFTER-LIFE COMMUNICATION PLAN ................................................................... 112 ANNEX ................................................................................................................ 114 Annex 1: List of Partner‘s Data ........................................................................... 115 Annex 2: Detailed Description of EnviFriendly Project Results (Task 1 – Task 7) ....... 118 Annex 3: References ......................................................................................... 301 Annex 4: Project tablets .................................................................................... 312 Final Report (Technical issue) – LIFE05 ENV/GR/00024 4/313 Environmental Friendly Technologies for Rural Development Lists of key-words (I) and abbreviations (II) (I) Environmental friendly technologies Watershed management plan Water management Agricultural product waste management Monitored Natural Attenuation Evrotas River (II) AB: Advisory Board AM: Alpha MENTOR BDL: Below Detection Limit CAP: Common Agricultural Policy EE: Environmental Education ERA: Evrotas Riverside Area GIS: Geographical Information System HCMR: Hellenic Centre for Marine Research HMS: Habitat Modification Score HQA: Habitat Quality Assessment LIA: Land Improvement Agency MCL: Maximum Contaminant Level MNA: Monitored Natural Attenuation NCSR: National Centre for Social Research OJW: Orange Juice Wastewaters OMW: Olive Mill Wastewaters PL: Prefecture of Laconia RDP: Rural Development Policy RHS: River Habitat Survey SC: Steering Committee SDO: Sustainable Development Observatory SPME: Solid Phase Microextraction SPs: Sampling Points TUC: Technical University of Crete UA: University of Athens Final Report (Technical issue) – LIFE05 ENV/GR/00024 5/313 Environmental Friendly Technologies for Rural Development PREFACE The present report to the European Commission, according to the time schedule of the LIFE/EnviFriendly project, is the final report (technical issue) covering the period activities between 01.12.2005 and 31.05.2009. The final report is based on the guidelines for reporting and the final report model obtained from the website (http://ec.europa.eu/environment/life/index.htm) LIFEEnvironment. This report has taken into consideration the notes of previous E.C. letters to the Beneficiary and comments from the Life monitoring external team to the Task Leaders. The financial report is attached as separate issue. Prof. Nikolaos Nikolaidis Scientific Responsible of the Project July 2009 Final Report (Technical issue) – LIFE05 ENV/GR/00024 6/313 Environmental Friendly Technologies for Rural Development 1. EXECUTIVE SUMMARY The Water Framework Directive (WFD requires the development of watershed management plans and remedial actions to improve water quality and ecological quality of surface, ground waters and coastal zone. To date, environmental technologies have been implemented in a ―surgical‖ approach without any concern of the impact to the watershed area as a whole. The premise of the EnviFriendly was the following: ―The selection, design characteristics and implementation of environmental friendly technologies for the minimization of non-point source pollution from agricultural lands should be conducted in conjunction with the development of watershed and coastal zone management plans.‖ The design of environmental technologies was integrated with the watershed management plans. The objective was the demonstration of a ―toolbox‖ of environmental friendly technologies for the minimization of non-point source pollution from agricultural lands and integration of their design in the watershed management plan of the Evrotas river basin and its coastal zone. This project was in line with the Rural Development Policy of EU regarding the objectives of axis 2 (land management/environment) and specifically the agri-environmental measures. The objectives were realized through a series of actions that included: (1) Identification and quantification of pollution loads to the watershed; environmental impact assessment of impacted water bodies; development of preliminary management plans. (2) Installation of stations for monitoring the hydrology, ecology and geochemistry; and Monitoring Natural Attenuation (MNA). (3) Installation of wells at a drainage canal site; systematic sampling and evaluation of nitrate loss in the drainage canals; planting of poplar trees (phytoremediation barrier) and river bank erosion control. (4) Installation of two prototype electrolytic units: one for the removal of color from the final effluent of an orange juice factory and another for the removal of odor from the effluent of an olive mill waste. The later was relocated towards the end of the project at a different factory that packages table olives for the treatment of the generated brines and the reduction of BOD because the olive mill was relocated to a different location. (5) Installation of a prototype unit for the subsurface disposal of olive mill waste and phytoremediation with poplar trees. (6) Monitoring of the application of olive mill waste water for irrigation of a corn field and evaluation of the impacts to ground water and soils. (7) Hydrologic and geochemical data analysis; calibration of watershed and coastal zone models; development of scenarios and model simulations. (8) Development of the integrated water resources management plans for the Evrotas River Basin. Furthermore, prior to developing the integrated management plan, we conducted public consulatation (more than 100 public meetings) and the input from local authorities and NGO representatives was gathered, followed by an analysis of the local socio-economic conditions and expectations. An evaluation of the activities and the degree of social acceptance was determined following the dissemination campaign. Finally, a Sustainable Development Observatory was created and staffed by permanent Laconia Prefecture employees to play a vital role in the WFD implementation. This project has mobilized the local authorities and communities for the proper WFD implementation. The prefecture of Lakonia and the Municipalies have already planned the design and implementation of several of the suggested environmental measures in the Final Report (Technical issue) – LIFE05 ENV/GR/00024 7/313 Environmental Friendly Technologies for Rural Development management plan for the reduction of water use and pollution in the river. The demonstrated technologies showed that a significant reduction of pollution can be achieved through the implementation. MNA can reduce nitrogen and phosphorous loads by 96 and 98% respectively. Similarly the drainage canals and the riparian forest reduce significantly non-point source pollution. Both the use of olive mill wastewater for irrigation as well as the subsurface disposal did not impact the groundwater of the respective areas. Finally, electrolytic treatment was shown as a viable refining technology for the treatment of color and odor of orange juice and olive mill waste water. The project generated the required infrastructure for the implementation of the WFD and the Rural Development Policy of EU. Final Report (Technical issue) – LIFE05 ENV/GR/00024 8/313 Environmental Friendly Technologies for Rural Development 2. INTRODUCTION Evrotas River Basin is a predominantly rural river basin with aged population more than 20% of the total population. The watershed is considered as a ―Less Favoured Area‖ due to its mountainous terrain and areas in danger of depopulation. Sections of the watershed are part of the NATURA 2000 Network. The watershed has intensive water quantity and quality problems resulting in over utilization of the river water and intense pollution problems. Evrotas is a permanent river, however during drought and uncontrolled use of water tends to become a temporary river. An additional aspect that is unique in the basin is that agricultural activities are conducted by small scale, family owned business that do not have the net worth to afford expensive environmental technologies to mitigate the impact from their agricultural practices. This is true not only in Greece, but also in other Mediterranean countries. On the other hand, in the case of olive mill waste, Greece is unique because there are many small olive mill units with small capacity as opposed in Spain that are more centralized large units. The large units can afford advance treatment technologies as oppose to small unit. The innovation of this project relied on: the use of environmental friendly technologies, the use of knowledge as the means to manage in a sustainable way the land and water resources, the development of watershed management plans for sustainable rural development, and the inclusion of all stakeholders and the buy-in of the farmers. The social aspects of the project have been emphasized and the social scientists played a very important role in the design and implementation of the project. The direct and continuous interaction of the social scientists with the stakeholders and the farmers in the field resulted in their involvement and buy-in of the project objectives and collaboration in the development of the watershed management plans that would ensure the best use of water resources and the sustainable growth of the region. The demonstration character of the project had two distinct and complementary strategies. The first strategy was to demonstrate a series of methods and technologies that reduce agricultural pollution from point and non-point sources. The second strategy dealt with the study of the social aspects of the region aiming at the identification of potential for changes in management practices towards sustainable development. The demonstrations of the first strategy were grouped into three categories. Monitored natural attenuation and water management: Pollutants are naturally attenuated in the environment. The capacity of this attenuation if monitored and in combination with proper water management can establish the limits for additional engineered approaches for minimizing the pollution loads and impacts. Drainage canal and river bank management: In agricultural areas, drainage canals decrease the levels of nitrates due to denitrification and plant uptake. Drainage canals are areas of accumulation of organic debris due to erosion and also areas of Final Report (Technical issue) – LIFE05 ENV/GR/00024 9/313 Environmental Friendly Technologies for Rural Development growth of plants such as Phragmitis australis (common reeds). We demonstrated that appropriate management of the reed could result in the minimization of nitrate pollution loads to surface waters. Plants like poplar trees have been shown to decrease nutrient loads due to uptake and enhanced denitrification if they are planted at the riparian zones of the river. Phytoremediation in conjunction with river bank erosion controls was demonstrated as a combined remediation tool for non-point source pollution of nutrients. The main objective was to apply environmental friendly solutions which will gradually merge into the natural environment and retain the equilibrium of the ecosystem. The benefits of proper stream bank stabilization go far beyond preventing loss of land and keeping sediment out of the rivers. It reaches to the point of quality and biodiversity of flora and fauna habitat. Agricultural product waste management: Demonstration of techniques for agricultural product waste management was the third area demonstration of environmental friendly technologies which could substantially reduce the polluting organic load entering the river watershed. Treatment and disposal of olive mill and orange juice wastewater was the focus of the demonstration. Two prototype electrolytic units were installed, one for the removal of color from the final effluent of an orange juice factory and another for the removal of odor from the effluent of an olive mill waste. The later was relocated towards the end of the project at a different factory that packages table olives for the treatment of the generated brines and the reduction of BOD. A prototype unit was installed for the subsurface disposal of olive mill waste and phytoremediation with poplar trees. Finally, monitoring of the application of olive mill waste water for irrigation of a corn field and evaluation of the impacts to ground water and soils was conducted. The second strategy of the demonstration character emphasized the interaction with the farmers and other stakeholders. The objective was to lay a base for the management of natural resources in a sustainable way. For that reason the following aspects were examined and proposed in the management plan: Changing the existing cultivations to more dynamic and less water-intensive. Changing some of the riparian uses towards more ecologically friendly ones. Gradual adaptation of biological ways of production, perspective which might lead on the one hand the products to a more ingrown dynamic infiltration to new markets and on the other to the considerable decrease of the pollution from the used fertilizers and chemicals. Development of mild forms of industry processes of agricultural products. Development of ecotourism projects, which will highlight the natural environment and will integrate with it. Finally, this project demonstrated that the integration of environmental friendly technologies into the development of the watershed management plans will ensure appropriate use of water resources, benefit the environment by improving the water quality and maintain future growth for the region. Final Report (Technical issue) – LIFE05 ENV/GR/00024 10/313 Environmental Friendly Technologies for Rural Development Evrotas River Basin was selected for the integration of environmental friendly technologies with watershed management plans for the following reasons: 1. Evrotas is a temporary river. About 42% of the area in Greece is covered by temporary rivers. The percentage of temporary rivers around the Mediterranean is much larger. Temporary rivers are more sensitive to extreme climatic conditions (droughts and floods) and water management plans are more difficult to be developed. 2. Common agricultural practices: Agricultural practices found in Evrotas River Basin are common in many areas of Greece. For instance the problem of oil mill waste is common to all areas of Greece, Italy, and Spain that produce olive oil. The methodology applied in this project can readily be transferred to other regions of Mediterranean. The problem of excess nitrates and pesticides in soils and waters is present throughout Europe. In addition, all European countries are gearing up towards the implementation of the Water Framework Directive and establishing watershed and coastal zone management plans. The incorporation of the results from the demonstration of environmental friendly technologies in the management plans will reduce the uncertainty in decision making and facilitate the development of robust scenarios during the development of watershed management plans. Finally, the methods and technologies that will be demonstrated in this project are highly innovative and it will be appropriate to be used in many other regions of Europe. It is a combination of methods and techniques that acknowledge and quantify nature‘s ability to reduce pollution loads (monitored natural attenuation, drainage canal) as well as intervene in environmental friendly ways (phytoremediation, river bank erosion protection) to combat non-point source pollution. On the other hand, it introduced innovative methods to reduce agricultural product waste from olive mills and orange juice factories. These methods by themselves can be applied in any part of the world; however, the incorporation of the results of these demonstrations in the development of the watershed management plans was the first application of its kind. This knowledge is complementary to research and application projects underway in Europe. The Central Water Agency of the Hellenic Ministry of Environment recognized the significance of the results of this project and included the Evrotas River Basin in the Pilot River Basins for Agricultural Measures (PRB-AGRI). The second PRB-AGRI meeting was hosted in Sparta in October 2008 by the Central Water Agency and the Prefecture where the results of the LIFE Project were presented. The project partners in coordination with the Central Water Agency activily participated in the 3rd meeting in Wesser and will participate in the future PRB-AGRI meetings. Final Report (Technical issue) – LIFE05 ENV/GR/00024 11/313 Environmental Friendly Technologies for Rural Development 3. LIFE – PROJECT FRAMEWORK 3.1 Methodology of work and planning The objectives of this proposal are the demonstration of environmental friendly technologies for the minimization of point and non-point source pollution from agricultural lands and integration of their design in the watershed management plans of the Evrotas River Basin and its coastal zone. To achieve these objectives the project was implemented in 4 Phases and 8 Tasks listed below: Phase 1: Development of Preliminary Management Plans and Design of Demonstration Technologies – This phase include only Task 1. The objective during the first 8 months of the project was to develop the preliminary management plans and evaluate what information was necessary to be obtained in order to ensure success in the development of the management plans. Phase 2: Demonstration of Environmental Friendly Technologies – This phase included Tasks 2, 3 and 4. Phase 3: Development of Watershed Management Plans – This phase included Tasks 5 and 6. The results from the previous two phases were incorporated in the development of the management plans. Phase 4: Evaluation of Social Acceptance, Dissemination of Results and Project Management – The final phase included Tasks 7 and 8. A time table for the completion of each phase and task is presented below. All phases and tasks were completed successfully and on time with minor time deviations. 3.2 Presentation of Partnership The partnership was comprised of 3 research institutions, 9 local authorities and 2 development companies. The partners and their role in the project was the following: 1. Prefecture of Lakonia – the beneficiary of the project. Prefecture employees participated in every task of the project. Final Report (Technical issue) – LIFE05 ENV/GR/00024 12/313 Environmental Friendly Technologies for Rural Development 2. Technical University of Crete – the scientific coordinator of the project responsible for tasks 1, 3, 4 and 6 and participated in the remaining tasks of the project. 3. Hellenic Centre for Marine Research – responsible for task 2 and participated in the remaining tasks of the project. 4. National Centre for Social Research – responsible for tasks 5 and 7 and participated in the remaining tasks of the project. 5. Alpha MENTOR Ltd – responsible for task 8 and participated in the remaining tasks of the project. 6. Lakonia Development Company - participated in the all tasks of the project. 7. Municipalities – Elos, Skala, Pellana, Mystra, Oinountos, Faridos, Krokeon and Therapnon participated in the all tasks of the project. Details regarding each partner (responsible persons, contact information) are attached in the annex of the present report. 3.3 Modifications according to the initial proposal There were several modifications that were made from the initial proposal. These modifications were necessary in order to better execute the project and fully achieve its objectives. The modifications were the following: 1. One of the proposed applications was the treatment of orange juice wastewater generated from the dumping of the surplus of oranges. During the conception of the proposal, there was a local practice to dump the surplus of oranges in uncontrolled dumps and receive subsidies from the EU. We had proposed to intervene and demonstrate technologies that would treat the wastewater of the leachate of the dump. By the time the project started the subsidies ended and the practice stopped. This necessitated the change of the demonstration to another problem related to orange juice production. We chose to improve the treatment of orange juice wastewater at the Lakonia Mill near Sparta. 2. The electrolytic treatment of olive mill waste for odor control at the Toutoulis Olive Mill was one of the proposed demonstrations. The technology was setup; however the owner never used it properly and was unwilling to collaborate with us. The technology was demonstrated in the lab. Towards the end of the project and after two years of unsuccessful in-situ demonstrations we moved the technology to table olive preparation plant to demonstrate the treatment of brines for the reduction of BOD. The results are very incouraging. 3. Surface irrigation of olive mill wastewater was not one of the proposed demonstrations. Tzinakos olive mill was using such technology, so it was decided to evaluate its effectiveness and potential impact to the environment. 4. In the initial Dissemination Strategy Plan several modifications took place, due to specific conditions and emerging problems: Final Report (Technical issue) – LIFE05 ENV/GR/00024 13/313 Environmental Friendly Technologies for Rural Development a. The first surveys in local residents and professionals and in the local representatives of the ERA Municipalities, as well as the preliminary study on 'Social and Economic dimensions – the first approach' revealed the low sensitization on environmental issues and more specifically the absence of any recycling and waste management systems. This condition called for a new survey in the local population and in the representatives of public agencies in order to evaluate existing capacity together with an effort for more sensitization. In this context a review of existing systems functioning at the national level was undertaken, in order to investigate their potential implementation in the PL (currently one of the four less developed Prefectures in Greece concerning recycling). Lists of the different waste management systems were produced beneficiaries, together with informative and distributed material to potential (posters, leaflets). Additionally, the potential recycling of expired drugs was investigated, based on the innovative practice adopted by the Pharmasists' Copartnership in the Prefecture of Thessaloniki. Relevant material was distributed to the pharmacists of the PL. b. In the first year of the Project severe floods caused extended damags in agricultural land and, in some cases, in settlements. The partners of the Project responded by several means: adequate surveys with representatives and farmers, elaboration of studies on flood prevention, data collection and processing in collaboration with the Hellenic Agricultural Association, organization of local meetings and seminars on flood prevention and restoration measures. c. Water shortage in the area has been observed to increase in recent years, due to reduced rains. This condition called for informative events, in order to discuss the impact on agricultural production and possible methods to decrease water consumption for agricultural and urban use. The example of the water distribution system established by the Local Organization for Land Improvement in the Prefecture of Serres was used as an indicative good practice, in order to investigate the possibility of similar practices in the ERA. Several relevant meetings with local representatives were organized. d. In the summer 2007 forest fires destroyed a great part of forest and agricultural land in the Region of Peloponness and in the mountainous part of Lakonia. The partners of the Project, in collaboration with other agents, responded by elborating studies on the restoration of the ecosystems, the preservation of the agricultural land and the possible establishment of stock-breeding parks, as in the case of the Municipality of Kyrros in the Prefecture of Pella, Region of Central Macedonia, focusing on the institutional framework and the economic viability. Final Report (Technical issue) – LIFE05 ENV/GR/00024 14/313 Environmental Friendly Technologies for Rural Development 4. TECHNICAL DEVELOPMENT 4.1 Descrption of the applied methodology and technologies 4.1.1. Methodology The demonstration character of this proposal had two distinct and complementary strategies. The first strategy was to demonstrate a series of methods and technologies that reduce agricultural pollution from point and non-point sources. All technologies were environmental friendly technologies because they were using nature‘s ability to reduce pollution. The demonstrations were grouped into three categories. Monitored natural attenuation and water management Drainage canal and river bank management Agricultural product waste management The second strategy dealt with the study of the social aspects of the region aiming at the identification of potential for changes in management practices towards sustainable development.The strategy emphasized the interaction with the farmers and other stakeholders. The objective was to lay a base for the management of the natural resources in a sustainable way. For that reason the following aspects were examined: Changing the existing cultivations to more dynamic and less water-intensive, changing some of the riparian uses towards more ecologically friendly ones, gradual adaptation of biological ways of production, perspective which might lead on the one hand the products to a more ingrown dynamic infiltration to new markets and on the other to the considerable decrease of the pollution from the used fertilizers and chemicals, development of mild forms of industry processes of agricultural products, development of ecotourism projects, which will highlight the natural environment and will integrate with it. Finally, this project demonstrated that the integration of environmental friendly technologies into the development of the watershed management plans will ensure appropriate use of water resources, benefit the environment by improving the water quality, and maintain future growth for the region. 4.1.2. Technologies Seven technologies were demonstrated during the project. These are: 1. Monitored Natural Attenuation and Water Management Monitored Natural Attenuation (MNA) is a remediation technology based on understanding and quantitatively documenting naturally occurring processes that ―destroy‖ or immobilise contaminants at a contaminated site in order to protect human and ecological receptors from unacceptable risks of exposure to hazardous contaminants. MNA is a ―knowledgebased‖ remedy where scientific and engineering knowledge is used to understand and document naturally occurring processes, instead of imposing active controls with Final Report (Technical issue) – LIFE05 ENV/GR/00024 15/313 Environmental Friendly Technologies for Rural Development engineering remedies. In order to apply MNA at a basin scale, field (collection of samples that would indicate that pollutants are being reduced as they follow their path to the river and eventually to the sea) and laboratory evidence (lab studies of the processes that attenuate pollutants and quantification of the kinetic rates of reactions) as well as modeling studies (modeling of the site that would illustrate how the pollutant behaves in nature and that the attenuation will continue to occur over geologic times) are required. 2. Drainage Canal management The drainage canal under study was located in region of Skala and drained fields of an orange grove. The length of the canal was 180m and the width of the vegetated zone was approximately 1.5m. Plants covered two distinct areas with Phragmites australis and Arundo donax. The objective of this demonstration was to evaluate the removal efficiency of nutrients due to natural attenuation mechanisms in drainage canals in Evrotas River delta in Greece (Fig. 4.1). Figure 4.1. Drainage canals at Skala region, Evrotas River delta in Greece. We investigated nutrients balance in groundwater, sediments, and reeds (Phragmites australis and Arundo donax) of the drainage canal. To monitor the temporal 3dimensional variability of hydrology and chemistry of surface and ground water in the drainage canal, eleven multi-level (3m, 4m and 5m) wells were installed. Field sampling (groundwater and surface water sampling) was conducted every two months, in order to assess the fate and transport of nutrients as they move from the groundwater to the drainage canal. In addition, laboratory studies were used to assess the biogeochemical processes that control the Nitrogen and Phosphorous cycles and evaluate the efficiency of the sediments to attenuate pollutants. Finally, the nutrient (nitrogen and phosphorus) uptake fluxes by Phragmites australis and Arundo donax were measured on a monthly basis in order to determine the timing of harvesting reeds that will maximize the removal of nutrients by plant uptake. Final Report (Technical issue) – LIFE05 ENV/GR/00024 16/313 Environmental Friendly Technologies for Rural Development 3. River Bank Mangement Temporary rivers are flashy in nature and under extreme precipitation events produce floods with extremely high erosion potential. An example of the flood destruction is a site in the area of Sparta where the river bank erosion control and phytoremediation was demonstrated. At the site, we designed and constructed a bank restoration system using large stones following the rivers curvatures to stabilize the bank and the riparian zone from future flood events. The bank erosion was therefore restored using a stone hedge of large boulders (Fig. 4.2). The length of the stone hedge was 120m, the width 2.5m at the bottom and 1m at the top, and the height 3.5m. In addition, we planted a riparian forest of 200 poplar trees to decrease nutrient loads due to uptake and enhanced denitrification. In this way, phytoremediation in conjunction with river bank erosion controls was demonstrated as a combined remediation tool for non-point source pollution of nutrients. To monitor the temporal 3-dimensional variability of hydrology and chemistry of ground water, nine multi-level (3m, 4m and 5m) wells were installed. Groundwater sampling was conducted every two months, in order to assess the fate and transport of nutrients as they move from the groundwater to the River and assess the efficiency of the technology. Figure 4.2. Sparta area – Riparian zone river bank erosion control and phytoremediation. 4. Olive Mill Waste Irrigation The basic idea behind this technology was to pre-treat the OMW with lime and pump the liquid to a nearby ―evaporation pond‖ for storage for the next 3 to 6 months. From the beginning of June the OMW was used for irrigation (after dilution with water) of a corn field. This approach has been used in a 20.000 m2 area near the ancient lake mentioned by Pafsania for the last 5 years (Fig. 4.3). The overall results from the corn production have been very positive as well as all wastewater in the pond was used up before the end Final Report (Technical issue) – LIFE05 ENV/GR/00024 17/313 Environmental Friendly Technologies for Rural Development of the summer. The primary objective of the EnviFriendly program was to evaluate any potential problem with the aquifer under the corn field. The particular location where this technology was implemented was the olive mill ―P. TZINAKOS Ltd‖ in Aiges (Gytheio, Laconia). The irrigation facility consisted of a CaO pretreatment tank, evaporation lagoon, mixing with fresh water and finally land application in cultivated corn field. We investigated the soil physical and chemical properties for the identification of soil effects after 5 years of land application of CaO pretreated OMWW. Figure 4.3. Corn field where OMW irrigation is implemented (―P. TZINAKOS Ltd‖ olive mill in Aiges, Gytheio, Laconia). 5. Olive Mill Waste Subsurface Disposal The site where this technology is implemented is the KOKKOLIS Olive Mill in Vassilaki, Laconia (Fig. 4.4). In this case, the poplars were planted in rows with a spacing of about 1.2 to 1.5m betweens the plants and a spacing of about 3.2m between the rows. The twoyear old poplars were planted in late November of 2006 and subsurface disposal was initiated in December of 2007. The OMW delivery system includes pumps and PVC pipes needed to transfer the OMW from the olive mill facility to the distribution system at the poplar site. The OMW is distributed in subsurface perforated pipes placed between the poplar rows. The distribution pipe is located approximately 40cm below the surface and it is placed in an excavated channel with a cross-sectional area of 50 cm X 50 cm. The channel is filled with medium size gravel. The maximum quantity of OMW that can be disposed on a particular site should be less than the Specific Retention of the soil in the area. Specific Retention is the measure of the water retained in the soil against gravity by capillary and hydroscopic forces when the water table of an unconfined aquifer drops. In our case, it is actually the maximum volume of water and OMW that can be retained against gravity in a unit area of the investigated site. Therefore, for a plant with a root system that reaches 5 m deep, the objective is not to allow the OMW plume to go beyond this limit. This corresponds to a maximum volume of OMW retained in a volume V (m 3) equal to 5m Area (m ). 2 Final Report (Technical issue) – LIFE05 ENV/GR/00024 18/313 Environmental Friendly Technologies for Rural Development Figure 4.4. Subsurface disposal of OMW with phytoremediation at the ―Kokkolis LTd‖ olive mill in Vasilaki, Hania). 6. Electrolytic Treatment of Olive Mill Waste One of the alternative methods for OMW partial treatment is the use of advanced oxidation processes for the complete oxidation of the phytotoxic polyphenols present in the OMW as well as for the simulataneous reduction of COD through oxidation and the removal of coagulated particles of high COD. The advanced oxidation process used in this application is electrolysis. OMW is often disposed in Evrotas riven without any prior pretreatment to remove at least the content of polyphenols. Electrolytic treatment of OMW for a short period can reduce substantially the polyphenols concentration and at the same time achieve a noticeable reduction in the COD of the OMW prior to disposal. As part of the LIFE EnviFriendly program, an electrolytic treatment unit was installed at the ―Ν & Α TOUTOULIS‖ Olive Mill in Platana (Laconia) with the following characteristics: (1) Electrolytic Cell. (2) DC Power supply. (3) Recirculation pump. (4) Stirring vessels. Following one season of unsuccessful operation due to complete unwillingness of the olive mill owner to follow the operating instructions, it was decided to change the location of the electrolytic unit to another place in Laconia, where the wastewater is from the production of table olives (EUROAMERICANA S.A.). Figure 4.5. Electrolytic treatment of olive mill wastewater at ―Toutoulis Ltd‖ and treatment of Brines at EUROAMERICANA SA. Final Report (Technical issue) – LIFE05 ENV/GR/00024 19/313 Environmental Friendly Technologies for Rural Development 7. Electrolytic Oxidation of Orange Juice Waste The Lakonia Orange Juice Plant produces large amounts of orange juice and although it has a complete biological wastewater treatment facility already in place, significant problem in the effluents are observed particularly during the period of peak production. We investigated possible improvements in the treatment and arrived at a few changes in the current operation of the facility. We installed an electrolytic pretreatment unit. The unit is placed in the outlet of the dissolved air flotation (DAF) unit and prior to the biological treatment. The location of the unit (Figure 4.6) is expected to aid by partially oxidizing the wastewater and making more easily degraded by the microorganisms. Excluding the mixing vessel, the rest of the equipment is placed on four wheels to make it easily transportable to another location in the plant. The installed electrolytic unit was evaluated for its capability to aid the overall operation (lower COD in the effluent stream) and decolourization of the final effluents. Figure 4.6. Installation of the electrolytic Unit in the Lakonia orange juice mill. Final Report (Technical issue) – LIFE05 ENV/GR/00024 20/313 Environmental Friendly Technologies for Rural Development 5. PROGRESS RESULTS 5.1 General description A brief overview of the project results per task is presented in the following sections of this chapter. A detailed description of the results can be found in Annex 2. This detailed description was necessary (eventhough it increases substantially the length of this report) since the deliverables were produced in the Greek language and the results have not been published in the scientific literature as of yet. The table below presents the percent completion of the progess indicators in each task according to the initial proposal. Progress Indicator Percent Completion Comments Task 1 Collection of existing literature 150% During the first 8 months two CDs were produced, one with the existing literature and another with the GIS information for the basin Development of database for nutrient and pesticide load estimation 100% All existing data were collected for initial load estimation and model simulation Site visits and field campaigns 100% All the proposed and planned site visits and field campaigns were conducted Identification of demonstration sites 100% Sites were identified and preliminary design was incorporated in the management plans Task 2 Installation of instrumentation and monitoring stations 100% Establishing routine monitoring and analytical techniques 100% Completion of intermediate studies 100% All the proposed instruments were installed and all the planned monitoring stations were established in Evrotas All the proposed monitoring and analytical techniques for water quality and ecological assement sampling were established All intermediate studies were completed Task 3 The planned groundwater monitoring wells were installed The proposed monitoring network was established both at the drainage canal and the riparian zone Equipment installation 100% Establishing monitoring network 100% Evaluation of background conditions 100% Field campaigns were conducted to establish background conditions Planting of trees for phytoremediation 100% 200 poplar trees were planted at the riparian zone site River bank erosion control 100% A rip-rap stone wall was built for erosion control Construction of prototypes 100% The electrolytic prototypes and the underground disposal system were constructed Installation of prototypes 100% All prototypes were installed at the respective facilities Task 4 Final Report (Technical issue) – LIFE05 ENV/GR/00024 21/313 Environmental Friendly Technologies for Rural Development 100% Three prototypes (Kokkolis, Tzinakos, Lakonia) were operated for 2 years and one prototype (Toutoulis) was moved to EuroAmericana Development of questionnaires 100% Questionnaires were developed for the different type of stakeholders Field data collection 100% Questionnaires were field out during field campaigns Completion of modelling 100% Hydrologic and nutrient modeling was conducted for the basin Stakeholder participation during open meetings 100% Two stakeholder open meetings were held for the discussion of the management plans Scenarios development 100% Alternative environmental practices and scenarios were included in the management plans 150% More than 100 meetings were held during the project 100% A website is in operation www.envifriendly.tuc.gr. 100% Several inormational brochures were printed 100% A brochure was created identifying potential trails and open farms 100% A final conference was held in May 2009 Operation of prototypes Task 5 Task 6 Task 7 Frequent stakeholder meetings Website operation Development of printed material Identification of potential trails and open farms Final conference Task 8 Advisory Board Meetings 100% Steering Committee meeting 100% Progress reports 100% The proposed (7) advisory board meetings were held The proposed (7) steering committee meetings were held The proposed (4) progress reports were completed Final report 100% 1 final report was completed The graph below shows the overall project development and the planned activities until the end of the project (May 2009). Final Report (Technical issue) – LIFE05 ENV/GR/00024 22/313 Environmental Friendly Technologies for Rural Development Final Report Period Interim Report Period 2 1st Progress Report Period 05 Bimonthly period TASK 1: 1.D1 1.D2 1.M1 1.M2 1.M3 6 Development of preliminary management plans and design of selected demonstration technologies Preliminary Watershed and Coastal Zone Management Plan Experimental design of demonstration technologies Identification and quantification of pollution loads to the watershed Environmental impact assessment of impacted water bodies th 2006 1 st 2 nd 3 rd 4 th nd Progress Report Period 2007 5 th 6 th 1 st 2 nd 3 rd 4 2008 th 5 th Completed Collection of existing data 1.M4 TASK 2: 2.D1 2.D2 Watershed and coastal zone preliminary modeling Monitored Natural Attenuation and water management Report on hydrologic and biogeochemical monitoring Completed Report on MNA demonstration results 2.D3 2.M1 2.M2 2.M3 2.M4 2.M5 TASK 3: Report on risk assessment of water management Installation of stations for monitoring the hydrology and geochemistry Instrumentation of field sites for risk assessment evaluation Protocol for a rapid assessment of riparian zone conservation Monitoring Natural Attenuation preliminary assessment Risk assessment of water management (preliminary assessment) Drainage canal and river bank management 3.D1 Efficiency of nitrate loss in drainage canals 3.D2 Drainage canal management techniques Final Report (Technical issue) – LIFE05 ENV/GR/00024 3rd Progress Report Period Completed 23/313 6 th 1 st 2 nd 3 rd 4 2009 th 5 th 6 th 1 st 2nd 3rd Environmental Friendly Technologies for Rural Development 05 6th 3.D4 3.M1 3.M2 TASK 4: 4.D1 4.D2 4.D3 4.M1 4.M2 TASK 5: 5.M1 5.M2 5.M3 5th 6th 1st 2nd 2007 3rd 4th 5th 6th 1st 2nd 2008 3rd 4th 5th 6th 1st Evaluation of nitrate loss in the drainage canals Planting of poplar trees and river bank erosion control 3.M4 5.D3 2006 3rd 4th Monitoring network sampling 3.M3 5.D2 2nd Manual of practice for the management of drainage canals Impact of phytoremediation and bank erosion control in the minimization of nitrate loads to the river Installation of wells at two drainage canal sites 3.D3 5.D1 1st Agricultural product waste management Completed Report on installation of the three prototypes and their operational characteristics Report on first evaluation of the demonstrated waste management technologies – Fine tuning of operational conditions for optimal results Report on second evaluation of the demonstrated waste management technologies. Installation of all three prototypes for waste management – operational testing completed - monitoring and sample analysis procedures established. First evaluation of demonstrated technologies for waste management; fine tuning adjustments; alternative management options tested. Integration of socio-economic aspects Completed Results of the fieldwork research Integral Planning for Sustainable Development Executive Summary and Conclusions of the local society‘s attitude Questionnaire completion Collection of existing data / Sampling and methodology of field research Statistical analysis and survey on socioeconomic impacts Final Report (Technical issue) – LIFE05 ENV/GR/00024 24/313 2009 2nd 3rd Environmental Friendly Technologies for Rural Development 05 6th TASK 6: 6.D1 1st 2nd 2006 3rd 4th 5th 6th 1st 2nd 2007 3rd 4th 5th Development of integrated watershed management plans 6th 1st 2nd 2008 3rd 4th 5th 6th 1st Completed Integrated management plans Minutes from open meetings on management plans Assessment of efficiency of technology demonstration and scaling up 6.D2 6.M1 6.M2 Open meetings on management plans 6.M3 Modeling of Watershed and Coastal Zone 6.M4 Development of scenarios TASK 7: Evaluation of social acceptance and dissemination of results 7.D1 Final Report with the results of evaluation. 7.D2 Executive Summary and Conclusions 7.D3 Creation of a Site in the Internet 7.D4 Creation of scientific observatory 7.D5 Final - International Conference 7.D6 Demonstration event 7.D7 Minutes from meetings 7.D8 International Water Day Event 7.D9 15 seminars with local stakeholders 7. D10 Creation of local network 7. D11 Publication of 2 booklets (brochures) 7. D12 Special education kit 7. D13 Dissemination strategy plan 7.M1 Creation of a local Development Observatory 7.M2 13 Meetings with local representatives 7.M3 Creation of local network 7.M4 Mapping of trails and open farms TASK 8: Project Management Completed Completed st 8.D1 1 Progress report 8.D2 Interim report Final Report (Technical issue) – LIFE05 ENV/GR/00024 25/313 2009 2nd 3rd Environmental Friendly Technologies for Rural Development 05 6th 8.D3 2nd Progress report 8.D4 3rd Progress report 8.D5 Final Report 8.D6 1st Advisory Board minutes 8.D7 1st Steering Committee meeting minutes 8.D8 8.D9 8. D10 8. D11 8. D12 8. D13 8.M1 1st Advisory Board meeting 8.M3 1st Steering Committee meeting 8.M5 8.M6 8.M7 8.M8 8.M9 2nd 2006 3rd 4th 5th 6th 1st 2nd 2007 3rd 4th 5th 6th 1st 2nd 2008 3rd 4th 5th 6th 1st 2nd Advisory Board and Steering Committee meetings minutes 3rd Advisory Board and Steering Committee meetings minutes 4th Advisory Board and Steering Committee meetings minutes 5th Advisory Board and Steering Committee meeting minutes 6th Advisory Board and Steering Committee meetings minutes 7th Advisory Board and Steering Committee meetings minutes Creation of Advisory Board and Steering Committee 8.M2 8.M4 1st 2nd Advisory Board and Steering Committee meetings 3rd Advisory Board and Steering Committee meetings 4th Advisory Board and Steering Committee meetings 5th Advisory Board and Steering Committee meetings 6th Advisory Board and Steering Committee meetings 7th Advisory Board and Steering Committee meetings Deliverables (Reports or any other material produced) Delay Achieved earlier Final Report (Technical issue) – LIFE05 ENV/GR/00024 Deliverables (Reports or any other material attached to the final report) New action – not proposed 26/313 2009 2nd 3rd Environmental Friendly Technologies for Rural Development 5.2 TASK 1 – Development of preliminary management plans and design of selected demonstration technologies The first action taken by the team was the collection of the existing data and studies of the watershed and the coastal zone. We collected the available hydrologic, hydrogeologic, meteorologic and water quality data from all known public and private institutions. In many cases, these data were not in electronic format, so we entered them in data bases. Similarly, we obtained available GIS databases such as CORRINE land use database from the JRC-ISPRA, the digital elevation model, geology, population, river network etc. In cases, portions of the GIS theme map was missing (such as in the case of geology), we digitized it. Finally, the reports from various studies were scanned in order to develop an electronic data base of all available studies. At the end, two CDs were produced, one with the GIS information for the basin and another for the existing studies (the cds were submitted to E.C. with the Interim Report). We worked very closely with two scientists from the Prefecture of Laconia, the hydrogeologist, Mr. Papadoulakis and the health inspector, Mr. Kouvatsos. This collaboration was necessary for us in order on one hand to acquire their scientific knowledge of the area and assessment of the problem and on the other hand to initiate their training in managing the watershed. The main pollution point sources are urban waste water, olive oil mills, and orange juice factories while diffuse sources are agricultural activities and livestock pollution. Based on the distributed information on the point and non-point sources for the watershed of Evrotas River, the nutrient (N and P) loads were estimated. The total input nitrogen load was estimated to be 46471 tn/yr and the P-load 19323 tn/yr. Agricultural activities contributed 43865 tn/yr of nitrogen (94.4%) and 18855 tn /yr of phosphorous (97.6%). Livestock, atmospheric deposition, urban waste water, olive oil mills and orange juice factories contributed the remaining of the load. Approximately 50% of the N and P fertilizer loads is contained in the produce and does not enter the system. Therefore, the net loads of N in the watershed were estimated to be 24539 tn/yr and of P 9896 tn/yr. Agricultural activities contributed 21933 tn/yr of N (89,4%) and 9896 tn/yr of P (95,3%). In this phase, we attempted to conduct a complete integrated study on nutrients for the development of the Preliminary Management Plan. A preliminary environmental assessment was based on the identification of pollution sources, estimation of pollution loads, assessment of hydro-morphological alterations and on the vulnerability of the basins‘ water resources. In addition, field investigations and a preliminary biological quality assessment, from the first sampling campaign were considered. Ecological quality assessment included the entire river basin (main stem and tributaries) and was be based on abiotic and biotic elements. A set of abiotic variables was selected on which an initial biotic typology (System B) for Greek running waters could be based. These variables include: catchment area, altitude, slope and geology. By combining GIS-layers of geology, altitude and slope on Evrotas basin, it results that 95% of the catchment area is covered by 11 theoretical types, while the sampling network belongs to 7 distinct types. During the first field campaign (5-12.04.2006), the following actions were carried out: Estimation of the geographical coordinates of each site. Final Report (Technical issue) – LIFE05 ENV/GR/000245 27/313 Environmental Friendly Technologies for Rural Development At each sampling reach photos and videos were taken. In addition, photos and videos of four fish species have been taken (in situ, ex-situ). In-situ measurements conductivity, pH, Eh, of physico-chemical dissolved oxygen, variables current velocity (temperature, with portable instruments) and estimation of the wetted cross section. Water sampling - Samples were analyzed for hydrochemical variables (total hardness, Ca2+, Mg2+, Na+, K+, HCO3-, CO32-, Cl-, SO42-, SiO2) and conventional pollutants (nitrate, ammonia, nitrite, total nitrogen, orthophosphate and total phosphorous). Sediment sampling - In selected stations sediment samples were collected for the estimation of mineralogical and chemical variables. Registration of river bed, river bank and riparian zone characteristics - For this purpose the AQEM/STAR protocol was applied, that aims to give an impression of river and floodplain morphology, hydrology, hydrochemistry and vegetation composition. The collection of these data was conducted at a distance of 500 m upstream and downstream of each sampling site. Hydro-morphological analysis was performed with the use of the river Habitat survey (RHS) method. RHS assesses the physical character of a sampling site at a 500 m length and involves the collection of numeous features recorded at a 10 spot-checks in 50 m intervals. The habitat quality of each site (stream channel and riparian habitat) was evaluated with the use of the Habitat quality Assessment score (HQA) and Habitat Modification Score (HMS). HQA assesses the habitat diversity, while HMS represents habitat modification. Sampling of benthic invertebrates - The AQEM/STAR macroinvertebrate sampling methodology was applied. Fish sampling - Field investigations on the presence of fish species and a preliminary sampling were carried out with the use of electrofishing, nets, etc. Additional sites have been selected for a systematic fish sampling during the next stages of the ecological assessment. As a result of the combined actions of water infiltration within the alluvial deposits and the karstic basement, surface water abstractions and groundwater pumping, parts of Evrotas main stem (headwaters, near Vrodamas-bridge, within Vrodamas-gorge, upstream of Skala village) dry out during the dry season. The vast majority of Evrotas tributaries, dry out in summer. In general, downstream of water abstraction facilities tributaries fall dry. Oinus, the main Evrotas tributary, episodically becomes temporal due to water use for irrigation. Similarly, the downstream portions of Gerakaris, Kakaris, Rasina, Xerias, Lagada (Magoulitsa) and other smaller tributaries have become temporal. The water resources problems of Evrotas River Basin can be summarized as follows: Quantity problems – These are problems caused due to flooding and include the weathering of soils and the river banks, as well as flooding of low elevation areas and destruction of properties. Final Report (Technical issue) – LIFE05 ENV/GR/000245 28/313 Environmental Friendly Technologies for Rural Development Quality problems – degradation of surface and ground water quality due to point and non-point source pollution. Ecological problems – Fish populations can not be established in many parts of the river because it dries out due to over-pumping of ground water. For the preliminary management plans, an emission based model, MONERIS was used to model the nutrient emissions from the watershed to the coastal zone. In addition, Laconikos Gulf was modelled with a simple mass balance model, CABARET, following the LOICZ methodology. Figure 5.2.1 presents a comparison between modeled and measured nitrogen loads for the watershed. The total nitrogen emissions were estimated to be 1940 t/yr. 58,7% of the emissions entered the river through ground water, 10,8% from urban waste water, 4,5% from point sources, 9,2% from erosion of soils, 5,5% from surface runoff and 0,4% from the atmosphere (directly to the river). Finally, in- stream loads contributed 10,8%. The total phosphorous emissions were estimated to be 208 t/y. 11,3% of the emissions entered the river through ground water, 2,9% from urban waste water, 29,6% from point sources, 44,1% from erosion of soils, 11,4% from surface runoff and 0,7% from the atmosphere (directly to the river). The results indicate that there is evidence of natural attenuation of nutrients in the watershed. The net annual nitrogen loads to the basin were reduced from 24539 tn/yr to 1940 tn/yr that entered the coastal zone (92% reduction). The net annual phosphorous loads to the basin were reduced from 9896 tn/yr to 208 tn/yr that entered the coastal zone (98% reduction). The coastal zone of Laconikos Gulf was modeled using the LOICZ methodology and the CABARET model. CABARET conducted mass balance calculations for water, salinity, dissolved inorganic and total nitrogen and phosphorous. It was estimated from the nutrient balance that ΓDIN=-377E+3 moles/day and ΓDIP=-12,7E+3 moles/day. Therefore the coastal zone is operating as a consumer of DIN and DΟΡ. The difference between photosynthesis and respiration (p-r) was 19 mmoles/m2/day. A positive difference (p-r) indicates that the system is a net organic matter producer. The difference between nitrogen fixation and denitrification (Nfix-denit) was -2,5 2 mmoles/m /day. The negative difference (Nfix-denit) indicates net denitrification. The fact that the system was oligotrophic in 1992, and consumed nutrients suggests that it is not saturated. It is not expected to have a nutrient status change if the nutrient loads to the system do not change significantly. Finally, 3 scenarios were simulated using MONERIS in order to evaluate the impact of the demonstrated technologies in reducing the nutrient loads to the coastal zone. 100000 100000 Nitrogen emissions-load 10000 DIN-load [t/a] TN-load [t/a] 10000 1000 100 100 Nitrogen (hydraulic load) 1000 100 1000 10000 Calculated TN-load [t/a] 100000 100 1000 10000 calculated DIN-load [t/a] 100000 Figure 5.2.1. Modeling results of Evrotas river basin – Comparison between modeled and field total nitrogen (TN) and Dissolved Inorganic Nitrogen (DIN). Final Report (Technical issue) – LIFE05 ENV/GR/000245 29/313 Environmental Friendly Technologies for Rural Development 5.3 TASK 2 – Monitored natural attenuation and water management 5.3.1. Monitored Natural Attenuation in Evrotas River Basin Monitored Natural Attenuation (MNA) is a remediation technology based on understanding and quantitatively documenting naturally occurring processes that ―destroy‖ or immobilise contaminants at a contaminated site in order to protect human and ecological receptors from unacceptable risks of exposure to hazardous contaminants. MNA is a ―knowledge-based‖ remedy where scientific and engineering knowledge is used to understand and document naturally occurring processes, instead of imposing active controls with engineering remedies. In order to apply MNA at a basin scale, field (collection of samples that would indicate that pollutants are being reduced as they follow their path to the river and eventually to the sea) and laboratory evidence (lab studies of the processes that attenuate pollutants and quantification of the kinetic rates of reactions) as well as modeling studies (modeling of the site that would illustrate how the pollutant behaves in nature and that the attenuation will continue to occur over geologic times) are required. 5.3.1.1. First step: Field evidence Historic water quality data of Evrotas River were collected to establish the first evidence for the reduction of contaminants in the study area. Pollutant concentrations (such as COD, Total N and Total P derived from diffuse pollution (agriculture, livestock etc.) and point sources (olive mills, juice producing factories, towns)) were decreasing along the river indicating active attenuation processes operating within the watershed. To augment the historic data, a sampling network was designed and intensive field campaigns were carried out to introduce new field evidence and account for all major ecotopes in the basin aiming at tracking the foot print of contamination (tracking contaminants from pollution sources to ground and surface water). The pollutants studied were nutrients, organic load and total phenols (a component of olive mill waste). Evrotas river basin has a complex hydrogeology and hydrographic network. It was necessary to develop a sampling network based on the hydrology of the region, the geology, the relief, slopes and land uses. Evrotas river basin was separated into seven sub-basins. The selection of the position of each sampling point was based on the typology of the basin (relief, slopes, geology, land use and point source maps) created using GIS. The selection of the sampling points (SPs) was based on the understanding of the hydrology and hydrogeology of the region. Surface water sampling points were chosen throughout the length of the river. The majority of the ground water sampling points were selected to be in sub-basins 5 and 7 (Sparta and Skala regions), since many point sources of pollution exist and agricultural activities are extensive. Additionally, sub-basin 5 has many and important tributaries of Evrotas river. Finally, important groundwater aquifers are found in the region and the ground water is used for irrigation and water supply. Based on the above considerations the sampling network consisted of 64 Final Report (Technical issue) – LIFE05 ENV/GR/000245 30/313 Environmental Friendly Technologies for Rural Development sampling points: 32 for surface water (Map 5.3.1) and 32 for underground water (10 Springs, 10 Shallow Well, 12 Deep Wells- Map 5.3.2). Six sampling campaigns were conducted on: (1st) 9-12 of May 2006, (2nd) 8-12 of September 2006, (3rd) 12-17 of January 2007, (4th) 26 of May – 1 of June 2007, (5th) 26 September - 12 December 2007, (6th) 3-5 of March 2008. During those field campaigns psychochemical parameters of the samples were measured in situ while water samples were taken to the laboratory for chemical analysis. The water samples were analyzed for Nitrate Nitrogen (NO3-N), Nitrite Nitrogen (NO2-N), Ammonia (NH4-N), Dissolved Inorganic Phophorous (DIP), Total Organic Carbon (TOC), Chemical Oxygen Demand (COD), phenols, selected heavy metals (Cu, Cd, Zn, Pb and Ni) and pesticides. The physicochemical parameters pH, Eh, Dissolved Oxygen and conductivity were measured in situ. Map 5.3.1. Sampling points of surface water. Map 5.3.2. Sampling points of groundwater. Evidences of Natural Attenuation in surface water Evrotas River samples were analyzed in order to evaluate the existence of natural attenuation. The sampling points along the river were: Pardali (8), Karavas (52), Sparta Bridge (53), Sparta Biological treatment (54), Skoura (22), Vrodamas Bidge (34), Palaiomonastiro (55) and Evrotas Estuaries (56). The following observations can be made: The highest average COD concentration was found at Skoura (14 mg/L) and there was a significant attenuation after the peak. The COD value at the Estuary of Evrotas was below detection limit. The COD concentration decreased significantly due to in-stream attenuation processes and dilution from unpolluted tributaries. The same trend existed for the other pollutants as well. The highest concentrations of NO2-N, NO3N and Total phenols were also measured at Skoura with a significant attenuation Final Report (Technical issue) – LIFE05 ENV/GR/000245 31/313 Environmental Friendly Technologies for Rural Development observed downstream. Phosphates peaked close to the wastewater treatment plant of Sparta. This peak was due to the outflow of the treatment plant. Evidence of Natural Attenuation in Ground Water The main ground water aquifer is found in the plain of Sparta. Ten shallow ground water wells and twelve deep ground water wells have been sampled. The following observations can be made: The average nitrate concentrations of the shallow wells 41 and 38 was reduced from 14.5 mg/L to 9 mg/L. In addition following ground water direction for shallow wells 46 to 37, a similar reduction for nitrates was taking place (13.1 mg/L to 12.6 mg/L). Nitrates reduction was also observed from the spring of Peristeri, 13.7 mg/L to shallow well 37, 12.6 mg/L. The results indicated that high nitrate concentrations were found in the Sparta aquifer and they were being attenuated as the water moved towards the area of Vrodamas. Total phenols concentration of shallow well 41 was 1.5 mg/L and the concentration of well 38 decreased to 1.2 mg/L. Similar reductions were observed for shallow wells 46 and 37. The COD and nitrate nitrogen concentrations of ground water deep wells indicated that the pollution load was attenuated along the ground water flow. The concentrations of COD and nitrate nitrogen of groundwater deep wells of SPs 12, 13, 14, 18 and 20-b were higher than those of SPs 16 και 17 despite the fact that there were many villages and significant agricultural activities taking place in the region. These results provide evidence of natural attenuation in groundwater. Overall, significant attenuation of pollutants was observed in the Evrotas river basin both for surface and ground water. Organic pollution was originated mostly from point sources and impacted the surface water (6.2 mg/L COD) as opposed the ground water (springs about 4 mg/L COD). Nitrates-N pollution impacted more the ground water (9 mg/L in shallow wells) and it was attenuated to 1.4 mg/L by the time it reached the surface water. Nitrates have impacted significantly the deep wells with average concentration of approximately 6 mg/L and a standard deviation of 12 mg/L. Phosphate-P was highest at the deep wells (0.163 mg/L) and it decreased to 0.087 mg/L at the springs and 0.055 mg/L at the shallow wells and surface water. The results suggest intense agricultural activities have impacted historically the deep ground water wells while recent practices have improved the water quality (lower concentration in shallow wells). 5.3.1.2. Second step: Modeling evidence Evrotas river basin modelling – MNA evaluation Evrotas River is a complicated hydrologic system that drains an area of 2420 km2, 50% of which is covered by limestone-karstic formations. The mountains of Taygetos and Parnonas, reaching an elevation of 2404m, affect drastically its hydrologic patterns. Final Report (Technical issue) – LIFE05 ENV/GR/000245 32/313 Environmental Friendly Technologies for Rural Development Modeling of the hydrology and nutrient emissions of the watershed was accomplished using the WMP-Med (Watershed Modeling Platform –Mediterranean) which is comprised of the Karstic Model and the ETD (Enhanced Trickle Down) Model and the model MONERIS. To simulate the hydrology of the watershed, it was subdivided into 6 subcatchments (NE Taygetos, NW Parnonas, NW Parnonas, Central Taygetos, Skalas and Gytheiou). The simulation period was 2000-2007 (8 years long). The hydrologic simulation results for the Vivari station (NE Taygetos subcatchment), the Kelefina station (NW parnonas) and Vrontamas station (Central Taygetos) are presented in Figure 5.3.3. The WMP-Med model was able to capture the seasonal and inteannual variability of the flow very well. The correlation coefficient between the simulated and field data was between 0.92 and 0.84 and the Nash Sutcliffe efficiency was between 0.61 and 0.68. The mean error in the annual flows was less than 10%. The annual average hydrologic balance of Evrotas River was as follows: the precipitation was 1048 Mm3, the karstic discharge 330 Mm3, the evaporation was 727 Mm3, stream discharge was 133 Mm3, stream withdrawals were 16 Mm3, and the change of storage in the watershed was 38 Mm3. estimated at 174 Mm 3 The annual irrigation needs of the watershed were based on typical irrigation plant requirements for the region. These irrigation needs were used in the model simulations. However, the real irrigation use was not known since there are more than 3500 public and private wells in the watershed, none of which water consumption has been monitored. The model estimated 3 that irrigation was underestimated by 337 Mm . The modeling results suggest that on the average irrigation used 3 times more water than the recommended values. The results from the hydrologic simulation were used as inputs in the MONERIS model. The MONERIS model was used for the simulation of nutrient emissions from Evrotas river basin. The model calibration was achieved by changing parameters such as phosphorous atmospheric deposition (0.99 kg/ha-yr) and inhabitant specific Phosphorous output factor (1.8 g/inhabitant-day). The dissolved inorganic nitrogen loads used for the calibration were 97 tn-N/yr in Selasia, 133 tn-N/yr in Sparta, 375 tn-N/yr in Vrontama and 413 tnN/yr in Tafros Omega. Figure 5.3.4 presents a comparison between measured and modeled nitrogen emission loads. The highest fluxes of nitrogen originated from the delta area (47.8%), followed by groundwater (24.7%), urban areas (13.9%) and point sources (8.6%). On the other hand, the highest fluxes of phosphorous originated from point sources (72.3%), followed by erosion (10.1%) and the delta area (7.8%). The total nitrogen emissions were estimated to be 1092 t/y which corresponded to 4.5% of the total Nitrogen input (24539 tn/yr) and the total phosphorous emission loads were 179.2 t/yr which corresponded to and 2% of the total Phosphorous input (9896 tn/yr). The modeling exercise quantified the reduction of nutrient loads in Evrotas watershed by natural attaenuation mechanisms. Final Report (Technical issue) – LIFE05 ENV/GR/000245 33/313 Environmental Friendly Technologies for Rural Development Figure 5.3.3. Evrotas river hydrologic simulation results using the WMP-Med model for the period of 2000-2007. Figure 5.3.4. Results of Evrotas modeling Comparison Dissolved Inorganic Nitrogen model and field. 5.3.1.3. Third step: Laboratory evidence The main objective of this phase was the quantification of the biogeochemical processes operating at the watershed. The processes were studied using mesocosm and microcosm laboratory experiments in order to quantify the kinetic rates of the processes that take place and result in the attenuation of pollutants by the soils. A soil sampling network was designed to cover most of the soil types found in Evrotas river basin. In Evrotas river basin 11 soil types are found according to the Greece soil map (1:1.000.000, 1967), 6 of those cover 94% of the watershed area. The location of the soil sampling was near the riparian zone of the Evrotas river. Riparian zone are areas where ground water interacts with surface water and active attenuation processes take place. Sampling took place in November 2007. Nine surface sediment samples (0-10 cm) and ten cores (50 cm depth) from 11 different locations were obtained. Final Report (Technical issue) – LIFE05 ENV/GR/000245 34/313 Environmental Friendly Technologies for Rural Development The total Nitrogen content ranged from 0.63 up to 1.99 g/kg and organic matter from 0.46 up to 2.36%. The soil pH ranges from 7.87 up to 8.41 and Electrical Conductivity from 587 up to 1075 μS/cm. Two soils (9A and 9B) were used to study the long term release of nitrogen species from the sediments. A release of organic N, ammonium N and nitrate N was observed in both soils. The released concentrations of organic N ranged between 4 to 9 mg/L, for ammonium N ranged between 0.4 to no detect and nitrate N ranged between 0.2 to 1.4 mg/L for soil 9A. The respective concentration ranges for soil 9B were 10-25 mg/L for organic N, 2 to no detect for ammonium N and no detect to 8 mg/L for nitrate N. Ammonium N was converted to nitrate N within a few days. The results between the two soils exhibited high variability due to variation in their oxidation-reduction capacity. DON reached a constant partitioning with the sediment bound organic nitrogen within 5 days. The DON concentrations at equilibrium were 8 and 11 mg/L for the two sediments respectively. Ammonia N was lost within 6 days and nitrate N followed a release and dissapperance cycle that lasted between 12 and 14 days. It is hypothesized that organic N is mineralized to ammonia and nitrate. Nitrate reached a maximum dissolved concentration after 6-10 days since the commencement of the experiment and then it dissappeared presumably due to denitrification. Nitrogen removal was most intense in sample 9B compared to 9A due to higher reduction capacity. To better understand the nitrate loss due to denitrification, an experiment was performed using sediment sample 5 by spiking the solution with 5 mg/L of nitrate N. Figure 5.3.14 presents the evolution of the concentrations of Nitrate-N and Ammonia-N in time. Only 3 out of the 5 mg/L nitrate N were measured in solution at steady state while ammonia N concentrations were not different between the spiked and the non spiked samples. The results suggest that the denitrification process is active and that it reaches steady state within 4 days. The phosphate sorption kinetic rates were estimated to be 0.19/d and 0.11/d for samples 9A and 9B respectively. Soil 9A is behaving as phosphate sink, since its EPC0 is less than 0.1 mg/L. In contrary Soil 9B is behaving as phosphate source (EPC0>0.1 mg/L). Similar phosphate sorption kinetics were found in 7 other sediment samples. The phosphate sorption kinetic rates ranged between 0.16/d and 0.32/d. The half life of phospahte sorption ranged between 2 and 4 days and the time to reach 95% steady state ranged between 9 and 19 days. Soils with high organic matter content had higher phosphate sorption capacity. The vertical variability of soil characteristics were examined using soil cores. The cores (50 cm length) were split into two parts (2/3 and 1/3 from the top) and were analyzed for electrical conductivity, pH, organic carbon and total nitrogen. The results are presented in Table 5.3.7. The electrical conductivity ranged between 253 and 1047 μS/cm, the pH between 7.66 and 7.99, the organic carbon between 0.5 and 5.7% and total nitrogen between 0.12 and 0.37%. The rates ranged between 0.23 and 0.55/d. In general, the results showed lower concentrations of organic carbon, TN and sorption rate with depth. The mineralization potential was estimated as the difference in ammonia concentration in solution in one week minus the ammonia concentration of the leachate in one hour. The Final Report (Technical issue) – LIFE05 ENV/GR/000245 35/313 Environmental Friendly Technologies for Rural Development PMN ranged from 0.13 to 3.29 mg/Kg and the partitioning coefficient from 664 to 13433 ml/g. Organic nitrogen was tightly adhering to the soil and the retardation factor (ratio of the velocity of the water to the velocity of the chemical) was between 2500 and 50000. In general, soils in Evrotas appear to have significant mineralization, nitrification and phosphate sorption capacities to attenuate nutrients originating from agricultural activities. 5.3.1.4. Conclusion The three steps of MNA implementation have been completed providing sufficient and documented evidence that mechanisms of natural attenuation operate at the Evrotas River Basin. The attenuation of nitrogen and phosphorous were quantified using an emission based model, MONERIS. 95.5% of the nitrogen and 98% of phosphorous were attenuated with the watershed. The nitrogen and phosphorous emissions to the coastal zone were 1092 tn/yr and 179 tn/yr, respectively. Organic nitrogen mineralization, nitrification, denitrification and phosphate sorption were studied in the laboratory using soil samples. Kinetic rates of the processes that control nitrogen and phosphorous attenuation were quantified in order to be guaranteed that these processes will operate long term. The results indicated that significant attenuation of nitrogen and phosphorous exist in the watershed and that MNA is a viable remedial measure for the watershed. 5.3.2. Water Management in Evrotas River Basin In the framework of the EnviFriendly project, the assessment of the “Hydrologic and biogeochemical monitoring” of Evrotas River was implemented according to the demands of the Water Framework Directive 2000/60/EC. The main tasks that were carried out included the estimation of the spatiotemporal hydrochemical regime and the assessment of pressures and impacts on the river network, and the ecological assessment of the river basin. The latter based on the typological characterization of the basin, the establishment of type specific reference conditions, and the classification of running waters using chemical, hydromorphological and biological components. For the development of conservation schemes, the ecological requirements for endangered fish species were investigated. In addition, since the river is subjected to severe hydromorphological pressures, the status of riparian vegetation of its courses (not included in the project‘s proposal) was evaluated. In the framework of the “Risk assessment of water management”, a methodology was developed and applied for the identification of natural and anthropogenic causes of desiccation. In addition, the geographical extent of desiccation and the impacts of water management on the river‘s ecosystem were carried out. The results of these studies assisted the development of specific measures and the design of management plans for the improvement of the ecological status of the river. Final Report (Technical issue) – LIFE05 ENV/GR/000245 36/313 Environmental Friendly Technologies for Rural Development Hydrologic and biogeochemical monitoring The implementation of Task 2 within the EnviFriendly project revealed specific pressures acting in Evrotas River Basin and assessed the impacts on river hydrology, river and riparian morphology, aquatic quality and biota. The Evrotas main course revealed higher nutrient levels than larger Balkan rivers. High loadings of organic matter and nutrients cause eutrophication, especially at the main course of the river below Sparta. Management of phosphorous sources of pollution is of first priority to control eutrophication. Herbicides, fungicides and insecticides were detected in 50% of the waters and sediments examined with concentrations in waters mostly exceeding the acceptable limit for potable water (0.1 μg/L). Olive oil and fruit juice processing wastes were proved toxic (according to LC50 tests) for certain macroinvertebrate species and receiving water bodies score a bad ecological status, especially during operation time. After the end of the olive oil production period, the biotic community recovered in contrast to fruit juice wastewaters where the biotic community was severely impacted throughout the year. Moreover, there is evidence of improper operation of the Municipal Waste Water Treatment Plant of Sparta (MWWTP). In order to achieve good ecological status for running waters, it is essential to apply best agricultural practices aiming in drastic reduction of agrochemicals and effective treatment of agro-industrial wastes. In addition, the MWWTP should operate properly throughout the year. Regarding the ecological assessment, the hydro-morphological status ranged from high to good in the upper parts of Evrotas tributaries and from poor to bad in the middle and lower part of the Evrotas main course. The river used to be famous for its lowland riparian forests. Today, the Evrotas has the most extensive and best preserved lowland riparian forests in Peloponnese. Nevertheless, the former extensive riparian forests are restricted in six main stands. The vast majority of these stands is affected by human activities and present lower than good status. The physico-chemical status ranged between high and moderate, with the majority of samplings sites (84%) classified between high and good. The biological status based on macroinvertebrate communities showed high spatial and temporal variability depending on the distribution of point pollution sources. In the majority of the examined stations (60%), the biological status scored between high and good. The ecological status in Evrotas River Basin, according to hydromorphological, physico-chemical and biological (macroinverte-brates) quality elements showed that the majority of the sites (70%) were classified good. The correlation coefficient between the metric scores of the biological and physico-chemical status was satisfactory, thus providing evidence for the dependence of biological assemblages on river quality. Ichthyofauna was used for assessing hydromorphological alterations. Fish fauna assessments showed a generally poorer biological status compared to macroinvertebrates, with more than half (52%) of the sampling sites classified as bad. This situation was largely the consequence of an unusual drought event which occurred in summer 2007, combined with overexploitation of the water resources. As a result, almost all tributaries and about 80% of the main river course dried out causing massive fish deaths in isolated reaches that maintained water (i.e. in remaining pools). In the remaining part of the river, where summer flow was maintained, the biological status of fish fauna ranged between high and moderate. Final Report (Technical issue) – LIFE05 ENV/GR/000245 37/313 Environmental Friendly Technologies for Rural Development The overall ecological status, including all the examined quality elements (for the main course of Evrotas and in Oinous, were fish communities were examined), was determined by fish, which in all cases presented a worse status than any other quality element. The vast majority of Evrotas tributaries dry out artificially and fish assemblages are either missing or strongly disturbed. According to local citizens, in the past fish were present in almost all Evrotas tributaries. If fish have been included in the assessment system of these tributaries, their ecological status would be termed, according to expert judgment, poor or bad. The Evrotas basin is a unique conservation hotspot in Greece, with a high biodiversity, including many local endemic plants and vertebrates. Three out of five native species inhabited in Evrotas are range-restricted endemics of high conservation value: Squalius keadicus and Pelasgus laconicus, which are confined exclusively to this river, and Tropidophoxinelus spartiaticus, which also occurs in some rivers of southern Peloponnese. In the framework of the project, the ecological requirements of fish were investigated aiming on the development of a fish based index for quality assessment and classification purposes and the design of appropriate conservation schemes. 5.3.3. Risk assessment of water management Water management practices in the Evrotas River Basin include intensive water abstractions from the river channel network and from the groundwater aquifers for irrigation, while severe morphological modifications of river channels, river banks and riparian vegetation, result from irrigation, land reclamation, flood protection and construction activities. These practices limit water and habitat availability and severely affect aquatic and riparian biota. Hydrological pressures Many reaches of the Evrotas River main course dry out during the summer for many kilometres, even in normal hydrological years. In 2007, 80% of the main river course desiccated. In addition, most tributaries dry out at the mid and lower reaches, and few only retain water at their upstream reaches near the springs. In the past, the Oinous, the major Evrotas tributary, used to retain water throughout the year; nowadays it retains water only at its upper reaches and in few spring areas midway. Intense water abstractions for irrigation during the last decades substantially affected the hydrological regime of the river network which has thus become intermittent. The following facts and evidence support this: a) historical analysis, which reveals that in the past the Evrotas was a perennial river, b) the existence of fish in the majority of its tributaries in the recent past, c) the dramatic diminishing in river runoff, which is the highest compared with 10 major Balkan rivers, d) the abrupt interruption of river flow in summer, and e) the estimation that the water balance without olive groves irrigation would ensure a substantial increase of summer flow. In particular, a long-term decrease of both rainfall and discharge in Evrotas Basin is evident within the last 35 years. Within the last decade, the average rainfall diminished Final Report (Technical issue) – LIFE05 ENV/GR/000245 38/313 Environmental Friendly Technologies for Rural Development by 13%, while the average discharge decreased by 53%. This fact provides evident for an ―artificial‖ discharge diminishing in the Evrotas Basin. Hydrograph analysis showed that in summer, water discharge in Evrotas at Sparta and Kelefina bridges reached the zero point abruptly indicating the impact of water abstractions. To quantify the effects of agricultural water uses on Evrotas discharge, the water balance of the river basin was estimated a) according to the current water uses and b) according to the current water uses by abstracting the water used for irrigation of olive groves. This approach was dictated by the fact that irrigation of olive trees has been recently introduced in the basin. The results of the monthly water budget analysis indicated that today in the end of the hydrologic period the remaining water resources in the catchment is less than 2.9 m3/s. Prior the irrigation of olive groves the discharge was 9.4 m 3/s. Considering that 50 years ago agricultural land was less extended than today it is realistic to assume that during that time the summer discharge of the river was almost four times higher, which is assumed to be enough to maintain water flow throughout the year. Morphological pressures Within the last decades, cultivations in Evrotas Basin have been extended towards natural and semi-natural land. In many parts of the Evrotas course, crops end where the river water starts. In order to protect the agricultural fields that lie besides the river, and also in order to facilitate the distribution of water into the agricultural land, the riparian zone of Evrotas has been shrunk, straightened, embanked, reinforced with grit or large stones or even with construction waste, while its natural vegetation has been removed. Riparian forests known from the recent history of the area for their role in flood control were reduced dramatically. A few decades ago, the Evrotas at its downstream (southern of Skala, Special Protection Zone - NATURA 2000) was meandering and was marked by extensive floodplains and marshes. This river section was straighten and embanked and the floodplain and the marshes turned to agricultural land. Over the last decades, as a result of deforestation in mountainous and semi-mountainous areas and climate change, the frequency and intensity of flood events has increased. To protect crops from flooding, the Laconia Prefecture regularly deepens river stretches by removing river bed material in an inappropriate and often catastrophic manner for river habitats and biota. The recent (2007) wildfires raised concern over probable winter floods and led to the decision to intensify flood-control interventions in the river bed and banks. Flood-control measures have adverse effects on the riverine habitats and ecosystems, in addition to having a high economic cost associated with them. Moreover, their usefulness against flooding events is doubtful, because the material deposited on the river banks will be flashed out and return to the river during the next severe flood event. In addition, illegal extraction of river bed material for construction activities takes place (e.g. huge amounts of gravel were removed from the river bed at Skoura to construct a new bridge). Final Report (Technical issue) – LIFE05 ENV/GR/000245 39/313 Environmental Friendly Technologies for Rural Development Impacts on water quality River water in summer showed increased nitrate and, especially, ammonia levels, compared to the wet periods as a result of discharge reduction, which causes diminishing of the river‘s dilution capacity. Moreover, low flow or standing waters enhance the development of aquatic vegetation and the expression of eutrophication conditions. The later may lead to anoxic state. Impacts on biota Fish fauna can be considered as the most appropriate indicator to assess hydromorphological degradation in its various forms. The application of fish based assessment systems revealed that the main environmental problem for the river basin faces is the immense and uncontrolled water abstraction. The hydrological effects on fish fauna can be divided in drought and post drought effects. During the summer 2007, in the drying river areas, fish either died or assembled at residual pools where hyperthermia, anoxia and increased predation from birds and otters led to significant mortality. Large bodied individuals appeared to be more sensitive than smaller-bodied ones. On the contrary, in limited river stretches which maintained a satisfactory flow the fish fauna assemblages were not affected. The sections which remained wet during the dry season, provided refugia. In 2008, fish populations started to recolonise the areas affected by drought by passive downstream dispersion of young or small sized individuals. Considering the absence of larger individuals, fish communities in the affected areas did not show signs of significant recovery. It seems that a series of hydrologically undisturbed years is required to restore fish assemblages in Evrotas main course. As it concerns the effects of morphological alterations, habitat-specialist species, like T. spartiaticus and S. keadicus are in severe recession, mainly as a result of bed leveling or pebble abstraction, which has led to loss of the specialised habitats these two species are utilising. Management implications Climatic models for the Mediterranean basin predict a reduction in precipitation and river runoff in summer and autumn. At the same time, agriculture will require more water especially in the hotter drier regions. An increase in water temperatures and lower river flows will affect water quality. In the case of Evrotas River, surface runoff has dramatically diminished and groundwater levels have severely dropped. Hence, climate change will further deteriorate aquatic quantity and quality. The ichthyological research illustrated how the 2007 drought caused substantial mortality that may affect the community composition in the long term. More severe droughts expected under altered future climates and elevated water consumption may result in severe declines or extinctions of sensitive species. Moreover, the occurrence of floods generates further stress to fish populations, exacerbating the stresses already experienced due to the drought events. If the current water management practices remain unchanging, it is most probable that unique endangered species will extinct. Final Report (Technical issue) – LIFE05 ENV/GR/000245 40/313 Environmental Friendly Technologies for Rural Development In the following, a number of actions are proposed to be applied in the framework of the Evrotas River Basin Management Plan to reduce adverse effects in the river system: Reduction of water abstractions A scenario focusing on reducing the irrigation water use by 40% is proposed. The implementation of that measure will improve the hydrological balance of the basin (Fig. 5.3.5). The surface and subsurface runoff in summer will increase from 2.9 to 6.5 m3/s (increase by 2.25 times). This would have positive effects on the conservation of aquatic and riparian ecosystems and would diminish river bank erosion. The proposed scenario is feasible through the improvement of the irrigation systems (installation of closed pipes) and the implementation of best agricultural practices (drip irrigation, development of irrigation systems according to the water needs of plants and the soil moisture), restructuring of agriculture, etc. Minimisation of morphological modifications It is essential to strictly forbid any extension of agricultural land towards the river courses and to apply integrated and sustainable flood control measures in order to minimise river bed scouring. The survival of aquatic biota and especially of fish during summer drought directly depends on the existence of deep remaining ponds that act as refuges, and over and above on the connectivity between aquatic habitats. Hence, morphological alterations should be minimised. It is additionally recommended that Environmental Impact Assessment Studies affecting river morphology should take into account the opinion of experts. Moreover, it is of first priority to protect and restore riparian vegetation. Figure 5.3.5. Monthly surface and subsurface runoff according to the current hydrological balance and according to a 40% irrigation water reduction scenario. Final Report (Technical issue) – LIFE05 ENV/GR/000245 41/313 Environmental Friendly Technologies for Rural Development Up-to-date flood control measures Current flood control measures are implemented in the plain areas with doubtful results and have dramatic effects on aquatic and riparian habitats. The implementation of flood control measures on the mountainous and semi-mountainous part of the basin, with afforestations, construction of small reservoirs and inhibitory weirs, artificial groundwater recharge and conservation/remediation of riparian vegetation in the riparian zones, should be the first priority. The uncontrollable development on floodplains significantly affects the extend and spatial display of floods. It is hence recommended to designate flood protection zones, where specific activities will be prohibited and may hinder floods to proceed downstream. Protection and conservation of fish fauna In the first instance, it is proposed that a perennial flow regime will be maintained, at least in certain areas which are of vital importance for fish conservation and management. We identified four areas of conservation priority, all of which include reaches fed by important springs: the Vivari and the Skoura areas, the Evrotas segment upstream the confluence of Kolliniotiko stream, and the Oinous midway. We recommend that these areas should be included in a management plan and be protected from surface water abstraction, while groundwater abstraction should be carefully regulated and should be designated as core areas for fish conservation. Bearing in mind that the fish fauna of the Evrotas contains unique range-restricted endemics, it is proposed that the local fish communities should be monitored on a regular basis to ensure that any impacts from human activities or water management measures are detected as early as possible. Special consideration must be given to the evaluation of the population status and trends during drought periods, when the frequency of sampling should increase. A monitoring programme designed to provide assessment of the chemical and ecological status of the Evrotas river is to be established, in accordance with the demands of the Water Framework Directive. With slight modifications and expansions, this programme can well accommodate the needs of fish conservation so that to provide on routine basis information on the status of fish populations and assessments of the human impacts on the ecosystem. Finally, it is important that a study will be undertaken to examine the minimum flow requirements in the area of the scheduled construction of in the Oinous R. dam, and this study will take into account the results of the present study. The implementation of the proposed actions will be only possible in the framework of an Integrated Management Plan of Evrotas River Basin. The development and continuous update of such a Plan will serve as the basis for water resources management, protection and conservation of the ecosystem both during ―normal‖ hydrological years as well as when extreme climatic events occur. Final Report (Technical issue) – LIFE05 ENV/GR/000245 42/313 Environmental Friendly Technologies for Rural Development 5.4 TASK 3 - Drainage canal and river bank management 5.4.1. Management of Drainage Canals Nitrogen (N) and Phosphorus (P) inputs are essential for increasing agricultural production and maintaining the economic viability of farming systems worldwide. Increases in worldwide use of N fertilizers combined with average N use efficiencies of 50% have contributed to increase of N concentration of surface waters. Fertilized farmland is frequently the main non-point source of nitrogen and phosphorus excess input to surface and groundwater ecosystems. A number of approaches have been identified to reduce nutrient (nitrate) losses to surface waters including controlled drainage, diverting or directing drainage discharge through natural or constructed wetlands, bioreactors-zones that surround or border the drain pipes and in stream denitrification Agricultural drainage canals have been used in poorly drained agricultural landscapes for regulating water retention to allow for crop production and for mitigating pollution (nutrients, pesticides and herbicides) as well as for erosion prevention. Drainage canals provide habitat to both aquatic and terrestrial biota and operate as nutrient pool due to decomposition of OM (lacking otherwise in dry and intensively managed agricultural areas). Drainage canals, usually situated in river deltas, which are areas of accumulation of organic debris (sediment deposition) and growth of macrophytes, such as Phragmites australis (common reeds) and Arundo donax (giant reeds). Such areas provide the suitable anaerobic conditions and electron donors for denitrification. In addition, plants (like reeds) can also promote phosphorus absorption onto the sand and prevent ammonia accumulation by the release of oxygen from the roots. The removal of N in riparian wetlands, zones, strips and drainage canals is mainly attributed to denitrification. Therefore, drainage canals are likely to act both as narrow buffers in filtering runoff waters and phosphorus pools during the dormant stage. Although, ditch performance has been shown to be highly variable, no holistic studies are available on the functioning of small field drains, with or without permanent water. Hydrologic Balance - Based on hydraulic conductivity (0.691 m/day for groundwater, and 0.587 m/day for Drainage canal recharge) and hydraulic gradients established by the piezometric heads of the water table, the velocity of ground water was determined to be 0.062 m/day (travel time, 16 d/m) and close to drainage canal-where the gradient is steeper-was 0.354 m/day (travel time, 3 d/m). The infiltration rate under steady state of moisture was estimated using Horton‘s equation to be 0.0135 cm/min and the constant K was 0.125±0.003 cm/min. Average potential evapotranspiration was 899±547 mm, and precipitation was 543±199 for the hydrologic years 2000-01 to 2006-07. Precipitation during 2006-2007 was 425 mm, while for 2007-2008 (until 31/05/2008) was 492 mm, indicating dry conditions. The estimated average potential water deficit for the studied region was estimated from April to October. Surface runoff to the drainage canal was estimated to take place only during precipitation events higher than 25 mm/day. Surface and ground water chemistry monitoring - Groundwater of the orange grove field was anoxic with high COD, phenols, DOC and DON and ammonia and seasonally with nitrates (Figure 5.4.1). The high organic load is due to the type of soil which is tyrf. Final Report (Technical issue) – LIFE05 ENV/GR/000245 43/313 Environmental Friendly Technologies for Rural Development The drainage canal had significantly lower concentrations of ammonia, COD, and DOC. Nitrate concentrations in drainage canal were less than in ground water with the exception when there was significant contribution from surface runoff. There was generally a consistent decrease of pollutants between ground water and drainage canal suggesting natural attenuation mechanisms in action. Organic N was ranging on average (sampling sessions) from 34% to 84% of total N for ground water. The average ratio of DOC to DON in ground water was relatively low ranging from 3.6 to 33.8 with a total average of 15, suggesting abundance of organic N. The molar DIN/DIP ratio for ground water was highly variable ranging on average (sampling sessions) from 10 to 288, with an average of 58 whereas for drainage canal ranged from 6 to 849 suggesting P limitation to eutrophication. The drainage canal phosphate concentrations were also highly variable, ranging from 9 μg/L to 399 μg/L, and exceeded the eutrophication criteria for lakes (20 μg/L). Drainage canal was oligotrophic due to reeds P uptake and once the reeds were cut (December 2006) it became successively mesotrophic to eutrophic. Sediment physicochemical characteristics - The results of the physicochemical characterization of the sediment are presented in table 5.4.3. pH of the sediment was slightly basic (7.64), while conductivity was not high (218 mS/cm). Dry bulk density was estimated to be 1125 kg/m3. The texture of the sediment was silty. Total organic carbon content was 11434 mg/kg whereas total kjeldahl nitrogen (TKN) was 1886 mg/kg and the total phosphorous is 3124 mg/kg. Therefore, the organic matter was enriched in nitrogen and phosphorus and the C/N ratio was 6. The chemical analysis indicated that sediments contained mostly aluminium (15.5 %) and silicon (54.8 %) oxides, while the high percentage of loss of ignition implied high content of organic matter. The sediment samples contained significant amounts of exchangeable nitrogen content, 4.65±0.36 mg NH3-N/kg sediment, 17.79±8.39 mg NO3-N/kg sediment, and 56.53±7.18 mg DON/kg sediment. Short term PMN and PTSN was also significant, 15.21 and 73.73 mg N/kg sediment, respectively. Anaerobic conditions prevented nitrification during the experiment. Mineralization rate, estimated by the leaching kinetic experiment, was found to be 0.21 mg N/L d, and therefore total capacity (adjusted for 7 days) was 10 mg N/Kg sediment, verifying the short term PMN values. Partitioning coefficient (kd), mL/g, for EMN, and PMN, was 400 and 600 mL/g, correspondingly, while for DON was much lower 200 mL/g, indicating the trend of the sediment to release DON. The sediment released 80 mg DON/Kg sediment. The aromaticity estimated in the leachate of the PMN test (ArIDOC, 1.169±0.052 L/mg C m, ArI DON, 280, 3.076±0.431 L/mg N m) compared with aromaticity observed in a range of Greek agricultural soils could be considered to be of the low-medium class explaining the enhanced mineralization response of the sediment. NO3-N concentration decline, observed in the kinetic experiment, could be attributed in denitrification since dissolved oxygen was negligible and redox potential was below 100 mV. Finally, the redox potential (Eh) of the sediment reached values lower than -50 mV in 200 h, suggesting potential for denitrification under anaerobic conditions and available electron donors. The sediment also released small quantities of phosphates (0.465±0.265 mg/kg PO4-P) as it was indicated from the leaching experiment. On the other hand, it had a large capacity to absorb phosphorous and no plateau was reached in the sorption experiment. Final Report (Technical issue) – LIFE05 ENV/GR/000245 44/313 Environmental Friendly Technologies for Rural Development This suggested that during the experiment (4 days) the equilibrium probably was not reached, but it was also an indication for possible surface precipitation. Therefore the experimental data couldn‘t be modelled by Freundlich, Langmuir or BET isotherm and the linear trend was obtained. The partitioning coefficient (Kd) was estimated to be 300 mL/g and the retardation factor 1092 or 1774 if instead of the estimated dry bulk density the typical value 2.65 g/cm3 was used. Equilibrium P concentration (EPC0) was estimated to be 0.08 mg/L. Figure 5.4.1. Seasonal averages from eight sampling sessions of physicochemical parameters of surface water and ground water underneath Drainage Canal at Skala. Phragmites australis and Arundo donax temporal nutrient content - During the monitoring period nutrient concentrations were higher in upper part and lower in lower part of above ground biomass, apart from certain periods of low concentrations, where concentration values among the three parts were relatively identical (15/2/2008 and 1/8/2008). Upper part (leaves) had higher N (and not P) content and N/P molar ratio compared to middle and lower part indicating the need of leave for N for chlorophyll formation. On the other hand, during growth periods where there was great need of P for the formation of new tissues the N/P ratio was decreased in the above ground biomass, and then remained relatively constant. The biomass was maximum soon after the maximum concentrations in June for P. australis (47 g/reed clone, 705 g/m2) and in late July for A. donax (204 g/reed clone, 3.1 kg/m2) (Figure 5.4.2) in accordance with other studies which also showed maximum reed biomass in early summer. Above ground biomass has been found to range from 97 g/m 2 (pristine nutrient substrate, translocation ecotype) to 1500 g/m2 (Rich nutrient substrate, assimilation ecotype) in August for P.australis. On the other hand, peak standing stock of nutrients was attained in June for both plants (A.donax: 432 mg P/shoot and 2023-2132 in July- mg N/shoot, P.australis: 151 mg P/shoot, 586 mg N/shoot) (Figure 5.4.3). Converting these contents to mg/g DW (Dry Weight), then P.australis exhibited 12.4 mg N/g DW and 3.2 mg P/g DW, while A.donax exhibited 18.4 mg N/g DW and 3.74 mg P/g DW. In literature, nutrient contents of P.australis observed during summer are 17.5-24.3 mg N/g DW and 1.3-3.14 mg P/g DW. Accounting for the reed density the square meter nutrient content is 8.78 g N/m2 and 2.26 g P/m2 regarding P.australis and 30.34 g N/m2 and 6.48 g P/m2 regarding Final Report (Technical issue) – LIFE05 ENV/GR/000245 45/313 Environmental Friendly Technologies for Rural Development A.donax, while in the literature the following ranges 17.8-35 g N/m2 and 0.96-3 g P/m2 have been observed. Phragnites Australis Arundo donax g of biomass/shoot g of biomass/shoot 250 200 150 100 50 90 80 70 60 50 40 30 20 10 0 0 May June Month July May September June July September Month (a) (b) Figure 5.4.2. Temporal variation of biomass of a) A.donax and b) P.australis from May to September. Nitrogen buffering processes - Drainage canals are areas of accumulation of organic matter (source of nutrients for microrganisms) due to erosion and growth of plants such as Phragmites australis and Arundo donax, that is important for nitrogen microbial processes (mineralization, nitrification, denitrification). In the drainage canal under study the substrate was tyrf and enriched in organic nitrogen. Groundwater exhibited high levels of DOC (approx. 14 mg/L) and DON (approx. 2.5 mg/L). Mineralization of organic nitrogen (15 mg/kg PMN, 0.21 mg/L d) was enhanced due to low aromaticity of DON which was released from the sediments. The reduction of groundwater DON flux passing through the riparian zone was an estimation of mineralized nitrogen for the study period and it was estimated to be on average 37.6 mg N/m2 (13.72 g/m2 year). Figure 5.4.3. Temporal variation of standing stock (S1) and b) P.australis (S2-S3) from May to September. of nutrients of a) A.donax Nitrification is an important aerobic process for the prevention of toxic ammonia accumulation. The process due the anaerobic substrate is strongly guaranteed on the oxygen release from the roots. The reduction of groundwater ammonia flux passing through the riparian zone indicated that the amount of nitrified nitrogen during the study Final Report (Technical issue) – LIFE05 ENV/GR/000245 46/313 Environmental Friendly Technologies for Rural Development period was on average 26.6 mg N/m2 day (9.72 g N/m2 year). Denitrification is the main processes responsible for the buffering capacity of drainage canals against diffuse nitrate pollution as described also by others. Denitrifers require, apart from electron donors, anaerobic and reductive conditions and such conditions observed in our case, since groundwater exhibited both low dissolved oxygen (mean value 1.6 mg/L) and redox potential (mean value 111mV, range: -182.5 mV έως +340.8 mV). Moreover, sediment redox potential under anoxic conditions was also low -50 mV. Hence, accounting that the microporosity environment would be even more anoxic, there was strong potential for dentitrification. The reduction of groundwater NO3-N flux passing through the riparian zone gave evidence that on average 56.1 mg N / m2 day (20.48 g N/m2 year) was denitrified. This nitrogen amount was removed from the system before entering the surface water. Phosphates buffering processes - Sediments showed a large capacity to absorb phosphorous. DIP concentration in groundwater was higher than the equilibrium concentration (EPC0 = 0.08 mg/L), therefore groundwater phosphate load was retained in sediments and the load entering the drainage canal was minimized. On the other hand, the levels of phosphorous in the drainage canal were seasonally below the EPC 0 making the process inactive. Thereafter, drainage canal buffering capacity concerning phosphates was not spent and higher phosphate loads could be absorbed. Root oxygen release was also important for adsorption as it enhances the oxidation of the soluble Fe +2 to the Fe+3 form that can be precipitated oxyhydroxides that bind phosphate. In this study PO4-P ranged from 0.009 (Method Detection Limit) to 0.437 mg/L, with DO from 0.45 to 5.00 mg/L and ORP from 140 to -215 (outlier -382). When the DO was higher than 3 mg/L the PO4-P ranged from 0.058 to 0.183 mg/L. However, there was no correlation of PO4-P concentrations higher than EPC0 with DO and ORP. Thus, we could assume that the redox potential enhances denitrification and not iron (Fe+3) reduction. Management issues of reed biomass - Harvesting of above ground biomass in June, when peak nutrient content of reeds was observed and N/P ratio of surface water was high enough to avoid toxic algal blooms, would remove 0.74 Kg P (2.73 g P/m 2) and 3.02 Kg N (11.2 g N/m2). Totally, 76.5 % of nitrate nitrogen (14.64 g N/m 2 year) and all phosphorus (1.39 g P/m2 year) entering the drainage canal would be removed by plant uptake. However, determination of the time of the management should take into account the effect of harvesting to re-growth and to ecological functioning of the habitat. Moreover, O2 supply to rhizomes depends on the redox potential of substrate and the water depth, and should be considered in the management plans. Harvesting either during the winter or the growing season has not been found to seriously affect re-growth of reeds and no clear differences have been found in total biomass production per unit area. Time of harvesting and ecological factors - Although, in general reed management has been found to have a significant negative impact on invertebrate community, a short term management (1-2 years) had no effect on invertebrates. On the other hand, reed harvesting and burning has been found to reduce abundance of passerine birds by about 60%, but this was probably associated with flood limitation as the numbers of butterflies, beetles and some spiders were reduced. Therefore, the optimal reed management regime to preserve number of birds and invertebrates in reedbeds could be indeed a rotation of Final Report (Technical issue) – LIFE05 ENV/GR/000245 47/313 Environmental Friendly Technologies for Rural Development short term management (1-2 years). Finally, the Hellenic Ornithological Society suggested that in alluvial Evrotas River plain reed harvesting is permitted from the 15th of June to the 30th of September (official communication with Hellenic Ornithological Society), excluding in this way the winter harvesting. Oxygen transport - The below ground parts of emergent macrophytes are dependent on oxygen transported from the shoots, since O2 is usually absent in the substrate. Oxygen is needed in these parts primarily for respiration and O 2 deficiency may limit the maximum water-depth penetration of emergent vegetation. Oxygen release from the roots of macrophytes to the surrounding substrate may have a positive influence on plant growth by oxidizing reduced, phytotoxic metabolites in the substrate (e.g. S 2-, Fe+2, Mn+2), promote phosphorus absorption onto the sand and prevent ammonia accumulation. P. Australis growing in a reducing substrate are more sensitive to a reduction in the O2 supply to rhizomes than reeds growing in a more oxidizing substrate. Conclusions - Sustainable agricultural practices have minimum environmental impact without imposing significant financial burdens on the farmers. Thus, understanding and implementing innovative technologies based on natural attenuation processes offers such advantages. The objective of this research was to elucidate removal of nutrients due to natural attenuation mechanisms in drainage canals in Evrotas River delta in Greece. We investigated nutrients balance in groundwater, sediments, and reeds (Phragmites australis and Arundo donax) of the drainage canal. Groundwater fluxes indicated that the rate of mineralization was 37.6 mg N/m2 day. The accumulation of toxic ammonia was prevented through the nitrification process (26.6 mg N/m2 d). The decrease of NO3-N flux in groundwater in the riparian zone, was calculated to be 56.1 mg N/m2 day (20.48 g N/m2 year). Phosphate was absorbed to sediments and its load to the drainage canal was minimized. Harvesting of above ground reed biomass in mid June, when maximum standing stock of nutrients was attained for both plants, would remove 2.73 g P/m2 and 11.2 g N/m2. 76.5 % of the nitrate nitrogen (14.64 g N/m2 year) and all the phosphorus (1.39 g P/m2 year) entering the drainage canal was removed by plants. This field and laboratory study revealed that the riparian zone of the agricultural drainage canal under study in the Evrotas River delta, natural attenuation mechanisms (denitrification and adsorption of phosphates), as well as phytoremediation (P. australis and A. donax nutrient uptake and harvesting of their above ground biomass), could remove significant amounts of N and P. The harvesting of above ground biomass of reeds (P.australis and A.donax) is suggested to take place in mid June when maximum standing stock of nutrients was attained for both plants P.australis and A.donax. Overall, drainage canal management is suggested as an efficient low cost – high gain agri-environmental measure, which is easy to be adapted by farmers, to reduce diffuse nutrient pollution. 5.4.2. Riparian Zone Restoration Temporary rivers are flashy in nature and under extreme precipitation events produce floods with extremely high erosion potential. An example of the flood destruction is a site in the area of Sparta where the river bank erosion control and phytoremediation was Final Report (Technical issue) – LIFE05 ENV/GR/000245 48/313 Environmental Friendly Technologies for Rural Development demonstrated. At the site, we designed and constructed a bank restoration system using large stones following the rivers curvatures to stabilize the bank and the riparian zone from future flood events. The bank erosion was therefore restored using a stone hedge of large boulders. In addition, we planted a riparian forest of 200 poplar trees to decrease nutrient loads due to uptake and enhanced denitrification. In this way, phytoremediation in conjunction with river bank erosion controls was demonstrated as a combined remediation tool for non-point source pollution of nutrients. To monitor the temporal 3dimensional variability of hydrology and chemistry of ground water, nine multi-level wells were installed. Groundwater sampling was conducted in order to assess the fate and transport of nutrients as they move from the groundwater to the River. The groundwater movement is almost paraller with the river flow. The average hydraulic conductivity was estimated to be 0.01 cm/sec. The infiltration rate under steady state of moisture was estimated using Horton‘s equation to be 0.0596 cm/min. Ground water chemistry monitoring gave the following findings: 1. The ground water presented low levels of dissolved oxygen. The samples from the 5m probes were colored (black) and smelled. 2. The ground water presented high levels of COD, which increased with depth, Τ.phenols, DOC, DON and NH3-N and seasonally of NO3-N and PO4-P. 3. The organic N was as significant as the inorganic N and was estimated to be approximately 60% of the total dissolved nitrogen. 4. Moreover the average DOC-to-DON ratio was relative low and ranged from 2.5 to 15, indicating abundance of organic N. 5. The molar DIN/DIP ratio for ground water was highly variable ranging on average (sampling sessions) from 30 to 350, suggesting P limitation to eutrophication. 6. There was generally a consistent decrease of pollutants in the restored riparian zone suggesting the role of phytoremediation and probably other natural attenuation mechanisms in action. Reduction of the pollutants at the restored Riparian Zone - The collected data from the monitoring of qround water quality allowed for the estimation of the nitrate reduction taking place at the riparian zone. As it was already mentioned denitrification was not expected to contribute significantly in the nitrate reduction due to the relative high dissolved oxygen and redox potential. Therefore the potential reduction would be attributed to the poplar trees uptake. The nitrate flux reduction was calculated for the 70 m length of the riparian zone for two equally divided parts (35 m). The water flow was calculated from the piezometric gradient between the wells (pairs of wells 3 andι 4, and 5 and 6), and then the difference between the concentrations resulted in the calculation of the flux. Totally, 8.2 kg ΝΟ3-Ν/y or 39 g ΝΟ3-Ν/m2y (for 3 m width of poplar trees) reduction of nitrates was estimated (70 % reduction). It is worth noting that the reduction the first period (until the July ‘07 sampling) was 60%, while the second period was 80%, coinciding with the further growth of the poplar trees and their root system. Moreover, accumulation of nitrogen ammonia was also observed which decreased in time, suggesting the contribution of the oxygen release from the trees‘ roots. The graphical depiction of the seasonal average concentrations of the pollutants in the wells Final Report (Technical issue) – LIFE05 ENV/GR/000245 49/313 Environmental Friendly Technologies for Rural Development before and after the poplar trees planted (Figure 5.4.4) indicates also the reduction of the ammonia accumulation after the July ‘07 and the enhancement of the nitrate reduction in the respective wells (after the trees). It is noticeable that nitrates presented during the six sampling sessions on average 81% higher, and 11.6, 18.9, 37.0, 49.4, and 32.7 lower concentration after the poplar trees planted zone. On the other hand the nitrate reduction in the 150 m filed from the irrigation well to the riparian zone (before the planted zone) was estimated to be only 8-25%. The nitrate flux reduction was calculated for the 70 m length of the riparian zone for two equally divided parts (35 m). The water flow was calculated from the piezometric gradient between the wells (pairs of wells 3 and 4, and 5 and 6), and then the difference between the concentrations resulted in the calculation of the flux. Totally, 8.2 kg ΝΟ3-Ν/y or 39 g ΝΟ3-Ν/m2y (for 3m width of poplar trees) reduction of nitrates was estimated (70% reduction). It is worth noting that the reduction the first period (until the July ‟07 sampling) was 60%, while the second period was 80%, coinciding with the further growth of the poplar trees and their root system. Moreover, accumulation of nitrogen ammonia was also observed which decreased in time, suggesting the contribution of the oxygen relese from the trees‘ roots. The graphical depiction of the sesaonal average concentrations of the pollutants in the wells before and after the poplar trees planted indicates also the reduction of the ammonia accumulation after the July ‘07 and the enhancement of the nitrate reduction in the respective wells (after the trees). It is noticable that nitrates presented during the six sampling sessions on average 81% higher, and 11.6, 18.9, 37.0, 49.4, and 32.7 lower concentration after the poplar trees planted zone. On the other hand the nitrate reduction in the 150 m filed from the irrigation well to the riparian zone (before the planted zone) was estimated to be only 8-25%. Consequently, phytoremediation in conjunction with river bank erosion controls is suggested as a combined efficient remediation tool, low cost – high gain, for non-point source pollution of nutrients. Final Report (Technical issue) – LIFE05 ENV/GR/000245 50/313 Environmental Friendly Technologies for Rural Development COD Concentration, mg/L 35 30 25 20 15 10 5 0 Mar-07 May-07 Concentration, mg/L Irrigation well Nov-07 Mar-08 May-08 after poplar trees planted NO2-N 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 0.000 Mar-07 May-07 Irrigation well Jul-07 Nov-07 before poplar trees planted Mar-08 May-08 after poplar trees planted NO3-N 3 Concentration, mg/L Jul-07 before poplar trees planted 2 2 1 1 0 Mar-07 Irrigation well May-07 Nov-07 Mar-08 May-08 after poplar trees planted NH3-N 0.70 Concentration, mg/L Jul-07 before poplar trees planted 0.60 0.50 0.40 0.30 0.20 0.10 0.00 Mar-07 Irrigation well May-07 Jul-07 Nov-07 before poplar trees planted Mar-08 May-08 after poplar trees planted Figure 5.4.4. Seasonal average concentrations of the pollutants in the irrigation well and the groundwater before and after the poplar trees planted. Final Report (Technical issue) – LIFE05 ENV/GR/000245 51/313 Environmental Friendly Technologies for Rural Development 5.5 TASK 4 - Agricultural product waste management The demonstration of agricultural waste treatment technologies was focused on the two most important point sources of pollution in Laconia, namely, olive mill effluents and wastewater from orange juice production. Two general technologies were used in four application sites: subsurface distribution of waste with phytoremediation and electrolytic treatment of wastes. The environmental impact of the olive oil production is very significant because of the very high COD content and the toxicity of some ingredients. The volume of the liquid effluents from the olive mill can be double or even quadruple the amount of olive oil produced, and there is a need to reuse or dispose large amounts of solids and liquid effluents in an environmentally acceptable manner. Whatever the type of the production plant (classical, two-phase or three-phase), about 1500 kg of by-products result from the production of 1000 kg of olive oil, either in the form of high humidity solids (2-phase process) or as vegetation water and medium humidity solids (classical and 3-phase processes). The disposal and treatment of this liquid waste are the main problem of the olive oil industry because of its high organic load and content of phytotoxic and antibacterial phenolic substances, which resist biological degradation. OMW has also a high potassium concentration and notable levels of nitrogen, phosphorus, calcium, magnesium, and iron, important factors in soil fertility. Lime precipitation and water evaporation in ponds constitute common practice in OME treatment. As part of EnviFriendly LIFE program, the following alternative treatment technologies have been implemented and their efficiency demonstrated. 5.5.1. Use of OMW for irrigation of crops during the summer months The basic idea behind this technology was to pre-treat the OMW with lime and pump the liquid to a nearby ―evaporation pond‖ for storage for the next 3 to 6 months. From the beginning of June the OMW was used for irrigation (after dilution with water) of a corn field. The overall results from the corn production have been very positive as well as all wastewater in the pond was used up before the end of the summer on an annual basis. The primary objective of the EnviFriendly program was to evaluate any potential problem with the aquifer under the corn field. The particular location where this technology was implemented was the olive mill ―P. TZINAKOS Ltd‖ in Aiges (Gytheio, Laconia). The irrigation facility consisted of a CaO pretreatment tank, evaporation lagoon, mixing with fresh water and finally land application in cultivated corn field. We investigated the soil physical and chemical properties for the identification of soil effects after 5 years of land application of CaO pretreated OMWW. The area was mainly comprised of Alluvial (quaternary) formations of conglomerates and loose sediments, of Tertiary formations mainly marls and phyllites and quarzites. The soil was characterized as alluvial mixed with regosols. The olive mill plant was a three phase olive mill and the OMWW management practice included liming of OMWW in tanks and then pumping the waste in lagoons during the olive oil production Final Report (Technical issue) – LIFE05 ENV/GR/000245 52/313 Environmental Friendly Technologies for Rural Development period (November to February). Evaporation lagoons accommodated the waste water up to May when the irrigation season commenced. From June to September waste water from the lagoons was mixed with fresh water to a ratio of 1/3 (OMWW/water) and was used for the irrigation of the maize field. The irrigation flow was 30 m3/h for 3 days a week. The surface area of the maize field was 18,750 m2 (1.8750 ha) which corresponded to 18,432 m3/ha/year (irrigation period for 4 months). Taking into account the dilution ratio (1/3), the total supply of OMWW was 6144 m 3/ha/4 months or a dose of 51.2 m3/ha/d for the irrigation period from June to September. Two experimental wells were constructed for groundwater monitoring to a depth of 10 m. The water table varied from 5 to 6.5 m seasonally (wet to dry period). Four topsoil samples (T1-T4) (0-15 cm) and an undisturbed core sample (C1-C3) were used for analysis, whereas, a control uncultivated topsoil sample (N) from an adjacent area covered with shrubs was used as reference soil. Sampling was conducted by obtaining 15 topsoil samples (0-15 cm depth) and three undisturbed soil cores C1-C3 (0-50 cm). Samples collected in November 2007 which was two months after the end of irrigation period (May-September) with treated OMWW. Six field campaigns (January 2007, March 2007, June 2008, August 2007, December 2007 and March 2008) were conducted for ground water sampling. Groundwater was sampled with a low flow peristaltic pump (< 1 L/min), so as turbidity was maintained at minimum levels and no atmospheric oxygen was introduced to the sample. The following physicochemical parameters: pH and temperature, electrical conductivity, dissolved oxygen, and redox potential were measured, in situ. The samples were filtered, in situ, through a 0.45 µm Nylon filter and analyzed for nitrates, nitrites, ammonia, phosphates, total phenols, dissolved organic carbon, chemical oxygen demand, and total nitrogen or Kheldalh nitrogen as well for cations like Ca, Mg, K. Dry bulk density was estimated to be 1698 ±70 Θg/m3 for cultivated soil (T1-T4) and 1612±62 Θg/m3 for control soil (N) whereas porosity was 38.5±2% and 35±2%, respectively. Infiltration was calculated to be 0.012 m/min in the treated soil. Topsoil organic carbon content decreased by 29%, and total kjeldahl nitrogen (TKN) decreased by 25% compared with the control uncultivated soil (N) (1.55 and 0.25% respectively). The lower organic matter content of the cultivated soil as well as the lime pretreated OMWW application was depicted in the higher pH (7.75) compared to control soil (N) (6.26). Electrical conductivity also increased by a 4.4 fold compared to that of control sample (N) (174 μS/cm). Magnesium availability decreased in the cultivated soil by 28 % compared to the control soil (N). On the other hand, calcium and potassium availability increased by 154 and 56 %, respectively. Finally, CEC increased by 86%. The bioavailability of phosphorous was extremely low (0.03 mg/Kg) in control soil, while it was high as 0.64 ± 0.2 mg/Kg in the cultivated soil. Exchangeable mineral nitrogen (EMN) was found to be 29% higher in the cultivated soil compared to the control (20 mg/kg) and was dominated by nitrate nitrogen in both soils (90% and 81% of EMN for cultivated and control soil, respectively). Potential mineralizable N (PMN) was estimated to be 22 and 29 mg/Kg for cultivated and control soil respectively. The dissolved organic nitrogen (7 day extraction) showed no significant changes for the cultivated soil (T1-T4) and the control soil (N) (Fig. 5.5.1). The total phenols were on average lower in the Final Report (Technical issue) – LIFE05 ENV/GR/000245 53/313 Environmental Friendly Technologies for Rural Development cultivated soil, and only T1 exhibited 20% higher content compared to the control. Finally, the dehydrogenase activity did not present any statistically important change. A spatial variability was observed mainly in the T1 composite with increases in the physicochemical parameters. K+, Ca, P-PO43-, N-NO3-, phenols and CEC increased for composite T1 (62%, 35%, 72%, 30% 66% and 18% respectively) compared to T3 and T4. T2 composite also presented some increase in N-NO3- and phenols compared to other composites (T3 and T4). 12.00 2a 10.00 mg/l 8.00 6.00 4.00 2.00 0.00 T1 T2 T3 Mineral N 3500 3000 T4 N PMN (7 days) Cu Cm Cd Cm Cd DON (7 days) 2b 2500 2000 1500 1000 500 0 T1 T2 T3 Kd Mineral N T4 PMN (7 days) N Cu Kd DON (7 days) Figure 5.5.1. Mineralizable Nitrogen (Mineral N=Ν-ΝΟ3- + Ν-ΝΖ4+) after 1 hour extraction with 2Μ KCl and Potential mineralizable nitrogen (PMN=Ν-ΝΟ3- + Ν-ΝΖ4+) and dissolved organic nitrogen (DON) after 7 days extraction with 2Μ KCl. 2b) Distribution coefficient Kd of mineral N, PMN and DON. The soil core samples Cu, Cm, and Cd showed similar pH values as the topsoil samples whereas the electrical conductivity was decreased in deeper horizons (by 48% in the Cd compared to Cu). TOC decreased with depth from Cu (1.0%) to Cd (0.7%). Total Kjeldahl nitrogen also decreased with depth from Cu (0.19%) to Cm (0.15%), while in the deeper horizon (Cd) presented an enrichment (34%) that can not be explained with the available data. Magnesium was relatively constant (4.57-4.93 g/kg) throughout the core depth, whereas potassium and phosphate content decreased with depth. It is worth noting that the availability of potassium and phosphorous of the Cm and Cd part of the soil core was similar to those of the control topsoil sample. Exchangeable mineral nitrogen (EMN) was estimated to be constant throughout the soil depth ranging from 18 Final Report (Technical issue) – LIFE05 ENV/GR/000245 54/313 Environmental Friendly Technologies for Rural Development to 20 mg/Kg. Potential mineralizable N (PMN) was constant between Cu and Cm (12.5 and 12 mg/Kg, respectively) and appeared to be negligible in the lower part of the core (Cd). DON (after 7 days extraction) was stable for all horizons. pH was alkaline (9.65) due to lime treatment. There was substantial decrease in COD (89 %), total phenols (90%) and TOC (48%) content. However, the electrical conductivity remained high and this was probably related to high potassium content. Nitrogen concentration in the treated OMWW was 1111 mg/L (54% DON, 30% N-NO3-, and 16% N-NH4+). The DOC/DON ratio was slightly higher than 20, indicating nitrogen as the limiting factor. Phosphate phosphorous concentration was 25.6 mg/L. The average physicochemical properties of groundwater are presented in Table 5.5.3. No significant spatial variability was observed between wells A1 and A2. The groundwater had high electrical conductivity, neutral pH, low nutrient concentrations and DO and reducing conditions. In general, no adverse effects were observed in ground water due to the surface application of the OMWW. However attention should be drawn to the electrical conductivity which could be related to potassium leaching from OMWW application and/or to geogenic factors due to interaction of groundwater with marls (rich in calcium) and phyllites (rich in potassium) from the soil parent material. Several publications referred to pH decreases in soil after irrigation with untreated OMWW which was however attributed to soil buffering capacity. Time dependent experiments showed initial decrease in pH and finally recovery to normal soil pH levels. In the present study the application of lime pre-treated OMWW lead to an increase of soil pH by 20% compared to that of the relatively acidic control soil. The pH change was related to the high alkalinity of the applied OMWW, (due to liming practice). The electrical conductivity increased in the amended soil (340% increase) and this was consistent with the scientific literature. Although, calcium concentration of OMWW is not as high as that of potassium, calcium availability showed even higher increase (154 %). The increase of calcium availability could be attributed to calcium oversaturation. After 5 years of OMWW application, organic carbon appeared lower in treated soil compared to the control soil (29% decrease). This was attributed to intense cultivation of the field for more than 10 years. Moreover, the OMWW application has not enriched the soil in organic carbon. This in accordance with the results presented by others who showed decrease of organic carbon and return to initial values after the OMWW application dose of 100 m3/ha and incubation time of 28 and/or 42 days. Moreover the same researcher showed that dehydrogenase activity was recovered to initial values after 28 days. Dehydrogenase activity was also estimated to be statistically the same between the cultivated and control soil. The fact that soil sampling took place in November, 2 months after the end of irrigation period with pre-treated OMWW, allowed the assumption to be drawn that decomposition bacteria probably had favourable conditions (OMWW had low COD and low phenolic content compared to untreated OMWW -Table 5.5.2) and enough time to act. In adittion, Mekki et al. (2006) presented increase in the colony forming units (CFU) for fungi populations, actinomycetes and spore forming bacteria (organic matter break down bacteria) and that was probably our case considering also the enhanced effect of maize root system in developing fungi populations and thus eased organic matter decomposition (e.g. mycorrhizal) (Tisdale et al., 1993). Consequently, decomposition of organic matter proceeded in satisfactory rate Final Report (Technical issue) – LIFE05 ENV/GR/000245 55/313 Environmental Friendly Technologies for Rural Development approximately 2 months after the end of OMWW application and no residual organic matter observed in soil after 5 years of practise. We expected high N concentration in soil after the application of OMWW due to mineralization of organic N. Our case revealed slightly higher N in soil and lower PMN which was probably related with the decomposition of organic nitrogen and transformation to leachable and absorbable mineral. In our case probably nitrification and/or denitrification processes were started after the end of irrigation with OMWW. The presence of maize had also contributed to the mineralization and nitrification of organic N with the development of bacteria in the vicinity of plant root. In addition, tillage after the crop period probably enhanced mineralization and nitrification processes. C/N ratio in treated soil was in average 3.1 whereas in control soil was 6.2 which exhibited satisfactory decomposition for treated soil. Furthermore, C/N for treated OMWW was 21 which meant that mineralization and nitrification processes were near to starting boundary value (<20). The supply of nitrates was attenuated probably by maize NO 3uptake and/or by denitrifying bacteria with concomitant release in the atmosphere. This was in accordance with the low values of nitrates observed through out the groundwater sampling campaign. Potential mineralizable nitrogen (PMN) had relevant concentration to all surface samples whereas PMN decreased for core samples as the depth increased and this was probably due to accumulation of organic matter deeper in soil which was more resistant in decomposition. This was also confirmed by the high PMN distribution coefficient of observed for Cd sample. Distribution coefficients for mineral N and DON for treated soil exhibited identical values which meant that organic matter decomposition proceeded and no residual effects observed. The content of nutrients in the upper 50 cm of N soil and treated soil (T1-T4) were also presented. The upper 50 cm of soil was considered for calculation of total nutrient load in soil since the majority of nutrients remained in this depth taking into account the hypothesis that nutrients infiltration rate was identical to water infiltration (0.012 cm/min, maximum ~50 cm-for 3 days constant irrigation). This hypothesis was true for the last year, since samples were taken November (high rainfall after December) and no significant rain could leach nutrients deeper in soil. In addition, return of most nutrients concentration into normal values (compared to N) for Cd sample (30-50 cm) enhanced this hypothesis. Comparison of nutrients increase in T1-T4 (Nutrient(T1-T4)-Nutrient(N)) with the OMWW nutrients input yielded the attenuation of nutrients which ranged from 55 to 100% according to the total input of nutrients in five years. Moreover, comparison with the last year nutrient input (2007) revealed the attenuation that occurred without the leaching effect of rain since the samples were obtained before the rain period in Greece as already mentioned (December-March). The last year attenuation in nutrient load was due to maize uptake. Potassium and calcium exhibited an increase of 55% and 175% respectively for treated soil (T1-T4) and attenuation of 82% and 40% for the last year load, respectively. Moreover, 97% and 92% was the attenuation for potassium and calcium respectively, after 5 years of OMWW application which showed that with increased application time we have increase in attenuation which was probably related with leached into deeper horizons and/or into groundwater (increased groundwater electrical conductivity). Magnesium deficiency was observed for the treated soil and probably that was related to ion exchange with potassium and leached deeper into soil. Final Report (Technical issue) – LIFE05 ENV/GR/000245 56/313 Environmental Friendly Technologies for Rural Development Significant amounts of potassium have been uptaken by maize (at least 45% from the last year nutrient input) due to high potassium requirements of the specific crop. Phosphates and phenols exhibited high attenuation in soil which was solely due to plant uptake and soil decomposition capacity. TKN showed 82% attenuation considering the five year of TKN input and increased load of +100% considering 1 year input. Thus treated soil contained residual organic matter with strongly bound nitrogen which yielded 23% increase for T1-T4. Leaching effect has not been observed since groundwater analysis exhibited no changes in nitrates and ammonium (decomposition products in anaerobic conditions of groundwater). Thus, there was an accumulation of organic matter which has higher content of nitrogen in treated soil and probably was decayed in very slow rate. Consequently, organic load (e.g. phenols) and nitrogen chemical species (nitrates and ammonium) have been effectively attenuated without impacting the groundwater, Irrigation with lime pre-treated and OMWW of a maize field for five years showed that the main soil effects included increase of electrical conductivity, correlated with increase of potassium and calcium availability in soil solution. Both pretreatment of OMWW and maize crop showed that enhanced the attenuation processes of organic load, phenols content, nitrates, and ammonium in soil. However, salinity was still far below threshold of salinization problem and probably application of limed OMWW in rotation with periods of non OMWW application could be an environmental convenient method of OMWW management in areas with water shortage or high irrigation demand and low organic matter and nutrient soil content (like phosphates). Groundwater quality remained untouched except electrical conductivity and this was correlated with both deep water level, slow infiltration rate and cultivation practises (cultivation of maize for potassium uptake, decomposition of organic load). 5.5.2. OMW subsurface disposal and phytoremediation Phytoremediation as a restoration technology is based on the use of vegetation for in situ treatment of contaminated soils, sediments, and water. It is applicable at sites containing organic contaminants, nutrients, or metal pollutants that can be accessed by the roots of plants and sequestered, degraded, immobilized, or metabolized in situ. As far as the subsurface disposal of OMW is it concerned, there are two technological approaches that can be followed: a) One is to have a confined soil disposal area with a protective membrane placed at least 5 m below the surface so that no wastewater leaks during the winter months to the groundwater. In addition through a series of perforated pipes and pumps, the ―stored OMW‖ disposed during the winter months is recycled vertically (during the spring/summer months) in order to enhance the phytoremediation action of poplar trees. In this process one can further enhance the remediation efficiency by adding isolated bacterial degraders (of OMW) from the rhizosphere of irrigated plants (for extended periods) with OMW (Oleico process/ recent Italian patent/LIFE Environment Project, http://www.lifeoleico.it). b) A second approach is to dispose the OMW in between densely planted poplar trees taking into account the soil properties so that the groundwater is not contaminated Final Report (Technical issue) – LIFE05 ENV/GR/000245 57/313 Environmental Friendly Technologies for Rural Development with disposed OMW and the cost is significantly reduced compared to the approach in (a) above (as no excavation and no continuous pumping is involved). Within EnviFriendly, we concentrate on the second approach. In general, the configuration of the plants in the chosen phytoremediation area is determined by a combination of factors like wastewater irrigation system and weed control methods, OMW disposal system etc. The site where this technology is implemented is the KOKKOLIS Olive Mill in Vassilaki, Laconia. In this case, the poplars were planted in rows with a spacing of about 1.2 to 1.5m betweens the plants and a spacing of about 3.2m between the rows. The two-year old poplars were planted in late November of 2006 and subsurface disposal was initiated in December of 2007. The OMW delivery system includes pumps and PVC pipes needed to transfer the OMW from the olive mill facility to the distribution system at the poplar site. The OMW is distributed in subsurface perforated pipes placed between the poplar rows. The distribution pipe is located approximately 40 cm below the surface and it is placed in an excavated channel with a cross-sectional area of 50 cm X 50 cm. The channel is filled with medium size gravel. The maximum quantity of OMW that can be disposed on a particular site should be less than the Specific Retention of the soil in the area. Specific Retention is the measure of the water retained in the soil against gravity by capillary and hydroscopic forces when the water table of an unconfined aquifer drops. In our case, it is actually the maximum volume of water and OMW that can be retained against gravity in a unit area of the investigated site. Therefore, for a plant with a root system that reaches 5 m deep, the objective is not to allow the OMW plume to go beyond this limit. This corresponds to a maximum volume of OMW retained in a volume V (m3) equal to 5m Area (m2). Based on our calculations, and the average rainfall in the area, the production of OMW by the KOKKOLIS olive mill which is about 1000 m3, can be accommodated by the area. The capacity of the poplar trees planted in the Phytoremediation area is quite high. Nonetheless, there is an additional area that it could be planted with poplar trees should the production of OMW by the plant increases substantially over the next few years. Six sampling wells constructed in the field. Three level loggers were placed in different depths (3, 4, and 5 m). Sampling campaigns were done to monitor the temporal 3dimensional variability of hydrology and chemistry of ground water, 6 multi-level (3, 4 and 5 m) wells were installed. Groundwater sampling was conducted in different periods prior and after the underground waste release. The field campaign dates were at 1/2007, 3/2007, 5/2007, 7/2007, 11/2007, 3/2008, 2/2009. The time period from 1/2007 to 11/2007 was prior the underground waste release, whereas field campaigns from 3/2008 to 2/2009 were done after the underground waste release. Ground water monitoring: The multilevel wells were sampled, with a peristaltic pump with low flow (< 1 L/min), so as turbidity was maintained in minimum levels, and the physicochemical parameters pH, temperature, conductivity, dissolved oxygen (D.O.), and, redox potential (Eh) were stable. The samples were filtered through a 0.45 µm Nylon filter, stored in low temperature and sent to laboratory. Water samples were analysed for the same parameters as in the previous applications Soil sampling: Core samples were collected in 2/2009, one year after the underground irrigation with waste water. Water samples were also collected in the same period. Final Report (Technical issue) – LIFE05 ENV/GR/000245 58/313 Environmental Friendly Technologies for Rural Development Sampling included 4 core samples in different depths below the irrigation pipe (0-20, 2040, 40-60, 60-80 cm). Figure 5.5.2 presents the mean values and standard deviation from 6 wells in the 4 m depth probe. After the underground disposal of OMWW, there was a decrease in the concentrations of nitrite, ammonia, TKN and phosphate while the nitrate and phenol concentration were statistical similar. The pH, dissolved oxygen (DO) and redox potential remained constant after the OMWW application, the electrical conductivity decreased. Soil samples were taken up to 80 cm below the irrigation pipe. In general, no changes were observed in pH and total organic carbon compared to the control soil (surface sample) apart from sample KE4 which showed decline in pH and increase in organic carbon content. Increase was also observed in the concentration of phenols. At 20-40 cm depth a great decrease was observed in phenol content whereas organic carbon was high for sample KE4 (Fig. 5.5.3 and 5.5.4). P-PO4 N-NO2 0.25 0.20 0.025 0.020 0.015 0.010 0.005 0.000 N-NO2 mg/L mg/L 0.035 0.030 P-PO4 0.15 0.10 0.05 0.00 March 07 March 07 March 08 N-NO3 Total phenols 2.00 5.00 4.00 N-NO3 mg/L mg/L 1.50 1.00 0.50 Total phenols 3.00 2.00 1.00 0.00 March 07 0.00 March 08 March 07 N-NΗ3 March 08 TKN 1.00 5.00 0.80 4.00 N-NΗ3 0.60 mg/L mg/L March 08 0.40 0.20 TKN 3.00 2.00 1.00 0.00 0.00 March 07 March 08 March 07 March 08 Figure 5.5.2. Nutrients concentration in wells of 4 m in two different time periods. The subsurface application of OMWW showed no adverse effect to groundwater quality. Stabilization of nutrient concentration after the planting the poplar trees, showed that biological action of the plants decreased the variability in nutrient content. The groundwater water level in the field was on average 2.5 m (winter) to 3 m (summer) below the surface. Soil coring showed no transfer of waste in deeper horizons (below 60-80 cm) thus there are no adverse effects in groundwater from waste application. Phenols showed no variability in concentration after the subsurface Final Report (Technical issue) – LIFE05 ENV/GR/000245 59/313 Environmental Friendly Technologies for Rural Development application of waste water which was probably related with adsorption in soil and concomitant degradation of phenols. The rhizosphere of the poplar trees was a crucial factor for the degradation of phenols. Low pH and high organic load in core KE4 showed high spillage of the wastewater in that place. The phenol content was high in depth 0-20 cm whereas it decreases in deeper horizons which had similar phenol content to undisturbed soils (36 mg/Kg, Tsinakos field). The control soil also exhibited similar values to Tsinakos field. The subsurface application of OMWW in conjunction with phytoremediation was shown to be an effective low cost technology. Irrigation pipe wastewater Depth cm 0-20 20-40 40-60 60-80 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Total phenols (mg/Kg) Figure 5.5.3. Total phenols in different depths in sample ΘΔ4. Figure 5.5.4. Total phenols in different depths for samples ΘΔ4 and ΘΔ3 and the control soil. 5.5.3. Electrolytic treatment of OMW. One of the alternative methods for OMW partial treatment is the use of advanced oxidation processes for the complete oxidation of the phytotoxic polyphenols present in the OMW as well as for the simulataneous reduction of COD through oxidation and the removal of coagulated particles of high COD. The advanced oxidation process used in this application is electrolysis. OMW is often disposed in Evrotas riven without any prior pretreatment to remove at least the content of polyphenols. Electrolytic treatment of OMW for a short period is expected to reduce substantially the polyphenols concentration and at the same time achieve a noticeable reduction in the COD of the OMW prior to disposal. Final Report (Technical issue) – LIFE05 ENV/GR/000245 60/313 Environmental Friendly Technologies for Rural Development As part of the LIFE EnviFriendly program, an electrolytic treatment unit was installed at the ―Ν & Α TOUTOULIS‖ Olive Mill in Platana (Laconia) with the following characteristics: (5) Electrolytic Cell (Anode: Ti/Pt/Ir with a total surface area of 160 cm 2, Cathode: stainless steel 316 (tubo) with an internal diameter of 70 cm; The complete electrolytic unit was manufactured by WATERSAFE S.A., Greece). (6) DC Power supply (WATERSAFE S.A., rated at 700 A @ 20 Vdc). (7) Recirculation pump (Lowara, stainless steel 316, with a flow of 30 m 3/h @ 4m). (8) Stirring vessels (PVC with a volume of 0.5, 0.5 and 1 m3). Following one season of unsuccessful operation due to complete unwillingness of the olive mill owner to follow the operating instructions, it was decided to change the location of the electrolytic unit to another place in Laconia, where the wastewater is from the production of table olives (EUROAMERICANA S.A.). The electrolytic system was also tested in parallel in our laboratories in order to ensure that the best operating conditions have been chosen for the particular application. OMW, diluted 1 to 20 with water and following addition of 4% (w/v) NaCl (4 g/cm 3), was subjected to electrolytic treatment employing three different voltages: 5 V, 7V and 9V. The recirculation flow through the electrolytic cell was 0,62 L/s. The temperature was kept within the range 27-35 oC. The temperature and pH increase was the highest during the electrolysis with 9V. The gradual increase of pH can be explained by the fact that throughout the electrolysis more OH- ions are generated than H+, with the results the gradual move towards more alkaline conditions. The value of pH does not affect the production of Cl2 and the overall efficiency of the process (for an initial pH in the range 4 to 10) and hance no pH control was implemented. The drop of COD as a function of time is given in the diagram below (Fig. 5.5.5). It is obvious that the rate of COD reduction is higher as the voltage increases. We observe an initial increase of COD for 5 and 7 V before the continuous reduction of COD with time commences. This is probably due to production of intermediates (chlorinated compounds or polymerized compounfd). The production of polymerized compounds is fovoured at a low pH and temperature leading to an increase in COD. The reduction of COD after 2 hours of treatment was 35,5 % at 9V, 24% at 7 V and just 3,4% at 5V. The COD reduction is directly linked to the current density which was: 7.77 A/dm2 at 5 V, 19.26 A/dm2 at 7 V and 31.54 A/dm2 at 9 V. The average COD reduction is 188 mg O2/Ah at 9 V, 200 mg O2/Ah at 7 V and 80 mg O2/Ah at 5 V. The the same amount of applied charge, the COD reduction is higher at higher voltages. The phenolic compounds are degraded totally within 15 min at 9V, 20 min at 7V and 40 min at 5V. The results of the electrolytic treatment are shown together for polypohenols and COD reduction in the following diagram. At an operating voltage of 9V, when the polyphenols are totally removed, the corresponding COD reduction is 14% (Fig. 5.5.6). Final Report (Technical issue) – LIFE05 ENV/GR/000245 61/313 Environmental Friendly Technologies for Rural Development Dilution 1:20, 4% NaCl 2700 2400 COD (mg/L) 2100 1800 1500 1200 0 50 5V 100 Time (min) 7V 150 9V Figure 5.5.5. Changes in COD versus time for different operating voltages. 2400 Dilution 1:20, 4% NaCl 2,0 Polyphenols (g caffeic/ L) Dilution 1:20, 4% NaCl 2700 1,6 COD (mg/L) 2100 1,2 1800 0,8 1500 0,4 1200 0,0 0,00 1,00 2,00per 3,00 4,00 (Ah/L) 5,00 Charge unit volume 5V 7V 9V 0 20 5V 40 Time (min) 7V 60 9V Figure 5.5.6. COD reduction as a function of the applied charge and times at different operating voltages. All the prevous experiments have been conducted with filtered OMW where all suspended solids have been removed. In order to examine the effectiveness of the unit in a real situation where the Olive Mill Owner neglects to remove the solids, two sets of experiments were conducted one with filtered OMW and the other without any filtering prior to the electrolytic treatment. As expected the initial COD is much higher compared to the filtered one. After 2 hours of electrolysis, the COD of the non-filtered OMW was reduced from 6545 mg/L to 5080 mg/L and for the filtered OMW, COD was reduced from 2310 mg/L to 1490 mg/L. For the filtered OMW, the polyphenols (1.52 g/L) are removed within 30 min. During the same period, the polyphenols drop from 2.85 g/L to 0.82 g/L. The presence of solids does not affect the phenol reduction rate as the two curves are practically parallel. The decolourization of the OMW corresponds to the degradation of high molecular weight compounds with mineralization of the low molecular weight aromatic compounds. The polymerized aromatic compounds are responsible for the dark colour. Complete decolorization coincides with the removal of the polyphenols. The colour is removed faster at higher operating voltages and higher NaCl concentrations.The time for decolorization varies from 10 min to 1 hour depending on the conditions. As seen in Fig. 5.5.7, the effect of solids is very strong on decolorization. Their presence results in a temporary increase in colour. We observe an increase in the rate of decolorization with increasing voltage and NaCl concentration. At higher OMW concentration we observe an initial increase in colour due to temporary polymerization of the polyphenols. Final Report (Technical issue) – LIFE05 ENV/GR/000245 62/313 Environmental Friendly Technologies for Rural Development Based on the above experiments we can readilty conclude that OMW pretreatment for the removal of the suspended solids is essential for a succeful and efficient decolorization and ployphenol removal. From the previous experiments we arrive at two important conclusions: Decolorization and removal of polyphenols takes place in a very short period of time if we have removed all suspended solids from the OMW. The effectiveness and efficiency of the electrolytic system increases substantially as the concentration of NaCl increases. The above findings coupled with the unwillingness of the TOUTOULIS Olive Mill ownwers to do any pretreatment whatsoever, lead us to the decision to transfer the electrolytic unit from their premises to another location in Laconia. It was decided to move the unit to the industrial unit for the production and packaging of table olives, EUROAMERICANA S.A., for the treatment of their wastewater. This choice was made since the wastewater of table olives is already rich in NaCl and the unit is expected to work much better. Indeed, in May 2009 the unit was put in operation at EUROAMERICANA S.A., and the first results were very encouraging. Table olive processing occurs through a series of steps, namely initial olive cleaning, debittering, washing, fermentation and packing. Table olives wastewater is similar to olive mill wastewater, however, it is not as strong in terms of COD and suspended solids and it has in addition sodium chloride, calcium chloride and lactic acid. As a result this wastewater has a high conductivity (about 100 mS/cm) and a pH of about 4.5. Since the amount of salt added for processing is quite high (about 10 kg salt per 120 kg of kalamata olives) EUROAMERICANA S.A. has instituted a brine recycle scheme to reduce the cost of salt usage and to reduce the amount of wastewater. EUROAMERICANA S.A. has final disposal vessels (septic tanks) to keep their effluents prior to final disposal. The electrolytic unit was installed prior to the disposal tanks whereby the effluents are pumped from a small flow equilibration tank to the electrolytic cell vessel where they are oxidized and overflow into the final disposal tanks. The overflowing stream is where the electrolytically-treated effluents can be sampled to test the efficacy of the installed unit. During the month of May (2009) the facility was mostly packing the olives and hence, the generated wastewater was not very strong in terms of COD. Nonetheless, the installed electrolytic unit was able to fully remove the dark color from the effluents. A couple of samples were tested for COD removal which was of the order of 50%, however, the initial COD load was quite low (of the order of 1.5 g/L). The unit is expected to work satisfactorily as we have conducted independent experiments in the Technical University of Crete where it was shown that electrolytic treatment of table olives wastewater can achieve complete decolorization, remove more that 50% of initial COD (a load of about 5 g/L) and essentially achieve complete removal (98%) of polyphenols. Final Report (Technical issue) – LIFE05 ENV/GR/000245 63/313 Environmental Friendly Technologies for Rural Development Figure 5.5.7. Change of color with time after treatment. 5.5.4. Prototype unit for treatment of Orange Juice wastewater The Lakonia Orange Juice Plant produces large amounts of orange juice and although it has a complete biological wastewater treatment facility already in place, significant problem in the effluents are observed particularly during the period of peak production. We investigated possible improvements in the treatment and arrived at a few changes in the current operation of the facility. We installed an electrolytic pretreatment unit. The unit is placed in the outlet of the dissolved air flotation (DAF) unit and prior to the biological treatment. The location of the unit is expected to aid by partially oxidizing the wastewater and making more easily degraded by the microorganisms. Excluding the mixing vessel, the rest of the equipment is placed on four wheels to make it easily transportable to another location in the plant. The installed electrolytic unit was evaluated for its capability to aid the overall operation (lower COD in the effluent stream) and decolourization of the final effluents. Existing situation - As a first step the overall wastewater treatment facility was examined and our findings were communicated to the Director of the plant. The general observation is that the system does not work satisfactorily during periods of peak production. By examing the existing units, we were able to pinpoint the problem. The wastewater reached first the flow equalization vessel and then proceeds to the Dissolved Air Flotation (DAF) unit where the solids (i.e., the natural fibers of the orange fruit) are removed. The efficiency of this unit is very important as ceculose is difficult to biodegrade. In the figure 5.5.8 the fibers are shown in the equillization vessel. Subsequently the wastewater is pumped to the DAF where the fibers are removed with the addition of coagulants. Final Report (Technical issue) – LIFE05 ENV/GR/000245 Addition of coagulants Effluent from the D.A.F. Flotation and removal of solids 64/313 Environmental Friendly Technologies for Rural Development Figure 5.5.8. Typical setup of the facility. The DAF works satisfactorily as the effluent does not contain at least visible fibers. The flocculated natural fibers are then taken to the dewatering unit where most of them are removed from the system; however, a large amount of smaller fibers is returned to the pumping station and directed to the biological treatment units (Fig. 5.5.9). The presence of the fibers is evident form the yellow color of the feed taken from the pumping station to the biological treatment unit. Given the above findings it was decided to follow two alternatives taking into consideration the fact that the plant was not in a position to change the dewater unit. 1st Alternative: Electrolytic Pretreatment of the wastewater - We proceeded with the installation of an electrolytic unit with the primary goal to oxidize in part the returning solids in the pumping station prior to their transfer to the biological treatment unit. The effectiveness of this approach was very difficult to evaluate on the site because of the variations in the federate and the long residence time of the wastewater in the biological treatment unit. As a result, we examined the efficiency of the unit with independent experiments in our laboratory using the same wastewater. 2nd Alternative: Decolorixation of final effluent - The goal here was to evaluate the electrolytic decolourization of the final effluent regardless of the overall treatment efficiency of the existing facility. This was done with independent experiments in our lab and in the field. Based on our findings a complete unit was designed for the decolorizationof the effluent at all times and was given to the plant Director. From D.A.F. (without fibers) Final Report (Technical issue) – LIFE05 ENV/GR/000245 From dewatering unit (fibers are present) 65/313 Environmental Friendly Technologies for Rural Development Figure 5.5.9. Pumping station (flow from DAF and dewatering unit). The graduate student involved in this project carried out a complete experimental design where many operating variables were examined. It is noted that the COD of the inlet wastewater to the biological treatment unit was higher than 10.000 mg/L whereas the final effluent was always less than 1.000 mg/L. In both cases the yellow colour was always there. Three different operating voltages were examined: 10, 20 και 40A. The salinity was 4% NaCl and the temperature was kept contsnat at about 25 0C.. A small yet consident increase of the pH was observed in all experiments. The COD measurements have been adjusted for apparent increase due to the presence of salt. Decolourization is achieved within the first 5 min of electrolytic treatment. The colour measurement at 440nm is the most representative.Whereas we have seen a COD reduction of about 50% after 120 min, no reduction in TOC is observed. This means that we have addition of oxygen atoms in the organic compound but no mineralization The wastewater was treated at four different salinities: NaCl – 0.5, 1, 2 and 4%. The changes in the pH are minimal. The highest reduction is observed for the experiments at 2 & 1% NaCl. Decolourization takes place within 5 min for the experiments with 2 and 4% NaCl whereas 15 min are required for the experiments at 0,5 and 1% NaCl. The samples with 2 and 4% NaCl were decolourized by 96%, whereas the experiments with 0,5 and 1% NaCl were only 30 and 56% decolorized (as measured at 440 nm). Based on the results the following recommendations were made 1. Change of the Dewatering Unit - The best solution, yet not the most economical, is the substitution of the existing dewatering unit with a new decanter of high effiency. This is the best solution for the long run. 2. Changing the existing piping – return from dewatering unit - The simplest approach is to change the location where the returned liwuids from the dewatering unit are returned. Instead of the pumping station, these should go to the flow equalization vessel and pass again from the DAF. As a result only the effluents from the DAF will be pumped to the biological unit. The only concerne is whether the quality of the separation in the DAF will fall if the flow is operated at a higher level. Final Report (Technical issue) – LIFE05 ENV/GR/000245 66/313 Environmental Friendly Technologies for Rural Development 3. Electrolytic Pretreatment - The electrolytic pretreatment resulted in a reduction of the overall COD however, no reduction was observed in the TOC. This suggests that oxygen atoms are insered in the organic compounds which makes them more easily biodegradable; however, no minerilzation of the wastewater was observed. 4. Decolourization - The electrolytic unit can be used independently for the decolourization of the final effluent. With residence times of the order of 5 min only, a satisfactory decolourization is achieved (>96%) where no yellow colour is visible. Recommendations 2 and 4 are readily implementable and the Director of the plant has accepted them. Final Report (Technical issue) – LIFE05 ENV/GR/000245 67/313 Environmental Friendly Technologies for Rural Development 5.6 TASK 5 - Integration of socio-economic aspects 5.6.1 Results of the fieldwork research Public Participation and Information The tasks of the NCSR research team within the framework of the LIFE project, included: the study of the social implications of the project interventions and the attainment of social consent and acceptance. The planning and implementation of a dissemination campaign to inform the public about the objectives and the results of the project. The NCSR research team elaborated a series of studies and fieldwork activities seeking to reveal and register the local peculiarities and problems (floods, fires), as well as the local dimension of specific environmental management issues (recycling). During the interim report, the NCSR team also implemented a series of information and sensitization actions (production and dissemination of printed and electronic material, organization of workshops and public events), mostly meetings and contacts with local stakeholders. Overall, the whole of the aforementioned activities set the basis for a long-term constructive public consultation process that evolved throughout the various research project phases (goal setting, opinion-registering, information about the project‘s actions and the foreseen implications, new meetings and new information events based on the latest data collected etc.). Thus, the NCSR team established a solid network of co-operation with the local stakeholders which resulted in spectacular partnerships (e.g. the creation of Open Farms with New Farmers Union, the Mapping Trails with the Sparta Hacking Association etc.). The co-operation with local stakeholders, such as the municipal authorities around Evrotas, the local agencies for land reclamation (TOEB) of these municipalities and the environmental education institutions of the wider area, was continuous. The overall objective of the aforementioned co-operation was the viability of the Network of Co-operation of Local Stake-Holders following the completion of the project. This Network will be based on the Observatory for Sustainable Development. Its operation will be the responsibility of the Prefecture of Laconia and its tasks will include the collection of information material regarding local development perspectives, the provision of information to and the collection of feedback from all stakeholders and citizens, the overall coordination of the development actions and the participation to the resolution of the emerging development problems. Brief summaries of these surveys and studies are presented below, offering a synopsis of the views and observations of the responsible (in each case) local actors and of a sample of the local population. Professionals - Residents Comparative presentation of the results of two surveys Following the completion of two surveys (initial and repetitive) the individual results have been correlated by the NCSR researchers. An overview of the comparison of these results is given below: Final Report (Technical issue) – LIFE05 ENV/GR/000245 68/313 Environmental Friendly Technologies for Rural Development 1. According to the initial survey, the Evrotas River is perceived primarily as a significant agricultural asset (55.00%) and secondarily as a source of natural wealth (31.00%). Only 14.00% of the respondents consider Evrotas as a historic and local cultural asset.Respectively, according to the repetitive survey, the Evrotas River is primarily perceived as a considerable agricultural asset (60.7%) and secondarily as a source of natural wealth (19.7%). Only 12.1% of the respondents perceive Evrotas as a historic and local cultural element. By comparison, the findings are similar and indicate a marked increase in the proportion of responses that positively value the contribution of Evrotas in the rural development especially as a supplier of water resources (44.4%). 2. Regarding the problems that Evrotas presents, respondents in the initial survey emphasized primarily the problem of pollution (total of relevant answers 65,00%) and secondarily the fact that most of the river‘s development potential remains unexploited (23.00%). A 12.00% percentage of the population referred to the problem of floods and draught. In the repetitive survey, 38.9% of the respondents stress the population problem while there is a marked increase in the percentage of respondents who consider draught and floods to be the primary problem generated by the Evrotas River (36.2%). This marked increase is attributed both to the damage caused by the relatively recent floods and particularly by the prolonged drought. The percentage of respondents that emphasized the unexploited development potential of the river (the irrational use of water resources) was about the same (22.2%). 3. With reference to the expectations generated by Evrotas, according to the results of the initial multiple-choice survey, the majority of respondents stressed the river‘s value as a clean and abundant source of water (72.2%) and a wetland of valuable flora and fauna (62.1%). Secondly, in the opinion of respondents, Evrotas could be used as a recreational area (22.7%) and serve as an incentive to attract tourists (19.5%). The findings of the repetitive survey are similar. Considering the future contribution of the Evrotas River in local development, 70.9% of respondents identified Evrotas‘ significance as a high-quality water resource (which contributes to the increase of agricultural production and the enhancement of quality of life), 16.2% of respondents referred to the rivers‘ use as a tourist attraction incentive, while 12.2% mentioned the use of Evrotas as a means to raise funding from Community and national resources. 4. According to the initial survey, respondents considered that the contribution of the LIFE / EnviFriendly project to the resolution of the Evrotas‘ management problems should primarily focus on the reduction of pollution (39.6%) and the elaboration of water resources and riparian land management plans (36.6%); and secondarily, on the best exploitation of the river (13.4%) and the management of seasonal floods (10.4%). According to the repetitive study, from the whole of the respondents who were familiar with the implementation of the LIFE / EnviFriendly project, 47.7% considered the project‘s main contribution to be the monitoring of pollution and of the pollution sources, while 15.4% most highly valued the quantitative and qualitative management of the water resources. Adding to the above percentages the percentage of respondents who emphasized the antiFinal Report (Technical issue) – LIFE05 ENV/GR/000245 69/313 Environmental Friendly Technologies for Rural Development pollution measures adopted for the Evrotas River (relevant categories) it is clear that the two major inputs of the projects consisted of the reduction of pollution and the wise water resources management. The above findings lead to the conclusion that both the initial content and objectives of the LIFE / EnviFriendly project and the implemented actions (elaboration of management proposals, dissemination – sensitization activities, local events and workshops etc.) evolved in accordance with the priorities and the expectations of the local professionals and residents. Subsequently, the NCSR research team argues that the goal of social acceptance of the proposed interventions has been largely achieved. Moreover, it is indicative that 16.9% of respondents have positively valued the contribution of the project to the mobilization of the relevant communication mechanisms and the provision of information to the local population regarding the prospects of sustainable local development. The basic conclusion of both the initial and (especially) the repetitive surveys is the promotion of the urgency of the Evrotas pollution problems and of the need for wise water resources management, and the realization by the vast majority of the local community of the fact that the aforementioned problems cannot be resolved without the adoption of relevant planning measures. This conclusion has been verified be the respondents‘ demand for the prioritization of pollution reduction and specialized water resources management plans in any future programming. Elected Officials – Representatives of the Municipalities around Evrotas Overview of the findings of the initial survey One of the most important, if not the most important, research findings is the fact that elected officials positively view their participation in practices that promote sustainable development (95%), particularly through institutional and communicative means. Moreover, a significant percentage (62.4%) of elected officials is familiar with the «integrated forms of agricultural production» and vastly supports the dissemination of information about them (76.5%). The aforementioned findings are indicative of the existence of a particularly fertile framework for the long-term exploitation of the project‘s results. The long-term implementation of the project foresees the establishment and operation of the Local Development Observatory. The positive inclination and the high degree of awareness of the elected officials will positively contribute to the success of the Observatory given that it will be housed in the prefecture and will be staffed by employees of the local authorities. As already mentioned, elected authorities have a primary role to play in the dissemination of information since they are themselves communication channels between the citizens and the project administrators. The dissemination of the relevant information can be realized through three different ways: Final Report (Technical issue) – LIFE05 ENV/GR/000245 70/313 Environmental Friendly Technologies for Rural Development a) First, through the information sources elaborated by the project: information workshops, website, environmental education, printed material, posters etc. b) Second, through the active participation of the elected authorities in the implementation of the project and the constant co-operation with the project managers; this is necessary for the two-way dissemination of information. The project seeks to produce a know-how totally adapted to the peculiarities and the needs of the local community. c) Finally, the elected local authorities can function as opinion leaders and disseminate information about the project, generate discussion over the achievement of the project‘s objectives and communicate expectations, ideas and solutions regarding the development perspectives of the region. One more remarkable finding is the fact that the majority of respondents perceive Evrotas as primarily contributing to the irrigation of the region and local agricultural development (39.8%). Simultaneously, respondents blame industrial, agricultural and house wastes (35.8%) and the irrational water resources management (29.9%) as the main sources of the pollution of the Evrotas River. Subsequently, elected authorities argue that the LIFE / EnviFriendly project should directly focus on the monitoring of the pollution and the pollution sources and the quantitative and qualitative management of the water resources (81% and 77% respectively). Within this framework one has to find practical and feasible solutions to combat pollution and achieve wise water management. For example, the local community should recognize the fact that the different types of waste are not the only source of pollution and that the irrational use of pesticides constitutes a similarly significant pollution source. These findings are very important since they reflect the needs and problems of the local community. Furthermore, they highlight particularly interesting issues such as the local authorities‘ utilitarian perception of the Evrotas River as a water source and their weakness up-to-date to fully explore the river‘s cultural, historical and environmental development potential. The rich and long-term history of the region, if properly explored, could contribute both to the economic development of the area, e.g. as a tourist attraction, and to the enhancement of the quality of life of the residents. However, it seems that today the agricultural qualities of the river have prevailed over its cultural, environmental and tourism qualities. Finally, elected officials have expressed their belief that the LIFE / EnviFriendly project would lead the way for the implementation of similar projects by local stake-holders (91.9%). The project also seeks the elaboration of a set of feasible solutions fully adapted to the local needs, the improvement of the current conditions and the dissemination of local ―best-practice‖ examples. The implementation tools of the project can be grouped in three broader categories: a) demonstration of environmental friendly technologies addressing such issues as the monitoring of natural restoration and water management, the management of drainage channels and of riparian regions, and the management of agricultural waste, b) elaboration of management plans for the catchment, Final Report (Technical issue) – LIFE05 ENV/GR/000245 71/313 Environmental Friendly Technologies for Rural Development c) evaluation of social acceptance and dissemination of results. The overall objective of the project is to make the region more attractive in order to enhance the quality of life of the residents and contribute the region‘s long-term development. Summary conclusions of the repetitive survey Following the completion of the survey and the analysis of the data, the following conclusions can be drawn: a) Overall, the vast majority of elected officials is substantially informed about the progress of the LIFE / EnviFriendly project and the project‘s implementation guidelines. Moreover, many elected officials had been directly participated in the information meetings that concerned the local peculiarities and needs, as well as to the various dissemination activities throughout the implementation of the project. b) Elected officials have demonstrated only limited awareness of the Observatory for Local Development. This could be due to the organizational difficulties that have hindered the smooth operation of the Observatory and the only partial clarification of the Observatory‘s tasks. The NCSR researchers estimate that in the long-run and following the full operation of the Observatory elected officials will comprehend its significant contribution in the development of the region mostly as a co-ordination and information mechanism. c) Regarding the familiarity of local officials with the ―integrated forms of agricultural production‖ there are significant differentiations depending on the orientation of each municipality (i.e. whether the municipality is oriented towards the primary or the tertiary sector). However, it is indicative that the elected officials who have a relevant professional activity are fully aware of the ―integrated forms of agricultural production‖ and could subsequently disseminate the relevant information to the residents of their locality. d) The whole of the officials have a positive opinion as regards the content and objectives of the LIFE / EnviFriendly project and its successful implementation. Moreover, they fully agree with the project‘s prioritization of the local development problems, as well as with the project‘s proposals regarding the required managerial measures. e) Finally, nearly the whole of the respondents consider the implementation of the LIFE / EnviFriendly project to have provided the local community with considerable know-how regarding the implementation of European projects in the field of local development and to have opened the way for participation in future European projects. Considering the fact that elected officials have agreed with the importance attributed by the LIFE / EnviFriendly project to the exploration and wise management of the water resources of the Evrotas River, it would be reasonable for any future European projects to follow the thematic lines of the LIFE / EnviFriendly project. The above findings allow a lot of optimism regarding the future participation of local officials in the management of forecoming projects and the achievement of the necessary social acceptance by the whole of the community. Final Report (Technical issue) – LIFE05 ENV/GR/000245 72/313 Environmental Friendly Technologies for Rural Development 5.6.2 Report on socio-economic impacts (Integral Planning for Sustainable Development) This study is about the demographic, economic and social characteristics of the Prefecture of Lakonia (PL), focusing on the Evrotas Riverside Area (ERA) (detailed issues are presented in the deliverable 5D.3). A brief analysis of the local development perspectives is presented here, together with the investigation of the development guidelines that appear to be of crucial importance for planning the development in the area concerned. In brief, the findings of the study are summarized in the following sections. Development Perspectives in the Prefecture of Lakonia The hierarchical context for the development perspectives of the area was elaborated through the analysis of the existing demographic, economic and social conditions, also exploiting information obtained in contacts and meetings with representatives of local agencies and by the surveys on the opinions of a) residents and professionals and b) local representatives in the municipal councils. The contribution of personal contacts with residents and stakeholders during the dissemination process was of great importance. Existing natural and human resources as well as the intentions and objectives of local agencies were investigated. The integration of economic development objectives with environmental protection and maintenance goals was attempted on this basis. Thus the following framework of investment proposals was concluded. Primary Sector Agricultural production in the PL is concentrated in specific products (olives, olive oil, oranges) that are characterized by increased demand and an organized distribution system. However, future development is connected with the production of organic products. In the context of the Single European Market there is strong competition regarding the traditional agricultural products. Moreover, the Common Agricultural Policy (CAP) is already directed to the elimination of subsidies concerning these products. Consequently, a general reorientation of the productive priorities is needed. Organic Products According to the record of cultivators of organic products as kept by one relevant certification agency (DEO, ΔΗΩ), the PL counts 310 cultivators. Registries started in 1992 and, although the annual variation was important, the general trend was one of increase. The biggest increase was observed during last years. There were 62 new entries in one single year (2006), while more than 50% of the cultivators entered the market after 2004. Same trends are recorded at the national level, reflecting international shifts. The demand for organic products is increasing, as a bigger proportion of the consumers is involved, although reservation concerning the increase prices still exist. The traditional products of Lakonia (olives, olive oil, oranges) already belong to the group of the most demanded organic products, while being exported to other countries. Advanced package, standardization and marketing activities are needed. Final Report (Technical issue) – LIFE05 ENV/GR/000245 73/313 Environmental Friendly Technologies for Rural Development Protected Destination of Origin (Pdo) Products The Protected Destination of Origin as well as the Protection of Geographical Indication (PGI) were institutionalised by the European Union in the Regulation 2081/92. The Regulation 2082/92 established the certification of traditional specialty guaranteed agricultural products. These two Regulations were replaced by Regulations 510/06 and 509/06 respectively, without altering the scope of implementation. According to this legal framework and in the CAP context cultivators have the possibility to exploit opportunities for integrated rural development, through the differentiation of agricultural production. Cultivators (especially those in remote areas) are able to place specialized products in the market, thus achieving better prices. Consumers on the other hand can purchase quality products of guaranteed geographic origin. In more detail, the basic categories of certified agricultural products are: a) Destination of Origin ―Destination of Origin‖ is the name of a territory, a specific place or in some cases of a country used for the description of an agricultural product or foodstuff originating from this territory, when the quality or the characteristics of this product are exclusively or mainly attributed to the geographic environment, including natural and human conditions, of the territory. The production, manufacture and processing of the product have to take place in the same area. b) Geographical Indication ―Geographical Indication‖ is the name of a territory, a specific place or in some cases of a country used for the description of an agricultural product or foodstuff originating from this territory, when the quality, the reputation or a specific characteristic of this product may attributed to this geographic origin. The production and/or the manufacture and/or the processing of the product have to take place in the same area. c) Traditional Specialty Guaranteed Agricultural Product A ―Traditional Specialty Guaranteed Agricultural Product‖ is an agricultural product or foodstuff with intrinsic characteristics that differentiate it from other similar products and which has been present in the common market for a period that proves intergenerational transmission. Intrinsic characteristics may concern physical, chemical, biological or organoleptic features or the production methods and conditions. The traditional character may concern the raw materials, the ingredients, the method of production or manufacture. The name has also to be peculiar or to express the peculiar character of the product. Since 1.6.2006 the Organization for Certification and Surveillance of Agricultural Products, under the distinctive title AGROCERT is responsible for the approval of relevant applications by enterprises concerned, the monitoring of production processes in collaboration with the Agricultural Directorates of the Prefectures, the observance of the prescriptions, the certification of products and the record of PDO and PGI holders. Final Report (Technical issue) – LIFE05 ENV/GR/000245 74/313 Environmental Friendly Technologies for Rural Development Other Development Possibilities in Primary Sector Non-stabling stockbreeding. There is a possibility to establish larger units (stockbreeding parks) of integral and organic character. During the Project process a specific study on the potential establishment of stockbreeding parks in Lakonia was elaborated, using the existing stockbreeding park in Grevena (Prefecture of Pella, Northern Greece) as an example. Other investment opportunities include the exploitation of wind energy and the energy production capacity of oil-factory waste. The possibility to exploit the existing lead deposit in the Municipality of Molaoi has to be investigated. Lead and silver mines operated in the area in the past (even during the ‗90s) but today their efficiency is contested. Secondary Sector Branches with development capacities: Olive processing, focusing on edible olives standardization, seed-oil exploitation for electricity production and other contiguous activities such as environmental protection (biological cleaning) and quality certification. Possibilities for the establishment of wind energy parks in Mt. Parnon Tertiary Sector Branches with development capacities: As the PL lacks hotel units, especially those of high standards, there still is enough space for further tourist development. Concerning high quality tourist services as well as ecotourist activities on Mt. Parnon and Taygetos. Existing tourist facilities in the ERA include: Four hostels in the Municipality of Faris: One in Toriza (MD of Xerokampi) with a restaurant, tavern and café; one in Paleopanagia (MD of Paleopnagia) in a 200,000 m2 plot with walnut and chestnut trees, near the Byzantine monastery of Gola; one in Rahivi (MD of Vassiliki); and one in the MD of Arna. Seven on the Mt. Taygetos: one municipal hostel in Georgitsi, the oldest in the area; one in Kastori, near a medieval castle characterized as archaeological site; one in Karyes; one in Polydroso (Tzitzina); two in Anavryti, one of which remains closed as an investor is requested‘ and one in Mystras - a traditional mansion that is going to be uses as a Vernacular Art Museum. Additionally there are several mountain shelters in Parnon and Taygetos that are used for the excursions organized by the Greek Mountaineering Club. Ecotourist activities and mountaineering offer the opportunity to extend the tourist season beyond summer months and to increase tourist services demand in remote areas of the PL. Final Report (Technical issue) – LIFE05 ENV/GR/000245 75/313 Environmental Friendly Technologies for Rural Development Evaluation of the life\envifriendly project in the development perspective LIFE\Envifriendly objectives According to the initial planning and schedule of the Projects, its objectives included: 1. To select, plan and implement environmentally friendly technologies in order to reduce pollution caused in the ERA by agricultural activities, industrial and urban waste. 2. To develop and demonstrate tools of technological restoration of water quality and to propose methods to incorporate these tools in the Evrotas basin and coastline Master Plans. 3. To provide the context for the integration of these technologies and tools in the socio-economic activities of the area and to promote the social acceptance of the proposed measures. 4. The sensitisation of the local population against sustainable development and environmental protection through dissemination of adequate information. Evaluation of the Achievements a) During the materialization of the Project the specific conditions of the area were investigated, the main sources of pollution were detected and alternative solutions for cleaning were planned and proposed. In collaboration with agencies responsible for water resources management a comprehensive plan for pollution and the problems caused by natural factors (floods, water shortage etc.) was elaborated. The comprehensive model was presented in several information meetings and scientific conferences. The acceptance of the proposals by the specialists of local agencies and by wider parts of the local population was encouraging and thus provided the ground for the next step, that is for the elaboration of the integrated plan for water resources management in the ERA. b) The adoption and demonstration of technical solutions based on environmental friendly technologies has been presented in detail, focusing on the advantages and disadvantages of each alternative proposal and method. Certain manufacture units in the area have implemented antilitter technologies, exhibiting satisfactory results. They also participated in demonstration events. The overall process of the final management plans included repeated contacts and meetings with representatives of local agencies (especially the Local Organizations for Land Improvement, ΤΟΕΒ). This constant process of public consultation was remarkably fruitful, giving the floor to express local views of all actors involved and to incorporate local specificities. This was crucial in order to widen social acceptance and consensus, as the local agencies participate in the formation of local views. On the other hand, the problem of personal responsibility remains, due to insufficient information and the social cost of effectively taking proactive and suppressive measures at the individual level. In any case the Project methods and practices provided all local participants with new ideas and stronger arguments. c) The establishment of adequate conditions for the incorporation of the Project interventions in the overall local socio-economic process has been attempted through: Final Report (Technical issue) – LIFE05 ENV/GR/000245 76/313 Environmental Friendly Technologies for Rural Development The conduction of two repeated surveys in the resident population and professionals of the ERA and in the focus group of the representatives in Municipal Councils. Ad hoc studies about specific local problems and conditions including the consequences of natural phenomena (fire disasters, floods, water shortage), suggested measures (stockbreeding parks) and other intervention for environmental improvement (recycling). Regular meetings with representatives of the participant Municipalities and with other agents about specific issues. The organization of public informative and scientific events and the participation n events organized by other local agents. More generally through the establishment of permanent public dialogue process. The surveys‘ results, the findings of the studies and the relevant feedback obtained by local agents exhibit the achievement of the above goals. More precisely, the overall picture shows that the local society has adopted the proposed interventions, agrees with the hierarchical classification of priorities and thinks that the Project demonstrates future directions and the preconditions for the successful materialization of other development projects. Furthermore, these projects should embrace the Projects‘ objectives, which are considered important for the development perspective of the area. d) The sensitization of the local population against sustainable development and environmental production has been incorporated in the Project through several activities. More precisely: The production of printed and digital informative material either presenting the immediate objectives and methods or other contiguous subjects of environmental management. The material was regularly distributed. The distribution of material from the above mentioned studies and relevant presentations in several occasions. The collaboration with the local EE agencies, together with the exploitation of the long-standing involvement of the NCSR in the central planning of EE at the national level. Several local events and conferences were organized. The evaluation of the results in these fields is very positive, especially in the field of EE. That is because EE has already established adequate structures of information and because activities in schools of every level have multiple effects in the, as the sensitization of students disseminates in other groups of the local society. Concerning the local population as a total, evaluation of the results is also positive, although certain gaps of information have been recorded. The absence of relevant policies and information in the past has been important at this point. However the Project as well as other interventions have made a contribution towards this direction. Nonetheless, a more comprehensive national strategy seems to be of relevance, in order to integrate the objectives of single projects. Final Report (Technical issue) – LIFE05 ENV/GR/000245 77/313 Environmental Friendly Technologies for Rural Development Demonstrative and Transferable „GOOD PRACTICES‟ of LIFE/ENVIFRIENDLY Project The implementation process of the Project indicated the need to adopt interventions and practices that could be used as experimental ‗good practices‘, also suitable to contribute to development objectives in other areas, Prefectures and Regions of the country. The main issues around which these interventions and practices were undertaken are as follows: The Water Resources Management Plans, aiming at the adaptation of the existing legal framework and of actual management practices in the field to EU Directive. The implementation of the Directive is obligatory for all memberstates and a precondition for rational water use. The Integrated Water Resources Management Plan was elaborated and completed after taking into account the analysis of local conditions. Accordingly, more than being a tool for local development in the ERA, it can be used as a model application in order to support similar plans in other water basins. Thus, it can be used as a Development Guide, after adequate revisions and adaptations to specific local conditions. The public consultation process was implemented in the ERA according to local social specificities. Similar specificities emerge at the most agricultural areas of Greece. The acceptance and the effectiveness of the public consultation process were found to depend on the ability to exploit local social networks. Thus, instead of a simple guidance by the Project team that would merely follow the guidelines of the central Dissemination Plan, more decentralized methods were adopted, in order both to exhibit local conditions and to correspond to the local potential at the micro-scale. Based on this ground, the informal meetings with representatives of a wide range of local institutions and agencies and the dissemination of the Projects achievements and progress in local social life spaces and events (the coffee bars [kafeneia], celebrations and annual festivals) proved to be of major importance for the mobilization and the participation of parts of the local society. The Observatory for Local Development will act as a field for the coordination of the Local Organizations for Land Improvement, where the synthesis of the above mentioned ‗inputs‘ (the Water Resources Management Plans and the consultation process) will be materialized. Moreover, the operation of the Observatory in the auspices of the Prefecture of Lakonia facilitates the cooperation with the Land Improvement Agency (LIA) and consequently the common planning of the Water Resources Management Plan. The LIA is in permanent contact with the Municipalities of the ERA and the respective TOEBs, having encharged the latter with the management of water resources at the local level. However the LIA also retains the capacity for central intervention when water resources management fails and management problems occur. Periodic and ad hoc meetings (on specific managerial problems) under the responsibility of the Observatory are proposed. Final Report (Technical issue) – LIFE05 ENV/GR/000245 78/313 Environmental Friendly Technologies for Rural Development This scheme guarantees the connection between the implementation of the management system and the broader development in the ERA. At the same time it gives the opportunity for sustainable public participation, since the Observatory will have become the basic dissemination mechanism in the local society. In brief, the Observatory will be responsible for the practical organization of the continuous public consultation process, thus providing the ground for the expression of the views of different social groups and their integration into an overall development strategy. These ‗Good Practices‘ can be used as paradigmatic cases for development plans and the respective necessary procedures in other areas. Future Planning on the basis of Project Objectives One of the aims of the project has been to extend its objectives beyond the period of materialization. Accordingly, certain preconditions for future exploitation of its results should be constructed. It is in this context that the creation of the Observatory for Local Development has been planned. It is expected to be an information center for local agencies and residents and a node for the coordination of investments, contributing to the investigation and planning of development activities. Up to now the overall operation of the Observatory is positive, despite functional problems and delays that occurred. However, the Observatory should be staffed with permanent employees, as this would reassure its sustainability after the end of the Project. The Prefecture of Lakonia and other involved agencies should maintain its activities. Another development perspective of the Project has been that of organic agricultural products, in the context of Codes of Equitable Agricultural Practice. Present conditions seem to be promising, if one judges from the experience of existing organic agricultural units and their efficacy. International and national trends provide an environment where profitable exports of quality products can be achieved. Organic agricultural production can be combined with eco- and agrotourist activities, thus providing one of the most directions for sustainable development. The developmental role of antilitter technologies should be stressed too. Antilitter activities in the industries of the area would contribute significantly to the amelioration of local environmental conditions. Furthermore they can be exploited as an added value in the promotion of local products and contribute to the increase and amelioration of tourist activities. Finally, such investments attract high national and supranational subsidies, while the socalled ‗green products‘ are expected to dominate in the near future, thus linking the sustainability of localities with the establishment of green economic units. Final Report (Technical issue) – LIFE05 ENV/GR/000245 79/313 Environmental Friendly Technologies for Rural Development 5.7 TASK 6 - Development of integrated watershed management plans The fundamental challenge in the development and management of environmental policies is the sustainability of the objectives of these policies. The objectives for sustainable development require decisions that satisfy the needs for this generation and they provide a chance to future generation to satisfy their needs as well. The strategic objective is the integrated management of water resources of Evrotas River Basin that will contribute to the – improvement of the environment, – social cohesion, – value added to the local economy, and – improvement of the quality of life. The objective is to create the conditions for sustainable rural development while the chemical and ecological quality of surface and ground waters is improved according to the Water Framework Directive 2000/60/EC. Evrotas can be the comparative advantage that would lead the Prefecture of Lakonia to the 21st Century. The Strategic Plan was developed around the following six axes: 1. Agricultural development 2. Drinking water 3. Irrigation 4. Reduction of point and non-point source pollution 5. Unified response to floods and drought 6. Protection of biodiversity and restoration of river ecosystems. 5.7.1. Agricultural Development The fundamental problems of agricultural production in Greece today should be fully understood before conditions for sustainable rural development can be established. Industrialized agriculture includes intensive grown mono-cultures, inorganic synthetic fertilizers, intensive use of herbicides and insecticides (that affect adversely the soil fungi and bacteria that catalyze the fertility of the soil), tilling (including deep tilling that destroys the soil structure, making it fine and subject to erosion) and irrigation (reduces the reserves of water resources). Agricultural production in Greece depends among other things on the price of fertilizers, the seed market, the international financial speculation on agricultural products and problems of social consensus. Fertilizer prices have increased dramatically that past two years. This price hike was not due to increases in oil prices, but due to increases in the price of phosphorous ore (from 50 to 350 dollars in 16 months). The price hike has been attributed to decreasing reserves (PEAK Phosphorous), in a similar way as with oil reserves (PEAK OIL). It is speculated that phosphorous reserves will decrease dramatically between 2025 and 2040. The problem is that we consume 22,5 kg of P-rock/person/yr while the daily recommended dose is 1,2 g/person/d or 0,438 kg P-rock/yr. We use 50 times more P than we need. The wasted P ends up in the Final Report (Technical issue) – LIFE05 ENV/GR/000245 80/313 Environmental Friendly Technologies for Rural Development wastewater treatment plants, the lakes and rivers and causes eutrophication. The price of the fertilizers will continue to increase because of the decreasing quantities of P-rock production causing increasing demand. How are we going to handle the situation when the reserves are depleted? The situation leads to a deadlock unless alternative means of fertilizing the land is found. The farmers also depend on the seed market (hybrid or genetically modified) created by the international food industries. Using biotechnology, the food industries have developed patented hybrid seeds. There is the notion among farmers that only hybrid seeds can bring good production the time that many ecologists recommend local varieties as the most appropriate since they could withstand local conditions in time. The international financial speculation on agricultural products (cereal, rice etc) creates uncertainty in the food prices causing a series of world-wide problems. In a similar fashion, farmer‘s speculation (i.e. production of corn for biodiesel and not for animal feed) provides temporal improvement in income without solving permanent agricultural problems. The international markets should have limits as the current financial crisis taught us. A few things in life should be outside the limits of international speculation and gambling. Finally, there are significant problem with social consensus that impedes the creation of successful farmers association that would develop market strategies for their products and eliminating the price gap between the field and the super market. There alternative ways to rural development. First we need to understand that agriculture, tourism, local culture and the environment are communicating vessels. The connecting link of these communicating vessels is the soil. Greece has forgotten to take care of its soils as it has behaved before since the ancient times. Plato in ―Kritias‖ described the Attica land as ―bones without flesh‖. The combination of erosion and bad land practices creates a defincit in carbon and other micro-nutrients necessary for soil fertility and health. Soil measurements in Greece show carbon content well below 2% and in many times below 1% (pre-desertification stage). In addition, we have observed significant deficiency in micro-nutrients like selenium that many connect such deficiency to wide-spread diseases such as the ―bird flu‖ in China and AIDS in Africa. The bottom line is that the Greek soils are eroded, have lost their fertility and this has consequences in the quality of the produce and our health. We should regenerate soil fertility by returning carbon, nutrients and micro-nutrients. There are examples all around the world showing that we can have agricultural development, sufficient food production to cover the global needs and at the same time to maintain ecological quality. An example from Amazon – The native Indian 2500 till 500 B.C. realized that once they cut the trees in the forest, the soil became infertile in 2-3 years. They had to find ways to regenerate soil fertility. They developed the soils named Terra Preta de Indio (Amazonian Dark Earths or Indian Black Earth). The soil was enhanced with Biochar (char made up of plant material, food waste such as bones from fish that has plenty of calcium). This material was composted before it was incorporated in the soil. This soil is fertile today. Final Report (Technical issue) – LIFE05 ENV/GR/000245 81/313 Environmental Friendly Technologies for Rural Development Collaboration between agriculture and livestock raising – An example of such a collaboration is Polyface farm in the State of Virginia, U.S.A. The farm is raising 5 types of animals (cows, chicken, pigs, turkeys and rabbits) eating grass without any animal feed. The owners make sure that there is plenty of available grass in the farm by creating new soil as follows. First the put cows in an area fenced by electric fences for several days. The cows eat the grass while they leave plenty of manure. The owners move the cows to another location, let the worms grow for 4 days and then they move the chickens in. The chickens eat the worms that are rich in proteins and they leave manure rich in ammonia. The soil is regenerated, grows new grass and the ecosystem is balanced. The result is that using the ecological services of the different animals, the owners earn $700.000/year (10 people) while they maintain the ecological integrity of the ecosystem. Combination agricultural practices – Monoculture is a recent agricultural practice. Farmer in Greece used to practice good agricultural practices by alternating what they grow in the field choosing between the set aside practice and growing legumes or alfa-alfa in an olive grove. Such combination agricultural practices replenish the soil with nutrient (without the use of fertilizers) while keeping down the production cost. Management of solid waste – Todate, landfilling has been the most wide spread practice of solid waste management in Greece. In a few areas recycling has been initiated as well. Since the current capacity of landfills is close to completion and new landfills are difficult to site due to local opposition, government officials have started looking into other options such as combustion and recycling and composting. Given the state of fertility the Greek soils are, the only logical and sustainable solution is separation at the source, recycling, composting the organic fraction and landfilling the remaining wastes. In the creation of the compost material other organic byproducts can be used such as the biosolids and sludges from the waste water treatment plants and braches from pumming of the plants. The compost can then be used to improve the quality and fertility of the soils and allow the farmers to be independent from the energy crisis. Such a system already is in operation at the Prefecture of Chanaia and is the only logical and sustainable alternative in solving the problem. Collaboration between tourism and agriculture – It is very important to understand that ―quality‖ tourism is related to local culture and agricultural activities. Local touristic establishments should support the local produce because they are part of the uniqueness of the region. For instance, all the hotels and restaurants of Lakonia should offer freshly squized orange juice in low prices to promote one of the main agricultural product of the region. The same could be followed for the other products. If every tourist was given a small bottle of olive oil upon arrival to the region, use the same olive oil in every restaurant he/she would go, this would become part of the trip experience and a value added for the products of the region. It would be the reason to return to the area in the future creating in this way the conditions for sustainable development. Final Report (Technical issue) – LIFE05 ENV/GR/000245 82/313 Environmental Friendly Technologies for Rural Development 5.7.2. Drinking Water Supply Drinking water supply for the towns and villages in Evrotas river basin is vulnerable to accidents in the pumps, water lines and natural disasters. Every village and town has its own water infrastructure and in case of system failure there is interruption in the service. In addition, the municipalities cannot afford to hire personnel to ensure the quality of the water and the service provided due to their small size (with the exception of the municipality of Sparta. To overcome these problems and establish quality in the water supply system the following are proposed: Every village should have alternative sources of water that can be activated in case of accidents and other system failures. In its simplest case, this can be drilling an additional well and instrumenting it as a back up. Develop an interconnected drinking water infrastructure that connects towns, villages and small settlements that can be used to optimize water use and improve the management of water resources of the region. Creation of public water companies that would serve many municipalities that can be staffed with scientist personnel and ensure the quality of the service. Pricing the water use at the appropriate level in order for the water company to be financially independent and be able to provide the quality of the service that is appropriate of the 21st century. 5.7.3. Irrigation There are approximately 150 public wells and 7,000 private wells in operation in the Prefecture of Lakonia (Table 5.7.1). Approximately 3,550 private wells are located within the basin and unknown is the number of the illigal private wells. Irrigation water annual demand was estimated at 174 Mm3 based on typical plant water needs. Hydrologic modeling suggested that the farmers are using 3 times more water. The overexploitation of water resources threatens important natural habitats and affects negatively the aquatic flora and fauna. Table 5.7.1. Private irrigation wells in Evrotas basin. Mn. Inountos 65 Mn.Therapnes 250 Mn. Geronthres 200 Mn. Skala 550 Mn. Elos 1100 Mn. Spartas 300 Mn. Mystras 350 Mn. Faridos 120 Mn. Pelanas 10 Mn. Niata 350 Mn. Krokees 250 Final Report (Technical issue) – LIFE05 ENV/GR/000245 83/313 Environmental Friendly Technologies for Rural Development The proposed program of measures for irrigation is the following: 1. Change irrigation methods - It is very difficult under current conditions to estimate the real consumption of water. In many private wells, there are not any records concerning well yield, well depth and any operational parameters. Estimation of the real irrigation needs is necessary to persuade the farmers that it is unnecessary to overexploit the water resources and switch to iirigation systems such as drip irrigation that consumes less water. 2. Appropriate pricing of water use – Agricultural water use is based on areal extent of the farm rather than the actual quantity of water used. This should be changed and progressive pricing of water use should be established. 3. Water re-use (municipal and industrial treated wastewater) - Water from the domestic wastewater treatment plant and the agro-industrial facilities isn‘t reused. Water re-use especially during the dry months for irrigation could help in the vital problem of water scarcity. Practical example for water re-use is the practices of ―Tzinakos olive mill‖ where the wastewater is stored in evaporation ponds and is used during the summer for the irrigation of a corn field. 4. Ecological flow of the river – There water abstraction from the main stem of Evrotas river at several location. In certain periods of the year, the water is abstracted completely, leaving the river downstream dry. Maintaining an ecological flow through out the year is essential for the survival of the fish and other aquatic life. The Prefecture of Lakonia has already initiated the planning of the enforcement of the above measures. Several public irrigation projects operate in the basin with the help of the local land reclamation office. Several of them have drip irrigation systems while others (Trinasou, Zacharias and Magoulas) operate with open channels. It is planned that these open channel irrigation systems will be converted to drip irrigation in the next few years. In addition, the prefecture is planning to reverse the seawater intrusion problem of the Glikovrisi and Molaon-Asopou aquifer with water diverted from Skalas springs and construct a dam in Kelefina. 5.7.4. Pollution Control Α. Pollution reduction of non-point sources Non-point source pollution is derived mostly by agricultural and livestock activities. Almost 38% of river basin area is covered by agriculture land (olive and orange trees, vineyards) and it is estimated that 21933 tones of Nitrogen and 9428 tones of Phosphorous are the annual loads in the basin. The livestock according to mucipalities records are approximately 130540 sheeps and goats, 58070 kitchen, 1729 cows and 100 pigs. The program of measures recommended for the reduction of non-point source pollution is the following. 1. Use of Fertiliser recommended rates - Fertilizers can be used in quantities that are necessary for plant nutrition and development. Overuse of fertilizers increases the cost of farming and creates environmental pollution. It is important Final Report (Technical issue) – LIFE05 ENV/GR/000245 84/313 Environmental Friendly Technologies for Rural Development that the state creates an agricultural service that would recommend appropriate fertilizer application rates based on the needs of the plant and the condition of the soil. 2. Organised livestock farms - It is proposed the creation of organized livestock farms in pre-selected areas and the adoption for their operation of the environmental standards. These farms have the advantage of offering better protection to natural resources (water / soil), and contaminants and dioxins aren‘t transferred to food chain and their solid wastes and wastewater can be reused after treatment. 3. Rotation plant crops – Crop rotation is very important to maintain the structure and integrity of the soil as well as enhance it with nitrogen improving in this way its productivity. 4. Biological farming - The main difference in biofarming comparing to traditional is that the agricultural practices don‘t include chemical fertilizers, pesticides, chemical pesticides or synthetic hormones of all kinds. 5. Erosion control – Erosion control measure such as no-till, crop rotation etc are recommended for adaption. 6. Integrated farming systems - Integrated Farming (IF) offers a whole farm policy and whole systems approach to farm management. It seeks to provide efficient and profitable production which is economically viable and environmentally responsible and delivers safe, wholesome and high quality food through the efficient management of livestock, forage, fresh produce and arable crops whilst conserving and enhancing the environment. It goes beyond simple compliance with current farming regulations, reinforces the positive impact of farming practices on the environment and reduces their negative effects, without losing sight of the profitability for the farm. It is geared towards the optimal and sustainable use of all farm resources such as farm, livestock, soil, water, air, machinery, landscape and wildlife. This is achieved through the integration of natural regulatory processes, on-farm alternatives and management skills, to make the maximum replacement of off-farm inputs, maintain species and landscape diversity, minimise losses and pollution, provide a safe and wholesome food supply and sustain income (EISA, 2006). 7. Retain and create terraces - Terracing reduces the length of slope on a hill side, which can help to reduce erosion and prevent gully formation. 8. Riparian zone restoration and phytoremediation – Riparian strips and buffers promote bank stability, prevent bank erosion and act as a filter for agricultural pollution. 9. Monitored natural attenuation technology – As it is shown in this project, MNA should be the starting point before any other measures are established. 10. Drainage canals management - The reeds (Phragmites australis) and in general the vegetation growing in drainage ditches if managed appropriately can reduce pollution from agricultural fields. Final Report (Technical issue) – LIFE05 ENV/GR/000245 85/313 Environmental Friendly Technologies for Rural Development B. Point Sources Point sources of pollution are the effluents of olive mills, the orange juice factories and domestic wastewater that are disposed untreated or partially treated into Evrotas river and its tributaries. In the framework of LIFE-EnviFriendly project five (5) alternative methods for OMWW treatment for single mills and five (5) for central units were proposed (Table 5.7.2). Two orange juice press factories are operating in the basin (Laconia and Papadimitracopoulos), where one of them «Laconia» has wastewater treatment unit and consequently a large part of the organic load and solids to be removed. In the framework of LIFE-EnviFriendly project an electrolytic unit was installed in ―Laconia press‖ regarding the improvement of treatement process. Table 5.7.2. Alternative solutions for the treatment of OMW. Single olive oil mill Central unit [1] Evaporation ponds Phytoremediation [2] Storage and irrigation during the summer Evaporation pond with odour control unit [3] Irrigation of olive trees Filtration with sawdust and resins [4] Subsurface disposal and phytoremediation without GW monitoring Anaerobic digestion [5] Subsurface disposal and phytoremediation with GW monitoring Deodorization and electrolytic process Finally there are villages such as Kastori which has no treatment plant, and dispose the raw wastewater directly into Evrotas. Also villages (i.e. Xirokampi, which has 1,500 residents) are served with septic tanks. These settlements could make use of small decentralized natural treatment systems for their wastewater. In general the point sources pose severe problems in chemistry and ecology of the river and a solution has to be found. There are alternatives and should be choosed the appropriate for each case. 7.5.5. Coordinated response to floods and droughts Significant flood and drought events have occurred historically in the Laconia. The Prefecture of Laconia has prepared a Management Plan (Master Plan) for the flood protection of the area. The plan has delineated and prioritized the flood prone areas and suggested a number of measures that take under consideration mitigation measures for droughts. 7.5.6. Biodiversity protection and restoration of river ecosystems Greece is characterized by high and unique biodiversity. This is particularly the case for the basin of the Evrotas which is a hot spot for endemic species. For example, the fish fauna of Evrotas includes species not found anywhere else. All these species can be considered particularly at risk because of environmental deterioration of river. The highest risk is the prolonged droughts. The fish in order to survive in difficult conditions, during the dry period, are hosted in sections of the river that flow is maintained, and can Final Report (Technical issue) – LIFE05 ENV/GR/000245 86/313 Environmental Friendly Technologies for Rural Development be used as shelters until the end of the drought. The sections that retain water should be protected from the intense water abstraction if we want to preserve a priceless biological heritage. The most effective way of protecting endemic species and biodiversity in general is to protect natural habitats. In this context, the protection and restoration of ecosystems of the river should be high priority and includes the following steps. Protection of riparian forests Protection of the active bed of the river Spatial measures for springs protection Restoration / Conservation flood areas Restoring connectivity to enhance fish movement - Maintain ecological flow Pressures on the coastal zone- Extension of protected area to preserve biodiversity cores- The region has a special aesthetic interest and keeps well (especially the upper part near Palaiomonastiro) a wild and natural character (high rocks, gullys, and absence of human made constructions. It is proposed, four areas (1. Kolliniotikou ravine junction, 2. Vivari springs, 3. Skoura – Lefkochoma and 4. Vrontama gorge) to be included in Natura 2000 network and to be protected in the framework of the EU Habitats Directive 92/43 of a point on the expansion of existing protected area network of Natura 2000 in Delta (Figure 5.7.1). This proposal ensures the special management of these small cores, but obviously does not exclude human activities and sustainable develpoment (agriculture, livestock, etc. on private land). Program of Measures A model for rural development has been applied in the river basin. The preliminary management plans were created according to the following six axes: 1. Agricultural Production, 2. Drinking Water Supply, 3. Irrigation, 4. Pollution Control, 5. Joint actions for flooding and drought protection, 6. Protection of the natural habitats biodiversity and restoration of the riverine ecosystem. The environmental measures were developed as follows. A database was created for each water body on pressures and impacts on the ecological status, and on the measures for the protection and restoration of water bodies. The corresponding municipalities were informed concerning the status of their water bodies and the respective measures. The main proposed measures are presented in Table 5.7.3. For each axis a detailed description of the measures have been done in order to achieve gut water quality. Some of the proposed measures have been implemented in Evrotas basin such as for example the biological farming system. During the Envifriendly project, several technologies for the minimization of point and non-point sources were demonstrated. In Table 5.7.4 the effectiveness of each demonstrated technology is presented. Some of the proposed measures have been implemented in Evrotas basin such as for example the biological farming system. During the Envifriendly project, several Final Report (Technical issue) – LIFE05 ENV/GR/000245 87/313 Environmental Friendly Technologies for Rural Development technologies for the minimization of point and non-point sources were demonstrated. In particular: (1) in ―Tzinakos olive mill‖ the wastewater is stored in evaporation ponds and is used during the summer for the irrigation of a corn field and for compost production, (2) in ―Kokkolis olive mill the underground disposal of olive mill waste and phytoremediation with poplar trees, (3) in an orange juice factory, an electrocoagulation unit was installed for the improvement of the wastewater effluent, (4) the management of drainage canals as a low cost agro-environmental measure was also demonstrated. Drainage canals are areas of accumulation of organic debris due to erosion and growth of plants such as Phragmites australis. The appropriate timing of cutting reeds maximize the removal of pollutants by plant uptake, (5) river bank management by the creating a riparian forest of poplar trees, (6) monitored natural attenuation of nutrients at the basin scale. It was proved that Evrotas basin has high capacity to attenuate pollutants such as nitrate and phosphorous. 1 2 3 4 Figure 5.7.1. Areas of biodiversity cores Final Report (Technical issue) – LIFE05 ENV/GR/000245 88/313 Environmental Friendly Technologies for Rural Development Axis 1 Axis 2 Axis 3 Axis 4 Axis 5 Axis 6 Table 5.7.3. Main environmental measures proposed in Evrotas River basin. MEASURES Modify Farming System Alternative Inter-municipalities companies of drinking water supply3, choices for Wise Cost estimate3. water supply Drip Irrigation Estimation of the real irrigation needs, Switching irrigation methods, and Drainage Change Charges for water abstraction3, Water re-use (municipal and system industrial treated wastewater)3 Phytoremediation1, Drainage canals management1. Fertilizer Control Vegetation Management on river banks3 & Reduction Use of Fertiliser recommendation system2 Estimation zones Riparian zone stabilazation1, Measures for fire disaster prevantion2, vulnerable to Natural hazards procasting2, Management plans for drought and flood flooding protection2. River bed protection, Remediation /Protection of flooded areas1, Riparian forest Ecological effective discharge quantification (during dry period) 3, protection Extension of protection areas to ensure the integrity of biodiversity cores3 1 active has studied and actions are on the way 3 under discussion 2 Residents believe that the most important function of Evrotas is to satisfy irrigation needs for agriculture. Secondarily, Evrotas is perceived to be a source of natural wealth. Its historic, ecological and cultural role is almost neglected. The over-exploitation of Evrotas River water resources and the pollution originated from agro-indurstry have created ecological implications that must be taken under consideration when designing environmental measures. The integrated water resources management is a difficult and multidisciplinary process. This study identified the dominant pressures and assessed the impacts and the chemical and ecological status of the river. Based on these studies, preliminary management plans were proposed and were specified for each municipality. The proposed measures faced fully public acceptance. The effectiveness of measures, i.e. the impact on the ecological status of Evrotas River, will be evaluated in the near future. However, preliminary results concerning the proposed measures have shown positive results. Concluding, designing an appropriate management plan for the Evrotas basin demands the participation of a wide range of scientists from additional fields (e.g. local agronomists, sociologists and economists). Moreover, the success of the management plan requires participation and acceptance of all the interested stakeholder groups. The public dialogue has been the cornerstone in the development of the existing management plans in the basin and it will continue in the future during the implementation of the research project MIRAGE (Mediterranean Intermittent River ManAGEment) that has been funded by FP7. Final Report (Technical issue) – LIFE05 ENV/GR/000245 89/313 Environmental Friendly Technologies for Rural Development Table 5.7.4. Evaluation of technologies demonstrated in the Envifriendly project. Pollution Olive Mill Waste Water Treatment Technologies Location Effectiveness Tzinakos (Surface Irrigation of a Corn Field) The study has shown that there is no adverse effect in the soil and groundwater from the application of diluted olive mill waste for the irrigation of the corn field. The corn production has increased since the OMW application and additional benefits arise also from the extra reserve of water supply during the dry period (May-August). The study has shown that during the two years of Kokolis (Subsurface demonstration that there is no impact of OMW to the Disposal and groundwater or toxicity issues to the poplar trees. Phytoremediation Monitoring of the effectiveness of the technology will be with Poplar Trees) continued in the future. Lakonia (Electrocoagulation) An electrocoagualtion unit was installed at the end of the wastewater treatment plant of the orange juice factory to reduce the color in the treated water. Specific alteration in the existing treatment scheme was suggested to improve the appearance and turbidity of the wastewater. Monitoring of the effectiveness of the technology will be continued in the future. Drainage Canals Management Skala (Phytoremediation with Reeds) The analysis of monthly samples of reeds suggested that a significant accumulation of N and P was achieved of the order of 20 and 3 g/Kg respectively. The reeds have a maximum accumulation of N and P during spring. The drainage canal sediments have also a significant reductive capacity reducing by 88% the concentration of nitrate from groundwater. The study showed that proper management of the drainage canals can reduce fluxes to surface waters by over 90%. River Bank Management Sparta (Riparian Zone Restoration and Phytoremediation by a Poplar Forest) Restoration of the riparian zone by the creation of a riparian forest was shown to be an effective technology for the combined reduction of non-point source pollution fluxes and bank erosion protection. In the first two year of the study, significant reductions in nutrient concentrations were observed. Monitoring of the effectiveness of the technology will be continued in the future. Basin Natural attenuation of nutrients in the basin was shown to be a very effective technology. Monitoring and modeling studies estimated that nitrogen and phosphorous were reduced in the basin by 86% and 92% respectively. Orange Juice Waste Water Monitored Natural Attenuation Final Report (Technical issue) – LIFE05 ENV/GR/000245 90/313 Environmental Friendly Technologies for Rural Development 5.8 TASK 7 - Evaluation of social acceptance and dissemination of results 5.8.1. Dissemination Strategy Plan The initial planning of dissemination activities for the Project was elaborated on the basis of four fundamental axes: a) thematic distribution of the activities, b) time schedule, c) definition of target-groups, d) methods of dissemination. A. Concerning the thematic distribution of the dissemination activities content, specific issues addressed were defined as follows: Overall local development perspectives. Modern methods and practices of integrated agricultural production. Alternative tourist activities (agro-tourism, eco-tourism). Water resources management (modes and techniques for water consumption reduction and anti-pollution technologies). Environmental information and sensitization of the public. B. The time schedule of the dissemination activities comprised: An initial stage, where the goal was to inform the local population about the Project objectives and thus to promote participation of several local agents and to achieve social acceptance of the Project methods and priorities. An intermediate stage, where the goal was to provide continuous information about the ongoing progress of the Project, together with enhancing local agents' participation in order to identify local specificities and development perspectives. A final stage, where a twofold goal had been put: to propose the final form of proposed measures and to disseminate the final results and the estimated benefits of these measures, through an adequate consultation process. This stage also aimed at the increasing the capacity for future development. C. For methodological purposes the target groups were categorized as follows: Local agencies/Project Participants (staff of the Prefecture of Lakonia, the ERA Municipalities and the Local Organizations for Land Improvement (ΤΟΕΒ). Representatives of professional and entrepreneurial associations (Commercial and Manufacture Association, Trade Union, Hotel Owners Association). Agricultural and Stock-breeding Co-partnerships. Environmental Education Agencies. Non Governmental Organizations (Environmental Organizations, Citizens' Associations) Local media. D. Means and methods of dissemination comprised activities at different scales, such as: Regular contacts and meetings with local agents and Projects participants (planning and organization of the Project activities, meetings on specific issues, organization and materialization of public events, participation in public events Final Report (Technical issue) – LIFE05 ENV/GR/000245 91/313 Environmental Friendly Technologies for Rural Development organized by third parts, public consultation processes and formation of the content of final measures). Public events (scientific and informative conferences, participation in conferences ans festivals organized by third parts), addressed to the above mentioned target groups. Elaboration, production and distribution of imprint and digital informative material (flyers, leaflets, posters, banners, CD, DVD etc.). Evaluation of Social Acceptance/Public Consultation Τhe comparison of the results of the two socio-economic studies (initial and repetitive) conducted throughout the project implementation (interviews with local electives and residents/professionals) demonstrate the fact that to a considerable extent society in the ERB has adopted the philosophy of the EnviFriendly project, accepted the need to implement the suggested actions in the field of water resources management and prioritized in similar ways the necessary changes. Local society is now aware of the alternative development perspectives of Evrotas and considers the implementation of EnviFriendly to have set the framework for the sustainable agricultural development of the region and to have paved the road for the implementation of new development projects in the region. Public participation is essential throughout the preparation, review and updating of the ERB management plans. Different types of participation refer to different levels of involvement of stakeholders and the public. The implementation of the WFD requires the following forms of participation: a) information supply, b) consultation and c) active involvement. It should be stressed that approaches to public participation should be context specific and adapted to the specific institutional, socio-economic and environmental context of the River Basin within which they are pursued. The EnviFriendly project organized the public participation process in full consideration of the centralized and hierarchical nature of the Greek state, the limited experience of public and private stakeholders in co-operation and the inexperience of the general public in participatory processes. Thus the project team closely cooperated with the local authorities (prefectures, municipalities and central state departments) in the preparation of the ERB management plan and approached local stakeholders and the public through the authorities. The analysis of the environmental problems of the ERB indicated the urgency of such problems as the olive mills wastes and drought. These two points were thoroughly addressed by all the participation mechanisms used towards the elaboration of the ERB management plan: 1) Information provision and awareness rising: information was provided to all the stakeholders (local and regional) in the ERB in order to raise the awareness of stakeholders and the population in general and give them the necessary know-how to participate in the consultation process at a second stage. More specifically, a) printed and electronic material was widely distributed on a regular basis, b) the results of the socio-economic studies conducted in the region were widely Final Report (Technical issue) – LIFE05 ENV/GR/000245 92/313 Environmental Friendly Technologies for Rural Development distributed and presented in public thematic events, c) environmental education was pursued with the collaboration of local educational institutions, d) information events and workshops were realized in different municipalities and e) information material was distributed and local stakeholders contacted during local celebrations organized for different reasons in at least six municipalities. With reference to oil mils wastes a handbook of 10 alternative scenarios for the treatment of wastes was prepared and a series of information and educational events were implemented with the vast participation of olive oil producers. Similar actions were addressed to farmers on draught and the role of wise agricultural practices. 2) Consultation: in May 2008 a series of meetings were organized locally in five municipalities in which local authorities (municipal council), large olive oil producers and farmers and their unions, and representatives of the TOEB reviewed and discussed the environmental and socio-economic analyses‘ results and the development prospects of their localities. The feedback was then incorporated in the drafting of the preliminary ERB management plan which was presented for open consultation in November (21st) 2008 in Sparta, the capital city of the Laconia Prefecture. The outcome of the consultation process and the written contributions were incorporated in the second draft of the ERB management plan which was presented for open consultation in February (26 th) 2009. Both consultation events were organized in a similar way. Participants were invited by the prefectural authorities who issued a press release in the local and prefectural press and the local radio stations – personal e-mails were also sent. Participants included representatives of the local and prefectural authorities and regional administration, representatives of the TOEB, large olive oil producers and farmers and representatives of their professional unions, scientists (agronomists, geologists, hydrologists etc.), civil society, NGO representatives and citizens. Written contributions-responses were then considered in the preparation of the final management plan which focused on the Integrated Water Resources Management of the ERB towards environmental enhancement, social cohesion, economic development and improvement of life quality. The goal of the management plan is the implementation of sustainable agricultural practices and the improvement of the chemical and ecological status of the surface and ground waters of the ERB. Environmental Education (E.E.) According to the initial (and also to the transformated) Dissemination Strategy Plan the role of environmental education (E.E.) activities is very important and crucial. NCSR‘s Environmental Team has longterm collaboration with the Headships of E.E. all over Greece. Especially, for the aims of the project, the collaboration with the Local E.E. agents was continious and included many types of activities (meetings, public conferences, information of E.E. teachers, educational material for the students etc). A guide of E.E activities and analytic methods of E.E. projects produced and distibuted to the E.E agents. In purpose to obtain the optimum motivation of local society, the role of E.E. agents provides special banefits. The teachers and the students are represented an important part of local population and their participation (estimated together their Final Report (Technical issue) – LIFE05 ENV/GR/000245 93/313 Environmental Friendly Technologies for Rural Development families and relatives over 70%) in dissemination campaign has multiple consequences to the motivation of local society. Additional material was produced and distributed for further information regarding Environmental Education activities. During the project the participation of young and new teachers increased continuously. As many of these teachers (independently from their specialization) were not familiarized with the basic principles and the methodology of the E.E. activities, the production of a book/guide was required. Therefore the Environmental Team of NCSR with the collaboration of Mr. Kousoulas, one of the Environmental Education‘s pioneers in Greece, produced a book/guide about EE activities and practices entitled ―An approach on Environmental Education‖. This book/guide was distributed to all teachers and a digital version is available in the project‘s webpage for the post-Project period. The NCSR Environmental Team believes that the production of the afore mentioned book/guide was required and constituted the first step for better dissemination of the project results during environmental education process. Issues of Dissemination Strategy 1. Project web site (http://www.envifriendly.tuc.gr) The construction of a web site for the Project had been planned at the initial stage of its implementation. The main objectives of the web page have been to include the research findings and to provide additional ground for dissemination, especially concerning local stakeholders. The web site is regularly updated and enriched with new emerging material. It contains pages both in Greek and in English. Its contents include the following thematic units: - The region - Local agents - The Project - Observatory for Local Development - Fire effects management - Environmental education - News and Events - Funding resources Thematic units contain informative material and links with relevant web sites of Ministries, public services and private agents whose activities concern water resources management, agricultural development, ecotourism etc. During the implementation of the Project the web site proved to be effective for the communication and information exchange among the partners. After the end of the implementation period the web site will continue to evolve under the responsibility of the Observatory, thus consisting an important tool for the constant realization of the objectives of the latter. Final Report (Technical issue) – LIFE05 ENV/GR/000245 94/313 Environmental Friendly Technologies for Rural Development The Technical University of Crete will continue the operation of the site. 2. Publications list of the EnviFriendly project in the Greek Press Part of the press publications regarding the EnviFriendly have attached as printed material with the 2nd Progress Report. At the table below are presented all press publications regarding the EnviFriendly. Local Press News paper Date of publication Lakonikos Typos 13.06.2006 Lakonikos Typos 08.12.2006 Lakonikos Typos 13.01.2007 Lakonikos Typos 16.01.2007 Lakoniki Epikairotita 01.04.2007 Peloponissos 07.04.2007 Thessalia 18.05.2007 Lakonikos Typos 05.06.2007 Eleftheria 17.06.2007 Lakonikos Typos 22.06.2007 Paratiritis 26.09.2007 Eleftheria 15.10.2007 Eleftheria 22.10.2007 Eleftheria 04.11.2007 Paratiritis 02.02.2008 Paratiritis 04.04.2008 Eleftheria 20.07.2008 Eleftheria 20.10.2008 Eleftheria 17.11.2008 Briza 26.11.2008 Eleftheria 30.11.2008 Eleftheria 23.02.2009 Eleftheria 02.03.2009 Eleftheria 09.03.2009 National Press Apogevmatini 22.09.2007 Kerdos 02.10.2007 Apogevmatini 30.11.2007 Final Report (Technical issue) – LIFE05 ENV/GR/000245 95/313 Environmental Friendly Technologies for Rural Development 5.8.2 Observatory for Local Development The Observatory for Local Development was established and operates as part of the Prefecture of Lakonia administrative structure. The function of Observatory institutionalized ordinary by the Peloponnesus region (number 725/16-04-09). Today hand it is primarily a mechanism for collection and dissemination of information on investment and development potential. In the future it is planned to obtain crucial role in the implementation of the Water Resources Management Plan. It is going to coordinate the continuous public consultation process, thus being able to accommodate views from different stakeholders and social groups and to direct them towards a common development perspective. 5.8.3 Open Farms and Mapping Trails The list of the Open Farms has been elaborated with the assistance of the Union of New Farmers and other Farmers‘ Cooperative Organizations, on the basis of specific criteria that seek to attract as many visitors and organized school / educational excursions as possible. The response and representativeness criteria that the project team used consisted of the following: a) The distribution of the farms had to represent the largest and most important part of the local agricultural production. Accordingly olive and orange groves and horticultural farms (as well as a cattle farm) had been selected (traditional local products). b) The production way should address the whole of the necessary production procedures. Thus, the Open Farms list included organic farms, traditional seasonal farms and greenhouses. c) The geographic distribution of the farms should cover the whole of the Evrotas River Basin. Accordingly, the list included farms in the Municipalities of Elos, Inounta, Krokees, Asopos, Molaoi, Skala and Pellana. d) The farms should be easily accessible. Thus, the list included farms that can be easily accessed by schools, tourists and other visitors through the highway or the main regional road network. Open Farms are selected in purpose to: - can be the ground for educational and informative activities for students who can get familiarized with the local production process. The current school year has been defined as the ‗Year for Agricultural Production and Wholesome Nutrition‘ and several relevant activities are being materialized. - Can contribute to the linkage between the Project objectives and results and the everyday agricultural practice, especially in what concerns the adoption of the Code for Good Agricultural Practice the cultivation of organic products and the use of new technologies for rural development. Final Report (Technical issue) – LIFE05 ENV/GR/000245 96/313 Environmental Friendly Technologies for Rural Development Moreover, the mapping of river and mountain trails in the ERA was proposed in the context of increasing possibilities for ecotourist development. Based on the study of the University of Ioannina and in collaboration with the local branch of the Greek Mountaineering Club maps of seven riverside and three mountainous forest zones were produced. Some of the routes of the mountainous area (Eastern Taygetos) are parts of the E4 international trail. Together with a relevant photographic presentation, this material is available at the Project web page. Evaluation of Dissemination Results Upon the completion of the project the following results indicate the effectiveness of the public participation tools towards a more active involvement in decision and policymaking: 1) The institutionalization of networking with the establishment of the Observatory for Sustainable Development. The amendment of the regulation of the organization and operation of the Prefectural Authorities of Laconia was published in the Official Journal of the Government in April 2009 (number 725/16.04.2009) establishing the Observatory for Sustainable Development. The Observatory will become operational under the jurisdiction of the Prefectural Authorities and its tasks will include the collection of all information material for the exploitation of the ERB development potential and the collection of feedback from all local stakeholders and citizens, the overall coordination of the development actions and the participation to the resolution of the emerging environmental and broader development problems. 2) Following the meetings with the local olive oil producers it became clear that the majority of them were willing to implement the suggested by the ENVIFRIENDLY group waste treatment measures on the condition that they would receive financial support and guidance by the State. Within this framework, the procedures have started for the release of a Local Health Provision with a detailed description of the obligations of the olive oil manufacturers in the ERB. The implementation of the participation procedures planned by the EnviFriendly project group has verified the assumption that for public participation approaches to be successful (i.e. produce technical knowledge or social capital) they should be tailoredmade to the specific institutional, socio-economic and environmental context within which they are pursued: 1) Considering the centralized and hierarchical nature of the Greek state it is no wonder that the Prefecture of Laconia had to operate as a ‗leader‘ in bringing together local stakeholders and the public at large. The inexperience of public and private actors in Greece in participatory procedures necessitated the assumption of a ‗leading‘ role by an authoritative public institution. Furthermore, in view of the financial considerations of farmers and olive-oil manufacturers, the most extensive participation of local authorities considerably diminished the reluctance of local stakeholders and society at large to proceed with the required alterations of wellestablished but not sustainable practices. 2) Local stakeholders and the public have no experience in participatory procedures and often ignore basic environmental facts. Within this framework, before planning Final Report (Technical issue) – LIFE05 ENV/GR/000245 97/313 Environmental Friendly Technologies for Rural Development and implementing the consultation procedures it is necessary to spend some time to environmentally educate stakeholders and the public and create the required participatory know-how. 3) While implementing the project the environmental conditions underwent dramatic changes with the extreme 2006 draught and the catastrophic 2007 fires. These changes had to be extensively studied by the project team and the results of the relevant studies were introduced in the strategic management plan. The provision of relevant advice to the stakeholders created trust between the project team and the local population and facilitated the participation process in the elaboration of the ERB management plan. Final Report (Technical issue) – LIFE05 ENV/GR/000245 98/313 Environmental Friendly Technologies for Rural Development 5.9 TASK 8 – Project Management This task deals with the management, coordination actions and reporting to the European Commission. 5.9.1. Steering Committee and Advisory Board meetings The table below summarizes the meetings among the partners during December 2005 May 2009. Action Participants Date Location Kick-off meeting Beneficiary/Partners 19.12.2005 Athens AB Partners 19.12.2005 Athens SC Partners/ Beneficiary 12.01.2006 Sparta AB Partners 26.06.2006 Sparta SC Partners 26.06.2006 Sparta AB Partners 06.02.2007 Sparta SC Partners 06.02.2007 Sparta AB Partners 21.06.2007 Sparta SC Partners 21.06.2007 Sparta Beneficiary/Partners/ASTRALE 27/28.11.2007 Sparta AB Partners 01.04.2008 Sparta SC Partners 01.04.2008 Sparta AB Partners 01.10.2008 Sparta EC/SC Partners/ASTRALE 02.10.2008 Sparta AB Partners 25.02.2009 Sparta SC Partners 26.02.2009 Sparta Beneficiary/Partners/ASTRALE 26.05.2009 Sparta 1st Advisory Board (AB) meeting 1st Steering Committee (SC) meeting 2nd Advisory Board (AB) meeting 2nd Steering Committee (SC) meeting 3rd Advisory Board (AB) meeting 3rd Steering Committee (SC) meeting 4th Advisory Board (AB) meeting 4th Steering Committee (SC) meeting Mid LIFE review meeting 5th Advisory Board (AB) meeting 5th Steering Committee (SC) meeting 6th Advisory Board (AB) meeting 6th Steering Committee (SC) meeting 7th Advisory Board (AB) meeting 7th Steering Committee (SC) meeting Final review meeting Final Report (Technical issue) – LIFE05 ENV/GR/000245 99/313 Environmental Friendly Technologies for Rural Development Kick-off meeting – 1st Advisory Board meeting According to the project timetable, the Technical University of Crete has organized a kick-off meeting the 19th December 2005 in Athens. During this kick-off meeting has taken place also the Advisory Board meeting. The participants were 22 people. The kickoff meeting has focused on the following issues: Presentations by each task Leader the ENVI-Friendly project. Presentation and discussion of other general points relative to the management of the project: The minutes are available in Greek language and were submitted to E.C. with the Interim Report. 1st Steering Committee meeting According to the project timetable organized the first Steering Committee meeting in 12.01.2006 in Sparta. The SC meeting has focused on the following issues: Presentation from the scientific responsible the ENVI-Friendly project. Presentations by each task Leader. Presentation of Development Corporation of the Prefecture of Laconia for project organization and management according to the local Municipalities. Presentation of the ENVI-Friendly project to the public. The minutes of the first SC meeting are available in Greek language and were submitted to E.C. with the Interim Report. 2nd Steering Committee and Advisory Board meetings According to the project timetable organized the second Steering Committee and Advisory Board meeting in 26.06.2006 in Sparta. The SC meeting has focused on the following issues: Presentations of the actions from the task Leaders from the first phase of the ENVI-Frindly project. Financial briefing from the Alpha MENTOR representative to the local authorities members in the frame of the first Progress Report submission. The AB meeting has focused on the following issues: Actions evaluation of the first phase of the project, Discussion on the installation of monitoring station along the Evrotas river. The minutes of the second SC and AB meetings are available in Greek language and were submitted to E.C. with the Interim Report. 3rd Steering Committee meeting and Advisory Board meetings The third Steering Committee and Advisory Board meetings were organized in 06.02.2007 in Sparta. The SC meeting has focused on the following issue: Final Report (Technical issue) – LIFE05 ENV/GR/000245 100/313 Environmental Friendly Technologies for Rural Development the progress of the activities and the results until December 2006 by each Task Leader, preparation for the next progress report. The AB meeting has focused on the following issues: Data evaluation. Sustainable Development Observatory. The minutes of the third SC and AB meetings are available in Greek language and were submitted to E.C. with the Interim Report. 4th Steering Committee meeting and Advisory Board meetings The fourth Steering Committee and Advisory Board meetings were organized in 21.06.2007 in Sparta. The main point of the discussions during afore mentioned meetings were the weakness of the public administration concerning implementation of the project results. The partners discussed particularly about the type of the organized structure and the methodology that will have to be proposed to the local bodies for better application of the project results. The minutes of the fourth SC and AB meetings are available in Greek language and were submitted to E.C. with the 2nd Progress Report. Mid LIFE review meeting The 27th and 28th November 2007 a project visit has been organized at Sparta. Attended to this meeting was Ms. C. Marouli, responsible of the Greek external Life monitoring team (ASTRALE), representatives of all Task leaders and local stakeholders of the EnviFriendly project. Field visit in five areas where experimental demonstration technologies were developed has been organized during the first day of the meeting (November, 27th). The same day, Ms. Marouli in the presence of N. Nikolaidis (Scientific responsible of the project), Alpha MENTOR team (responsible of the project management including the financial management) and NCSR team, according to the letter ENV.E.4LIFE 18921/22-10-2007 from European Committee to the Beneficiary (Prefecture of Laconia), check up the financial archive of the project (for each partner). During the discussions, Ms. Marouli emphasizes the following: - All invoices and every other voucher should have the stamp of the project and in cases of apportionment with another project this should be stated on the invoice. - Category ―PERSONNEL‖: Payment slips or signed private contracts should be submitted for every person that works for the project and is in the declared Work Team. Changes or additions in Work Teams should be stated as soon as possible and in formal letter. - Category ―TRAVELS‖: Expenses charging should be stated in clear and written commitment of every partner. The recording on the expenses base table should coincide with the standing regulations and changes should be stated. Final Report (Technical issue) – LIFE05 ENV/GR/000245 101/313 Environmental Friendly Technologies for Rural Development - Category ―CONSUMABLES‖: Expenses recording should be very detailed in quality and quantity with detailed explanation wherever is required (e.g. ΔΘΘΔ for the training package "tool-kit" for teachers and students). - Category ―OVERHEADS‖: No data is obligatory to be submitted. It is calculated as 7% of the total budget. The second day of the meeting (November, 28 th) the Task Leaders presented the results of the project in connection with the fire episodes in the area last summer. The discussion among project partners and Ms. Marouli focused on the following issues: - The function of the local Development Observatory. - The role and the results of the local network establishment. - The time schedule of dissemination strategy plan. - The progress and the results of good practices plan. - The results of the meetings and seminars with local stakeholders and school teachers (Environmental education). - The progress of Evrotas river water quality evaluation according to the water directive. The minutes of the Mid LIFE review meetings are available in Greek language and were submitted to E.C. with the 2nd Progress Report. 5th Steering Committee meeting and Advisory Board meetings The fifth Steering Committee and Advisory Board meetings were organized in 01.04.2008 in Sparta. The partners, exchanged views about the discussions and the meetings that have to be made with the local public authorities and the service representatives of the central administration of the country, so that the methodology and administrative designs, that are applied within the framework of the current project for Evrotas River, to be a standard or a pattern to similar systems in other regions of Greece. The minutes of the fifth SC and AB meetings are available in Greek language and were submitted to E.C. with the 2nd Progress Report. 6th Steering Committee meeting and Advisory Board meetings The sixth Advisory Board and Steering Committee meetings were organized in 01.10.2008 and 02.10.2008, respectively in Sparta. Attended to the SC meeting were representatives of all Task leaders and local stakeholders of the EnviFriendly project, Mr. A. Tsalas, Desk Officer of LIFE programme of European Commission and Ms. C. Marouli, responsible of the Greek external Life monitoring team (ASTRALE). The main point of the discussions during the afore mentioned meeting were the actions in the final phase of the project regarding the: 1. Open meetings on management plans. 2. Modeling of Watershed and Coastal Zone and scenarios developing. 3. Function of the local Development Observatory. Final Report (Technical issue) – LIFE05 ENV/GR/000245 102/313 Environmental Friendly Technologies for Rural Development The minutes of the sixth SC and AB meetings are available in Greek language and were submitted to E.C. with the 3rd Progress Report. 7th Steering Committee meeting and Advisory Board meetings The seventh Advisory Board and Steering Committee meetings were organized in 25.02.2009 and 26.02.2009, respectively in Sparta. Main objectives of the meetings were: - The public consultation procedure. - The preparation of the international conference during May 2009. - The preparation of the final report. The minutes of the seventh SC and AB meetings are available in Greek language and it‘s attached to the current (final) Report as separate issue. Final review meeting The final review meeting was organized in 26.05.2009 in Sparta. Attended to this meeting were representatives of all Task leaders and local stakeholders of the EnviFriendly project and Ms. C. Marouli, responsible of the Greek external Life monitoring team (ASTRALE). The main point of the discussions during the afore mentioned meeting were the preparation of the final report. 5.9.2. Reporting to EC The table below summarizes the submitted reports to European Commission during December 2005 - May 2009. Report Date of submission 1st Progress Report 03.08.2006 Interim Report 28.05.2007 2nd Progress Report 27.05.2008 3rd Progress Report 05.12.2008 Final Report 25.08.2009 1st Progress Report According to the project schedule the first Progress Report was submitted to the European Commission in August 2006 covering the project activities from 01.12.2005 to 31.07.2006. Final Report (Technical issue) – LIFE05 ENV/GR/000245 103/313 Environmental Friendly Technologies for Rural Development Interim Report Dealing with the reporting to the European Commission the Beneficiary has submitted the Interim Report, covering the project activities between 01.08.2006 and 30.04.2007 and summarized the activities from the beginning (December 2005) until July 2006. The interim report included a financial report, as separate issue. After the evaluation from E.C. a revised financial report was submitted on 30.11.2007 and additional financial information was sent on 17.01.2008. 2nd Progress Report The second progress report was submitted to the European Commission during May 2008 covering the project activities between 01.05.2007 and 30.04.2008. 3nd Progress Report The third progress report was submitted to the European Commission during December 2008 covering the project activities between 01.05.2008 and 31.10.2008. Final Report The Final Report (the present report) sums up all global activities carried in the frame of the project from the beginning (December 2005) to the end (May 2009). The financial report is attached as separate issue. Final Report (Technical issue) – LIFE05 ENV/GR/000245 104/313 Environmental Friendly Technologies for Rural Development 6. DISSEMINATION ACTIVITIES & DELIVERABLES 6.1. Dissemination activities Details regarding dissemination activities you can see in chapter 5.8.1. and Annex 2. 6.2 Deliverables (last phase) According to the project schedule, the deliverables which have been produced (and are attached as separate issues) during the period 01.11.2008 and 31.05.2009 concerns the: - - TASK 2: o Report on hydrologic and biogeochemical monitoring (2D1) – In Greek language. o Report on MNA demonstration results (2D2) - In Greek language. o Report on risk assessment of water management (2D3) - In Greek language. TASK 3: o Drainage canal management techniques (3D2) - In Greek language. o Impact of phytoremediation and bank erosion control in the minimization of nitrate loads to the river (3D4) - In Greek language. - TASK 4: o Report on second evaluation of the demonstrated waste management technologies (4D3) - In Greek language. - TASK 5: o Results of the fieldwork research – Part A and Part B (5D1) - In Greek language. o Integral Planning for Sustainable Development (5D2) - In Greek language. o Executive Summary and Conclusions of the local society‘s attitude (5D3) – In English language. - - TASK 6: o Integrated management plans (6D1) - In Greek language. o Minutes from open meetings on management plans (6D2) - In Greek language. TASK 7: o Final Report with the results of evaluation (7D1) - In Greek language. o Executive Summary and Conclusions (7D2) - In English language. o Final – International Conference material (7D5). o Creation of Local Network (7D10) - In Greek language with tables in English. Final Report (Technical issue) – LIFE05 ENV/GR/000245 105/313 Environmental Friendly Technologies for Rural Development - TASK 8: o The current report (Final Report). o Layman‘s Report - In Greek and English language. o The 7th Advisory Board and Steering Committee meetings minutes (8D13) - In Greek language. 6.3 List of project deliverables and milestones According to the project schedule, it‘s attached to the current (final) report a deliverables table, as separate issue, summarizes the deliverables and milestones which have been produced since the start of the project. Final Report (Technical issue) – LIFE05 ENV/GR/000245 106/313 Environmental Friendly Technologies for Rural Development 7. EVALUATION & CONCLUSIONS A comprehensive assessment of the project performance follows. The project for the most part was ahead of schedule and very successful. In a few areas we experienced delays; however these tasks were completed successfully at the end. The major objective was the collection of data for the demonstration of the efficiency of the proposed environmental friendly technologies. The project has been extremely successful by Greek standards. The secret of the success was the involvement of local stakeholders, the attitude of the local people, the circumstances (such as the droughts of 2007 and 2008 which have put a pressure to discuss openly water demand issues; the global financial crises that has put pressure on the farmers and their dependence on fertilizers to reduce the actual usage; etc) and the low profile we have kept in the media where one hand we promoted the work at the local level without telling people that this is a magic bullet and they do not need to do anything. This project was evaluated on the following four components: 1. Development of Watershed Management Plans – The development of the integrated water resources management plans progressed very well. The stakeholder/public participation process was very successful and was implemented for the first time in Greece with respect to the development of management plans that follow the implementation of the Water Framework Directive. We integrated water quality, ecological quality and agricultural practices in the development of the management plans. The public participation process started in April 2008 and lasted for 14 months until the end of the project. During April and May, 2008 we had meeting with stakeholders at the various municipalities and at the Prefecture level. The two main issues were drought measures and dealing with the olive mill contamination. On the 14th of May, 2008 had a public meeting in Sparta to show the interested parties 10 alternatives and low cost ways to treat olive mill wastes. These meetings were very successful because we were able to reach almost every signle olive mill owner and disseminate treatment information. For the first time in Greece it was shown that it possible to treat OMW with low cost methods. Our collaboration with the Central Water Agency made Evrotas the representative basin of Greece in the PRB-Agriculture. This part exceeded even our own expectations. The PRB-Agri group had one of its meetings in Sparta (Oct. 2008). The group plans to publish several ―books‖ on application of environmental measures, public participation, public acceptance and management plans and the LIFE project will be represented in these publications. These achievements are quite unique for Greece and facilitated the participation of the partners and the site in the FP7 proposal called ―MIRAGE‖ which was funded and started on Jan 2009. Under the auspices of the Prefecture and the CWA, EnviFriendly organized a conference and field trip in Sparta (June 21-22, 2007) to present the project and special water management issues to all stakeholders, water companies from Greece, regional governmental offices, representatives from the Ministry of Environment, Agriculture, and Development. This project has become a show case and we hope to set the agenda for water resources management in Greece and other Mediterranean countries. 2. Demonstration of Technology Efficiency – The demonstration of the technologies has been very successful. The results have been quite impressive. It has been shown Final Report (Technical issue) – LIFE05 ENV/GR/00024 107/313 Environmental Friendly Technologies for Rural Development that major environmental benefits can be obtained with low cost technologies. The demonstrated technologies were: 1. Monitored Natural Attenuation - This study documented evidence that mechanisms of natural attenuation operate at the Evrotas River Basin. The attenuation of nitrogen and phosphorous were quantified using an emission based model, MONERIS. 95.5% of the nitrogen and 98% of phosphorous were attenuated with the watershed. The results indicated that MNA is a viable remedial measure for the watershed. 2. Drainage canal management - This field and laboratory study revealed that the riparian zone of the agricultural drainage canal, natural attenuation mechanisms, as well as phytoremediation could remove significant amounts of N and P. 76.5 % of the nitrate nitrogen and all the phosphorus entering the drainage canal were removed by plants. 3. Riparian zone management - Phytoremediation in conjunction with river bank erosion controls is suggested as a combined efficient remediation tool, low cost – high gain, for non-point source pollution of nutrients. The reduction of nitrates during the first period (until the July ‟07) was 60%, while the second period was 80%, coinciding with the further growth of the poplar trees and their root system. 4. OMW-Tzinakos - Irrigation of crops with OMWW in areas with water shortage and low organic matter and nutrient soil content was demonstrated to be a viable environmental friendly management technology. Irrigation of OMWW did not affect the groundwater quality while the adverse effects on the soil were minimal (small increases of electrical conductivity, correlated with increases of potassium and calcium availability in soil solution). Soil salinity was still far below the threshold of soil salinization. 5. OMW – Kokkolis - The subsurface application of OMWW showed no adverse effect to groundwater quality. Stabilization of nutrient concentration after the planting the poplar trees, showed that the biological action of the plants decreased the variability in nutrient content. Soil coring showed no transfer of waste in deeper horizons (below 60-80 cm) thus there are no adverse effects in groundwater from waste application. The subsurface application of OMWW in conjunction with phytoremediation was shown to be an effective low cost technology. 6. Electrolytic OMWW - OMWW pretreatment for the removal of the suspended solids was shown to be essential for a succeful and efficient decolorization and polyphenol removal. Decolorization and removal of polyphenols took place in a very short period of time after the removal of the suspended solids. The efficiency of the electrolytic system increased substantially as the concentration of NaCl increases. Testing of the unit for the treatment of the wastewater from a table olives packaging facility, EUROAMERICANA S.A., provided incouraging preliminary results (50% of COD reduction). Final Report (Technical issue) – LIFE05 ENV/GR/00024 108/313 Environmental Friendly Technologies for Rural Development 7. Electrolytic – Orange Juice factory - Electrolytic post treatment of Orange Juice Wastewater was shown to be an efficient technology for refining the effluent of the treatment plant. The results showed that a 50% reduction in COD can be achieved after 120 min treatment while the effluent was decolourized by 96% with 2 and 4% NaCl. These pilots were more than we originally proposed. We have collected data from all the pilots and evaluated/demonstrated the efficiency of the treatment technologies. Minor delays were experienced in pilots 6 and 7 that were completed on time. These technologies can be transferred not only in other parts of Greece, but also in other parts of the world. The participation in the PRB-AGRI group showed us that such technologies can really help EU countries reduce pollution to water bodies and achieve their management objectives. We were also invited to participate in a COST Action meeting in Wageningen (May 2009) and present the LIFE project. The feedback from the organizers was that ―the Greek presentation was the only comprehensive approach to integrated management and program of measures‖. 3. Social Acceptance (as epitomized by the Creation of the Sustainable Development Observatory) – This issue is hard to provide ―proof‖ for. The project has been ―accepted both by the elected officials and by the people‖. The acceptance can be seen by their participation and the contacts we have during our campaigns. It is a common belief that Evrotas River can be the value added to the regional development. The social acceptance is epitomized by the strides we have made in the development of the SDO. The long term sustainability of the SDO depends on the following six factors: Experienced staff with appropriate educational background Recognized official status with enforcement responsibilities Financial support Scientific support Social acceptability Stakeholder (―people‖) participation. Here we have to be very clear that our team can not perform miracles. We have institutional obstacles that do not allow proper implementation of such structures neither do we have the authority to assign enforcement responsibilities to manage the river basin. Having said that, we believe that we have made strides of unforeseen magnitude that will ensure the sustainability of the SDO. Here is the evidence that suggests that the SDO will be successful. Experienced staff - We have been very lucky to find the five representatives from the Prefecture staff as well as other supporting personnel that have been helping us in every step of the way as well as taking on significant responsibility of the research and monitoring activities. Without them and their knowledge of the area the work we have done in such a short period would not be possible. Recognized official status with enforcement responsibilities – Here we have Final Report (Technical issue) – LIFE05 ENV/GR/00024 109/313 Environmental Friendly Technologies for Rural Development problems and the only thing we can do is to raise awareness at the higher government levels. The Head of the Prefecture, Mr. K. Fourkas officially reassigned the above individuals into a unit that can deal with the management of the river basin and staffing the SDO (number 725/16-042009). However, the Greek law has not assigned clear responsibilities. Many ministry and local authorise are involved having partial responsibilities. The Prefecture, together with EnviFriendly organized two Conferences on June 2122, 2007 and May 2009 under the auspices of the Ministry of Environment. In the Conference participated all involved Ministry and Local governmental structures as well as local stakeholders. During the months of April and May of 2008, we arranged a public meeting to address the issue of the upcoming DROUGHT of 2008, local meeting at 5 municipalities during April and 3 during May, and an open meeting to state engineers and olive mill owners on the 10 low cost ways to treat OMW. Two open meeting reagarding the public consultation on the management plans took place on Nov. 2008 and Feb 2009. Financial support – The Land Resources Survey Unit has been receiving funding from the Ministry of Agriculture for monitoring. This funding will continue. In addition, the Head of the Prefecture has been encouraging its staff to participate in proposals. The Prefecture is participating as a partner in the proposal called ―MIRAGE‖ that was funded. The funding issues have not been solved; however we feel we are at the right direction. Scientific support – SDO will rely on the scientific support from the EnviFriendly partners. Social acceptability – The staff of SDO have the social acceptability from the local people due to their previous regulatory function. For instance, many towns have located ground water sources for drinking and irrigation purposes with the help of Mr. V. Papadoulakis the Prefecture‘s geologists. Stakeholder (―people‖) participation – Here we can only provide evidence from our continuous contact with the local people in our sampling campaigns. Large teams from many institutions have been carrying out week long campaigns coming in touch with the local people. Their enthusiasm and help suggests high participation. Overall, we believe we are at the right place, the right time to make a difference. 4. Project Management – The management of the project is progressing very well. There is sufficient flow of information among partners on scientific issues as well as on financial issues. Project meetings were conducted on a regular basis to ensure smooth running of the project. This project has organized and positioned the local, regional and central government to implement the water framework directive for the first time in Greece. In fact, Evrotas River Basin is highly likely to achieve its environmental objectives by 2015. The environmental benefits of the project are significant for the area and for the Mediterranean region. We have quantified the reductions in emissions for 7 environmental friendly technologies that farmers can afford to implement by themselves without the financial help from the government. We targeted water usage and pollution problems and formulated rigorous program of measures that when Final Report (Technical issue) – LIFE05 ENV/GR/00024 110/313 Environmental Friendly Technologies for Rural Development implemented the water quality and ecological status of all water bodies in the basin will achieve the ―good‖ status. Such problems are common in Greece, the Mediterranean countries as well as the central and northern EU countries to some extent. The EnviFriendly proposed and demonstrated environmental measures have a long-term sustainability aspect that makes them more attractive in selecting them as alternatives to water resources management. For instance, if all 168 olive mills in Lakonia implement one of the treatment technologies proposed by the project, the environmental benefit and ecological benefit will be great. Pollution will be substantially reduced and the ecology of the river will be greatly improved. This will have indirect economic benefits to the olive mill owners because it will ensure the long-term sustainability of their operation. The cost to implement such technologies will not overwhelm the olive mill owners and will initiate a new social code between the owners and the people since the owners ―solve a social tension‖ issue (odors) by themselves. We have developed the first Integrated Water Resources Management Plan for Greece that will be used extensively as an example in developing Management Plans for other watersheds. The fact that the Central Water Agency and the Regions has shown a sincere interest in the project demonstrates the feasibility in transferring the technologies and methods of this project to other areas of Greece. Final Report (Technical issue) – LIFE05 ENV/GR/00024 111/313 Environmental Friendly Technologies for Rural Development 8. AFTER-LIFE COMMUNICATION PLAN An Integrated Water Resources Management Plan is an active document that should be updated on a regular basis as new data and information are emerging from its implementation. In the EnviFriendly Project we operated on the assumpltion that a Management Plan would successfully be implemented only if the local authorities actively contribute in preparing it and ―adapt it‖ and the ―technical partners‖ provide continuous technical support where needed. We are proud to say that we have achieved this objective. The Prefecture actively participated through out this project in every aspect of the demonstrations as well as in the development and dissemination of the management plan. The Prefecture was re-organized (Common Minestirial Decision 16-4-2009) and a water resources management unit was created. The Unit was charged with the collection of data and actions necessary for the integrated management of water resources and natural disasters. The After-Life Communication Plan is based on a two prong approach: 1. Continue the collaboration with the Central Water Agency to promote the EnviFriendly Project Results – The Central Water Agency of the Hellenic Ministry of Environment recognized the significance of the results of this project and included the Evrotas River Basin in the Pilot River Basins for Agricultural Measures (PRB-AGRI). The second PRB-AGRI meeting was hosted in Sparta in October 2008 by the Central Water Agency and the Prefecture where the results of the LIFE Project were presented. The project partners in coordination with the Central Water Agency activily participated in the 3 rd meeting in Wesser and will participate in the future PRB-AGRI meetings. The Agency recognizes that the EnviFriendly project developed the first Integrated Water Resources Managemnt Plan for Greece based on the WFD guidelines and uses the Plan as a prototype for the implementation of the WFD for all Greece. 2. Submit proposals to secure the necessary finances for the continuous presence of the technical partners - In order to ensure the financial cost necessary for the continuous presence of the technical partners in the future dissemination of the results of the LIFE-EnviFriendly project, we submitted a successful FP7 proposal that was funded and its implementation started on January 2009. The FP7 Project MIRAGE has as objectives “(1) provide an applicable and transferable set of reference conditions for temporary streams, specifically linking terrestrial and aquatic ecology; (2) determine effects of dry periods on accumulation and transformation of nutrients, sediments and hazardous substances on land and in river channels, at selected sites with test catchments. (3) specify and test measures to support achieving good ecological and water quality status including the integration of up- and downstream management. This will be done initially for the two mirror basins Candelaro (Italy) and Evrotas (Greece) in close cooperation with local water management organisations; (4) support the implementation of the WFD and the development of strategies for integrated water resources management for Mediterranean river basins, generalising from the Mirror Basins on the basis of modern ecohydrology concepts, in the context of characterising runoff regimes and flood responses on a Final Report (Technical issue) – LIFE05 ENV/GR/00024 112/313 Environmental Friendly Technologies for Rural Development regional basis. Five other Mediterranean catchments, including one in Morocco, will be used as the primary focus for this work; The transfer of experience and the establishment of common guidelines is then seen as a significant support for WFD implementation across the region.” In other words, the MIRAGE project was designed to provide answers to scientific questions that are important for the implementation of WFD to temporary rivers. Four of the EnviFriendly partners (TUC, HCMR, Lakonia Prefecture and NCSR) are participating in the project ensuring the further dissemination of the results until 2012. Both objectives have already been achieved. The results of the EnviFriendly project will be disseminated in the future and they will provide a lasting impact (as guidelines) for the implementation of WFD in Greece. However, the challenge still remains in terms of ensuring that the farmers and in general the local people will make the necessary life changes and truly adapt and implement the recommendations. The jury is still out. The Evrotas River Basin can achieve the ―good‖ ecological status on all water bodies by 2015 if the following issues are addressed: 1. Reduce irrigation water use – 2. Implement OMW and OJW treatment – 3. Eliminate municipal Wastewater disposal – 4. Implement riparian zone restoration – The Prefecture of Lakonia in coordination with the Municipalities and other local stakeholders has already initiated actions for each of the issues identified above. For instance, closed irrigations systems are in the stage of planning and implementation at two locations (Tirnassou and Magoulitsas) and will replace open water irrigation that ―wastes‖ a lot of water. Regarding the OMW issue, the Prefecture has announced that will issue a Prefect‘s Order on Olive Mill waste Disposal. Given that the EnviFriendly project identified 10 waste management alternatives that are cost effective, the Prefecture will give Olive Mill owners two years to comply with the new order. Steps have also been taken to control illegal dumping of wastewater in the river and plans have been made for riparian zone restoration and the prefecture is seeking finances for their implementation. The project has empowered the local authorities to take actions, ensuring in this way the sustainability of the outcomes. The Prefecture of Lakonia has become a protype prefecture for water management in Greece. The Central Water Agency considers that the Management Plan developed is the first comprehensive management plan for water resources in Greece. The results of this project are readily transferable in other regions of Greece and other Mediterranean countries. Our participation in the Pilot River Basins (PRB-AGRI) consortium ensures the dissemination of knowledge derived in the LIFE project to other EU Countries. Final Report (Technical issue) – LIFE05 ENV/GR/00024 113/313 Environmental Friendly Technologies for Rural Development ANNEX Annex 1: List of Partner‘s Data Annex 2: Detailed Description of EnviFriendly Project Results Annex 3: References Annex 4: Project tablets Final Report (Technical issue) – LIFE05 ENV/GR/00024 114/313 Environmental Friendly Technologies for Rural Development Annex 1: List of Partner‟s Data Beneficiary Prefecture of Laconia (PL) 2nd km National Road Sparta - Gythio, GR-23100 Sparta, GREECE Contact persons: Mr. P. Koulogeorgiou Mr. V. Papadoulakis Tel.: +30 27310 93859 Fax: +30 27310 93805 E-mail: grafeio.symvoulou@lakonia.gr papkal1@otenet.gr Web: www.lakonia.gr Scientific Responsible Technical University of Crete (TUC) Department of Environmental Engineering, GR-37132 Chania, GREECE Contact person: Prof. Nikolaos Nikolaidis Tel.: +30 28210 37785 Fax: +30 28210 37846 E-mail: nikolaos.nikolaidis@enveng.tuc.gr Web:http://www.enveng.tuc.gr/ http://www.herslab.tuc.gr/ http://www.Koiliaris.tuc.gr/ http://www.EnviFriendly.tuc.gr/ http://www.aquatrain.eu/ http://www.mirage-project.eu/ Partners Development Corporation of the Prefecture of Laconia, Ltd 2nd km National Road Sparta - Gythio, GR-23100 Sparta Contact person: Mr. A. Dimitrakakis Tel.: +30 27310 93800 Fax: +30 27310 26810 E-mail: anelae@otenet.gr No logo Hellenic Centre for Marine Research (HCMR) P.O.Box 712, GR-19013 Anavissos Attika, GREECE Contact person: Mr. N. Skoulikidis Tel.: +30 22910 76394 Fax: +30 22910 76323 E-mail: nskoul@hcmr.gr Web: http://www.hcmr.gr Final Report (Technical issue) – LIFE05 ENV/GR/00024 115/313 Environmental Friendly Technologies for Rural Development National Centre for Social Research (NCSR) Institute of Urban And Rural Sociology Mesogeion 14-18, GR-11527 Athens, GREECE Contact person: Mr. K. Tsakiris Tel.: +30 210 7491715-16 Fax: +30 210 7489143 E-mail: ktsaki@NCSR.gr Web: http://www.NCSR.gr Alpha MENTOR Ltd (AM) M. Alexandrou 28, GR-55535 Pylaia, Thessaloniki, GREECE Contact persons: Mrs. A. Chatzinikolaou Mr. K. Koukaras Tel.: +30 2310 322498 Fax: +30 2310 309768 E-mail: info@alphamentor.gr Web: http://www.alphamentor.gr Municipality of ELOS GR-23055 Vlachioti, Laconia, GREECE Contact person: Mrs. A. Stratakou Tel.: +30 27350 42210 Fax: +30 27350 42233 E-mail: d.elous@kep.gov.gr No logo Municipality of SKALA GR-23051 Skala, Laconia, GREECE Contact person: Mrs. G. Karachaliou Tel.: +30 27350 24035 Fax: +30 27350 24032 E-mail: gkarahaliou@1499.syzefxis.gov.gr No logo Municipality of PELLANA GR-23059 Kastorio, Laconia, GREECE Contact person: Mrs. G. Machaira Tel.: +30 27310 57220 Fax: +30 27310 57828 E-mail: otapella@otenet.gr No logo Municipality of MYSTRA GR-23100 Magoula, Laconia, GREECE Contact person: Mrs. V. Kontogeorgakou Tel.: +30 27310 22226, +30 27310 61111 Fax: +30 27310 82201, +30 27310 61115 E-mail: birginia.kontogeorgakoy@1439.syzefxis.gov.gr Final Report (Technical issue) – LIFE05 ENV/GR/00024 116/313 Environmental Friendly Technologies for Rural Development Municipality of OINOUNTOS GR-23100 Sellasia, Lakonia, GREECE Contact person: Mr. T. Tsintolas Tel.: +30 27310 94123 / +30 27310 94124 Fax: +30 27310 94245 / +30 27310 60720 E-mail: doinount@otenet.gr No logo Municipality of FARIDOS GR-23054 Xyrokampi, Laconia, GREECE Contact person: Mr. I. Vrinios Tel.: +30 27310 35388 Fax: +30 27310 36545 E-mail: d.faridos@kep.gov.gr No logo Municipality of KROKEON GR-23057 Krokees, Laconia, GREECE Contact person: Mrs. A. Maglara Tel.: +30 27350 71195 Fax: +30 27350 71195 E-mail: d.krokeon@kep.gov.gr No logo Municipality of THERAPNON GR-23100 Goritsa, Lakonia, GREECE Contact person: Mr. S. Nikoletos Tel.: +30 27310 74400 Fax: +30 27310 74111 E-mail: dimthera@otenet.gr Web: http://www.therapnai.gr Final Report (Technical issue) – LIFE05 ENV/GR/00024 117/313 Environmental Friendly Technologies for Rural Development Annex 2: Detailed Description of EnviFriendly Project Results (Task 1 – Task 7) TASK 1 – Development of preliminary management plans and design of selected demonstration technologies The first action taken by the teams was the collection of the existing data and studies of the watershed and the coastal zone. We collected the available hydrologic, hydrogeologic, meteorologic, and water quality data from all known public and private institutions. In many cases, these data were not in electronic format, so we entered them in data bases. Similarly, we obtained available GIS databases such as CORRINE land use database from the JRC-ISPRA, the digital elevation model, geology, population, river network etc. In cases, portions of the GIS theme map was missing (such as in the case of geology), we digitized it. Finally, the reports from various studies were scanned in order to develop an electronic data base of all available studies. At the end, two CDs were produced, one with the GIS information for the basin and another for the existing studies. We worked very closely with two scientists from the Prefecture of Laconia, the hydrogeologist, Mr Papadoulaki and the health inspector, Mr. Kouvatso. This collaboration was necessary for us in order on one hand to acquire their scientific knowledge of the area and assessment of the problem and on the other hand to initiate their training in managing the watershed. The main pollution point sources are urban waste water, olive oil mills, and orange juice factories while the diffuse sources are agricultural activities and livestock pollution. Figure 5.2.1 presents the spatial variability of the pollution point and non-point sources of the watershed. Figure 5.2.1. Point and non-point sources of pollution in Evrotas River Watershed. Based on the distributed information on the point and non-point sources for the watershed of Evrotas River, the nutrient (N and P) loads were estimated. The total input nitrogen load was estimated to be 46471 tn/yr and the P-load 19323 tn/yr. Agricultural Final Report (Technical issue) – LIFE05 ENV/GR/00024 118/313 Environmental Friendly Technologies for Rural Development activities contributed 43865 tn/yr of nitrogen (94.4%) and 18855 tn /yr of phosphorous (97.6%). Livestock, atmospheric deposition, urban waste water, olive oil mills and orange juice factories contributed the remaining of the load. Approximately 50% of the N and P fertilizer loads is contained in the produce and does not enter the system. Therefore, the net loads of N in the watershed were estimated to be 24539 tn/yr and of P 9896 tn/yr. Agricultural activities contributed 21933 tn/yr of N (89,4%) and 9896 tn/yr of P (95,3%). In this phase of the project we did not estimate the other pollutant loads like the organic loads from livestocks, urban waste waters, olive oil mills and the orange juice factory as well as the loads of phenols from the olive oil mills or the pesticide loads from agriculture. We attempted to conduct a complete integrated study on nutrients due to more available data and limited time (7 months) for the development of the Preliminary Management Plan. A preliminary environmental assessment has been based on the identification of pollution sources, estimation of pollution loads, assessment of hydro-morphological alterations and on the vulnerability of the basins‘ water resources. In addition, field investigations and a preliminary biological quality assessment, based on the results of the first sampling campaign, have been considered. In the framework of ENVI-Friendly, environmental assessment incorporates the principles of ecological quality assessment, as defined by the WFD (2000/60/EC). Ecological quality assessment will include the entire river basin (main stem and tributaries) and will be based on abiotic and biotic elements. Abiotic elements refer to aquatic quality (physicochemical and chemical characteristics, incl. priority substances, etc.) and hydromorphological features. Biotic elements include benthic macroinvertebrates and fish. The riparian vegetation will be additionally considered. Design of a representative sampling network Based on the available information and a field visit to the entire catchment (512.04.2006), a representative sampling network has been designed, according to hydrological aspects and human impacts. Hydrological issues. Sites have been selected in permanent and periodically flowing waters. Sites have been selected in as many as possible river tributaries (only very small streams with very low flow have been excluded). Human impacts. Ecological quality assessment and classification systems are based on the differences between expected faunal assemblages (those found in undisturbed or minimally disturbed, i.e. reference sites) and those observed. Hence, according to the analysis of pressures and related field investigations, emphasis has been given to select as many as possible potentially reference sites. In total, 42 stations for macroinvertebrate sampling and 27 preliminary stations (additional stations will be considered during the next field campaigns) for fish sampling have been selected. Fig. 5.2.2 presents the sampling network. Final Report (Technical issue) – LIFE05 ENV/GR/00024 119/313 Environmental Friendly Technologies for Rural Development Figure 5.2.2. Sampling network designed for ecological assessment purposes. Development of a typological classification methodology According to the WFD, ecological quality assessment should be type-specific. In absence of a national typological framework for running waters, a methodology for the typological characterization of water bodies within Evrotas basin has been established. According to previous research, a set of abiotic variables has been selected on which an initial biotic typology (System B) for Greek running waters could be based (Skoulikidis et al., submitted). These variables include: catchment area, altitude, slope and geology. By combining GIS-layers of geology, altitude and slope on Evrotas basin, it results that 95% of the catchment area is covered by 11 theoretical types (Fig. 5.2.3), while the sampling network belongs to 7 distinct types. The predominant types found in Evrotas basin are: Mid altitude clastic deposits with low slopes (sl1 - al2 - g1) (18 sampling sites) Low altitude clastic deposits with low slopes (sl1 - al1 -g1) (5 sites) Mid altitude silicate basement with medium slopes (sl2 - al2 - g3) (5 sites) High altitude silicate basement with medium slopes (sl2 - al3 -g3) (5 sites) Final Report (Technical issue) – LIFE05 ENV/GR/00024 120/313 Environmental Friendly Technologies for Rural Development Figure 5.2.3. Typological classification of Evrotas basin. Legend: slope, altitude and geology classes, codes and coefficients slope (ο) altitude (m) geology code class coefficient code class coefficient code class coefficient sl1 >10 2 al1 >150 3 geo1 clastic 100 sl2 10- 30 4 al2 150-600 5 geo2 carbonate 1000 sl3 <30 6 al3 >600 7 geo3 silicate 10000 Field studies During the first field campaign (5-12.04.2006), the following actions have been carried out: Estimation of the geographical coordinates of each site. Final Report (Technical issue) – LIFE05 ENV/GR/00024 121/313 Environmental Friendly Technologies for Rural Development At each sampling reach photos and videos have been taken. In addition, photos and videos of four fish species have been taken (in situ, ex-situ). In-situ measurements conductivity, pH, Eh, of physico-chemical dissolved oxygen, variables current velocity (temperature, with portable instruments) and estimation of the wetted cross section. Water sampling. Samples were collected in plastic vials from mid depths from the center of the river bed, and a few drops of saturated solution of HgCl 2 were added. A sub-sample has been kept separately, for the analysis of chloride ions. Samples were transferred in portable refrigerators in the laboratory as quick as possible and filtered through 0.45 μm membrane filters for the analysis of hydrochemical variables (total hardness, Ca 2+, Mg2+, Na+, K+, HCO3-, CO32-, Cl-, SO42-, SiO2) and conventional pollutants (nitrate, ammonia, nitrite, total nitrogen, orthophosphate and total phosphorous). Sediment sampling. In selected stations sediment samples have been collected for the estimation of mineralogical and chemical variables. Registration of river bed, river bank and riparian zone characteristics. For this purpose the AQEM/STAR protocol has been applied, that aims to give an impression of river and floodplain morphology, hydrology, hydrochemistry and vegetation composition. The collection of these data was conducted at a distance of 500 m upstream and downstream of each sampling site. Hydro-morphological analysis was performed with the use of the river Habitat survey (RHS) method. RHS assesses the physical character of a sampling site at a 500 m length and involves the collection of numeous features recorded at a 10 spot-checks in 50 m intervals. The habitat quality of each site (stream channel and riparian habitat) was evaluated with the use of the Habitat quality Assessment score (HQA) and Habitat Modification Score (HMS). HQA assesses the habitat diversity, while HMS represents habitat modification. Sampling of benthic invertebrates. The AQEM/STAR macroinvertebrate sampling methodology has been applied. It is based on a multi-habitat scheme designed for sampling major habitats proportionally according to their presence within a sampling reach of 20-25 m length. Each sample consisted of 20 ―replicates‖ taken from all microhabitat types at the sampling site with a share of at least 5% coverage, which must be distributed according to the share of microhabitats. Benthic macroinvertebrates were collected with a rectangular hand net of 0.25 m x 0.25 m with a mesh size of 500-μm nytex screen. Thus, a total area of 1.25 m2 was sampled for each sampling site. Sampling started at the downstream end of the reach and proceeded upstream. Samples were preserved in ca. 70% ethanol and the species were collected with soft tweezers and transferred to the laboratory in order to be identified with state of the art determination literature. Fish sampling. Field investigations on the presence of fish species and a preliminary sampling have been carried out with the use of electrofishing, nets, Final Report (Technical issue) – LIFE05 ENV/GR/00024 122/313 Environmental Friendly Technologies for Rural Development etc. Additional sites have been selected for a systematic fish sampling during the next stages of the ecological assessment. Environmental impact assessment has been based on literature review, interviews from administrators, agro-technicians, local citizens and field investigations. In the following, the environmental impacts on hydro-morphology, aquatic quality of surface and groundwaters, ecosystems and ecogical status of surface waters are summarized: Impacts on hydro-morphology As a result of the combined actions of water infiltration within the alluvial deposits and the karstic basement, surface water abstractions and groundwater pumping, parts of Evrotas main stem (headwaters, near Vrodamas-bridge, within Vrodamas-gorge, upstream of Skala village) dry out during the dry season. Especially downstream Karavas area, numerous surface water pumping stations and drillings affect river flow. It is worth noting however, that even along stretches where Evrotas falls dry (e.g. in Vrodamas plain and gorge), there is water remaining in small ponds, thus partly preserving aquatic fauna and flora. River channel modifications along the Evrotas main stem mainly appear at the river‘s midway and downstream portions. In the past, below Skala, Evrotas was flooding extended areas. Today, the lower part of the river is embanked and straightened to control flooding. Farmers extended orchard cultivations up to the embankment. Other morphological alterations along Evrotas main-stem concern bank reinforcement for flood control, ford construction at Skoura, and an underwater weir construction, eighty meters upstream of the river‘s mouth, in order to prevent sea water intrusion and littering. The whole basin lacks in cadastre and there is no public property along the whole river course from both sides (Public Land Service, personal communication). The vast majority of Evrotas tributaries, dry out in summer. In general, downstream of water abstraction facilities tributaries fall dry. Oinus, the main Evrotas tributary, episodically becomes temporal due to water use for irrigation. Similarly, the downstream portions of Gerakaris, Kakaris, Rasina, Xerias, Lagada (Magoulitsa) and other smaller tributaries have become temporal. Morphological modifications are apparent mainly at Vrisiotiko, Kastaniotis, Perdikari, Lagada (downstream), Skatias, Paroritis (downstream), Riviotisa, Ag. Kyriaki, Oinus (at Kelefina-bridge). The main impacts concern river bank modifications for flood control (resection or reinforcement), construction of by-pass channels for water abstraction and littering. Aquatic quality Groundwater Evrotas basin is characterized by two types of groundwater reservoirs: a karstic and a sedimentary. Karstic aquifers generally recharge the sedimentary aquifers. According to previous studies (Andonakos, 1998; Mariolakos et al., 2003 and 2005; Karalemas, 2006), the Faculty of Geology and Geoenvironment of the University of Athens, distinguished Evrotas basin into 14 hydrogeological water bodies (Fig. 5.2.4). Final Report (Technical issue) – LIFE05 ENV/GR/00024 123/313 Environmental Friendly Technologies for Rural Development Figure 5.2.4. The fourteen hydrogeological water bodies of Evrotas basin (Faculty of Geology and Geoenvironment - University of Athens). Due to groundwater over-pumping for irrigation, the water table in some aquifers diminished dramatically. Today, a number of drillings, as in the case of the Municipality of Faridos, are not operating, while others, as in the case of the delta area (Skala and Elos), became unsuitable for irrigation due to sea water intrusion. According to Andonakos and Lambrakis (2000), the shallow unconfined aquifer of the broad Sparti area was substantially enriched with nitrates (average 62.6 mg/l). In fact, 65% of nitrate concentrations in groundwater exceeded the legislative threshold for drinking water (50 mg/l), while nitrates contributed with 12% to the sum of equivalent anion concentrations. The elevated nitrate and sulphate concentration in groundwater has been attributed to the use of [(NH4NO3)(CaCO3)] and [(NHA)2SO4] fertilizers. Fig. 5.2.5 illustrates the problem of groundwater pollution at the broader Sparti area. Final Report (Technical issue) – LIFE05 ENV/GR/00024 124/313 Environmental Friendly Technologies for Rural Development Figure 5.2.5. Contours of equal nitrate concentration in groundwater (Andonakos and Lambrakis, 2000). Surface water According to MEDSPA (1993) program fifteen years ago, the water quality of Evrotas was already deteriorated. The high organic load of the river was attributed to organic pollution, originating from direct municipal waste water discharges, prior to the construction of the WWTP, and orange juice manufacturing. For example, in summer 1992 at Sparti-bridge, BOD reached 95 mg/l and COD 210 mg/l. The WWTP operation (August 1992), resulted in lowering of COD, BOD, SS and total Ν concentrations (MEDSPA, 1993). However, recent extreme BOD and COD concentrations (maximum 315 and 630 mg/l respectively) (Mariolakos et al., 2005) point out that the river is still occasionally subject to organic pollution impact. Nitrate concentrations between Sparti and Skala for the year 1992 ranged between ~9 mg/l for Platana site and ~4 for Skala, with an average concentration of about 5 mg/l (MEDSPA, 1993). According to recent data (Land Reclamation Service, Ministry of Agricultural Development and Food, 2001-2005) average nitrate concentration (for sites Vordonia, Vrodamas, Skala) has doubled (10 mg/l). This nitrate level terms the river, according to a nutrient classification system (Skoulikidis et al., 2006), as a ―bad" quality water body (threshold 7.8 mg/l). Moreover, by applying a Ministry of Environment (1994) classification, based on eutrophication criteria, the river can be classified as a threatened water body (threshold 5 mg/l). In fact, Evrotas belongs to the Greek rivers that are highly loaded with nitrates. A downstream (from Vordonia to Skala) raise in nitrate, chloride and sodium concentrations and a decrease in oxygen saturation (data: Land Reclamation Service, Ministry of Agricultural Development and Food, 2001-2005) are attributed to respective increasing human impact (agriculture, food processing, municipal wastes). Riviotisa tributary is highly Final Report (Technical issue) – LIFE05 ENV/GR/00024 125/313 Environmental Friendly Technologies for Rural Development degraded, due to discharges of orange juice processing wastes. This stream revealed very high suspended solid and nitrate (22.7 mg/l) concentrations, acid waters and low oxygen saturation (5.8%), indicating anoxic conditions (according to a few measurements from the Land Reclamation Service, Ministry of Agricultural Development and Food, 2002). Nevertheless, according to MEDSPA (1993), self-purification processes are active along the river course (e.g. nutrient fixation by reeds). Mariolakos et al. (2005) reported that river water infiltration within the karstic system of Vrodamas gorge contributes to its quality improvement downstream Skala. The relative low average nitrate concentration in Omega ditch (12.9 mg/l, according to data of the Land Reclamation Service, Ministry of Agricultural Development and Food, 2004-2005), which receives karstic inflows and agricultural return flows, indicates the dilution capacity of Skala karstic springs and the efficiency of self-purification processes. Monthly variation of major ion concentrations, points toward dilution processes during high water level. During the dry season, increased baseflow contribution to river flow, enhances solute concentrations. Regarding nitrate, the main enrichment mechanism, excluding occasional pollution incidents, is arable land flushing that takes place in the fall, during water level increase (Fig. 5.2.6). The MEDSPA (1993) study came also to the same conclusion for the extended orchard cultivations at Platana, Skoura and Skala. With increasing discharge, in winter, dilution processes drop nitrate concentrations (Fig. 5.2.7). According to the physico-chemical variables measured at the different stations during the first sampling campaign, it can be figured out that river water mineralization was enhanced by karstic spring inputs and by point source pollution (WWTP, orange juice manufacturing wastes). Dissolved oxygen concentration was controlled by karstic inputs (low oxygen content), the WWTP outflow (high oxygen concentrations due to photosynthesis) and the inputs of Riviotisa tributary (low oxygen concentrations). Figure 5.2.6. Nitrate concentration in various major Greek rivers (data: Ministry of Agricultural Development and Food). Final Report (Technical issue) – LIFE05 ENV/GR/00024 126/313 Environmental Friendly Technologies for Rural Development Figure 5.2.7. Monthly variation of discharge and nitrate concentration of Evrotas at Vordonia (data: Land Reclamation Service, Ministry of Agricultural Development and Food). Ecological status According to information, in the past, Evrotas River was characterized by rich riparian forest vegetation. Today, relicts of the former riparian forests are present at the upper portion of the river, were Platanus orientalis dominates. At the river‘s midway, relicts of mixed forests with Platanus orientalis, Salix spp., Salix alba are found. The river‘s delta is dominated by extended bush lands with Tamarix spp. Along temporal tributaries Nerium oleander and Vitex agnus-castus tufts dominate. Vrodamas gorge is of high aesthetic value and amazing natural beauty, with Platanus, salix and oleander. Evrotas presents a significantly rich riparian (hydrophilous) vegetation, which includes a great number of aquatic (Potamogeton sp. etc.) and helophyte (Nasturdium officinale, Lycopus europaeus, Mentha aquatica, Typha domingensis, Phragmites australis etc.) plants. According to previous studies (Economidis, 1991; Zalidis and Mantzavelas, 1994; EKBY, 1994; HCMR, 1999), the following fish species are found in Evrotas R.: Leuciscus keadicus, Tropidophoxinellus spartiaticus, Pseudophoxinus laconimus, Salaria fluviatilis και Anguila anguila. From these species, the most threatened one is Leuciscus keadicus, which is found exclusively in Evrotas. The endemic fish Tropidophoxinelus spartiaticus is also distributed in Vasilopotamos and other rivers of Peloponnisos. In the past, several species of fish were found at least in five tributaries, as well as in many springs of Lakonia valley. However, due to the drying out of these tributaries during summer in the last twenty years, springs became seasonal and the distribution of fish species was limited in the main river. Sampling during 1994-1998 in Evrotas tributaries (Paroritis, Mesiano, Kelefina etc.) and independent springs (St. Ioannis Kefalari), where fish species were found in the past, was fruitless. In the area of Skala, Gambusia affinis, Atherina boyeri and several Mugilidae of sea origins species can be found Final Report (Technical issue) – LIFE05 ENV/GR/00024 127/313 Environmental Friendly Technologies for Rural Development Regarding benthic invertebrates, the Evrotas basin has not been studied at all. According to the preliminary biological assessment based on macroinvertabrates (Table 3) and fish (Table 4), the following results could be drawn out: Regarding macroinvertebrates, 10 stations were pre-classified as reference, 3 as highgood, 1 as good, 9 as good-moderate, 1 as moderate, 5 as moderate-poor,10 as poorbad and 3 as bad quality (Fig. 5.2.8). If this is so after the final classification and if sites belonging to good-moderate status are equally distributed within these quality classes, 65% of the examined sites would be of lower than good quality, thus they will require remediation. Number of sites 12 10 8 6 4 2 bad poor-bad moderatepoor moderate goodmoderate good high-good high 0 Figure 5.2.8. Pre-classification of sites based on macroinvertebrates. Regarding fish, 2 sites were pre-classified as high-good, 12 as moderate-poor and 12 as poor-bad (Fig. 5.2.9). Again if this is the case after the final classification and if sites belonging to good-moderate status are equally distributed within these quality classes, 92% of the examined sites would be of lower than good quality, thus they will also require remedy actions. 14 Number of sites 12 10 8 6 4 2 0 high-good moderate-poor poor-bad Figure 5.2.9. Pre-classification of sites based on fish. Final Report (Technical issue) – LIFE05 ENV/GR/00024 128/313 Environmental Friendly Technologies for Rural Development When comparing common sites, differences in the classification results of the biological assessment methods are apparent (Fig. 5.2.10). These differences are due to the fact that macroinvertebrates are more suitable in detecting pollution, while fishes are more appropriate in detecting hydro-morphological pressures. Common sites found in Evrotas tributaries present higher quality according to macroinvertebrate assessment methods than (regarding) fish assessment methods. This is due to the fact that these tributaries are generally not heavily polluted, while their hydrological regime is heavily altered. Water abstractions drive these tributaries dry and fish communities either disappear or survive in small ponds. On the contrary, along Evrotas main stem (at Achuria and Skala), where water is permanently flowing throughout the year, macroinvertebrate assessment methods presented the same or worse quality compared to fish assessment methods. This is attributed to the fact that Evrotas main stem is polluted, but hydrologically better preserved. macroivertebrates Pre-classification 5 fish 4 3 2 1 Evrotas (Skala bridge) Evrotas (Pellana-Sellasia bridge)) Evrotas (Achuria) Oinus (Kelefina bridge) Paroritis trib. Lagada trib. At Trypi Perdikaris trib. Roman aquaduct trib.. Voutikiotis trib. Kollines trib. 0 Figure 5.2.10. Biological quality pre-classification of sites according to macroinvertebrates and fish Development of preliminary management plans; The water resources problems of Evrotas River Basin can be summarized as follows: Quantity problems – These are problems caused due to flooding and include the weathering of soils and the river banks, as well as flooding of low elevation areas and destruction of properties. Quality problems – degradation of surface and ground water quality due to point and non-point source pollution. Ecological problems – Fish populations can not be established in many parts of the river because it dries out due to over-pumping of ground water. In order to manage the watershed and its coastal zone, one needs to use mathematical models. Modeling of Evrotas River Basin and its coastal zone, Laconikos Gulf will be modelled in two phases. For the preliminary management plans, an emission based Final Report (Technical issue) – LIFE05 ENV/GR/00024 129/313 Environmental Friendly Technologies for Rural Development model, MONERIS was used to model the nutrient emissions from the watershed to the coastal zone. In addition, Laconikos Gulf was modelled with a simple mass balance model, CABARET, following the LOICZ methodology. In the final management plans, detailed models such as HSPF for the watershed and WASP for the coastal zone will be used. However, preliminary simulations of the hydrology of the watershed were performed with HSPF in order to evaluate the quality of the hydrologic data. Watershed Modeling: MONERIS has been used widely to model nutrient emissions in Europe as part of the EUROCAT, DANUBE and other projects. We have used MONERIS to model several watersheds in Greece such as Axios River Basin, Acheloos River Basin and Krathis River Basin. Figure 5.2.11 presents a comparison between modeled and measured nitrogen loads for the watershed. The total nitrogen emissions were estimated to be 1940 t/y (Table 5.2.1). 58,7% of the emissions entered the river through ground water, 10,8% from urban waste water, 4,5% from point sources, 9,2% from erosion of soils, 5,5% from surface runoff and 0,4% from the atmosphere (directly to the river). Finally, in-stream loads contributed 10,8%. The total phosphorous emissions were estimated to be 208 t/y. 11,3% of the emissions entered the river through ground water, 2,9% from urban waste water, 29,6% from point sources, 44,1% from erosion of soils, 11,4% from surface runoff and 0,7% from the atmosphere (directly to the river). The results indicate that there is evidence of natural attenuation of nutrients in the watershed. The net annual nitrogen loads to the basin were reduced from 24539 tn/yr to 1940 tn/yr that entered the coastal zone (92% reduction). The net annual phosphorous loads to the basin were reduced from 9896 tn/yr to 208 tn/yr that entered the coastal zone (98% reduction). 100000 100000 Nitrogen emissions-load 10000 DIN-load [t/a] TN-load [t/a] 10000 1000 100 100 Nitrogen (hydraulic load) 1000 100 1000 10000 Calculated TN-load [t/a] 100000 100 1000 10000 calculated DIN-load [t/a] 100000 Figure 5.2.11: Modeling results of Evrotas river basin – Comparison between modeled and field total nitrogen (TN) and Dissolved Inorganic Nitrogen (DIN). Final Report (Technical issue) – LIFE05 ENV/GR/00024 130/313 Environmental Friendly Technologies for Rural Development Table 5.2.1: Modeling results of Evrotas river basin – Nutrient emissions estimated by MONERIS (2000 -2004) Total Emissions and Contribution of Different Pathways Nitrogen Phosphorous [t/a] [%] Atmospheric deposition 8,3 0,4 1,4 0,7 Tile drainage 0,0 0,0 0,0 0,0 Ground water 1139,5 58,7 23,5 11,3 Surface runoff 105,9 5,5 23,6 11,4 Soil erosion 178,0 9,2 91,4 44,1 87,9 4,5 61,4 29,6 In-stream loads 210,2 10,8 Urban wastes 209,9 10,8 5,9 2,9 1939,8 100,0 207,3 100,0 Point sources Total Emissions Coastal Zone Modeling: [t/a] [%] The coastal zone of Laconikos Gulf was modeled using the LOICZ methodology and the CABARET model. The 1992 data of NCMR were used to model the system that was extended to the 500 m depth (Figure 5.2.12). CABARET conducted mass balance calculations for water, salinity, dissolved inorganic and total nitrogen and phosphorous. It was estimated from the nutrient balance that ΓDIN=-377E+3 moles/day and ΓDIP=12,7E+3 moles/day. Therefore the coastal zone is operating as a consumer of DIN and DΟΡ. The difference mmoles/m2/day. between photosynthesis and respiration (p-r) was 19 A positive difference (p-r) indicates that the system is a net organic matter producer. The difference between nitrogen fixation and denitrification (Nfix-denit) was -2,5 mmoles/m2/day. denitrification. The negative difference (Nfix-denit) indicates net The fact that the system was oligotrophic in 1992, and consumed nutrients suggests that it is not saturated. It is not expected to have a nutrient status change if the nutrient loads to the system do not change significantly. Finally, 3 scenarios were simulated using MONERIS in order to evaluate the impact of the demonstrated technologies in reducing the nutrient loads to the coastal zone. Final Report (Technical issue) – LIFE05 ENV/GR/00024 131/313 Environmental Friendly Technologies for Rural Development Figure 5.2.12. Laconikos Gulf bathymetry (―system box‖). TASK 2 – Monitored natural attenuation and water management 1. Monitored Natural Attenuation in Evrotas River Basin Monitored Natural Attenuation (MNA) is a remediation technology based on understanding and quantitatively documenting naturally occurring processes that ―destroy‖ or immobilise contaminants at a contaminated site in order to protect human and ecological receptors from unacceptable risks of exposure to hazardous contaminants. MNA is a ―knowledge-based‖ remedy where scientific and engineering knowledge is used to understand and document naturally occurring processes, instead of imposing active controls with engineering remedies (USEPA, 1998; USEPA, 1999 a and b; Hellerich et al., 2003, 2005 a and b, and 2007; ITRC, 1999; AFCEE, 1995 and 1999; ASTM, 1997; Palmer and Puls, 1994). In order to apply MNA at a basin scale, field (collection of samples that would indicate that pollutants are being reduced as they follow their path to the river and eventually to the sea) and laboratory evidence (lab studies of the processes that attenuate pollutants and quantification of the kinetic rates of reactions) as well as modeling studies (modeling of the site that would illustrate how the pollutant behaves in nature and that the attenuation will continue to occur over geologic times) are required (Figure 5.3.1). First step: Field evidence Historic water quality data of Evrotas River were collected from the Ministry of Agriculture, the MEDSPA90 project (MedSPA, 1993) and a study conducted by the University of Patras (Antonakos et al., 1997), to establish the first evidence for the reduction of contaminants in the study area. Pollutant concentrations (such as COD, Total Final Report (Technical issue) – LIFE05 ENV/GR/00024 132/313 Environmental Friendly Technologies for Rural Development N and Total P derived from diffuse pollution (agriculture, livestock etc.) and point sources (olive mills, juice producing factories, towns)) were decreasing along the river indicating active attenuation processes operating within the watershed. To augment the historic data, a sampling network was designed and intensive field campaigns were carried out to introduce new field evidence and account for all major ecotopes in the basin aiming at tracking the foot print of contamination (tracking contaminants from pollution sources to ground and surface water). The pollutants studied were nutrients, organic load and total phenols (a component of olive mill waste). Evrotas river basin has a complex hydrogeology and hydrographic network. It was necessary to develop a sampling network based on the hydrology of the region, the geology, the relief, slopes and land uses. Evrotas river basin was separated into seven sub-basins presented in Figure 5.3.2. The selection of the position of each sampling point was based on the typology of the basin (relief, slopes, geology, land use and point source maps - Figure 5.2.3) created using GIS. A brief description of the main characteristics of the sub-basins is following. Sub-basins‟ Description 1. Sub-basin 1 is at the north side of the basin and covers a portion of Parnonas Mountain. Main characteristics of the area include: i) existence of calcareous formations, ii) high altitude and iii) steep slopes 10–30%. The area is covered with natural vegetation, low agricultural activities and population density. 2. Sub-basin 2 covers the northwest part of the basin. At the west side of the region calcareous formations exist which recharge Evrotas springs. Main characteristics of the area include: i) medium altitudes (except in the west) and ii) medium to mild slopes. Nine settlements exist in the area. Main activities of the population include agriculture and livestock. The upper part of Evrotas exist dries during the summer. 3. Sub-basin 3, Inoundas is the largest sub-basin of Evrotas. This sub-basin is mainly covered by karst. Main environmental pressures come from livestock and from the few settlements. Some parts of Inoundas have permanent flow throughout the year. 4. Sub-basin 4 includes the largest portion of Taigetos Mountain. The area is characterised of high altitudes and steep slopes. The geology is mainly karst (intensively karstified). Karst formations are the most important aquifers of the region and are responsible for the creation of many springs. The springs of Tripi, Sotiros and Katagianni recharge important tributaries such as Magoulitsa and Kakari. 5. Sub-basin 5 is characterised of low altitudes and gentle slopes while alluvials are the main formations. Many tributaries exist in the area: Magoulitsa, Kakari, Gerakaris etc. The municipality of Sparta is included in this sub-busin. The environmental pressures are significant due to the existence of large towns, small industries and significant agricultural activities in the area. Final Report (Technical issue) – LIFE05 ENV/GR/00024 133/313 Environmental Friendly Technologies for Rural Development 6. Sub-basin 6 is the southeast part of Parnonas Mountain. Karstic formations are found in high altitude while in lower altitudes other types of geology exist. Environmental pressures on this area are not significant. The main stream is Mariorema. 7. Sub-busin 7 includes the regions of Skala, Elos and Githio as well as the Evrotas river estuaries. The sub-basin is under high environmental pressure due to intensive agricultural activities. In addition, a large number of olive mills exist in the region. The selection of the sampling points (SPs) was based on the understanding of the hydrology and hydrogeology of the region. Surface water sampling points were chosen throughout the length of the river. The majority of the ground water sampling points were selected to be in sub-basins 5 and 7 (Sparta and Skala regions), since many point sources of pollution exist and agricultural activities are extensive. Additionally, sub-basin 5 has many and important tributaries of Evrotas river. Finally, important groundwater aquifers are found in the region and the ground water is used for irrigation and water supply. Based on the above considerations the sampling network consisted of 64 sampling points: 32 for surface water (Map 5.3.1) and 32 for underground water (10 Springs, 10 Shallow Well, 12 Deep Wells- Map 5.3.2). Six sampling campaigns were conducted on: (1st) 9-12 of May 2006, (2nd) 8-12 of September 2006, (3rd) 12-17 of January 2007, (4th) 26 of May – 1 of June 2007, (5th) 26 September - 12 December 2007, (6th) 3-5 of March 2008. During those field campaigns psychochemical parameters of the samples were measured in situ while water samples were taken to the laboratory for chemical analysis. The water samples were analyzed using a Hack phasmatophotometer for Nitrate Nitrogen (NO3-N) (Cadmium Reduction Method, 8039), Nitrite Nitrogen (NO2-N) (Diazotization {Chromotropic Acid} Method, 8507), Ammonia (NH4-N) (Salicylicate Method, 10023), Dissolved Inorganic Phophorous (DIP) (PhosVer3 Method, 8048, Total Organic Carbon (TOC) (Direct Method, Low Range, 10129), Chemical Oxygen Demand (COD) (Low Range, 8048), phenols (Folin Ciocalteu method), selected heavy metals (Cu, Cd, Zn, Pb and Ni) (Anodic Stripping Voltammetry (ASV) -Trace Detect Nanoband Explorer) and pesticides. The physicochemical parameters pH, Eh, Dissolved Oxygen and conductivity were measured in situ using the following electrodes: Orion 9107 pH meter, Orion 081010 D.O. meter, and Orion 011050 Conductivity meter. Final Report (Technical issue) – LIFE05 ENV/GR/00024 134/313 Environmental Friendly Technologies for Rural Development PRIMARY LINE: DOCUMENTED LOSS OF CONTAMINANTS SECONDARY LINE: DOCUMENTED NA PROCESS THIRD LINE: DOCUMENTED MICROBIAL ACTIVITY Preliminaray Historical data Data by soil sampling Modeling Data from water sampling 1st Line of Evidence ETD and MONERIS Model 2nd Line of Evidence 3rd Line of Evidence Sampling Network Organisation of Sampling Campaigns Laboratory analysis Figure 5.3.1. Steps of MNA application in Evrotas river basin – Lines of evidence Final Report (Technical issue) – LIFE05 ENV/GR/00024 135/313 Environmental Friendly Technologies for Rural Development Figure 5.3.2. Sub-basins of Evrotas River Basin. Map 5.3.1. Sampling points of surface water. Final Report (Technical issue) – LIFE05 ENV/GR/00024 Figure 5.3.3. Main point pollution sources (Towns, olive mill and orange factories). Map 5.3.2. Sampling points of groundwater. 136/313 Environmental Friendly Technologies for Rural Development Evidences of Natural Attenuation in surface water Evrotas River samples were analyzed in order to evaluate the existence of natural attenuation. The sampling points along the river were: Pardali (8), Karavas (52), Sparta Bridge (53), Sparta Biological treatment (54), Skoura (22), Vrodamas Bidge (34), Palaiomonastiro (55) and Evrotas Estuaries (56). Figures 5.3.4 and 5.3.5 present the average concentrations of COD, phenols and nutrients along the river. The following observations can be made: The highest average COD concentration was found at Skoura (14 mg/L) and there was a significant attenuation after the peak. The COD value at the Estuary of Evrotas was below detection limit. The COD concentration decreased significantly due to in-stream attenuation processes and dilution from unpolluted tributaries. Figure 5.3.4. Average Concentration of COD along Evrotas River. The same trend existed for the other pollutants as well. The highest concentrations of NO2-N, NO3-N and Total phenols were also measured at Skoura with a significant attenuation observed downstream. Phosphates peaked close to the wastewater treatment plant of Sparta. This peak was due to the outflow of the treatment plant. Figure 5.3.5. Average values of the main pollutants along Evrotas River (mean value of six field campaigns). Tables 5.3.2 and 5.3.3 present the average values of physicochemical parameters and concentrations for the main pollutants namely COD, Ν-ΝΟ3-, Ρ-ΡΟ4-3 and total phenols for surface and ground waters of Evrotas River. Final Report (Technical issue) – LIFE05 ENV/GR/00024 137/313 Environmental Friendly Technologies for Rural Development Table 5.3.2. Mean Physicochemical Parameters Values and Concentration of Pollutants in Surface and Groundwater Samples. Deep Wells Shallow Wells Spring Surface Water s T (oC) pH DO (mg/L) Cond (μS/cm) Eh (mV) COD (mg/L) NO2-N (mg/L) NO3-N (mg/L) NH3-N (mg/L) PO4-P (mg/L) T.phenols (mg/L) Mean value 17.0 8.0 6.8 606.7 233.6 6.243 0.031 1.408 0.055 0.058 0.907 Standard Deviation 3.6 0.4 2.0 342.5 52.0 3.368 0.035 1.236 0.032 0.029 0.398 Mean value 16.7 7.3 6.4 624.9 240.3 3.998 0.004 2.776 0.043 0.087 0.842 Standard Deviation 2.9 0.4 2.8 285.4 75.0 0.517 0.001 4.258 0.022 0.079 0.446 Mean value 18.6 7.3 4.7 706.9 382.2 4.097 0.013 9.083 0.063 0.055 1.128 Standard Deviation 2.8 0.2 1.3 135.1 154.8 0.525 0.014 3.624 0.050 0.023 0.226 Mean value 18.5 7.3 5.1 583.1 283.7 3.943 0.005 5.980 0.042 0.163 0.433 Standard Deviation 3.3 0.3 1.1 456.9 252.2 0.365 0.002 11.872 0.019 0.093 0.285 Final Report (Technical issue) – LIFE05 ENV/GR/00024 138/313 Environmental Friendly Technologies for Rural Development Table 5.3.3. Average Values of the main pollutants along Evrotas River. 52 Karavas 54 WWTP Sparta 22 Skoura 34 Vrontamas 55 Paleo/ro 56 Estuary mean value 0.988 0.302 1.991 1.492 0.851 0.357 st. dev. 0.204 0.349 0.718 0.642 0.193 0.168 mean value 0.006 0.036 0.128 0.020 0.029 0.020 st. dev. 0.002 0.007 0.097 0.111 0.164 0.060 mean value 0.031 0.099 0.058 0.043 0.042 0.031 st. dev. 0.007 0.039 0.096 0.684 0.532 0.022 mean value 0.024 0.082 0.081 0.044 0.109 0.047 st. dev. 0.019 0.055 0.062 0.047 0.068 0.039 mean value 0.675 0.979 1.804 0.994 1.257 0.913 st. dev. 0.385 0.662 0.878 1.890 0.641 0.256 mean value st. dev. 9.203 3.750 15.130 7.439 bdl bdl 3.087 0.482 17.522 2.257 Station ID, Name NO3-N N-NO2 N-NΗ3 P-PO4 Tphenols COD Evidence of Natural Attenuation in Ground Water The main ground water aquifer is found in the plain of Sparta. Ten shallow ground water wells and twelve deep ground water wells have been sampled. Figure 5.3.6 presents the sampling points and the arrows illustrate the ground water movement. Sparta Platana Kefalas Figure 5.3.6. Shallow and Deep Wells at Sparta Plain. Final Report (Technical issue) – LIFE05 ENV/GR/00024 139/313 Environmental Friendly Technologies for Rural Development The following observations can be made: The average nitrate concentrations of the shallow wells 41 and 38 was reduced from 14.5 mg/L to 9 mg/L. In addition following ground water direction for shallow wells 46 to 37, a similar reduction for nitrates was taking place (13.1 mg/L to 12.6 mg/L). Nitrates reduction was also observed from the spring of Peristeri, 13.7 mg/L to shallow well 37, 12.6 mg/L. The results indicated that high nitrate concentrations were found in the Sparta aquifer and they were being attenuated as the water moved towards the area of Vrodamas. Total phenols concentration of shallow well 41 was 1.5 mg/L and the concentration of well 38 decreased to 1.2 mg/L. Similar reductions were observed for shallow wells 46 and 37. The COD and nitrate nitrogen concentrations of ground water deep wells indicated that the pollution load was attenuated along the ground water flow. The concentrations of COD and nitrate nitrogen of groundwater deep wells of SPs 12, 13, 14, 18 and 20-b were higher than those of SPs 16 και 17 despite the fact that there were many villages and significant agricultural activities taking place in the region. These results provide evidence of natural attenuation in groundwater. Analysis for Heavy Metals - Five heavy metals were analyzed (Cu, Cd, Zn, Pb and Ni) for 12 surface and ground water samples to examine potential pollution. The analyses were conducted using Anodic Striping Voltametry at the Technical University of Crete with a Detection Limit of 5 ppb for all metals. Table 5.3.4 presents the results that were detected in the samples. The concentrations were Below Detection Limit (BDL) for Cu, Cd, and Ni for all samples. Only two samples had detectable Pb concentrations which were below the Maximum Contaminant Level (MCL) as proposed by EPA for drinking water. Finally, all samples had Zn concentrations above the detection limit, but below the National Secondary Drinking Water Regulations (NSDWRs or secondary standards) as proposed by EPA for drinking water. In general, the results suggest that either there is little heavy metal pollution (the metals measured only) or the metals are being retained well in the environment and do not appear in the aquatic phase. Table 5.3.4. Average concentration of heavy metals in surface water, springs, shallow and deep well groundwater (BDL= 5 ppb). Pb (ppb) MCL(1) = 15 ppb Zn (ppb) NSDWRs(2) = 5.000 ppb Mean SD n Mean SD n Surface Water BDL - 6 19 19 6 Springs BDL - 1 8 - 1 Shallow groundwater 6 - 1 27 12 3 Deep groundwater 9 - 1 21 23 2 (1) EPA, 2006: Maximum Contaminant Level (MCL): The highest level of a contaminant that is allowed in drinking water. MCLs are enforceable standards. Final Report (Technical issue) – LIFE05 ENV/GR/00024 140/313 Environmental Friendly Technologies for Rural Development (2) EPA, 2006: National Secondary Drinking Water Regulations (NSDWRs) or secondary standards are nonenforceable guidelines regulating contaminants that may cause cosmetic effects (such as skin or tooth discoloration) or aesthetic effects (such as taste, odor, or color) in drinking water. EPA recommends secondary standards to water systems but does not require systems to comply. However, they can be adopted as enforceable standards. Analysis for Pesticides - Analysis for pesticides was conducted by the Laboratory of Aquatic Chemistry, Department of Environmental Engineering at the Technical University of Crete. Samples were taken at the (1st) 9-12 of May 2006 and (4th) 26 of May – 1 of June 2007, sampling campaigns in order to determine pesticides residues in water samples. Target compounds included: 1.Azinphos-ethyl, 2.Diazinon, 3.Dicofol, 4. Propargite, 5. Captan, 6. Amitrol, 7. Alachlor, 8.Malathion Parathion methyl Endosulfan, 15. (pestanal), 9. Fenthion (pestanal), 10. (pestanal), 11.Chloropyriphos, 12. Simazin, 13.B-Endosulfan, 14. A– Atrazin and 16.PAHs. Solid phase microextraction (Solid Phase Microextraction SPME) was used as a selective and sensitive tool for preconcentrating hydrophobic organic pollutants. For SPME, a 5 ml aqueous sample, withdrawn from the reaction vessel, was added in a 7 ml clear glass vial (Supelco), fitted with aluminium foil and screw caps with hole (Supelco). Extraction was performed at room temperature and under intensive magnetic stirring (1250 rpm) using a glass-coated mini-impeller (8 mm x 3 mm). The 100-μm polydimethylsiloxane (PDMS) SPME fibre type and SPME fibre holder assembly (all purchased from Supelco) were used for extraction. Before the first usage, the fibre was conditioned according to the manufacturer‘s recommendations. Three blank runs were run to verify the absence of impurities and phthalate peaks on the SPME fibre. Each day and prior to extracting any samples, the fibre was immersed for few minutes in a stirred acetonitrile solution, and a blank analysis was then run as to ensure that the fibre was free of contaminants. For extraction, the SPME fibre holder assembly was clamped and allowed to sit on top of the 7-ml glass vials containing the 5-ml samples. The SPME fibre was exposed to the aqueous phase and after sampling for 45 min at room temperature, the fibre was retracted and transferred to the heated injection port of the GC-MS for desorption, where it remained for 5 min. The analysis in a Gas Chromatographer coupled of with a Mass Spectrometer gives the possibility to use an organic substances‘ identification library (internationally acknowledged). Consequently, it is possible to determine the organic substances that are in solution. GC-MS analysis was effectuated using a Shimadzu GC-17A QP-5050A gas chromatographmass spectrometer system. The split/splitless injector operated at 260C with the split closed for 5 min. Helium (> 99.999% pure) was used as the carrier gas at a flow-rate of 1.2 ml min-1. The instrument was equipped with a 30 m 0.25 mm, 0.25 μm HP-5MS capillary column (Agilent Technologies). The column oven was programmed as follows: 70C for 2 min and then to 180C at a rate of 10C min-1, and finally to 300C at a rate of 5C where it was held for 5 min. The interface temperature was set at 310C and the detector voltage at 1.40 kV. The ionization mode was electron impact (70 eV). Data was acquired in the fullscan detection mode from 50 to 465 amu at rate of 0.5 scan sec -1. Standard solutions of the aforementioned compounds were analysed in order to verify the presence of these pollutants based on their mass spectra as well as retention times. A similarity index > 90 % was used for identifying the presence of a compound. The presence of hydrophobic organic Final Report (Technical issue) – LIFE05 ENV/GR/00024 141/313 Environmental Friendly Technologies for Rural Development compounds could not be confirmed nor detected under the present experimental conditions for the samples analyzed. Overall, significant attenuation of pollutants was observed in the Evrotas river basin both for surface and ground water. Organic pollution was originated mostly from point sources and impacted the surface water (6.2 mg/L COD) as opposed the ground water (springs about 4 mg/L COD). Nitrates-N pollution impacted more the ground water (9 mg/L in shallow wells) and it was attenuated to 1.4 mg/L by the time it reached the surface water. Nitrates have impacted significantly the deep wells with average concentration of approximately 6 mg/L and a standard deviation of 12 mg/L. Phosphate-P was highest at the deep wells (0.163 mg/L) and it decreased to 0.087 mg/L at the springs and 0.055 mg/L at the shallow wells and surface water. The results suggest intense agricultural activities have impacted historically the deep ground water wells while recent practices have improved the water quality (lower concentration in shallow wells). Second step: Modeling evidence Evrotas river basin modelling – MNA evaluation Evrotas River is a complicated hydrologic system that drains an area of 2420 km2, 50% of which is covered by limestone-karstic formations. The mountains of Taygetos and Parnonas, reaching an elevation of 2404m, affect drastically its hydrologic patterns. Modeling of the hydrology and nutrient emissions of the watershed was accomplished using the WMP-Med (Watershed Modeling Platform –Mediterranean) which is comprised of the Karstic Model and the ETD (Enhanced Trickle Down) Model (Nikolaidis et al., 1988, 1989, 1991, 1993 and 1994) and the model MONERIS (Behrendt, 1999). To simulate the hydrology of the watershed, it was subdivided into 6 subcatchments (NE Taygetos, NW Parnonas, NW Parnonas, Central Taygetos, Skalas and Gytheiou) presented in Figure 5.3.7. The simulation period was 2000-2007 (8 years long). The hydrologic simulation results for the Vivari station (NE Taygetos subcatchment), the Kelefina station (NW parnonas) and Vrontamas station (Central Taygetos) are presented in Figure 5.3.8. The WMP-Med model was able to capture the seasonal and inteannual variability of the flow very well. The correlation coefficient between the simulated and field data was between 0.92 and 0.84 and the Nash Sutcliffe efficiency was between 0.61 and 0.68. The mean error in the annual flows was less than 10%. The annual average hydrologic balance of Evrotas River was as follows: 3 the precipitation 3 was 1048 Mm , the karstic discharge 330 Mm , the evaporation was 727 Mm3, stream discharge was 133 Mm3, stream withdrawals were 16 Mm3, and the change of storage in the watershed was 38 Mm3. The annual irrigation needs of the watershed were estimated at 174 Mm3 based on typical irrigation plant requirements for the region. These irrigation needs were used in the model simulations. However, the real irrigation use was not known since there are more than 3500 public and private wells in the watershed, none of which water Final Report (Technical issue) – LIFE05 ENV/GR/00024 142/313 Environmental Friendly Technologies for Rural Development consumption has been monitored. The model estimated that irrigation was underestimated by 337 Mm3. The modeling results suggest that on the average irrigation used 3 times more water than the recommended values. The results from the hydrologic simulation were used as inputs in the MONERIS model. The model, Modelling Nutrient Emissions into River Systems, MONERIS (Behrendt et al., 1999) was developed to simulate nutrient inputs into river basins of Germany by various points and diffuse sources. The model uses river flow and water quality data in a geographical information system (GIS) framework to develop the equations that estimate nutrient export loads in the river. Six diffuse pathways and point source emissions are modelled. The diffuse pathways modelled are: atmospheric deposition, erosion, surface runoff, groundwater, tile drainage, and paved urban areas. Point source emissions are from wastewater treatment plants and direct industrial discharges. Point emissions are directly discharged into the rivers. Diffuse emissions into surface waters are the sum of different pathways. Transformation and retention processes necessary to quantify and predict nutrient emissions are included in the model in relation to their sources. MONERIS equations of the various pathways are developed especially for the modelling of medium to large-scale watersheds. The model incorporates the following seven subroutines. 1. A GIS framework for regional estimation of diffuse and point emissions for large river basins (larger than 500 km2). 2. A submodel for regionally differentiated estimation of nutrient discharges from wastewater treatment plants. 3. A submodel that calculates input of nutrients and suspended solids by erosion (based on a modified uniform soil loss equation). 4. A submodel for the estimation of groundwater nitrogen concentrations in agricultural areas. The model has a retention function that depends on hydrogeological conditions, the rate of groundwater recharge and nitrogen surplus. 5. A GIS-submodel for nutrient emissions from agricultural areas modified by tile drainage. 6. A submodel for nutrient emissions from urban areas. The model considers regional differences in sewer systems and development of storage volume for combined sewer systems. 7. Finally, there is a submodel for nutrient retention and losses in surface waters (based on nutrient retention, the hydraulic load or the specific runoff in the river system). The MONERIS model was used for the simulation of nutrient emissions from Evrotas river basin. The model calibration was achieved by changing parameters such as phosphorous atmospheric deposition (0.99 kg/ha-yr) and inhabitant specific Phosphorous output factor (1.8 g/inhabitant-day). The dissolved inorganic nitrogen loads used for the calibration were 97 tn-N/yr in Selasia, 133 tn-N/yr in Sparta, 375 tn-N/yr in Vrontama and 413 tn-N/yr in Tafros Omega. Figure 5.3.7 presents a comparison between measured and modeled nitrogen Final Report (Technical issue) – LIFE05 ENV/GR/00024 143/313 Environmental Friendly Technologies for Rural Development emission loads. The highest fluxes of nitrogen originated from the delta area (47.8%), followed by groundwater (24.7%), urban areas (13.9%) and point sources (8.6%). On the other hand, the highest fluxes of phosphorous originated from point sources (72.3%), followed by erosion (10.1%) and the delta area (7.8%). The total nitrogen emissions were estimated to be 1092 t/y which corresponded to 4.5% of the total Nitrogen input (24539 tn/yr) and the total phosphorous emission loads were 179.2 t/yr which corresponded to and 2% of the total Phosphorous input (9896 tn/yr) (Table 5.3.5). The modeling exercise quantified the reduction of nutrient loads in Evrotas watershed by natural attaenuation mechanisms. Figure 5.3.7. Sub-catchements of Evrotas river basin. Final Report (Technical issue) – LIFE05 ENV/GR/00024 144/313 Environmental Friendly Technologies for Rural Development Figure 5.3.8. Evrotas river hydrologic simulation results using the WMP-Med model for the period of 2000-2007. Figure 5.3.9. Results of Evrotas modeling Comparison Dissolved Inorganic Nitrogen model and field. Final Report (Technical issue) – LIFE05 ENV/GR/00024 145/313 Environmental Friendly Technologies for Rural Development Table 5.3.5. Nutrients emissions estimated by MONERIS model for Evrotas basin Total emissions and proportion of the different pathways nitrogen phosophorus [t/a] [%] [t/a] [%] atmospheric deposition 5,2 0,5 1,0 0,5 Delta drainage 522,5 47,8 14,0 7,8 groundwater 269,4 24,7 6,8 3,8 overland flow 7,1 0,6 0,8 0,4 erosion 38,2 3,5 18,2 10,1 WWTP(Point Sources) 94,1 8,6 129,6 72,3 In-stream Secondary Sources 3,8 0,3 urban systems (total) 152,1 13,9 8,8 4,9 total emissions 1092,3 100,0 179,2 100,0 Third step: Laboratory evidence The main objective of this phase was the quantification of the biogeochemical processes operating at the watershed. The processes were studied using mesocosm and microcosm laboratory experiments in order to quantify the kinetic rates of the processes that take place and result in the attenuation of pollutants by the soils. A soil sampling network was designed to cover most of the soil types found in Evrotas river basin. In Evrotas river basin 11 soil types are found according to the Greece soil map (1:1.000.000, 1967), 6 of those cover 94% of the watershed area. The location of the soil sampling was near the riparian zone of the Evrotas river. Riparian zone are areas where ground water interacts with surface water and active attenuation processes take place. Sampling took place in November 2007. Nine surface sediment samples (0-10 cm) and ten cores (50 cm depth) from 11 different locations were obtained. Figure 5.3.10 presents the locations of the soil sampling network. Figure 5.3.11 presents photos taken during the sampling campaign. Soils and sediment samples were analysed for their physicochemical charactaristics (pH, water content, porosity, dry bulk density, grain size distribution) (Method ISO 11277:1998 + Corr. 1:2002 (without destruction of carbonates)), metal determination (XRF), Total Kjeldahl Nitrogen (Nessler Method, 8075) and Total Organic Carbon (Walkley Black Method). Release kinetic experiment was conducted in the laboratory in order to study the rate of release of nutrients and phenols from the sediment. The experiment was carried out in 100 ml bottles using 2.5g of sediment samples (< 2 mm fraction), 2.5g sand (fraction 0.5-2 mm) and adding 100 ml synthetic river water as release solution. The release solution composition had similar geochemistry to Evrotas river water in Skoura (without nutrients): KCl 0.056 mM, MgSO4*7H20 0.893 mM, Na(HCO3) 2.522 mM, CaF2 2.545, HCl 2.5 mM. The pH of the solution was regulated 7.7 (by adding HCl 1.2 mM) and the ionic strength 1.2 mM. All samples were placed on a shaking table at 20oC. The samples were analyzed in duplicate at 12 hours, one day and one sample every day for 22 days. The supernatant was filtered through a 0.45 μm Nylon filter and analyzed using a Hack spectrophotometer 2010 for TOC (Direct Method Patent Pending, 10129), COD (COD Reactor Digestion Method), NH3-N (Salicylicate Method, 10023), NO3-N (Cadmium Final Report (Technical issue) – LIFE05 ENV/GR/00024 Reduction Method, 8039), NO2-N 146/313 Environmental Friendly Technologies for Rural Development (Diazotization Method, 8507), Total Nitrogen (TNT Persulfate Digestion Method, 10071) and phenols (Folin Ciocalteu). Similarly sorption experiments were conducted in order to study the kinetics of phosphate sorption in the sediment in relation to the temperature variation. For the experiments 5g of soil were added in 100 ml flasks that were then filled up to 100 ml synthetic river water as release solution; the initial aqueous phosphate-P concentration was 1.0 mg/L P. The experiments were conducted at 20 oC at pH value 8.0. The samples were analyzed in triplicate at 1, 2, 3, 4 days. The supernatant was filtered through a 0.45 µm Nylon filter and analyzed using a Hack spectrophotometer for Dissolved Inorganic Phosphorous (DIP) (PhosVer3 Method, 8048). Figure 5.3.12 presents the chemical characteristics of selected Evrotas soils. The total Nitrogen content ranged from 0.63 up to 1.99 g/kg and organic matter from 0.46 up to 2.36%. The soil pH ranges from 7.87 up to 8.41 and Electrical Conductivity from 587 up to 1075 μS/cm. Two soils (9A and 9B) were used to study the long term release of nitrogen species from the sediments (Figure 5.3.13). A release of organic N, ammonium N and nitrate N was observed in both soils. The released concentrations of organic N ranged between 4 to 9 mg/L, for ammonium N ranged between 0.4 to no detect and nitrate N ranged between 0.2 to 1.4 mg/L for soil 9A. The respective concentration ranges for soil 9B were 10-25 mg/L for organic N, 2 to no detect for ammonium N and no detect to 8 mg/L for nitrate N. Ammonium N was converted to nitrate N within a few days. The results between the two soils exhibited high variability due to variation in their oxidation-reduction capacity. DON reached a constant partitioning with the sediment bound organic nitrogen within 5 days. The DON concentrations at equilibrium were 8 and 11 mg/L for the two sediments respectively. Ammonia N was lost within 6 days and nitrate N followed a release and dissapperance cycle that lasted between 12 and 14 days. It is hypothesized that organic N is mineralized to ammonia and nitrate. Nitrate reached a maximum dissolved concentration after 6-10 days since the commencement of the experiment and then it dissappeared presumably due to denitrification. Nitrogen removal was most intense in sample 9B compared to 9A due to higher reduction capacity. Final Report (Technical issue) – LIFE05 ENV/GR/00024 147/313 Environmental Friendly Technologies for Rural Development Figure 5.3.10. Soil Sampling Network in Evrotas river basin. Final Report (Technical issue) – LIFE05 ENV/GR/00024 148/313 Environmental Friendly Technologies for Rural Development Vathirema Vivari Vrontamas bridge Vivari Karavas Sparta Paleomonastiro Figure 5.3.11. Images from the soil sampling campaign of November 2007. Final Report (Technical issue) – LIFE05 ENV/GR/00024 149/313 Environmental Friendly Technologies for Rural Development Figure 5.3.12. Total Nitrogen, pH, Electrical Conductivity and Organic Matter content of Evrotas soils. To better understand the nitrate loss due to denitrification, an experiment was performed using sediment sample 5 by spiking the solution with 5 mg/L of nitrate N. Figure 5.3.14 presents the evolution of the concentrations of Nitrate-N and Ammonia-N in time. Only 3 out of the 5 mg/L nitrate N were measured in solution at steady state while ammonia N concentrations were not different between the spiked and the non spiked samples. The results suggest that the denitrification process is active and that it reaches steady state within 4 days. Figure 5.3.15 presents the phosphate sorption kinetic rates for samples 9A and 9B. The phosphate sorption kinetic rates were estimated to be 0.19/d and 0.11/d respectively. Soil 9A is behaving as phosphate sink, since its EPC0 is less than 0.1 mg/L. In contrary Soil 9B is behaving as phosphate source (EPC0>0.1 mg/L). Similar phosphate sorption kinetics were found in 7 other sediment samples. The results are presented graphically in Figure 5.3.16 and in tabular form in Table 5.3.6. The phosphate sorption kinetic rates ranged between 0.16/d and 0.32/d. Table 5.3.6 presents the half life of the reaction and the time to reach 95% of steady state. The half life of phospahte sorption ranged between 2 and 4 days and the time to reach 95% steady state ranged between 9 and 19 days. Soils with high organic matter content had higher phosphate sorption capacity. The vertical variability of soil characteristics were examined using soil cores. The cores (50 cm length) were split into two parts (2/3 and 1/3 from the top) and were analyzed for electrical conductivity, pH, organic carbon and total nitrogen. The results are presented in Table 5.3.7. The electrical conductivity ranged between 253 and 1047 Final Report (Technical issue) – LIFE05 ENV/GR/00024 150/313 Environmental Friendly Technologies for Rural Development μS/cm, the pH between 7.66 and 7.99, the organic carbon between 0.5 and 5.7% and total nitrogen between 0.12 and 0.37%. Figure 5.3.17 presents the results of the phosphate kinetic sorption experiment. The estimated sorption rates are presented in Table 5.3.7. The rates ranged between 0.23 and 0.55/d. In general, the results showed lower concentrations of organic carbon, TN and sorption rate with depth. Figure 5.3.13. Nutrient release (Nitrate-N and Dissolved Organic Nitrogen and Ammonia-N) from soils 9A and 9B (Paleomonastiro). Final Report (Technical issue) – LIFE05 ENV/GR/00024 151/313 Environmental Friendly Technologies for Rural Development Figure 5.3.14. Release of Nitrate and ammonia with and without the addition of 5 mg/L Nitrate-N (sample 5). Figure 5.3.15. Phosphate sorption kinetic experiments for soils 9A and 9B. Figure 5.3.14. Phosphate sorption kinetic experiments of Evrotas riparian soils. Table 5.3.6. Phosphate sorption rates. 1 5 t50% (days) 4.0 3.14 t95% (days) 18.16 13.56 -K (1/d) 0.17 0.22 6 4.44 19.20 0.16 8 2.19 9.49 0.32 10 2.88 12.44 0.24 11 2.67 11.55 0.26 12 3.49 15.10 0.20 Soil Table 5.3.7. Physicochemical and chemical characteristics of soil samples in different depths. Soil Electrical Conductivity (μS/cm) pH C/N Organic Carbon (%) TN (%) Sorption rate constant (-k) 2Α1+2 676 7.99 4.658 0.961 0.120 0.2814 2Α3 898 7.77 6.091 1.509 0.144 0.5069 31+2 586 7.70 5.273 1.475 0.162 0.2408 354 7.89 2.389 0.549 0.133 0.227 253 7.66 8.839 5.660 0.371 0.539 1047 7.87 4.556 1.818 0.231 0.4471 3 3 41+2 4 3 Final Report (Technical issue) – LIFE05 ENV/GR/00024 152/313 Environmental Friendly Technologies for Rural Development 7Α1+2 397 7.91 6.241 2.161 0.201 0.343 7Α3 449 7.93 4.236 1.132 0.155 0.3802 Figure 5.3.17. Phosphate sorption kinetic experiments of Evrotas riparian soils in different depths. Table 5.3.8 presents the organic nitrogen mineralization potential and partitioning of 7 Evrotas soils. The mineralization potential was estimated as the difference in ammonia concentration in solution in one week minus the ammonia concentration of the leachate in one hour. The PMN ranged from 0.13 to 3.29 mg/Kg and the partitioning coefficient from 664 to 13433 ml/g. Organic nitrogen was tightly adhering to the soil and the retardation factor (ratio of the velocity of the water to the velocity of the chemical) was between 2500 and 50000. Table 5.3.8. Mineralization rates of Evrotas soils. Soil Nitrogen Mineralization Potential -PMN (mg/kg) Kd (ml/g) 1 3.17 664 5 2.36 1078 6 0.13 13433 8 3.29 751 10 0.29 6518 11 0.54 4069 12 0.47 4266 In general, soils in Evrotas appear to have significant mineralization, nitrification and phosphate sorption capacities to attenuate nutrients originating from agricultural activities. Final Report (Technical issue) – LIFE05 ENV/GR/00024 153/313 Environmental Friendly Technologies for Rural Development Conclusion The three steps of MNA implementation have been completed providing sufficient and documented evidence that mechanisms of natural attenuation operate at the Evrotas River Basin. The attenuation of nitrogen and phosphorous were quantified using an emission based model, MONERIS. 95.5% of the nitrogen and 98% of phosphorous were attenuated with the watershed. The nitrogen and phosphorous emissions to the coastal zone were 1092 tn/yr and 179 tn/yr, respectively. Organic nitrogen mineralization, nitrification, denitrification and phosphate sorption were studied in the laboratory using soil samples. Kinetic rates of the processes that control nitrogen and phosphorous attenuation were quantified in order to be guaranteed that these processes will operate long term. The results indicated that significant attenuation of nitrogen and phosphorous exist in the watershed and that MNA is a viable remedial measure for the watershed. Final Report (Technical issue) – LIFE05 ENV/GR/00024 154/313 Environmental Friendly Technologies for Rural Development 2. Water Management in Evrotas River Basin Introduction The water management in Evrotas river basin focuses on a) the assessment of the spatiotemporal hydrogeological and hydrogeochemical regime of Evrotas River in order to estimate the impacts of water management and pollution, b) the establishment of type specific reference conditions and the classification of running waters using chemical and biological components (according to the demands of the Water Framework Directive 2000/60/EC, WFD) in order to assist sustainable management plans and c) the drafting of conservation schemes for the endangered fish species of the Evrotas River based on assessments of their ecological requirements. In addition, the hydromorphological features and the riparian vegetation of the river courses (not included in the project‘s proposal) were evaluated, since Evrotas is subjected to several hydromorphological pressures. Based on historical data assembled, the river used to be famous for its lowland riparian forests, which are now rare, extremely threatened and barely studied in the Balkan region. Hence, this effort aimed in identifying the dominant pressures and assessing the impacts on the hydrological and hydrochemical regime and on the ecological status of the Evrotas basin, using hydromorphological, chemical and biological (fish and macroinvertebrates) quality elements, and finally in identifying the status of riparian vegetation, thus providing more details on morphological alterations. Historically, the vast majority of the Evrotas hydrological network retained water throughout the year. Nowadays, as a result of intense hydromorphological modifications mainly for agricultural purposes, most of the main course of Evrotas River and its tributaries dessicate during the dry period (see 2.D3 deliverable). The WFD does not particularly addresses temporary rivers, although they are dominant in the Mediterranean area for reasons related to both climatic and anthropogenic factors. Temporary rivers are barely monitored and little is known regarding their hydrology, ecology and biogeochemical behaviour (Jacobson et al., 2004). Prior to EnviFriendly, Evrotas was marginally monitored for hydrological and hydrochemical features and only barely surveyed regarding ecological aspects. In view of the temporal character of the river and scarcely existing hydrological, physicochemical and ecological data, our task was particularly ambitious. In order to improve the assessment of ecological status, fishbased metrics were developed and applied for respective classifications. This effort significantly assisted the assessment of hydromorphological impacts on the biological status of the river. Methodology For the study of the hydrological regime of Evrotas main course, seven automatic water level recording stations were installed. Data from these stations together with the wetted cross section were used for the calculation of daily water discharge. The characterisation of river types, the establishment of reference conditions and the classification of the ecological status of Evrotas River Basin was based on hydromorphological, physicochemical and biological (macroinvertebrates and fish) quality elements. Phytoplankton is not abundant in small rivers like Evrotas, whereas aquatic macrophytes are restricted Final Report (Technical issue) – LIFE05 ENV/GR/00024 155/313 Environmental Friendly Technologies for Rural Development only along the main course of the river. Hence, these quality elements were not included in the assessment system. A sampling network of 43 stations was established along the Evrotas main course and many of its tributaries for monitoring hydromorphological, physico-chemical and biological (macroinvertebrates) quality elements. For the ichtyological investigation 66 stations were selected mainly along the Evrotas main stem and along the Oinous tributary. The differentiation of the two sampling networks was established for the following reasons: a) fish communities are absent or significantly restricted in the vast majority of Evrotas tributaries, as a result of frequent desiccation due to water abstractions, b) for the development of fish-based metrics for status classification purposes, the most appropriate sampling season is summer, when extended river reaches get dry, and c) macroinvertebrate communities are more suitable for assessing pollution impacts, while fish communities are better indicators of hydro-morphological alterations. Monitoring of hydromorphological quality elements took place in summer 2006. Hydrochemical and macroinvertebrate sampling was performed at three seasonal periods (May 2006, September 2006, March 2007). In addition, six stations were monitored in a monthly base in the period February 2007 – March 2008 for hydrochemical parameters. For the ichtyological investigations, six sampling campaigns at high and low flow periods (spring and summer) were conducted during the years 2006-2008. At each station, physico-chemical variables (temperature, conductivity, pH, Eh, dissolved oxygen, current velocity and estimation of the wetted cross section) were measured in-situ with portable instruments. Water samples were analysed for hydrochemical variables (total hardness, Ca2+, Mg2+, Na+, K+, HCO3-, CO32-, Cl-, SO42-and SiO2) and conventional pollutants (nitrate, ammonia, nitrite, total nitrogen, orthophosphate and total phosphorous). Sediment samples were analysed for major elements, heavy metals, organic carbon, total carbon, total nitrogen, organic and inorganic phosphorous. In selected sites, pesticide residues were determined in water and sediments. Finally, acute toxicity tests were performed to evaluate the toxicity of olive mill and fruit juice processing wastewaters. The classification of the physico-chemical status (within the frame of the ecological status) was carried out, using water and sediment criteria, according to the guidelines of ECOSTAT and Skoulikidis (2008) and by averaging the results of the seasonal samplings. Two groups of chemical quality parameters, related to particular types of pressures, were identified: a) dissolved oxygen, ammonia, nitrite, that point to ―organic pollution‖ and b) nitrate, phosphate, heavy metals and pesticides (when available), that indicate ―chemical pollution‖. The quality scores of individual chemical quality parameters (e.g. dissolved oxygen, nutrients, etc.) were achieved by comparing their levels with existing classification systems or appropriate modified quality standards. The status of each group of parameters was carried out by averaging the quality scores of the individual parameters. Finally, the chemical status of each site was derived by the results of the group of parameters that indicated the greater impact. The morphological, hydrological, hydrochemical and vegetational characteristics of the river bed and river banks were rapidly assessed at a distance of 500 m upstream and downstream of each sampling site with the use of the AQEM/STAR protocol (AQEM Consortium, 2002). Hydro-morphological analysis was performed at a 500 m length of Final Report (Technical issue) – LIFE05 ENV/GR/00024 156/313 Environmental Friendly Technologies for Rural Development each site with the use of the River Habitat Survey (RHS) method (Raven et al., 1997). The RHS method assesses the natural character and quality of river habitats based on two metric systems, the Habitat Quality Assessment (HQA) and the degree of habitat modification (Habitat Modification Sore, HMS). The HQA assesses the quality of habitat in terms of its diversity. The HMS assesses the degree of river degradation. For the HMS classification, the six initial HMS categories were merged into five (Skoulikidis, 2008). For the collection of benthic macroinvertebrates, the STAR-AQEM (AQEM Consortium, 2002) sampling methodology was applied. To assess and classify the biological status of Evrotas River Basin using macroinvertebrates, the following procedure was performed: a) typological classification according to the Intercalibration Exercise (EC, 2007), b) definition and establishment of type specific reference conditions (AQEM Consortium, 2002; REFCOND, 2003) and c) assessment and classification of biological status using the STAR ICMi multimetric index (Buffagni et al., 2007). The final classification of benthic invertebrate status was performed by averaging the results of the seasonal samplings. The ichthyological investigation had a three-fold objective: a) to determine the fish species composition and abundance in the river basin, b) to assess the structure and quality of fish habitats in relation to the ecological requirements of fish (with special focus on endangered endemic species) and c) to develop/apply a fish-based method for biological quality assessment and classification. Ichthyological sampling was conducted by electrofishing using standardised methods as developed in the EU FAME project (2005). For the assessment and classification of the biological status of the river using fish fauna, the following key stages were carried out: a) development of a biotic (bottom-up) typological approach with the aim to (i) establish biotic river types defining areas of ichthyological homogeneity, using statistical clustering techniques, and (ii) describe the abiotic conditions which are responsible for the structuring of the fish assemblages in each type. b) Establishment of type-specific reference conditions, which were mainly based on the expert judgment technique (data from ‗near reference‘ sites and previous ichthyological research in this area were combined with data on the biology and habitat requirements of the local species and historical information concerning the distribution of the species in the basin). c) Selection of appropriate metrics for each biotic type using expert judgment, having as main criteria the capacity of the potential metrics to express structural and functional characteristics of the fish assemblages, and their ability to describe the environmental degradation resulting from human activities (responsiveness to impacts). d) Calibration of the metrics to a five class scale and their combination in a multiparametric index. The class boundaries were set following instructions given in Annex IV of the WFD. For the classification of the ecological status, the guidelines of ECOSTAT were considered. Thus, hydromorphological quality elements were taken into account when assigning water bodies to high ecological status, physico-chemical quality elements were considered when assigning water bodies to high and good status and biological quality Final Report (Technical issue) – LIFE05 ENV/GR/00024 157/313 Environmental Friendly Technologies for Rural Development elements when assigning water bodies to any of the ecological status classes. For common sites, the ecological status was assessed with the whole set of quality elements (including fish). Results and Discussion Natural and anthropogenic characteristics of Evrotas River Basin Evrotas River is well known from the ancient history and mythology of Greece, mainly from the mighty city of Sparta, which is located near the banks of the river. It is located in south-eastern Peloponnesus in the Prefectures of Laconia and Arcadia covering an area of 2,418 km2, and discharges into the Laconic Gulf after crossing 90 km of semimountainous areas and floodplains. The Evrotas River Basin expands between the mountain complexes of Taygetos and Parnon, where numerous permanent, ephemeral and intermittent streams discharge into the main course, such as the Oinous (its main tributary), Magoulitsa, Vrysiotiko, Kastaniotiko, Vathyrema, Yerakaris and Mariorema. The mountainous area of the basin is formed by Mesozoic-Palaeogene limestones (42% of the basin) and impermeable rocks, such as flysch and schists (29% of the basin), while the lower parts are covered by Pliocene and Quaternary sediments. The basin of Evrotas has a typical Mediterranean climate with mild and cold winters and prolonged hot and dry summers with an average annual temperature of 16 oC. The majority of rainfall occurs during the months of October through March; highest rainfall precipitation being on December and the driest on June. The mountainous region is characterised by heavy winters, large temperature fluctuations between the hot and cold period and also between the day and night. The Evrotas River has a flashy hydrological regime and presents nowadays temporary flow characteristics. From an ecological point of view, the Evrotas basin is a unique conservation hotspot in Greece, with a high biodiversity, including many local endemic plants and vertebrates. This high proportion of endemicity is attributed to the complex geological and climatic history of the area which, combined with geographical isolation and environmental diversification, have provided conditions conducive to speciation. Some of the natural aquatic environments and riparian formations occurring in the basin are indeed rare in the thermo-bioclimatic zone of southern Greece. These relatively rare environments include large karstic sources, riparian forests, riparian swaps, inaccessible canyons and ravines, deltaic systems and estuaries. The river accommodates five native freshwater fish species plus two that have been introduced. Three of the native species are rangerestricted endemics of high conservation value: Squalius keadicus (Stephanidis, 1971) and Pelasgus laconicus (Kottelat & Barbieri, 2004), which are confined exclusively to this river, and Tropidophoxinelus Spartaaticus (Schmidt-Ries, 1943), which also occurs in some rivers of southern Peloponnese. The native fish fauna also includes the species Anguilla anguilla (eel), which is widely distributed in Europe, and the perimediterranean Salaria fluviatilis. In addition, Evrotas basin accomodates several unique macroinvertabrate species such as the gastropod Melanopsis praemorsa which was recorded for the first time in the Greek mainland (Gritzalis, 2009). The vast majority of the river basin is covered by natural and semi-natural areas accounting for 61% of the total river basin, followed by agricultural areas that account Final Report (Technical issue) – LIFE05 ENV/GR/00024 158/313 Environmental Friendly Technologies for Rural Development for 38% (919 km2), while urban areas account for 1%. The main cultivations are olive groves and orange trees, which cover ~90% of the agricultural land, and make Laconia one of the main and largest producers of olive oil and orange juice in Greece. To increase and protect their crops, farmers apply high quantities of fertilizers and pesticides, which are significant diffuse pollution sources. Solid and liquid wastes from municipalities and from agro-industrial units comprise the most important point pollution sources in the basin. Only one Waste Water Treatment Plant (WWTP) operates (occasionally not sufficiently) in the basin, for the municipality of Sparta, while the rest of the area is served by cesspools (permeable and impermeable) thus threatening water bodies. Many small illegal and uncontrolled landfills are located in steep slopes, canyons and even inside forests. These sites are sources of atmospheric and aquatic pollution, but also may cause fires during high temperatures. In August 2007, a series of draught waves caused wild fires that burned 216 Km2, mainly at Parnon Mt. Olive oil mills (79 in total) operate seasonally (November-March) and discharge their effluents usually untreated in small streams or directly into the Evrotas River thus causing severe adverse effects on the aquatic ecosystem. Their wastewaters have very high organic load, significant concentrations of solids, nitrogen and phosphorus and low pH and contain high concentrations of phenols that are toxic to many organisms. Two orange juice processing units, located a few kilometres south of Sparta, operate seasonally (November-May). They discharge a complex effluent, composed by high concentrations of organics (due to high levels of cellulose), unsaturated hydrocarbons, proteins and fibre, high limonene, nitrate and sodium, which thus decreases their effective treatment. Expansion of farming towards the river banks, flood control works and other construction activities (e.g. for roads, bridges) including removal of riparian vegetation, straightening and embankment of river courses and significant extraction of inert materials from the river bed (also illegal for construction purposes), have caused significant morphological modifications in Evrotas River and its tributaries. These alterations degrade natural habitats, modify river and riparian natural processes and deteriorate the ecological status of the river system (see 2.D2). Hydro(geo)logical and hydrochemical features The long-term variation of precipitation and of the river‘s hydrology, the daily hydrological regime during the implementation of the project and the water abstractions contributing to the desiccation of the river are described in 2.D2 deliverable. The presence of extensive masses of carbonate and Plio-Quaternary rocks in Evrotas River Basin facilitated the formation of extended karstic and alluvial aquifers. The karstic aquifers occupy approx. 570 km 2 in Taygeros and Parnon Mts. In the lowlands, two main alluvial aquifer systems are placed at the upstream portion of the river (220 km 2) and at the downstream portion of Evrotas-Vasilopotamos aquatic system (275 km2), respectively. At the upper and mid portions of the basin, a number of karstic springs of Taygetos Mt. significantly contribute to the flow of Evrotas River (e.g. the Skortsinou, Zoros and Vivari springs) and to Taygetos streams. The Parnon Mt. does not contribute significant karstic discharges since the impermeable basis of the particular aquifers is Final Report (Technical issue) – LIFE05 ENV/GR/00024 159/313 Environmental Friendly Technologies for Rural Development encountered at high depths. The northern part of Parnon Mt. feeds the upper Evrotas and Oinus, while karstic waters of the central part either discharge in the Vasilopotamos springs (at the area of Skala) or are lost in the sea. (Zouridakis et al., 2008). The lowland aquifers are water fed by the river. In the lower elevation part of the catchment, close to the coastal zone, the Evrotas passes trough the Vrodamas gorge, structured by karstified calcareous rocks. In that gorge the river partly disappears and in summer only some ponds maintain water. Downstream, at the area of Skala, the river reappears again as a result of significant karstic inputs of the Vasilopotamos springs. The density of the catchment‘s hydrographic network is relatively low due to the significant coverage of high permeability rock formations (60%) while the average slope of Evrotas river bed is approximately 15‰ (Zouridakis et al., 2008). Just upstream of Vrodamas gorge, the average discharge of the river during the period 1974-2008 was estimated at 3.3 m3/s (see 2.D2 deliverable), while near the outflow, in the area of Skala, the discharge ranges between 3 and 4.6 m3/s, approximately. Nevertheless, there is a significant long-term decrease in river flow (see 2D.2 deliverable). The Evrotas basin presents a common and homogenous hydrochemical regime, since the main course of the river and the vast majority of its tributaries belong to the most representative hydrochemical type found in Greece (Ca > Mg > Na > K – HCO3 > SO4 > Cl; Skoulikidis et al., 2006), resulting from the dissolution of carbonate rocks. Maximum solute concentration was observed during the dry period as a result of the lower dissolution capacity of waters and increased evapotranspiration. Along the Evrotas main stem, higher hydrogen carbonate concentrations were found upstream and near the outflow, due to increased karstic spring inputs. Sodium revealed a downstream increase as a result of soil salinisation processes (due to irrigation), impact of olive oil production wastes, salinisation of coastal aquifers and transport of sea salt aerosol. In a catchment scale, the mean nutrient concentrations are considered low, especially for phosphorus. Low phosphorus concentrations have been reported also for other Greek carbonate basins probably due to adsorption mechanisms on carbonate material (Skoulikidis, 2009). However, the Evrotas main course reveals higher nutrient levels than larger Balkan rivers with greater population density (i.e. Neretva, Acheloos, Aoos and Alfeios) (Fig. 5.3.18). In addition, mean nitrate concentration in the sites examined correlates positively with agricultural land in the respective subbasins (Fig. 5.3.19), suggesting impact of nitrogen fertilizers. Moreover, point sources of organic pollution (municipal wastes, the WWTP, agro-industrial units) enhance nutrient concentrations (e.g. Fig. 5.3.20). As a result, eutrophication is a common phenomenon in summer especially around Sparta (Fig. 5.3.21). In the vast majority of the examined stations, the N/P molar ratio is by far more than 16, thus indicating phosphorus limited photosynthesis. Hence, to control eutrophication, management plans should initially focus on the reduction of point sources of phosphorus pollution. Finally, herbicides (Metolachlor and Alachlor), fungicides (Triadimenol and Penconazole) and insecticides (Dimethoate, Monocrotophos, Malathion, Fenthion and Carbofenothion) were detected in 50% of the waters and sediments examined. In most of them, concentrations exceeded the acceptable limit for potable water (0.1 μg/L), while stream sediments revealed significant levels. The effects of olive mill and fruit juice processing wastewaters on the biological status of Evrotas river streams were assessed Final Report (Technical issue) – LIFE05 ENV/GR/00024 by the use of macroinvertebrate fauna. 160/313 Environmental Friendly Technologies for Rural Development Macroinvertebrate fauna was collected few meters upstream and downstream from the outlets of the industrial units (olive mill and juice processing units) from November 2006 to May 2008. In addition 24-hour LC50 acute toxicity tests were performed to evaluate the toxicity of the two agro-industrial effluents. Two macroinvertebrate species were used (Gammarus pulex and Hydropsyche peristerica). The results showed that during the period of wastewater discharges, the biotic fauna downstream the industrial units were eliminated (Fig. 5.3.22). Only highly pollution tolerant species were present (e.g. Chironomidae, Anthomyiidae) with very low numbers while after the end of the olive oil production period, the biotic community recovered (Fig. 5.3.22). The same was not observed for streams receiving fruit juice wastewaters where the biotic community was severely impacted throughout the year (Fig. 5.3.22). This was attritubed to the intermittent character of the streams, significant hydromorphological degradation and to the prolonged period of wastewater discharge (Karaouzas et al., in preparation). The 24 hrs LC50s values of olive mill wastewater ranged from 2 % to 4% for G. pulex and H. peristerica, while the LC50s of orange juice processing wastewater ranged from 17% to 25% for G. pulex and H. peristerica (Karaouzas et al, submitted). Based on a 5-class hazard classification system established for wastewaters discharged into the aquatic environment (Persoone et al., 2003), olive mill wastewater and orange juice processing wastewater were classified as highly toxic and toxic, respectively. 8 N-NH4*10 7 TP*10 6 5 DIN 4 3 2 1 0 Aoos Neretva Acheloos Alfeios Sperchios Arachthos Evrotas Aliakmon Vjose Nestos Strymon Pinios Drin Axios Evros Kamchia Figure 5.3.18. Mean nutrient concentrations (mg/l) in major Balkan rivers (Skoulikidis et al., 2009). 16 y = 0,0957x + 0,6504 R2 = 0,3863 ΝΟ3 (mg/l) 14 12 10 8 6 4 2 0 0 20 40 60 80 % of cropland in subcatchments Figure 5.3.19. Correlation between nitrate concentration in the sites examined and the percentage of arable land in the respective subcatchments. Final Report (Technical issue) – LIFE05 ENV/GR/00024 161/313 Environmental Friendly Technologies for Rural Development May 06 0,25 Sept 06 March 07 WWTP NH4 (mg/l) 0,2 Olive oil mill, aquaculture 0,15 0,1 Boundary between good/moderate status Evrotas (River mouth) Evrotas (Skala) Evrotas (Skoura) Lagkada (Trypi) Evrotas (SpartiKastori) Evrotas (upstream WWTP) Evrotas (downstream WWTP) Gerakaris (upstream) Oinous Evrotas Springs Vresiotiko Kastaniotiko 0 Oinous (middle reach) Oinous (Karyes) 0,05 Figure 5.3.20. Ammonia concentration in Evrotas River Basin from upstream to downstream sites and boundary between good and moderate ammonia status. Figure 5.3.21. Eutrophic conditions in Evrotas near Sparta. 1 2 Figure 5.3.22. 1) Biological status variation upstream and downstream from an olive mill unit. The dark arrows on axis x indicate the wastewater discharge period. 2) Biological status variation upstream and downstream from a fruit juice processing unit. The wastewater discharge period usually lasts from November to May. Final Report (Technical issue) – LIFE05 ENV/GR/00024 162/313 Environmental Friendly Technologies for Rural Development Ecological quality assessment and classification Hydromorphological status Table 1 (Appendix) presents the results of HMS and HQA and the classification of sampling sites according to the HMS. Regarding the results of HMS, the values ranged from 0 to 89. This indicates that the Evrotas River system presents great range regarding modifications and in several cases is significantly modified. In specific parts of the river, especially downstream Sparta, some of these interventions are even from the age of ancient Sparta. Lower values appear in sites of medium and high altitude, as well as in distant areas of the river. Only eleven (11) stations that are distributed mainly in mountainous tributaries scored high. Ten (10) stations, two (2) of which at the upstream portion of Evrotas main stem, had a good status, while the rest of the stations (22) scored below good status. Particularly affected is the Evrotas main course from the area upstream Sparta up to the river mouth. The values of HQA presented good results in undisturbed and slightly modified parts and even in significantly modified parts of the Evrotas River. In significantly modified parts the relatively high values were due to the presence of vegetation in the riparian area and in the river bed, as a result of low slopes and eutrophication. These small slopes however, presented limited number of flow types compared to the mountainous and semi mountainous parts, where there were several flow types and increased discharge. Physico-chemical status According to Table 2 (Annex), the physico-chemical status of Evrotas River Basin ranges between high and moderate, whereas the vast majority of the examined stations (84%) score good and high. Three (3) sites of Evrotas main course downstream Sparta and four (4) tributaries score moderate due to high organic and chemical impact, resulting from point and disperse pollution sources, such as the WWTP outflow, fruit juice factories, olive oil mills, slaughterhouses, agrochemicals, etc. The applied physico-chemical assessment and classification system provides the following advantages: a) through the differentiation of pollution parameters into groups (following the guidelines of ECOSTAT) results a more representative classification of the physico-chemical status (the ―one out all out‖ principle may lead to an underestimation of the physico-chemical status, whereas averaging the whole set of parameters may lead to an overestimation of the physicochemical status), b) it includes sediment quality elements, which is recommended by other authors and European networks (e.g. Quevauviller, 2006; SedNet, 2004), since sediments better response to past pollution incidents than water, and c) it integrates toxic substances (heavy metals, and, partly, pesticides) although respective point sources were missing. This was prescribed by the presence of extensive diffuse sources of pollution. The inclusion of pesticides in the assessment system may result to the decrease of the physico-chemical status. For example, after the inclusion of pesticides, station 17 shifted from high to moderate status. A weakness of the applied system is that certain parameters, such as ΒΟD5, phenols and pesticides (in the majority of the sampling network), have not been examined. If these parameters were integrated in the assessment system, possibly the quality of this group, and hence the final physicochemical status, would have been termed worse. Final Report (Technical issue) – LIFE05 ENV/GR/00024 163/313 Environmental Friendly Technologies for Rural Development Biological status (macroinvertebrate fauna) In the majority of the examined stations (60%), the biological status based on macroinvertebrates scored between high and good (Table 3, Appendix). A total of twelve (12) stations was classified as high status (reference sites), which were mostly confined to the mountainous regions of Parnon and Taygetos. Nineteen (19) sites were classified as good, including mountainous, semi-mountainous and even lowland stations (e.g. Evrotas River mouth, as a result of karstic spring inputs). Seven (7) stations were classified as moderate. Here belongs the stream Skortsinos (station 4) which joins the homonymous springs at the upper part of the basin. According to local citizens, the comunal chesspool is from time to time emptied into the stream. A similar situation faces the Kolliniotiko stream (station 31), which drains the settlement of Aj. Varvara. At the banks of Kastaniotiko stream (station 2) lies an olive oil mill and an aquaculture unit. The later may affect the stream with organic matter, antibiotics and heavy metals. Four (4) stations were classified as poor and one (1) as bad status. Mylopotamos (station 20) and Tyflo (19) tributaries receiving fruit juice processing effluents and pesticides, score poor and bad, respectively. Stations situated along the Evrotas main course downstream Sparta (stations: 38, 39, 48 and 50) were of moderate or poor quality, as a result of a multitude of point and non point pressures. It should be mentioned, that stations which were dry in summer 2007 were not classified bad (as in the case of fish), since macroinvertebrate communities seem to recover after the next rainy season. In spite of missing historical data, this statement needs justification. Biological status (ichthyofauna) In the past, all fish species were widely distributed along the entire river and its tributaries. Due to human interventions (mainly severe water abstraction), fish populations are constantly declining. Nowadays, the majority of Evrotas tributaries are either fishless or contain heavily disturbed fish assemblages. Regarding the ichthyological index, three main ichthyological types where identified where there is a significant ichthyological homogeneity. The three types were given conventional names related to their geographic location (Upper Evrotas, Middle Evrotas and the Estuaries). The ichthyological reference conditions for each type are described in Table 4 (Annex). A multi-parametric ichthyological index was formulated which includes 3-5 metrics per biotic river type. Table 5 (Annex) presents the metrics finally selected for each type and gives the ranges of values (class boundaries) for each ecological quality class. The index was applied to the ichthyological data to assess the ecological status of the sampled regions. According to the results, more than half of the sites sampled in 2007 and 2008 (52% and 54%, respectively) were classified as bad (Fig. 9 & 10, Appendix). This situation was largely the consequence of an unusual prolonged drought event, which occurred in summer 2007 and, combined with overexploitation of the water resources, resulted to the complete drying of almost all Evrotas tributaries and about 80% of the main river course. In the remaining part of the river, where summer flow was maintained, the biological status of fish fauna ranged between high and moderate. It is remarkable that the biological status was not improved in the year 2008, which had highest rainfall precipitation than 2007, though the fish fauna showed signs of recovery Final Report (Technical issue) – LIFE05 ENV/GR/00024 164/313 Environmental Friendly Technologies for Rural Development (beginning of recolonization of dried river segments). The persistence of the generally poor biological status in 2008 is attributed to the slow rate of re-establishment of fish communities in hydrologically disturbed areas, given that fish a) are wholly waterdependent organisms that require ‗‗water bridges‘‘ for their migration, and b) have longer life-spans and later age at maturity than most other aquatic organisms. Effectively, fishbased ecological assessments can reveal remaining effects of past hydromorpological disturbances and can be successfully implemented to trace long-term human impacts on the ecosystems. Ecological requirements of fish Various methods for assessing the ecological quality of rivers use a combination of metrics (measurable characteristics of the biotic communities that express structural or functional aspects of the ecosystem) in order to assess the degree of ecological degradation. The basic assumption of these methods is that if an anthropogenic alteration on hydrological, morphological and chemical parameters of a sampling site or a river section will occur, it will affect the abundance or biological attributes of at least some species that present a limited range of tolerance to changes in these parameters, and thus it will alter the values of the respective metrics in this site or section relative to the values before the alteration. The quantification of these alterations can give a measure of the degree of the ecological degradation in this site or river section. Within the project, we undertook an investigation targeting to the identification of biological and ecological elements that are likely to be affected by anthropogenic disturbances. Squalius keadicus Squalius keadicus is rheophilic species, requiring permanently flowing waters, an aquatic habitat type which is being severely impacted by water abstraction. It is a very energetic fish that can resist fast flow. It is characterized as a coldwater species and is intolerant to low concentrations of oxygen. In normal conditions it is found in deep fast flowing areas (deep runs) on the main course of Evrotas, avoiding areas with stagnant water (however, during the early life stages it may occur in protected areas where the flow is low or minimal). It prefers areas with coarse substrate and hides in large submerged tree roots, but can be found in near aquatic vegetation. Reproduction takes place in the second half of April and the beginning of May. In the summer, when the river recedes, S. keadicus is forced to occupy unfavourable habitats with little or zero flow. Indeed, we often observed this species to be stranded in remaining pools where it existed under suboptimum conditions. In shallow pools, where surface water temperature follows ambient air temperatures closely and oxygen concentration is low, dead or dying fish were frequently observed, because they were already living near the threshold of oxygen and temperature tolerance. When there was some flow of water between pools, fish tended to concentrate in the shallow water corridor connecting the pools presumably for respiratory reasons. S. keadicus, as a rheophilic species, can be considered as a good indicator of hydrological disturbance. Reducing the amount or rate of water flow results to a decrease in the abundance or even to total mortality, which effects particularly the larger size or age classes, which are more intolerant to reduced flow. Therefore, the biological effects of changing flow characteristics can be estimated by measuring the change in the abundance and percentage contribution of species in the assemblage, and the percentage participation of large groups of size or age populations. Final Report (Technical issue) – LIFE05 ENV/GR/00024 165/313 Environmental Friendly Technologies for Rural Development Tropidophoxinellus Spartaaticus Tropidophoxinellus Spartaaticus is a less rheophilic species that shows preference for waters with slow flow. It is a strongly phytophilic species that depends on vegetation for reproduction, foraging and protection from natural enemies. It is often found in backwaters hidden among aquatic plants. It breeds in April and May and feeds on insect larvae, invertebrates, mollusks and algae. It was caught exclusively in the middle and lower portion of the Evrotas R. were aquatic vegetation is abundant. Interestingly, its abundance in the middle portion was much lower than expected on the basis of results of previous investigations conducted in the late 1990s (Economou et al., 1999). We speculate that repeated drying episodes have generated adverse ecological conditions for this species, perhaps because of the reduction of aquatic vegetation. T. Spartaaticus was never caught in the upper portion of the Evrotas R. where aquatic vegetation is lacking or sparse. However, the species appears to be dominant in the lower part of Evrotas as this section contains the appropriate vegetated habitats. P. laconicus P. laconicus is a helophytic species showing little mobility and lives in protected sites with stagnant waters or sluggish flow. The presence of aquatic vegetation is an important habitat requirement for this species. During the reproductive period it lays down adhesive eggs on aquatic plants. Its food consists of algae and a great variety of small organisms. This species has wide environmental tolerances. Its capacity to tolerate a wide range of thermal regimes and to live in poorly oxygenated waters confers a survival advantage under stressful conditions. However, it is vulnerable to wide flow regime fluctuations that cause damage of the aquatic vegetation and/or destruction of protected embayments and pools utilized as habitats. S. fluviatilis S. fluviatilis is cryptobenthic, spending most of its time in crevices, under stones or among plants. Its food consists of young stages of fish and amphibians, insects and other small animals. It grows to a maximum size of 10 cm. The female lays down small elliptical eggs in holes or under stones. The eggs are guarded by the male until they hatch. The tiny larvae are planktonic and require for their survival limnetic conditions where rotifers and other microplanktonic organisms utilized as food abound. This species was found only in the lower portion of the Evrotas R. where lentic conditions enabling the survival of the early life-stages can still be found. In the past, S. fluviatilis had a wider distribution in the Evrotas basin. However, human interventions, particularly hydromorphological alterations, have caused the destruction of the specialized habitats needed for the survival of its larvae, causing the disappearance of this species from the middle and upper parts of the basin. A. anguilla A. anguilla (European eel) presents perhaps the most mysterious life strategies. It is a catadromous species, which just before the reproduction maturity begins a downstream migration from the European inland waters and travels thousands of kilometres in order to arrive to the Sargasso Sea, at the western Atlantic Ocean, which consist the only reproduction area for this species. It reproduces only once in a lifetime and then dies. After the spawn, the larvae (Leptocephalus) migrate through the Gulf Stream towards to Europe in a three-year-long Final Report (Technical issue) – LIFE05 ENV/GR/00024 166/313 Environmental Friendly Technologies for Rural Development migration. As glass eels they reach the coasts of Europe and enter estuaries. Before entering fresh water, the glass eels metamorphose into elvers. Eels are critically endangered species. Since the 1970s, the numbers of eels reaching Europe is thought to have declined by around 90% (possibly even 98%). In the past, in Evrotas river, eels were abundant almost throughout the entire river network. Nowadays, the abundance of eel has dramatically decreased as a result of frequent summer drying episodes and illegal fishing. Ecological status (hydromorphological, physico-chemical, macroinvertebrate fauna, ichtyofauna) Table 6 and Figure 11 (Appendix) present the ecological status of the examined sites in Evrotas River Basin, according to hydromorphological, physico-chemical and biological (macroinvertebrates) quality elements. To meet the guidelines of the WFD and related Guidance Documents, the lower scores for the considered quality elements were used. Table 6 additionally presents the potential pressures causing a degradation of the ecological status. The following results may be highlight: a) none of the stations presented a high ecological status, b) only one station (Langada at Vatopouleika, station 16) revealed reference conditions simultaneously for the physico-chemical and the biological quality elements (however, this station is hydromorphologically modified and thus scores good), c) twelve (12) stations that showed high biological status were termed ecologically good, since the physico-chemical status was good, d) eleven (11) stations presented good physico-chemical and biological status and hence a good ecological status, and d) in eleven (11) stations biological status was moderate or worse, while physico-chemical quality elements scored a better status. The correlation coefficient between the scores of the biological and physico-chemical status (Fig. 5.3.23) is satisfactory (r2 = 0.46), thus providing evidence a) that the applied classification systems for the physico-chemical and biological status are adequate, b) for the dependence of biological assemblages on river quality (reported also for other Greek rivers; Skoulikidis et al., 2004), c) that averaging seasonal quality scores better represents the annual average conditions (if one applies the ―one out all out‖ principle by selecting the worse season as most representative for the physico-chemical and biological status, there is no satisfactory correlation between these two quality elements). Physico-chemical quality elements and mavroinvertebrates can be safely used for assessing pollution impacts on riverine ecosystems. In Evrotas basin there are significant point and disperse pollution sources that, locally and temporarily, adversely affect the ecological status. In fact, downstream of fruit juice factories, certain olive oil mills, and even the WWTP, the ecological status ranges between moderate and bad quality. It should be mentioned that for a number of stations affected by olive oil processing wastewaters, the resulting ecological status seems to be overestimated (i.e. good status), since the winter sampling did not coinsided with the operation of olive oil mills, as initially designed. This is attributed to the fact that in 2007 olive oil units stopped operating earlier than usually due to the low harvest of this particular year. As a result, riverine ecosystems have partially recovered before our sampling efforts. Hence, a number of streams, such as Magoulitsa (station 22), Nikova (station 24), Kotitsanis Final Report (Technical issue) – LIFE05 ENV/GR/00024 167/313 Environmental Friendly Technologies for Rural Development (station 34) and Gerakaris (station 47) that are subject to olive mill wastewaters presented a good ecological status, thus indicating fast recovery processes, in spite of the high toxicity properties of these wastewaters, even in high dilution. 1.4 y = 0.3145x - 0.3002 R2 = 0.4633 1.3 1.2 Biological status 1.1 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0 1 2 3 4 5 Physico-chemical status High Good Moderate Poor: Bad: Figure 5.3.23. Correlation between the biological status based on macroinvertebrates and the physico-chemical status for the stations examined in Evrotas River Basin. Table 7 (Appendix) presents the results of the overall ecological status including all the examined quality elements. Ichtyofauna is a safe quality element for assessing hydromorphological alterations. In the main course of Evrotas and in Oinus (where fish communities were examined) the ecological status is determined by fish, which in all cases present a worse status than any other quality element. The vast majority of Evrotas tributaries dry out artificially and fish communities are either missing or strongly disturbed. If fish have been included in the assessment system of these tributaries, their ecological status would be termed, according to expert judgment, poor or bad. It becomes apparent that the main environmental problem that the Evrotas River Basin faces, is the immence and uncontrolled water abstraction. The latter, in combination with the unusual draught in 2007-08, resulted in the desiccation of the vast majority of the river network, which caused massive fish deths in isolated reaches that maintained water (i.e. in remaining pools). If the current water uses remain unchanging, it is most probable that unique endangered species will extinct. Despite any of the aforementioned weeknesses of the applied ecological quality assessment, it appears that it responses satisfactory to pollution and hydromorphological pressures that affect the basin. The inclusion of sediment quality characteristics and the separation physico-chemical quality elements into groups makes the system more robust, while the biological metrics show satisfactory response to pollution. Moreover, the ichthyofauna responded well to the intense hydro-morphological alterations. Conclusions High loadings of organic matter and nutrients cause eutrophication of the main course of Evrotas River below Sparta. Management of phospohrous sources of pollution is of first Final Report (Technical issue) – LIFE05 ENV/GR/00024 168/313 Environmental Friendly Technologies for Rural Development priority to control eutrophication. The use of fertilizers and pesticides is widespred and their effects on humans, water quality and biota is well documented. It is essential to apply best agricultural practices aiming in drastic reduction of agrochemicals in the basin. Olive oil and fruit juice processing wastes are toxic and receiving water bodies score a bad ecological status, especially during operation time. Through effective waste treatment these water bodies may achieve good ecological status. Land management practices for agriculture, flood control and construction activities modify riparian areas and river courses and adversely affect river habitats. It is essential to striktly forbeed any extention of agricultural land towards the river courses and to apply integrated flood control measures (see 2D.2 deliverable) in order to minimise river bed scouring. However, the most challenging environmental problem that deteriorates the ecological status of the basin is the current water management practices. Massive and uncontrolled water abstractions exhaust groundwater aquifers and surface water cources fall dry during summer. Hence, Integrated River Basin Management Plans should special focus to pollution abatement, sustainable water use and protection and remediation of river courses and adjacent zones (see 2D.2 deliverable). The implementation of Task 2 within the EnviFriendly project revealed specific pressures acting in Evrotas River Basin and assessed the impacts on river hydrology, river and riparian morphology, aquatic quality and biota. For that purpose, an ecological status assessment system has been developed and applied. The results of this effort may assist specific measures to be implemented within Integrated River Basin Management Plans in order to improve environmental conditions and achieve a good ecological status for the whole basin. It should be mentioned however that the assessment of the status of an ecosystem is a continous and dynamic procedure. This is particularly true for the Mediterranean area, where historical data are missing, particularly for biota, and is marked by vast inter-annual and intra-annual climatic and hydrologic variability, with respective effects on aquatic quality and biotic assemblages. 3. Risk assessment of water management Introduction Water management practices in the Evrotas River Basin include intensive water abstractions from the river channel network and from the groundwater aquifers for irrigation, while severe morphological modifications of river channels, river banks and riparian vegetation, result from irrigation, land reclamation, flood protection and construction activities. These practices result to an artificial desiccation of the river network during summer and significant morphological degradation of the river system, thus limiting water and habitat availability and severely affecting aquatic and riparian biota. Naturally drawn dryness, as a result of climatic variability (including global climatechange) occurs more or less gradually. Thus, organisms of temporary rivers historically adapt to environmental stress (decreasing flow regime, remaining pools, complete dryness in particular reaches, with respective changes in aquatic and sediment quality) and develop suitable survival mechanisms. This is the ―natural‖ condition. On the contrary, when a river dries out as a result of intense water abstractions the Final Report (Technical issue) – LIFE05 ENV/GR/00024 169/313 Environmental Friendly Technologies for Rural Development environmental risk increases substantially. Environmental changes occur abruptly causing deterioration of habitats, and organisms may face conditions to which they are evolutionary inexperienced, thus leading to migration of certain species (if possible) or massive deaths which may result to the extinction of some species. Particularly severe are the effects on fish species, which are water-dependent organisms throughout their life. Other aquatic organisms (e.g. macroinvertebrates), by contrast, have aerial, terrestrial or diapause phases and can quickly recolonise the dried areas when humid conditions are re-established. Moreover, the reduction of the water volume causes ―concentration‖ of salts and pollutants, thus increasing eutrophication and depleting oxygen, and thereby generating harsh environmental conditions that negatively affect aquatic biota. Overall, water scarcity and pollution act cumulatively and cause deterioration of the chemical and biological status of the river. In the sense of the Water Framework Directive, the difference between a ―naturally‖ and an ―artificially‖ drying stream, as far as it concerns aquatic organisms, is significant. If a river or a reach dries out from anthropogenic causes then its biological status based on fish-based assessment will score bad. In contrast, if a reach dries out due to natural causes (i.e. long drought) then its biological quality based on fish fauna will be assessed with biological reference criteria and not with hydrological ones. Hence, one of the most important questions addressed when assessing the ecological status of an intermittent river is to identify whether desiccation is due to natural or anthropogenic causes. However, the distinction of the causes of desiccation is very complicated. It is usually carried out indirectly, and the results may have a certain amount of error associated with them, since climatic and human processes are highly dynamic and interact in an often unpredictable manner. Methodology To assess the risk of water management in Evrotas Basin, it is essential to recognise the causes of water deficiencies in the river network during the summer period. For that purpose, the following steps were implemented: 1. Assessment of the geographical extent of desiccation. To assess the extent of the phenomenon, the current hydrological conditions (presence/ absence of water, running/ standing waters) were recorded and mapped during successive wet and dry periods in 2007 and 2008 (April-May 2007, June-July 2007, September-October 2007 and September 2008) in order to illustrate the seasonal flow pattern and to designate the areas that retain water or dry out. 2. Identification of natural versus anthropogenic causes of desiccation. To assess the impact of man made desiccation it is essential to reconstruct the Evrotas Basin ―Leitbild‖, i.e. to provide an image of the basin prior to intense man-made interventions which can provide useful information on the environmental status and thus contribute to the definition of hydromorphological and biological reference conditions. For that purpose a) numerous field surveys were carried out to investigate particular hydromorphological pressures related to water management in the basin (e.g. water abstraction sites, flood control measures, land use changes, etc.), b) Final Report (Technical issue) – LIFE05 ENV/GR/00024 170/313 Environmental Friendly Technologies for Rural Development historical information was collected from the general literature and local libraries and authorities (books, reports, newspapers) and analysed - also, local citizens were interviewed (elders that know well the area), c) historical and present hydrological data (irrigated land area, monthly rainfall, air temperature, water discharge and groundwater depth time series, and continuous flow measurements from the automatic gauging stations that have been installed for the purposes of the project) were collected and analysed and d) the current water balance model of the basin was compared to the theoretical one prior to agricultural intensification. 3. Assessment of the impacts of water management on the river‘s ecosystem. To examine the environmental impacts of water management on river habitats, a hydromorphological study was carried out using the River Habitat Survey (RHS) methodology (Raven et al., 1997). The habitat quality of each site (stream channel and riparian habitat) was assessed with the use of the Habitat Quality Assessment Score (HQA) and the Habitat Modification Score (HMS). To assess the impact of drought on water quality, water mineralisation and pollution indices were used. To assess the impacts on biota, fish and riparian vegetation were used as indicators of ecosystem health. Concerning fish, the effects of drought on fish populations, particularly with respect to impacts on distribution, survival, percentage species composition and habitat use patterns, were carried out. The impacts were assessed through electrofishing surveys covering the main river course and few tributaries during wet and dry periods. To assess the impacts of hydromorphological modifications on the riparian forests, the riparian forest vegetation along the Evrotas River course was recorded (literature research, field investigations, analysis of aerial photographs and GIS-mapping) and its condition was evaluated and classified by applying an appropriate protocol developed for that purpose of describing the status of riparian vegetation through the use of the QBR-index (Dimopoulos et al., 2007). Results Historical Analysis The historical references collected during this survey can be roughly divided in two periods. The first period includes general information for the environmental and hydrologic physiognomy of Evrotas R. from the ancient Greek Era and the Era of the Roman Empire. However the biological and hydrological data from these sources are very scarce. The second one includes data from the beginning of the 19 th century until the present time, and is focused mainly on the agricultural development of Laconia and the man made interventions in the riverine ecosystem. The gap between these aforementioned periods derives from the lack of historical references concerning the study area. Ancient times The name Evrotas derives from the ancient Greek words ―εύρως‖ (evros) and ―ώτος‖ (otos) which means mould, humidity resulting to decay and deterioration. In Greek mythology, according to Pausanias, the Laconia valley was covered by a lake. To prevent flooding, Evrotas, the legendary king of Lacedaemon was said to have created a canal Final Report (Technical issue) – LIFE05 ENV/GR/00024 171/313 Environmental Friendly Technologies for Rural Development through of Vrodamas conducting the water towards the Laconia Gulf. Thus, an artificial river outflow was developed, and in order to honor the king, the river was named after him. Even if this story belongs to the sphere of the myth, evidence from research boreholes in the area has proved the existence of a Pliocene lake that covered the greater part of the Spartan valley (Piper et al. 1982). Evidence that further supports the presence of a lake in the Laconia valley is that the suburbs of Sparta were almost always covered by standing waters and that is why they were called ―The Lakes‖. The majority of the historical writers (Euripides, Theogenis, Polivios, Vergilios, Aineias and Statios) describe the Spartan valley as a very fertile land, however not extensively cultivated due to frequent flooding of the valley when the river overflowed. They also provide information concerning the flora of the area which included wetlands species such as reeds, laurels, myrtles and additionally olive trees near the river banks. The greatest source of references for the Evrotas catchment area are the writings of Pausanias who provided several information concerning mainly the hydrological conditions of the river. Specifically he mentioned the periodic increase of the water level; which was later affirmed by Cicerones as well. In addition, Pausanias and other ancient authors, both Greek and Roman, mentioned that the Evrotas R. and Alpheios R. had common springs1 in the Assea of Megalopolis. They described that both rivers shared a common drainage for approximately twenty stadiums2 and separated after entering into a land gap. Evrotas would appear again in the area of Veleminatida from the springs of Pellanitida and Lageia. Finally, Pausanias refers to some hydraulic projects that were conducted in the area. The aim of these projects was the agricultural development of the greater part of the fertile Laconia land and the protection of the communities. Vivid examples were the irrigation of the Velemina area, the drainage of the Trinasos swamp, which overflowed again not being well maintained, and the construction of the Sparta aqueduct which pumped water from the Vivari springs. Modern times During 19th century the references of Greek and foreigner authors are similar to the previous ones, but they also provide information about the development of the area. As agricultural activities are concerned, Mansolas (1875) describes that there was an increase in agricultural production not only for self consumption but also for trade purposes. During the second half of the 19th and the beginning of the 20th century the basic agricultural products of Laconia were olive oil and olives, mulberry leaves, acorns and figs. That same period, an expansion in the variety of cultivations occurred. Mansolas mentions the intense land reclamation which took place. The majority of the new land created was used for the cultivation of wheat, cereals, small cultivations of tobacco and vineyards. Finally, during that period citrus cultivations started to expand. By the end of the century these cultivations had increased in such degree that the citrus were considered as the basic agricultural products of Laconia. From 1900 and for several decades the river had maintained its natural characteristic. In the beginning of this century the first flood events are officially recorded. Specifically, in October 1902, its precipitous waters drifted the Kopanos bridge, which was built in 1749 1 2 See Travels in the Morea with maps and plans. By William Martin Leake, Vol III p. 37 1 stadium is 185 meters Final Report (Technical issue) – LIFE05 ENV/GR/00024 172/313 Environmental Friendly Technologies for Rural Development (Anonymous, 1922). In the 1930‘s and 1940‘s the Evrotas River overflowed during the intense autumn and winter rainfalls and drifted everything in his pass (even humans). At that time extensive riparian forests existed which minimized the impacts of floodings. In addition, in order to prevent the river water to move into their cultivations, the farmers had planted trees and bushes in the river banks which served as natural ―green‖ barriers. As time went by, dense scrubs were created near the river, which became known as the ‗‗Evrotas Scrub‘‘. Many hydrophilous trees were growing there, converting it into an impermeable jungle during spring. The scrub sheltered a large number of animals: small mammals, amphibians, reptiles and mainly birds both endemic and emigrating species (Anonymous, 1922). According to Grigoris (2000), the major tributary of Evrotas, Oinous (or Kelefina) also presented in some periods of the year extreme floods and as so the farmers used the same techniques described above (building green barriers) to prevent the flooding of their cultivations. Similarly to ancient years, Evrotas exhibited permanent flow along its whole length and throughout the year. Evidence of the above constitutes the natural or artificial swimming pools which were formed, and which accommodated many swimmers during summer, as for instance the natural swimming pool at Stefani near Sparta. Pools that were found in hollows of the river were had great depths. Another evidence of Evrotas permanent flow was the existence of fish both in the main river and its tributaries. The inhabitants of the area used to fish fishes and eels using several techniques. During 1950‘s, several studies and projects were carried out in the area in order to reduce the floods, increase the cultivated and irrigated land and limit the danger of malaria coming from the swamps. In the 1960‘s, large scale hydrological, irrigation, land reclamation and drainage projects were meterialised, including swamp drainage, control of stream flow in the Evrotas tributaries, alignment of the lower part of river, drillings for groundwater abstraction and construction of aqueducts for the water supply of Laconia. At the end of 1970 and beginning of 1980, a project for the drainage of Trinasos swamp at the river estuaries was carried out for agricultural development. Finally, in the 1990s, construction projects were conducted near the estuary, in order to lift and support the river banks as a flood control measure. As it concerns the water level of Evrotas River, the Great Geography - Atlas of Greece, informs us for the decade 1950 that the river had a lot of water in winter but in summer the water level was so low that in some parts the river was passable by foot. Also, other reference sources (Anonymous, 1922) state that the shrink of the river and its flushy character resulted from deforestation and exploitation of water resources. Drepanias (1981) states that: «In past years Evrotas R. retained water during the year. In recent years, however, the decrease of precipitation combined with water abstractions resulted to the desiccation of a large section between the villages of Skoura and Pyri». In addition, Grigoris (2000) states that: «...This is not the wide Evrotas that we knew but a miserable dry stream. In the great drought in the early „90s, the once „„haughty body‟‟ of Evrotas was pierced by numerous drillings ... ». He also stated for Oinous tributary that: «...Kelefina seems now powerless and pathetic like a dry stream and is not any more permanently flowing as previously used to be». Final Report (Technical issue) – LIFE05 ENV/GR/00024 173/313 Environmental Friendly Technologies for Rural Development The extent of desiccation during the project Information was collected during field expeditions and from personal communications with the Direction of Land Reclamation, Laconia Prefecture (DLR) (V. Papadoulakis) the Geotechnical Office of Skala (V. Lerikos) and various locals. All evidence suggests that there are numerous water abstraction points for irrigational uses scattered over the entire basin (Fig. 5.3.24). There are many permanents weirs which divert water to the agricultural fields, while during late spring and summer many more weirs are being temporarily installed for irrigational purposes. Pump stations, both private and communal, and drillings have been established throughout the length of Evrotas and particularly at the area of Karavas and immediately downstream. Irrigation from surface and groundwater is prohibited from Pellana - Sellasia Bridge (near Pellana village) to Skala at a distance of 300m from the river‘s banks. However, there are many private pump stations which are not being regulated or controlled by local authorities. Many reaches of the Evrotas River main course dry out during the summer for many kilometres, even in normal hydrological years. In addition, most streams that discharge into the Evrotas River dry out at the mid and lower reaches, and few only retain water at their upstream reaches near the springs. In the past, the Oinous, the most important tributary of Evrotas, used to retain water throughout the year; nowadays it retains water only at its upper reaches and in few spring areas midway. The three important streams at south-western Taygetos (Gerakaris, Rasina and Kakaris) retain during the summer period water only at their upper reaches, and occasionally in some middle portions, again due to water abstraction. The same occurs in the three important streams of northwestern Taygetos (Vrysiotiko, Kastaniotiko, Kardaris). Magoulitsa is a stream small in length but with significant water volume, supplied by the springs of Trypi. Again, due to irrigation and abstraction for the water supply of Sparta, this stream does not reach the Evrotas R. during the summer. Figure 5.3.25 illustrates the hydrological pattern of Evrotas River from the wet period (April) until the end of the dry period (September-October) in the year 2007. It is evident that most reaches along the main course of Evrotas desiccate completely by the end of the summer. In the hydrologically adverse year 2007, few only parts of Evrotas retained flow: a segment near the estuaries, a small gorge located about 5 km downstream of the Evrotas springs, and another small segment about 3 km long downstream of Vivari karstic springs. Furthermore, most tributaries of Evrotas River have dried out, while some maintained water only at their upper reaches. In several parts of the Evrotas and its tributaries, however, small pools with stagnant water were formed. Despite absence of flow, these pools with remaining water are critically important for the maintenance of aquatic life, especially fish, and serve as sources of migrants and recruits for the recolonisation of the river once flow is re-established. For example, within the Vrodamas Gorge there are several pools ranging from 5 to 10 m in diameter which sometimes reach a depth of 3m. Water is reserved in these pools throughout the year or at least most of the year. Many large pools were also formed downstream from Vivari springs for about 400-600m, 500m upstream Sparta Bridge and at the area of Skoura-Leukochoma. As aforementioned, 2007 was a particularly dry year. However, despite precipitation increase in 2008, the hydrological picture in September 2008 did not change Final Report (Technical issue) – LIFE05 ENV/GR/00024 174/313 Environmental Friendly Technologies for Rural Development significantly. As for the year 2009, there are not yet signs of substantial hydrological recovery, despite heavy winter precipitations. This evidence may suggest that dramatic groundwater level lowering in the basin has prevented the establishment of normal flow conditions. Figure 5.3.24. Water abstractions (left) and diversions (right) in many locations in the main course of Evrotas River and its tributaries. Natural versus anthropogenic causes of desiccation Hydrological Analysis Within the last 35 years a long-term decrease of both rainfall and discharge in Evrotas basin is evident (Fig. 5.3.26 & 5.3.27). According to data of six rain gauges in the Evrotas basin, a severe draught affects the area every 7-8 years. The driest period (that affected whole Europe) was 1989-94. Other severe draughts took place in 1977, in the period 1983-86, in 2004, and finally during 2006-08. 2007 was very poor in rainfall and the snow cover was very limited. In addition, three heat waves affected the area in summer 2007 and created the conditions for catastrophic wild fires. The mean annual discharge of Evrotas at Vrondamas (upstream the homonymous gorge) was calculated at 3.302 m3/sec (74.4 mm/yr or 1.01 km 3/yr). Gaps in measurements were filled by interpolation using a formula proposed by Skoulikidis (2002). A comparison of the average rainfall of the initial decade of the time-series (1974-83) for three gauging stations with the average rainfall of the last decade (1999-2008) of the same stations reveals that the average rainfall diminished by 13% within the last decade. A similar comparison of the discharge at Vrodamas (average discharge of initial decade: 5.214 m3/sec – average discharge of last decade: 2.400 m3/sec) shows that discharge decreased by 53.2%. This fact provides evident for an ―artificial‖ discharge diminishing the water supply in the Evrotas basin. Final Report (Technical issue) – LIFE05 ENV/GR/00024 175/313 Environmental Friendly Technologies for Rural Development Figure 5.3.25. Hydrological mapping of the Evrotas River Basin from spring (left figure) to end of summer (right figure) of 2007. The green colour in the left figure represents the reaches with water. The orange colour in the right figure (October 2007) represents the reaches that retained pools with water. The red marks illustrate the weirs established throughout the watershed. Blue lines represent the ideal hydrologic network of the river basin. Final Report (Technical issue) – LIFE05 ENV/GR/00024 176/313 Environmental Friendly Technologies for Rural Development Sellasia 2500 2000 y = -0.0942x + 5.0296 8 R2 = 0.2297 7 Discharge (m3/s) Rainfall (mm) 9 Kastori Vassaras 1500 1000 500 6 5 4 3 2 1 0 2008 2006 2004 2002 2000 1998 1996 1994 1992 1990 1988 1986 1984 1982 1980 1978 1976 1974 2006 2004 2002 2000 1998 1996 1994 1992 1990 1988 1986 1984 1982 1980 1978 1976 1974 Fig. 5.3.26 35-year rainfall variation at the stations Sellasia, Kastori and Vassaras. 0 Fig 5.3.27. 35-year discharge variation at Vrondamas and 5-year moving averages. Data: Direction for Land Reclamation, Laconia Prefecture Hydrograph analysis Daily discharge was calculated from water level data obtained from seven automatic gauging stations and wet cross section measurements. High values of discharge were observed in less than 3% of the year. On an annual base, the Evrotas at Sparta Bridge requires less than 20% of the year to drain 50% of its water quantity. These figures underline the flashy character of the river. The results also show that in summer 2007 water discharge in Evrotas and its main tributary Oinus reached the zero point abruptly indicating the impact of intense water abstractions during periods of low rainfall. On the contrary, the Evrotas at Vivari desiccated more gradually due to the inputs of karstic springs. Hydrological balance To quantify the effects of agricultural water uses on Evrotas discharge, the water balance of the river basin was estimated a) according to the current water uses and b) according to the current water uses by abstracting the water used for irrigation of olive groves. This approach was dictated by the fact that irrigation of olive trees has been recently introduced in the basin. For that purpose, the components of the water balance were estimated for the period 1998-2000. The annual water balance of the basin was estimated by the classical equation (Ward, 1975). The annual precipitation and the potential evapotranspitration (according to Hamon‘s method) were 727 mm and 1586 mm, respectively. The real evapotranspitration (according to Hillel‘s method, 1980) was 566 mm. Finally, 162 mm represented surface runoff and infiltration. The annual water supply needs were 0.091 km 3 (250 lit/inh./day, OECD, 2000). The irrigation water uses were estimated from the area and the water needs of each cultivation (Papazafeiriou, 1999) at 0.287 km3 annually. Domestic consumption is only 2% of the annual (surface and ground) water storages, while irrigation reaches 73% and the remaining 24% covers the environmental demands (approx. 95x106 m3 annually). The monthly water balance in the study basin was estimated with the Hilllel method (1980, Final Report (Technical issue) – LIFE05 ENV/GR/00024 177/313 Environmental Friendly Technologies for Rural Development soil moisture deficiency) for the period 1998-2000. For this process, the software ISBH water balance (www.intersoft.tk) was used. The temporal distribution for the irrigation water abstractions was based on the experience from other agricultural Greek catchments (Zacharias et al., 2003), while 2/3 of the olive trees are irrigated according to DLR. The cumulative water abstractions and storages were estimated from the monthly water budget. The results of the monthly water budget analysis indicated that in the end of the hydrologic period the remaining water resources in the catchment is less than 38mm (2.9 m3/s), while the maximum water storages are estimated in February with 160 mm of water (12.3 m3/s). 77% of Evrotas basin agricultural land is covered by olive groves. The total irrigation needs prior the irrigation of olive groves was estimated at 0.084 km3/year, i.e. 30% less than the current uses. According to this scenario, the discharge at the river outflow during the dry period was 9.4 m3/s, which is 70% higher than the recent one. Considering that 50 years ago agricultural land was less extended than today it is realistic to assume that during that time the summer discharge of the river was double, which is assumed to be enough to maintain water flow throughout the year. Assessment of the impacts of water management Morphological impacts Besides the severe impact of irrigation on the basin‘s water balance and the river‘s hydrography, major impacts imposed by water and land management activities concern morphological alterations that become detrimental to river habitats and biota. Within the last decades, cultivations have been extended towards natural and semi-natural land. Nowadays, many semi-mountainous areas are covered by olive groves. In many parts of the Evrotas course, crops end where the river water starts. In order to protect the agricultural fields that lie besides the river, and also in order to fascilitate the distribution of water into the agricultural land, the riparian zone of Evrotas has been shrunk, straightened, embanked, reinforced with grit or large stones or even with construction waste, while its natural vegetation has been removed. Riparian forests known from the recent history of the area for their role in flood control, were reduced dramatically (Dimopoulos et al., 2007). Over the last decades, as a result of deforestation in mountainous and semi-mountainous areas and climate change, the frequency of flood events has increased. For example, during the period 1999-2006, five extreme events occurred (Nikolaidis et al., 2006). To protect crops from flooding, the Laconia Prefecture regularly deepens river stretches by removing river bed material in an inappropriate and often catastrophic manner for river habitats. The recent (2007) wildfires raised concern over probable winter floods and led to the decision to intensify flood-control interventions in the river bed and banks (removal of aquatic vegetation, construction of flank levees using material extracted from the river bed). These flood-control measures have adverse effects on the riverine habitats and ecosystems, in addition to having a high economic cost associated with them. Moreover, their usefulness against flooding events is doubtful, because the material deposited on the river banks will be Final Report (Technical issue) – LIFE05 ENV/GR/00024 178/313 Environmental Friendly Technologies for Rural Development flashed out and return to the river during the first severe flood event. We therefore question the effectiveness and utility of such measures which also have negative impacts on the biota. In addition, illegal extraction of river bed material for construction activities takes place (e.g. huge amounts of gravel were removed from the river bed at Skoura to construct a new bridge). Sand and gravel/pebble extraction occur particularly northern from Vivari springs, around and downstream Sparta, at Skoura and Skala (Fig. 5.3.28). The intense sand extraction north and south of Sparta has vanished any kind of sand and gravel from the area and destroyed the natural habitats of the river. A few decades ago (Special Protection Zone - NATURA 2000), the Evrotas at its downstream (southern of Skala) was meandering and was marked by extensive floodplains and marshes. This river section was straighten and embanked and the floodplain and the marshes turned to agricultural land. The agricultural fields now extend up to the river banks, while groundwater overpumping caused salinisation of coastal aquifers. Moreover, illegal housing and extension of croplands up to the coastline caused the reduction of sand dunes area. Morphological degradation results to habitat degradation or destruction, which results to decreases in species diversity and to the formation of a relatively homogeneous macroinvertebrate communities dominated by tolerant and generalist species with significant abundances (Karaouzas & Gritzalis 2002; Karaouzas et al. 2007). River channel and riparian habitat degradation may also be detrimental for macroinvertebrate species and their eggs and through limiting nutrient and food availability, or preventing effective reproduction. Fish species are also vulnerable to morphological degradation, in its various forms. Population of habitat-specialist species, like Tropidophoxinelus Spartiaticus and Squalius keadicus are in severe recession, mainly as a result of bed levelling or pebble abstraction, which has led to loss of the specialised habitats these two species are utilising. Figure 5.3.28. Construction waste at Evrotas banks few meters downstream Sparta‘s wastewater treatment plant (left). Clearing and straightening of the Evrotas bed in the Skala region as a flood control measure (right). Final Report (Technical issue) – LIFE05 ENV/GR/00024 179/313 Environmental Friendly Technologies for Rural Development The Evrotas river system in recorded HMS intersections presents great range regarding modifications and in several cases is strongly modified. Better conditions appear in sites of medium and high altitude, as well as in distant areas of the river. According to the HMS, several reaches along the Evrotas main stem (at the area of Sparta, at Skoura and downstream Skala) show severe modifications. Similarly, a number of tributaries are significantly (e.g. the downstreams of Gerakaris and Kardaris, Kastaniotiko, Oinus at Kelefina, Skatias and Ag. Kyriaki) or severely modified (e.g. the confluence of Gerakaris and Rasina). Impacts on water quality Soil and water salinisation Water management, and particularly intense irrigation, causes soil salinisation. Salts that accumulate in the soils are then transferred into surface and groundwater and can raise water salinity. At high concentrations, salt can adversely affect aquatic species, while droughts additionally enhance this phenomenon (Skoulikidis, 2008). The positive correlation between electrical conductivity and alkali ions of the examined stations with the percentage of agricultural areas in the respective subcatchments of these stations indicates a probable impact of agricultural practices (mainly irrigation) on the salt balance of a number of water courses. However, this correlation is not strong as observed elsewhere (Skoulikidis, 2008). Moreover, only two stations illustrated a conductivity > 750 μS/cm, whereas all stations examined presented a SAR far below 3 (average 0.32) indicating an overall good irrigation water quality. Nevertheless, an increase of sodium along the river‘s main course, points out to the existence of soil salinisation processes, salinisation of downstream aquifers and sea salt aerosol transportation. Aquatic quality Discharge strongly controls the dilution capacity of a water body and hence pollutant concentrations. Low flow or standing waters enhance the development of aquatic vegetation and the expression of eutrophication conditions (Fig. 5.3.29). The later may lead to anoxic state. River water in summer showed increased nitrate and, especially, ammonia levels (Fig. 5.3.30), compared to the wet periods as a result of discharge reduction. Figure 5.3.29. Typical explosive development of algae during summer 2007 in Evrotas at Sparta. Final Report (Technical issue) – LIFE05 ENV/GR/00024 180/313 Environmental Friendly Technologies for Rural Development May 06 0,25 Sept 06 March 07 NH4 (mg/l) 0,2 0,15 0,1 Evrotas (River mouth) Evrotas (Skala) Evrotas (Skoura) Evrotas (SpartiKastori) Evrotas (upstream WWTP) Evrotas (downstream WWTP) Gerakaris (upstream) Lagkada (Trypi) Oinous Oinous (middle reach) Oinous (Karyes) Vresiotiko Kastaniotiko 0 Evrotas Springs 0,05 Figure 5.3.30. Seasonal variation of ammonium concentration in Evrotas Basin. In contrast, the oxygen concentration in summer does not show any statistical differences compared to the wet periods, although water flow in a number of cases was minimal, most probably due to strong photosynthetic activity during the time of sampling. Concluding, the summer flow reduction of Evrotas system, which is enhanced by intense water abstraction, causes an increase in nutrient concentrations that in turn foster eutrophication. Impacts on biota (ichthyofauna) Benthic invertebrates were excluded from the assessment of the impacts of desiccation for the following reasons: most macroinvertebrate species are relatively resistant to drought, they have the ability to recolonise former dry areas and it is difficult to distinguish the effects of pollution from those of drought on their communities. In the framework of the present project an ichthyological investigation was undertaken (see 2D.1 delivelable). The year 2007 was a particularly dry year and it was followed by a generally wet year. These conditions offered a unique opportunity to study the effects of drought on fish population. However, faced with an extreme in severity drought event (that may become a normal feature for the Evrotas in the future due to the combined effects of climate change and escalating water abstraction), we undertook an investigation aiming: To examine how desiccation and the altered flow regimes modified the distribution of fish species and affected fish abundance, species richness and fish community structure. To consider the role of water refugia (reaches retaining some flow and pools with remaining water) on fish population dynamics during drought. Final Report (Technical issue) – LIFE05 ENV/GR/00024 181/313 Environmental Friendly Technologies for Rural Development To study the re-colonisation processes from drought refugia and the rate of reestablishment of the depleted populations after a severe hydrological disturbance. This study took place during 2007 and 2008 and was executed in parallel with the study of ecological status classification through the use of an ichthyological multi-parametric index. Eventually, common methodologies and and the same sampling network were used in both studies (see 2D.2 deliverable). Briefly, the design of the sampling scheme in the year 2007 took mainly into account the need to estimate the drought effects in the fish assemblages. So as to meet the needs of the present study, additional sites were added in areas where the phenomenon of drought was particularly intense. Special effort was devoted to include sites in hydrologically adverse segments of the river (i.e. suffering substantial reduction of flow and water level) in order to examine the effects of drought on fish populations. In 2008, ichthyological surveys focused in the evaluation of the post drought effects of the 2007 drought on populations. The capacity of the biota to recover, the rate of recovery and the re-colonization routes from drought refugia (e.g. upstream migration of adults or downstream transport of larvae) were examined through monitoring changes of fish densities and size distribution in a number of stations. Drought effects The surveys conducted in 2007 clearly demonstrated adverse drought effects on fish communities. In the drying areas fish either died or assemble at residual pools where hyperthermia, anoxia and increased predation from birds and otters led to significant mortality. An interesting comparison indicating drought effects was between samples taken around the Sparta Bridge (Fig. 5.3.31, see section G) in different time periods, namely spring and summer. In April 2007 this area had substantial flow and maintained connections with upstream and downstream segments of the Evrotas. At sites, the wetted river width exceeded 40m (e.g. downstream of the Sparta bridge). Flow reduction through the season resulted to the decrease of the wetted width and the overall surface area. In July the river channel downstream of the Sparta Bridge was less than 3m wide. Thereafter this riverine section continued to shrink and in August almost all sites downstream of the Sparta Bridge were completely dry. At the same time, hydrological connectivity was disrupted because most upstream and downstream river segments were dry. In the beginning of September the remaining wetted area was an isolated narrow channel about 1km long. This area became a refuge for fish (and other aquatic organisms) during the dry season. Fish previously dispersed over a wider wetted area retreated and survived during the drought event in this narrow channel, albeit at suboptimum conditions. We observed very high abundances of fishes in this channel, which were previously dispersed over a much wider and longer area. However, fish abundances and the composition of the community were very different than in the previous spring. On the one hand, we observed that population densities of all species area increased during the dry season, which was apparently the result of fish aggregating in greatly reduced areas/volumes of water as the river dried up. Therefore, inferences of the effects of drought events on fish population dynamics based on population densities may be misleading, because concentration of fish in reduced space (e.g. narrow channels or few remaining pools) leads to increases in ―apparent‖ fish densities, even though the overall population size in the broader area has declined severely. On the other hand, the Final Report (Technical issue) – LIFE05 ENV/GR/00024 182/313 Environmental Friendly Technologies for Rural Development fish community structure in the Sparta bridge area changed through the dry season, with S. keadicus dominating downstream of the Sparta bridge in April but becoming the dominant species upstream of the Sparta bridge in July and August. Our interpretation of this changing distribution pattern is that S. keadicus, being a cold-water and strongly rheophilic species with high oxygen demands, tended to migrate to the upstream limits of the wetted area, where there was some influx of groundwater, in order to reduce the risk of death from hypoxia and hyperthermia. The survey design, the time and means available did not allowed to assess the magnitude of fish population losses due to the drought event. However, considering that about 80% of the main river course and almost all of its tributaries dried up during the 2007 desiccation, we assert that fish mortalities were enormous. Indeed, large sections of the river were left for 40 to 120 days without flow in late spring – autumn 2007. Effectively, all or nearly all fish in these areas died. Although freshwater fish are generally mobile, able to escape harsh conditions by migrating upstream or downstream to find more favourable areas, fish movements were prevented by progressive habitat isolation. Shallow areas were the first to dry with the reduction of flow. Surface flow sometimes ceased across riffles, setting barriers to dispersal. Fish were thus trapped in deeper sites, which progressively shrank, and finally dried out. Low flow 2007 inds/1000m2 1000 800 DRY 600 DRY DRY DRY 400 200 0 B C D E F G H F G H inds/1000m2 High flow 2008 1000 800 600 N/S 400 200 0 B C D E inds/1000m2 Low flow 2008 P. laconicus T. spartiaticus S. keadicus 1000 800 DRY 600 400 200 0 B C D E F G H River sections of the main channel of Evrotas River Figure 5.3.31. Total abundance of the three endemics fish species and comparisons between low and high periods. Refugia during the drought event Final Report (Technical issue) – LIFE05 ENV/GR/00024 183/313 Environmental Friendly Technologies for Rural Development The sections which remained wet during the dry season provided refugia from harsh physical conditions and were also a source of fish for recolonization after flows reestablished in the rainy season. Dry-season refugia were of different types (small or longer reaches maintaining flowing waters, shallow or deeper pools) and varied in suitability and functional importance for different fish species and life stages. Deep run and pool refugia seem to play a key role in the maintenance of the Evrotas fish species, first because they usually show a higher probability of persisting through the dry season and second because large water bodies are less affected by ambient air temperatures and other physical extremes than smaller water bodies. Moreover, crowding of fish in reduced space strengthened biotic interactions, leading to reduced food availability and increased vulnerability to aquatic and terrestrial predators. Generally, large bodied S. keadicus individuals appeared to be more sensitive to hyperthermia and oxygen deprivation than smaller-bodied ones and individuals of other species. Most probably, large-bodied S. keadicus is also highly vulnerable to predation by otter, which was the main fish predator in the study area (other fish predators such as eel, trout and aquatic snakes did not occur at densities high enough to justify a significant predatory impact). Otter activity was most heavily concentrated in deep pools, as indicated by the high incidence of occurrence of otter feces containing fish scales and bones around pools. Post drought effects and recolonization The surveys initiated in April 2008 were designed to answer whether, to which extent and how quickly a fish community will recover from the perturbation induced by extreme drought in summer 2007: 1. Our data show great declines in population abundance in spring 2008 in comparison to spring 2007. Such declines were evident mainly in sites which experienced the effects of drought. However, much reduced population abundance was also observed in some sites that did not dry. For example, we caught very few fish in sites around the bridge of Sparta (sites K_Sparta and Us Gef Spartas) where, in the period from April to August 2007, enormous fish concentrations were recorded. To some extent, this low fish density in April 2008 may be the result of poor electrofishing sampling efficiency due to wide and deep habitats at this site. However, we are confident that the main reason of poor catches was low fish density, as considerable effort was devoted to sample different stretches and a variety of habitats. Moreover, we noticed that reproductive activity in this site was extremely low. In fact, we detected only one small shoal of P. laconicus larvae, whereas in the equivalent period of 2007 this same area was found to be swarming with larvae and fry. Therefore, poor catches seems to be a true reflection of scarcity of fish in this area in 2008. 2. Fish populations had already started to re-colonise, albeit slowly, the areas affected by the drought. Our evidence suggests that re-colonisation occurred mainly through passive downstream dispersion of young of the year or small sized individuals (Fig. 5.3.32) from drought refugia. Figure 5.3.32 presents the recolonization of the dry areas where the majority of the colonizers are young of the year individuals. Undoubtedly, such refugia play a critical role in promoting Final Report (Technical issue) – LIFE05 ENV/GR/00024 184/313 Environmental Friendly Technologies for Rural Development population re-establishment processes and thereby the persistence of native fish populations. In normal years, the Evrotas river fish populations appear resilient to the occurrence of droughts, and they tend to recover shortly after the cessation of the dry period. The 2007 drought, however, was very severe, and the rate of recolonisation was extremely slow. In 2008, the fish communities in the affected areas did not show signs of significant recovery. The rate of recovery can vary from area to area and is a function of various factors, such as: number and quality of the drought refugia that will provide the colonists, number of remaining fish in the refugia, distance of the affected area from the refugia, features affecting longitudinal connectivity, current habitat conditions, and availability of suitable microniches in the affected areas. Various human constructions in the Evrotas, such as the high pedal of the Pelana Bridge and many small irrigation dams along the river‘s route, bare fish reinvasions from downstream refugia. Finally, recovery rates may differ among species, depending on migratory patterns, habitat preferences and life-history traits such as body size, timing and duration of the breeding season, reproductive age and reproductive effort. Low flow 2007 100% 80% 60% DRY 40% DRY DRY 20% 0% Low flow 2008 100% 80% 60% 40% 20% 0% B C E F G H River sections of the main channel of Evrotas river S.keadicus >5cm T.spartiaticus >5cm S.keadicus <5cm T.spartiaticus <5cm Figure 5.3.32. Size comparisons of S. keadicus and T. Spartaaticus in low flow periods of 2007 and 2008. In 2007, G section dried after sampling. According to our data, T. Spartaaticus was the species which was mostly adversely affected by the drought. Indeed, the extremely small number of individuals of this species sampled in 2008 indicates that the populations are near to the limits of collapse. This fact, coupled with evidence of poor reproductive success of T. Spartaaticus, in 2008 (at least in the northern and middle part of Evrotas), may suggest that the re- Final Report (Technical issue) – LIFE05 ENV/GR/00024 185/313 Environmental Friendly Technologies for Rural Development establishment of the populations may be very slow. However, we did not sample the lower portion of the Evrotas, e.g. the area downstream of the bridge of Skala, which seems to be a stronghold for this species. A significant factor that may slow down the rate of recovery of this species is that the flood defence engineering works caused a substantial damage to backwaters, pools and vegetated habitats that are mostly used by this species. On the contrary, P. laconicus appeared to be less sensitive to the drought effects, as significant concentrations of this species were recorded at places with suitable habitat conditions. This species possesses life-history traits such as small body size, early maturation and protracted spawning season, which reflects resistance to low water levels and rapid colonisation efficiency. Furthermore, spawning activity (presence of larvae and fry) of P. laconicus was observed in various places. For the above reasons, it may take long, perhaps years, for the fish communities to recover fully. We speculate that a sequence of harsh events such as a series of hydrologically adverse summers or flash flooding events in winter may delay recovery and/or result in significant modifications to community structure. Local extinctions during years of severe drought are not unlikely. This has already happened in several streams which were once perennial and historically harboured fish, and now have temporary flow characteristics. The anticipated climate change may act additively to the already elevated water abstraction, turning the Evrotas to an intermittent river that may not be able to support fish. Synthesis – Assessment of drought effects on fish communities Summer droughts, arising from a combination of natural causes and water abstraction, are becoming an increasingly more frequent phenomenon in the Evrotas. Droughts generate major impacts on the survival of fish, and also influence growth and reproductive activities; thereby, they affect densities and size or age structure of populations. The effects of droughts on the Evrotas fish populations are of two kinds: direct and indirect. Direct effects include death from hypoxia or hyperthermia, habitat contraction or deterioration, loss of connectivity among river segments and poor reproductive success. Indirect effects include changes in food web structure that may result to food limitation, competition due to confinement in small living space, elevated predation, increased parasite load, evolutionary changes in life-history traits and changes in gene frequency because of ‗bottleneck‘ effects. The impacts of human-induced droughts (through water abstraction) exacerbate the stresses already experienced by fish populations by other causes, such as flood control engineering, introduction of exotic species and deterioration of water quality due to organic pollution. It is not easy to determine the specific mechanisms underlying population declines or the exact reason of death of individuals, because several stressful agents can have interactive effects on individuals or populations (for example, individuals stressed by food limitation or oxygen depletion are more vulnerable to predation by otter and birds). However, we can see the overall effect of droughts on fish populations through estimations of mortality rates and assessments of re-colonisation and recovery rates. A specially designed study should be launched to address these issues in a quantitative way. It might be argued that the Evrotas fishes are adapted to harsh and highly variable ecological conditions, because they have been subject to consistent selective pressure for droughts during the course of their evolutionary history. However, our historical hydrological data indicate that, at least Final Report (Technical issue) – LIFE05 ENV/GR/00024 186/313 Environmental Friendly Technologies for Rural Development until the 1950s, drought events were rare and locally restricted. It may therefore happen that the Evrotas fishes have not evolved specific adaptive strategies to face drought. In extreme years as during the prolonged drought during the years 1988-1992, fish nearly reached the edge of their tolerance limits to drought effects. Therefore, they may be evolutionarily unprepared to tolerate further stressors in a future period of prolonged and extreme drought. This again reiterates the need for studies examining (a) the status of native fishes especially during and after drought periods, (b) the species‘ resistance mechanisms for drought, and (c) the resilience of the fish communities to drought, especially with regard to reproductive efficiency and dispersal abilities after droughts. Risk assessment - Management considerations The hydrological data presented in this report reveal general trends towards reduced precipitation and increased inter-annual variability, which is likely the consequence of ongoing climate change. In the future, the magnitude and frequency of summer droughts is likely to increase due to the combined effect of climate change and growing demands for water by agricultural. The ichthyological surveys yielded results demonstrating that the summer 2007 drought has caused substantial mortality that may produce long-term effects on fish assemblages. More severe droughts expected under altered future climates and elevated water consumption may result in severe declines or extinctions of sensitive species. Concurrently, floods during the wet season are becoming more common, partly as a result of (a) loss of the floodplains that were important for buffering extreme water fluctuations in river flow during flooding episodes, and (b) the clearing of riparian forests, which provided protection against bank erosion. The occurrence of such floods generates further stress to fish populations, exacerbating the stresses already experienced due to the drought events. Changing drought and flood regimes thus need to be duly considered in the development of conservation strategies for the Evrotas fish species. Better management of the Evrotas during and following droughts and floods is of critical importance for the protection and persistence of the native fish community. Reducing unnecessary water consumption is probably the most viable conservation strategy for protecting the water resource and the water-dependent organisms. Some additional actions in the direction of alleviating the adverse impacts of human induced disturbances are considered below. Both the survival of fish during droughts and the rate of recovery following droughts depend strongly on the existence of suitable microhabitats and deep pool refugia, as well as on the existence of sufficient connectivity among habitat patches. Gravel abstraction and engineering works associated with flood control operations (e.g. river straightening, levelling and flanking) generate substantial damage to fish habitats and they also reduce the availability of drought refugia. Therefore, it is important to include the issue of fish habitats and fish refugia (e.g. deep pools) in future water management projects. Morphological disturbances affecting fish habitats (gravel abstraction, embankment) or fragmenting populations through impeding fish movements (dams and bridges preventing fish passage) should be minimised to the degree possible. Environmental impacts Final Report (Technical issue) – LIFE05 ENV/GR/00024 187/313 Environmental Friendly Technologies for Rural Development assessments through the cooperation of competent scientists should be undertaken when river regulation or agricultural projects are implemented. Water abstraction represents the greatest threat to the Evrotas fish and other elements of the biota. Maintenance of ecological flows until the end of the dry season, in at least some reaches, is a critical issue. It is suggested that some spring-fed reaches should be set aside and protected from overpumping. Possible areas to be included in the protection scheme are spring-fed sections of the Evrotas at Vivari and at confluence of the river with the Kollyniatiko stream. Another possible refugial area is at a middle portion of the Oinous stream, where a thriving S. keadicus population still persists. To support human activities which depend on water and are socially advantageous, alternative sources of water should be considered where possible. Due to isolated large pools play an important role in fish survival and the recovery process, some areas known to maintain large pools should be included in the protection scheme. In this context, care should be taken for the maintenance of pool water throughout the dry period (e.g. these pools should not be pumped in particularly dry years). Because of the hydraulic connection between surface water and groundwater, restrictive measures for groundwater pumping in the designated protected areas should also be considered. Native fishes should be watched closely, especially following periods of drought. Long-term monitoring of the water resources (water quantity and quality) and the fish living in the Evrotas should be established with the two-fold objective to constantly assess the conservation status of fish populations and to evaluate the influence of anthropogenic disturbances on the ecosystem. Impacts on riparian vegetation Until recently, riparian zone assessments are usually not included in evaluations of environmental assessments, although riparian forests constitute significant ecological pathways and refuges for terrestrial and aquatic biodiversity, predominately in landscapes marked by intense anthropogenic modifications and seasonally extreme arid conditions, such as in the case of Evrotas river. The preliminary assessment undertaken within this project has shown that along the main course of Evrotas, only six outstanding riparian woodland stands remain today. Along most river segments, the riparian woodland is either eliminated or severely degraded. The examined stands showed a variety of riparian woodland resources in various states of ecological status. A large proportion of the examined stands were in moderate condition, and although vegetation quality and channel condition scored relatively high within the QBR sub-scores, total vegetation cover and vegetation cover structure sub-scores were low in more than half of all surveyed sites. Conclusions and Recommendations From the analysis presented above it becomes apparent that intense water abstractions for irrigation during the last decades substantially affected the hydrological regime of the Evrotas river network which has thus become intermittent. The following facts and Final Report (Technical issue) – LIFE05 ENV/GR/00024 188/313 Environmental Friendly Technologies for Rural Development evidence support this: a) historical analysis of information, which reveals that in the past the Evrotas was a perennial river, b) the existence of fish in the majority of its tributaries in the recent past, c) the dramatic diminishing in river runoff, which is the highest compared with 10 major Balkan rivers (Skoulikidis et al., 2009; Skoulikidis, 2009), d) the abrupt interruption of river flow at Sparta and Kelefina bridges in summer (contrary to Vivari area, where supporting karstic springs lead to a more gradual decrease of river flow) and e) the estimation that the water balance without olive groves irrigation would ensure a substantial increase of summer flow. Climatic models predict a reduction in precipitation in the Mediterranean, with an increased frequency and severity of droughts and a reduction of summer and autumn river runoff. At the same time, agriculture will require more water especially in the hotter drier regions. An increase in water temperatures and lower river flows in the south will also affect water quality (EEA, 2009). In the case of Evrotas river, surface runoff has dramatically diminished and groundwater levels have severely dropped. Hence, climate change will further deteriorate aquatic quantity and quality. The ichtyological research illustrated how the 2007 draught caused significant fish deaths that may affect the community composition in the long term. The fish communities may take years to recover, and only if hydrological disturbances will not occur in the meanwhile. However, the frequency of summer desiccation appears to rise diachronically due to the increase of water abstractions. A series of dry summers or extreme flood events may slow down the recovery process of the communities and/or significantly affect their structure. To control floods and for construction purposes, massive exractions of inert material from the river bed takes place thus causing the disappearance of several habitat types and summer refuges (deep water pools) with dramatic consequences mainly on the fish fauna. It should be noted that if the ecological status of tributaries would be based on ichthyofauna, the vast majority of them would be termed (with expert judgment) poor or bad. Hence, a better management approach of Evrotas basin is urgently needed. In the following, a number of actions are proposed to be applied in the framework of the Evrotas River Basin Management Plan to reduce adverse effects in the river system: Reduction of water abstractions A scenario focusing on reducing the irrigation water use by 40% is proposed. The implementation of that measure will improve the hydrological balance of the basin (Fig. 5.3.33). The surface and subsurface runoff in summer will increase from 2.9 to 6.5 m3/s (increase by 2.25 times). This would have positive effects on the conservation of aquatic and riparian ecosystems and would diminish river bank erosion. The proposed scenario is feasible through the improvement of the irrigation systems (installation of closed pipes) and the implementation of best agricultural practices (drip irrigation, development of irrigation systems according to the water needs of plants and the soil moisture), restructuring of agriculture, etc. Final Report (Technical issue) – LIFE05 ENV/GR/00024 189/313 Environmental Friendly Technologies for Rural Development Figure 5.3.33. Monthly surface and subsurface runoff according to the current hydrological balance and according to a 40% irrigation water reduction scenario. Minimisation of morphological modifications The survival of aquatic biota and especially of fish during summer draught directly depends on the existence of deep remaining ponds that act as refuges, and over and above on the connectivity between aquatic habitats. Hence, morphological alterations, such as leveling and extraction of river bed material should be minimised. It is worth noting that the effectiveness of the currently applied flood control works (levee construction using inert material taken from the river bed) is doubtful, since gravels and pebbles tend to be transported again to the river bed during the next flood event. Finally, it is recommended Environmental Impact Assessment Studies concerning river corridor arrangement or land reclamation works should take into account the opinion of experts. In addition, it is of first priority to protect and restore riparian vegetation. Riparian vegetation plays an important role not only for flood control but also in improving instream aquatic quality and ecological conditions. Thus, there are important opportunities for conservation and restoration riparian woodlands within the frame of Evrotas River Basin Management Plan. Up-to-date flood control measures Current flood control measures are implemented in the plain areas with doubtful results, as previously mentioned. Such measures are large scale interventions, bearing high economical cost and having dramatic effects on aquatic and riparian habitats. The implementation of flood control measures on the mountainous and semi-mountainous part of the basin, with afforestations, construction of small reservoirs and inhibitory weirs, artificial groundwater recharge and conservation/remediation of riparian vegetation in the riparian zones, should be the first priority (Mariolakos et al., 2007; Dimitriou, 2007). This will inhibit flood generation processes. Flood control measures should be mild and combinational in order to conserve landscapes and disturb water balance. The uncontrollable development on floodplains significantly affects the extend and spatial display of floods. It is hence recommended to designate flood protection zones, where specific activities will be prohibited and may hinder floods to proceed downstream. Protection and conservation of fish fauna Final Report (Technical issue) – LIFE05 ENV/GR/00024 190/313 Environmental Friendly Technologies for Rural Development In the first instance, it is proposed that a perennial flow regime will be maintained, at least in certain areas which are of vital importance for fish conservation and management. We identified four areas of conservation priority, all of which include reaches fed by important springs: the Vivari and the Skoura areas, the Evrotas segment upstream the confluence of Kolliniotiko stream, and the Oinous midway. We recommend that these areas should be included in a management plan and be protected from surface water abstraction, while groundwater abstraction should be carefully regulated and should be designated as core areas for fish conservation. Bearing in mind that the fish fauna of the Evrotas contains unique range-restricted endemics, it is proposed that the local fish communities should be monitored on a regular basis to ensure that any impacts from human activities or water management measures are detected as early as possible. Special consideration must be given to the evaluation of the population status and trends during drought periods, when the frequency of sampling should increase. A monitoring programme designed to provide assessment of the chemical and ecological status of the Evrotas river is to be established, in accordance with the demands of the Water Framework Directive. With slight modifications and expansions, this programme can well accommodate the needs of fish conservation so that to provide on a routine basis information on the status of fish populations and assessments of the human impacts on the ecosystem. Finally, it is important that a study will be undertaken to examine the minimum flow requirements in the area of the scheduled construction of in the Oinous R. dam, and this study will take into account the results of the present study. The implementation of the proposed actions will be only possible in the framework of an Integrated Management Plan of Evrotas River Basin. The development and continuous update of such a Plan will serve as the basis for water resources management, protection and conservation of the ecosystem both during ―normal‖ hydrological years as well as when extreme climatic events occur. Final Report (Technical issue) – LIFE05 ENV/GR/00024 191/313 Environmental Friendly Technologies for Rural Development Appendix: Detailed Water Quality and Ecological Quality Results Table 1. Habitat Modification Score (HMS) and Habitat Quality Assessment (HQA) of the examined Evrotas Basin stations related to specific pressures. Canalisation Halting-crossings Algae Aquatic plants in river channel 1 78 ~ ~ ~ ~ ~ ~ *** ** 2 Kastaniotiko 17 66 * * * * * * *** ** 3 Vresiotiko 1 81 ~ ~ ~ ~ * ~ *** * 4 Evrotas Springs (Scortchinou) 7 88 ~ * * ~ * * *** *** 5 Evrotas (Palaiochora) 0 92 ~ ~ ~ ~ * ~ *** ** 6 Kotitsanis (downstream) 1 87 ~ ~ ~ ~ * ~ *** *** 7 Oinous (mid-reach) 1 69 ~ ~ ~ ~ * ~ *** ** 9 Oinous (Karyes) 2 86 ~ ~ ~ ~ * ~ *** *** 10 Oinous (Kelefina Bridge) 17 51 * ** ** * * ~ * * 11 Oinous (upstream Kelefina B.) 2 79 ~ ~ ~ ~ * ~ ** * 12 Oinous Tributary (Sofroni) 1 82 ~ ~ ~ ~ * ~ ** ** 14 Lagkada (upstream) 0 92 ~ ~ ~ ~ * ~ *** * 15 Lagkada (Trypi) 1 94 ~ ~ ~ ~ * ~ *** ** 16 Lagkada (Vatopouleika) 18 79 * ~ ~ * * ~ ** *** 17 Skatias (Palaiologio) 11 66 ** ** * ~ ** ~ * * 18 Paroritis (Paroreio) 4 76 * ~ ~ ~ ~ ~ ** ** 19 Tyflo (Riviotissa) 6 68 * * ~ ~ ** ~ ** * 20 Mylopotamos (Ag.Kyriaki) 25 44 * ** * * * ~ * * 21 Skatias (Nikolareika) 17 49 * * * ~ * ~ ** ** 22 Magoulitsa (downstream) 27 38 * * *** * * ~ ** * 23 Perdikaris 18 42 * * * * * ~ ** * 24 Nikova (Roman Aquaduct) 4 79 ~ ~ ~ ~ * ~ *** ** 25 Xerilas 2 85 ~ ~ ~ ~ ** ~ *** *** 26 Evrotas (Pellana-Sellasia Bridge) 4 74 ~ ~ ~ ~ * ~ ** ** 27 Kardaris (downstream) 23 64 ** * ~ * * ~ * ** Site Number Final Report (Technical issue) – LIFE05 ENV/GR/00024 192/313 Hydrologic Types Chaneel & Bank Modification Kardaris (upstream) Riparian Vegetation Water Abstraction 1 HQA Stream Name HMS General pressures and their characteristics Halting-crossings Algae Aquatic plants in river channel ~ ~ ~ * * ** ** 11 70 ~ ** ~ ~ ~ * * *** Kolliniotiko (Kollines) 8 81 ~ ~ ~ ~ * ~ *** ** 34 Kotitsanis (Logkanikos) 5 67 ~ * ~ ~ ~ ~ ** ** 37 Evrotas (Sparta-Kastori) 29 77 * * * * ** ** ** ** 38 Evrotas (upstream WTTP) 45 57 * *** * * * ** ** ** 39 Evrotas (downstream WTTP) 37 44 * *** * * * ** ** ** 42 Kakaris (Dipotama) 4 82 ~ ~ ~ ~ * * *** ** 44 Fteroti (Hellenistic Bridge) 14 77 * * ~ * * ~ *** *** 46 Gerakaris (upstream) 8 76 * ~ ~ ~ ~ ~ ** ** 47 Gerakaris (downstream) 22 68 * * ~ * * ~ ** * 48 Evrotas (Skoura) 26 70 * * ~ ~ ** ** *** * 49 Gerakaris-Rasina Confluence 27 61 * * * * ** ~ * ** 50 Evrotas (Leukochoma) 14 69 * * ~ ~ ** * ** ** 51 Vasilopotamos 52 58 * ~ ** ~ *** *** * * 52 Evrotas (Skala) 88 58 * *** *** * *** ** * ** 53 Evrotas (estuary) 89 61 * *** *** * *** ** * ** Site Number Voutikiotis 30 Evrotas (Achouria) 31 ~: no effect, *: slight effect, **: moderate effect, ***: significant effect Final Report (Technical issue) – LIFE05 ENV/GR/00024 193/313 Hydrologic Types Canalisation ~ 29 Riparian Vegetation Chaneel & Bank Modification 80 HQA 6 Stream Name HMS Water Abstraction Environmental Friendly Technologies for Rural Development Environmental Friendly Technologies for Rural Development Table 2. Classification of the physico-chemical status of Evrotas basin sampling sites for the hydrological year 2006-07. The mean of all seasons was considered as the final physico-chemical status. Numbers represent scores, where high: >4-5, good: >3-4, moderate:>2-3, poor: >1-2 and bad <1. ID 1 2 3 4 5 6 7 9 10 11 12 14 15 16 17 18 19 20 21 22 23 24 25 26 27 29 30 31 34 37 38 39 42 44 46 47 48 49 50 51 52 53 54 Station name Kardaris (upstream) Kastaniotiko Vresiotiko Evrotas Springs (Scortchinou stream) Evrotas (Scortchinou) (Palaiochora) Kotitsanis (downstream) Oinous (mid-reach) Oinous (Karyes) Oinous (Kelefina Bridge) Oinous (upstream Kelefina B.) Oinous Tributary (Sofroni) Lagkada (upstream) Lagkada (Trypi) Lagkada (Vatopouleika) Skatias (Palaiologio) Paroritis (Paroreio) Tyflo (Riviotissa) Mylopotamos (Ag.Kyriaki) Skatias (Nikolareika) Magoulitsa (downstream) Perdikaris Nikova (Roman Aquaduct) Xerilas Evrotas (Pellana-Sellasia Bridge) Kardaris (downstream) Voutikiotis Evrotas (Achouria) Kolliniotiko (Kollines) Kotitsanis (Logkanikos) Evrotas (Sparta-Kastori) Evrotas (upstream WTTP) Evrotas (downstream WTTP) Kakaris (Dipotama) Fteroti (Hellenistic Bridge) Gerakaris (upstream) Gerakaris (downstream) Evrotas (Skoura) Gerakaris-Rasina Confluence Evrotas (Leukochoma) Vasilopotamos Evrotas (Skala) Evrotas (estuary) Evrotas (Dafni) Physico-Chemical Status Spring Summer Winter Average 3,9 4,4 4,1 3,2 2,9 2,6 2,9 3,9 3,6 4,4 3,96 3,6 3,1 3,9 3,5 3,4 3,9 3,7 3,6 3,9 3,7 3,6 3,6 4,4 3,8 4,2 3,2 4,4 3,9 3,8 4,3 4,1 3,6 3,6 4,4 3,8 3,9 3,9 4,2 4,4 4,3 3,9 3,6 4,2 3,9 4,2 4,2 4,2 2,9 2,9* 3,6 4,4 3,95 2,5 2,0 2,3* 2,4 2,4 2,4* 3,1 3,3 3,2 3,9 4,2 4,02 3,1 3,1 3,6 4,1 3,8 3,6 4,1 3,8 3,6 3,6 3,6 4,3 3,9 3,6 3,6 3,6 3,6 3,9 3,7 2,8 3,8 3,3 3,9 3,6 4,2 3,9 3,6 3,9 3,6 3,7 3,2 3,9 3,9 3,6 3,2 2,6 4,1 3,3 3,6 4,3 3,9 3,6 4,1 3,8 3,6 4,0 4,0 3,8 3,2 4,3 3,7 2,6 3,2 2,6 2,8 3,2 4,0 3,6 2,5 3,6 3,04 3,6 3,7 3,6 2,9 3,2 2,6 2,9 3,9 3,6 3,7 3,6 3,6 *: pesticides have been included in the assessment system Physico-chemical status (2006-07)/ Number of stations (%): High: 5 (11.6%) Good: 31 (72.1%) Final Report (Technical issue) – LIFE05 ENV/GR/00024 Moderate: 7 (16.3%) Poor: 0 Bad: 0 194/313 Environmental Friendly Technologies for Rural Development Table 3. Classification of the biological status of Evrotas Basin sampling sites for the hydrological year 2006-07 based on macroinvertebrate fauna for all three seasons. The mean of all seasons was considered as the final biological status. Numbers represent scores, where high: >0.94, good: >0.72-0.94, moderate: >0.47-0.72, poor: >0.24-0.47 and bad <0.24. ID 1 2 3 4 5 6 7 9 10 11 12 14 15 16 17 18 19 20 21 22 23 24 25 26 27 29 30 31 34 37 38 39 42 44 46 47 48 49 50 51 52 53 54 Station Name Kardaris (upstream) Kastaniotiko Vresiotiko Evrotas Springs (Scortchinou stream) Evrotas (Palaiochora) Kotitsanis (downstream) Oinous (mid-reach) Oinous (Karyes) Oinous (Kelefina Bridge) Oinous (upstream Kelefina B.) Oinous Tributary (Sofroni) Lagkada (upstream) Lagkada (Trypi) Lagkada (Vatopouleika) Skatias (Palaiologio) Paroritis (Paroreio) Tyflo (Riviotissa) Mylopotamos (Ag.Kyriaki) Skatias (Nikolareika) Magoulitsa (downstream) Perdikaris Nikova (Roman Aquaduct) Xerilas Evrotas (Pellana-Sellasia Bridge) Kardaris (downstream) Voutikiotis Evrotas (Achouria) Kolliniotiko (Kollines) Kotitsanis (Logkanikos) Evrotas (Sparta-Kastori) Evrotas (upstream WTTP) Evrotas (downstream WTTP) Kakaris (Dipotama) Fteroti (Hellenistic Bridge) Gerakaris (upstream) Gerakaris (downstream) Evrotas (Skoura) Gerakaris-Rasina Confluence Evrotas (Leukochoma) Vasilopotamos Evrotas (Skala) Evrotas (estuary) Evrotas (Dafni) Biological status (macroinvertebrates) Spring Summer Winter Average 0.785 0.536 0.660 0.505 0.724 0.775 0.668 0.914 1.165 0.968 1.016 0.77 0.519 0.644 1.153 1.001 1.077 0.979 0.910 0.944 1.329 1.000 1.082 1.137 1.198 1.187 1.193 0.783 0.783 1.045 0.955 1.184 1.061 1.263 1.263 0.631 0.990 0.810 0.677 1.012 1.215 0.968 1.112 1.014 1.063 0.917 0.630 0.769 0.690 0.636 0.663 0.221 0.218 0.219 0.462 0.331 0.396 0.676 0.575 0.620 0.992 0.718 0.855 0.710 0.710 0.934 0.986 0.960 0.997 0.984 0.986 0.838 0.838 1.01 0.731 0.868 0.91 0.983 0.947 0.973 0.844 0.908 0.544 0.544 0.959 0.767 0.782 0.836 0.968 1.053 1.074 1.032 0.667 0.597 0.771 0.678 0.707 0.681 0.694 0.949 0.485 1.195 0.876 1.034 0.715 0.874 1.050 1.072 1.007 1.043 0.819 0.819 0.391 0.784 0.278 0.484 0.299 0.299 0.501 0.394 0.448 0.756 0.780 0.768 0.801 0.907 0.854 0.760 0.823 0.792 0.390 0.390 Biological status (2006-07)/ Number of stations (%): High: 14 (32.6%) Good: 12 (27.9%) Moderate: 8 (18.6%) Final Report (Technical issue) – LIFE05 ENV/GR/00024 Poor: 3 (7%) Bad:1 (2.3%) 195/313 Environmental Friendly Technologies for Rural Development Table 4. The ichthyological reference conditions for each biotic type. Biotic Type Upper Evrotas Middle Evrotas Richness and Abundance 2 to 3 species - S. keadicus>50 % of total abundance Abundance varies in relation with microhabitats and other parameters but should be >300 individuals 4 to 5 (S. keadicus, P. laconicus, Τ. Spartaaticus, A. anguilla and S. fluviatilis) - Abundance should be >500 individuals -Percentage of S. keadicus and Conditions of Reproduction Type specific species In good habitat conditions reproduction of the species S. keadicus is observed. S. keadicus P. laconicus High abundance of Τ. Spartaaticus when appropriate habitats exist. S. keadicus P. laconicus, Τ. Spartaaticus Reproduction of S. fluviatilis S. keadicus P. laconicus, Τ. Spartaaticus A. anguilla S. fluviatilis Τ. Spartaaticus individuals should be >80% Estuarie s -5 species (S. keadicus, P. laconicus, Τ. Spartaaticus, A. anguilla and S. fluviatilis), -High abundance >2000 individuals - The dominant species is Τ. Spartaaticus (>80%) - Absence of invasive species Final Report (Technical issue) – LIFE05 ENV/GR/00024 196/313 Size classes - S. keadicus: at least four age classes, presence of individuals > 15 cm. Percentage of S. keadicus individuals >10 cm should be >60% -S. keadicus at least three age /size classes - Τ. Spartaaticus (2 to 3 size classes) - Percentage of S. keadicus individuals >10 cm should be >60% - Percentage of Τ. Spartaaticus individuals >5cm should be >70% Percentage of Τ. Spartaaticus individuals >5cm should be >70% Environmental Friendly Technologies for Rural Development Table 5. The ichthyological multiparametric index. List of metrics that where selected for the spatial based method and the values of metrics which correspond in the categories of ecological quality. The values concern the data set for the index development. Biological status METRICS High Good Moderate Poor Bad Upper Evrotas 3 2 1 1 0 Middle Evrotas 4-5 3 2 1 0 Estuaries 5 4 3 2 0-1 Upper Evrotas >300 100300 50-100 5-50 <5 Middle Evrotas >500 300500 100-300 10-100 <10 Estuaries >2000 10002000 200-1000 30-1000 <30 Estuaries 100% 90100% 70-90% 50-70% <50% Percentage of S. keadicus Upper Evrotas >50% 4050% 20-40% 5-20% <5% Proportion of S. keadicus >10cm Upper Evrotas, Middle Evrotas >60% 4060% 25-40% 5-25% <5% Proportion of (S. keadicus+T. Spartaaticus) Middle Evrotas >80% 6080% 40-60% 10-40% <10% Percentage of T. Spartaaticus Estuaries >80% 6580% 50-65% 10-50% <10% Proportion T. Spartaaticus >5cm Middle Evrotas, Estuaries >70% 5070% 30-50% 15-30% <15% Species‟ richness Species‟ Abundance Percentage of native species Type Final Report (Technical issue) – LIFE05 ENV/GR/00024 197/313 Environmental Friendly Technologies for Rural Development Figures 9 & 10. The biological quality based on fish fauna for the years 2007 and 2008 (with ▲ are symbolized sites where the index did not responded to the existing pressures). Final Report (Technical issue) – LIFE05 ENV/GR/00024 198/313 Environmental Friendly Technologies for Rural Development Table 6. Classification of the ecological status (ECO) of Evrotas Basin sampling sites for the hydrological year 2006-07 based on hydromorphological (H-M), physico-chemical (P-C) quality 1 2 3 4 5 6 7 9 10 11 12 14 15 16 17 18 19 20 21 22 23 24 25 26 27 29 30 31 34 37 38 39 42 44 46 47 48 49 50 51 52 53 54 Kardaris (upstream) Kastaniotiko Vrysiotiko Evrotas Springs (Scortchinou stream) Evrotas (Palaiochora) Kotitsanis (downstream) Oinous (mid-reach) Oinous (Karyes) Oinous (Kelefina Bridge) Oinous (upstream Kelefina B.) Oinous Tributary (Sofroni) Lagkada (upstream) Lagkada (Trypi) Lagkada (Vatopouleika) Skatias (Palaiologio) Paroritis (Paroreio) Tyflo (Riviotissa) Mylopotamos (Ag.Kyriaki) Skatias (Nikolareika) Magoulitsa (downstream) Perdikaris Nikova (Roman Aquaduct) Xerilas Evrotas (Pellana-Sellasia Bridge) Kardaris (downstream) Voutikiotis Evrotas (Achouria) Kolliniotiko (Kollines) Kotitsanis (Logkanikos) Evrotas (Sparta-Kastori) Evrotas (upstream WTTP) Evrotas (downstream WTTP) Kakaris (Dipotama) Fteroti (Hellenistic Bridge) Gerakaris (upstream) Gerakaris (downstream) Evrotas (Skoura) Gerakaris-Rasina Confluence Evrotas (Leukochoma) Vasilopotamos Evrotas (Skala) Evrotas (estuary) Evrotas (Dafni) 1 17 1 7 0 1 1 2 17 2 1 0 1 18 11 4 6 25 17 27 18 4 2 4 23 6 11 8 5 29 45 37 4 14 8 22 26 27 14 52 88 89 Final Report (Technical issue) – LIFE05 ENV/GR/00024 4.1 2.9 3.96 3.5 3.7 3.7 3.8 3.9 4.1 3.8 3.9 4.3 3.9 4.2 2.9 3.95 2.3 2.4 3.2 4.02 3.1 3.8 3.8 3.6 3.9 3.6 3.7 3.3 3.9 3.7 3.6 3.3 3.9 3.8 3.8 3.7 2.8 3.6 3.04 3.6 2.9 3.7 3.6 0.660 0.67 1.02 0.64 1.08 0.94 1.14 1.19 0.78 1.06 1.26 0.81 0.97 1.06 0.77 0.66 0.22 0.39 0.62 0.85 0.71 0.96 0.99 0.84 0.87 0.95 0.91 0.54 0.84 1.03 0.68 0.69 0.88 0.87 1.04 0.82 0.484 0.299 0.448 0.768 0.854 0.792 0.390 Municipal WW Difuse pollution Fruit juice Olive mills Significant abstractions ECO Β P-C Station Name H-M Station ID elements and macroinvertebrate fauna (B) for all three seasons (WW: wastewater) Χ Χ ? Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ ? Χ Χ Χ Χ Χ Χ Χ Χ Χ ? Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ ? Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ Χ 199/313 Χ Χ Environmental Friendly Technologies for Rural Development Figure 11. Ecological status based on hydromorphological, physico-chemical quality elements and the macroinvertebrate fauna for all three seasons High: 0 (0%) Good: 30 (69.8%) Moderate: 8 (18.6%) Final Report (Technical issue) – LIFE05 ENV/GR/00024 Poor: 4 (9.3%) Bad:1 (2.3%) 200/313 Environmental Friendly Technologies for Rural Development 26 Evrotas (Palaiochora) Oinous (Kelefina Bridge) Oinous (upstream Kelefina B.) Evrotas (Pellana-Sellasia Bridge) 30 37 48 52 Evrotas Evrotas Evrotas Evrotas 5 10 11 Ecological status 2008 Β (F) 2006-7 2006-7 (Achouria) (Sparta-Kastori) (Skoura) (Skala) Β (F) 2008 Β(M) 2007 PC 2006-7 Station Name H-M 2006-7 Station Table 7. Classification of the overall ecological status (ECO) of Evrotas Basin sampling sites for the hydrological year 2006-07 based on hydromorphological (H-M), physico-chemical (P-C) quality elements, macroinvertebrate fauna (B) and ichtyofauna (F) for common sites (between fish and macroinvertebrates). E.J. E.J. 2006-07: May 06 September 06, March 07 2007: September 2008: September E.J.: expert judgement Final Report (Technical issue) – LIFE05 ENV/GR/00024 201/313 Environmental Friendly Technologies for Rural Development TASK 3 - Drainage canal and river bank management 1. Management of Drainage Canals Nitrogen (N) and Phosphorus (P) inputs are essential for increasing agricultural production and maintaining the economic viability of farming systems worldwide. Increases in worldwide use of N fertilizers combined with average N use efficiencies of 50% have contributed to increase of N concentration of surface waters. Fertilized farmland is frequently the main non-point source of nitrogen and phosphorus excess input to surface and groundwater ecosystems (European Environment Agency, 1999). A number of approaches have been identified to reduce nutrient (nitrate) losses to surface waters including controlled drainage, diverting or directing drainage discharge through natural or constructed wetlands, bioreactors-zones that surround or border the drain pipes and in stream denitrification (Madramootoo et al., 2007; Wang et al., 2007; Burchell et al., 2005; Evans et al, 1995; Fausey et al., 2004; Skaggs et al., 2005; Herzon and Helenius, 2008). Agricultural drainage canals have been used in poorly drained agricultural landscapes for regulating water retention to allow for crop production and for mitigating pollution (nutrients, pesticides and herbicides) as well as for erosion prevention. Drainage canals provide habitat to both aquatic and terrestrial biota and operate as nutrient pool due to decomposition of OM (lacking otherwise in dry and intensively managed agricultural areas). Drainage canals, usually situated in river deltas, which are areas of accumulation of organic debris (sediment deposition) and growth of macrophytes, such as Phragmites australis (common reeds) and Arundo donax (giant reeds). Such areas provide the suitable anaerobic conditions and electron donors for denitrification (Hiscock and Grischek, 2002). In addition, plants (like reeds) can also promote phosphorus absorption onto the sand and prevent ammonia accumulation by the release of oxygen from the roots. The removal of N in riparian wetlands, zones, strips and drainage canals is mainly attributed to denitrification. Therefore, drainage canals are likely to act both as narrow buffers in filtering runoff waters and phosphorus pools during the dormant stage. Although, ditch performance has been shown to be highly variable, no holistic studies are available on the functioning of small field drains, with or without permanent water (Legacherie et al., 2006). Plant N and P uptake is often considered less important compared to mitigation of nutrients in riparian buffers due to denitification and phosphate adsorption in sediments. Most of the nutrients uptaken by vegetation are released back into the water once the vegetation dies and decomposes (Verchot et al., 1997; Schade et al., 1991). On the other hand, a pan-European study demonstrated that annual N retention in vegetation and litter accounts for 13-99% of the total mitigation (Hefting et al., 2005). Although higher N uptake and retention is found in forested buffers, periodic harvesting of herbaceous biomass contributes considerably to the N retention. It has been shown that plants like reeds uptake nutrients during the growing period and release them back in aquatic environment and their roots after the foliar period (Graneli et al., 1988). Consequently, cutting the reeds the proper time, results in the overall reduction of nutrients in the receiving surface water bodies (Nikolaidis et al., 1996). Final Report (Technical issue) – LIFE05 ENV/GR/00024 202/313 Environmental Friendly Technologies for Rural Development The chemistry of such systems is very complex with dissolve, colloidal and particulate materials biogeochemically interacting within soils, sediments, and organisms. Elucidating the functioning of drainage canals in removal of chemicals will assist in the design and implementation of water quality protection technologies (Needeman et al., 2007), based on natural attenuation mechanisms. In Greece, 39000 hectares of such canals exist in the delta plains of Evrotas, Achelloos, Aksios and other Rivers (www.minagric.gr). The objective of this task was to assess the efficiency of natural attenuation of nutrients in a drainage canal of the Evrotas River Delta and demonstrate its efficacy as a remedial technology. Methodology - The drainage canal under study was located in Evrotas River delta in Greece and drained fields of orange groves (totally 4500 m2). The length of the canal was 180m and the width of the vegetated zone was approximately 1.5m. The average density growth of both Phragmites australis and Arundo donax was 15 clones per m2. Plants covered two distinct areas of 160 and 20m length for Phragmites australis and Arundo donax, respectively. To monitor the temporal 3-dimensional variability of hydrology and chemistry of surface and ground water in the drainage canal, eleven multi-level (3, 4 and 5m) wells were installed (Fig. 5.4.1). Field sampling (groundwater and surface water sampling) was conducted in order to assess the fate and transport of nutrients as they move from the groundwater to the drainage canal. In addition, laboratory studies were used to assess the biogeochemical processes that control the Nitrogen and Phosphorous cycles and evaluate the efficiency of the sediments to attenuate pollutants. Finally, the nutrient (nitrogen and phosphorus) uptake fluxes by Phragmites australis and Arundo donax were measured on a monthly basis in order to determine the timing of harvesting reeds that will maximize the removal of nutrients by plant uptake but also keep the N/P ratio high enough to avoid toxic algal blooms (Nikolaidis et al., 2005). Multi-level probe clusters Drainage Canal A1 A3 A2 Multi-level well clusters A9 A4 Drainage Canal A7 A6 A5 A10 A11 A8 Figure 5.4.1. Multi-level probe design in relation to drainage canal. Field hydrologic studies - The water depth of the wells was monitored on a monthly basis. The hydraulic characteristics of the subsurface were determined by conducting single well pumping tests and the infiltration capacity of the fields was estimated by conducting in situ infiltration experiments. Horton‘s equation was used to obtain the kt infiltration rate ( f f c f co f c e where fco and fc were the initial and final infiltration rates and k was an empirical constant. The surface runoff (overland flow) to Final Report (Technical issue) – LIFE05 ENV/GR/00024 203/313 Environmental Friendly Technologies for Rural Development the drainage canal was estimated by converting the measured daily precipitation (Elos station, at 4 m altitude) to hourly (WDMUtil version 2.2, Basin) and then subtracting the infiltration rate. Potential water deficit was also estimated by subtracting daily potential evapotranspiration (PET) (Hamon‘s equation) from precipitation. Surface and ground water chemistry monitoring - The multilevel wells and the drainage canal water were sampled every 2 months (11/06, 1/07, 3/07, 5/07, 7/07, 11/07, 3/08, 5/08), with a peristaltic pump with low flow (< 1 L/min), so as turbidity was maintained in minimum levels, and the physicochemical parameters pH, temperature, conductivity, dissolved oxygen (D.O.), and, redox potential (Eh) were measured in situ using the following electrodes: Orion 9107 pH meter, Orion 081010 D.O. meter, and Orion 011050 Conductivity meter. The samples were filtered through a 0.45 µm Nylon filter and analyzed using a Hack 2010 spectrophotometer for nitrates (NO3-N, Cadmium Reduction Method, 8039), nitrites (NO2-N, Diazotization Method, 8507), ammonia (NH3N, Salicylicate Method, 10023), phosphates (PO4-P, phosVer3 Method, 8048), total phenols (T.phenols, Folin Ciocalteu method), dissolved organic carbon (Direct Method Patent Pending, 10129) or by a TOC analyzer (Shimadzu 5050), after the removal of inorganic carbon by air sparging for 10 min), chemical oxygen demand (COD, Reactor Digestion Method, 8000), and total nitrogen (TN, TNT Persulfate Digestion Method, 10071) or Kheldalh nitrogen (TKN, by the Kjeldahl digestion technique with a Hach digestahl digestion apparatus, Nessler method, 8075). Dissolved organic nitrogen was derived by the abstraction of ammonia from the TKN. Laboratory process studies Sediment physico-chemical characterization - Sediments were analyzed for the following physico-chemical parameters, using standard methodologies (Nikolaidis et al., 1999): porosity, dry bulk density (Bowles, 1986), pH and conductivity (measured in a 1:2.5 soil to water ratio), and particle size distribution (wet sieving, 2-0.063 mm). When the soil sample was fine (less than 63 μm), Laser Diffraction Size Analysis was conducted. Soil organic C was determined by the Walkley-Black (WB) acid dichromate digestion technique (Soil Survey Laboratory Methods Manual, 2004) and Total Kjeldahl N and Total Phosphorus by the Kjeldahl digestion technique. All sediment analysis was run in triplicates. Nitrate release kinetic experiment - The experiment was carried out at 100 mL flasks using 10 g of sediment samples (< 2 mm fraction) and adding 100 mL synthetic water as release solution. The samples were placed on a shaking table (200 rpm) under 20 0C, for 21 days. The release solution composition had similar geochemistry with drainage canals at Skala (without nutrients): Ca2+ 2.0 mM, Mg2+ 0.6 mM, SO42- N0.6 mM, Na 4.99 mM, HCO3- C4.99 mM, and Cl- 0.752 mM. The ionic strength of the solution was 1.1 mM and the pH was regulated at 7.8. The samples were analyzed in triplicates on 1st, 3rd, 7th, 10th, and 21st day). The supernatant was filtered through a 0.45 nylon filter and analyzed using a Hack 2010 spectrophotometer for nitrates, ammonia, total Kjeldahl nitrogen and dissolved organic nitrogen with the aforementioned standard methods. Potential mineralizable nitrogen - The methodology suggested from Stamati et al., (2009) was also applied to assess the exchangeable mineral nitrogen (EMN), the Final Report (Technical issue) – LIFE05 ENV/GR/00024 204/313 Environmental Friendly Technologies for Rural Development potential mineralizable nitrogen (PMN), potential total soluble nitrogen (PTSN). The aromaticity (DOC and DON aromaticity indices, ArI) of the soluble OM was also calculated and the origin of ―exogenous‖ SOM (the higher the ArI the more the plant derived SOM) was assessed. Sediment redox potential - Redox potential of the sediments, as an indication of the potential for denitrification, was estimated by a batch kinetic study. Thus, 25 g of sediment and 250 mL D.I. water were added in a beaker of 500 mL. The suspension was stirred continuously with a magnetic stirrer and constant flow of nitrogen gas (N 2) was added in the system in order to remove the oxygen (O2). The beaker was sealed and Eh, DO and temperature were monitored with time until the system was stabilized. Release and adsorption of dissolved inorganic phosphorus - To study the sorption of phosphate in sediment the adsorption isotherm at 20 0C and pH 7.8 was conducted by filling the 100 ml flasks with 5 g of sediment and 100 mL of synthetic drainage canal water solution with concentrations of phosphate-phosphorus 0.1, 0.3, 0.6, 0.8, 1, 3, and 5 mg/l. The release of DIP was studied under the same conditions without the addition of phosphorous. The samples were placed on a shaking table for 4 days (200 rpm). After the end of the experiment the dissolved phase of the supernatants was analyzed for PO 4P. Phragmites australis and Arundo donax nutrient uptake - Above and below-ground plant (reed) biomass was sampled from three randomly selected plots (1m x 1m) on a monthly basis, from October 2006 to August 2008, to determine the plant uptake rates of nutrients (nitrogen and phosphorus). Four plants were harvested from the first plot (S1) corresponded to Arundo donax (Giant reeds) and ten from each of the other two plots (S2 and S3) corresponded to Phragmites australis (common reeds). Below-ground biomass (roots and rhizomes) was sampled only from the S1 plot. The above ground biomass was separated in situ into three parts from the top to the base of the shoot. Upper part was mostly consisted of leaves, middle part of leaves and stems and lower part of stems. All harvested biomass portion samples were gently washed by hand, to get rid of soil and adhering particles, dried (90 oC, 48 h), weighed, ground into fine powder by a micro-hammer mill, and subsamples were ground sieved at 0.5 mm and stored before nutrient analysis. Nitrogen and phosphorus concentration of the collected plant samples were determined by the Kjeldahl digestion technique (Nessler method, 8075 for nitrogen and phosVer3 Method, 8048 for phosphorus). Results Hydrologic Balance - Based on hydraulic conductivity (0.691 m/day for groundwater, and 0.587 m/day for Drainage canal recharge) and hydraulic gradients established by the piezometric heads of the water table, the velocity of ground water was determined to be 0.062 m/day (travel time, 16 d/m) and close to drainage canal-where the gradient is steeper-was 0.354 m/day (travel time, 3 d/m). The infiltration rate under steady state of moisture was estimated using Horton‘s equation to be 0.0135 cm/min and the constant K was 0.125±0.003 cm/min. Average potential evapotranspiration was 899±547 mm, and precipitation was 543±199 for the hydrologic years 2000-01 to 2006-07. Precipitation during 2006-2007 was 425 mm, while for 2007-2008 (until 31/05/2008) was 492 mm, Final Report (Technical issue) – LIFE05 ENV/GR/00024 205/313 Environmental Friendly Technologies for Rural Development indicating dry conditions. The estimated average potential water deficit for the studied region is presented in Figure 5.4.2 and was estimated to last from April to October. The corresponding variation in the piezometric heads of groundwater is presented in Figure 5.4.3. Surface runoff to the drainage canal was estimated to take place only during precipitation events higher than 25 mm/day. Surface and ground water chemistry monitoring - Total and seasonal averages results of the eight sampling sessions of ground and surface water are presented in table 5.4.2 and figure 5.4.4 (Seasonal averages are presented in Tables 5.4.6 and 5.4.7 at the end of this section). Groundwater of the orange grove field was anoxic with high COD, phenols, DOC and DON and ammonia and seasonally with nitrates. The high organic load is due to the type of soil which is tyrf. The drainage canal had significantly lower concentrations of ammonia, COD, and DOC. Nitrate concentrations in drainage canal were less than in ground water with the exception when there was significant contribution from surface runoff. There was generally a consistent decrease of pollutants between ground water and drainage canal suggesting natural attenuation mechanisms in action. Organic N was ranging on average (sampling sessions) from 34% to 84% of total N for ground water. The average ratio of DOC to DON in ground water was relatively low ranging from 3.6 to 33.8 with a total average of 15, suggesting abundance of organic N. The molar DIN/DIP ratio for ground water was highly variable ranging on average (sampling sessions) from 10 to 288, with an average of 58 whereas for drainage canal ranged from 6 to 849 suggesting P limitation to eutrophication. The drainage canal phosphate concentrations were also highly variable, ranging from 9 μg/L to 399 μg/L, and exceeded the eutrophication criteria for lakes (20 μg/L). Drainage canal was oligotrophic due to reeds P uptake and once the reeds were cut (December 2006) it became successively mesotrophic to eutrophic. Sediment physicochemical characteristics - The results of the physicochemical characterization of the sediment are presented in table 5.4.3. pH of the sediment was slightly basic (7.64), while conductivity was not high (218 mS/cm). Dry bulk density was estimated to be 1125 kg/m3. The texture of the sediment was silty. Total organic carbon content was 11434 mg/kg whereas total kjeldahl nitrogen (TKN) was 1886 mg/kg and the total phosphorous is 3124 mg/kg. Therefore, the organic matter was enriched in nitrogen and phosphorus and the C/N ratio was 6. The chemical analysis indicated that sediments contained mostly aluminium (15.5 %) and silicon (54.8 %) oxides, while the high percentage of loss of ignition implied high content of organic matter. The sediment samples contained significant amounts of exchangeable nitrogen content, 4.65±0.36 mg NH3-N/kg sediment, 17.79±8.39 mg NO3-N /kg sediment, and 56.53±7.18 mg DON/kg sediment. Short term PMN and PTSN was also significant, 15.21 and 73.73 mg N/kg sediment, respectively. Anaerobic conditions prevented nitrification during the experiment. Mineralization rate, estimated by the leaching kinetic experiment, was found to be 0.21 mg N/L d, and therefore total capacity (adjusted for 7 days) was 10 mg N/Kg sediment, verifying the short term PMN values. Partitioning coefficient (kd), mL/g, for EMN, and PMN, was 400 and 600 mL/g, correspondingly, while for DON was much lower 200 mL/g, indicating the trend of the sediment to release DON. The sediment released 80 mg DON/Kg sediment (Figure 5.4.5). The aromaticity estimated in the leachate of the PMN test (ArI-DOC, 1.169±0.052 L/mg C m, ArI DON, 280, 3.076±0.431 Final Report (Technical issue) – LIFE05 ENV/GR/00024 206/313 Environmental Friendly Technologies for Rural Development L/mg N m) compared with aromaticity observed in a range of Greek agricultural soils (Stamati et al., 2008b) could be considered to be of the low-medium class explaining the enhanced mineralization response of the sediment. NO3-N concentration decline, observed in the kinetic experiment, could be attributed in denitrification since dissolved oxygen was negligible and redox potential was below 100 mV. Finally, the redox potential (Eh) of the sediment reached values lower than -50 mV in 200 h, (Figure 5.4.6) suggesting potential for denitrification under anaerobic conditions and available electron donors. The sediment also released small quantities of phosphates (0.465±0.265 mg/kg PO4-P) as it was indicated from the leaching experiment (Figure 5.4.7). On the other hand, it had a large capacity to absorb phosphorous and no plateau was reached in the sorption experiment. This suggested that during the experiment (4 days) the equilibrium probably was not reached, but it was also an indication for possible surface precipitation. Therefore the experimental data couldn‘t be modelled by Freundlich, Langmuir or BET isotherm and the linear trend was obtained. The partitioning coefficient (Kd) was estimated to be 300 mL/g and the retardation factor 1092 or 1774 if instead of the estimated dry bulk density the typical value 2.65 g/cm3 was used. Equilibrium P concentration (EPC0) was estimated to be 0.08 mg/L in compliance with the value obtained from the empirical equation of Potential Water Deficit, mm Smith et. al. (2005). 200 150 100 50 0 -50 -100 -150 -200 Sep Oct Nov Dec Water Deficit -71 -11 72 69 Jan Feb Mar Apr May Jun 62 31 11 -14 -59 Jul Aug -127 -151 -127 Figure 5.4.2. Average potential water deficit in the study region for the hydrologic years 2001-02 to 2006-07. Final Report (Technical issue) – LIFE05 ENV/GR/00024 207/313 5.0 4.5 4.0 3.5 F-08 D-07 N-07 O-07 S-07 A-07 J-07 J-07 M-07 A-07 M-07 F-07 2.5 J-08 A 1.4 A 3.4 A 2.4 3.0 J-07 Piezometric head from the same datum, m Environmental Friendly Technologies for Rural Development Date Figure 5.4.3. Temporal variation of piezometric heads (from the same datum) from three piezometers of four m depth and distance from the drainage canal 1.5 m (A2.4), 3.2 m(A3.4), and 4.7 m (A1.4). 9 8 7 6 5 4 3 2 1 0 40 35 30 25 20 15 10 5 0 0 100 NO3-N 200 300 400 Time, h NH3-N DON 500 Conc., mgDOC/L Concentration, mgN/L Figure 5.4.4. Seasonal averages from eight sampling sessions of physicochemical parameters of surface water and ground water underneath Drainage Canal at Skala. 600 DOC Figure 5.4.5. Kinetic release of dissolved nitrogen forms and dissolved organic carbon. Final Report (Technical issue) – LIFE05 ENV/GR/00024 208/313 Environmental Friendly Technologies for Rural Development 200 Eh, mV 150 100 50 0 -50 0 50 -100 100 150 200 250 Time (min) Figure 5.4.6. Sediment redox potential evolution under stirring and anoxic conditions. Adsorped phospates (qe), mg PO4-P/Kg sediment 120 Experimental data 100 80 Linear (Experimental data) y = 300.35x 2 60 R = 0.822 40 20 0 0.0 EPCo 0.2 0.4 0.6 0.8 1.0 Equilibrium Concentration (Ce), mg/L Figure 5.3.7. Phosphate sorption isotherm at drainage canals‘ sediments (pH 7.8 and temperature 20 οC). Phragmites australis and Arundo donax temporal nutrient content - Nutrient (TKN and total P) concentration of Phrgmites australis (averages for plots S2 and S3) and Arundo donax (plot S1) for the three parts (upper, middle, lower) of the above ground biomass and the below ground biomass (roots and rhizomes) for plot S1 are presented in Figure 5.4.8 (growing periods of 2007 and 2008). The concentration evolution patterns observed in the two growing periods are described in the following paragraph. Nutrient concentration patterns were very similar for both growing periods. Maximum N concentration was observed in March/ April for Phragmites australis (S2-S3 plots, approx. 30-31, 12-18, 6-8 g/kg for upper, middle, and lower biomass respectively for the two growing seasons), while for Arundo donax the exact time was not distinct but seemed to be in April/May (S1 plots, approx. 26-39, 17-19, 10-17 g/kg for upper, middle, and lower biomass, respectively). On the other hand, maximum P concentration for upper and middle part was in May for S1 plot, and March/April for S2-S3 plots (approx. S1: 4.5-5 and 3.2-4 g/kg, S2-S3: 4-5.6, and 3-4.8 g/kg for upper, and middle biomass respectively). In subsequent months, there was a gradual decrease in P concentration of these two parts and an increase in that of lower part and below ground biomass. This pattern can be attributed to P translocation to the roots. Nitrogen concentration decreased for the three parts of the above ground plants biomass. Final Report (Technical issue) – LIFE05 ENV/GR/00024 209/313 Environmental Friendly Technologies for Rural Development A portion of the decrease of nutrient concentration could be attributed to the dilution with an increasing biomass, as maximum biomass is usually observed after maximum nutrient concentration. Moreover, there is possibility that P had returned to roots as it has been also observed in other studies (Lippert et al., 1999). The increase of phosphorus concentration in roots at the summer period has been also reported by others (Lippert, et al., 1999) who mentioned phosphorus translocation from stems and leaves (25-50% of P) to roots for fertilization of next growth period (Graneli et al., 1988). Figure 5.4.8. Temporal variation of shoot content in N and P of a) A.donax (S1) and b) P.australis (S2-S3) from May to September. On the whole, during the monitoring period nutrient concentrations were higher in upper part and lower in lower part of above ground biomass, apart from certain periods of low concentrations, where concentration values among the three parts were relatively identical (15/2/2008 and 1/8/2008). Upper part (leaves) had higher N (and not P) content and N/P molar ratio compared to middle and lower part indicating the need of leave for N for chlorophyll formation. On the other hand, during growth periods where there was great need of P for the formation of new tissues the N/P ratio was decreased in the above ground biomass, and then remained relatively constant. Final Report (Technical issue) – LIFE05 ENV/GR/00024 210/313 Environmental Friendly Technologies for Rural Development During the growing season in 2008, the biomass was maximum soon after the maximum concentrations in June for P. australis (47 g/reed clone, 705 g/m2) and in late July for A. donax (204 g/reed clone, 3.1 kg/m2) (Figure 5-3-9) in accordance with other studies which also showed maximum reed biomass in early summer (J. García-Pintado et al., 2007). Above ground biomass has been found to range from 97 g/m 2 (Pure nutrient substrate, translocation ecotype, Lippert et al., 1999) to 1500 g/m2 (Rich nutrient substrate, assimilation ecotype., Kuhl et al., 1997) in August for P.australis. Phragnites Australis Arundo donax g of biomass/shoot g of biomass/shoot 250 200 150 100 50 90 80 70 60 50 40 30 20 10 0 0 May June Month July May September June July September Month (a) (b) Figure 5.4.9. Temporal variation of biomass of a) A.donax and b) P.australis from May to September. On the other hand, peak standing stock of nutrients was attained in June for both plants (A.donax: 432 mg P/shoot and 2023-2132 in July- mg N/shoot, P.australis: 151 mg P/shoot, 586 mg N/shoot) (Figure 5.4.10). Converting these contents to mg/g DW (Dry Weight), then P.australis exhibited 12.4 mg N/g DW and 3.2 mg P/g DW, while A.donax exhibited 18.4 mg N/g DW and 3.74 mg P/g DW. In literature, nutrient contents of P.australis observed during summer are 17.5-24.3 mg N/g DW and 1.3-3.14 mg P/g DW. Accounting for the reed density the square meter nutrient content is 8.78 g N/m2 and 2.26 g P/m2 regarding P.australis and 30.34 g N/m2 and 6.48 g P/m2 regarding A.donax, while in the literature the following ranges 17.8-35 g N/m2 and 0.96-3 g P/m2 have been observed (Lippert et al., 1997). Discussion Nitrogen buffering processes - Drainage canals are areas of accumulation of organic matter (source of nutrients for microrganisms) due to erosion and growth of plants such as Phragmites australis and Arundo donax, that is important for nitrogen microbial processes (mineralization, nitrification, denitrification). In the drainage canal under study the substrate was tyrf and enriched in organic nitrogen. Groundwater exhibited high levels of DOC (approx. 14 mg/L) and DON (approx. 2.5 mg/L). Mineralization of organic nitrogen (15 mg/kg PMN, 0.21 mg/L d) was enhanced due to low aromaticity of DON which was released from the sediments. The reduction of groundwater DON flux passing through the riparian zone was an estimation of mineralized nitrogen for the study period and it was estimated to be on average 37.6 mg N/m2 (13.72 g/m2 year). Final Report (Technical issue) – LIFE05 ENV/GR/00024 211/313 Environmental Friendly Technologies for Rural Development Figure 5.4.10. Temporal variation of standing stock of nutrients of a) A.donax (S1) and b) P.australis (S2-S3) from May to September. Nitrification is an important aerobic process for the prevention of toxic ammonia accumulation. The process due the anaerobic substrate is strongly guaranteed on the oxygen release from the roots. The reduction of groundwater ammonia flux passing through the riparian zone indicated that the amount of nitrified nitrogen during the study period was on average 26.6 mg N/m2 day (9.72 g N/m2 year). Denitrification is the main processes responsible for the buffering capacity of drainage canals against diffuse nitrate pollution as described also by others (Hiscock and Grischek, 2002). Denitrifers require, apart from electron donors, anaerobic and reductive conditions and such conditions observed in our case, since groundwater exhibited both low dissolved oxygen (mean value 1.6 mg/L) and redox potential (mean value 111mV, range: -182.5 mV έως +340.8 mV). Moreover, sediment redox potential under anoxic conditions was also low -50 mV. Hence, accounting that the microporosity environment would be even more anoxic, there was strong potential for dentitrification. The reduction of groundwater NO3-N flux passing through the riparian zone gave evidence that on average 56.1 mg N / m2 day (20.48 g N/m2 year) was denitrified. This nitrogen amount was removed from the system before entering the surface water. These fluxes are similar to other studies (Fustec et al., 1991;Trudell et al., 1986). Phosphates buffering processes - Sediments showed a large capacity to absorb phosphorous. DIP concentration in groundwater was higher than the equilibrium concentration (EPC0 = 0.08 mg/L), therefore groundwater phosphate load was retained in sediments and the load entering the drainage canal was minimized. On the other hand, the levels of phosphorous in the drainage canal were seasonally below the EPC 0 making the process inactive. Thereafter, drainage canal buffering capacity concerning phosphates was not spent and higher phosphate loads could be absorbed. Root oxygen release was also important for adsorption as it enhances the oxidation of the soluble Fe +2 to the Fe+3 form that can be precipitated oxyhydroxides that bind phosphate. Caryl et al. (2001) suggested that low soluble reactive phosphorus (SRP) concentrations occurred in groundwater with DO concentrations > 3 mg L-1 and low Fe+2 and on the contrary high SRP concentrations of > 0.05 mg/L were associated with low DO and high Fe +2 Final Report (Technical issue) – LIFE05 ENV/GR/00024 212/313 Environmental Friendly Technologies for Rural Development concentrations in areas of buried channel sediments near the river bank. In this study PO4-P ranged from 0.009 (Method Detection Limit) to 0.437 mg/L, with DO from 0.45 to 5.00 mg/L and ORP from 140 to -215 (outlier -382). When the DO was higher than 3 mg/L the PO4-P ranged from 0.058 to 0.183 mg/L. However, there was no correlation of PO4-P concentrations higher than EPC0 with DO and ORP. Thus, we could assume that the redox potential enhances denitrification and not iron (Fe+3) reduction. Management issues of reed biomass - Harvesting of above ground biomass in June, when peak nutrient content of reeds was observed and N/P ratio of surface water was high enough to avoid toxic algal blooms, would remove 0.74 Kg P (2.73 g P/m 2) and 3.02 Kg N (11.2 g N/m2). Totally, 76.5 % of nitrate nitrogen (14.64 g N/m2 year) and phosphorus (1.39 g P/m2 year) entered the drainage canal would removed by plant uptake. However, determination of the time of the management should take into account the effect of harvesting to re-growth and to ecological functioning of the habitat. Moreover, O2 supply to rhizomes depends on the redox potential of substrate and the water depth, and should be considered in the management plans. Harvesting either during the winter or the growing season has not been found to seriously affect re-growth of reeds (Valkama et al., 2008) and no clear differences have been found in total biomass production per unit area (Bjorndahl, 1984; Valkama et al., 2008). For the protection of next year reed (P. australis) performance, Graneli et al., 1992 suggested the harvesting of above-ground biomass, when rhizome energy reserves (carbohydrates) have already been replenished; Translocation starts immediately after the foliar structure has been established (during June in south Sweden) and it has been finished until August. In this study root replenishment in phosphorus seemed to take place from May to June. Time of harvesting and ecological factors - Although, in general reed management has been found to have a significant negative impact on invertebrate community, a short term management (1-2 years) had no effect on invertebrates (Valkama et al., 2008). On the other hand, reed harvesting and burning has been found to reduce abundance of passerine birds by about 60%, but this was probably associated with flood limitation as the numbers of butterflies, beetles and some spiders were reduced (Valkama et al., 2008). Therefore, the optimal reed management regime to preserve number of birds and invertebrates in reedbeds could be indeed a rotation of short term management (1-2 years) (Valkama et al., 2008). Finally, the Hellenic Ornithological Society suggested that in alluvial Evrotas River plain reed harvesting is permitted from the 15 th of June to the 30th of September (official communication with Hellenic Ornithological Society), excluding in this way the winter harvesting. Oxygen transport - The below ground parts of emergent macrophytes are dependent on oxygen transported from the shoots, since O 2 is usually absent in the substrate. Oxygen is needed in these parts primarily for respiration and O2 deficiency may limit the maximum water-depth penetration of emergent vegetation. Oxygen release from the roots of macrophytes to the surrounding substrate may have a positive influence on plant growth by oxidizing reduced, phytotoxic metabolites in the substrate (e.g. S 2-, Fe+2, Mn+2) (Weisner, 1988), promote phosphorus absorption onto the sand and prevent ammonia accumulation. P. Australis growing in a reducing substrate are more sensitive Final Report (Technical issue) – LIFE05 ENV/GR/00024 213/313 Environmental Friendly Technologies for Rural Development to a reduction in the O2 supply to rhizomes than reeds growing in a more oxidizing substrate (Weisner and Graneli, 1989). Conclusions Sustainable agricultural practices have minimum environmental impact without imposing significant financial burdens on the farmers. Thus, understanding and implementing innovative technologies based on natural attenuation processes offers such advantages. The objective of this research was to elucidate removal of nutrients due to natural attenuation mechanisms in drainage canals in Evrotas River delta in Greece. We investigated nutrients balance in groundwater, sediments, and reeds (Phragmites australis and Arundo donax) of the drainage canal. Groundwater fluxes indicated that the rate of mineralization was 37.6 mg N/m2 day. The accumulation of toxic ammonia was prevented through the nitrification process (26.6 mg N/m2 d). The decrease of NO3-N flux in groundwater in the riparian zone, was calculated to be 56.1 mg N/m2 day (20.48 g N/m2 year). Phosphate was absorbed to sediments and its load to the drainage canal was minimized. Harvesting of above ground reed biomass in mid June, when maximum standing stock of nutrients was attained for both plants, would remove 2.73 g P/m2 and 11.2 g N/m2. 76.5 % of the nitrate nitrogen (14.64 g N/m2 year) and all the phosphorus (1.39 g P/m2 year) entering the drainage canal was removed by plants. This field and laboratory study revealed that the riparian zone of the agricultural drainage canal under study in the Evrotas River delta, natural attenuation mechanisms (denitrification and adsorption of phosphates), as well as phytoremediation (P.australis and A.donax nutrient uptake and harvesting of their above ground biomass), could remove significant amounts of N and P. The harvesting of above ground biomass of reeds (P.australis and A.donax) is suggested to take place in mid June when maximum standing stock of nutrients was attained for both plants P.australis and A.donax. Overall, drainage canal management is suggested as an efficient low cost – high gain agri-environmental measure, which is easy to be adapted by farmers, to reduce diffuse nutrient pollution. 2. Riparian Zone Restoration Temporary rivers are flashy in nature and under extreme precipitation events produce floods with extremely high erosion potential. An example of the flood destruction is a site in the area of Sparta where the river bank erosion control and phytoremediation was demonstrated (Figure 5.4.11). At the site, we designed and constructed a bank restoration system using large stones following the rivers curvatures to stabilize the bank and the riparian zone from future flood events. The bank erosion was therefore restored using a stone hedge of large boulders. The length of the stone hedge was 120m, the width 2.5m at the bottom and 1 m at the top, and the height 3.5m. In addition, we planted a riparian forest of 200 poplar trees to decrease nutrient loads due to uptake and enhanced denitrification. In this way, phytoremediation in conjunction with river bank erosion controls was demonstrated as a combined remediation tool for non-point source pollution of nutrients. Final Report (Technical issue) – LIFE05 ENV/GR/00024 214/313 Environmental Friendly Technologies for Rural Development Figure 5.4.11. Sparta area – Riparian zone river bank erosion control and phytoremediation. To monitor the temporal 3-dimensional variability of hydrology and chemistry of ground water, nine multi-level (3, 4 and 5m) wells were installed (Figure 5.4.12). Groundwater sampling was conducted in order to assess the fate and transport of nutrients as they move from the groundwater to the River. Field hydrologic studies - The water depth of the wells was monitored on a monthly basis. The hydraulic characteristics of the subsurface were determined by conducting single well pumping tests and the infiltration capacity of the fields was estimated by conducting in situ infiltration experiments. Horton‘s equation was used to obtain the kt infiltration rate ( f f c f co f c e where fco and fc were the initial and final infiltration rates and k was an empirical constant. Final Report (Technical issue) – LIFE05 ENV/GR/00024 215/313 Environmental Friendly Technologies for Rural Development Multi-level probe clusters A1 River Multi-level well clusters A2 A3 River A4 A5 A7 A6 A8 A9 9 6 4 2 3 5 7 8 1 Figure 5.4.12. Multi-level probe design in relation to restored riparian zone. Surface and ground water chemistry monitoring - The multilevel wells were sampled every 2 months (3/07, 5/07, 7/07, 11/07, 3/08, 5/08), with a peristaltic pump with low flow (< 1 L/min), so as turbidity was maintained in minimum levels, and the physicochemical parameters pH, temperature, conductivity, dissolved oxygen (D.O.), and, redox potential (Eh) were measured in situ using the following electrodes: Orion 9107 pH meter, Orion 081010 D.O. meter, and Orion 011050 Conductivity meter. The samples were filtered through a 0.45 µm Nylon filter and analyzed using a Hack 2010 spectrophotometer for nitrates (NO3-N, Cadmium Reduction Method, 8039), nitrites (NO2-N, Diazotization Method, 8507), ammonia (NH3-N, Salicylicate Method, 10023), phosphates (PO4-P, phosVer3 Method, 8048), total phenols (T.phenols, Folin Ciocalteu method), dissolved organic carbon (Direct Method Patent Pending, 10129) or by a TOC analyzer (Shimadzu 5050), after the removal of inorganic carbon by air sparging for 10 min), chemical oxygen demand (COD, Reactor Digestion Method, 8000), and total nitrogen (TN, TNT Persulfate Digestion Method, 10071) or Kheldalh nitrogen (TKN, by the Kjeldahl digestion technique with a Hach digestahl digestion apparatus, Nessler method, Final Report (Technical issue) – LIFE05 ENV/GR/00024 216/313 Environmental Friendly Technologies for Rural Development 8075). Dissolved organic nitrogen was derived by the abstraction of ammonia from the TKN. Results Hydraulic characteristics - The spatial distribution of the wells at the at the restored riparian zone of Evrotas River is presented in the Figure 5.4.13. Typical results of the piezometry are given in the figure 5.4.14. The groundwater movement is almost paraller with the river flow (Figure 5.4.15). The average hydraulic conductivity was estimated to be 0.01 cm/sec. The infiltration rate under steady state of moisture was estimated using Horton‘s equation to be 0.0596 cm/min. Ground water chemistry monitoring - seasonal averages results of the six sampling sessions of ground water are presented in table 5.4.8 and figure 5.4.16. Moreover in the figure 5.4.17 is presented the vertical 2-D profile of polutants in groundwater of the restored riparian zone of Evrotas River in May 2007. The following findings were identified: 7. The ground water presented low levels of dissolved oxygen. The samples from the 5m probes were colored (black) and smelled. 8. The ground water presented high levels of COD, which increased with depth, Τ.phenols, DOC, DON and NH3-N and seasonally of NO3-N and PO4-P. 9. The organic N was as significant as the inorganic N and was estimated to be approximately 60% of the total dissolved nitrogen. 10. Moreover the average DOC-to-DON ratio was relative low and ranged from 2.5 to 15, indicating abundance of organic N. 11. The molar DIN/DIP ratio for ground water was highly variable ranging on average (sampling sessions) from 30 to 350, suggesting P limitation to eutrophication. 12. There was generally a consistent decrease of pollutants in the restored riparian zone suggesting the role of phytoremediation and probably other natural attenuation mechanisms in action. Spatial distribution of wells - Sparta area 16 N2 14 y, m 12 10 River 8 N1 6 N9 N4 4 2 N3 10 20 30 40 N8 N7 N5 0 0 N6 50 60 70 x, m Figure 5.4.13. Spatial distribution of the wells at the restored riparian zone of Evrotas River. Final Report (Technical issue) – LIFE05 ENV/GR/00024 217/313 2.90 2.70 N4.3 2.50 N 3.3 2.30 N 6.3 N 5.3 N 7.3 2.10 N 9.3 Dec-07 Nov-07 Oct-07 Sep-07 Aug-07 Jul-07 Jun-07 May-07 Apr-07 Mar-07 Feb-07 1.90 Jan-07 Piezometric Height from the same datum, m Environmental Friendly Technologies for Rural Development (a) 2,90 2,70 N4.4 N 3.4 2,50 N 5.4 2,30 N 6.4 N 7.4 2,10 N 9.4 Dec-07 Nov-07 Oct-07 Sep-07 Aug-07 Jul-07 Jun-07 May-07 Apr-07 Mar-07 Feb-07 1,90 Jan-07 Piezometric Height from the same datum, m Date Date (b) Figure 5.4.14. Horizontal profile of the piezometriuc height in time (piezometers of a) 3 and b) 4m depth). 2.87 2.85 Hydro 3 all May 07 2.83 2.81 2.79 2.77 2.75 10 2.73 2.71 2.69 5 2.67 2.65 10 20 30 40 50 60 50 60 Hydro 4 all May 07 10 5 10 20 30 40 2.63 2.96 2.94 2.92 2.9 2.88 2.86 2.84 2.82 2.8 2.78 2.76 2.74 2.72 2.7 2.68 2.66 2.64 2.62 Figure 5.4.15. 2-D profile of groundwater movement in the restored riparian zone of Evrotas River in May 2007. Final Report (Technical issue) – LIFE05 ENV/GR/00024 218/313 Environmental Friendly Technologies for Rural Development Averages physicochemical parameters of Ground water underneath Riparian Zone at Sparta 1400 1200 25 1000 20 800 15 600 10 400 5 Conductivity Temperature, pH, DO, Eh 30 200 0 0 Mar-07 May-07 Temperature (oC) Jul-07 Nov-07 Sampling month pH DO (mg/L) Mar-08 May-08 Conductivity (μS/cm) 8 7 6 5 4 3 2 1 0 1.0 0.8 0.6 0.4 0.2 DON/TDN ratio Concentration, mg/L Averages chemical parameters of Ground water underneath Riparian Zone at Sparta 0.0 Mar-07 May-07 Jul-07 Nov-07 Mar-08 May-08 Sam pling m onth DIN (mg/L) DON (mg/L) DON/TDN Averages chemical parameters of Ground water underneath Riparian Zone at Sparta 150 15 100 10 50 5 0 COD, mg/L Concentration, mg/L 20 0 Mar-07 May-07 Jul-07 Nov-07Mar-08 May-08 Sampling month DOC (mg/L) T.phenols (mg/L) COD (mg/L) Figure 5.4.16. Seasonal averages from six sampling sessions of physicochemical parameters of ground water underneath the restored Riparian Zone at Sparta. Final Report (Technical issue) – LIFE05 ENV/GR/00024 219/313 Environmental Friendly Technologies for Rural Development 2.96 2.94 2.92 2.9 2.88 2.86 2.84 2.82 2.8 2.78 2.76 2.74 2.72 2.7 2.68 2.66 2.64 2.62 y, m Piezometric heights, m (4 m depth wells, May 07) 10 5 10 20 30 40 50 60 x, m y, m Concentration of NO3-N, mg/L (4 m depth wells, May 07) 10 5 10 20 30 40 50 60 x, m 1.75 1.65 1.55 1.45 1.35 1.25 1.15 1.05 0.95 0.85 0.75 0.65 0.55 0.45 0.35 0.25 0.48 0.44 0.4 Concentration of NH3-N, mg/L (4 m depth wells, May 07) 0.36 0.32 0.28 y, m 0.24 10 0.2 0.16 0.12 5 0.08 0.04 0 10 20 30 40 50 60 x, m 20 18 16 Concentration of COD, mg/L (4 m depth wells, May 07) 14 y, m 12 10 10 8 6 5 4 2 10 20 30 40 50 60 x, m 0 14.5 13.5 12.5 Concentration of DOC, mg/L (4 m depth wells, May 07) 11.5 10.5 y, m 9.5 8.5 10 7.5 6.5 5 5.5 4.5 3.5 10 20 30 40 50 60 x, m Figure 5.4.17. 2-D profile of polutants in groundwater of the restored riparian zone of Evrotas River in May 2007. Final Report (Technical issue) – LIFE05 ENV/GR/00024 220/313 Environmental Friendly Technologies for Rural Development Reduction of the pollutants at the restored Riparian Zone - The collected data from the monitoring of qround water quality allowed for the estimation of the nitrate reduction taking place at the riparian zone. As it was already mentioned denitrification was not expected to contribute significantly in the nitrate reduction due to the relative high dissolved oxygen and redox potential. Therefore the potential reduction would be attributed to the poplar trees uptake. The nitrate flux reduction was calculated for the 70 m length of the riparian zone for two equally divided parts (35 m). The water flow was calculated from the piezometric gradient between the wells (pairs of wells 3 andι 4, and 5 and 6), and then the difference between the concentrations resulted in the calculation of the flux. Totally, 8.2 kg ΝΟ3-Ν/y or 39 g ΝΟ3-Ν/m2y (for 3 m width of poplar trees) reduction of nitrates was estimated (70 % reduction). It is worth noting that the reduction the first period (until the July ‘07 sampling) was 60%, while the second period was 80%, coinciding with the further growth of the poplar trees and their root system. Moreover, accumulation of nitrogen ammonia was also observed which decreased in time, suggesting the contribution of the oxygen release from the trees‘ roots. The graphical depiction of the seasonal average concentrations of the pollutants in the wells before and after the poplar trees planted (Figure 5.4.18a and b) indicates also the reduction of the ammonia accumulation after the July ‘07 and the enhancement of the nitrate reduction in the respective wells (after the trees). It is noticeable that nitrates presented during the six sampling sessions on average 81% higher, and 11.6, 18.9, 37.0, 49.4, and 32.7 lower concentration after the poplar trees planted zone. On the other hand the nitrate reduction in the 150 m filed from the irrigation well to the riparian zone (before the planted zone) was estimated to be only 8-25%. Conclusions The bank erosion was restored using a stone hedge of large boulders and moreover a riparian forest of 200 poplar trees was planted. The collected data from the monitoring of ground water quality allowed for the estimation of the nitrate reduction taking place at the riparian zone. As it was already mentioned denitrification was not expected to contribute significantly in the nitrate reduction due to the relative high dissolved oxygen and redox potential. Therefore the potential reduction would be attributed to the poplar trees uptake. The nitrate flux reduction was calculated for the 70 m length of the riparian zone for two equally divided parts (35 m). The water flow was calculated from the piezometric gradient between the wells (pairs of wells 3 and 4, and 5 and 6), and then the difference between the concentrations resulted in the calculation of the flux. Totally, 8.2 kg ΝΟ3-Ν/y or 39 g ΝΟ3-Ν/m2y (for 3m width of poplar trees) reduction of nitrates was estimated (70% reduction). It is worth noting that the reduction the first period (until the July ‟07 sampling) was 60%, while the second period was 80%, coinciding with the further growth of the poplar trees and their root system. Moreover, accumulation of nitrogen ammonia was also observed which decreased in time, suggesting the contribution of the oxygen relese from the trees‘ roots. The graphical depiction of the sesaonal average concentrations of the pollutants in the wells before and after the poplar trees planted (Figure 5.4.18a and b) indicates also the reduction of the ammonia accumulation after the July ‘07 and the enhancement of the nitrate reduction in the respective wells (after the trees). It is noticable that nitrates Final Report (Technical issue) – LIFE05 ENV/GR/00024 221/313 Environmental Friendly Technologies for Rural Development presented during the six sampling sessions on average 81% higher, and 11.6, 18.9, 37.0, 49.4, and 32.7 lower concentration after the poplar trees planted zone. On the other hand the nitrate reduction in the 150 m filed from the irrigation well to the riparian zone (before the planted zone) was estimated to be only 8-25%. Consequently, phytoremediation in conjunction with river bank erosion controls as a is suggested as a combined efficient remediation tool, low cost – high gain, for non-point source pollution of nutrients. Final Report (Technical issue) – LIFE05 ENV/GR/00024 222/313 Environmental Friendly Technologies for Rural Development COD Concentration, mg/L 35 30 25 20 15 10 5 0 Mar-07 May-07 Concentration, mg/L Irrigation well Nov-07 before poplar trees planted Mar-08 May-08 after poplar trees planted NO2-N 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 0.000 Mar-07 May-07 Irrigation well Jul-07 Nov-07 before poplar trees planted Mar-08 May-08 after poplar trees planted NO3-N 3 Concentration, mg/L Jul-07 2 2 1 1 0 Mar-07 Irrigation well May-07 Nov-07 Mar-08 May-08 after poplar trees planted NH3-N 0.70 Concentration, mg/L Jul-07 before poplar trees planted 0.60 0.50 0.40 0.30 0.20 0.10 0.00 Mar-07 Irrigation well May-07 Jul-07 Nov-07 before poplar trees planted Mar-08 May-08 after poplar trees planted Figure 5.4.18a. Seasonal average concentrations of the pollutants in the irrigation well and the groundwater before and after the poplar trees planted. Final Report (Technical issue) – LIFE05 ENV/GR/00024 223/313 Environmental Friendly Technologies for Rural Development PO4-P Concentration, mg/L 0.25 0.20 0.15 0.10 0.05 0.00 Mar-07 Irrigation well May-07 Nov-07 Mar-08 May-08 after poplar trees planted T.Phenols 2.50 Concentration, mg/L Jul-07 before poplar trees planted 2.00 1.50 1.00 0.50 0.00 Mar-07 Irrigation well May-07 Nov-07 Mar-08 May-08 after poplar trees planted DOC 16 Concentration, mg/L Jul-07 before poplar trees planted 14 12 10 8 6 4 2 0 Mar-07 Irrigation well May-07 Nov-07 Mar-08 May-08 after poplar trees planted DON 7 Concentration, mg/L Jul-07 before poplar trees planted 6 5 4 3 2 1 0 Mar-07 Irrigation well May-07 Jul-07 Nov-07 before poplar trees planted Mar-08 May-08 after poplar trees planted Figure 5.4.18b. Seasonal average concentrations of the pollutants in the irrigation well and the groundwater before and after the poplar trees planted. Final Report (Technical issue) – LIFE05 ENV/GR/00024 224/313 Environmental Friendly Technologies for Rural Development TASK 4 - Agricultural product waste management The demonstration of agricultural waste treatment technologies was focused on the two most important point sources of pollution in Laconia, namely, olive mill effluents and wastewater from orange juice production. Two general technologies were used in four application sites: subsurface distribution of waste with phytoremediation and electrolytic treatment of wastes. The environmental impact of the olive oil production is very significant because of the very high COD content and the toxicity of some ingredients. The volume of the liquid effluents from the olive mill can be double or even quadruple the amount of olive oil produced, and there is a need to reuse or dispose large amounts of solids and liquid effluents in an environmentally acceptable manner. Whatever the type of the production plant (classical, two-phase or three-phase), about 1500 kg of by-products result from the production of 1000 kg of olive oil, either in the form of high humidity solids (2-phase process) or as vegetation water and medium humidity solids (classical and 3-phase processes). The disposal and treatment of this liquid waste are the main problem of the olive oil industry because of its high organic load and content of phytotoxic and antibacterial phenolic substances, which resist biological degradation. OMW has also a high potassium concentration and notable levels of nitrogen, phosphorus, calcium, magnesium, and iron, important factors in soil fertility. Lime precipitation and water evaporation in ponds constitute common practice in OME treatment. As part of EnviFriendly LIFE program, the following alternative treatment technologies have been implemented and their efficiency demonstrated. 1. Use of OMW for irrigation of crops during the summer months The basic idea behind this technology was to pre-treat the OMW with lime and pump the liquid to a nearby ―evaporation pond‖ for storage for the next 3 to 6 months. From the beginning of June the OMW was used for irrigation (after dilution with water) of a corn field. This approach has been used in a 20.000 m2 area near the ancient lake mentioned by Pafsania for the last 5 years (Figure 5.5.1). The overall results from the corn production have been very positive as well as all wastewater in the pond was used up before the end of the summer on an annual basis. The primary objective of the EnviFriendly program was to evaluate any potential problem with the aquifer under the corn field. Figure 5.5.1. Corn field where OMW irrigation is implemented (―P. TZINAKOS Ltd‖ olive mill in Aiges, Gytheio, Laconia). Final Report (Technical issue) – LIFE05 ENV/GR/00024 225/313 Environmental Friendly Technologies for Rural Development The particular location where this technology was implemented was the olive mill ―P. TZINAKOS Ltd‖ in Aiges (Gytheio, Laconia). The irrigation facility consisted of a CaO pretreatment tank, evaporation lagoon, mixing with fresh water and finally land application in cultivated corn field. We investigated the soil physical and chemical properties for the identification of soil effects after 5 years of land application of CaO pretreated OMWW. Figure 5.5.2 presents a satellite image (Google Earth) with the Olive mill plant, the evaporation/storage lagoons and the maize field. The area was mainly comprised of Alluvial (quaternary) formations of conglomerates and loose sediments, of Tertiary formations mainly marls and phyllites and quarzites. The soil was characterized as alluvial mixed with regosols. The olive mill plant was a three phase olive mill and the OMWW management practice included liming of OMWW in tanks and then pumping the waste in lagoons during the olive oil production period (November to February). Evaporation lagoons accommodated the waste water up to May when the irrigation season commenced. From June to September waste water from the lagoons was mixed with fresh water to a ratio of 1/3 (OMWW/water) and was used for the irrigation of the maize field. The irrigation flow was 30 m3/h for 3 days a week. The surface area of the maize field was 18,750 m2 (1.8750 ha) which corresponded to 18,432 m3/ha/year (irrigation period for 4 months). Taking into account the dilution ratio (1/3), the total supply of OMWW was 6144 m3/ha/4 months or a dose of 51.2 m3/ha/d for the irrigation period from June to September. Two experimental wells were constructed for groundwater monitoring to a depth of 10 m. The water table varied from 5 to 6.5 m seasonally (wet to dry period). Four topsoil samples (T1-T4) (0-15 cm) and an undisturbed core sample (C1-C3) were used for analysis, whereas, a control uncultivated topsoil sample (N) from an adjacent area covered with shrubs was used as reference soil. Sampling was conducted by obtaining 15 topsoil samples (0-15 cm depth) and three undisturbed soil cores C1-C3 (0-50 cm). The 15 topsoils were blended as depicted in figure 5.4.2 (e.g. T1 composite consists of T1.1 T1.4) Samples collected in November 2007 which was two months after the end of irrigation period (May-September) with treated OMWW. Figure 5.5.2 illustrates the sampling grid for surface samples T1.1-T4.3. Soil auger (Edelman type) was used for surface sample collection. Samples were transferred to the laboratory, dried at 37ºC for 48 h, homogenized and sieved with 2 mm sieves. The samples were then placed in plastic containers and stored at room temperature in the dark until use. Core samples were divided into 3 parts with depth (0-10 cm), (10-30 cm), (30-50 cm) and the respective parts from C1-C3 cores were blended and three composite samples Cu (0-10 cm), Cm (10-30 cm), Cd (30-50 cm) obtained. Six field campaigns (January 2007, March 2007, June 2008, August 2007, December 2007 and March 2008) were conducted for ground water sampling. Groundwater was sampled with a low flow peristaltic pump (< 1 L/min), so as turbidity was maintained at minimum levels and no atmospheric oxygen was introduced to the sample. The following physicochemical parameters: pH and temperature (pH/cond WTW 340i), electrical conductivity (EC: ORION 105), dissolved oxygen (DO: WTW oxi 340i), and redox potential (Eh: ORION 250A), were measured, in situ. The samples were filtered, in situ, through a 0.45 µm Nylon filter and analyzed using a Hack 2010 spectrophotometer for nitrates (NO3-N, Cadmium Reduction Method, 8039), nitrites (NO2-N, Diazotization Final Report (Technical issue) – LIFE05 ENV/GR/00024 226/313 Environmental Friendly Technologies for Rural Development Method, 8507), ammonia (NH3-N, Salicylicate Method, 10023), phosphates (PO 4, phosVer3 Method, 8048), total phenols (T.phenols, Folin Ciocalteu method (Box, 1983)), dissolved organic carbon (Direct Method Patent Pending, 10129 or by a TOC analyzer (Shimadzu 5050), after the removal of inorganic carbon by air sparging for 10 min), chemical oxygen demand (COD, Reactor Digestion Method, 8000), and total nitrogen (TN, TNT Persulfate Digestion Method, 10071) or Kheldalh nitrogen (TKN, by the Kjeldahl digestion technique with a Hach digestahl digestion apparatus, Nessler method, 8075). Dissolved organic nitrogen was derived by the abstraction of ammonia from the TKN. OMWW from evaporation lagoons (after lime treated) was once sampled and analyzed for the aforementioned, as well for nutrients like Ca, Mg, K, with ICP-MS. Olive mill plant Lagoons Liming Mixing C1 T1.1 T2.1 T3.1 T1.2 T2.2 T3.2 A2 T2.3 T3.3 T1.4 T2.4 T3.4 50 m T4.1 T4.2 Maize field Lagoons C2 T1.3 A1 Olive mill C3 T4.3 25 m Figure 5.5.2. Satellite image of maize field, sampling grid and geology of the area. Black circles denote drill position. Soil dry bulk density and porosity, were estimated according to standard methodologies (Nikolaidis et al., 1999). The sand, silt, and clay content of the soil samples were determined by Bouyoucos method (Bouyoucos, 1962). Soil infiltration capacity was estimated by conducting in situ infiltration experiments with the use of regular infiltrometers. A 50 cm cylinder was inserted into the soil, filled with water, and the time it took for the water to drain into the sediment was measured. Horton‘s equation was Final Report (Technical issue) – LIFE05 ENV/GR/00024 227/313 Environmental Friendly Technologies for Rural Development used to model the infiltration rate ( f f c f co f c e kt ) where fco and fc were the initial and final infiltration rates and k was an empirical constant. Soil total organic carbon was determined using the Walkley-Black (WB) acid dichromate digestion technique Walkley (1946) and total Kjeldahl N by the Kjeldahl digestion technique. Soil pH was determined in the supernatant of a 1:2 soil to water ratio, as described in Thomas (1996). Electrical conductivity was determined by a conductivity electrode in the extract from saturated soil paste. Calcium content was determined in the aforementioned, paper filtrated, extract, by inductively coupled plasma mass spectroscopy (ICP-MS Agilent 7500 cx). Available K and Mg were extracted from soil samples by CH3COONH4 1 M in pH 7 (Bower, et al., 1952, Thomas, 1982), and determined by ICP-MS. Cation exchange capacity (CEC) was determined with the method described by Amrhein & Suarez (1990) for soils salts and/or carbonates. Soil was initially saturated with 0.2M CaCl2, adjusted to pH 8.2, and then extracted with 0.5 M Mg(NO3)2. Correction for calcite dissolution was made by the determination of HCO 3- in soil solution prior to extraction. Determination of Ca2+ in extracted solutions was carried out by inductively coupled plasma mass spectroscopy (ICP-MS) and HCO3- with IC analyzer (Shimadzu 5050). Bioavailable phosphorous was extracted with 0.5M sodium bicarbonate (Olsen et al., 1954) and measured spectrophotometrically (PO4-P, phosVer3 Method, 8048). Soil nitrogen fertility was accessed by the estimation of exchangeable mineral N (EMN) content and potential mineralizable N (PMN) of soils. EMN and short-term PMN (ammonium-nitrogen production under anaerobic waterlogged conditions) in soil was extracted with 2 mol L−1 KCl in a 1:5 soil:solution ratio shaken at 200 rpm, and incubated 1 h at 20 o C (EMN) and for 1 week at 40 oC. PMN was calculated as the difference between incubated and non-incubated samples. The leachates of both tests were filtered through a 0.45 µm Nylon filter and analyzed for NO3-N and NH4-N and TKN and dissolved organic carbon with the methods described in the ground water chemistry monitoring section. Regarding NO3-N measurement calibration curves were prepared for Cl− interference. Total phenols content in soil was extracted with 120 dichlomethane (DCM), for 24h at a rate of 6 cycles per hour, in a soxhlet apparatus (Helaleh et al. 2001) and measured with the Folin-Ciocalteu colorimetric method (Box, 1983). Soil dehydrogenase activity was determined by the reduction of triphenyltetrazolium chloride (TTC) to triphenylformazan (TPF) (Chu et al. 2007, Wittling et al. 1995). Calcium dehydrogenase and CEC measurements were not possible to core samples due to limited sample amount. All soil analysis was run in triplicates. Results The physicochemical properties of soil samples are presented in Table 5.5.1. Dry bulk density was estimated to be 1698 ±70 Θg/m3 for cultivated soil (T1-T4) and 1612±62 Θg/m3 for control soil (N) whereas porosity was 38.5±2% and 35±2%, respectively. Infiltration was calculated to be 0.012 m/min in the treated soil. Topsoil organic carbon content decreased by 29%, and total kjeldahl nitrogen (TKN) decreased by 25% compared with the control uncultivated soil (N) (1.55 and 0.25% respectively). The lower organic matter content of the cultivated soil as well as the lime pretreated OMWW application was depicted in the higher pH (7.75) compared to control soil (N) (6.26). Final Report (Technical issue) – LIFE05 ENV/GR/00024 228/313 Environmental Friendly Technologies for Rural Development Electrical conductivity also increased by a 4.4 fold compared to that of control sample (N) (174 μS/cm). Magnesium availability decreased in the cultivated soil by 28 % compared to the control soil (N). On the other hand, calcium and potassium availability increased by 154 and 56 %, respectively. Finally, CEC increased by 86%. The bioavailability of phosphorous was extremely low (0.03 mg/Kg) in control soil, while it was high as 0.64 ± 0.2 mg/Kg in the cultivated soil. Exchangeable mineral nitrogen (EMN) was found to be 29% higher in the cultivated soil compared to the control (20 mg/kg) and was dominated by nitrate nitrogen in both soils (90% and 81% of EMN for cultivated and control soil, respectively). Potential mineralizable N (PMN) was estimated to be 22 and 29 mg/Kg for cultivated and control soil respectively. The dissolved organic nitrogen (7 day extraction) showed no significant changes for the cultivated soil (T1-T4) and the control soil (N) (Figure 5.5.3). The total phenols were on average lower in the cultivated soil, and only T1 exhibited 20% higher content compared to the control. Finally, the dehydrogenase activity did not present any statistically important change. A spatial variability was observed mainly in the T1 composite with increases in the physico-chemical parameters. K+, Ca, P-PO43-, N-NO3-, phenols and CEC increased for composite T1 (62%, 35%, 72%, 30% 66% and 18% respectively) compared to T3 and T4. T2 composite also presented some increase in N-NO3- and phenols compared to other composites (T3 and T4). Figure 5.5.4 presents the grain size distribution which was found to be slightly finer for the four composites compared to the control soil probably due to tillage. 12.00 2a 10.00 mg/l 8.00 6.00 4.00 2.00 0.00 T1 T2 T3 Mineral N 3500 3000 T4 N PMN (7 days) Cu Cm Cd Cm Cd DON (7 days) 2b 2500 2000 1500 1000 500 0 T1 T2 T3 Kd Mineral N T4 PMN (7 days) N Cu Kd DON (7 days) Figure 5.5.3. Mineralizable Nitrogen (Mineral N=Ν-ΝΟ3- + Ν-ΝΖ4+) after 1 hour extraction with 2Μ KCl and Potential mineralizable nitrogen (PMN=Ν-ΝΟ3- + Ν-ΝΖ4+) and dissolved organic nitrogen Final Report (Technical issue) – LIFE05 ENV/GR/00024 229/313 Environmental Friendly Technologies for Rural Development (DON) after 7 days extraction with 2Μ KCl. 2b) Distribution coefficient Kd of mineral N, PMN and DON. Figure 5.5.4. Grain size distribution of treated soil (T1-T4) and control soil (N). The soil core samples Cu, Cm, and Cd showed similar pH values as the topsoil samples whereas the electrical conductivity was decreased in deeper horizons (by 48% in the Cd compared to Cu). TOC decreased with depth from Cu (1.0%) to Cd (0.7%). Total Kjeldahl nitrogen also decreased with depth from Cu (0.19%) to Cm (0.15%), while in the deeper horizon (Cd) presented an enrichment (34%) that can not be explained with the available data. Magnesium was relatively constant (4.57-4.93 g/kg) throughout the core depth, whereas potassium and phosphate content decreased with depth. It is worth noting that the availability of potassium and phosphorous of the Cm and Cd part of the soil core was similar to those of the control topsoil sample. Exchangeable mineral nitrogen (EMN) was estimated to be constant throughout the soil depth ranging from 18 to 20 mg/Kg. Potential mineralizable N (PMN) was constant between Cu and Cm (12.5 and 12 mg/Kg, respectively) and appeared to be negligible in the lower part of the core (Cd). DON (after 7 days extraction) was stable for all horizons. Measured physicochemical properties of the OMWW and the lime treated OMWW -in the evaporation ponds before the mixing with fresh water- are presented in Table 5.5.2. pH was alkaline (9.65) due to lime treatment. There was substantial decrease in COD (89 %), total phenols (90%) and TOC (48%) content. However, the electrical conductivity remained high and this was probably related to high potassium content. Nitrogen concentration in the treated OMWW was 1111 mg/L (54% DON, 30% N-NO3-, and 16% N-NH4+). The DOC/DON ratio was slightly higher than 20, indicating nitrogen as the limiting factor. Phosphate phosphorous concentration was 25.6 mg/L. The average physicochemical properties of groundwater are presented in Table 5.5.3. No significant spatial variability was observed between wells A1 and A2. The groundwater had high electrical conductivity, neutral pH, low nutrient concentrations and DO and reducing conditions. In general, no adverse effects were observed in ground water due to the surface application of the OMWW. However attention should be drawn to the electrical conductivity which could be related to potassium leaching from OMWW application and/or Final Report (Technical issue) – LIFE05 ENV/GR/00024 230/313 Environmental Friendly Technologies for Rural Development to geogenic factors due to interaction of groundwater with marls (rich in calcium) and phyllites (rich in potassium) which consist the soil parent material. Discussion Several publications referred to pH decreases in soil after irrigation with untreated OMWW (Cabrera et al., 1996; Sierra et al., 2001) which was however attributed to soil buffering capacity. Time dependent experiments showed initial decrease in pH and finally recovery to normal soil pH levels (Levi-Minzi R. et al., 1992; Piotrowska et al., 2006). In the present study the application of lime pre-treated OMWW lead to an increase of soil pH by 20% compared to that of the relatively acidic control soil. The pH change was related to the high alkalinity of the applied OMWW, (due to liming practice). The electrical conductivity increased in the amended soil (340% increase) and this was consistent with the scientific literature (Paredes et al., 1987; Mekki et al., 2007). These studies referred to EC increases up to 275% (dose 200 m3/ha) (Mekki et al, 2007) and 54% (Paredes et al., 1987) after direct application of untreated OMWW for 5 years or single application of 690,000 L of waste. Potassium and sodium accumulation in soil has been found to be the main reason for the increase of electrical conductivity (Zenjari and Neimeddine, 2001). In such cases, exchange of calcium with potassium and sodium in soil can lead to the depletion of calcium (Sierra et al. 2001, Cabrera et al., 1996) and to soil degradation (Paredes et al., 1987). In our case, potassium availability was increased by 56%. Although, calcium concentration of OMWW is not as high as that of potassium, calcium availability showed even higher increase (154 %). The increase of calcium availability could be attributed to calcium oversaturation. Final Report (Technical issue) – LIFE05 ENV/GR/00024 231/313 Environmental Friendly Technologies for Rural Development Table 5.5.1. Physicochemical parameters for surface soil samples (T1-T4), different depth core samples (Cu, Cm, Cd) and control soil N. Sample pH EC (μS/cm) K+ (g/Kg) Mg2+ (g/Kg) Ca2+ P-PO4 (mg/L)† (mg/Kg) C% CEC N-NO3- N-NH4+ N-NO3- N-NH4+ Phenols Dehydrogenas cmole/K TKN(%) mg/Kg (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) e (mg/Kg) g (7 days) (7 days) T1 † 8.35 704 2.36 4.38 101.3 0.94 1.14 125.62 2034 25.90 2.37 32.59 23.84 42.16 0.12 Stdev 0.20 32 0.29 0.08 1.4 0.08 0.25 105 1.16 0.35 5.27 0.50 2.3 0.05 Stdev 7.19 0.40 998 21 1.53 0.09 4.60 0.29 111.1 0.6 0.54 0.21 1.29 0.16 3714 122 27.14 0.38 2.44 0.05 30.10 1.22 30.51 0.25 38.25 5.2 0.12 0.06 Stdev 7.22 0.50 697 22 1.46 0.09 5.25 0.26 73.0 2.2 0.52 0.09 1.22 0.23 4082 50 21.60 0.22 2.30 0.24 22.94 0.54 27.27 5.98 28.29 3.4 0.17 0.06 635 41 1.38 0.08 5.06 0.04 80.2 0.9 0.58 0.13 0.77 0.19 2593 87 18.44 0.41 2.94 0.25 23.70 3.51 27.94 0.34 23.43 4.2 0.15 Stdev 8.24 0.22 7.29 0.58 739 27 1.31 0.03 4.57 0.02 - Stdev 0.31 0.03 1.01 0.21 1876 136 15.96 0.46 2.97 0.10 14.14 1.3 17.30 1.32 28.86 1.2 Stdev 7.25 0.31 488 44 1.08 0.03 4.61 0.03 - 0.05 0.01 0.90 0.24 1466 85 15.77 0.57 1.86 0.03 17.20 1.64 12.38 2.32 24.94 1.3 7.44 0.11 387 32 0.86 0.01 4.93 0.11 - Stdev 0.04 0.02 0.68 0.13 3388 139 16.92 0.62 2.62 0.12 10.32 2.01 7.99 1.02 28.24 2.5 Stdev 6.26 0.15 172.7 12 1.08 0.04 6.69 0.47 36 4.2 0.03 0.01 1.55 0.07 3.79 T2 101.43 20.10 T3 107.68 17.78 T4 110.12 5.64 Cu Cm Cd N 59.82 12.12 2490 75 16.15 0.32 3.81 0.16 14.62 1.49 27.66 6.15 35.45 1.7 0.08 0.11 0.07 Concetration in soil solution (extraction media: aqua) Final Report (Technical issue) – LIFE05 ENV/GR/00024 232/313 Environmental Friendly Technologies for Rural Development Table 5.5.2. Physicochemical characteristics of OMWW and treated OMWW in evaporation ponds. pH EC (mS/cm) Mg2+ (mg/L) K+ (mg/L) Ca2+ (mg/L) N-NO3- (mg/L) N-NH4+ (mg/L) TKN (mg/L) P-PO4 (mg/L) COD (mg/L) TOC (mg/L) T.Phenols (mg/L) OMWW 4.9 (±0.17) 3,93 (±0.1) 57,384 (±2,500) 24,285 Treated OMWW 9.65 (±0.25) 10.68 (±0.12) 80 (±1.45) 4474 (±1.25) 109 (±0.53) 335 180 776 25.58 6,295 (±1,199) 12,665 6,337 (±356) 606 (±50) - Not measured Table 5.5.3. Groundwater physicochemical parameters. pH EC μS/cm Eh mV Dissolved oxygen (mg/L) N-NO3- (mg/L) N-NH3 (mg/L) P-PO4+ 3 (mg/L) COD (mg/L) TOC (mg/L) Total phenols (mg/L) A 1.8 6.92(±0.15) 1259 (±310) 132 (±66) A 2.8 7.09 (±0.25) 1185(±324) 99 (±34) 1.68(±0.75) 0.46(±0.32) 0.45(±0.32) 0.08(±0.05) 27 (±16) 2.54 (±2.43) 2.04 (±0.81) 1.2 (±0.57) 0.26 (±0.01) 0.34 (±0.15) 0.14 (±0.01) 35 (±18) 1.30 (±0.98) 2.05 (±0.13) The increase of CEC observed in this study has been also observed by Paredes et al. (1987). However the previous researcher did not clearly identified the causes of CEC increase which were probably related with higher organic matter after the OMWW application. The increase of cation exchange capacity could be related to the higher pH of the treated soil, since oxides and hydroxides in soils can generate negatively charge sites in alkaline environment (McBride 1994). After 5 years of OMWW application, organic carbon appeared lower in treated soil compared to the control soil (29% decrease). This was attributed to intense cultivation of the field for more than 10 years. Moreover, the OMWW application has not enriched the soil in organic carbon. This in accordance with the results presented by others (Piotrowska et al., 2006) who showed decrease of organic carbon and return to initial values after the OMWW application dose of 100 m3/ha and incubation time of 28 and/or 42 days. Moreover the same researcher showed that dehydrogenase activity was recovered to initial values after 28 days. Dehydrogenase activity was also estimated to be statistically the same between the cultivated and control soil. The fact that soil sampling took place in November, 2 months after the end of irrigation period with pretreated OMWW, allowed the assumption to be drawn that decomposition bacteria probably had favourable conditions (OMWW had low COD and low phenolic content Final Report (Technical issue) – LIFE05 ENV/GR/00024 233/313 Environmental Friendly Technologies for Rural Development compared to untreated OMWW -Table 5.5.2) and enough time to act. In adittion, Mekki et al. (2006) presented increase in the colony forming units (CFU) for fungi populations, actinomycetes and spore forming bacteria (organic matter break down bacteria) and that was probably our case considering also the enhanced effect of maize root system in developing fungi populations and thus eased organic matter decomposition (e.g. mycorrhizal) (Tisdale et al., 1993). Consequently, decomposition of organic matter proceeded in satisfactory rate approximately 2 months after the end of OMWW application and no residual organic matter observed in soil after 5 years of practise. We expected high N concentration in soil after the application of OMWW due to mineralization of organic N. Our case revealed slightly higher N in soil and lower PMN which was probably related with the decomposition of organic nitrogen and transformation to leachable and absorbable mineral (Perez and Gallardo-Lara, 1987). Furthermore, Paredes et al. (1987) reported increase of 704% and 537% of denitrifiers and nitrobacteria after 16 days from the end of ‗alpechin‘ application. Thus, in our case probably nitrification and/or denitrification processes were started after the end of irrigation with OMWW. The presence of maize had also contributed to the mineralization and nitrification of organic N with the development of bacteria in the vicinity of plant root (Tisdale et al., 1993). In addition, tillage after the crop period probably enhanced mineralization and nitrification processes. C/N ratio in treated soil was in average 3.1 whereas in control soil was 6.2 which exhibited satisfactory decomposition for treated soil. Furthermore, C/N for treated OMWW was 21 which meant that mineralization and nitrification processes were near to starting boundary value (<20). The supply of nitrates was attenuated probably by maize NO3- uptake and/or by denitrifying bacteria with concomitant release in the atmosphere. This was in accordance with the low values of nitrates observed through out the groundwater sampling campaign. Potential mineralizable nitrogen (PMN) had relevant concentration to all surface samples whereas PMN decreased for core samples as the depth increased and this was probably due to accumulation of organic matter deeper in soil which was more resistant in decomposition. This was also confirmed by the high PMN distribution coefficient of observed for Cd sample. Distribution coefficients for mineral N and DON for treated soil exhibited identical values which meant that organic matter decomposition proceeded and no residual effects observed. Table 5.5.4 presents the load input of nutrients, organic carbon, PMN and electrical conductivity after 5 and 1 years of OMWW application. The content of nutrients in the upper 50 cm of N soil and treated soil (T1-T4) were also presented. The upper 50 cm of soil was considered for calculation of total nutrient load in soil since the majority of nutrients remained in this depth taking into account the hypothesis that nutrients infiltration rate was identical to water infiltration (0.012 cm/min, maximum ~50 cm-for 3 days constant irrigation). This hypothesis was true for the last year, since samples were taken November (high rainfall after December) and no significant rain could leach nutrients deeper in soil. In addition, return of most nutrients concentration into normal values (compared to N) for Cd sample (30-50 cm) enhanced this hypothesis. Comparison of nutrients increase in T1-T4 (Nutrient(T1-T4)-Nutrient(N)) with the OMWW nutrients input yielded the attenuation of nutrients which ranged from 55 to 100% according to the total input of nutrients in five years. Moreover, comparison with the last year nutrient input Final Report (Technical issue) – LIFE05 ENV/GR/00024 234/313 Environmental Friendly Technologies for Rural Development (2007) revealed the attenuation that occurred without the leaching effect of rain since the samples were obtained before the rain period in Greece as already mentioned (December-March). The last year attenuation in nutrient load was due to maize uptake. Potassium and calcium exhibited an increase of 55% and 175% respectively for treated soil (T1-T4) and attenuation of 82% and 40% for the last year load, respectively. Moreover, 97% and 92% was the attenuation for potassium and calcium respectively, after 5 years of OMWW application which showed that with increased application time we have increase in attenuation which was probably related with leached into deeper horizons and/or into groundwater (increased groundwater electrical conductivity). Magnesium deficiency was observed for the treated soil and probably that was related to ion exchange with potassium and leached deeper into soil. Significant amounts of potassium have been uptaken by maize (at least 45% from the last year nutrient input) due to high potassium requirements of the specific crop (Sugiyama and Ae, 2001). Phosphates and phenols exhibited high attenuation in soil which was solely due to plant uptake and soil decomposition capacity. TKN showed 82% attenuation considering the five year of TKN input and increased load of +100% considering 1 year input. Thus treated soil contained residual organic matter with strongly bound nitrogen which yielded 23% increase for T1-T4. Leaching effect has not been observed since groundwater analysis exhibited no changes in nitrates and ammonium (decomposition products in anaerobic conditions of groundwater). Thus, there was an accumulation of organic matter which has higher content of nitrogen in treated soil and probably was decayed in very slow rate. Consequently, organic load (e.g. phenols) and nitrogen chemical species (nitrates and ammonium) have been effectively attenuated without impacting the groundwater, Conclusions Irrigation with lime pre-treated and OMWW of a maize field for five years showed that the main soil effects included increase of electrical conductivity, correlated with increase of potassium and calcium availability in soil solution. Both pretreatment of OMWW and maize crop showed that enhanced the attenuation processes of organic load, phenols content, nitrates, and ammonium in soil. However, salinity was still far below threshold of salinization problem and probably application of limed OMWW in rotation with periods of non OMWW application could be an environmental convenient method of OMWW management in areas with water shortage or high irrigation demand and low organic matter and nutrient soil content (like phosphates). Groundwater quality remained untouched except electrical conductivity and this was correlated with both deep water level, slow infiltration rate and cultivation practises (cultivation of maize for potassium uptake, decomposition of organic load). Final Report (Technical issue) – LIFE05 ENV/GR/00024 235/313 Environmental Friendly Technologies for Rural Development Table 5.5.4. Amount of nutrients input in soil for 5 and 1 year OMWW application, estimated content of nutrients for the upper 50 cm of treated soil ( Nutrient (T1T4) ) and control soil ( Nutrient (N) ), percentage of nutrient changes in soil and percentage of attenuation for 5 and 1 year nutrient load compared to residual nutrient in soil (1- Nutrient (T1T4) Nutrient ( N) 5 or 1 year input OMWW InputOMWW (Kg) ± 5 years InputOMWW (Kg) ± 1 years Nutrient (T1T4) Nutrient (N) (Kg) (Kg) TKN 44,695 8,939 42,162 TOC Phenols PMN PO43+ K Mg † Ca 729,504 34,905 145,901 6,981 1,473 257,702 5,068 2,552 294 51,540 1013 510 E.C. ± † ) Nutrient (T1T4) Nutrient ( N) Nutrient ( N) Nutrient (T1T4) Nutrient (N) 1 100 5 year input OMWW Nutrient (T1T4) Nutrient (N) 1 100 1 year input OMWW 34,002 +23% -82% +100% 166,071 465 24 10 25,135 72,113 321† 231,901 480 22 0.136 16,158 100,091 117† -28% -3.5% +10% -100% -100% +55% -28% +175% -100% -97% -97% -82% -92% -40% 758 172 +340% Calculations for total nutrients in soil considered the volume of upper 50 cm of soil Calcium load was calculated from the volume of porosity considering saturation humidity. Final Report (Technical issue) – LIFE05 ENV/GR/00024 236/313 Environmental Friendly Technologies for Rural Development 2. OMW subsurface disposal and phytoremediation Phytoremediation as a restoration technology is based on the use of vegetation for in situ treatment of contaminated soils, sediments, and water. It is applicable at sites containing organic contaminants, nutrients, or metal pollutants that can be accessed by the roots of plants and sequestered, degraded, immobilized, or metabolized in situ. As far as the subsurface disposal of OMW is it concerned, there are two technological approaches that can be followed: a) One is to have a confined soil disposal area with a protective membrane placed at least 5 m below the surface so that no wastewater leaks during the winter months to the groundwater. In addition through a series of perforated pipes and pumps, the ―stored OMW‖ disposed during the winter months is recycled vertically (during the spring/summer months) in order to enhance the phytoremediation action of poplar trees. In this process one can further enhance the remediation efficiency by adding isolated bacterial degraders (of OMW) from the rhizosphere of irrigated plants (for extended periods) with OMW (Oleico process/ recent Italian patent/LIFE Environment Project, http://www.lifeoleico.it). b) A second approach is to dispose the OMW in between densely planted poplar trees taking into account the soil properties so that the groundwater is not contaminated with disposed OMW and the cost is significantly reduced compared to the approach in (a) above (as no excavation and no continuous pumping is involved). Within EnviFriendly, we concentrate on the second approach. In general, the configuration of the plants in the chosen phytoremediation area is determined by a combination of factors like wastewater irrigation system and weed control methods, OMW disposal system etc. The site where this technology is implemented is the KOKKOLIS Olive Mill in Vassilaki, Laconia (Figure 5.5.5). In this case, the poplars were planted in rows with a spacing of about 1.2 to 1.5m betweens the plants and a spacing of about 3.2m between the rows. The two-year old poplars were planted in late November of 2006 and subsurface disposal was initiated in December of 2007. The OMW delivery system includes pumps and PVC pipes needed to transfer the OMW from the olive mill facility to the distribution system at the poplar site. The OMW is distributed in subsurface perforated pipes placed between the poplar rows. The distribution pipe is located approximately 40 cm below the surface and it is placed in an excavated channel with a cross-sectional area of 50 cm X 50 cm. The channel is filled with medium size gravel. The maximum quantity of OMW that can be disposed on a particular site should be less than the Specific Retention of the soil in the area. Specific Retention is the measure of the water retained in the soil against gravity by capillary and hydroscopic forces when the water table of an unconfined aquifer drops. In our case, it is actually the maximum volume of water and OMW that can be retained against gravity in a unit area of the investigated site. Therefore, for a plant with a root system that reaches 5 m deep, the objective is not to allow the OMW plume to go beyond this limit. This corresponds to a maximum volume of OMW retained in a volume V (m3) equal to 5m 2nd Progress Report – LIFE05 ENV/GR/000245 Area (m2). 237/313 Environmental Friendly Technologies for Rural Development Raw OMW from the mill OMW distribution piping system Equilibration Tank 40 m3 1.2 m Poplar tree 29.8 m Perforated pipe 35.2 m 3.2 m Figure 5.5.5. Subsyrface disposal of OMW with phytoremediation at the ―Kokkolis LTd ‖ olive mill in Vasilaki, Hania) with phytoremediation field design. Specific yield and porosity of various materials: Group Sedimentary materials Metamorphic rocks Porous Material Range of Specific Yield Sy Average Specific Yield Syavg Range of Porosity ε Average Porosity εavg Sandstone 0.02-0.40 0.21 0.14-0.49 0.34 Siltstone 0.01-0.33 0.12 0.21-0.41 0.35 Sand (fine) 0.01-0.46 0.33 0.26-0.53 0.43 Gravel (fine) 0.13-0.40 0.28 0.25-0.38 0.34 Silt 0.01-0.39 0.20 0.34-0.61 0.46 Clay 0.01-0.18 0.06 0.35-0.57 0.42 Limestone 0.00-0.36 0.14 0.07-0.56 0.30 Schist 0.22-0.33 0.26 0.04-0.49 0.39 Final Report (Technical issue) – LIFE05 ENV/GR/00024 238/313 Environmental Friendly Technologies for Rural Development To determine the values of specific retention (S r), the values in the Table given above can be subtracted from the porosity according to equation: Sr = ε – Sy Observing the values in the Table, it can be seen that clayey soils (like the ones in our test area) have one of the highest retention capacities which is very advantageous as it allows us to dispose higher volumes of OMW at the phytoremediation site. Maximum retention capacity of the Phytoremediation area: Clay (max) Clay (min) porosity specific yield Specific Retention Area (m2) Depth (m) Liquid volume (m3) 0.57 0.06 0.51 1049 5 2675 0.35 0.06 0.29 1049 5 1521 To determine the actual maximum amount of OMW that can be disposed, one should subtract the amount of anticipated rainfall in the same area. Maximum volatilization capacity of the poplar trees in the Phytoremediation area: Poplar Trees mature > 5 years young < 5 years Pumping rate L/day Activity period days (4 mo.) Volume/tree m3/year/tree No. of trees Total volume m3 200 120 24 300 7200 120 120 14.4 300 4320 Based on our calculations, and the average rainfall in the area, the production of OMW by the KOKKOLIS olive mill which is about 1000 m3, can be accommodated by the area. As seen from the second Table above, the capacity of the poplar trees planted in the Phytoremediation area is quite high. Nonetheless, there is an additional area that it could be planted with poplar trees should the production of OMW by the plant increases substantially over the next few years. Figure 5.5.6. Sampling wells constructed in the field by the KOKKOLIS olive mill. Six sampling wells constructed in the field (Figure 5.5.6). Three level loggers were placed in different depths (3, 4, and 5 m). Sampling campaigns were done to monitor the Final Report (Technical issue) – LIFE05 ENV/GR/00024 239/313 Environmental Friendly Technologies for Rural Development temporal 3-dimensional variability of hydrology and chemistry of ground water, 6 multilevel (3, 4 and 5 m) wells were installed (Figure 5.5.7). Groundwater sampling was conducted in different periods prior and after the underground waste release. The field campaign dates were at 1/2007, 3/2007, 5/2007, 7/2007, 11/2007, 3/2008, 2/2009. The time period from 1/2007 to 11/2007 was prior the underground waste release, whereas field campaigns from 3/2008 to 2/2009 were done after the underground waste release. Poplar trees Κ2 Κ4 Κ6 Figure 5.5.7. Sampling wells design. Κ3 Κ5 Κ1 River Ground water monitoring: The multilevel wells were sampled, with a peristaltic pump with low flow (< 1 L/min), so as turbidity was maintained in minimum levels, and the physicochemical parameters pH, temperature, conductivity, dissolved oxygen (D.O.), and, redox potential (Eh) were measured in situ using the following electrodes: Orion 9107 pH meter, Orion 081010 D.O. meter, and Orion 011050 Conductivity meter. The samples were filtered through a 0.45 µm Nylon filter, stored in low temperature (with preservative when needed) and sent to laboratory. Water samples were analysed with a Hack 2010 spectrophotometer for nitrates (NO3-N, Cadmium Reduction Method, 8039), nitrites (NO2-N, Diazotization Method, 8507), ammonia (NH3-N, Salicylicate Method, 10023), phosphates (PO4-P, phosVer3 Method, 8048), total phenols (T.phenols, Folin Ciocalteu method), dissolved organic carbon (Direct Method Patent Pending, 10129) or by a TOC analyzer (Shimadzu 5050), after the removal of inorganic carbon by air sparging for 10 min), chemical oxygen demand (COD, Reactor Digestion Method, 8000), and total nitrogen (TN, TNT Persulfate Digestion Method, 10071) or Kheldalh nitrogen (TKN, by the Kjeldahl digestion technique with a Hach digestahl digestion apparatus, Nessler method, 8075). Dissolved organic nitrogen was derived by the abstraction of ammonia from the TKN. Soil sampling: Core samples were collected in 2/2009, one year after the underground irrigation with waste water. Water samples were also collected in the same period. Figure 5.5.8 shows the soil samples position. Sampling included 4 core samples in different Final Report (Technical issue) – LIFE05 ENV/GR/00024 240/313 Environmental Friendly Technologies for Rural Development depths below the irrigation pipe (0-20, 20-40, 40-60, 60-80 cm). Samples analysed for organic carbon (Walkley & Black, 1934), pH and phenols content. Phenols were extracted with 120 ml of dichlomethane (DCM) for 24 hours with 6 extraction circles per hour, in soxlet apparatus. Phenols ware measured with the Folin-Ciocalteu method (Box, 1983). Figure 5.5.8. Core samples position. Results Figure 5.5.9 presents the mean values and standard deviation from 6 wells in the 4 m depth probe. After the underground disposal of OMWW, there was a decrease in the concentrations of nitrite, ammonia, TKN and phosphate while the nitrate and phenol concentration were statistical similar. The pH, dissolved oxygen (DO) and redox potential remained constant after the OMWW application, the electrical conductivity decreased (Fig. 5.5.10). Soil samples were taken up to 80 cm below the irrigation pipe. In general, no changes were observed in pH and total organic carbon compared to the control soil (surface sample) apart from sample KE4 which showed decline in pH and increase in organic carbon content (Figure 5.5.11 and 5.5.12). Increase was also observed in the Final Report (Technical issue) – LIFE05 ENV/GR/00024 241/313 Environmental Friendly Technologies for Rural Development concentration of phenols (Figure 5.5.13). At 20-40 cm depth a great decrease was observed in phenol content whereas organic carbon was high for sample KE4. The comparison of phenols content in two samples KE4 and KE3 and the surface sample (above the irrigation pipe) is presented in figure 5.5.14. P-PO4 N-NO2 0.25 0.20 0.025 0.020 0.015 0.010 0.005 0.000 N-NO2 mg/L mg/L 0.035 0.030 P-PO4 0.15 0.10 0.05 0.00 March 07 March 07 March 08 N-NO3 Total phenols 2.00 5.00 4.00 1.50 N-NO3 mg/L mg/L March 08 1.00 0.50 Total phenols 3.00 2.00 1.00 0.00 March 07 0.00 March 08 March 07 March 08 N-NΗ3 TKN 1.00 5.00 4.00 N-NΗ3 0.60 mg/L mg/L 0.80 0.40 0.20 TKN 3.00 2.00 1.00 0.00 0.00 March 07 March 08 March 07 March 08 Figure 5.5.9. Nutrients concentration in wells of 4 m in two different time periods. pH DO 4.00 8.00 7.50 pH mg/L 3.00 7.00 6.50 6.00 5.50 5.00 DO 2.00 1.00 0.00 March 2007 March 2007 March 2008 Electrical conductivity Redox potential 2500.00 200.00 2000.00 μS/cm 150.00 mV March 2008 100.00 50.00 1500.00 1000.00 0.00 March 2007 March 2008 Final Report (Technical issue) – LIFE05 ENV/GR/00024 500.00 March 2007 March 2008 242/313 Environmental Friendly Technologies for Rural Development Figure 5.5.10. Physicochemical parameters for wells in depth of 4 m in two different time periods. Organic matter% a 6 0-20 cm 5 20-40 4 40-60 % 3 60-80 2 1 0 ΚΕ1 ΚΕ2 ΚΕ3 ΚΕ4 ΚΕ5 ΚΕ6 Control (surface sample) Figure 5.5.11. Organic matter in all samples and in control sample b) pH in all samples. b pH 14 0-20 cm 20-40 40-60 60-80 12 10 8 6 4 2 0 ΚΕ1 ΚΕ2 ΚΕ3 ΚΕ4 ΚΕ5 ΚΕ6 Control (surface sample) Figure 5.5.12. Organic matter in all samples and in control sample b) pH in all samples. Irrigation pipe wastewater Depth cm 0-20 20-40 40-60 60-80 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Total phenols (mg/Kg) Final Report (Technical issue) – LIFE05 ENV/GR/00024 243/313 Environmental Friendly Technologies for Rural Development Figure 5.5.13. Total phenols in different depths in sample ΘΔ4. Figure 5.5.14. Total phenols in different depths for samples ΘΔ4 and ΘΔ3 and the control soil. Discussion - Conclusions The subsurface application of OMWW showed no adverse effect to groundwater quality. Stabilization of nutrient concentration after the planting the poplar trees, showed that biological action of the plants decreased the variability in nutrient content. The groundwater water level in the field was on average 2.5 m (winter) to 3 m (summer) below the surface. Soil coring showed no transfer of waste in deeper horizons (below 60-80 cm) thus there are no adverse effects in groundwater from waste application. Phenols showed no variability in concentration after the subsurface application of waste water which was probably related with adsorption in soil and concomitant degradation of phenols. The rhizosphere of the poplar trees was a crucial factor for the degradation of phenols. Low pH and high organic load in core KE4 showed high spillage of the wastewater in that place. The phenol content was high in depth 0-20 cm whereas it decreases in deeper horizons which had similar phenol content to undisturbed soils (36 mg/Kg, Tsinakos field). The control soil also exhibited similar values to Tsinakos field. The subsurface application of OMWW in conjunction with phytoremediation was shown to be an effective low cost technology. 3. Electrolytic treatment of OMW. One of the alternative methods for OMW partial treatment is the use of advanced oxidation processes for the complete oxidation of the phytotoxic polyphenols present in the OMW as well as for the simulataneous reduction of COD through oxidation and the removal of coagulated particles of high COD. The advanced oxidation process used in this application is electrolysis. OMW is often disposed in Evrotas riven without any prior pretreatment to remove at least the content of polyphenols. Electrolytic treatment of OMW for a short period is expected to reduce substantially the polyphenols concentration and at the same time achieve a noticeable reduction in the COD of the OMW prior to disposal. Final Report (Technical issue) – LIFE05 ENV/GR/00024 244/313 Environmental Friendly Technologies for Rural Development As part of the LIFE EnviFriendly program, an electrolytic treatment unit was installed at the ―Ν & Α TOUTOULIS‖ Olive Mill in Platana (Laconia) with the following characteristics: (9) Electrolytic Cell (Anode: Ti/Pt/Ir with a total surface area of 160 cm 2, Cathode: stainless steel 316 (tubo) with an internal diameter of 70 cm; The complete electrolytic unit was manufactured by WATERSAFE S.A., Greece). (10) DC Power supply (WATERSAFE S.A., rated at 700 A @ 20 Vdc). (11) Recirculation pump (Lowara, stainless steel 316, with a flow of 30 m 3/h @ 4 m). (12) Stirring vessels (PVC with a volume of 0.5, 0.5 and 1 m3). Following one season of unsuccessful operation due to complete unwillingness of the olive mill owner to follow the operating instructions, it was decided to change the location of the electrolytic unit to another place in Laconia, where the wastewater is from the production of table olives (EUROAMERICANA S.A.). Experimental Results The electrolytic system was also tested in parallel in our laboratories in order to ensure that the best operating conditions have been chosen for the particular application. Effect of Voltage OMW, diluted 1 to 20 with water and following addition of 4% (w/v) NaCl (4 g/cm 3), was subjected to electrolytic treatment employing three different voltages: 5 V, 7V and 9V. The recirculation flow through the electrolytic cell was 0,62 L/s. The temperature was kept within the range 27-35 oC (Figure 5.5.15). The temperature and pH increase was the highest during the electrolysis with 9V. The gradual increase of pH can be explained by the fact that throughout the electrolysis more OH- ions are generated than H+, with the results the gradual move towards more alkaline conditions. The value of pH does not affect the production of Cl2 and the overall efficiency of the process (for an initial pH in the range 4 to 10) and hance no pH control was implemented (Rajkumar & Palanivelu, 2004). Temperature (C) 37 35 33 31 29 27 Final Report (Technical issue) – LIFE05 ENV/GR/00024 90 60 9V 120 7V 45 Time (min) 5V 30 20 15 10 5 2 25 245/313 Environmental Friendly Technologies for Rural Development 9 pH 8 7 6 7V 120 90 60 45 30 Time (min) 5V 20 15 10 5 2 0 5 9V Current Intensity (Α) Dilution 1:20, 4% NaCl 25 20 15 10 5 0 2 5 10 15 20 30 Time (min) 5V 7V 45 60 90 120 9V Figure 5.5.15. Variation of (α) Temperature, (β) pH and (γ) current intensity, during electrolysis at a constant voltage of 5, 7, 9 V. COD The drop of COD as a function of time is given in the diagram below (Fig. 5.5.16). It is obvious that the rate of COD reduction is higher as the voltage increases. We observe an initial increase of COD for 5 and 7 V before the continuous reduction of COD with time commences. This is probably due to production of intermediates (chlorinated compounds or polymerized compounfd). The production of polymerized compounds is fovoured at a low pH and temperature leading to an increase in COD (Chen et al., 2003). Final Report (Technical issue) – LIFE05 ENV/GR/00024 246/313 Environmental Friendly Technologies for Rural Development Figure 5.5.16. Changes in COD versus time for different operating voltages. The reduction of COD after 2 hours of treatment was 35,5 % at 9V, 24% at 7 V and just 3,4% at 5V. The COD reduction is directly linked to the current density which was: 7.77 A/dm2 at 5 V, 19.26 A/dm2 at 7 V and 31.54 A/dm2 at 9 V. The diagram (Fig. 5.5.17) shows the dependency of COD on the applied charge per unit volume of the liquid phase being treated. The average COD reduction is 188 mg O 2/Ah at 9 V, 200 mg O2/Ah at 7 V and 80 mg O2/Ah at 5 V. The the same amount of applied charge, the COD reduction is higher at higher voltages. Polyphenols As seen in the diagram below (Fig. 5.5.18), the phenolic compounds are degraded totally within 15 min at 9V, 20 min at 7V and 40 min at 5V. Dilution 1:20, 4% NaCl 2700 COD (mg/L) 2400 2100 1800 1500 1200 0,00 1,00 2,00 3,00 4,00 Charge per unit volume (Ah/L) 5V 7V 5,00 9V Figure 5.5.17. COD reduction as a function of the applied charge at different working voltages. Final Report (Technical issue) – LIFE05 ENV/GR/00024 247/313 Environmental Friendly Technologies for Rural Development Dilution 1:20, 4% NaCl Polyphenols (g caffeic/ L) 2,0 1,6 1,2 0,8 0,4 0,0 0 10 20 5V Time (min) 30 7V 40 50 9V Figure 5.5.18. Reduction in polyphenols as a function of time at different operating voltages. The results of the electrolytic treatment are shown together for polypohenols and COD reduction in the following diagram (Fig. 5.5.19). At an operating voltage of 9V, when the polyphenols are totally removed, the corresponding COD reduction is 14%. % Reduction COD, polyphenols 100 80 polyphenols 60 COD 40 20 0 Figure 5.5.19. Comparison of % COD and polyphenol reduction. 0 15 30 Effect of Solids 45 5V 60 75 Time (min) 7V 90 105 9V All the prevous experiments have been conducted with filtered OMW where all suspended solids have been removed. In order to examine the effectiveness of the unit in a real situation where the Olive Mill Owner neglects to remove the solids, two sets of experiments were conducted one with filtered OMW and the other without any filtering prior to the electrolytic treatment. The results are shown on the figure 5.5.20 working at a voltage of 9 V and 4% NaCl. COD The profile of COD with respect to time for not filtered OMW is shown on the figure 5.5.21. As expected the initial COD is much higher compared to the filtered one. After 2 Final Report (Technical issue) – LIFE05 ENV/GR/00024 248/313 120 Environmental Friendly Technologies for Rural Development hours of electrolysis, the COD of the non-filtered OMW was reduced from 6545 mg/L to 5080 mg/L and for the filtered OMW, COD was reduced from 2310 mg/L to 1490 mg/L. Figure 5.5.20. Changes in (a) temperature, (b) pH and (c) current density, during the electrolytic treatment of OMW filtered and not filtered. Polyphenols First it is worth noticing that the total amount of phenolic compounds is double for the nonfiltered OMW. The reduction of polyphenols as a function of time is shown in figure 5.5.22. For the filtered OMW, the polyphenols (1.52 g/L) are removed within 30 min. During the same period, the polyphenols drop from 2.85 g/L to 0.82 g/L. The presence of solids does not affect the phenol reduction rate as the two curves are practically parallel. Figure 5.5.21. COD reduction of non-filtered OMW as a function of (a) time and (b) charge. Final Report (Technical issue) – LIFE05 ENV/GR/00024 249/313 Environmental Friendly Technologies for Rural Development Figure 5.5.22. Reduction of polyphenols versus time for filtered and non-filtered OMW. Colour The decolourization of the OMW corresponds to the degradation of high molecular weight compounds with mineralization of the low molecular weight aromatic compounds. The polymerized aromatic compounds are responsible for the dark colour. Complete decolorization coincides with the removal of the polyphenols. The colour is removed faster at higher operating voltages and higher NaCl concentrations.The time for decolorization varies from 10 min to 1 hour depending on the conditions. (a) (b) Figure 5.5.23. Samples from experiment at a volatage of (a) 9V and (b) 7V. Effect of Solids As seen below (Fig. 5.5.24), the effect of solids is very strong on decolorization. Their presence results in a temporary increase in colour. Final Report (Technical issue) – LIFE05 ENV/GR/00024 250/313 Environmental Friendly Technologies for Rural Development Figure 5.5.24. Change of color with time after treatment. We observe an increase in the rate of decolorization with increasing voltage and NaCl concentration. At higher OMW concentration we observe an initial increase in colour due to temporary polymerization of the polyphenols (Fig. 5.5.25). Based on the above experiments we can readilty conclude that OMW pretreatment for the removal of the suspended solids is essential for a succeful and efficient decolorization and ployphenol removal. Figure 5.5.25. Comparison of change of color of filtered and non-filtered OMW with time. Conlusions and Recommendations From the previous experiments we arrive at two important conclusions: Decolorization and removal of polyphenols takes place in a very short period of time if we have removed all suspended solids from the OMW. The effectiveness and efficiency of the electrolytic system increases substantially as the concentration of NaCl increases. The above findings coupled with the unwillingness of the TOUTOULIS Olive Mill ownwers to do any pretreatment whatsoever, lead us to the decision to transfer the electrolytic unit from their premises to another location in Laconia. It was decided to move the unit to the industrial unit for the production and packaging of table olives, EUROAMERICANA Final Report (Technical issue) – LIFE05 ENV/GR/00024 251/313 Environmental Friendly Technologies for Rural Development S.A., for the treatment of their wastewater. This choice was made since the wastewater of table olives is already rich in NaCl and the unit is expected to work much better. Indeed, in May 2009 the unit was put in operation at EUROAMERICANA S.A., and the first results were very encouraging. Table olive processing occurs through a series of steps, namely initial olive cleaning, debittering, washing, fermentation and packing. Table olives wastewater is similar to olive mill wastewater, however, it is not as strong in terms of COD and suspended solids and it has in addition sodium chloride, calcium chloride and lactic acid. As a result this wastewater has a high conductivity (about 100 mS/cm) and a pH of about 4.5. Since the amount of salt added for processing is quite high (about 10 kg salt per 120 kg of kalamata olives) EUROAMERICANA S.A. has instituted a brine recycle scheme to reduce the cost of salt usage and to reduce the amount of wastewater. EUROAMERICANA S.A. has final disposal vessels (septic tanks) to keep their effluents prior to final disposal. The electrolytic unit was installed prior to the disposal tanks whereby the effluents are pumped from a small flow equilibration tank to the electrolytic cell vessel where they are oxidized and overflow into the final disposal tanks. The overflowing stream is where the electrolytically-treated effluents can be sampled to test the efficacy of the installed unit. During the month of May (2009) the facility was mostly packing the olives and hence, the generated wastewater was not very strong in terms of COD. Nonetheless, the installed electrolytic unit was able to fully remove the dark color from the effluents. A couple of samples were tested for COD removal which was of the order of 50%, however, the initial COD load was quite low (of the order of 1.5 g/L). The unit is expected to work satisfactorily as we have conducted independent experiments in the Technical University of Crete where it was shown that electrolytic treatment of table olives wastewater can achieve complete decolorization, remove more that 50% of initial COD (a load of about 5 g/L) and essentially achieve complete removal (98%) of polyphenols. 4. Prototype unit for treatment of Orange Juice wastewater The Lakonia Orange Juice Plant produces large amounts of orange juice and although it has a complete biological wastewater treatment facility already in place, significant problem in the effluents are observed particularly during the period of peak production. We investigated possible improvements in the treatment and arrived at a few changes in the current operation of the facility. We installed an electrolytic pretreatment unit. The unit is placed in the outlet of the dissolved air flotation (DAF) unit and prior to the biological treatment. The location of the unit is expected to aid by partially oxidizing the wastewater and making more easily degraded by the microorganisms. Excluding the mixing vessel, the rest of the equipment is placed on four wheels to make it easily transportable to another location in the plant. The installed electrolytic unit was evaluated for its capability to aid the overall operation (lower COD in the effluent stream) and decolourization of the final effluents. Existing situation Final Report (Technical issue) – LIFE05 ENV/GR/00024 252/313 Environmental Friendly Technologies for Rural Development As a first step the overall wastewater treatment facility was examined and our findings were communicated to the Director of the plant. The general observation is that the system does not work satisfactorily during periods of peak production. By examing the existing units, we were able to pinpoint the problem. The wastewater reached first the flow equalization vessel (Fig. 5.5.26) and then proceeds to the Dissolved Air Flotation (DAF) unit where the solids (i.e., the natural fibers of the orange fruit) are removed. The efficiency of this unit is very important as ceculose is difficult to biodegrade. In the figure 5.5.27 the fibers are shown in the equillization vessel. Subsequently the wastewater is pumped to the DAF where the fibers are removed with the addition of coagulants (Fig. 5.5.27). Figure 5.5.26. Flow Equilization vessel where the wastewater arrives first. Addition of coagulants Flotation and removal of solids Effluent from the D.A.F. Natural fibers that have been collected Final Report (Technical issue) – LIFE05 ENV/GR/00024 253/313 Environmental Friendly Technologies for Rural Development Figure 5.5.27. Typical setup of the facility. The DAF works satisfactorily as the effluent does not contain at least visible fibers. The flocculated natural fibers are then taken to the dewatering unit where most of them are removed from the system; however, a large amount of smaller fibers is returned to the pumping station and directed to the biological treatment units (Fig. 5.5.28). From D.A.F. (without fibers) From dewatering unit (fibers are present) Figure 5.5.28. Pumping station (flow from DAF and dewatering unit). The presence of the fibers is evident form the yellow color of the feed taken from the pumping station to the biological treatment unit (Fig.5.5.29). Figure 5.5.29. Pumping of pretreated wastewater where fibers are still present as evidenced by the yellow colour. Final Report (Technical issue) – LIFE05 ENV/GR/00024 254/313 Environmental Friendly Technologies for Rural Development Given the above findings it was decided to follow two alternatives taking into consideration the fact that the plant was not in a position to change the dewater unit. 1st Alternative: Electrolytic Pretreatment of the wastewater We proceeded with the installation of an electrolytic unit with the primary goal to oxidize in part the returning solids in the pumping station prior to their transfer to the biological treatment unit (Fig. 5.5.30). Figure 5.5.30. Installation of the electrolytic Unit in the pumping station. The effectiveness of this approach was very difficult to evaluate on the site because of the variations in the federate and the long residence time of the wastewater in the biological treatment unit. As a result, we examined the efficiency of the unit with independent experiments in our laboratory using the same wastewater. 2nd Alternative: Decolorixation of final effluent The goal here was to evaluate the electrolytic decolourization of the final effluent regardless of the overall treatment efficiency of the existing facility. This was done with independent experiments in our lab and in the field. The color of the final effluent is shown in the figure 5.5.31 when no treatment is applied. Based on our findings a complete unit was designed for the decolorizationof the effluent at all times and was given to the plant Director. Final Report (Technical issue) – LIFE05 ENV/GR/00024 255/313 Environmental Friendly Technologies for Rural Development Figure 5.5.31. Colour of final effluent during the period of normal operation (not peak period). Results The graduate student involved in this project carried out a complete experimental design where many operating variables were examined. The complete experimental matrix is shown in the table 5.5.5. It is noted that the COD of the inlet wastewater to the biological treatment unit was higher than 10.000 mg/L whereas the final effluent was always less than 1.000 mg/L. In both cases the yellow colour was always there. Table 5.5.5. Experimental setup. Current 10Α Flowart e 0,9L/s ec 0,6L/s ec Electr olytic cell Operating conditions Pt/Ir Concetration of Na2SO4 Concetration of NaCl 0,5% 1% 2% 3% √ 4% 6% 1% √ 20Α √/ √ √ 40Α √ √/ √ 6% √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √/ √ BDD √ √ 120 min √ √/ √ >450 min √: Final effluent √: wastewater from the inlet of the biological unit Effect of operating voltage Final Effluent Three different operating voltages were examined: 10, 20 και 40A. The salinity was 4% NaCl and the temperature was kept contsnat at about 25 0C.. A small yet consident increase of the pH was observed in all experiments (Fig. 5.5.32). pH NaCl 4% 8,8 8,6 8,4 pH 8,2 8 7,8 7,6 10 A 20 A 7,4 Final Report (Technical issue) – LIFE05 ENV/GR/00024 0 20 40 256/313 40 A 7,2 60 80 t (min) 100 120 140 Environmental Friendly Technologies for Rural Development Figure 5.5.32. Change of pH with time. COD The COD removal as a function of operating current density is shown in the figure 5.5.33. The COD measurements have been adjusted for apparent increase due to the presence of salt. COD removal (%) Time (min) Figure 5.5.33. COD removal with time. Decolourization As seen, decolourization is achieved within the first 5 min of electrolytic treatment. The colour measurement at 440nm is the most representative (Fig. 5.5.34). TOC Whereas we have seen a COD reduction of aboput 50% after 120 min, no reduction in TOC is observed. This means that we have addition of oxygen atoms in the organic compound but no mineralization (Fig. 5.5.35). Χρώμα NaCl 4% 20A 4000 0 min 3500 Χρώμα colour NaCl 4%, 20A 3000 5 min 60 min 2500 120 min 2000 1500 1000 500 0 400 450 500 550 Wave length (nm) 600 650 700 Χρώμα NaCl 4% 40A Μήκος κύματος (nm ) 10000 9000 Χρώμα colour 0 min NaCl 4%, 40A 8000 5 min 7000 60 min 6000 120 min 5000 4000 Final Report (Technical 3000issue) – LIFE05 ENV/GR/00024 257/313 2000 1000 0 400 450 500 550 Wave length (nm) Μήκος κύματος (nm ) 600 650 700 Environmental Friendly Technologies for Rural Development Figure 5.5.34. Absorbance of effluent as a function of time and wavelength. TOC 10-20-40A 29,00 27,00 TOC (ppm) 25,00 23,00 21,00 19,00 4% NaCl 10A 4% NaCl 20A 17,00 4% NaCl 40A 15,00 5 25 45 65 85 105 125 t (m in) Figure 5.5.35. TOC of the effluent as function of time at different operating currents. Effect of Salinity The wastewater was treated at four different salinities: NaCl – 0.5, 1, 2 and 4%. The changes in the pH are minimal as shown in figure 5.5.36. pH 20A 10 9,5 pH 9 8,5 8 0,5% NaCl 1% NaCl 7,5 2% NaCl 4% NaCl 7 0 20 40 60 80 100 120 t (m in) Final Report (Technical issue) – LIFE05 ENV/GR/00024 258/313 Environmental Friendly Technologies for Rural Development Figure 5.5.36. change of pH with time for the different NaCl treatments. The COD reduction as a function of time and operating current is shown in the figure 5.5.37. The highest reduction is observed for the experiments at 2 & 1% NaCl. %Απομάκρσνση COD 70 60 COD removal (%) % Απομάκρσνση COD3 50 40 30 0,5% NaCl 20 1% NaCl 2% NaCl 10 4% NaCl 0 0 20 40 60 80 100 120 Time t (m(min) in) Figure 5.5.37. COD removal with time. Decolourization Decolourization takes place within 5 min for the experiments with 2 and 4% NaCl whereas 15 min are required for the experiments at 0,5 and 1% NaCl. The samples with 2 and 4% NaCl were decolourized by 96%, whereas the experiments with 0,5 and 1% NaCl were only 30 and 56% decolorized (as measured at 440 nm) (Fig. 5.5.38). Χρώμα NaCl 1% 5000 0 min 4500 5 min 4000 NaCl 1% 3500 Χρώμα colour 15 min 3000 60 min 2500 120 min 2000 1500 1000 500 0 360 410 460 4000 Χρώμα NaCl 2% 510 560 610 Wave length (nm) 660 Μήκος κύματος (nm ) 0 min 3500 5 min Χρώμα 3000 colour NaCl 2% 60 min 2500 120 min 2000 1500 1000 500 0 380 430 480 530 580 630 680 Wave length (nm)) Χρώμα NaCl 4% 20A (nm Μήκος κύματος 4000 0 min 3500 3000 NaCl 4% Χρώμα 2500 Final Report (Technical issue) – LIFE05 ENV/GR/00024 colour 2000 1500 1000 500 5 min 60 min 120 min 259/313 Environmental Friendly Technologies for Rural Development Figure 5.5.38. Change of color with time. TOC Similarly we observe no reduction in TOC although a significant reduction in COD was observed. Conlusions and Recommendations Based on the results the following recommendations were made Change of the Dewatering Unit - The best solution, yet not the most economical, is the substitution of the existing dewatering unit with a new decanter of high effiency. This is the best solution for the long run. Changing the existing piping – return from dewatering unit - The simplest approach is to change the location where the returned liwuids from the dewatering unit are returned. Instead of the pumping station, these should go to the flow equalization vessel and pass again from the DAF. As a result only the effluents from the DAF will be pumped to the biological unit. The only concerne is whether the quality of the separation in the DAF will fall if the flow is operated at a higher level. Electrolytic Pretreatment - The electrolytic pretreatment resulted in a reduction of the overall COD however, no reduction was observed in the TOC. This suggests that oxygen atoms are insered in the organic compounds which makes them more easily biodegradable; however, no minerilzation of the wastewater was observed. Decolourization - The electrolytic unit can be used independently for the decolourization of the final effluent. With residence times of the order of 5 min only, a satisfactory decolourization is achieved (>96%) where no yellow colour is visible. Recommendations 2 and 4 are readily implementable and the Director of the plant has accepted them. Final Report (Technical issue) – LIFE05 ENV/GR/00024 260/313 Environmental Friendly Technologies for Rural Development TASK 5 - Integration of socio-economic aspects 1 Results of the fieldwork research Public Participation and Information Within the framework of the LIFE project, the tasks of the NCSR research team included: The study of the social implications of the project interventions and the attainment of social consent and acceptance. The planning and implementation of a dissemination campaign to inform the public about the objectives and the results of the project. The NCSR research team elaborated a series of studies and fieldwork activities seeking to reveal and register the local peculiarities and problems (floods, fires), as well as the local dimension of specific environmental management issues (recycling). During the interim report, the NCSR team also implemented a series of information and sensitization actions (production and dissemination of printed and electronic material, organization of workshops and public events), many meetings and discussions with local stakeholders. Overall, the whole of the aforementioned activities set the basis for a long-term constructive public consultation process that evolved throughout various research project phases (goal setting, opinion-registering, information about the project‘s actions and the foreseen implications, new meetings and new information events based on the latest data collected etc.). Thus, the NCSR team established a solid network of co-operation with the local stakeholders which resulted in spectacular partnerships (e.g. the creation of Open Farms with New Farmers‘ Union, the Mapping Trails with the Sparta Hacking Association etc.). The co-operation with local stakeholders, such as the municipal authorities around Evrotas, the local agencies for land reclamation (TOEB) of these municipalities and the environmental education institutions of the wider area, was continuous. The overall objective of the aforementioned co-operation was the viability of the Network of Co-operation of Local Stake-Holders following the completion of the project. This Network will be based on the Observatory for Sustainable Development. Its operation will be the responsibility of the Prefecture of Laconia and its tasks will include the collection of information material regarding local development perspectives, the provision of information to and the collection of feedback from all stakeholders and citizens, the overall coordination of the development actions and the participation to the resolution of the emerging development problems. Brief summaries of these surveys and studies are presented below, offering a synopsis of the views and observations of the responsible (in each case) local actors and of a sample of the local population. Professionals - Residents Comparative presentation of two surveys results Following the completion of two surveys (initial and repetitive) the results have been correlated by the NCSR researchers. An overview of the comparison of these results is given below: Final Report (Technical issue) – LIFE05 ENV/GR/00024 261/313 Environmental Friendly Technologies for Rural Development 5. According to the initial survey, the Evrotas River is perceived primarily as a significant agricultural asset (55.00%) and secondarily as a source of natural wealth (31.00%). Only 14.00% of the respondents consider Evrotas as a historic and local cultural asset.Respectively, according to the repetitive survey, the Evrotas River is primarily perceived as a considerable agricultural asset (60.7%) and secondarily as a source of natural wealth (19.7%). Only 12.1% of the respondents perceive Evrotas as a historic and local cultural element. By comparison, the findings are similar and indicate a marked increase in the proportion of responses that positively value the contribution of Evrotas in the rural development especially as a supplier of water resources (44.4%). 6. Regarding the problems that Evrotas presents, respondents in the initial survey emphasized primarily the problem of pollution (total of relevant answers 65.00%) and secondarily the fact that most of the river‘s development potential remains unexploited (23.00%). A 12.00% percentage of the population referred to the problem of floods and draught. In the repetitive survey, 38.9% of the respondents stress the population problem while there is a marked increase in the percentage of respondents who consider draught and floods to be the primary problem generated by the Evrotas River (36.2%). This marked increase is attributed both to the damage caused by the relatively recent floods and particularly by the prolonged drought. The percentage of respondents that emphasized the unexploited development potential of the river (the irrational use of water resources) was about the same (22.2%). 7. With reference to the expectations generated by Evrotas, according to the results of the initial multiple-choice survey, the majority of respondents stressed the river‘s value as a clean and abundant source of water (72.2%) and a wetland of valuable flora and fauna (62.1%). Secondly, in the opinion of respondents, Evrotas could be used as a recreational area (22.7%) and serve as an incentive to attract tourists (19.5%). The findings of the repetitive survey are similar. Considering the future contribution of the Evrotas River in local development, 70.9% of respondents identified Evrotas‘ significance as a high-quality water resource (which contributes to the increase of agricultural production and the enhancement of quality of life), 16.2% of respondents referred to the rivers‘ use as a tourist attraction incentive, while 12.2% mentioned the use of Evrotas as a means to raise funding from Community and national resources. 8. According to the initial survey, respondents considered that the contribution of the LIFE / EnviFriendly project to the resolution of the Evrotas‘ management problems should primarily focus on the reduction of pollution (39.6%) and the elaboration of water resources and riparian land management plans (36.6%); and secondarily, on the best exploitation of the river (13.4%) and the management of seasonal floods (10.4%). According to the repetitive study, from the whole of the respondents who were familiar with the implementation of the LIFE / EnviFriendly project, 47.7% considered the project‘s main contribution to be the monitoring of pollution and of the pollution sources, while 15.4% most highly valued the quantitative and qualitative management of the water resources. Adding to the above percentages the percentage of respondents who emphasized the antiFinal Report (Technical issue) – LIFE05 ENV/GR/00024 262/313 Environmental Friendly Technologies for Rural Development pollution measures adopted for the Evrotas River (relevant categories) it is clear that the two major inputs of the projects consisted of the reduction of pollution and the wise water resources management. The above findings lead to the conclusion that both the initial content and objectives of the LIFE / EnviFriendly project and the implemented actions (elaboration of management proposals, dissemination – sensitization activities, local events and workshops etc.) evolved in accordance with the priorities and the expectations of the local professionals and residents. Subsequently, the NCSR research team argues that the goal of social acceptance of the proposed interventions has been largely achieved. Moreover, it is indicative that 16.9% of respondents have positively valued the contribution of the project to the mobilization of the relevant communication mechanisms and the provision of information to the local population regarding the prospects of sustainable local development. The basic conclusion of both the initial and (especially) the repetitive surveys is the promotion of the urgency of the Evrotas pollution problems and of the need for wise water resources management, and the realization by the vast majority of the local community of the fact that the aforementioned problems cannot be resolved without the adoption of relevant planning measures. This conclusion has been verified the respondents‘ demand for the prioritization of pollution reduction and specialized water resources management plans in any future programming. Elected Officials – Representatives of the Municipalities around Evrotas Overview of the findings of the initial survey One of the most important, if not the most important, research findings is the fact that elected officials positively view their participation in practices that promote sustainable development (95%), particularly through institutional and communicative means. Moreover, a significant percentage (62.4%) of elected officials is familiar with the «integrated forms of agricultural production» and vastly supports the dissemination of information about them (76.5%). The aforementioned findings are indicative of the existence of a particularly fertile framework for the long-term exploitation of the project‘s results. The long-term implementation of the project foresees the establishment and operation of the Local Development Observatory. The positive inclination and the high degree of awareness of the elected officials will positively contribute to the success of the Observatory given that it will be housed in the prefecture and will be staffed by employees of the local authorities. As already mentioned, elected authorities have a primary role to play in the dissemination of information since they are themselves communication channels between the citizens and the project administrators. The dissemination of the relevant information can be realized through three different ways: a) First, through the information sources elaborated by the project: information workshops, website, environmental education, printed material, posters etc. Final Report (Technical issue) – LIFE05 ENV/GR/00024 263/313 Environmental Friendly Technologies for Rural Development b) Second, through the active participation of the elected authorities in the implementation of the project and the permanent co-operation with the project managers; this is necessary for the two-way dissemination of information. The project seeks to produce a know-how totally adapted to the peculiarities and the needs of the local community. c) Finally, the elected local authorities can function as opinion leaders and disseminate information about the project, generate discussion over the achievement of the project‘s objectives and communicate expectations, ideas and solutions regarding the development perspectives of the region. One more remarkable finding is the fact that the majority of respondents perceive Evrotas as primarily contributing to the irrigation of the region and local agricultural development (39.8%). Simultaneously, respondents blame industrial, agricultural and house wastes (35.8%) and the irrational water resources management (29.9%) as the main sources of the pollution of the Evrotas River. Subsequently, elected authorities argue that the LIFE / EnviFriendly project should directly focus on the monitoring of the pollution and the pollution sources and the quantitative and qualitative management of the water resources (81% and 77% respectively). These findings are very important since they reflect the needs and problems of the local community. Furthermore, they highlight particularly interesting issues such as the local authorities‘ utilitarian perception of the Evrotas River as a water source and their weakness up-to-date to fully explore the river‘s cultural, historical and environmental development potential. The rich and long-term history of the region, if properly explored, could contribute both to the economic development of the area, e.g. as a tourist attraction, and to the enhancement of the quality of life of the residents. However, it seems that today the agricultural qualities of the river have prevailed over its cultural, environmental and tourism qualities. Finally, elected officials have expressed their belief that the LIFE / EnviFriendly project would lead the way for the implementation of similar projects by local stake-holders (91.9%). However, it shoul;d be noted that the implementation of new projects is not the only goal of the project. The project also seeks the elaboration of a set of feasible solutions fully adapted to the local needs, the improvement of the current conditions and the dissemination of local ―best-practice‖ examples. Summary conclusions of the repetitive survey Following the completion of the survey and the analysis of the data, the following conclusions can be drawn: a) Overall, the vast majority of elected officials is substantially informed about the progress of the LIFE / EnviFriendly project and the project‟s implementation guidelines. Moreover, many elected officials had been directly participated in the information meetings that concerned the local peculiarities and needs, as well as to the various dissemination activities throughout the implementation of the project. Final Report (Technical issue) – LIFE05 ENV/GR/00024 264/313 Environmental Friendly Technologies for Rural Development b) Elected officials have demonstrated only limited awareness of the Observatory for Local Development. This could be due to the organizational difficulties that have hindered the smooth operation of the Observatory and the only partial clarification of the Observatory‘s tasks. The NCSR researchers estimate that in the long-run and following the full operation of the Observatory elected officials will comprehend its significant contribution in the development of the region mostly as a co-ordination and information mechanism. c) Regarding the familiarity of local officials with the ―integrated forms of agricultural production‖ there are significant differentiations depending on the orientation of each municipality (i.e. whether the municipality is oriented towards the primary or the tertiary sector). However, it is indicative that the elected officials who have a relevant professional activity are fully aware of the ―integrated forms of agricultural production‖ and could subsequently disseminate the relevant information to the residents of their locality. d) The whole of the officials have a positive opinion as regards the content and objectives of the LIFE / EnviFriendly project and its successful implementation. Moreover, they fully agree with the project‘s prioritization of the local development problems, as well as with the project‘s proposals regarding the required managerial measures. e) Finally, nearly the whole of the respondents consider the implementation of the LIFE / EnviFriendly project to have provided the local community with considerable know-how regarding the implementation of European projects in the field of local development and to have opened the way for participation in future European projects. Considering the fact that elected officials have agreed with the importance attributed by the LIFE / EnviFriendly project to the exploration and wise management of the water resources of the Evrotas River, it would be reasonable for any future European projects to follow the thematic lines of the LIFE / EnviFriendly project. The above findings allow a lot of optimism regarding the future participation of local officials in the management of forecoming projects and the achievement of the necessary social acceptance by the whole of the community. Research Results on Floods The pilot research on the floods of the Evrotas River in Laconia complements the research «Reducing the floods‘ impact - New methods to cope with flooding and the central role of local authorities‖ of Dr. R. Gkeka and A. Mitsou. To get a broad picture of floods in the case-study region the NCSR researchers first contacted the Laconia branch of the General Secretariat for Civil Protection (GSCP) and then the Greek Agricultural Insurance Organization (first the Tripolis Branch and second the Central Office in Athens) from where they obtained the approvals and allowances tables for 2003 and 2005 and the Prefecture of Laconia. Then, the NCSR researchers specially designed two questionnaires to address the specific target-groups. The first questionnaire was addressed to the local authorities of the municipalities around the Evrotas River and was Final Report (Technical issue) – LIFE05 ENV/GR/00024 265/313 Environmental Friendly Technologies for Rural Development completed by the Mayors with the goal to register the readiness and the prevention and recovery capacity of the municipalities in case of flood. The second questionnaire was addressed to the residents affected by floods and was completed through personal interviews with the aim to detect the residents‘ familiarity with the protection measures and the relevant compensation and rehabilitation procedures. Below there is a brief overview of the relevant findings. Results of the flood awareness questionnaire to local authorities The questionnaires were completed with the assistance of the elected officials – managers of the LIFE / EnviFriendly project in January 2007 by the Mayors of 7 out of 8 municipalities to which the questionnaires had been originally distributed. The findings of the questionnaire to the local authorities and the relevant research ―Plan for flood disaster management in Laconia‖ are summarized below: 1. 4 out of 7 municipalities ignore the existence of an emergency plan in case of flood in their region. 2. The vast majority of respondents (5 municipalities) declared the flood readiness of both manpower and equipment. 3. During the peak rainfall periods 4 out of 7 municipalities are particularly alert. 4. Only 2 municipalities are aware of the regular monitoring of the hydrology and geomorphology of the river by the Prefecture. 5. Most of the municipalities regularly follow the weather forecast (meteorological data) on the Media (TV, radio etc.) while one municipality has its own local meteorological station. 6. 3 out of 7 municipalities monitor the history of floods in their region while 2 keep a record of floods. 7. In all 7 municipalities, there is no municipal institutionalized specialized mechanism to coordinate activities in case of emergency (there are however cases of co-operation between municipalities, e.g. the co-operation between the Skala and Elos municipalities). 8. Similarly, there is no compensation foreseen (through contribution) for properties which have been shown to impede the flow of the river. 9. Municipal authorities in all the municipalities ignore the existence of information and education programmes for the citizens whose property is located in high risk areas. 10. In over half of the municipalities the local population (agricultural associations and citizens) participate in flood protection actions. 11. 5 out of 7 municipalities agree on the need for better information and enhanced readiness of the local community regarding flood prevention and rehabilitation. Final Report (Technical issue) – LIFE05 ENV/GR/00024 266/313 Environmental Friendly Technologies for Rural Development 12. The majority of the municipalities agree that flood management is problematic and recognizes the need for inter-municipal co-operation for flood protection and rehabilitation in the case of the Evrotas River. Results of the flood awareness questionnaire to residents The questionnaires were completed in Sparta in January 2007. The respondents affected by floods can be grouped in 3 categories: 1. Riviotissa area: The GSCP had prepared an initial list of the financial compensation petitions of the home owners affected by the 2006 floods. 2. Klada area: The GSCP possessed information about those affected (crop production) by the 2003 flood. 3. In the street market of Sparta the NCSR researchers interviewed four producers who had been affected by floods outside the Sparta Municipality (harvest located in other municipalities). A number of questionnaires were also completed by Riviotissa and Klada residents not recommended by the GSCP. More specifically: 12 questionnaires were completed in Riviotissa. 6 in Kladas. 4 in regions of other municipalities outside the Sparta Municipality. To the question « Is your property located in a high risk area? » the majority of the Riviotissa residents and the whole of the residents of Klada and of the regions outside Sparta gave a positive answer. The land uses in the case-study regions consisted of: 1. Half of the Riviotissa residents and all of the Kladas / other regions‘ residents answered that they have crops (orange trees in Riviotissa and Klada and garden produce in the other regions). 2. In Riviotissa there is one enterprise; all respondents have their primary residence in Riviotissa, Kladas and the other regions. 3. With the exception of the aforementioned enterprise, 2 farms exist in Riviotissa, 1 in Kladas and 1 in the other regions (sufficient number of animals, sheep and goat). To the question « Do you think that a system of early warning would more efficiently protect your property? » positive responses were divided in all three cases: Riviotissa (40-60%), Kladas (70-30%) and other regions (50-50%). To the question « Do you know how to protect your-self from floods? » most of the respondents in Riviotissa (10 out of 12) gave a negative answer, while most of the respondents in Kladas gave a positive answer (5 out of 6). Final Report (Technical issue) – LIFE05 ENV/GR/00024 267/313 Environmental Friendly Technologies for Rural Development To the question « Do you know whom to contact in case of flood? » responses were divided with 7 out of 12 respondents in Riviotissa, 2 out of six in Kladas and 1 out of 4 in the other regions giving a negative response. To the question « Would you be willing to participate to a system of prevention of the impact of floods in Evrotas? » the majority gave a positive response in all three cases. Concerning the issue of financial compensation, 40% had submitted the necessary documents and had already received or were in the process of receiving financial compensation, 32% had submitted the relevant documents but had been rejected while 27% had not taken any action. (The storage equipment enterprise in Riviotissa which had flooded did not apply for financial compensation). In conclusion, the following remarks can be made: The residents are well aware of the fact that their property (produce/residences) is located in high risk areas. There is a need for the establishment of an information and early warning system. There is a need to inform the population as to the agencies involved in the repairing of the damages following a flood. People are willing to participate to preventive actions and activities. Management Measures on the Impact of Fires The LIFE project research team thoroughly analyzed the impact of the 2007 fires and prepared a series of studies on fire restoration treatment. In particular, the researchers of NCSR examined the prospect of the creation of Animal Parks in the region and prepared a relevant study whose main findings are presented below. ANIMAL PARKS It is obvious that livestock farmers in the affected areas are in need of extensive support and better information. Furthermore, the recent damages and the subsequent need for restoration – reform demand radical changes in the operating system of the animal farms and the adoption of improved (if not integrated) long-term business actions by the producers. All these constitute prerequisites for the restructuring of animal husbandry and of the broader primary production in accordance with the new Common Agricultural Policy (CAP) requisitions. At this point it would be useful to mention the peculiarities of Greek animal husbandry. The Greek land use agenda, rural infrastructures and climate conditions constitute a framework with the following dimensions: a) Animal husbandry consists of numerous small units, many of which are located within settlements. Final Report (Technical issue) – LIFE05 ENV/GR/00024 268/313 Environmental Friendly Technologies for Rural Development b) The urban organization of the countryside and the relevant differentiation of land use and infrastructures, combined with the small size of plots, have led to the emergence of agricultural settlements rather than scattered farms. c) The climate conditions do not allow the development of natural pasture of large grazing-capacity resulting in animal husbandry directly depending on agricultural fodder production. The aforementioned points demonstrate the need of the creation of animal reception and husbandry units that will be adapted to the local conditions and the pre-defined organizational framework. Subsequently, the creation of Animal Farms would enhance the livestock producers‘ capacity to find effective and economically-sound solutions to their problems, and would simultaneously secure the operation of the smaller units and the protection of the environment. Today, there is an urgent need for animal stalling at least in the fire-affected areas. However, a lot of complexities emerge and need to be considered: a) Technological complexities: bio-ethical reasons and enhanced production purposes demand the modernization of the animal stalling conditions. b) Social complexities: animal stalling requires the improvement of farmers‘ working conditions, the protection of the agricultural environment (villages and settlements) and the safeguarding of residents‘ health. c) Financial complexities: animal stalling demands considerable financial resources and defines the sustainability of goat, sheep and cow breeding. The main benefits of the operation of Animal Farms include: Significant increase in the livestock farmers‘ income, protection of the environment, enhanced quality of the produce, improved health and controlled feeding of the animals, improved living conditions for the animals and working conditions for the people, farmers and herds spending the winter with the mountain Communities avoiding the disorganization of the latter, co-operation and trust between different small animal husbandry groups, use of the common infrastructure of the parks, pre-planned and controlled pasture management and exploration, more effective environmental protection (infestation, pollution, degradation) and beautification of agricultural landscape with the building of environmentally harmonized farms. Survey on the Recycling Procedures and Problems Questionnaire to Public Stakehoders During the first week of April 2008, the NCSR researchers conducted their fieldwork in the Municipality of Sparta regarding public and private stakeholders‘ role in the recycling of paper, personal computers, printers and ink cartridges. The completion of the relevant questionnaires took place in the Prefecture of Laconia, the Municipality of Sparta, the educational institutions of the region and other public actors (Banks, Hospital, Tax Office, Hellenic Telecommunications Organization, Social Insurance Institute, Public Power Corporation and Library), as well as in private businesses involved in the transfer of paper. Final Report (Technical issue) – LIFE05 ENV/GR/00024 269/313 Environmental Friendly Technologies for Rural Development The existing situation in the recycling field is presented below based on the replies of the respondents: Paper recycling: the Municipality lacks a system of organized and regular collection. Thus, the actors that collect paper for recycling do not know how to dispose of the collected material. The whole of the respondents have expressed their will to participate in any future recycling action, though some (Tax Office and other public stakeholders) emphasized the existence of confidential documents that should be destroyed. PC and printers‟ recycling: there is considerable variation in the disposal of older or obsolete appliances. More specifically, the Prefecture gives them for recycling, the Municipality grants them to schools, the educational institutions and the Hellenic Telecommunications Organization save them for potential future use while the private companies store them in their basement. Ink cartridge: the Prefecture and the Library are the only public or private stakeholders with a collection system. There are individual recycling initiatives (a teacher collects cartridges from all the educational institutions and recycle them in Tripoli). A lot of the respondents argued for the necessity of a municipal collection system. Finally, special comments were made by the respondents for the proper disposal of infectious waste (hospital waste), as well as for the disposal of aluminum packaging to street gypsies. Not ignoring the good intention of the respondents and the existing individual attempts to solution there is no doubt that the lack of an organized collection system for paper and ink cartridges in Sparta should be rapidly addressed. Questionnaire to the Shopkeepers The study was conducted from 22 to 28/02/2008 and involved the interviewing of shopkeepers (mass catering and leisure) in Sparta and in the settlements of: Skala, Vlahiotis, Gythio, Krokees, Xirokampi, Goritsa, Geraki, Mystras, Parori and Agios Ioannis. The NCSR researchers studied the participation of the relevant shopkeepers in a system of collection and recycling of plastic, aluminum and other packaging. The first finding is that the aforementioned Laconia municipalities lack even an elementary system of collection of recyclable waste. More specifically: In the Municipality of Sparta, no business participates in a system of collection of recyclable wastes. A small number of shops collect paper for recycling and used cooking oils. Most of these shops were coffee places. The consumption of soft drinks, bottled water and relevant products substantially increases during the summer months, while tetra-pack packaging is more often used compared to other regions. In Skala there is no collection system; a relevant attempt was never made. However, the Municipality attempts to inform the local population about the collection of used cooking oil. Nevertheless, very few shopkeepers participate in this initiative, while others seem to completely ignore it. Considering the operation of a system for recyclable products, respondents prioritize the installation of collection points near their shops over the regular and orderly collection by the recycling agencies. Finally, Final Report (Technical issue) – LIFE05 ENV/GR/00024 270/313 Environmental Friendly Technologies for Rural Development in Skala too, there is an increase (slight) of consumption and tetra-pack packages during the summer months. The picture is similar in Gythio, though there are cases of shopkeepers who properly dispose of paper and used cooking oils. Respondents here emphasize the existence of an organized system of recycling over the distance factor. The average consumption per shop is larger than that of Skala, however there is no significant increase during the summer months. In the smaller municipalities the picture is similar and the only differentiation is that the consumption patterns are much smaller. More specifically: In Elos there is no collection / recycling system and respondents emphasize the need for organized collection and sanitation. In Krokees, there is no collection system; a relevant attempt was never made. Consumption increase during the summer months however it remains smaller compared to Gythio and Skala. With reference to the setting up of a recycling system, respondents emphasized the significance of the location of the collection point issue. A recycling attempt was never made in Mystras. In view of the establishment of such a system respondents are divided between those who stress the significance of the proximity of the collection points and those who emphasize the issues of sanitation and organized collection. In the municipality of Farida the picture is the same with small consumption patterns and emphasis placed by respondents on the organized collection dimension of any future recycling system. In the Municipality of Therapnes, despite the lack of an organized system a small percentage of shopkeepers collect aluminum packaging. Here too, consumption increases during the summer months and the organized and orderly collection of recyclable products is considered to be the most important factor of success for any future organized recycling activity. The Municipality of Geronthron presents exactly the same picture with the Municipality of Therapnes. It should be stressed here that, independently of the location and the size of the respective municipality, shopkeepers declare their will to participate in any future organized recycling action, however they often present as an insurmountable obstacle the existing workload and the problem of assigning new (recycling) responsibilities to old personnel. On the basis of the analysis of the findings there is no significant variation (attitude, practice) with regard to demographic characteristics such as gender, age and education level. 2 Report on socio-economic impacts (Integral Planning for Sustainable Development) This study is about the demographic, economic and social characteristics of the Prefecture of Lakonia (PL), focusing on the Evrotas Riverside Area (ERA). An analysis of Final Report (Technical issue) – LIFE05 ENV/GR/00024 271/313 Environmental Friendly Technologies for Rural Development the local development perspectives is presented, together with the investigation of the development guidelines that appear to be of crucial importance for planning the development in the area concerned. In brief, the findings of the study are summarized in the following sections. Socio-economic characteristics and local conditions Demographic data The demographic changes of the population in the PL do not reflect the economic and social evolution. The population increase in the capital Municipality of Sparta is attributed to the residential mobility of the residents of the rural areas. However, this movement does not mean that former rural residents stop to undertake economic activities and to participate in the social life of their villages of origin. For example, a remarkable population decrease is observed in the Municipality of Skala, despite the considerable tourist development and the increase of the number of local agricultural units (greenhouses). On the other hand, the birth rate of the PL is below the death rate in recent years, bringing unsetting indices about future demographic perspectives and the social potential. In 2002 the number of the Elementary Schools presented a decrease of 15% compared with that of 1994. On the contrary, in 2002 there were 21 Secondary Schools and 22 High Schools, compared with 18 and 15 respectively in 1994. In any case the student population retains a crucial size, thus constituting an important target group for the dissemination of the Project objectives and results, through adequate Environmental Education (EE) courses, already established in the schools of the country. Concerning the health sector recent changes seem to be positive, as the number of bed in hospitals and medical centers increased by 21% and the number of doctors per 1,000 thousands by 56%. Further improvement in social infrastructure will contribute to the management of current problems and to the exploitation of development opportunities. Economic and social data The dominant sector of employment in the area is that of the primary (and especially agricultural) activities. Employment in manufacture is rather weak, limited at only 4.5% of resident population. This percentage is lower than that of people employed in Public Administration (even excluding public education and health agencies). The local employment structure is a useful guide for any approach of the social profile and indicates local problems and perspectives. Agricultural production in Greece faces several problems and the restructuring of the economy is under permanent discussion, calling for the implementation of informed policies. At the local scale, any initiative should exploit the local comparative advantages, especially concerning secure and certified quality agricultural products. Data analysis in the ERA shows that the biggest part of the population work in agriculture: the percentage varies between 62% and 66% in the Municipalities of Skala, Therapnai, Elos and Krokees, while important percentages also emerge in the rest. In the Final Report (Technical issue) – LIFE05 ENV/GR/00024 272/313 Environmental Friendly Technologies for Rural Development capital Municipality of Sparta the percentage is significantly lower (18.5%), as there is considerable concentration in the public administration, education and health sectors. The secondary sector is generally low. Constructions sector prevails, especially concentrating in the Municipalities of Sparta and Mystras. Other manufacture activities concern almost exclusively food industries, concentrating in the same area. Sustainable agricultural development is of large importance in order to maintain the local population. Moreover, many researchers argue that agricultural production is not sufficient, proposing solutions that focus on multiple and complementary activities. Although current data show that the possibilities for multiple employments are found mainly in the tertiary sector (in services as well as in commerce), the small share of manufacture and the potential for vertical organization in some industries mean that the secondary sector should be considered too. In general, the ERA presents common problems with other similar agricultural areas in Greece but with specific perspectives. Regarding occupational structure the largest single category is that of specialized arm workers. Despite any reservations about the reliability of statistical data, this is a positive indication, in terms of a local productive system that incorporates local skills, experience, knowledge and flexibility. Once the percentage of those employed in professional job positions is added, the general picture becomes even more promising. On the other hand specific local conditions seem to endanger the possibility that most productive socioprofessional groups remain in the area and specific measures should be taken. The total surface of cultivated land is being reduced, while at the same time agricultural production is still dominated by citrus trees. The decrease in agricultural production is directly connected with the Project oblectives. The transformation of Common Agricultural Policy (CAP) calls for secure quality agricultural products. Rational water use in the ERA is meant to provide an environment where new initiatives for agricultural development could occur, through dissemination of information and technology. Moreover, secure quality products result to reduced and more rational use of chemical additives, a prerequisite for the increase of agricultural income as well as the effective waste management in Evrotas. Environmental management and natural resourses exploitation - Antifouling projects In summer 2007, among other areas of Greece, the PL suffered the consequences of extensive fire disasters. These consequences concern not only economic conditions but also the social cohesion of the area, thus calling for specific measures in order to restore development perspectives. The estimated areas confronting erosion danger (of high, medium or small degree) have a total surface of 232.677 km2. Proposed measures against erosion and soil degrading include a) measures for the improvement of the flora (in agricultural land, breeding grounds and forestland), b) constructions against erosion and c) erosion control measures. The total budget of the proposed measures rises at €9,503,455. Water resourses protection Final Report (Technical issue) – LIFE05 ENV/GR/00024 273/313 Environmental Friendly Technologies for Rural Development The fire-stricken areas have may cause water quality problems in the Evrotas basin. Negative effects include: Diminution of breeding use water Land sliding in agricultural areas Land sliding in pasturelands and stockbreeding units Water shortage in mountainous areas Water shortage in irrigation systems Major land gliding Proposed measures include aiming at the confrontation of these anticipated effects include: Bargaining of water tanks with capacity of 1.000 m³ for 6 months for stockbreeding use. Rehabilitation of 30 water drills in mountainous areas Construction of 10 small water dams with capacity of at least 1,500 m³ Protection of streams and slopes Drainage works Water transportation and storage for six months Construction of 8 new water drills of average depth 200 m in areas where the altitude is lower than 200 m Works against gliding in six places The total estimated cost rises at €6,165,000. Fire Consequences Management and Forest Protection The most affected Municipalities are those of Therapnai (Municpial Districts of Ag. Anargyroi, Chrysafai and Goritsa), Krokees (MDs of Krokees and Dafni), Oitylon (MD of Aeropoli) and Geronthrai (MD of Kallithea). The total surface of the fire-stricken MDs is 1,425.7 km2, about 39.2% of the total area of the PL. Their population represents 54% of the PL population. They include an important percentage of farmers (31%), a relatively big percentage of routine occupations (13.8%), while about 30% is equally shared by specialized technicians, those employed in services and clerks. Their cultivated agricultural land (CAL) rises at 585.6 km2, 43.5% of the total CAL of the PL. 1,847 applications for reparation have been submitted to the Greek Organization for Agricultural Insurance, concerning 17.64 km2, i.e. 1.3% of the CAL. The real disaster may be even greater than described, because fired-stricken breeding grounds were not declared. Olive trees units seem to have suffered more, as they represent 98.4% of the fire-stricken agricultural land. The loss was 0.6% in the sheep and goats segment and 5.6% in the cattle sector, mainly in the Municipality of Anatoliki Mani (MD of Kokkalas) Final Report (Technical issue) – LIFE05 ENV/GR/00024 274/313 Environmental Friendly Technologies for Rural Development and the Municipality of Oitylon (MD of Aeropoli). The loss in forestland was 170 km 2, representing 9.7% of the forestland of the PL. Immediate activities in the forestland of the PL include: Antifouling projects together (corm and bough webs) following woodcutting works Temporary flood-preventing projects (wooden dams) Permanent flood-preventing projects (cement and stone dams) Further intervention is also needed concerning: Maintenance of the forest road network Maintenance and construction of fire-preventing zones Reforestation works Breeding grounds restoration and improvement The total cost of these projects rises at €23.200.000. Development Perspectives in the Prefecture of Lakonia The hierarchical context for the development perspectives of the area was elaborated through the analysis of the existing demographic, economic and social conditions, also exploiting information obtained in contacts and meetings with representatives of local agencies and by the surveys on the opinions of a) residents and professionals and b) local representatives in the municipal councils. The contribution of personal contacts with residents and stakeholders during the dissemination process was of great importance. Existing natural and human resources as well as the intentions and objectives of local agencies were investigated. The integration of economic development objectives with environmental protection and maintenance goals was attempted on this basis. Thus the following framework of investment proposals was concluded. Primary Sector Agricultural production in the PL is concentrated in specific products (olives, olive oil, oranges) that are characterized by increased demand and an organized distribution system. However, future development is connected with the production of organic products. In the context of the Single European Market there is strong competition regarding the traditional agricultural products. Moreover, the Common Agricultural Policy (CAP) is already directed to the elimination of subsidies concerning these products. Consequently, a general reorientation of the productive priorities is needed. Organic Products According to the record of cultivators of organic products as kept by one relevant certification agency (DEO), the PL counts 310 cultivators. Registries started in 1992 and, although the annual variation was important, the general trend was one of increase. The Final Report (Technical issue) – LIFE05 ENV/GR/00024 275/313 Environmental Friendly Technologies for Rural Development biggest increase was observed during last years. There were 62 new entries in one single year (2006), while more than 50% of the cultivators entered the market after 2004. Same trends are recorded at the national level, reflecting international shifts. The demand for organic products is increasing, as a bigger proportion of the consumers is involved, although reservation concerning the increase prices still exist. The traditional products of Lakonia (olives, olive oil, oranges) already belong to the group of the most demanded organic products, while being exported to other countries. Advanced package, standardization and marketing activities are needed. Protected Destination of Origin (Pdo) Products The Protected Destination of Origin as well as the Protection of Geographical Indication (PGI) were institutionalised by the European Union in the Regulation 2081/92. The Regulation 2082/92 established the certification of traditional specialty guaranteed agricultural products. These two Regulations were replaced by Regulations 510/06 and 509/06 respectively, without altering the scope of implementation. According to this legal framework and in the CAP context cultivators have the possibility to exploit opportunities for integrated rural development, through the differentiation of agricultural production. Cultivators (especially those in remote areas) are able to place specialized products in the market, thus achieving better prices. Consumers on the other hand can purchase quality products of guaranteed geographic origin. In more detail, the basic categories of certified agricultural products are: d) Destination of Origin ―Destination of Origin‖ is the name of a territory, a specific place or in some cases of a country used for the description of an agricultural product or foodstuff originating from this territory, when the quality or the characteristics of this product are exclusively or mainly attributed to the geographic environment, including natural and human conditions, of the territory. The production, manufacture and processing of the product have to take place in the same area. e) Geographical Indication ―Geographical Indication‖ is the name of a territory, a specific place or in some cases of a country used for the description of an agricultural product or foodstuff originating from this territory, when the quality, the reputation or a specific characteristic of this product may attributed to this geographic origin. The production and/or the manufacture and/or the processing of the product have to take place in the same area. f) Traditional Specialty Guaranteed Agricultural Product A ―Traditional Specialty Guaranteed Agricultural Product‖ is an agricultural product or foodstuff with intrinsic characteristics that differentiate it from other similar products and which has been present in the common market for a period that proves intergenerational transmission. Intrinsic characteristics may concern physical, chemical, biological or organoleptic features or the production methods and conditions. The traditional character may concern the raw materials, the ingredients, the method of production or Final Report (Technical issue) – LIFE05 ENV/GR/00024 276/313 Environmental Friendly Technologies for Rural Development manufacture. The name has also to be peculiar or to express the peculiar character of the product. Since 1.6.2006 the Organization for Certification and Surveillance of Agricultural Products, under the distinctive title AGROCERT is responsible for the approval of relevant applications by enterprises concerned, the monitoring of production processes in collaboration with the Agricultural Directorates of the Prefectures, the observance of the prescriptions, the certification of products and the record of PDO and PGI holders. Other Development Possibilities in Primary Sector Non-stabling stockbreeding. There is a possibility to establish larger units (stockbreeding parks) of integral and organic character. During the Project process a specific study on the potential establishment of stockbreeding parks in Lakonia was elaborated, using the existing stockbreeding park in Grevena (Prefecture of Pella, Northern Greece) as an example. Other investment opportunities include the exploitation of wind energy and the energy production capacity of oil-factory waste. The possibility to exploit the existing lead deposit in the Municipality of Molaoi has to be investigated. Lead and silver mines operated in the area in the past (even during the ‗90s) but today their efficiency is contested. Secondary Sector Branches with development capacities: Olive processing, focusing on edible olives standardization, seed-oil exploitation for electricity production and other contiguous activities such as environmental protection (biological cleaning) and quality certification. Possibilities for the establishment of wind energy parks in Mt. Parnon Tertiary Sector Branches with development capacities: As the PL lacks hotel units, especially those of high standards, there still is enough space for further tourist development. Concerning high quality tourist services as well as ecotourist activities on Mt. Parnon and Taygetos. Existing tourist facilities in the ERA include: Four hostels in the Municipality of Faris: One in Toriza (MD of Xerokampi) with a restaurant, tavern and café; one in Paleopanagia (MD of Paleopnagia) in a 200,000 m2 plot with walnut and chestnut trees, near the Byzantine monastery of Gola; one in Rahivi (MD of Vassiliki); and one in the MD of Arna. Seven on the Mt. Taygetos: one municipal hostel in Georgitsi, the oldest in the area; one in Kastori, near a medieval castle characterized as archaeological site; one in Karyes; one in Polydroso (Tzitzina); two in Anavryti, one of which remains closed as an investor is requested‘ and one in Mystras - a traditional mansion that is going to be uses as a Vernacular Art Museum. Final Report (Technical issue) – LIFE05 ENV/GR/00024 277/313 Environmental Friendly Technologies for Rural Development Additionally there are several mountain shelters in Parnon and Taygetos that are used for the excursions organized by the Greek Mountaineering Club. Ecotourist activities and mountaineering offer the opportunity to extend the tourist season beyond summer months and to increase tourist services demand in remote areas of the PL. 3. Evaluation of the Life/EnviFriendly project in the development perspective LIFE\Envifriendly objectives According to the initial planning and schedule of the Project, its objectives included: 1. To select, plan and implement environmentally friendly technologies in order to reduce pollution caused in the ERA by agricultural activities, industrial and urban waste. 2. To develop and demonstrate tools of technological restoration of water quality and to propose methods to incorporate these tools in the Evrotas basin and coastline Master Plans. 3. To provide the context for the integration of these technologies and tools in the socio-economic activities of the area and to promote the social acceptance of the proposed measures. 4. The sensitisation of the local population against sustainable development and environmental protection through dissemination of adequate information. Evaluation of the Achievements 5. During the materialization of the Project the specific conditions of the area were investigated, the main sources of pollution were detected and alternative solutions for cleaning were planned and proposed. In collaboration with agencies responsible for water resources management a comprehensive plan for pollution and the problems caused by natural factors (floods, water shortage etc.) was elaborated. The comprehensive model was presented in several information meetings and scientific conferences. The acceptance of the proposals by the specialists of local agencies and by wider parts of the local population was encouraging and thus provided the ground for the next step, that is for the elaboration of the integrated plan for water resources management in the ERA. 6. The adoption and demonstration of technical solutions based on environmental friendly technologies has been presented in detail, focusing on the advantages and disadvantages of each alternative proposal and method. Certain manufacture units in the area have implemented antilitter technologies, exhibiting satisfactory results. They also participated in demonstration events. The overall process of the final management plans included repeated contacts and meetings with representatives of local agencies (especially the Local Organizations for Land Improvement). This constant process of public consultation was remarkably fruitful, giving the floor to express local views of all actors involved and to Final Report (Technical issue) – LIFE05 ENV/GR/00024 278/313 Environmental Friendly Technologies for Rural Development incorporate local specificities. This was crucial in order to widen social acceptance and consensus, as the local agencies participate in the formation of local views. On the other hand, the problem of personal responsibility remains, due to insufficient information and the social cost of effectively taking proactive and suppressive measures at the individual level. In any case the Project methods and practices provided all local participants with new ideas and stronger arguments. 7. The establishment of adequate conditions for the incorporation of the Project interventions in the overall local socio-economic process has been attempted through: The conduction of two repeated surveys in the resident population and professionals of the ERA and in the focus group of the representatives in Municipal Councils. Ad hoc studies about specific local problems and conditions including the consequences of natural phenomena (fire disasters, floods, water shortage), suggested measures (stockbreeding parks) and other intervention for environmental improvement (recycling). Regular meetings with representatives of the participant Municipalities and with other agents about specific issues. The organization of public informative and scientific events and the participation n events organized by other local agents. More generally through the establishment of permanent public dialogue process. The surveys‘ results, the findings of the studies and the relevant feedback obtained by local agent‘s exhibit the achievement of the above goals. More precisely, the overall picture shows that the local society has adopted the proposed interventions, agrees with the hierarchical classification of priorities and thinks that the Project demonstrates future directions and the preconditions for the successful materialization of other development projects. Furthermore, these projects should embrace the Projects‘ objectives, which are considered important for the development perspective of the area. 8. The sensitization of the local population against sustainable development and environmental production has been incorporated in the Project through several activities. More precisely: The production of printed and digital informative material either presenting the immediate objectives and methods or other contiguous subjects of environmental management. The material was regularly distributed. The distribution of material from the above mentioned studies and relevant presentations in several occasions. The collaboration with the local EE agencies, together with the exploitation of the long-standing involvement of the NCSR in the central planning of EE at the national level. Several local events and conferences were organized. Final Report (Technical issue) – LIFE05 ENV/GR/00024 279/313 Environmental Friendly Technologies for Rural Development The evaluation of the results in these fields is very positive, especially in the field of EE. That is because EE has already established adequate structures of information and because activities in schools of every level have multiple effects in the, as the sensitization of students disseminates in other groups of the local society. Concerning the local population as a total, evaluation of the results is also positive, although certain gaps of information have been recorded. The absence of relevant policies and information in the past has been important at this point. However the Project as well as other interventions have made a contribution towards this direction. Nonetheless, a more comprehensive national strategy seems to be of relevance, in order to integrate the objectives of single projects. Demonstrative and Transferable ‗GOOD PRACTICES‘ of LIFE/ENVIFRIENDLY Project The implementation process of the Project indicated the need to adopt interventions and practices that could be used as experimental ‗good practices‘, also suitable to contribute to development objectives in other areas, Prefectures and Regions of the country. The main issues around which these interventions and practices were undertaken are as follows: The Water Resources Management Plans, aiming at the adaptation of the existing legal framework and of actual management practices in the field to EU Directive. The implementation of the Directive is obligatory for all member-states and a precondition for rational water use. The Integrated Water Resources Management Plan was elaborated and completed after taking into account the analysis of local conditions. Accordingly, more than being a tool for local development in the ERA, it can be used as a model application in order to support similar plans in other water basins. Thus, it can be used as a Development Guide, after adequate revisions and adaptations to specific local conditions. The public consultation process was implemented in the ERA according to local social specificities. Similar specificities emerge at the most agricultural areas of Greece. The acceptance and the effectiveness of the public consultation process were found to depend on the ability to exploit local social networks. Thus, instead of a simple guidance by the Project team that would merely follow the guidelines of the central Dissemination Plan, more decentralized methods were adopted, in order both to exhibit local conditions and to correspond to the local potential at the micro-scale. Based on this ground, the informal meetings with representatives of a wide range of local institutions and agencies and the dissemination of the Projects achievements and progress in local social life spaces and events (the coffee bars, celebrations and annual festivals) proved to be of major importance for the mobilization and the participation of parts of the local society. The Observatory for Local Development will act as a field for the coordination of the Local Organizations for Land Improvement, where the synthesis of the above mentioned ‗inputs‘ (the Water Resources Management Plans and the consultation process) will be materialized. Moreover, the operation of the Observatory in the auspices of the Prefecture of Lakonia facilitates the cooperation with the Land Improvement Agency (LIA) Final Report (Technical issue) – LIFE05 ENV/GR/00024 280/313 Environmental Friendly Technologies for Rural Development and consequently the common planning of the Water Resources Management Plan. The LIA is in permanent contact with the Municipalities of the ERA and the respective Local Irrigation Boards (TOEBs), having encharged the latter with the management of water resources at the local level. However the LIA also retains the capacity for central intervention when water resources management fails and management problems occur. Periodic and ad hoc meetings (on specific managerial problems) under the responsibility of the Observatory are proposed. This scheme guarantees the connection between the implementation of the management system and the broader development in the ERA. At the same time it gives the opportunity for sustainable public participation, since the Observatory will have become the basic dissemination mechanism in the local society. In brief, the Observatory will be responsible for the practical organization of the continuous public consultation process, thus providing the ground for the expression of the views of different social groups and their integration into an overall development strategy. These ‗Good Practices‘ can be used as paradigmatic cases for development plans and the respective necessary procedures in other areas. Future Planning on the Basis of Project Objectives One of the aims of the project has been to extend its objectives beyond the period of materialization. Accordingly, certain preconditions for future exploitation of its results should be constructed. It is expected to be an information center for local agencies and residents and a node for the coordination of investments, contributing to the investigation and planning of development activities. Up to now the overall operation of the Observatory is positive, despite functional problems and delays that occurred. However, the Observatory was staffed with permanent employees, as this would reassure its sustainability after the end of the Project. The Prefecture of Lakonia and other involved agencies should maintain its activities. Another development perspective of the Project has been that of organic agricultural products, in the context of Codes of Equitable Agricultural Practice. Present conditions seem to be promising, if one judges from the experience of existing organic agricultural units and their efficacy. International and national trends provide an environment where profitable exports of quality products can be achieved. Organic agricultural production can be combined with eco- and agrotourist activities, thus providing one of the most directions for sustainable development. The developmental role of antilitter technologies should be stressed too. Antilitter activities in the industries of the area would contribute significantly to the amelioration of local environmental conditions. Furthermore they can be exploited as an added value in the promotion of local products and contribute to the increase and amelioration of tourist activities. Finally, such investments attract high national and supranational subsidies, while the socalled ‗green products‘ are expected to dominate in the near future, thus linking the sustainability of localities with the establishment of green economic units. Final Report (Technical issue) – LIFE05 ENV/GR/00024 281/313 Environmental Friendly Technologies for Rural Development TASK 6 - Development of integrated watershed management plans The fundamental challenge in the development and management of environmental policies is the sustainability of the objectives of these policies. The objectives for sustainable development require decisions that satisfy the needs for this generation and they provide a chance to future generation to satisfy their needs as well. The strategic objective is the integrated management of water resources of Evrotas River Basin that will contribute to the – improvement of the environment, – social cohesion, – value added to the local economy, and – improvement of the quality of life. The objective is to create the conditions for sustainable rural development while the chemical and ecological quality of surface and ground waters is improved according to the Water Framework Directive 2000/60/EC. Evrotas can be the comparative advantage that would lead the Prefecture of Lakonia to the 21st Century. The Strategic Plan was developed around the following six axes: 1. Agricultural development 2. Drinking water 3. Irrigation 4. Reduction of point and non-point source pollution 5. Unified response to floods and drought 6. Protection of biodiversity and restoration of river ecosystems. 1. Agricultural Development The fundamental problems of agricultural production in Greece today should be fully understood before conditions for sustainable rural development can be established. Industrialized agriculture includes intensive grown mono-cultures, inorganic synthetic fertilizers, intensive use of herbicides and insecticides (that affect adversely the soil fungi and bacteria that catalyze the fertility of the soil), tilling (including deep tilling that destroys the soil structure, making it fine and subject to erosion) and irrigation (reduces the reserves of water resources). Agricultural production in Greece depends among other things on the price of fertilizers, the seed market, the international financial speculation on agricultural products and problems of social consensus. Fertilizer prices have increased dramatically that past two years. This price hike was not due to increases in oil prices, but due to increases in the price of phosphorous ore (from 50 to 350 dollars in 16 months). The price hike has been attributed to decreasing reserves (PEAK Phosphorous), in a similar way as with oil reserves (PEAK OIL). It is speculated that phosphorous reserves will decrease dramatically between 2025 and 2040. The problem is that we consume 22,5 kg of Final Report (Technical issue) – LIFE05 ENV/GR/00024 282/313 Environmental Friendly Technologies for Rural Development P-rock/person/yr while the daily recommended dose is 1,2 g/person/d or 0,438 kg P-rock/yr. We use 50 times more P than we need. The wasted P ends up in the wastewater treatment plants, the lakes and rivers and causes eutrophication. The price of the fertilizers will continue to increase because of the decreasing quantities of P-rock production causing increasing demand. How are we going to handle the situation when the reserves are depleted? The situation leads to a deadlock unless alternative means of fertilizing the land is found. The farmers also depend on the seed market (hybrid or genetically modified) created by the international food industries. Using biotechnology, the food industries have developed patented hybrid seeds. There is the notion among farmers that only hybrid seeds can bring good production the time that many ecologists recommend local varieties as the most appropriate since they could withstand local conditions in time. The international financial speculation on agricultural products (cereal, rice etc) creates uncertainty in the food prices causing a series of world-wide problems. In a similar fashion, farmer‘s speculation (i.e. production of corn for biodiesel and not for animal feed) provides temporal improvement in income without solving permanent agricultural problems. The international markets should have limits as the current financial crisis taught us. A few things in life should be outside the limits of international speculation and gambling. Finally, there are significant problem with social consensus that impedes the creation of successful farmers association that would develop market strategies for their products and eliminating the price gap between the field and the super market. There alternative ways to rural development. First we need to understand that agriculture, tourism, local culture and the environment are communicating vessels. The connecting link of these communicating vessels is the soil. Greece has forgotten to take care of its soils as it has behaved before since the ancient times. Plato in ―Kritias‖ described the Attica land as ―bones without flesh‖. The combination of erosion and bad land practices creates a defincit in carbon and other micro-nutrients necessary for soil fertility and health. Soil measurements in Greece show carbon content well below 2% and in many times below 1% (pre-desertification stage). In addition, we have observed significant deficiency in micro-nutrients like selenium that many connect such deficiency to wide-spread diseases such as the ―bird flu‖ in China and AIDS in Africa. The bottom line is that the Greek soils are eroded, have lost their fertility and this has consequences in the quality of the produce and our health. We should regenerate soil fertility by returning carbon, nutrients and micro-nutrients. There are examples all around the world showing that we can have agricultural development, sufficient food production to cover the global needs and at the same time to maintain ecological quality. An example from Amazon – The native Indian 2500 till 500 B.C. realized that once they cut the trees in the forest, the soil became infertile in 2-3 years. They had to find ways to regenerate soil fertility. They developed the soils named Terra Preta de Indio (Amazonian Dark Earths or Indian Black Earth). The soil was enhanced with Biochar (char made up of plant material, food waste such as bones Final Report (Technical issue) – LIFE05 ENV/GR/00024 283/313 Environmental Friendly Technologies for Rural Development from fish that has plenty of calcium). This material was composted before it was incorporated in the soil. This soil is fertile today. Collaboration between agriculture and livestock raising – An example of such a collaboration is Polyface farm in the State of Virginia, U.S.A. The farm is raising 5 types of animals (cows, chicken, pigs, turkeys and rabbits) eating grass without any animal feed. The owners make sure that there is plenty of available grass in the farm by creating new soil as follows. First the put cows in an area fenced by electric fences for several days. The cows eat the grass while they leave plenty of manure. The owners move the cows to another location, let the worms grow for 4 days and then they move the chickens in. The chickens eat the worms that are rich in proteins and they leave manure rich in ammonia. The soil is regenerated, grows new grass and the ecosystem is balanced. The result is that using the ecological services of the different animals, the owners earn $700.000/year (10 people) while they maintain the ecological integrity of the ecosystem. Combination agricultural practices – Monoculture is a recent agricultural practice. Farmer in Greece used to practice good agricultural practices by alternating what they grow in the field choosing between the set aside practice and growing legumes or alfa-alfa in an olive grove. Such combination agricultural practices replenish the soil with nutrient (without the use of fertilizers) while keeping down the production cost. Management of solid waste – Todate, landfilling has been the most wide spread practice of solid waste management in Greece. In a few areas recycling has been initiated as well. Since the current capacity of landfills is close to completion and new landfills are difficult to site due to local opposition, government officials have started looking into other options such as combustion and recycling and composting. Given the state of fertility the Greek soils are, the only logical and sustainable solution is separation at the source, recycling, composting the organic fraction and landfilling the remaining wastes. In the creation of the compost material other organic byproducts can be used such as the biosolids and sludges from the waste water treatment plants and braches from pumming of the plants. The compost can then be used to improve the quality and fertility of the soils and allow the farmers to be independent from the energy crisis. Such a system already is in operation at the Prefecture of Chanaia and is the only logical and sustainable alternative in solving the problem. Collaboration between tourism and agriculture – It is very important to understand that ―quality‖ tourism is related to local culture and agricultural activities. Local touristic establishments should support the local produce because they are part of the uniqueness of the region. For instance, all the hotels and restaurants of Lakonia should offer freshly squized orange juice in low prices to promote one of the main agricultural product of the region. The same could be followed for the other products. If every tourist was given a small bottle of olive oil upon arrival to the region, use the same olive oil in every restaurant he/she would go, this would become part of the trip experience and a value added for the Final Report (Technical issue) – LIFE05 ENV/GR/00024 284/313 Environmental Friendly Technologies for Rural Development products of the region. It would be the reason to return to the area in the future creating in this way the conditions for sustainable development. 2. Drinking Water Supply Drinking water supply for the towns and villages in Evrotas river basin is vulnerable to accidents in the pumps, water lines and natural disasters. Every village and town has its own water infrastructure and in case of system failure there is interruption in the service. In addition, the municipalities cannot afford to hire personnel to ensure the quality of the water and the service provided due to their small size (with the exception of the municipality of Sparta. To overcome these problems and establish quality in the water supply system the following are proposed: Every village should have alternative sources of water that can be activated in case of accidents and other system failures. In its simplest case, this can be drilling an additional well and instrumenting it as a back up. Develop an interconnected drinking water infrastructure that connects towns, villages and small settlements that can be used to optimize water use and improve the management of water resources of the region. Creation of public water companies that would serve many municipalities that can be staffed with scientist personnel and ensure the quality of the service. Pricing the water use at the appropriate level in order for the water company to be financially independent and be able to provide the quality of the service that is appropriate of the 21st century. 3. Irrigation There are approximately 150 public wells and 7,000 private wells in operation in the Prefecture of Lakonia (Table 5.7.1). Approximately 3,550 private wells are located within the basin and unknown is the number of the illigal private wells. Irrigation water annual demand was estimated at 174 Mm3 based on typical plant water needs. Hydrologic modeling suggested that the farmers are using 3 times more water. The overexploitation of water resources threatens important natural habitats and affects negatively the aquatic flora and fauna. Table 5.7.1: Private irrigation wells in Evrotas basin Mn. Inountos 65 Mn.Therapnes 250 Mn. Geronthres 200 Mn. Skala 550 Mn. Elos 1100 Mn. Spartas 300 Mn. Mystras 350 Mn. Faridos 120 Final Report (Technical issue) – LIFE05 ENV/GR/00024 285/313 Environmental Friendly Technologies for Rural Development Mn. Pelanas 10 Mn. Niata 350 Mn. Krokees 250 The proposed program of measures for irrigation is the following: 5. Change irrigation methods - It is very difficult under current conditions to estimate the real consumption of water. In many private wells, there are not any records concerning well yield, well depth and any operational parameters. Estimation of the real irrigation needs is necessary to persuade the farmers that it is unnecessary to overexploit the water resources and switch to iirigation systems such as drip irrigation that consumes less water. 6. Appropriate pricing of water use – Agricultural water use is based on areal extent of the farm rather than the actual quantity of water used. This should be changed and progressive pricing of water use should be established. 7. Water re-use (municipal and industrial treated wastewater) - Water from the domestic wastewater treatment plant and the agro-industrial facilities isn‘t reused. Water re-use especially during the dry months for irrigation could help in the vital problem of water scarcity. Practical example for water re-use is the practices of ―Tzinakos olive mill‖ where the wastewater is stored in evaporation ponds and is used during the summer for the irrigation of a corn field. 8. Ecological flow of the river – There water abstraction from the main stem of Evrotas river at several location. In certain periods of the year, the water is abstracted completely, leaving the river downstream dry. Maintaining an ecological flow through out the year is essential for the survival of the fish and other aquatic life. The Prefecture of Lakonia has already initiated the planning of the enforcement of the above measures. Several public irrigation projects operate in the basin with the help of the local land reclamation office. Several of them have drip irrigation systems while others (Trinasou, Zacharias and Magoulas) operate with open channels. It is planned that these open channel irrigation systems will be converted to drip irrigation in the next few years. In addition, the prefecture is planning to reverse the seawater intrusion problem of the Glikovrisi and Molaon-Asopou aquifer with water diverted from Skalas springs and construct a dam in Kelefina. 4. Pollution Control Α. Pollution reduction of non-point sources Non-point source pollution is derived mostly by agricultural and livestock activities. Almost 38% of river basin area is covered by agriculture land (olive and orange trees, vineyards) and it is estimated that 21933 tones of Nitrogen and 9428 tones of Phosphorous are the annual loads in the basin. The livestock according to mucipalities records are approximately 130540 sheeps and goats, 58070 kitchen, 1729 cows and 100 Final Report (Technical issue) – LIFE05 ENV/GR/00024 286/313 Environmental Friendly Technologies for Rural Development pigs. The program of measures recommended for the reduction of non-point source pollution is the following. 11. Use of Fertiliser recommended rates - Fertilizers can be used in quantities that are necessary for plant nutrition and development. Overuse of fertilizers increases the cost of farming and creates environmental pollution. It is important that the state creates an agricultural service that would recommend appropriate fertilizer application rates based on the needs of the plant and the condition of the soil. 12. Organised livestock farms - It is proposed the creation of organized livestock farms in pre-selected areas and the adoption for their operation of the environmental standards. These farms have the advantage of offering better protection to natural resources (water / soil), and contaminants and dioxins aren‘t transferred to food chain and their solid wastes and wastewater can be reused after treatment. 13. Rotation plant crops – Crop rotation is very important to maintain the structure and integrity of the soil as well as enhance it with nitrogen improving in this way its productivity. 14. Biological farming - The main difference in biofarming comparing to traditional is that the agricultural practices don‘t include chemical fertilizers, pesticides, chemical pesticides or synthetic hormones of all kinds. 15. Erosion control – Erosion control measure such as no-till, crop rotation etc are recommended for adaption. 16. Integrated farming systems - Integrated Farming (IF) offers a whole farm policy and whole systems approach to farm management. It seeks to provide efficient and profitable production which is economically viable and environmentally responsible and delivers safe, wholesome and high quality food through the efficient management of livestock, forage, fresh produce and arable crops whilst conserving and enhancing the environment. It goes beyond simple compliance with current farming regulations, reinforces the positive impact of farming practices on the environment and reduces their negative effects, without losing sight of the profitability for the farm. It is geared towards the optimal and sustainable use of all farm resources such as farm, livestock, soil, water, air, machinery, landscape and wildlife. This is achieved through the integration of natural regulatory processes, on-farm alternatives and management skills, to make the maximum replacement of off-farm inputs, maintain species and landscape diversity, minimise losses and pollution, provide a safe and wholesome food supply and sustain income (EISA, 2006). 17. Retain and create terraces - Terracing reduces the length of slope on a hill side, which can help to reduce erosion and prevent gully formation. 18. Riparian zone restoration and phytoremediation – Riparian strips and buffers promote bank stability, prevent bank erosion and act as a filter for agricultural pollution. Final Report (Technical issue) – LIFE05 ENV/GR/00024 287/313 Environmental Friendly Technologies for Rural Development 19. Monitored natural attenuation technology – As it is shown in this project, MNA should be the starting point before any other measures are established. 20. Drainage canals management - The reeds (Phragmites australis) and in general the vegetation growing in drainage ditches if managed appropriately can reduce pollution from agricultural fields. B. Point Sources Point sources of pollution are the effluents of olive mills, the orange juice factories and domestic wastewater that are disposed untreated or partially treated into Evrotas river and its tributaries. In the framework of LIFE-EnviFriendly project five (5) alternative methods for OMWW treatment for single mills and five (5) for central units were proposed (Table 5.7.2). Two orange juice press factories are operating in the basin (Laconia and Papadimitracopoulos), where one of them «Laconia» has wastewater treatment unit and consequently a large part of the organic load and solids to be removed. In the framework of LIFE-EnviFriendly project an electrolytic unit was installed in ―Laconia press‖ regarding the improvement of treatement process. Table 5.7.2. Alternative solutions for the treatment of OMW. Single olive oil mill Central unit [1] Evaporation ponds Phytoremediation [2] Storage and irrigation during the summer Evaporation pond with odour control unit [3] Irrigation of olive trees Filtration with sawdust and resins [4] Subsurface disposal and phytoremediation without GW monitoring Anaerobic digestion [5] Subsurface disposal and phytoremediation with GW monitoring Deodorization and electrolytic process Finally there are villages such as Kastori which has no treatment plant, and dispose the raw wastewater directly into Evrotas. Also villages (i.e. Xirokampi, which has 1,500 residents) are served with septic tanks. These settlements could make use of small decentralized natural treatment systems for their wastewater. In general the point sources pose severe problems in chemistry and ecology of the river and a solution has to be found. There are alternatives and should be choosed the appropriate for each case. 5. Coordinated response to floods and droughts Significant flood and drought events have occurred historically in the Laconia. The Prefecture of Laconia has prepared a Management Plan (Master Plan) for the flood protection of the area. The plan has delineated and prioritized the flood prone areas and suggested a number of measures that take under consideration mitigation measures for droughts. 6. Biodiversity protection and restoration of river ecosystems Final Report (Technical issue) – LIFE05 ENV/GR/00024 288/313 Environmental Friendly Technologies for Rural Development Greece is characterized by high and unique biodiversity. This is particularly the case for the basin of the Evrotas which is a hot spot for endemic species. For example, the fish fauna of Evrotas includes species not found anywhere else. All these species can be considered particularly at risk because of environmental deterioration of river. The highest risk is the prolonged droughts. The fish in order to survive in difficult conditions, during the dry period, are hosted in sections of the river that flow is maintained, and can be used as shelters until the end of the drought. The sections that retain water should be protected from the intense water abstraction if we want to preserve a priceless biological heritage. The most effective way of protecting endemic species and biodiversity in general is to protect natural habitats. In this context, the protection and restoration of ecosystems of the river should be high priority and includes the following steps. Protection of riparian forests Protection of the active bed of the river Spatial measures for springs protection Restoration / Conservation flood areas Restoring connectivity to enhance fish movement - Maintain ecological flow Pressures on the coastal zone- Extension of protected area to preserve biodiversity cores- The region has a special aesthetic interest and keeps well (especially the upper part near Palaiomonastiro) a wild and natural character (high rocks, gullys, and absence of human made constructions. It is proposed, four areas (1. Kolliniotikou ravine junction, 2. Vivari springs, 3. Skoura – Lefkochoma and 4. Vrontama gorge) to be included in Natura 2000 network and to be protected in the framework of the EU Habitats Directive 92/43 of a point on the expansion of existing protected area network of Natura 2000 in Delta (Figure 5.7.1). This proposal ensures the special management of these small cores, but obviously does not exclude human activities and sustainable develpoment (agriculture, livestock, etc. on private land). Program of Measures A model for rural development has been applied in the river basin. The preliminary management plans were created according to the following six axes: 1. Agricultural Production, 2. Drinking Water Supply, 3. Irrigation, 4. Pollution Control, 5. Joint actions for flooding and drought protection, 6. Protection of the natural habitats biodiversity and restoration of the riverine ecosystem. The environmental measures were developed as follows. A database was created for each water body on pressures and impacts on the ecological status, and on the measures for the protection and restoration of water bodies. The corresponding municipalities were informed concerning the status of their water bodies and the respective measures. The main proposed measures are presented in Table 5.7.3. For each axis a detailed description of the measures have been done in order to achieve good water quality. Final Report (Technical issue) – LIFE05 ENV/GR/00024 289/313 Environmental Friendly Technologies for Rural Development Some of the proposed measures have been implemented in Evrotas basin such as for example the biological farming system. During the Envifriendly project, several technologies for the minimization of point and non-point sources were demonstrated. In Table 5.7.4 the effectiveness of each demonstrated technology is presented. Some of the proposed measures have been implemented in Evrotas basin such as for example the biological farming system. During the Envifriendly project, several technologies for the minimization of point and non-point sources were demonstrated. In particular: (1) in ―Tzinakos olive mill‖ the wastewater is stored in evaporation ponds and is used during the summer for the irrigation of a corn field and for compost production, (2) in ―Kokkolis olive mill the underground disposal of olive mill waste and phytoremediation with poplar trees, (3) in an orange juice factory, an electrocoagulation unit was installed for the improvement of the wastewater effluent, (4) the management of drainage canals as a low cost agro-environmental measure was also demonstrated. Drainage canals are areas of accumulation of organic debris due to erosion and growth of plants such as Phragmites australis. The appropriate timing of cutting reeds maximize the removal of pollutants by plant uptake, (5) river bank management by the creating a riparian forest of poplar trees, (6) monitored natural attenuation of nutrients at the basin scale. It was proved that Evrotas basin has high capacity to attenuate pollutants such as nitrate and phosphorous. 1 2 3 4 Figure 5.7.1. Areas of biodiversity cores Final Report (Technical issue) – LIFE05 ENV/GR/00024 290/313 Environmental Friendly Technologies for Rural Development Axis 1 Axis 2 Axis 3 Axis 4 Axis 5 Axis 6 Table 5.7.3. Main environmental measures proposed in Evrotas River basin. MEASURES Modify Farming System Alternative Inter-municipalities companies of drinking water supply3, choices for Wise Cost estimate3. water supply Drip Irrigation Estimation of the real irrigation needs, Switching irrigation methods, and Drainage Change Charges for water abstraction3, Water re-use (municipal and system industrial treated wastewater)3 Phytoremediation1, Drainage canals management1. Fertilizer Control Vegetation Management on river banks3 & Reduction Use of Fertiliser recommendation system2 Estimation zones Riparian zone stabilazation1, Measures for fire disaster prevantion2, vulnerable to Natural hazards procasting2, Management plans for drought and flood flooding protection2. River bed protection, Remediation /Protection of flooded areas1, Riparian forest Ecological effective discharge quantification (during dry period) 3, protection Extension of protection areas to ensure the integrity of biodiversity cores3 1 active has studied and actions are on the way 3 under discussion. 2 Residents believe that the most important function of Evrotas is to satisfy irrigation needs for agriculture. Secondarily, Evrotas is perceived to be a source of natural wealth. Its historic, ecological and cultural role is almost neglected. The over-exploitation of Evrotas River water resources and the pollution originated from agro-indurstry have created ecological implications that must be taken under consideration when designing environmental measures. The integrated water resources management is a difficult and multidisciplinary process. This study identified the dominant pressures and assessed the impacts and the chemical and ecological status of the river. Based on these studies, preliminary management plans were proposed and were specified for each municipality. The proposed measures faced fully public acceptance. The effectiveness of measures, i.e. the impact on the ecological status of Evrotas River, will be evaluated in the near future. However, preliminary results concerning the proposed measures have shown positive results. Concluding, designing an appropriate management plan for the Evrotas basin demands the participation of a wide range of scientists from additional fields (e.g. local agronomists, sociologists and economists). Moreover, the success of the management plan requires participation and acceptance of all the interested stakeholder groups. The public dialogue has been the cornerstone in the development of the existing management plans in the basin and it will continue in the future during the implementation of the research project MIRAGE (Mediterranean Intermittent River ManAGEment) that has been funded by FP7. Final Report (Technical issue) – LIFE05 ENV/GR/00024 291/313 Environmental Friendly Technologies for Rural Development Table 5.7.4. Evaluation of technologies demonstrated in the Envifriendly project. Pollution Location Effectiveness The study has shown that there is no adverse effect in the soil and groundwater from the application of diluted olive Tzinakos (Surface mill waste for the irrigation of the corn field. The corn Olive Mill Waste Irrigation of a Corn production has increased since the OMW application and Water Field) additional benefits arise also from the extra reserve of Treatment water supply during the dry period (May-August). Technologies The study has shown that during the two years of Kokolis (Subsurface demonstration that there is no impact of OMW to the Disposal and groundwater or toxicity issues to the poplar trees. Phytoremediation Monitoring of the effectiveness of the technology will be with Poplar Trees) continued in the future. An electrocoagualtion unit was installed at the end of the wastewater treatment plant of the orange juice factory to reduce the color in the treated water. Specific alteration Orange Juice Lakonia (Electroin the existing treatment scheme was suggested to Waste Water coagulation) improve the appearance and turbidity of the wastewater. Monitoring of the effectiveness of the technology will be continued in the future. The analysis of monthly samples of reeds suggested that a significant accumulation of N and P was achieved of the order of 20 and 3 g/Kg respectively. The reeds have a Drainage Skala maximum accumulation of N and P during spring. The Canals (Phytoremediation drainage canal sediments have also a significant reductive Management with Reeds) capacity reducing by 88% the concentration of nitrate from groundwater. The study showed that proper management of the drainage canals can reduce fluxes to surface waters by over 90%. Restoration of the riparian zone by the creation of a Sparta (Riparian riparian forest was shown to be an effective technology for Zone Restoration the combined reduction of non-point source pollution River Bank and fluxes and bank erosion protection. In the first two year of Management Phytoremediation by the study, significant reductions in nutrient concentrations a Poplar Forest) were observed. Monitoring of the effectiveness of the technology will be continued in the future. Natural attenuation of nutrients in the basin was shown to Monitored be a very effective technology. Monitoring and modeling Natural Basin studies estimated that nitrogen and phosphorous were Attenuation reduced in the basin by 86% and 92% respectively. Final Report (Technical issue) – LIFE05 ENV/GR/00024 292/313 Environmental Friendly Technologies for Rural Development TASK 7 - Evaluation of social acceptance and dissemination of results 1. Dissemination Strategy Plan The initial planning of dissemination activities for the Project was elaborated on the basis of four fundamental axes: a) thematic distribution of the activities, b) time schedule, c) definition of target-groups, d) methods of dissemination. A. Concerning the thematic distribution of the dissemination activities content, specific issues addressed were defined as follows: Overall local development perspectives. Modern methods and practices of integrated agricultural production. Alternative tourist activities (agro-tourism, eco-tourism). Water resources management (modes and techniques for water consumption reduction and anti-pollution technologies). Environmental information and sensitization of the public. B. The time schedule of the dissemination activities comprised: An initial stage, where the goal was to inform the local population about the Project objectives and thus to promote participation of several local agents and to achieve social acceptance of the Project methods and priorities. An intermediate stage, where the goal was to provide continuous information about the ongoing progress of the Project, together with enhancing local agents' participation in order to identify local specificities and development perspectives. A final stage, where a twofold goal had been put: to propose the final form of proposed measures and to disseminate the final results and the estimated benefits of these measures, through an adequate consultation process. This stage also aimed at the increasing the capacity for future development. C. For methodological purposes the target groups were categorized as follows: Local agencies/Project Participants (staff of the Prefecture of Lakonia, the ERA Municipalities and the Local Organizations for Land Improvement. Representatives of professional and entrepreneurial associations (Commercial and Manufacture Association, Trade Union, Hotel Owners Association). Agricultural and Stock-breeding Co-partnerships. Environmental Education Agencies. Non Governmental Organizations (Environmental Organizations, Citizens' Associations) Local media. D. Means and methods of dissemination comprised activities at different scales, such as: Regular contacts and meetings with local agents and Projects participants (planning and organization of the Project activities, meetings on specific issues, organization and materialization of public events, participation in public events Final Report (Technical issue) – LIFE05 ENV/GR/00024 293/313 Environmental Friendly Technologies for Rural Development organized by third parts, public consultation processes and formation of the content of final measures). Public events (scientific and informative conferences, participation in conferences ans festivals organized by third parts), addressed to the above mentioned target groups. Elaboration, production and distribution of imprint and digital informative material (flyers, leaflets, posters, banners, CD, DVD etc.). 2. Transformations according to local specificities and urgent problems (fire disasters, floods, water shortage, recycling) The initial Dissemination Strategy Plan was shaped according to the Project objectives, the above mentioned methodology and the information obtained by local agents. However, during the materialization process (and even in the stage of its final formation), several transformations appeared to be of crucial importance, due to specific conditions and emerging problems. Representatives of the ERA Municipalities, as well as the preliminary study on 'Social and Economic dimensions – the first approach' revealed the low sensitization on environmental issues and more specifically the absence of any recycling and waste management systems. This condition called for a new survey in the local population and in the representatives of public agencies in order to evaluate existing capacity together with an effort for more sensitization. In this context a review of existing systems functioning at the national level was undertaken, in order to investigate their potential implementation in the PL (currently one of the four less developed Prefectures in Greece concerning recycling). Lists of the different waste management systems were produced and distributed to potential beneficiaries, together with informative material (posters, leaflets). Additionally, the potential recycling of expired drugs was investigated, based on the innovative practice adopted by the Pharmasists' Co-partnership in the Prefecture of Thessaloniki. Relevant material was distributed to the pharmacists of the PL. In the first year of the Project severe floods caused extended damags in agricultural land and, in some cases, in settlements. The partners of the Project responded by several means: adequate surveys with representatives and farmers, elaboration of studies on flood prevention, data collection and processing in collaboration with the Hellenic Agricultural Association, organization of local meetings and seminars on flood prevention and restoration measures. Water shortage in the area has been observed to increase in recent years, due to reduced rains. This condition called for informative events, in order to discuss the impact on agricultural production and possible methods to decrease water consumption for agricultural and urban use. The example of the water distribution system established by the Local Organization for Land Improvement in the Prefecture of Serres was used as an indicative good practice, in order to investigate the possibility of similar practices in the ERA. Several relevant Final Report (Technical issue) – LIFE05 ENV/GR/00024 294/313 Environmental Friendly Technologies for Rural Development meetings with local representatives were organized. In the summer 2007 forest fires destroyed a great part of forest and agricultural land in the Region of Peloponnesus and in the mountainous part of Lakonia. The partners of the Project, in collaboration with other agents, responded by elborating studies on the restoration of the ecosystems, the preservation of the agricultural land and the possible establishment of stock-breeding parks, as in the case of the Municipality of Kyrros in the Prefecture of Pella, Region of Central Macedonia, focusing on the institutional framework and the economic viability. The emerging transformations were incorporated in the initial Dissemination Plan and the final framework of activities and interventions was adequately informed. The initial definition of the target groups and the proposed means remained the same but the thematic content was enriched, according to the new data. 3. Evaluation of Social Acceptance/Public Consultation Τhe comparison of the results of the two socio-economic studies (initial and repetitive) conducted throughout the project implementation (interviews with local electives and residents/professionals) demonstrate the fact that to a considerable extent society in the Evrotas River Basin (ERB) has adopted the philosophy of the EnviFriendly project, accepted the need to implement the suggested actions in the field of water resources management and prioritized in similar ways the necessary changes. Local society is now aware of the alternative development perspectives of Evrotas and considers the implementation of EnviFriendly to have set the framework for the sustainable agricultural development of the region and to have paved the road for the implementation of new development projects in the region. Public participation is essential throughout the preparation, review and updating of the ERB management plans. Different types of participation refer to different levels of involvement of stakeholders and the public. The implementation of the WFD requires the following forms of participation: a) information supply, b) consultation and c) active involvement. It should be stressed that approaches to public participation should be context specific and adapted to the specific institutional, socio-economic and environmental context of the River Basin within which they are pursued. The EnviFriendly project organized the public participation process in full consideration of the centralized and hierarchical nature of the Greek state, the limited experience of public and private stakeholders in co-operation and the inexperience of the general public in participatory processes. Thus the project team closely cooperated with the local authorities (prefectures, municipalities and central state departments) in the preparation of the ERB management plan and approached local stakeholders and the public through the authorities. Public participation took place at: 1) the central level: with the active involvement of the Laconia Prefecture in the elaboration of the ERB management plans (the Land Reclamation Office specialized in the problem of draught and the adoption of preventive practical measures, while the Final Report (Technical issue) – LIFE05 ENV/GR/00024 295/313 Environmental Friendly Technologies for Rural Development Department of Hygiene specialized on pollution issues in the Evrotas RB and the riparian areas). The regional Office of the General Secretariat for Civil Protection also actively participated in the elaboration of measures against natural disasters. 2) the local level: first with the active involvement of the local authorities and the respective local organizations of land reclamation that specialize on water management issues and second with the establishment of an informal information network that includes all local stakeholders (NGOs, professional unions, professionals, civil society organizations) and households. Public participation was organized along the following steps: 1) Initial step: upon the starting of the project a timetable and a strategic plan for the project implementation towards the elaboration of the ERB management plan were prepared. 2) Intermediate step: the regional peculiarities, the main pollution sources and the related polluting activities were registered and the water management stakeholders at the national, regional and local level were mapped and contacted. The basis for the management plan was set. Some of the proposed measures have been demonstrated in Evrotas basin, during the EnviFriendly project, such as for example (1) in ―Tzinakos olive mill‖ the wastewater is stored in evaporation ponds and is used during the summer for the irrigation of a corn field and for compost production, (2) the management of drainage canals as a low cost agro-environmental measure. 3) Final step: The management plan was presented to the stakeholders and the public in general for open discussion. Different views were presented, comments and suggestions were taken into consideration and the results of the discussion were incorporated in the final version of the management plan. The analysis of the environmental problems of the ERB indicated the urgency of such problems as the olive mills wastes and drought. These two points were thoroughly addressed by all the participation mechanisms used towards the elaboration of the ERB management plan: 3) Information provision and awareness rising: information was provided to all the stakeholders (local and regional) in the ERB in order to raise the awareness of stakeholders and the population in general and give them the necessary knowhow to participate in the consultation process at a second stage. More specifically, a) printed and electronic material was widely distributed on a regular basis, b) the results of the socio-economic studies conducted in the region were widely distributed and presented in public thematic events, c) environmental education was pursued with the collaboration of local educational institutions, d) information events and workshops were realized in different municipalities and e) information material was distributed and local stakeholders contacted during local celebrations organized for different reasons in at least six municipalities. With reference to oil mils wastes a handbook of 10 alternative scenarios for the treatment of wastes was prepared and a series of information and educational events were implemented with the vast participation of olive oil producers. Similar actions were addressed to farmers on draught and the role of wise agricultural practices. Final Report (Technical issue) – LIFE05 ENV/GR/00024 296/313 Environmental Friendly Technologies for Rural Development 4) Consultation: in May 2008 a series of meetings were organized locally in five municipalities in which local authorities (municipal council), large olive oil producers and farmers and their unions, and representatives of the local organizations of land reclamation reviewed and discussed the environmental and socio-economic analyses‘ results and the development prospects of their localities. The feedback was then incorporated in the drafting of the preliminary ERB management plan which was presented for open consultation in November (21st) 2008 in Sparta, the capital city of the Laconia Prefecture. The outcome of the consultation process and the written contributions were incorporated in the second draft of the ERB management plan which was presented for open consultation in February (26th) 2009. Both consultation events were organized in a similar way. Participants were invited by the prefectural authorities who issued a press release in the local and prefectural press and the local radio stations – personal e-mails were also sent. Participants included representatives of the local and prefectural authorities and regional administration, representatives of the Local organations of land reclamation, large olive oil producers and farmers and representatives of their professional unions, scientists (agronomists, geologists, hydrologists etc.), civil society, NGO representatives and citizens. Written contributions-responses were then considered in the preparation of the final management plan which focused on the Integrated Water Resources Management of the ERB towards environmental enhancement, social cohesion, economic development and improvement of life quality. The goal of the management plan is the implementation of sustainable agricultural practices and the improvement of the chemical and ecological status of the surface and ground waters of the ERB. 4. Issues of Dissemination Strategy Project web site (http://www.envifriendly.tuc.gr) The construction of a web site for the Project had been planned at the initial stage of its implementation. The main objectives of the web page have been to include the research findings and to provide additional ground for dissemination, especially concerning local stakeholders. The web site is regularly updated and enriched with new emerging material. It contains pages both in Greek and in English. Its contents include the following thematic units: - The region - Local agents - The Project - Observatory for Local Development - Fire effects management - Environmental education - News and Events - Funding resources Final Report (Technical issue) – LIFE05 ENV/GR/00024 297/313 Environmental Friendly Technologies for Rural Development Thematic units contain informative material and links with relevant web sites of Ministries, public services and private agents whose activities concern water resources management, agricultural development, ecotourism etc. During the implementation of the Project the web site proved to be effective for the communication and information exchange among the partners. After the end of the implementation period the web site will continue to evolve under the responsibility of the Observatory, thus consisting an important tool for the constant realization of the objectives of the latter. Observatory for Local Development The Observatory for Local Development was established and operates as part of the Prefecture of Lakonia administrative structure. The function of Observatory institutionalized ordinary by the Peloponnesus region (number 725/16-04-09). Today it is primarily a mechanism for collection and dissemination of information on investment and development potential. In the future it is planned to obtain crucial role in the implementation of the Water Resources Management Plan. It is going to coordinate the continuous public consultation process, thus being able to accommodate views from different stakeholders and social groups and to direct them towards a common development perspective. Open Farms and Mapping Trails The aim of the LIFE/EnviFriendly coordinators is for Open Farms to: Become educational and information centres for students: acquaint students with the agricultural production procedures, the management and operation of an organized farm, the seasonal problems, the connection between the supply of raw material, production and marketing etc. Link the objectives and results of the LIFE project with every agricultural practices since the project emphasizes the adoption of the Codes of Good Agricultural Practices, the promotion of organic products and the application of the demonstration technologies in the agricultural field. Facilitate the promotion of the local agricultural products, familiarize students with the way local products are produced and inform the public about the advantages of the local agricultural products and their contribution to the local economy. The list of the Open Farms has been elaborated with the assistance of the Union of New Farmers and other Farmers‘ Cooperative Organizations, on the basis of specific criteria that seek to attract as many visitors and organized school / educational excursions as possible. The response and representativeness criteria that the project team used consisted of the following: e) The distribution of the farms had to represent the largest and most important part of the local agricultural production. Accordingly olive and orange groves and horticultural farms (as well as a cattle farm) had been selected (traditional local products). Final Report (Technical issue) – LIFE05 ENV/GR/00024 298/313 Environmental Friendly Technologies for Rural Development f) The production way should address the whole of the necessary production procedures. Thus, the Open Farms list included organic farms, traditional seasonal farms and greenhouses. g) The geographic distribution of the farms should cover the whole of the Evrotas River Basin. Accordingly, the list included farms in the Municipalities of Elos, Inounta, Krokees, Asopos, Molaoi, Skala and Pellana. h) The farms should be easily accessible. Thus, the list included farms that can be easily accessed by schools, tourists and other visitors through the highway or the main regional road network. According to the initial Dissemination Strategy Plan, the selection of specific farms had been proposed, as a means to show off the local agricultural production and products and to achieve interconnection with ecotourist activities. Self-consumption and non-market exchange of agricultural products are well-established practices in local social networks. Consequently, instead of constituting a way to integrate the local agricultural market, the basic goal of the ‗Mapping of Open Farms‘ activity was to inform and educate the broader audience. More precisely, Open Farms: - can be the ground for educational and informative activities for students who can get familiarized with the local production process. The current school year has been defined as the ‗Year for Agricultural Production and Wholesome Nutrition‘ and several relevant activities are being materialized. - can contribute to the linkage between the Project objectives and results and the everyday agricultural practice, especially in what concerns the adoption of the Code for Good Agricultural Practice the cultivation of organic products and the use of new technologies for rural development. Moreover, the mapping of river and mountain trails in the ERA was proposed in the context of increasing possibilities for ecotourist development. Based on the study of the University of Ioannina and in collaboration with the local branch of the Greek Mountaineering Club maps of seven riverside and three mountainous forest zones were produced. Some of the routes of the mountainous area (Eastern Taygetos) are parts of the E4 international trail. Together with a relevant photographic presentation, this material is available at the Project web page. 5. Evaluation of Dissemination Results Upon the completion of the project the following results indicate the effectiveness of the public participation tools towards a more active involvement in decision and policymaking: 3) The institutionalization of networking with the establishment of the Observatory for Sustainable Development. The amendment of the regulation of the organization and operation of the Prefectural Authorities of Laconia was published in the Official Journal of the Government in April 2009 (number 725/16-04-2009) establishing the Observatory for Sustainable Development. The Observatory will become operational under the jurisdiction of the Prefectural Authorities and its tasks will include the collection of all information material for the exploitation of Final Report (Technical issue) – LIFE05 ENV/GR/00024 299/313 Environmental Friendly Technologies for Rural Development the ERB development potential and the collection of feedback from all local stakeholders and citizens, the overall coordination of the development actions and the participation to the resolution of the emerging environmental and broader development problems. 4) Following the meetings with the local olive oil producers it became clear that the majority of them were willing to implement the suggested by the EnviFriendly project group waste treatment measures on the condition that they would receive financial support and guidance by the State. Within this framework, the procedures have started for the release of a Local Health Provision with a detailed description of the obligations of the olive oil manufacturers in the ERB. The implementation of the participation procedures planned by the EnviFriendly project group has verified the assumption that for public participation approaches to be successful (i.e. produce technical knowledge or social capital) they should be tailoredmade to the specific institutional, socio-economic and environmental context within which they are pursued: 4) Considering the centralized and hierarchical nature of the Greek state it is no wonder that the Prefecture of Laconia had to operate as a ‗leader‘ in bringing together local stakeholders and the public at large. The inexperience of public and private actors in Greece in participatory procedures necessitated the assumption of a ‗leading‘ role by an authoritative public institution. Furthermore, in view of the financial considerations of farmers and olive-oil manufacturers, the most extensive participation of local authorities considerably diminished the reluctance of local stakeholders and society at large to proceed with the required alterations of well-established but not sustainable practices. 5) Local stakeholders and the public have no experience in participatory procedures and often ignore basic environmental facts. Within this framework, before planning and implementing the consultation procedures it is necessary to spend some time to environmentally educate stakeholders and the public and create the required participatory know-how. 6) While implementing the project the environmental conditions underwent dramatic changes with the extreme 2006 draught and the catastrophic 2007 fires. These changes had to be extensively studied by the project team and the results of the relevant studies were introduced in the strategic management plan. 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