Supplementary Material to accompany A Final Exam Review Activity Based on the Jeopardy Format Michael V. Keck Division of Physical Sciences, Emporia State University, 1200 Commercial St., Emporia, KS 66801 Contents Game3 Questions Game3 Answers Game3 Questions Thermochemistry 100 Define a formation reaction. 200 What is the sign of H for an endothermic reaction? 300 State Hess' Law. 400 If it takes 10 J to raise the temperature of a 10 g object by 1 °C, what is the specific heat 500 of the object? Is the reaction H2 (g) -----> 2 H (g) exothermic or endothermic? Atomic Structure 100 Name the three major particles that comprise an atom. 200 The observation of line spectra for atoms is a direct result of ????????? 300 Which quantum number defines the energy of the electron in a hydrogen atom? 400 Which orbitals are partially filled for the transition metals? 500 Name the quantum numbers required to completely specify an electron. The Periodic Table 100 The first periodic tables were constructed on the basis of ???????? 200 Which element in period 3 has the highest ionization energy? 300 Which group on the periodic table has an s2p5 valence electron cofiguration? 400 Which element has the larger second ionization energy, Na or Mg? 500 Which has the larger atomic radius: S, Cl, F ? 2 Bonding 100 In one sentence, describe the difference between an ionic bond and a covalent bond. 200 Which is the most electronegative element on the periodic table? 300 The driving force which allows ionic solids to be stable is called ??? 400 Jeopardy Challenge: Send one member of the team to the board to draw the Lewis dot structure of PCl3. 500 What is the electron geometry about an atom that is sp3 hybridized? Liquids and Solids 100 Which is larger, Hvap or Hfus? 200 Name two types of unit cell. 300 What property of a liquid is defined as a resistance to increase in surface area? 400 Define the boiling point of a substance. 500 Consider water and ammonia, both at 25 °C. Which has the greater vapor pressure? Strong Acids and Bases 100 The algebraic definition of pH. 200 300 The pH of a 0.010 M hydrobromic acid solution. Definition of the Kw , and its numerical value at 25 °C. 400 Concentration of hydroxide ion in a solution of pH 13.0. 500 The pH at the endpoint of a strong acid/strong base titration. 3 Answers to Game3 Questions Thermochemistry 100 the formation of a compound from the elements in their standard states 200 positive (+) 300 For any reaction which can be considered as the sum of two or more other reactions, the enthalpy change for the overall reaction is the sum of the enthalpy changes for each of the individual steps. 400 1 J / g·K 500 endothermic Atomic Structure 100 proton, neutron, electron 200 quantization of energy 300 principle quantum number (n) 400 d orbitals principle (n), angular momentum (l), magnetic (ml), spin (ms) 500 The Periodic Table 100 trends in chemical reactivity 200 argon 300 halogens (also refered to as group 17 or group VII A) 400 Na 500 Sulfur 4 Bonding 100 covalent bond -- shared electrons; ionic bond -- electron transfer and electrostatic attraction 200 Fluorine 300 Lattice energy 400 Cl P Cl Cl 500 tetrahedral Liquids and Solids 100 Hvap 200 simple cubic, body centered cubic, face centered cubic 300 surface tension 400 temperature at which vapor pressure equals atmospheric pressure 500 ammonia (weaker intermolecular forces) Strong Acids and Bases 100 -log[H+] 200 300 2.0 Kw=[H+][OH-] = 1.00 x 10-14 (could also be Kw = Ka x Kb) 400 0.10 M 500 7.00 5