Chapter 5 The Lipids: Fats and Oils 2010 Cengage-Wadsworth A Primer on Fats • Lipids: a family of compounds that includes: Triglycerides (fats and oils) Phospholipids (lecithin) Sterols (cholesterol) • Obvious sources of fat are oil, butter, margarine, and shortening. • Other foods contributing fat include meat, nuts, mayonnaise, salad dressings, eggs, bacon, gravy, cheese, ice cream, and whole milk. 2010 Cengage-Wadsworth A Primer on Fats • Fats: lipids that are solid at room temperature. • Oils: lipids that are liquid at normal room temperature. 2010 Cengage-Wadsworth Muscles derive fuel from fat. 2010 Cengage-Wadsworth A Primer on Fats • After eating, the body stores some fat as an energy reserve. • The body has unlimited potential to store fat. • Excess carbohydrate and protein can be converted to fat, but they cannot be made from fat. • One pound of body fat is worth 3,500 calories. Within the fat cell, lipid is stored in a droplet. This droplet can enlarge, and the cell membrane will grow to accommodate its swollen contents. 2010 Cengage-Wadsworth Fat droplet Cell membrane Cell nucleus p. 138 A Primer on Fats • Satiety: the feeling of fullness or satisfaction that people feel after meals. Fats slow the rate at which the stomach empties. 2010 Cengage-Wadsworth A Closer View of Fats • Excess energy from the energyyielding nutrients is stored as fat. • The fat is first broken into fragments called fatty acids. Fatty acids: basic units of fat composed of chains of carbon atoms with an acid group at one end and hydrogen atoms attached all along their length. 2010 Cengage-Wadsworth A Closer View of Fats About 95 percent of the lipids in foods and in the human body are triglycerides. • Triglycerides (tryGLISS-er-ides): the major class of dietary lipids, including fats and oils. • A triglyceride is made up of three units known as fatty acids and one unit called glycerol. • Glycerol (GLISS-er-all): an organic compound that serves as the backbone for triglycerides. 2010 Cengage-Wadsworth G l y c e r o l Fatty acid + Fatty acid Fatty acid Glycerol + Fatty acids Triglyceride p. 139 A Closer View of Fats Other members of the lipid family are: •Phospholipid (FOSS-foh-LIP-ids): a lipid similar to a triglyceride but containing phosphorus; one of the three main classes of lipids. Examples include: Lecithin - a major constituent of cell membranes, manufactured by the liver and found in many foods. •Sterols (STEER-alls): lipids with a structure similar to that of cholesterol; one of the three main classes of lipids. Examples include: Cholesterol - one of the sterols, manufactured in the body for a variety of purposes. 2010 Cengage-Wadsworth A Closer View of Fats • Fatty acids differ in the degree of saturation. • Saturation refers to the chemical structure— specifically to the number of hydrogens the fatty acid chain holds. Saturated fatty acids are filled to capacity with hydrogen. Unsaturated fatty acids hold an “empty spot” or point of unsaturation. 2010 Cengage-Wadsworth Saturated vs. Unsaturated Fats • Saturated fatty acid: a fatty acid carrying the maximum possible number of hydrogen atoms (having no points of unsaturation). Saturated fats are found in animal foods like meat, poultry, and full-fat dairy products, and in tropical oils such as palm and coconut. 2010 Cengage-Wadsworth Saturated vs. Unsaturated Fats • Unsaturated fatty acid: a fatty acid with one or more points of unsaturation. Unsaturated fats are found in foods from both plant and animal sources. Unsaturated fatty acids are further divided into monounsaturated fatty acids and polyunsaturated fatty acids. • Monounsaturated fatty acid: a fatty acid containing one point of unsaturation, found mostly in vegetable oils such as olive, canola, and peanut. 2010 Cengage-Wadsworth Saturated vs. Unsaturated Fats • Polyunsaturated fatty acid: (sometimes abbreviated PUFA) a fatty acid in which two or more points of unsaturation occur, found in nuts and vegetable oils such as safflower, sunflower, and soybean, and in fatty fish. 2010 Cengage-Wadsworth Saturated vs. Unsaturated Fats 2010 Cengage-Wadsworth The Essential Fatty Acids • The human body can synthesize all fatty acids except: Linoleic (lin-oh-LAY-ic) acid, linolenic (lin-ohLEN-ic) acid: polyunsaturated fatty acids, essential for human beings. • Essential fatty acid: a fatty acid that cannot be synthesized in the body in amounts sufficient to meet physiological need. 2010 Cengage-Wadsworth Omega-6 vs. Omega-3 Fatty Acids • Omega-3 fatty acids, found in fish oils, offer a protective effect on health. Interest in fish oils was first kindled when someone thought to ask why the Eskimos of Greenland, who eat a diet very high in fat, have such a low rate of heart disease. Blood clot formation, inflammation (e.g. arthritis, asthma), irregular heart rhythm, and cancer also seem to be beneficially affected by DHA and/ or EPA. 2010 Cengage-Wadsworth Something’s Fishy Eating fish at least two times per week as part of a balanced diet can: Reduce blood clot formation ( heart attacks and strokes). Decrease risk of heart arrhythmias. Decrease blood triglycerides. Decrease atherosclerotic plaque formation. Improve health of arteries. Slightly lower blood pressure. 2010 Cengage-Wadsworth A comparison of saturated & unsaturated fatty acids in dietary fats & oils 2010 Cengage-Wadsworth Characteristics of Fats in Foods • Unsaturated fats are more likely to react with oxygen and become rancid. • Food manufacturers may alter fats and oils by: Hydrogenation (high-droh-gen-AY-shun): the process of adding hydrogen to unsaturated fat to make it more solid and more resistant to chemical change. Antioxidant (anti-OX-ih-dant): a compound that protects other compounds from oxygen by itself reacting with oxygen. Emulsifier: a substance that mixes with both fat and water and can break fat globules into small droplets, thereby suspending fat in water. 2010 Cengage-Wadsworth Other Members of the Lipid Family Phospholipids… • Important components of cell membranes. • Can serve as emulsifiers in the body, joining with both water and fat. • Also used in foods such as margarine, chocolate, salad dressings, and frozen desserts to keep the fats dispersed. • Widespread in foods. 2010 Cengage-Wadsworth Other Members of the Lipid Family Sterols such as cholesterol… Sterols such as cholesterol have a multiple-ring structure. • Incorporated as an integral part of the structure of cell membranes. • Used to make bile for digestion. • Used to make sex hormones (estrogen and testosterone). • Made into vitamin D. • Deposited in the artery walls, leading to plaque buildup and heart disease. 2010 Cengage-Wadsworth How the Body Handles Fat • Lipoproteins (LIP-oh-PRO-teens): clusters of lipids associated with protein that serve as transport vehicles for lipids in blood and lymph. The four main types of lipoproteins are: 1. 2. 3. 4. Chylomicron (KIGH-loh-MY-cron): a type of lipoprotein that transports newly digested fat—mostly triglyceride—from the intestine through lymph and blood. VLDL (very-low-density lipoprotein): carries fats packaged or made by the liver to various tissues in the body. LDL (low-density lipoprotein): carries cholesterol (much of it synthesized in the liver) to body cells. A high blood cholesterol level usually reflects high LDL. HDL (high-density lipoprotein): carries cholesterol in the blood back to the liver for recycling or disposal. 2010 Cengage-Wadsworth The composition of lipoproteins 2010 Cengage-Wadsworth “Good” vs. “Bad” Cholesterol • ATHEROSCLEROSIS: As LDL particles penetrate the walls of the arteries, they become oxidized-LDL and next are scavenged by the body’s white blood cells. • These foam cells are then deposited into the lining of the artery wall. • This process, known as atherosclerosis, causes plaque deposits to enlarge, artery walls to lose elasticity, and the passage through the artery to narrow. 2010 Cengage-Wadsworth Atherosclerosis 2010 Cengage-Wadsworth Smooth muscle layer Artery lining Vessel opening Plaque Normal artery Early injury triggers inflammation* Oxidized LDL Scavenger + oxidized LDL (incorporated into lining of artery as Cholesterol loaded foam cell) Atherosclerosis White blood cell (scavenger) LDL + oxygen White blood cell Muscle cells Accumulation of cholesterolloaded foam cells—plaque formation Fig. 5-6, p. 147 2010 Cengage-Wadsworth Nourish the Heart 1. Become a savvy supermarket shopper. 2. Keep blood cholesterol at or below the recommended levels. 3. Balance energy intake with energy needs. 2010 Cengage-Wadsworth Checking Out the Food Label for Fat Information • Total fat refers to all the fat in the food: saturated, monounsaturated, polyunsaturated, and trans fat. • Total fat, saturated fat, trans fat, and cholesterol information are required on the label. • Listing the amount of monounsaturated and polyunsaturated fats is voluntary. 2010 Cengage-Wadsworth Checking out the food label for fat information 2010 Cengage-Wadsworth Fat Can Be Healthy • Use olive oil and other plant oils that are rich in monounsaturated and polyunsaturated fats. • Consume more omega-3 fats. Consider eating fish twice a week as part of a balanced diet. Plant sources of omega-3 fats include soybeans, flaxseed, pecans, and walnuts. • Consume a diet that is lower in saturated fat and higher in complex carbohydrates and fiber. Include more fruits, vegetables, whole-grain breads, and other grains and legumes. 2010 Cengage-Wadsworth 2010 Cengage-Wadsworth Fat Can Be Healthy One place to find omega-3 fats is fish, especially fatty fish like salmon. Nuts are rich in many nutrients and other beneficial substances but are also high in fat. 2010 Cengage-Wadsworth 2010 Cengage-Wadsworth Major sources of saturated fat in the U.S. diet 2010 Cengage-Wadsworth Legumes and nuts 2% High-fat meats (e.g., beef, pork) High-fat dairy products (e.g., whole milk, cheese, ice cream, butter) 20% Eggs 2% 40% 34% Other (fruits, vegetables, grains) 2% Added fats and oils (e.g., shortening, palm oil, coconut oil, palm kernel oil) Fig. 5-8, p. 153 Trans Fatty Acid Controversy • Trans fatty acid: a type of fatty acid created when an unsaturated fat is hydrogenated. Found primarily in margarines, shortenings, commercial frying fats, and baked goods. Trans fatty acids have been implicated in research as culprits in heart disease. 2010 Cengage-Wadsworth Trans Fat Controversy Major sources of trans fatty acids in the U.S. diet 2010 Cengage-Wadsworth Animal products Candy: 1% Breakfast cereal: 1% Cakes, cookies, crackers, pies, bread, etc. 21% 40% Salad dressing: 3% Household shortening: 4% Potato chips, corn chips, popcorn: 5% 17% Fried potatoes: 8% Margarine Fig. 5-10, p. 154 Trans Fat Controversy Compare spreads In 2006, the Food and Drug Administration began requiring that manufacturers list the trans fat content on food labels. 2010 Cengage-Wadsworth Choose Fats Sensibly Choose Fats Sensibly… • Cook and bake with a vegetable oil, such as canola or olive oil, instead of butter, shortening, or margarine whenever possible. • Try reducing fat in recipes a little at a time and use nonstick sprays, fat-free broth or wine in place of butter or margarine. • Refrigerate soups and broth, then skim off the hardened fat. • Prepare lean meats, trim visible fats, remove poultry skin and cook meats so that fats can drain off. • Use herbs, spices, onions or garlic, salsa, lemon juice, or mustard instead of butter, margarine, or oil. Bake, broil, poach, or steam. Season with herbs & spices. 2010 Cengage-Wadsworth Understanding Fat Substitutes • Simplesse®: the trade name for a protein-based, low-calorie artificial fat, approved by the FDA for use in foods such as frozen desserts; cannot be used for frying or baking. • Olestra: an artificial fat derived from vegetable oils and sugar combined in such a way that the body cannot break them down. Sold under the brand name Olean®, olestra does not contribute calories to food. It can, however, prevent absorption of some nutrients. Thus, the FDA requires all products made with it to be fortified with fat-soluble vitamins. 2010 Cengage-Wadsworth Diet & Heart Disease • More than half the people who die in the U.S. each year die of heart and blood vessel disease. • Twin demons that lead to heart disease are: 1. Atherosclerosis: narrowing of the arteries caused by plaque build-up. 2. Hypertension: high blood pressure. 2010 Cengage-Wadsworth A normal artery provides open passage for blood to circulate. Plaques along an artery wall narrow the passage and obstruct blood flow. 2010 Cengage-Wadsworth Leading Risk Factors for Heart Disease • High LDL blood cholesterol level • Low HDL blood cholesterol level • High blood pressure • Cigarette smoking • Obesity • Physical inactivity • Diabetes • An “atherogenic” diet (high in saturated and trans fats, & low in fruits, vegetables, legumes, & whole grains) • Other risk factors cannot be changed: advanced age, male gender, & family history 2010 Cengage-Wadsworth 2010 Cengage-Wadsworth Relationship between blood cholesterol level & death rate from heart disease 2010 Cengage-Wadsworth 2010 Cengage-Wadsworth Diet and Heart Disease • Eat a variety of antioxidant-rich fruits and vegetables. Choose 5 or more daily. • Choose fat-free or low-fat dairy products, such as fat-free milk or low-fat or fat-free yogurt. • Consume abundant legumes of many varieties, including soybeans, kidney beans, and lentils. • Eat a variety of grains, including whole grains. • Choose skinless poultry, lean meat, and fish, especially omega-3 fatty acid-rich fish such as salmon. • Limit intake of foods high in calories and low in nutrition. 2010 Cengage-Wadsworth Diet and Heart Disease • Limit foods high in saturated fat, trans fat, and/or cholesterol, such as full-fat milk products, fatty meats, tropical oils, partially hydrogenated vegetable oils and egg yolks. • Adopt low-fat cooking methods, such as broiling, baking, steaming, braising, and stirfrying. • Eat less than 6 grams of salt (sodium chloride) per day (2400 milligrams of sodium). • Consume alcohol only in moderation, if at all. • Have no more than one alcoholic drink per day (woman) or no more than two drinks per day (man). 2010 Cengage-Wadsworth