Chapter 6 6 Chemical Reactions Study Goals • • • • • • • Classify a change in matter as a chemical change or a physical change. Show that a balanced equation has an equal number of atoms of each element on the reactant side and the product side. Write a balanced equation for a chemical reaction when given the formulas of the reactants and products. Classify an equation as a combination, decomposition, replacement and/or combustion reaction. Describe the features of an oxidation-reduction reaction. Describe the factors that affect the rate of a reaction. Use the concept of reversible reactions to explain chemical equilibrium. Chapter Outline 6.1 Chemical Changes Explore Your World: Evidence of a Chemical Change 6.2 Chemical Equations 6.3 Balancing a Chemical Equation 6.4 Types of Reactions Health Note: Smog and Health Concerns 6.5 Oxidation-Reduction Reactions Explore Your World: Oxidation of Fruits and Vegetables 6.6 Energy in Chemical Reactions Health Note: Hot Packs and Cold Packs Explore Your World: Hotter or Colder? Explore Your World: How Fast Can it Go? 6.7 Rate of Reaction 6.8 Chemical Equilibrium Explore Your World: Modeling an Equilibrium System Health Note: Oxygen, Hemoglobin, and Carbon Monoxide Poisoning Health Note: Homeostasis: Regulation of Body Temperature Chapter Summary and Demonstrations 1. Chemical Reactions and Equations Examples of physical and chemical changes introduce the idea of chemical reaction. The process of writing and balancing a chemical equation is carefully explained with several sample problems. In the final sections of the chapter, mole relationships and mole conversion factors in an equation are written from the equation coefficients and used to calculate the grams or moles of a reactant or product in a reaction. Demonstration: I use examples of an everyday process to introduce the idea of writing an equation. A cooking example: 2 slices of bread + 3 slices turkey + 1 slice tomato + 2 lettuce leaves = 1 turkey-tomato-lettuce sandwich. Any recipe could be used. A sport example: 1 can tennis balls + 2 tennis racquets + 1 net + 2 players = 1 tennis game. Chemical Reactions 2. Energy in Chemical Reactions The heat of reaction is described as the energy difference between reactants and products. In exothermic reactions, heat is released; in endothermic, heat is absorbed. The rate of reaction is the speed at which products form and can be increase by adding more reactant, raising the temperature, or adding a catalyst. Demonstration: Obtain some hot packs and/or cold packs at a pharmacy. Have students read the labels to determine contents. Then have them hit the packs to break the vials. Describe the results. Which solution reaction was exothermic? Which reaction was endothermic? In which pack was the energy of the reactant higher than the product? Laboratory Suggestions Lab 10 Chemical Reactions and Equations Students carry out a variety of chemical reactions that demonstrate the combustion of magnesium, the reactions of zinc and CuSO4 (aq), metals and acid, and double replacement reactions. Students describe the physical properties of the reactants and the products to show evidence of reaction. A balanced equation is written for each reaction and the type of reaction is determined. A. Magnesium and Oxygen B. Zinc and Copper (II) Sulfate C. Metals and HCl D. Reactions of Ionic Compounds E. Sodium Carbonate and HCl Laboratory Skills to Demonstrate Proper handling of reagent bottles and water disposal Labeling test tubes and organizing beakers Balancing a chemical equation. Identifying the type of reaction Lab 11 Reaction Rates and Equilibrium In an exothermic reaction, heat is released causing the temperature of the surroundings to increase. An endothermic reaction absorbs heat, which causes a drop in the temperature of the surroundings. The rate or speed at which a reaction occurs depends on the amounts of the reactants, the temperature, and the presence of a catalyst. When a reaction begins, reactants are converted to products. As the reaction proceeds, products react to form reactants. Increasing reactants shifts a reversible reaction to products; an increase in products shifts the equilibrium to reactants. A. Exothermic and Endothermic Reactions B. Rates of Reactions C. Reversible Reactions D. Iron (III)-thiocyanate equilibrium Laboratory Skills to Demonstrate Describe how to write heat as a reactant or product in an equation. Review the factors that affect the rate of a reaction. Review the effects of temperature, reactants and products on a reversible reaction. Relate the change in appearance of a reactant or product to a shift in equilibrium.