Apple Product Information Sheet ≤ 20 Watt Hours

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AppleProductInformationSheet≤20WattHours
The products referenced herein are “articles” and “consumer products” and therefore are excepted from the 29 CFR 1910.1200
Hazard Communication requirements. The European Classification and Labelling Regulation (EC) No 1272/2008 (CLP) and the
Globally Harmonized System (GHS) of Classification and Labelling of Chemicals exempt articles from the Safety Data Sheet
requirements. This Product Information Sheet is provided only as a service to our customers and is not based upon any
requirement or regulation.
Product:Lithiumionsinglecellbatteries(Li-ion)(“Product”)
WattHours:≤20
(Forpurposeoftransportregulations,asinglecellbattery
isconsidereda“cell”forclassificationpurposes)
Models:SeespecificproductslistedinthisdocumentunderAppleProductBatteryInformation,
manufacturedafterJanuary1,2007.
EditionDate:March7,2016
Version:16.01
GENERALSAFETY
Thisproduct,whenusedunderreasonableconditionsandinaccordancewiththedirectionsfor
use,shouldnotpresentahealthhazard.Themixtureisencapsulatedintheproduct.Onlyif
releasedduetouseorprocessingoftheproductinamannernotinaccordancewiththe
product’sdirectionsforusemayitpresentpotentialhealthandsafetyhazards.
FIRSTAID
Ingestion:IngestionofaLi-ionbatteryishighlyunlikelyintheworkplace,asthecontentsofa
Li-ionbatteryaremostlysolid,andanyfreeliquid(ester-basedelectrolyte)that
mightdripoutofadamagedbatteryislimitedtoafewdrops.However,care
shouldbetakennottotouchfingerstomouthwhilehandlingadamagedbatteryso
astoavoidanyingestionofcontents.Donotinducevomiting.Washoutmouth
withwater.Getmedicalattentionfollowingpotentialexposureoriffeelingunwell.
Inhalation: Removeindividualtofreshairandkeepatrestinapositioncomfortablefor
breathing.Getmedicalattentionifindividualisfeelingunwell.
Skincontact:Flushcontaminatedskinwithplentyofwater.Removecontaminatedclothing.
Continuetorinseforatleast15minutes.Getmedicalattention.Washclothing
beforereuse.
EyeContact:Immediatelyflusheyeswithplentyofwater,occasionallyliftingtheupperand
lowereyelids.Checkforandremoveanycontactlenses.Continuetorinseforat
least15minutes.Getmedicalattentionifirritationpersists.
HANDLING&STORAGE
Handling–Donotexposeproducttoexcessivephysicalshockorvibration.Donotdisassemble.
Shouldanindividualcellintheproductbecomeruptured,donotallowcontactwithwater.
AppleProductInformationSheet≤20WattHours
Storage–Storeinacool,wellventilatedarea.Storageabove100degreescanresultinlossof
productperformance,leakage,orrust.Donotexposeproducttoopenflame.
FIRESAFETY
Incaseoffirewhereproductsarestored,floodtheareawithwaterasneededtocontrolthe
fireonnearbyordinarycombustibles.Ifanyproductsareinvolved,watermaynotextinguish
them,butwillcooltheadjacentproductsandcontrolthespreadoffire.Firefightersshould
wearself-containedbreathingapparatus.Tocontrol/stopathermalbatteryeventwhereonly
theproductisinvolved,useplentifulamountsofclean/drysandtoimmediatelysmotherthe
thermalreactionandreducingsmoke.Thisismosteffective,ifappliedtocoverthebattery,
especiallyinthefirstfewsecondsoftheevent.CO2,drychemical,andfoamextinguishersmay
alsobeusedforsmallfiresinareaswhereproductsarestored,butmaynotextinguishthe
involvedproductsthemselves.LITH-X(powderedgraphite)orcopperpowderfireextinguishers,
drygrounddolomiteorsodaashmayalsobeused(thesematerialsalsoactassmothering
agents).
DISPOSAL
Appleproductscontainrecyclablematerialsandshouldnotbeputintothemunicipalwaste
stream.Refertothefollowingwebsitesforbatteryreplacementandrecyclingoptions
(http://www.apple.com/batteries/replacements.html,http://www.apple.com/recycling/).Do
notdisposeofinfire.
TRANSPORTATION
Apple’sproductcellshavebeensuccessfullytestedandcomplywiththeUNModelRegulations,
ManualofTestandCriteria,PartIII,subsection38.3.Productcellshavebeenmanufactured
underaqualitymanagementprogramasspecifiedin2.9.4oftheUNModelRegulations.
PERFORMEDTESTS
RESULTS
38.3.4.1
38.3.4.2
38.3.4.3
38.3.4.4
38.3.4.5
38.3.4.6
38.3.4.7
T1
T2
T3
T4
T5
T6
T7
AltitudeSimulation
ThermalTest
Vibration
Shock
ExternalShortCircuit
Impact/Crush
Overcharge
Pass
Pass
Pass
Pass
Pass
Pass
Pass
38.3.4.8
T8
ForcedDischarge
Pass
AppleProductInformationSheet≤20WattHours
AppleProduct’scellsareratedat20Watt-hoursorlessandmeettherequirementsfor
transportationunder:
UNModelRegulations18threvisededitionSpecialProvisions188and230
InternationalCivilAviationOrganization(ICAO)TechnicalInstructionsandtheInternational
AirTransportAssociation(IATA)DangerousGoodsRegulationsPackingInstructions:
o 965SectionIBorSectionII(UN3480,Lithiumionbatteries)
§ Thesebatterieswillbeofferedfortransportatastateofcharge(SOC)not
exceeding30%oftheirrateddesigncapacity.
o 966SectionII(UN3481,Lithiumionbatteriespackedwithequipment)
o 967SectionII(UN3481,Lithiumionbatteriescontainedinequipment)
InternationalMaritimeOrganization(IMO)SpecialProvisions188and230
EuropeanAgreementConcerningtheInternationalCarriageofDangerousGoodsbyRoad
(ADR)SpecialProvisions188and230
U.S.DepartmentofTransportation(DOT)49CFR173.185and173.185(c)
CanadianTransportofDangerousGoodsRegulations(TDGR)SpecialProvision34
•
•
•
•
•
•
ThefollowingtableprovidesAppleProductBatteryInformation
UNCodes
Numberof
Watt-Hours
AppleProducts
UN3481:Lithiumionbatteries
Batteriesper
per
containedinequipment
Product
Battery
UN3480:Lithiumionbatteries
iPadmini1 and4 generation
UN3481
1
≤20
iPodtouch
UN3481
1
≤20
iPodnano
UN3481
1
≤20
iPodclassic
UN3481
1
≤20
iPodshuffle
UN3481
1
≤20
iPhone
UN3481
1
≤20
AppleWatch
UN3481
1
≤20
AppleTV4 generationw/SiriRemote
UN3481
1
≤20
Applepencil
UN3481
1
≤20
iMacw/Retinadisplayw/Magic
KeyboardandMagicMouse2
UN3481
2
≤20
(StandardConfiguration)
SiriRemote
UN3481
1
≤20
MagicKeyboard
UN3481
1
≤20
MagicMouse2
UN3481
1
≤20
MagicTrackpad2
UN3481
1
≤20
iPhoneSmartBatteryCase
UN3481
1
≤20
XserveRAID
UN3481
1
≤20
MacProRAID
UN3481
1
≤20
Standalonesinglecellbattery(iPod
UN3480
1
≤2.7
nano,classicandshuffle)
StandalonesinglecellBattery(iPod
UN3480
1
>2.7but≤20
st
th
th
touchandiPhone)
LithiumIonbattery
weightonlyinkg
(heaviestper
family)
0.094
0.021
0.021
0.031
0.0175
0.06
0.0046
0.009
0.004
0.0571
0.009
0.0155
0.0416
0.037
0.0354
0.9
0.9
Seespecific
productabovefor
batteryweight
AppleProductInformationSheet≤20WattHours
REGULATORYINFORMATION
Ifhazardousmaterialsarepresentintheworkplace,MaterialSafetyDataSheets(MSDS)/Safety
DataSheets(SDS)arerequiredbyvariousnationalandinternationaloccupationalworker
safetyregulations.However,MSDS/SDS’sarenotrequiredforarticles(see29CFR1910.1200(b)(6)(v)).
Exceptionsalsoapplyforconsumerproductsasdefinedin29CFR1910.1200(b)(6)(ix).Anarticleisdefined
asamanufactureditemotherthanafluidorparticle;(i)whichisformedtoaspecificshapeor
designduringmanufacture;(ii)whichhasendusefunction(s)dependentinwholeorinpart
uponitsshapeordesignduringenduse;and(iii)whichundernormalconditionsofusedoesnot
releasemorethanverysmallquantities,e.g.minuteortraceamountsofahazardouschemical,
anddoesnotposeaphysicalhazardorhealthrisktoemployees.
GENERALRECOMMENDATIONS
CAUTION:Underextremeconditions,ariskoffire,explosionandburnsexists.Donotshortcircuit,crush,puncture,heat,incinerateordisassemblecells.
AppleProductInformationSheet≤100WattHours
The products referenced herein are “articles” and “consumer products” and therefore are excepted from the 29 CFR 1910.1200
Hazard Communication requirements. The European Classification and Labelling Regulation (EC) No 1272/2008 (CLP) and the
Globally Harmonized System (GHS) of Classification and Labelling of Chemicals exempt articles from the Safety Data Sheet
requirements. This Product Information Sheet is provided only as a service to our customers and is not based upon any
requirement or regulation.
Product:Lithiumionmulti-cellbatteries(Li-ion)(“Product”)
WattHours:≤100
(Forpurposeoftransportregulations,amulticellbattery
isconsidereda“battery”forclassificationpurposes)
Models:SeespecificproductslistedinthisdocumentunderAppleProductBatteryInformation,
manufacturedafterJanuary1,2007.
EditionDate:March7,2016
Version:16.01
GENERALSAFETY
Thisproduct,whenusedunderreasonableconditionsandinaccordancewiththedirectionsfor
use,shouldnotpresentahealthhazard.Themixtureisencapsulatedintheproduct.Onlyif
releasedduetouseorprocessingoftheproductinamannernotinaccordancewiththe
product’sdirectionsforusemayitpresentpotentialhealthandsafetyhazards.
FIRSTAID
Ingestion: IngestionofaLi-ionbatteryishighlyunlikelyintheworkplace,asthecontentsofa
Li-ionbatteryaremostlysolid,andanyfreeliquid(ester-basedelectrolyte)that
mightdripoutofadamagedbatteryislimitedtoafewdrops.However,care
shouldbetakennottotouchfingerstomouthwhilehandlingadamagedbatteryso
astoavoidanyingestionofcontents.Donotinducevomiting.Washoutmouth
withwater.Getmedicalattentionfollowingpotentialexposureoriffeelingunwell.
Inhalation: Removeindividualtofreshairandkeepatrestinapositioncomfortablefor
breathing.Getmedicalattentionifindividualisfeelingunwell.
Skincontact:Flushcontaminatedskinwithplentyofwater.Removecontaminatedclothing.
Continuetorinseforatleast15minutes.Getmedicalattention.Washclothing
beforereuse.
EyeContact:Immediatelyflusheyeswithplentyofwater,occasionallyliftingtheupperand
lowereyelids.Checkforandremoveanycontactlenses.Continuetorinseforat
least15minutes.Getmedicalattentionifirritationpersists.
HANDLING&STORAGE
Handling–Donotexposeproducttoexcessivephysicalshockorvibration.Donotdisassemble.
Shouldanindividualcellintheproductbecomeruptured,donotallowcontactwithwater.
AppleProductInformationSheet≤100WattHours
Storage–Storeinacool,wellventilatedarea.Storageabove100degreescanresultinlossof
productperformance,leakage,orrust.Donotexposeproducttoopenflame.
FIRESAFETY
Incaseoffirewhereproductsarestored,floodtheareawithwaterasneededtocontrolthe
fireonnearbyordinarycombustibles.Ifanyproductsareinvolved,watermaynotextinguish
them,butwillcooltheadjacentproductsandcontrolthespreadoffire.Firefightersshould
wearself-containedbreathingapparatus.Tocontrol/stopathermalbatteryeventwhereonly
theproductisinvolved,useplentifulamountsofclean/drysandtoimmediatelysmotherthe
thermalreactionandreducingsmoke.Thisismosteffective,ifappliedtocoverthebattery,
especiallyinthefirstfewsecondsoftheevent.CO2,drychemical,andfoamextinguishersmay
alsobeusedforsmallfiresinareaswhereproductsarestored,butmaynotextinguishthe
involvedproductsthemselves.LITH-X(powderedgraphite)orcopperpowderfireextinguishers,
drygrounddolomiteorsodaashmayalsobeused(thesematerialsalsoactassmothering
agents).
DISPOSAL
Appleproductscontainrecyclablematerialsandshouldnotbeputintothemunicipalwaste
stream.Refertothefollowingwebsitesforbatteryreplacementandrecyclingoptions
(http://www.apple.com/batteries/replacements.html,http://www.apple.com/recycling/).Do
notdisposeofinfire.
TRANSPORTATION
Apple’sproductbatterieshavebeensuccessfullytestedandcomplywiththeUNModel
Regulations,ManualofTestandCriteria,PartIII,subsection38.3.Productbatterieshavebeen
manufacturedunderaqualitymanagementprogramasspecifiedin2.9.4oftheUNModel
Regulations.
PERFORMEDTESTS
RESULTS
38.3.4.1
38.3.4.2
38.3.4.3
38.3.4.4
38.3.4.5
38.3.4.6
T1
T2
T3
T4
T5
T6
AltitudeSimulation
ThermalTest
Vibration
Shock
ExternalShortCircuit
Impact/Crush
Pass
Pass
Pass
Pass
Pass
Notapplicable
38.3.4.7
38.3.4.8
T7
T8
Overcharge
ForcedDischarge
Pass
Notapplicable
AppleProductInformationSheet≤100WattHours
AppleProduct’sbatteriesareratedat100Watt-hoursorlessandmeettherequirementsfor
transportationunder:
•
•
•
•
•
•
UNModelRegulations18threvisededitionSpecialProvisions188and230
InternationalCivilAviationOrganization(ICAO)TechnicalInstructionsandtheInternational
AirTransportAssociation(IATA)DangerousGoodsRegulationsPackingInstructions:
o 965SectionIBorSectionII(UN3480,Lithiumionbatteries)
§ Thesebatterieswillbeofferedfortransportatastateofcharge(SOC)not
exceeding30%oftheirrateddesigncapacity.
o 966SectionII(UN3481,Lithiumionbatteriespackedwithequipment)
o 967SectionII(UN3481,Lithiumionbatteriescontainedinequipment)
InternationalMaritimeOrganization(IMO)SpecialProvisions188and230
EuropeanAgreementConcerningtheInternationalCarriageofDangerousGoodsbyRoad
(ADR)SpecialProvisions188and230
U.S.DepartmentofTransportation(DOT)49CFR173.185and173.185(c)
CanadianTransportofDangerousGoodsRegulations(TDGR)SpecialProvision34
ThefollowingtableprovidesAppleProductBatteryInformation
UNCodes
Numberof
Watt-Hours
AppleProducts
UN3481:Lithiumionbatteries
Batteries
per
containedinequipment
perProduct
Battery
UN3480:Lithiumionbatteries
MacBookPro
UN3481
1
≤100
MacBookAir
UN3481
1
≤100
MacBook
UN3481
1
≤100
iPadPro
UN3481
1
≤100
iPad
UN3481
1
≤100
iPadAir1&2
UN3481
1
≤100
iPadmini2 and3 generation
UN3481
1
≤100
nd
rd
MacBookstand-alonebattery
UN3480
1
>2.7but≤100
LithiumIonbattery
weightonlyinkg
(heaviestperfamily)
0.9
0.47
0.9
0.1746
0.214
0.264
0.115
Seespecificproduct
aboveforbatteryweight
REGULATORYINFORMATION
Ifhazardousmaterialsarepresentintheworkplace,MaterialSafetyDataSheets(MSDS)/Safety
DataSheets(SDS)arerequiredbyvariousnationalandinternationaloccupationalworker
safetyregulations.However,MSDS/SDS’sarenotrequiredforarticles(see29CFR1910.1200(b)(6)(v)).
Exceptionsalsoapplyforconsumerproductsasdefinedin29CFR1910.1200(b)(6)(ix).Anarticleisdefined
asamanufactureditemotherthanafluidorparticle;(i)whichisformedtoaspecificshapeor
designduringmanufacture;(ii)whichhasendusefunction(s)dependentinwholeorinpart
uponitsshapeordesignduringenduse;and(iii)whichundernormalconditionsofusedoesnot
releasemorethanverysmallquantities,e.g.minuteortraceamountsofahazardouschemical,
anddoesnotposeaphysicalhazardorhealthrisktoemployees.
GENERALRECOMMENDATIONS
CAUTION:Underextremeconditions,ariskoffire,explosionandburnsexists.Donotshortcircuit,crush,puncture,heat,incinerateordisassemblecells.
LinkstoExternalCoinCellSupplierDocuments
LinktoPanasonicandRayovac
Panasonic
http://industrial.panasonic.com/ww/downloads/product-safety-data-sheet
742-0048(CR2032)
742-0062(BR2032)
742-0064(BR2330)
RAYOVAC
http://www.rayovacindustrial.com/Technical-OEM/SDS.aspx
742-0080(BR2032)
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