Name:______________________________________________________Pd:_______Date:_________________ Chapter 9: Electrons in Atoms and the Periodic Table – Study Guide *Do not forget about the extra resources available to help you study and prepare for this test! Textbook pages 285 – 323 Mastering Chemistry Study Area: http://www.pearsonmylabandmastering.com/northamerica/ Miss Marnik’s Website: http://www.northallegheny.org/Page/16665 Labs, problem packets, and homework assignments Section 1 – Light and Quantized Energy: (text pages 285-293) Need to be able to: Compare the wave and particle natures of light. Define a quantum of energy, and explain how it is related to an energy change of matter. Contrast continuous electromagnetic spectra and atomic emission spectra. Practice Problems: Use the words from the box to fill in the blanks: 1. amplitude energy frequency light speed wave wavelength Electromagnetic radiation is a kind of ______________________________ that behaves like a(n) ______________________________ as it travels through space. ______________________________ is one type of electromagnetic radiation. Other examples include x-rays, radio waves, and microwaves. All waves can be characterized by their wavelength, amplitude, frequency, and ______________________________. The shortest distance between equivalent points on a continuous wave is called a(n) ______________________________. The height of a wave from the origin to a crest or from the origin to a trough is the ______________________________. ______________________________ is the number of waves that pass a given point in one second. 2. List the types of electromagnetic radiation in order from lowest energy to highest energy. 3. Which type of electromagnetic radiation has the longest wavelength? 4. Which type of electromagnetic radiation has the highest frequency? 1 5. Which color in the visible spectrum has the least amount of energy? 6. Which color in the visible spectrum has the most amount of energy? 7. A(n) __________________ is the minimum amount of energy that can be lost or gained by an atom. a. valence electron c. quantum b. electron d. photon 8. The ________________ is the phenomenon in which electrons are emitted from a metal’s surgace when a light of a certain frequency shines on it. a. quantum c. wave b. photon effect d. photoelectric effect For each statement below, write true or false: 9. _______________ Like the visible spectrum, an atomic emission spectrum is a continuous range of colors. 10. _______________ Each element has a unique atomic emission spectrum. 11. _______________ A flame test can be used to identify the presence of certain atoms in a compound. 12. _______________ Atomic emission spectra can be explained by the wave model of light. 13. _______________ The neon atoms in a neon sign emit their characteristic color of light as they absorb energy and jump to higher energy levels. Section 2 – Classifying Reactions: (text pages 294-298) Need to be able to: Compare the Bohr and quantum mechanical models of the atom. Explain the impact of de Broglie’s wave particle duality and the Heisenberg uncertainty principle on the current view of electrons in atoms. Identify the relationships among a hydrogen atom’s energy levels, sublevels, and atomic orbitals. Practice Problems Use the words in the box to fill in the blanks below: atomic emission spectrum electron frequencies higher lower energy levels ground state 14. The lowest allowable energy state of an atom is called its _________________________. Honors Chemistry 2 15. Bohr’s model of the atom predicted the _____________________ of the lines in hydrogen’s atomic emission spectrum. 16. According to Bohr’s atomic model, the smaller an electron’s orbit, the _____________________ the atom’s energy level. 17. According to Bohr’s atomic model, the larger an electron’s orbit, the _____________________ the atom’s energy level. 18. Bohr proposed that when energy is added to a hydrogen atom, its __________________________ moves to a higher-energy orbit. 19. According to Bohr’s atomic model, the hydrogen atom emits a photon corresponding to the difference between the ____________________________ associated with the two orbits it transitions between. 20. Bohr’s atomic model failed to explain the _____________________ of elements other than hydrogen. For each item in Column A, write the letter of the matching item in Column B. Column A Column B 21. _______States that it is impossible to know both the velocity and the position of a particle at the same time. a) Heisenberg uncertainty principle 22. _______A three-dimensional region around the nucleus representing the probability of finding an electron. c) Quantum mechanical model b) Schrödinger wave equation d) Atomic orbital 23. _______Originally applied to the hydrogen atom, it led to the quantum mechanical model of the atom. 24. _______The modern model of the atom that treats electrons as waves. 25. How do the Bohr model and the quantum mechanical model of the atom differ in how they describe electrons? Circle the word the makes the statement correct: 26. Each orbital may contain at most (two, four) electrons. 27. All s orbitals are (spherically shaped, dumbbell shaped). 28. There are (three, five) equal energy p orbitals. 29. Hydrogen’s principal energy level 2 consists of (2s and 3s, 2s and 2p) orbitals. 30. Hydrogen’s principal energy level 3 consists of (nine, three) orbitals. Honors Chemistry 3 31. Sketch the 1s and 2p orbitals. How do the 2s and 3p orbitals differ from the 1s and 2p orbitals? 32. Which electron, on average, is closer to the nucleus: an electron in a 2s orbital or an electron in a 3s orbital? 33. According to the quantum-mechanical model for the hydrogen atom, which electron transition produces light with longer wavelength: 2p to 1s or 3p to 1s? 34. What is the maximum number of electrons that can occupy each of the following shells? a. n=1 c. n=3 b. n=2 d. n=4 Section 3 – Electron Configurations: (text pages 298-305) Need to be able to: Apply the Pauli exclusion principle, the aufbau principle, and Hund's rule to write electron configurations using orbital diagrams and electron configuration notation. Practice Problems: Aufbau Principle electron configuration ground-state configuration Hund’s rule lowest Pauli exclusion principle spins stable 35. The arrangement of electrons in an atom is called the atom’s __________________________. Electrons in an atom tend to assume the arrangement that gives the atom the _________________________ possible energy. This arrangement of electrons is the most _________________________ arrangement and is called the atom’s _______________________. Three rules define how electrons can be arranged in an atom’s orbitals. The __________________________ states that each electron occupies the lowest energy orbital available. The _________________________ states that a maximum of two electrons may occupy a single atomic orbital, but only if the electrons have opposite _______________________. ____________________________ states that single electrons with the same spin must occupy each equal-energy orbital before additional electrons with opposite spins occupy the same orbitals. Honors Chemistry 4 36. Write full orbital diagrams and indicate the number of unpaired electrons for each element: a. He d. N3- b. B e. Li c. N f. Li+ 37. Write the full electron configuration for each element: a. Sr b. Ge c. Li d. Zn e. K+ f. Ca2+ 38. Write the noble gas configuration for each element: a. Ga b. As c. Pb d. Cr e. Ff. Al3+ 39. Identify the neutral element with each of the following electron configurations: a. [Ne]3s23p5 b. [Ar]4s23d104p1 c. [Xe]6s2 d. [Kr]5s24d105p3 Honors Chemistry 5 Section 4 – Valence Electrons: (text pages 305-307) Need to be able to: Define valence electrons, and draw electron-dot structures representing an atom's valence electrons. Practice Problems: 40. Indicate the number of valence electrons looking at the full electron configurations of the following elements: a. 1s22s22p63s23p64s23d104p2 c. 1s22s22p63s23p64s23d104p65s2 b. 1s22s22p63s23p5 d. 1s22s22p63s23p64s23d104p6 41. How many valence electrons are in the following elements: a. Sb b. N c. B d. K c. Be d. Se 42. Draw the electron dot structures of the following elements: a. Ba b. Al Section 5 – Periodic Trends: (text pages 307-312) Need to be able to: Identify and understand periodic trends such as atomic size, ionization energy, and metallic character. Practice Problems: 43. Choose the element with the higher ionization energy from each pair: a. As or Bi c. S or I b. As or Br d. S or Sb 44. Arrange the elements in order of increasing ionization energy: Te, Pb, Cl, S, Sn 45. Choose the larger element from each pair: a. Al or In b. Si or N c. P or Pb d. C or F 46. Arrange these elements in order of increasing atomic size: Ca, Rb, S, Si, Ge, F 47. Which is larger, K or K+? Explain why. Which is larger Cl or Cl-? Explain why. 48. Choose the more metallic element from each pair: a. Sr or Sb c. Cl or O b. As or Bi d. S or As Honors Chemistry 6 Name ________________________________________ Date ________________ Class _________________ 9 Chemistry: Matter and Change 7 Copyright © Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc. Study Guide