Outline PSPICE: device non-uniformity modeling and other examples • PSpice for study of device non-uniformity • Other applications – Propagation of signal in PV cell – FET system for cancer drug studies • Hands-on session Lecture 10 – Editing PSPICE models – Modeling mini-module example file Special Topics: Device Modeling Introduction PV device performance • Semiconductor device modeling in 2-D and 3-D through equivalent circuits • Applicable to modeling of any other problems involving electro-magnetic signals • Basic approach: draw equivalent circuit, vary part models, parameters, etc. J Voc Jsc Rsc FF Jsc Rsc Voc V Roc FF Roc Voc is the open-circuit voltage Isc is the short-circuit current FF is the fill factor Pmax is the maximum power η is the efficiency Pmax V OC I SC FF V OC I SC FF Pin Study of PV device non-uniformity J Voc V Roc The input power for efficiency calculations is 1 kW/m2 or 100 mW/cm2 PV device performance J FF • • • • • V Jsc Rsc • Example of the shunt (RSC=>0) effect on IV curve and major PV parameters • Device is represented by equivalent circuits for 2D or 3D connections • Applicable at a cell, cell-on-a-substrate, module, or PV field levels • Device optimization, influence of component parameters, and various other phenomena can be studied 1 PV non-uniformity: Equivalent circuit for module Study of PV device non-uniformity • Introduced distributions of PV parameters (Voc, Jsc, Rser, Rsh), both statistical and spatial • Calculated resulting device efficiency dependent on changes in: V bus bar cell .. . .. . .. . .. . PV non-uniformity: Procedure ... R s e r3 1 R s e r3 2 R s e r3 3 13 13 13 13 R sh 3 0 9999 9 I3 0 20.5mA d c R sh 3 1 9999 9 I3 1 D 30 20.5mA d c R sh 3 2 9999 9 I3 2 D 31 R r1 0 .5 20.5mA d c R sh 3 3 9999 9 I3 3 D 32 R r2 0 .5 2. Model J-V curve of non-uniform module, calculate relative efficiency: D 33 R r3 0 .5 ... R s e r1 R s e r2 13 20.5mA d c 13 R sh 1 9999 9 I1 20.5mA d c D 1 V1 R s e r3 20.5mA d c D 2 13 R sh 3 9999 9 I3 rel non R s e r4 13 R sh 2 9999 9 I2 20.5mA d c Equivalent circuit 3 by 4 sub-cells, lump parameters 1. Generate parameter distributions: statistics – by first three moments (average, SD, and skewness ); geometry – assign values to sub-cells R r3 2 0 .5 R s e r3 0 V Integrated module – 3 linear cells in-series through metallized scribes PV non-uniformity: PSPICE Schematics 20.5mA d c bus bar substrate Diana Shvydka and V. G. Karpov, Power generation in random diode arrays, Phys. Rev. B 71, 2005, pp. 115314-1-5. Diana Shvydka and V. G. Karpov, Modeling of nonuniformity losses in integrated large area solar cell modules, Proc. 31st IEEE PVSC, Florida, 2005, pp 359-362. R r3 1 0 .5 Rr electrodes – Module size and disorder amplitude – Series and interconnect resistances – Shunting-like phenomena R r3 0 0 .5 Rsh Rs unif / uniform R sh 4 9999 9 I4 D 3 or relative mismatch loss: D 4 R o u t1 ... 0 .0 1 m Pnon • Represents 2x1 ft module with 1 cells • 58 linear cells in series, 29 sub-cells in parallel, total 1682 sub-cells • Parameters: Voc, Jsc, Rs, Rsh, Rr (one fluctuating) cm2 PV non-uniformity: Module size dependence C o n tin u o u s d is o r d e r d is o r d e r ) sc 0 .0 1 500 50 650 300 800 B i-m o d a l L o g ( C o u n ts ) oc re l S D ( 50 J 0 .1 100 1000 14 V Geometry (Voc maps) First three moments: <Voc>=755mV, SD=100mV, =-1.3 500 40 1 E -3 40 / Puniform 3. Study dependence on module size, degree of disorder PV non-uniformity: Parameter distributions Statistics unif R e l. M is m a tc h L o s s ( m ) , % 0Vd c V 12 J d is o r d e r oc sc d is o r d e r 10 8 6 4 2 0 100 700 30 10 rel 0 . 923 900 30 20 20 10 10 rel 0 . 919 10 Scaling law: SD N Voc 0 . 74 1 150 300 450 600 V oc, m V 750 900 5 10 15 20 25 Continuous 100 N u m b e r o f s u b - c e lls 5 10 15 20 25 Bi-modal Jsc 0 . 64 1000 10 100 1000 N u m b e r o f s u b - c e lls • SD of relative efficiency changes by 2 orders • Module size changes from 3x3 to 35x35 sub-cells • For large module mismatch loss converges • Each point obtained on 20 simulations 2 PV non-uniformity: Disorder Dependence V oc 1 .0 0 = 0 .3 scribe lines V 25 20 V oc oc re l 30 = 0 .2 5 R e l. E ffic ie n c y , R e l. M is m a tc h L o s s (m ), % 35 PV non-uniformity: Series and scribe resistances = 0 .2 15 V 10 oc = 0 .1 3 0 .9 5 Rr 0 .9 0 S c r ib e ( r o w ) r e s is t a n c e : R r= 2 5 R r= 5 0 .8 5 R r= 0 .5 5 Rs 0 .8 0 0 -1 .5 -1 .0 -0 .5 0 .0 S kew ness 0 .5 1 .0 1 .5 2 .0 S h u n ts R e l. E ffic ie n c y , re l " H o le s " Shunt: Rsh=0 0 .7 0 .6 ‘Hole’: Rs=0 and low Voc 0 .4 0 .3 0 .0 0 0 .0 5 0 .1 0 0 .1 5 15 20 25 30 s 0 .8 0 .5 10 S e r ie s r e s is t a n c e R , O h m PV non-uniformity: Shunting-like phenomena 0 .9 5 (V o c ) Voc disorder: m ~ 8% for moderate disorder Voc ~ 13% m ~ 30% for higher degree of disorder Voc ~ 30% 1 .0 0 0 .2 0 F r a c tio n o f d a m a g e d e le m e n ts Large module 29x56 sub-cells, disorder in Voc (Voc ~ 13%) Large module 29x56 sub-cells, disorder in Voc (Voc ~ 13%) Low resistance promotes non-uniformity losses PV non-uniformity: Conclusions • Parameter distribution statistics plays the dominant role in resulting module efficiency; geometry has a minor effect • Mismatch loss is almost independent of the module size; depends on degree of disorder • Module series and scribe resistances interfere with non-uniformity effects • Shunting entities close to scribes and bus bars can be a significant efficiency loss factor Effect of shunts and “holes” is comparable at fraction < 0.1 Propagating electric impulses in thin film photovoltaics • Modeled a new physical phenomenon: solitons traveling in the lateral directions of thin-film PV • A small signal perturbation decays while pulses of certain shape and amplitude propagate • Soliton velocity depends on specific resistance, capacitance, and nonuniformity screening length • Verified with experiment Propagating electric impulses • Equivalent circuit j J • Experimental setup G T. K. Wilson, Diana Shvydka, and V. G. Karpov, Propagating electric impulses in thin film photovoltaics, Proc. 4th IEEE PV World Conference, Waikoloa, HI, 2006, pp 471 - 474. O TCO CdS/CdTe 3 Propagating electric impulses: Edge effect Propagating electric impulses: Parameters 0.6 0.6 Propagating electric impulses • The predicted phenomenon of soliton propagation could develop into a future non-destructive diagnostic technique sensitive to device imperfections • Applicable to the problem of electric pulse propagation in living tissues, particularly, nerves (axon of a giant squid system) – Ion channels of biological membranes typically exhibit the diode-like IV characteristics Analysis of anti-cancer drug action R=0.5 R=0.1 0.2 0.4 Voltage, V 0.4 Voltage, V • Considered circuits of 20 – 100 diodes with the parameters chosen to allow for pulse propagation trough the entire system • Typical parameters: Voc = 520 mV, j0 =0.1515mA, R=0.01 – 10 Ohm, C=5-2500 nF • Rectangular pulses with varying amplitudes in the range of +/- 700 mV and durations 10-1000 ms 0.0 5 nF 0.2 25 nF 0.0 250 nF R=0.02 -0.2 -0.2 0 10 20 30 40 50 Diode # Voltage on different diodes rescaled according to y=(Diode #)/L with L inversely proportional to the lateral resistance R. Higher resistances show good scaling, since L is considerably shorter than the system dimension. For low R=0.05 Ohm, L becomes comparable to the system dimension thus violating the scaling 2500 nF 0.00 0.02 0.04 0.06 0.08 0.10 Time, s Pulse shape on a given diode for systems with different capacitors measured at different instances and scaled as Q=t/t. The scaling fails for small C when velocity v becomes large enough for the pulse to span across the entire system and experience edge effects Impedance spectroscopy with field-effect transistor arrays for the analysis of anti-cancer drug action on individual cells A. Susloparova, D. Koppenhofer, X.T. Vu, M. Weil, S. Ingebrandt • Impedance spectroscopy measurements of silicon-based open-gate field-effect transistor (FET) devices were utilized to study the adhesion status of cancer cells at a single cell level • A well-known chemotherapeutic drug, topotecan hydrochloride, was used to investigate the effect of this drug to tumor cells cultured on the FET devices • Real-time impedance measurements were performed to verify the design Analysis of anti-cancer drug action • The developed method could be applied for the analysis of the specificity and efficacy of novel anti-cancer drugs in cancer therapy research on a single cell level in parallelized measurements 4 Summary • Semiconductor device modeling in 2-D and 3-D through equivalent circuits • Basic approach: draw equivalent circuit, vary part models, parameters, etc. • Applicable to modeling of any other problems involving electro-magnetic signals References • OrCAD Capture user manual • OrCAD PSpice user manual • Additional references are given within slides 5