CHARACTERIZING AND IDENTIFYING THE ERUPTIVE SOURCE OF THE SOLDIER MEADOW TUFF IN NORTHWESTERN NEVADA Julie A. Smith B.S., University of California, Davis, 2007 THESIS Submitted in partial satisfaction of the requirements for the degree of MASTER OF SCIENCE in GEOLOGY at CALIFORNIA STATE UNIVERSITY, SACRAMENTO SUMMER 2011 CHARACTERIZING AND IDENTIFYING THE ERUPTIVE SOURCE OF THE SOLDIER MEADOW TUFF IN NORTHWESTERN NEVADA A Thesis by Julie A. Smith Approved by: __________________________________, Committee Chair Dr. Brian P. Hausback __________________________________, Second Reader Dr. Lisa Hammersley __________________________________, Third Reader Dr. Christopher D. Henry ____________________________ Date ii Student: Julie A. Smith I certify that this student has met the requirements for format contained in the University format manual, and that this thesis is suitable for shelving in the Library and credit is to be awarded for the thesis. __________________________, Department Chair ___________________ Dr. David Evans Date Department of Geology iii Abstract of CHARACTERIZING AND IDENTIFYING THE ERUPTIVE SOURCE OF THE SOLDIER MEADOW TUFF IN NORTHWESTERN NEVADA by Julie A. Smith The Soldier Meadow Tuff (SMT) consists mostly of a voluminous sheet of distinctive phenocryst-rich comendite ash-flow tuff distributed around the eastern to southern margin of the High Rock caldera (HRC), source of the 16.3 Ma Summit Lake Tuff. The SMT is a lithologically complex single cooling unit composed of several repetitions of planar and cross-bedded surges, lag-breccias, and massive lithofacies. Stratigraphic repetition of these deposits suggests the SMT erupted in several, closely-spaced pulses, each of which developed eruption columns and column collapses. The HRC is the likely source of the SMT, which erupted approximately 16.1 Ma. The ash-flow sheet of the SMT thins away from ring fracture vents, and pumice imbrications and surge deposits indicate southeast flow away from the HRC. Eruption of the SMT may have caused additional caldera collapse as indicated by aeromagnetic lows in the southeastern part of the HRC. Collinear trends of major element-oxides, trace elements, and rare earth elements genetically link Summit Lake Tuff, Soldier Meadow Tuff, Soldier Meadow lavas, and postSoldier Meadow pyroclastic and lava units to a common magmatic source, likely a continental tholeitte. The magma evolved through typical crystal fractionation processes. _______________________, Committee Chair Dr. Brian P. Hausback _______________________ Date iv ACKNOWLEDGMENTS I extend great gratitude to my advisor, Dr. Brian Hausback, of California State University, Sacramento, for his support and guidance since we started this project in 2009. Dr. Hausback has demonstrated the attributes of a remarkable geologist in the field, laboratory, and classroom. He has been a great companion in the field, and I thank him for the all the great memories and experiences from one of the most beautiful and geologically fascinating places I have visited. I also express thanks to Dr. Christopher Henry of the Nevada Bureau of Mines and Geology at University of Nevada, Reno, for his insurmountable contributions to this project. Dr. Henry has generously provided geochemical data and Ar/Ar dates for samples he collected prior to my involvement in this project. Much of the data and interpretations of this project come from insightful discussions with Dr. Henry. Also, I thank Richard Hilton of Sierra College for his contributions to field work, as well as his continued support and guidance. It has been very rewarding conducting field work with Dr. Henry and Richard Hilton and I appreciate their dedication to this project. Additionally, I would like to thank Robin Wham for her voluntary position as my field assistant. Her enthusiasm and geologic curiosity are respectable traits that inspired me in the field. I thank her for the many great memories we shared on our trips. I extent great thanks to my thesis committee: Dr. Brian Hausback, Dr. Lisa Hammersley, and Dr. Christopher Henry, for their time, patience, and guidance in reviewing my work. Finally, I give immense thanks to my family and friends. I appreciate their continued love and support that helped me to achieve my goals. This project was mostly funded by the United States Geological Survey EDMAP cooperative mapping program in early 2010. Funding from EDMAP covered expenses for field work, as well as XRF and ICP-MS geochemical analyses conducted at the GeoAnalytical Laboratory at Washington State University. I give thanks to the staff at the GeoAnalytical Laboratory for their time and effort into analyzing my samples. Additional funding originated from the Jack Kleinman Memorial Fund for Volcanic Research Scholarship in 2009, awarded by the Community Foundation for Southwest Washington in collaboration with the Cascades Volcano Observatory. Funding was also received in 2009 from the Northern California Geological Survey Scholarship. This funding helped with field expenses for my first field season in High Rock caldera in summer 2009. v TABLE OF CONTENTS Page Acknowledgments..................................................................................................................... v List of Tables ........................................................................................................................ viii List of Figures .......................................................................................................................... ix Illustrations ................................................................................................................................ x Chapter 1. INTRODUCTION ................................................................................................................. 1 Previous Studies and Proposed Calderas ...................................................................... 3 Geologic Setting .......................................................................................................... 7 Regional Geology ............................................................................................ 7 High Rock Caldera Complex ........................................................................... 7 Development of the Basin and Range Province .............................................. 9 2. METHODS .......................................................................................................................... 10 3. RESULTS ............................................................................................................................ 12 Geologic Mapping – Stratigraphy of Volcanic Units in the Eastern HRC ................. 12 Summit Lake Tuff .......................................................................................... 12 Rhyolite Lava................................................................................................. 12 Soldier Meadow Tuff ..................................................................................... 15 Soldier Meadow Lavas .................................................................................. 20 Bedded Sequence of Intermediate-Silicic Pyroclastic Deposits .................... 22 Rhyolite Lavas and Domes ............................................................................ 23 Basaltic Andesite to Dacite Lavas and Dikes ................................................ 24 Petrography ................................................................................................................. 25 Geochemistry .............................................................................................................. 32 XRF Analyses of Major and Trace Elements ................................................ 32 ICP-MS Analyses of Rare Earth Elements .................................................... 50 4. DISCUSSION ...................................................................................................................... 54 Mapping Interpretations .............................................................................................. 54 Eruptive Model for the Soldier Meadow Tuff ............................................................ 57 Geochemical and Petrological Interpretations ............................................................ 64 vi 5. CONCLUSIONS.................................................................................................................. 68 Appendix A. Methods ............................................................................................................ 71 Geologic Mapping................................................................................ 71 Petrographic Analysis .......................................................................... 71 Geochemical Analysis.......................................................................... 73 Ar/Ar Dating ........................................................................................ 74 Appendix B. Petrography of the High Rock Caldera Volcanic Suite .................................... 76 Appendix C. XRF Data: Major Element Oxides of the High Rock Caldera Volcanic Suite ..... ....................................................................................................................... 86 Appendix D. XRF Data: Trace Elements of the High Rock Caldera Volcanic Suite ............ 91 Appendix E. ICP-MS Data of the High Rock Caldera Volcanic Suite .................................. 95 References ............................................................................................................................. 100 vii LIST OF TABLES Page 1. Table 1 Radiometric Dating of the High Rock Caldera Volcanic Suite ....................... 13 2. Table 2 Petrography of the High Rock Caldera Volcanic Suite ................................... 25 viii LIST OF FIGURES Page Figure 1. Figure 1 Location map of the HRCC and Yellowstone hot spot track ............................... 2 2. Figure 2 Location map of the calderas of the HRCC. ......................................................... 6 3. Figure 3 Map of geographic features of the High Rock caldera ....................................... 14 4. Figure 4 Proximal lithofacies of the Soldier Meadow Tuff .............................................. 18 5. Figure 5 Massive lithofacies of the Soldier Meadow Tuff ............................................... 19 6. Figure 6 Coarse-grained Soldier Meadow Tuff ................................................................ 28 7. Figure 7 Fine-grained Soldier Meadow Tuff .................................................................... 28 8. Figure 8 Total alkalis vs. silica of the High Rock caldera volcanic suite ........................ 33 9. Figure 9 Agpaicity Index (AI) vs. silica of the High Rock caldera volcanic suite ........... 34 10. Figure 10 Harker variation diagrams of major element oxides......................................... 38 11. Figure 11 Trace element plots of the High Rock caldera volcanic suite .......................... 44 12. Figure 12 Spider diagram of rare earth elements .............................................................. 51 13. Figure 13 TiO2 – Y/Nb discrimination diagram ............................................................... 53 14. Figure 14 Statigraphic deposits of a complete eruption episode....................................... 58 15. Figure 15 Eruptive model for the Soldier Meadow Tuff .................................................. 63 ix ILLUSTRATIONS Page Plate 1. Plate 1 Geologic Map of the Southeastern Part of the High Rock Caldera, Northwestern Nevada ................................................................................................................... in-pocket 2. Plate 2 Stratigraphic Section of the Soldier Meadow Tuff: Ampitheatre .............. in-pocket 3. Plate 3 Stratigraphic Section of the Soldier Meadow Tuff: High Rock Peak ........ in-pocket CD-ROM containing pdfs of Plates 1-3................................................................. in-pocket x 1 Chapter 1 INTRODUCTION The High Rock caldera complex (HRCC) in northwestern Nevada is in the oldest part and represents the location of initial impingement of the Yellowstone hotspot plume beneath the western edge of the North American craton around 16.5 Ma (Perkins and Nash, 2002; Castor and Henry, 2000; Figure 1). The High Rock caldera (HRC) is one of four probable calderas in a northeast-aligned series that make up the HRCC, and is infilled and surrounded by numerous rhyolitic tuffs, lavas, and domes. The Soldier Meadow Tuff and Summit Lake Tuff are voluminous peralkaline to mildly peralkaline pyroclastic-flow deposits widely distributed around the HRC, but the source of these outflow sheets and other major ash-flow tuffs and possible source calderas has been controversial. Korringa (Korringa and Noble, 1970; Korringa, 1972; Korringa, 1973) interpreted that the Soldier Meadow Tuff and lava members erupted from a series of north-trending fissures located in Soldier Meadow. Greene and Plouff (1981) suggested the Soldier Meadow Tuff erupted from a buried caldera in the Badger Mountain area northwest of Soldier Meadow. Smith and others (2009; 2010) suggested HRC as a likely eruption source of Soldier Meadow Tuff and related lavas. This study provides detailed mapping, petrographic and geochemical analyses that support HRC as the likely eruption source of the Soldier Meadow Tuff and related lavas. 2 Figure 1. Location map of the HRCC and Yellowstone hot spot track (modified from Perkins and Nash, 2002). The dashed line represents the path of the Yellowstone hot spot track. Dark gray polygons represent silicic volcanic centers; medium gray is the northern Nevada rift zone; black circles illustrate four calderas of the High Rock Caldera Complex (HRCC); HRC – High Rock caldera, which formed 16.33 Ma (Noble et al., 2009); McD – McDermitt caldera.The HRCC likely represents volcanism associate with the incipient Yellowstone hot spot (Perkins and Nash, 2002). 3 PREVIOUS STUDIES AND PROPOSED CALDERAS Field studies by Noble and others (1970) and Korringa (1973) identified numerous ash-flow sheets distributed throughout northwest Nevada. Soldier Meadow Tuff is a distinctive marker unit and named for exposures in Soldier Meadow, east of HRC. Noble and others (1970) and Korringa (1973) described field characteristics and petrography of the Soldier Meadow Tuff and a group of lavas that are petrographically and compositionally- similar to Soldier Meadow Tuff (herein referred to as Soldier Meadow lavas (SM-lavas)). Korringa (1973) suggested the Soldier Meadow Tuff and lava members of middle Miocene age erupted from a linear fissure-vent complex 5 miles north of Soldier Meadow Ranch, herein referred as Korringa vent area (KVA; Figure 2). Greene and Plouff (1981) identified several gravity lows and magnetic anomalies in northwestern Nevada and interpreted them to be associated with calderas. An area centered approximately 30-35 kilometers slightly northwest of Soldier Meadow in the Badger Mountain region has distinct gravity and magnetic minimums (Greene and Plouff, 1981). Greene and Plouff (1981) interpreted this 300 km2 area as the Badger Mountain caldera and the possible eruption source for the Soldier Meadow Tuff and petrographically-similar rhyolite of Badger Mountain. A gravity minimum around Rock Spring Table, northeast of the proposed Badger Mountain caldera, was interpreted to be a smaller (approximately 80 km2) caldera. An area of approximately 250 km2 west of Soldier Meadow displays a magnetic minimum that was interpreted to be a possible caldera (Greene and Plouff, 1981), but gravity data was not available to further support this interpretation. 4 The tuffs of Badger Mountain (TBM) and Alkali Flat (TAF) and the rhyolite of Badger Mountain (TRB) are exposed along the northern margin of HRC near Badger Mountain. These units were initially mapped as Soldier Meadow Tuff by Greene and Plouff (1981) based on lithologic similarities. Park (1983) did detailed mapping in the northern margin of HRC and around the Badger Mountain caldera, and distinguished TBM, TAF, and TRB from the Soldier Meadow Tuff based on geochemical, petrographical, and paleomagnetic data. Geochemical and petrological difference led Park (1983) to conclude that TBM, TAF, and TRB erupted from different vents than that of the Soldier Meadow Tuff. Additionally, TBM has reversed polarity of thermoremnant magnetization (TRM), whereas TAF and Soldier Meadow Tuff have identical TRM directions (Park, 1983). The stratigraphic relation of TBM, TAF, and TRB to other HRC units remains uncertain. Ach and Swisher (1990) named the High Rock caldera complex (HRCC) and defined it as a northeast-aligned series of “nested” calderas that generated local, smallvolume ash-flow tuffs and lavas from ring fractures, including the Soldier Meadow Tuff. Ach and Swisher (1990) suggested that Summit Lake Tuff, a relatively high-volume ashflow tuff in the HRCC, erupted from the proposed Badger Mountain caldera, and did not identify the source of the Soldier Meadow Tuff and related lavas. Noble and others (1970) identified and described the Summit Lake Tuff from exposures in northern Black Rock Range, mapped approximate distributions of the tuff (D.C. Noble’s unpublished map), and did preliminary geochemical analyses on Summit Lake Tuff (Noble et al., 1970). Noble and others (2009) suggested that eruption of this 5 voluminous ash-flow tuff resulted in initial collapse of HRC approximately 16.33 Ma. Detailed geologic mapping by Smith and others (2009; 2010) indicates Soldier Meadow Tuff erupted from the eastern to southern HRC ring-fractures approximately 16.1 Ma, followed by SM-lavas and other post-Soldier Meadow volcanic units. 6 Figure 2. Location map of the calderas of the HRCC (modified from Erwin et al., 2005). The HRCC was defined by Ach and Swisher (1990) as a series of NE-aligned “nested” calderas. Virgin Valley caldera formed 16.30 Ma from the eruption of Idaho Canyon Tuff (Castor and Henry, 2000). High Rock caldera (HRC) formed 16.33 Ma from the eruption of Summit Lake Tuff (Noble et al., 2009). The Soldier Meadow Tuff erupted approximately 16.1 Ma from the SE ring fractures of the HRC (Smith et al., 2009; 2010). The general area of study is illustrated by the gray rectangle and is focused near the southeastern HRC ring fractures. TBM – tuff of Badger Mountain; TRB – rhyolite of Badger Mountain; TAF – Tuff of Alkali Flat; KVA – Korringa vent area (Korringa, 1973). 7 GEOLOGIC SETTING Regional Geology The HRCC lies in Humboldt and Washoe counties in far northwestern Nevada, near 42˚N Latitude and 119˚W Longitude, within the North American Cordilleran complex and west of the Northern Nevada rift zone. Models from Coney and Harms (1984) indicate that during formation of the Cordillera, crustal thickening from largescale thrust faulting resulted in an estimated total crustal thickness of 40 kilometers in northwestern Nevada. Gravitational and various lithospheric processes made the thickened crust structurally unstable above the mantle, and the Cordillera region was intruded with a swarm of plutons in Late Cretaceous time (Wernicke et al., 1987). Wernicke and others (1987) suggest that rising plutons beneath the thick, unstable crust lead to the onset of extensional faulting within the Cordillera Complex during the Eocene epoch, further enabling magma to rise to the surface. Northwestern Nevada experienced strong magmatism in Middle Miocene, coincident with Nevada rift-zone volcanism to the east (Zoback et al., 1994). During this time, volcanism in the HRCC climaxed, creating silicic calderas and widespread ash-flow sheets, such as Soldier Meadow Tuff and Summit Lake Tuff. High Rock Caldera Complex Figure 2 (modified from Erwin et al., 2005) illustrates the approximate outlines of four silicic calderas in the HRCC, located near the Black Rock Range, Pueblo Mountains, and Calico Mountains in Washoe and Humboldt Counties: Virgin Valley, Badger 8 Mountain, High Rock, and Cottonwood caldera, from northeast to southwest, respectively. (Cottonwood caldera has also been referred to as Hog Ranch caldera by Erwin and others (2005). This study uses Cottonwood caldera to avoid confusion with the acronym for High Rock caldera). Approximate ages of the calderas of the HRCC range from 14.5 Ma to 16.5 Ma, based on field relationships and 40Ar/39Ar dating of their associated volcanic units (Hilton, et al., 2008). Virgin Valley caldera formed during the eruption of Idaho Canyon Tuff approximately 16.30 ± 0.06 Ma (Castor and Henry, 2000). Badger Mountain and High Rock calderas were interpreted from gravity and aeromagnetic anomalies from geophysical studies conducted by Greene and Plouff (1981). Mapping studies by Park (1983) further support the hypothesis of a caldera structure near Badger Mountain. Cottonwood caldera has not been studied in detail. Volcanic rocks associated with this caldera are of unknown age. Noble and others (1970) describe the stratigraphy and depositional relationships of the units located within the HRCC from the Black Rock Range in the south to the Pine Forest Range in the north. The oldest outcrops are Lower Miocene olivine basalt lavas, found in the central Black Rock Range, and Middle Oligocene pyroclastic rocks in the southern Calico Mountains, with ages of approximately 31.3 Ma (Bonham, 1969; Noble et al., 1970). Overlying the lower units are Upper Miocene volcanic rocks dating from 16.6 Ma to 16.1 Ma (Perkins and Nash, 2002), including the Summit Lake Tuff, Soldier Meadow Tuff, SM-lavas, and post-Soldier Meadow volcanic units. 9 Development of the Basin and Range Province Despite extensive Basin and Range normal faulting in northwestern Nevada, eruptive products and their field relationships are relatively well preserved. Faults through northwestern Nevada typically express normal motion and generally trend slightly northwest to northeast with high dip angles of 60 to 90 (Korringa, 1973), thus coinciding with regional Basin and Range deformational trends. Attitudes of volcanic units within the northern Black Rock Range show gentle tilting of 5 to 10 degrees to the northwest. Basin and Range deformation in this region began after 15 Ma, but lowtemperature thermochronology in the northern Black Rock Range indicates that the majority of normal faulting in this region occurred after 12 Ma (Lerch et al., 2008). A major fault that has raised the west side of the Black Rock Range above the east side of Soldier Meadow has offset the Soldier Meadow Tuff more than 3,000 feet (Noble et al., 1970). More than 3,000 feet of displacement of volcanic units has been recognized by Willden (1964) in the Pine Forest Range to the northeast of HRC. 10 Chapter 2 METHODS This study included geologic mapping, petrography, geochemical analyses, and Ar40/Ar39 dating analyses. Refer to Appendix A for more thorough mapping, petrographic, and geochemical methods. Detailed geologic mapping was conducted in parts of the Soldier Meadow, Yellow Hills East, Yellow Hills West, and High Rock Lake 7.5 minute quadrangles, and focused on mapping the Soldier Meadow Tuff, Soldier Meadow-type lavas, and other related volcanic rocks (Plate 1). Special attention was given to document contacts, faults, ring fractures associated with caldera margins, eruptive vents, and other important features useful for establishing stratigraphic, structural, and magmatic relationships. Fifty-one standard 30-micron thin-sections were made from these hand samples at California State University, Sacramento. Detailed petrographic descriptions of multiple units were recorded from these thin-sections, including mineralogy, modal percentages, colors, presence of lithic fragments, and textures from volcanic and depositional processes. Whole-rock and pumice samples of ash-flow tuffs, lavas, and dikes representative of igneous activity of the HRC were analyzed by XRF (57 samples) and ICP-MS (24 samples) at Washington State University GeoAnalytical Laboratory (Appendices C, D, and E). Radiometric ages of collected samples were calculated from measured 40Ar/39Ar of sanidine and anorthoclase phenocrysts using an Ar-Ar total fusion method. Radiometric 11 analyses were conducted by Christopher Henry at the New Mexico Geochronology Research Laboratory (NMGRL) (results in Table 1). 12 Chapter 3 RESULTS GEOLOGIC MAPPING – STRATIGRAPHY OF VOLCANIC UNITS IN THE EASTERN HRC Summit Lake Tuff The Summit Lake Tuff does not crop out within the mapping area, but its stratigraphic relationship is important for interpretation of the HRC eruptive sequence. Stratigraphic and age relationships show Summit Lake Tuff is the oldest volcanic unit of the HRC eruptive sequence, and yields an 40Ar/39Ar date of 16.33 ± 0.03 Ma (sample H06-18; Table 1). Summit Lake Tuff is a voluminous ash-flow tuff that is preserved over a 100 km diameter area and is covered to the west (Noble et al., 2009). Exposures are found to the northeast near Summit Lake, to the northwest near Massacre Lake, and beyond McConnel Canyon more than 20 kilometers south of HRC (refer to Figure 3 for geographic locations). Summit Lake Tuff is massive in outcrop and provides no evidence of a cooling break. It is recognized in the field by tabular, columnar-jointed ledges that are commonly reddish-brown to very dark brown. Pumice imbrications in exposures north of Steven’s Camp indicate a flow direction to the northwest, outward from HRC. Rhyolite Lava Rhyolite lava overlies the Summit Lake Tuff along the western HRC ring fractures near Stevens Camp. To the south of HRC, similar rhyolite lava is exposed along 13 the base of tilted fault blocks east of High Rock Lake. Outcrops of rhyolite lava are characterized by sparse (<1% by volume) sanidine phenocrysts. Sample H08-78, collected from rhyolite lava to the north-northeast of Stevens Camp, yields an 40Ar/39Ar date of 16.22 ± .03 Ma (Table 1). Although this particular rhyolite lava does not crop out in the mapping area, 40Ar/39Ar dates and stratigraphic relationships suggest this rhyolite lava may be precursor lava to Soldier Meadow Tuff. TABLE 1. RADIOMETRIC DATING OF THE HIGH ROCK CALDERA VOLCANIC SUITE Map Unit Ttp Tra; lava Age (Ma) Sample Description 14.28 ± .18 - K-Ar of glass in ash-fall horizon, Fly Canyon (Ach et al., 1991) 14.44 ± .18 - K-Ar of plag in ash-fall horizon, Fly Canyon (Ach et al., 1991) 15.71 ± .03 H08-119 Massive rhyolite lava on top of SMT; Little HR Canyon 15.9 ± .04 H08-134 Upper SM lava- Korringa vent area 15.93 ± .07 H08-79 Grassy Rock lava; SM-like lava 16.04 ± .03 H08-123 SM-lava at base of SMT type-locality 15.95 ± .05 H08-130 Soldier Meadow pumice; Korringa vent area 15.86 ± .04 H08-124 Pumice-rich SMT; lowest at Type-locality 16.12 ± .05 H06-112 SMT; base of cuesta; west of SM Ranch Tra 16.22 ± .03 H08-78 Rhyolite lava NE of Stevan's Camp; W-NW ring fracture SLT 16.33 ± .03 H06-18 (anorthoclase); Summit Lake Tuff (top); N of Summit Lake SM-lava SMT Table 1. 40Ar/39Ar (K-Ar where noted) dates of select samples from the High Rock caldera volcanic suite. All reported ages are in millions of years. A (-) symbol indicates that no sample number was reported in the indicated studies. 40Ar/39Ar dates on H08- samples are on sanidine phenocrysts (anorthoclase where noted) and were analyzed by Christopher Henry at the New Mexico Geochronology Research Laboratory. 14 Figure 3. Map of geographic features of the High Rock caldera. The Soldier Meadow Tuff type-locality was defined by Noble and others (1970). Stratigraphic sections were measured at Ampitheatre and High Rock Peak. The geologic mapping area is defined in light gray (Plate 1). The dark gray area is KVA – Korringa vent area (Korringa, 1973). Grassy Rock and South Grassy Rock are ring fracture lavas that are lithologically indistinguishable from SM-lava. TBM – Tuff of Badger Mountain; TRB – rhyolite of Badger Mountain; TAF – Tuff of Alkali Flat. 15 Soldier Meadow Tuff The Soldier Meadow Tuff is distinct in appearance from other volcanic units in the mapping area. Fresh surfaces are typically light bluish gray to dark bluish gray, and weathered surfaces are rusty reddish-brown. Vertical columnar jointing and laterallycontinuous horizontal jointing are common. Two 40Ar/39Ar dates on Soldier Meadow Tuff provide distinctly different apparent ages: 16.12 ± 0.05 Ma (H06-12) from an outcrop west of the Soldier Meadow Ranch, and 15.86 ± 0.04 Ma (H08-124) from the Soldier Meadow Tuff type locality (Table 1). The difference in these ages is outside of normal analytical uncertainty and is one factor that prompted this study. The older age may have been a calibration problem, and there will be dating of all major units again in future studies. The Soldier Meadow Tuff is mostly distributed from the east to the south of the HRC. Northernmost exposures of Soldier Meadow Tuff occur near Upper Warm Springs Canyon and Summit Lake; easternmost exposures are in the Black Rock Range; southernmost exposures are near McConnel Canyon and Willow Creek opal mine; westernmost exposures are in Little High Rock Canyon (nearly due south of HRC). The type locality of the Soldier Meadow Tuff is located west of Soldier Meadow near 41.375º N, -119.261º, and was defined and described by Noble and others (1970). The Soldier Meadow Tuff covers an area greater than 700 km2 with a roughly-estimated volume of 60 km3 calculated from unit distribution from mapping (Noble, D.C., unpublished) and average thickness, varying from 150 m to 30 m. The only exposure of the base of the tuff occurs at the bottom of the Soldier Meadow Tuff type locality, where it overlies an older 16 SM-lava (H08-123). Thick exposures of the Soldier Meadow Tuff occur near the approximated ring fracture locus. The thickest measured exposure (herein termed the “Ampitheatre” section) is a minimum of 157 m approximately 1 kilometer west of Franco Reservoir and 3.5 kilometers south of the Soldier Meadow Tuff type-locality (Figure 3). Detailed stratigraphic sections measured at the Ampitheatre (Plate 2) and near High Rock Peak (Plate 3) illustrate the complexity of the Soldier Meadow Tuff deposits. Three common lithofacies of the Soldier Meadow Tuff repeat stratigraphically through the tuff and include laminated, breccia, and massive ignimbrite deposits. The lithofacies change in thickness and appearance depending on distance from vents. No complete cooling breaks are observed throughout the entire Soldier Meadow Tuff sequence. Laminated deposits of the Soldier Meadow Tuff contain three sub-types of thin layers: fine-grained planar, coarse-grained planar, and cross-bedded. Fine-grained layers typically contain only 10-15% phenocrysts by volume with sizes typically less than 2 mm, and individual layers vary from approximately 1 to 10 cm in thickness. Coarsegrained layers contain from 15-35% phenocrysts by volume. Phenocrysts are commonly up to 3.5 mm diameter. Coarse-grained layers are more abundant than fine-grained layers, and range significantly in thickness from 10 cm up to 3 m. All laminated deposits of Soldier Meadow Tuff are interpreted as surge deposits. Laminated surge deposits of the Soldier Meadow Tuff are generally finesdepleted near the presumed vents and grade into fines-rich deposits in medial distances. Pumice imbrications in near-vent surge deposits at High Rock Peak and near Franco Reservoir indicate flow direction ranging from 170º azimuth (southeast) to 190º azimuth 17 (southwest) (Figure 4 (a)). Finer-grained surges west of Soldier Meadow Ranch exhibit low-angle cross-bedding with flow direction towards 162º azimuth to 165º azimuth (southeast), away from the southeastern HRC ring fractures (Figure 4 (b)). Laminated surge deposits are interpreted to be proximal, near-vent facies that typically occur less than 4 km from the ring fractures. Soldier Meadow Tuff breccia deposits contain up to 80% by volume lithic clasts. Sizes of the clasts range from a few centimeters up to 1.5 m diameter near the base of the Soldier Meadow type-locality proximal to the eastern HRC ring fracture. Figure 4 (c) shows breccia deposits that are stratigraphically above surge deposits at the High Rock Peak section, close to the approximate HRC ring fracture (Figure 4 (c); Plate 2 and Plate 3). The breccias are interpreted as lag deposits produced by Soldier Meadow pyroclastic flows, and are proximal facies that mostly occur less than 4 km from the ring fractures. Massive Soldier Meadow Tuff deposits (Figure 5) are typically medium- to coarsegrained and characterized by 25-60% crystals by volume. Individual flow-unit bedding planes are difficult to distinguish in these massive deposits, but laterally-continuous horizontal jointing every 2-10 meters is common and likely coincides with flow-unit boundaries. The massive Soldier Meadow Tuff lithofacies forms deposits over 100 meters thick in medial to distal locations (i.e. more than 4 km) from the eastern to southern ring fractures of the HRC. Columnar jointing is common in most massive outcrops, and eutaxitic foliation of fiamme structures indicates a strong-degree of welding. The massive, columnar-jointed character of the tuff likely formed as a result of ponding in topographically low-lying areas. 18 Figure 4. Proximal lithofacies of the Soldier Meadow Tuff. Proximal distances are generally < 4 km distance from the HRC southeastern ring fractures. (a) Surge beds with pumice imbrications near Franco Reservoir indicate flow direction of the Soldier Meadow Tuff to the southeast, away from the HRC ring fractures; flow is left to right in the photo. (b) Surge deposits with low-angle cross bedding west of Soldier Meadow Ranch. Surge beds are fine-grained consisting of less than 15% crystals by volume. Flow direction of the Soldier Meadow Tuff is to the southeast, away from the HRC ring fractures; flow is left to right in the photo. (c)Below the dashed black line are low-angle cross-bedded surge deposits, overlain by Soldier Meadow Tuff breccia. Surges and breccias repeat throughout stratigraphy. This photo is from the thick section of Soldier Meadow Tuff at High Rock Peak. 19 Figure 5. Massive lithofacies of the Soldier Meadow Tuff. Massive of Soldier Meadow Tuff generally crops out in distal areas (> 4 km) from the southeastern ring fractures of the HRC. Mild to moderate columnarjointing is common.These deposits likely formed as pyroclastic density currents slowed away from the vent, and ponding may have occurred in some areas. (Top) Massive Soldier Meadow Tuff just east of High Rock Lake. Soldier Meadow Tuff is tabular and mildly columnar-jointed. The exposed upper ledge is approximately 5 m in thickness. (Bottom) Southernmost exposures of Soldier Meadow Tuff near Willow Creek Opal Mine. This outcrop expresses mild columnar joints and laterally continuous horizontal joints, probably indicating boundaries of individual pyroclastic density current flow units. 20 Soldier Meadow Lavas SM-lavas are a group of lavas with minor inter-lava tuffs that have a similar phenocryst assemblage and composition as Soldier Meadow Tuff. The SM-lava group includes lavas of the Korringa vent area (KVA; Korringa, 1973), SM-lava at the base of the Soldier Meadow Tuff type locality, lavas directly above the Soldier Meadow Tuff just north of Ampitheatre, SM-lava at Grassy Rock along the western ring fracture, and SMlava south of Grassy Rock. All SM-lavas are likely HRC ring-fracture lavas. A highlysilicified lava in the HRC interior is petrographically similar to SM-lavas, consisting of approximately 20% (by volume) phenocrysts of sanidine, quartz, and minor arfvedsonite. However, the stratigraphic relationship of this interior lava to the SM-lavas and rhyolite lavas of Badger Mountain (TRB) are unknown. The SM-lavas contain abundant sanidine and quartz phenocrysts with minor arfvedsonite and rare iron-rich clinopyroxene. In outcrop, SM-lavas are rusty reddishbrown in color on weathered surfaces and light to medium grayish-blue on fresh surfaces. Korringa (1973) described and mapped in detail SM-lavas that crop out northwest of Soldier Meadow Ranch. Here, a prominent linear vent area (KVA) is evident from radial flow patterns in SM-lava defined by concentric ogives away from five or more northaligned vents. Korringa (1973) mapped SM-lava at the base of the section, with a pumice-rich, poorly-welded tuff directly above. This tuff layer is interpreted in this study to be Soldier Meadow Tuff (sample H08-130). Directly above the Soldier Meadow Tuff is the upper SM-lava of this section. Noble and others (1970) reported that the tuff and 21 lower and upper lavas were emplaced very closely in time since is no evidence for a cooling break between the tuff and lavas. Most SM-lavas overlie the Soldier Meadow Tuff, but one underlies the tuff at its type locality. No evidence of a cooling break at contacts between SM-lavas and the Soldier Meadow Tuff outside of the KVA further supports that these lavas erupted shortly after the tuff. Two outcrops of SM-lava lay directly above the Soldier Meadow Tuff approximately 1.5 kilometers northwest of Franco Reservoir. An intrusion of Soldier Meadow mineralogy crops out approximately 1.4 kilometers east of the Soldier Meadow Tuff type locality, and has a general northeast trend parallel to the HRC eastern ring fractures. This intrusion may be a feeder dike for a subsequently eroded SM-lava. Sanidine from four samples of SM-type rocks using the 40Ar/39Ar method (Table 1). The lava that underlies Soldier Meadow Tuff at the type locality yielded 16.04 ± 0.03 Ma. A single pumice fragment from the inter-lava tuff in the SM-lava sequence from the KVA yielded an age of 15.95 ± 0.05 Ma (sample H08-130), and the uppermost lava in that sequence yielded 15.90 ± 0.04 Ma (sample H08-134). SM-lava at Grassy Rock yielded an age of 15.93 ± 0.07 Ma. Thus, these ages are consistent, with all post-Soldier Meadow Tuff lavas being indistinguishable in age from Soldier Meadow Tuff itself. The analytical uncertainties are consistent with the post-Soldier Meadow Tuff lavas being as much as many tens of thousands of years younger than the Soldier Meadow Tuff. 22 Bedded Sequence of Intermediate-Silicic Pyroclastic Deposits A sequence of unwelded to slightly-welded bedded pyroclastic deposits (Ttp map unit) directly overlies the Soldier Meadow Tuff (Plate 1) and is exposed from the eastern to southern margins of the HRC, as well as in the southeastern HRC interior. This pumiceous sequence ranges from andesite to rhyolite in composition and contains sparse (1-10% by volume) phenocrysts of sanidine, plagioclase, quartz, hornblende, and biotite. Near the ring fractures, accretionary lapilli indicate hydrovolcanic eruptions that were subaqueous or that interacted with water-saturated material. Accidental lithics are abundant and typically composed of aphyric rhyolite lava and Soldier Meadow Tuff. Blocks of densely-welded Soldier Meadow Tuff measure up to 3 meters in diameter and are commonly found in areas proximal to Ttp eruption vents along the eastern to southern ring fractures (Smith et al., 2010). The locations of abundant Soldier Meadow blocks are illustrated by small blue dots on the geologic map (Plate 1). In addition, Soldier Meadow blocks are found in Ttp in High Rock Canyon (west of the southern mapping boundary). Bomb sag structures in Ttp bedding at the base of some of the Soldier Meadow Tuff blocks indicate the blocks were balistically-ejected and probably not transported far from source. Slight imbrications in glassy dacitic ribbon bombs (sample JS10HR-135A) in layers south of Buck Springs indicate transport direction to the south-southeast away from the HRC. In outcrops at Fly Canyon and the Fly Canyon tributary to the east, Ttp contains layers of gray and white glassy ash-fall, dark gray to black scoria, and brown lahar deposits with occasional mammal bones. Merriam (1910a; 1910b; 1911), Stirton (1939), 23 and Swisher (1992) described the vertebrate fauna in the fossiliferous horizon of Ttp at Fly Canyon. According to Noble and others (1987), the fossils from Fly Canyon are contained in bedded and reworked tuff, largely of rhyolitic composition, that overlies the Soldier Meadow Tuff. Swisher (1992), reports that the beds directly above Soldier Meadow Tuff at Fly Canyon date to 16.12 ± 0.025 Ma. Swisher (1992) reported K-Ar ages of 14.48 ± 1.12 Ma, 14.28 ± 0.36 Ma, and 14.49 ± 1.14 Ma on biotite, glass, and plagioclase, respectively, from a single sample of tuff approximately 25 feet above the fossil-bearing beds. At the top of this sequence is a 1-2 meter-thick, brick-red, resistant layer of foliated, fused tuff that was heated and compressed during emplacement of overlying basaltic andesite to dacite lava (Tad map unit). This fused tuff layer acts as a marker bed for Ttp and makes for easy identification of this unit in the field (Plate 1). Rhyolite Lavas and Domes Sparsely porphyritic rhyolite lava and domes (Trd map unit) locally intrude Ttp and crop out along eastern ring fractures near Buck Springs and Chukar Gulch. Massive rhyolite domes also crop out along southern ring fractures in High Rock Canyon. The rhyolite domes are flow-foliated and commonly display well-developed columnar joints. They contain less than 1% sanidine phenocrysts that are up to 3 mm in length. The rhyolite domes are coeval with Ttp since they intrude and are also locally overlain by pumiceous tuff of Ttp (Ach et al., 1991). It is possible the rhyolite domes may have filled Ttp eruption vents. 24 Basaltic Andesite to Dacite Lavas and Dikes Thick basaltic andesite to dacite lavas cap the Soldier Meadow Tuff-Ttp sequence from the eastern to southern parts of the HRC (Tad map unit, Plate 1). The lavas erupted from the eastern to southern HRC ring fractures and mainly flowed northwest into the caldera interior, while some lavas flowed outward of the HRC near Chukar Gulch and west of Warm Springs Canyon. The overall unit averages 50 to 100 meters thick, with a maximum exposed thickness of 240 meters (Ach et al., 1991). On fresh surfaces, the lavas are dark gray to black with a glassy groundmass. Weathered surfaces have iron oxidation and are dark purple-brown. Outcrops are dense and massive with vesicular zones primarily in the upper parts. Tad lavas are typically aphyric to crystal-poor with up to 2% plagioclase phenocrysts that measure less than 3 mm diameter. Near vents, Tad lavas contain rare lithic clasts of Soldier Meadow Tuff measuring from a few centimeters up to 5 centimeters across. Local eruptive centers for Tad lavas (Tac map unit, Plate 1) are characterized by spatter and scoriaceous lava mounds that are commonly rusty red to brick red. Tac eruptive vents commonly contain lithic clasts of Soldier Meadow Tuff that range from a few centimeters up to 12 cm in diameter. The margins of most Soldier Meadow Tuff lithics are partly melted from heating in Tac vents that likely ranged from 1,000º- 1,200º C. Tac eruptive centers appear to be concentrated along the southeastern ring fractures of the HRC. Aphyric basaltic andesite feeder dikes (Td) for Tad lavas intruded through Ttp and Soldier Meadow Tuff. The Td dikes are steep with northeast preferential orientations and may roughly define the eastern to southern HRC ring fractures (Smith et al., 2010). 25 PETROGRAPHY Detailed petrographic descriptions of 51 samples from within and around the HRC are recorded in Appendix B. Descriptions include phenocryst assemblage, modal percentages, groundmass content, and textures. Table 2 lists a brief overview of phenocryst assemblage and average modal percentages of the lithologies sampled. TABLE 2. PETROGRAPHY OF THE HIGH ROCK CALDERA VOLCANIC SUITE Unit Trd Phenocryst % Phenocrysts (by volume) Major phenocryst size (mm) ≤1 san up to 3 mm Tad lava & Td-dikes <1 plag < 1 mm Ttp 1-5 san, qtz, plag < 2 mm SM-lava, Grassy Rock 15-20 san, qtz, arfved* 0.5 – 4 mm SM-lava; SM-dike 10-25 san, qtz, arfved* 1.5 – 4 mm SMT-fine 10-15 san, qtz, arfved* 0.5 – 2 mm SMT-coarse 15-35 san, qtz, arfved* 0.5 – 3.5 mm SMT-breccia 15-35 san, qtz, arfved* 0.5 – 3.5 mm SLT 15-25 anorth, cpx*, amph*, bt* 0.5 – 3 mm * Accessory phenocrysts not included in phenocryst size. TABLE 2. Generalized petrography of the High Rock caldera volcanic suite. Phenocryst percent and sizes were estimated and averaged from petrographically-similar thin-sections of each unit. Abbreviations: san – sanidine; plag – plagioclase; qtz – quartz; arfved – arfvedsonite; anorth – anorthoclase; cpx – clinopyroxene; amph – amphibole; bt – biotite. 26 Petrographic observations of Summit Lake Tuff samples H08-136, H08-137, H09-12A and H09-13 (refer to Appendix B) are similar to previously reported descriptions by Noble and others (1970), Korringa (1973), and Park (1983). Summit Lake Tuff includes 15-25% phenocrysts by volume, mainly anorthoclase (3 mm) that commonly display grid-iron twinning. Minor phenocrysts of clinopyroxene, amphibole and biotite are usually less than 1 mm diameter and are most common in the groundmass. Light-colored volcanic lithics of intermediate composition are less than 1% abundance and range from 1-5 cm in diameter (Park, 1983). The groundmass is commonly glassy with some minor devitrification in some samples. Moderate welding is indicated by elongated pumice clasts (fiamme) from compaction and retained heat in the ash-flow tuff. Soldier Meadow Tuff, SM-lavas, and Soldier Meadow feeder dike (JS10HR-73) have identical phenocryst assemblages of euhedral sanidine and quartz with minor arfvedsonite (sodic amphibole) (Korringa, 1973; Smith et al., 2009; Smith et al., 2010). Sanidine phenocrysts commonly display blue chatoyancy (adularescence) in hand sample, and have Carlsbad twins in thin-section. A significant percentage of quartz grains are embayed along the crystal margins. In Soldier Meadow Tuff samples, both sanidine and quartz phenocrysts are commonly fragmented, likely due to vesiculation and decompression during highly explosive eruptions (Best and Christiansen, 1997). Phenocryst sizes and percentages vary drastically in each of the Soldier Meadow Tuff lithofacies. Coarse-grained layers and breccia clasts of the Soldier Meadow Tuff contain 15-35% phenocrysts that range up to 3.5 mm in size (Figure 6). Fine-grained Soldier Meadow Tuff layers usually contain only 10-15% phenocrysts with a range from 27 0.5 – 2 mm diameter (Figure 7). Most of the Soldier Meadow Tuff sequence is highlywelded to moderately-welded, as indicated by significantly compacted pumice fragments (fiamme). Unwelded samples JS10HR-93, JS10HR-85, and JS09HR-35, collected from the uppermost parts of the Soldier Meadow Tuff, display vapor-phase arfvedsonite in relatively equant pumice clasts. 28 FIGURE 6. Coarse-grained Soldier Meadow Tuff. Contains phenocrysts of sanidine, quartz, and arfvedsonite. Groundmass contains glass (welded), sanidine, quartz, Fe-Ti oxides, and occasional vapor-phase arfvedsonite. Maximum phenocryst size is 3.5 mm. Field of view is 4.5 mm width at 4x magnification. (a) Plane-polarized light. (b) Crossed-nichols. FIGURE 7. Fine-grained Soldier Meadow Tuff. Contains phenocrysts of sanidine, quartz, and arfvedsonite. Groundmass contains glass (welded), sanidine, quartz, Fe-Ti oxides, and occasional vapor-phase arfvedsonite. Maximum phenocryst size is 2.5 mm. Field of view is 4.5 mm width at 4x magnification. (a) Plane-polarized light. (b) Cross-nichols. 29 In most samples, the groundmass of Soldier Meadow Tuff and SM-lavas is partially devitrified and contains minor amounts of euhedral to subhedral phenocrysts of clinopyroxene, arfvedsonite, and Fe-Ti oxides. Sanidine and quartz microlites are also common in the groundmass. Well-developed acicular vapor-phase crystals of clinopyroxene and arfvedsonite are attributed to the peralkalinity of the Soldier Meadow units. These typically peralkaline minerals of the Soldier Meadow Tuff and lavas distinguish them from the tuffs of Badger Mountain and Alkali Flat, which contain biotite phenocrysts, a typically metaluminous phase (Park, 1983). The Ttp sequence of bedded pyroclastics overlies the Soldier Meadow Tuff and significantly varies in petrography depending on stratigraphic position and geographic location (i.e. distance from vent). Sample JS10HR-87 was collected near the base of Ttp, approximately 1 meter above the top of Soldier Meadow Tuff in the northern Chukar Gulch area west of upper Warm Springs Canyon. This sample is glassy, very pumicerich, and contains approximately 10% phenocrysts of sanidine and quartz. Felsic lithics up to 3 mm in diameter in thin-section contain microlites of sanidine and quartz, although the modal percentages of each are somewhat difficult to determine due to the small sizes. It is likely these lithic fragments are accidental clasts of Soldier Meadow Tuff. Accretionary lapilli are present in the bedded layers close to the presumed ring-fracture vents. Just south of Buck Springs, Ttp is palagonitized. Palagonitization likely developed from hydrothermal alteration in the porous and permeable unwelded sequence. In the Ttp fused tuff marker bed in the uppermost parts of the sequence, sample JS10HR- 30 34 has a highly-welded glassy matrix with plagioclase microlites. This tuff layer was fused by heating and compression from overlying Tad lava. Rhyolite lavas and domes (Trd) that locally intrude Ttp contain sparse phenocrysts of sanidine that measure up to 2.5 mm in length. Rare phenocrysts of amphibole (arfvedsonite?) with brown to green pleochroism may indicate a peralkaline composition. The glassy groundmass contains microlites of sanidine (?) and possibly some quartz, although it is difficult to determine due to the small size. Sparsely porphyritic rhyolite lava (sample H08-119) overlies Soldier Meadow Tuff in Little High Rock Canyon. It is unclear whether this rhyolite lava is related to Trd lavas and domes, but it is indistinguishable from other Trd occurrences mapped in this study. In thinsection, both contain sparse (<1% by volume) sanidine phenocrysts in a glassy, microlitic groundmass. Basaltic andesite to dacite lavas and basaltic andesite dikes (Tad and Td, respectively) are petrographically indistinguishable. Sample JS10HR-39 is a sample from a dike (Td map unit) that intruded through Soldier Meadow Tuff at the top of the “Ampitheatre” stratigraphic section approximately 1 km west of Franco Reservoir. Sparse phenocrysts of plagioclase are less than 2 mm long. The groundmasss is dark gray to black in hand sample and is glassy, nearly opaque in thin section. The groundmass has a microlitic texture with abundant feldspar (likely plagioclase) microlites. Tad lava is also sparsely porphyritic and contains plagioclase phenocrysts less than 2 mm diameter. Rare phenocrysts of clinopyroxene exist in hand specimen and in the groundmass. As in Td 31 dikes, the glassy groundmass of Tad lavas has a microlitic texture with plagioclase microlites set in a nearly opaque groundmass, as observed in thin-section. 32 GEOCHEMISTRY XRF Analyses of Major and Trace Elements XRF analyses of major element oxide and trace element concentrations were conducted on 57 whole rock and pumice samples of the High Rock caldera volcanic suite. (Refer to Appendix C for major element oxide data; Refer to Appendix D for trace element data). A total alkalis versus silica (TAS) diagram (Figure 8), defined by Le Bas and others (1986) and modified by Le Maitre (1989), illustrates the range in compositions of the HRC volcanic suite, which is marginally alkalic, except for the Soldier Meadowrelated eruptive products, which are subalkaline. Summit Lake Tuff is an alkali-rich, lowSiO2 rhyolite, while the Soldier Meadow Tuff and SM-lavas are subalkaline high-SiO2 rhyolites. Post-Soldier Meadow units of bedded pyroclastics (Ttp) and aphyric dikes and lavas (Td and Tad, respectively) are basaltic trachy-andesite to trachydacite. The Agpaicity Index (AI) was defined by Shand (1947) to characterize the alkalinity of volcanic rocks. Agpaitic coefficients of High Rock samples were calculated by dividing the sum of molecular (Na2O + K2O) by molecular Al2O3. Samples with Agpaitic coefficients (AI) greater than one are as peralkaline, and values less than one are metaluminous or peraluminous. All samples of Soldier Meadow Tuff and related tuffs and lavas are peralkaline (Figure 9). Summit Lake Tuff is metaluminous with the exception of the most silicic samples, which are slightly peralkaline (Figure 9). 33 Figure 8. Total alkalis vs. silica of the High Rock caldera volcanic suite. Fields were defined by Le Bas and others (1986) and modified by Le Maitre (1989). The alkaline-subalkaline dividing line (in red) was defined by Irvine and Baragar (1971). Tad-lava – basaltic trachy-andesite to trachydacite; Td-dike – basaltic trachy-andesite; Ttp – trachydacite; Rhyolite group: SM-lava, GR (Grassy Rock); SM- lava, South GR; SM-lava; SM-dike; SMT (Soldier Meadow Tuff); Tr rhyolite lava; SLT (Summit Lake Tuff); TBM (Tuff of Badger Mountain); TAF (Tuff of Alkali Flat). 34 Figure 9. Agpaicity Index (AI) vs. silica of the High Rock caldera volcanic suite. AI is based on the definition by Shand (1947) to describe alkalinity of volcanic rocks. Agpaitic coefficients of High Rock samples were calculated by dividing molecular (Na2O + K2O) by molecular Al2O3. Peralkaline rocks have AI coefficients > 1, whereas metaluminous and peraluminous rocks have AI coefficients < 1. Peralkaline: lava in HRC interior; SM-lava at Grassy Rock (GR); SM-lava at South GR; SM-lava; SM-intrusion (feeder dike); SMT (Soldier Meadow Tuff); Tr rhyolite lava. Metaluminous: Tad-lava; Td-dike; Ttp; SLT (Summit Lake Tuff; northern samples mildly peralkaline). 35 Summit Lake Tuff was sampled at five sections, three north and two south of the HRC. The tuff is a high-SiO2 trachydacite to low-SiO2 rhyolite, with a range from 69% to 72% SiO2. Harker variation diagrams (Figure 10) show decreases in TiO2, Al2O3, FeO*, Na2O, CaO, and MgO and with increasing SiO2. Figure 10 (a) (inset) is a simplified variation diagram with only select samples from stratigraphic sections of the Summit Lake Tuff and Soldier Meadow Tuff. In the Summit Lake section south of Little High Rock Canyon, a basal sample (H09-12A) has intermediate SiO2 (70.3%) and lower TiO2, whereas an upper sample (H09-13) has 68.9% SiO2 and higher TiO2 (Figure 10 (a) inset). Trace element concentrations of the Summit Lake Tuff also vary with stratigraphic position. Compositions vary only slightly at three sections (north of Summit Lake, near Massacre Lake, and in the southeastmost occurrence) but more distinctly at the sections north of Stevens Camp and south of Little High Rock Canyon. For example, four samples, including a basal vitrophyre (H09-35) and three single pumice samples (H09-36, H09-37, H09-38) that represent most of the thickness of the tuff north of Stevens Camp, have nearly indistinguishable compositions. The three single pumice samples are slightly peralkaline. A single pumice (H09-39) from the top of the tuff in the same area has distinctly lower SiO2, K2O, Zr, Nb, Zn, and Y and higher TiO2, FeO, CaO, Sr, and Ba and is distinctly not peralkaline (refer to Appendices C and D for major element oxide and trace element data, respectively). Compositions of Summit Lake Tuff also vary geographically relative to the caldera (Figure 10). Most samples north of the caldera, except the upper pumice sample north of Stevens Camp, are more differentiated and have higher SiO2. Samples south of 36 the caldera, except the basal sample south of Little High Rock Canyon, are less differentiated, with lower SiO2. Indistinguishable geochemical signatures of Tr-rhyolite lava (one sample that stratigraphically underlies the Soldier Meadow Tuff east of High Rock Lake, and one sample collected from northeast of Stevens Camp) to the Soldier Meadow Tuff may indicate that Tr-rhyolite lava might be a related, locally-extruded, precursor lava. 37 Figure 10. Harker variation diagrams of major element oxides. Major element oxides have been normalized to 100 %. Major element oxides (a) TiO2, (b) Al2O3, (c) FeO*, (d) Na2O, (e)CaO, and (f) MgO are plotted against silica. Relatively collinear trends genetically connect the Summit Lake Tuff, Soldier Meadow group, and post-Soldier Meadow units and suggest the magma evolved from typical fractionation processes. Samples of the Summit Lake Tuff consistently show geographic zonation in which northern samples are more evolved than southern samples. (a) Inset: this is a simplified inset showing select basal and upper samples from stratigraphic sections of the Summit Lake Tuff (SLT) and Soldier Meadow Tuff (SMT). Summit Lake Tuff and Soldier Meadow Tuff show vertical zonation in which basal samples are more evolved (i.e. higher silica content and lower major element oxides) and erupted earlier than their stratigraphic upper counterparts. The Summit Lake Tuff section is from a canyon south of Little High Rock Canyon; the Soldier Meadow Tuff section is from upper Warm Springs Canyon. GR – Grassy Rock. 38 Figure 10. (Figure caption on page 37) 39 Figure 10 (cont). (Figure caption on page 37) 40 Figure 10 (cont). (Figure caption on page 37) 41 The Soldier Meadow Tuff is a high-SiO2 rhyolite with a range from 76% to 80% SiO2. It is important to note that 77.4% is generally considered the maximum silica content for an igneous rock (Hildreth, 1981, p. 10154). Silica contents greater than this value are likely due to post-depositional alteration processes, such as silicification. Nevertheless, the more immobile elements, such as TiO2, Zr, and the REEs, can be used to evaluate geochemical characteristics and evolution even in somewhat altered rocks. Soldier Meadow Tuff was sampled at five sections along the eastern to southern margins of the caldera. The Soldier Meadow Tuff, similar to the Summit Lake Tuff, shows notable variations in major element oxide and trace element concentrations through stratigraphy. Total alkali (Na2O + K2O) content ranges from 8.17% to 9.22% (Figure 8), with four of the five sections having higher total alkali concentrations near the base of the tuff compared to poorly-welded samples collected in the top parts of the tuff. Samples JS10HR-33, JS10HR-93, and H08-133 were collected in unwelded, uppermost parts of the Soldier Meadow Tuff. These three samples are consistently higher in concentrations of major element oxides, most notably in Al2O3, CaO, and MgO, and are slightly off-trend from the rest of the Soldier Meadow group. These uppermost samples have relatively low pre-normalized total major element oxide values (90.22%, 91.47%, and 96.92%, respectively), which may reflect post-depositional alteration or hydration of glass. Outliers JS10HR-93 and JS10HR-33 are not included in Figures 9 and 10 due to their low major-element oxide totals (refer to Appendix B for major element oxide data). Despite a somewhat low major-element total for H08-133, this sample plots 42 along the same trend as the Soldier Meadow group in Figures 9 and 10, with the exception of higher MgO concentretation as indicated in Figure 10 (f). Figure 10 (a) (inset) is a simplified inset variation diagram with only select samples from stratigraphic sections of the Summit Lake Tuff and Soldier Meadow Tuff. Figure 10 (a) (inset) illustrates the variations in TiO2 concentrations in Soldier Meadow Tuff samples collected from the base (H09-20) and top (JS09HR-35) of the Soldier Meadow Tuff section in upper Warm Springs Canyon. Additionally, samples collected near the base of all sections consistently have higher concentrations of incompatible trace elements Nb, La, Ce, and Zr (refer to Appendices C and D). Sample H09-20 is a basal vitrophyre sample from the Soldier Meadow Tuff section in Upper Warm Springs Canyon, and has higher concentrations of Ce and La than its upper counterpart, sample H09-23 (Figure 11 (a) and (b)). There are three Soldier Meadow Tuff outliers in Zr and Nb concentrations (for simplification, these samples were not plotted in Figure 11; refer to Appendix D for trace element data). BH08HR-49 and JS09HR-35 are unwelded uppermost Soldier Meadow Tuff whole-rock samples collected near Upper Warm Springs Canyon; H08-130 is a single, frothy pumice from the KVA. Since whole rock XRF analyses were conducted on samples BH08HR-49 and JS09HR-35, it is possible there may have been some lithic inclusions that affected analyses of trace element concentrations. It is difficult to decipher from the available data what alteration or contamination processes could have affected Zr and Nb concentrations of these samples. 43 Stratigraphic variations of major oxide and trace element concentrations suggest the Soldier Meadow Tuff erupted from a vertically-zoned magma chamber in which more-evolved compositions were concentrated in the upper parts of the chamber and therefore erupted earlier in the sequence. Both the Summit Lake Tuff and the Soldier Meadow Tuff display similar stratigraphic chemical variation. Unlike the Summit Lake Tuff, the Soldier Meadow Tuff shows no noticeable geographic variations in composition across its eastern to southern exposures. 44 Figure 11. Trace element plots of the High Rock caldera volcanic suite. In (a) and (b), the constant ratio slopes of Ce vs. La and Nb vs. La, respectively, genetically link the Summit Lake Tuff (SLT), Soldier Meadow units, and post-Soldier Meadow units to a common magma source. Soldier Meadow Tuff (SMT) shows vertical zonation in the Upper Warm Springs Canyon section, in which the base (H09-20) is more evolved than the upper counterpart (H09-23). SMlava outliers indicated with labels may have experienced contamination or post-depositional alteration processes. In (c) and (d), Summit Lake Tuff, Soldier Meadow units, and post-Soldier Meadow units follow a collinear trend and are genetically connected. Summit Lake Tuff shows geographic zonation in which northern samples are more evolved than southern samples. SM-lava outliers are indicated with labels and may have experienced contamination or post-depositional alteration processes. GR – Grassy Rock. 45 Figure 11 (cont). (Figure caption on page 44) 46 Figure 11 (cont). (Figure caption on page 44) 47 Directly overlying the Soldier Meadow Tuff are SM-lavas, with the exception of SM-lava at the base of the Soldier Meadow Tuff type locality. SM-lavas are petrographically very similar to the Soldier Meadow Tuff and have major-element geochemical signatures identical to Soldier Meadow Tuff (Figure 10). SM-lava sample H08-129, collected from the lower SM-lava at KVA, is an outlier in both Ce vs. La and Nb vs. La ratios (Figure 11 (a) and (b)). However, H08-129 plots well with the Soldier Meadow group in both Zr and Nb vs. SiO2 ratios (Figure 11 (c) and (d)). Sample H08134, collected from the upper SM-lava at KVA, is an outlier in Zr and Nb vs. SiO2 ratios (Figure 11 (c) and (d)), but plots well with the Soldier Meadow group in both Ce vs. La and Nb vs. La ratios (Figure 11 (a) and (b)). Sample H08-123 of SM-lava from the bottom of the Soldier Meadow Tuff type locality is significantly higher in Nb concentrations compared to the rest of the Soldier Meadow group. This SM-lava sample, however, plots similarily with the Soldier Meadow group in other trace element concentrations. The SM-lava south of Grassy Rock is notably in higher in Ce, Nb, and Zr concentrations plots outside of the pattern of each of the trace elements plotted in Figure 11. In this study, with the exception of the SM-lava at Grassy Rock, each sample of SMlava is an outlier in one or more trace element concentrations. More analyses need to be conducted to explain the implications of the SM-lava outliers, but simple fractionation processes alone cannot account for these variations. It is possible that contamination, possibly from incorporation of lithic inclusions, or possibly post-depositional alteration processes, affected analyses of trace element concentrations in these SM-lava samples. However, overall patterns of SM-lava petrography and geochemical analyses suggest that 48 SM-lavas are related to the rest of the Soldier Meadow group, and likely represent HRC ring fracture lavas. Post-Soldier Meadow units, including dacitic pyroclastic deposits (Ttp), basaltic andesite dikes (Td) and basaltic andesite to low-silica-dacite lavas (Tad), are not as evolved as the Soldier Meadow Tuff. A lesser degree of fractionation is indicated by the lower silica content, higher concentrations of the compatible oxides TiO2, Al2O3, FeO*, CaO, and MgO (Figure 10), and lower concentrations of the incompatible elements Ce, Nb, La, and Zr (Figure 11). Analyses of the tuffs of Badger Mountain (TBM) and Alkali Flat (TAF) in Figure 11(a) show values in Ce vs. La that are collinear with Summit Lake Tuff and the Soldier Meadow Tuff. However, the trends of the tuffs of Badger Mountain and Alkali Flat in Figure 11 (b), (c), and (d) are not collinear with other High Rock units. Incompatible element concentrations and ratios from the tuffs of Badger Mountain and Alkali Flat generally differ somewhat from other High Rock units, suggesting that there is either no genetic link or a more complex relationship to the magmas of the Summit Lake Tuff and Soldier Meadow Tuff. Trace elements plots are useful for evaluating genetic relationships between different rock types. The concentration of an incompatible element in the liquid fraction of a magma increases as crystallization proceeds, and the ratio of two or more equallyincompatible elements should remain constant as crystallization proceeds. If the ratio plot of two incompatible elements is linear, then all samples are likely related to a single magma system. If the ratio of incompatible elements for the samples lie along parallel but 49 not collinear trends, this could indicate crystallization of rocks from magmas that had different ratios of the incompatible elements. Trace element plots were used to interpret genetic relationships of the Summit Lake Tuff, Soldier Meadow Tuff, SM-lavas, post-Soldier Meadow units, and the tuffs of Badger Mountain and Alkali Flat (Figure 11 (a-d)). Incompatible-element pairs Ce vs. La and Nb vs. La were used to compare ratio trends between these units in Figures 11 (a) and (b), respectively. These trace elements are fairly immobile and not prone to drastic changes in concentrations during alteration. In Figures 11 (a) and (b), the Summit Lake Tuff, Soldier Meadow Tuff, and post-Soldier Meadow groups plot on a collinear trend. Incompatible elements Zr and Nb (Figure 11 (c) and (d), respectively) increase linearly as the degree of magma fractionation increases. For Summit Lake Tuff samples, basal samples of northern exposures have higher Zr and Nb concentrations, and upper samples from southern exposures have the lowest Zr and Nb concentrations. The vertical and geographic variations in Zr and Nb concentrations further suggest the Summit Lake Tuff erupted from a zoned magma chamber, with earlier eruptions occurring in the north. With the exception of the previously discussed Soldier Meadow Tuff and SMlava outliers, ratio-slopes for Summit Lake Tuff, Soldier Meadow Tuff, SM-lavas, Ttpbedded pyroclastics and younger dikes and lavas follow curvilinear trends on major element oxides and trace element plots.The curvilinear trend of the Summit Lake Tuff, Soldier Meadow Tuff, SM-lavas, and post-Soldier Meadow units suggests a genetic relationship in which of all these magmatic units evolved from a common parental magma probably more mafic than the Td analyses. 50 ICP-MS Analyses of Rare Earth Elements ICP-MS analyses were conducted on 24 High Rock samples for Rare Earth Element (REE) abundances. For units with multiple analyses, average REE concentrations were calculated. These REE concentrations were normalized to chrondrite abundances from Sun and McDonough (1989) and plotted on a spider diagram (Figure 12). Summit Lake Tuff shows a mildly negative Eu anomaly, also documented by Noble and others (1979). This Eu anomaly is best explained by the fractionation of anorthoclase as Eu readily substitutes for Ca in feldspars, causing a difficiency of Eu within the remaining melt. Figure 12 illustrates a strong negative Eu anomaly for Soldier Meadow Tuff and the Soldier Meadow intrusion (sample JS10HR-73, a feeder-dike for the Soldier Meadow lavas). Post-Soldier Meadow unit Td-dike does not exhibit this Eu anomaly. The relatively constant negative slope from light REE to heavy REE in all samples indicates that the suite of REE, except Eu, had a similar spectrum of incompatibilities in all the HRC magmas, as well as the tuffs of Badger Mountain and Alkali Flat. The tuffs of Badger Mountain and Alkali Flat have even stronger negative Eu-anomalies than the Soldier Meadow Tuff. Additionally, it is important to note the strong negative Eu anomaly of a lava found in the HRC interior (sample BH10HR-23) that is petrographically-similar to SMlava. The REE geochemical signature may suggest a genetic relationship of this lava in the caldera interior to the tuffs of Badger Mountain or Alkali Flat. The lava and tuffs are similar in many trace-element characteristics, but the lava has distinctly higher Ta/Yb and Th/Yb. Additional analyses are required to further characterize this lava. 51 Figure 12. Spider diagram of rare earth elements. REEs are normalized to chrondrite abundances (Sun and McDonough, 1989). The negative slope from light REEs to heavy REEs reflects crystal fractionation processes. SLT shows an Eu depletion from crystallization of anorthoclase. Further fractionation resulted in strong Eu depletion in the magmas for SMT, SM-dike, and Tr rhyo lava. Lava in the HRC interior has a significant Eu anomaly and is likely related to TBM and/or TAF. Abbrev: Td-dike – basaltic-andesite dike; Ttp – bedded pyroclastics; Lava, HRC interior – identifified lava in the High Rock caldera interior; SMT – Soldier Meadow Tuff; Tr rhyo. lava – Tr rhyolite lava; SLT – Summit Lake Tuff; TBM – tuff of Badger Mountain; TAF – tuff of Alkali Flat. 52 Determining the geochemical signature of the parental magma source for the High Rock volcanic suite is difficult because most rocks are highly evolved. A discrimation plot of TiO2 versus Y/Nb for basalts can be used to determine the magma series of the source, with some indication of continental or MORB tectonic settings (adapted from Floyd and Winchester, 1975 and Rollinson, 1993). The discrimination plot is only valid for rocks with low degrees of fractionation, i.e., basalt to andesite compositions. Therefore, data for Td dikes are plotted on the TiO2 – Y/Nb discrimination diagram (Figure 13) to characterize the likely magma origin of the High Rock caldera volcanic suite. The geochemical signatures of these feeder dikes suggest a magma source most related to continental tholeiite, which have higher SiO2, K2O, and light rare earth element concentrations than do oceanic tholeittes (Campbell, 1985). 53 Figure 13. TiO2 – Y/Nb discrimination diagram. Three fields are plotted and overlap in some parts: Alk. (alkali basalt, including continental and ocean-island alkali basalt), Cont. thol. (continental tholeiite), and MORB (Mid-Ocean Ridge Basalt) (adapted from Floyd and Winchester, 1975 and Rollinson, 1993). This discrimination diagram is used to determine the magma series of the source, with some indication of continental or MORB tectonic settings. The discrimination plot is only valid for rocks with low degrees of fractionation, i.e., basalt to andesite compositions. Td-dikes are the least evolved of the High Rock caldera volcanic suite and reflect a magma source most related to continental tholeitte. 54 Chapter 4 DISCUSSION MAPPING INTERPRETATIONS Noble and others (2009) state that the eruption of Summit Lake Tuff induced initial collapse of the HRC at approximately 16.33 Ma. Data used to support this statement included distribution of the Summit Lake Tuff to the northwest, north, east, and south of the HRC, as well as paleocurrent indicators showing flow direction outward from the HRC. Eruption of the Soldier Meadow Tuff occurred at least 200,000 years and possibly as much as 400,000 years after the caldera-forming eruption of the Summit Lake Tuff. Korringa and Noble (1970) and Korringa (1972; 1973) interpreted that the Soldier Meadow Tuff erupted from a linear fissure vent area marked by and underlying the SMlavas in the KVA, but did not indicate any relationship to a caldera structure. Field observations in this study further characterize the Soldier Meadow units and define an eruptive relationship to the HRC. Field data, including unit thicknesses, paleocurrent indicators, clast sizes, lithic inclusions and other deposit characteristics were used to infer the eruptive source of the Soldier Meadow Tuff. The thickest exposures of the Soldier Meadow Tuff occur along the eastern to southern ring fractures of the HRC; however, thickness alone cannot determine an eruptive source due to topographic influences during deposition of ash-flow sheets. Schmincke and Swanson (1967), Mimura and MacLeod (1978), and Kamata and Mimura (1983) report that pumice imbrications can be useful for 55 determining the flow direction of pyroclastic flow deposits. Kamata and Mimura (1983) successfully used data from pumice imbrications to determine flow direction and locate the source of the Handa pyroclastic flow in Japan. In this study, pumice imbrications and surge beds in the Soldier Meadow Tuff indicate a flow direction towards the southeast, away from the southeastern HRC ring fractures (refer to Plate 1). Detailed descriptions of pyroclastic deposits are important for determining distance from source and flow dynamics of ash-flow tuffs. Models of eruptive dynamics of ash-flow sheets (Sparks et al., 1973; Sheridan, 1979; Cas and Wright, 1987; Branney and Kokelaar, 2002) are applied to the Soldier Meadow Tuff depositional facies to interpret flow dynamics and location of the most-likely eruptive source. In general, maximum size of lithics decreases from proximal to distal sites (Branney and Kokelaar, 2002) as the ash-flow sheet loses momentum and carrying capacity. Aguirre-Díaz and Labarthe-Hernández (2003) record lag-breccias in voluminous ignimbrites in the Sierra Madre Occidental that occur in proximal distances to fissure vents. Almost all Soldier Meadow breccia deposits occur in proximal locations to the HRC ring fractures and are not found in distal areas. This suggests the mapped ring fractures of the HRC are the most likely vent sources of the Soldier Meadow Tuff. The SM-lavas erupted soon after the Soldier Meadow Tuff, approximately 15.9 Ma, as indicated by their indistinguishable ages and the lack of a complete cooling break at the contact documented by Noble and others (1970). The SM-lavas are concentrated along the southeastern ring fractures and in the area surrounding Soldier Meadow. Korringa (1973) mapped at least five north-south aligned eruptive vents for SM-lavas 56 north of Soldier Meadow Ranch and east of the HRC topographic rim. Howard (2010) describes four concentric zones of subsidence structures that develop during caldera collapse, with zone 1 located on the caldera floor and zone 4 along the outermost ring fractures. The eruption of Soldier Meadow Tuff may have caused further subsidence of the HRC beyond that formed in the earlier Summit Lake Tuff eruption (Smith et al., 2010). The Soldier Meadow Tuff eruption may have been confined to vents along the southern to eastern margin and likely widened the zone 4 ring-fractures along the southeastern margin of the HRC. As a result, SM-lavas at the base of the type-locality and south of the type-locality erupted near, or just outboard, of primary ring fractures of the HRC (Plate 1). The Soldier Meadow dike also intruded along the HRC ring fractures. SM-lavas of the KVA (Korringa, 1973) in Soldier Meadow likely erupted along peripheral ring fractures of the HRC just east (outboard) of the inferred HRC ring fractures (Plate 1). SM-lava at Grassy Rock erupted along western HRC ring fractures, perhaps synchronously and from the same magma source as the SM-lavas of the southeastern ring fractures. This signifies that the magma source for the Soldier Meadow Tuff and SM-lavas was located under at least the southern half of the HRC. Explosive eruptions continued after extrusion of Soldier Meadow Tuff and lavas, resulting in a thick sequence of unwelded ash-fall and hydrovolcanic deposits (Ttp). Large accidental blocks up to 3 m in diameter of densely-welded Soldier Meadow Tuff were ballistically emplaced, as indicated by bomb-sag structures in Ttp pyroclastic beds. Soldier Meadow Tuff accidental blocks are mostly located proximal to the HRC ring fractures (refer to Plate 1). The locations and dense welding of the blocks suggest thick 57 accumulation of Soldier Meadow Tuff along the eastern to southern part of the HRC (Smith et al., 2010). Effusive volcanism occurred along the southeastern ring fractures after pyroclastic eruptions ceased. Northeast-striking basaltic andesite dikes (Td) intruded into Ttp along what is now the topographic rim of the southeastern margin of the HRC. Eruptive vents for Tad lavas and rhyolite domes (Trd) are also aligned in a northeastern fashion, likely along preexisting HRC ring fractures. Distribution patterns and thick accumulation of Soldier Meadow Tuff, SM-lava, Ttp bedded pyroclastics and late effusive volcanic units, as well as a strong magnetic minimum (Greene and Plouff, 1981), large densely-welded accidental blocks of Soldier Meadow Tuff in Ttp, and the preferential northeast orientation of feeder dikes and eruptive vents suggest a large, longlived magma source was concentrated beneath the eastern to southern ring fractures of the HRC. Eruptive Model for the Soldier Meadow Tuff Ash-flow deposits are commonly formed by one to many flow units emplaced sequentially, generally from a “pulsing” effect of large-scale eruptions. Thick sequences of flow units can create a massive ignimbrite many tens of meters to hundreds of meters in thickness (Druitt, 1998). Sparks and others (1973) described three distinct types of pyroclastic deposits that constitute a related eruptive sequence: Layer 1 - sandwave, massive, or planar surge deposits (Wohletz and Sheridan, 1979), Layers 2a and 2b - the main pyroclastic flow, and Layer 3 - fine ash deposits. Sheridan (1979) added a basal layer of Plinian fall deposits beneath the surge deposits of Layer 1 (Figure 14). 58 Figure 14. Stratigraphic deposits of a complete eruption episode (from Sheridan (1979); modified from Sparks and others (1973)). Layer 0: inversely-graded Plinian fall deposit; Layer 1: surge deposit of sandwave (shown), massive, or planar facies (Wohletz and Sheridan, 1979); Layer 2a: basal layer of the pyroclastic flow that may show inverse grading; Layer 2b: main part of the pyroclastic flow that has double-grading. Lithic inclusions (L) are concentrated near the base of the pyroclastic flow unit, and pumice fragments (P) are concentrated near the top. FP – fumarolic pipes that may be present throughout the pyroclastic flow unit. A lava flow may cap the sequence. 59 The fine, capping ash-cloud deposits derived from overriding co-ignimbrite clouds are rarely preserved. Therefore, surges and the main pyroclastic flow are commonly found as facies of a single pyroclastic flow unit. Co-ignimbrite lag breccias are an additional, proximal facies intimately associated with surge deposits (Cas and Wright, 1987). The three most common pyroclastic deposits in the Soldier Meadow Tuff are surges, breccias, and massive ignimbrite lithofacies. Commonly, surge deposits are well-stratified and have planar to low-angle cross beds and dune formations (Sparks et al., 1973) that are generated by traction-dominated flow (McPhie et al., 1993). Fines-depleted surge facies predominantly occur in proximal (near vent) locations formed by a high degree of agitation-fluidisation near the vent. Surge deposits are therefore closely associated with co-ignimbrite breccias (Cas and Wright, 1987). The Soldier Meadow Tuff surge deposits likely formed near the eastern to southern HRC ring fracture vents from turbulent, relatively high-velocity flow during initial stages of multiple column collapses. As an eruption column collapses, air is ingested into the flow head, causing the flow to become fluidized. Upward flow of gases in the fluidized flow removes fine particles, causing the breccia facies to be fines-depleted (Branney and Kokelaar, 2002). In general, maximum sizes of lithics in the breccia facies decreases from proximal to distal sites (Branney and Kokelaar, 2002). This is in part due to a decrease in flow velocity away from the source, thus decreasing the maximum clast-carrying capabilities of the pyroclastic current. Larger blocks deposit near vent and in higher concentrations, thus breccias are commonly a proximal-vent facies. Blocks can be generated from 60 erosion or collapse of the eruptive vent or conduit, avalanches into the pyroclastic deposit, or erosion of the substrate (Branney and Kokelaar, 2002). The majority of Soldier Meadow Tuff breccias deposits occur in proximal distances, or less than 4 km, from the southeastern HRC ring fractures. Breccia deposits vary from 50-80% concentration of Soldier Meadow Tuff clasts. Breccia clasts are commonly crystal rich, and sometimes glassy. Most Soldier Meadow Tuff breccia deposits directly overlie surge deposits, which corresponds to a typical expected eruptive sequence of a single eruption pulse described by Sheridan (1979). Measured stratigraphic sections near High Rock Peak and the Ampitheatre expose Soldier Meadow Tuff surge and breccia deposits that repeat multiple times in stratigraphy (Plates 2 and 3). The repetition of breccia lithofacies in stratigraphic sections suggest the Soldier Meadow Tuff erupted in multiple pulses; many of these produced lag breccias. The lack of cooling breaks in the Soldier Meadow Tuff section suggests the pulses created multiple column-collapse events that were closely spaced in time. Lag breccias within the Soldier Meadow Tuff are composed of densely welded clasts Soldier Meadow Tuff. This indicates that the Soldier Meadow Tuff eruption was sufficiently long-lived for tuff to deposit, lithify, and then be re-fragmented and entrained into subsequent pulses of the ongoing Soldier Meadow Tuff eruption. No cooling break has been recognized within the Soldier Meadow Tuff, so the eruption was likely continuous, with any breaks in the explosive eruption very short-lived. Massive ignimbrite deposits are characterized by poorly-sorted non-stratified deposits (Branney and Kokelaar, 2002). These massive deposits lack internal 61 stratification and individual beds may be hard to distinguish due to a lack of visible bedding planes. The massive character of this type of deposit indicates minimal shearing between particles during deposition (Branney and Kokelaar, 2002). The main body of the pyroclastic flow, represented by Layer 2b (see Figure 14), is commonly interpreted to be deposited en masse (Sparks, 1976), typically as velocity and the amount of shearing between grains decrease. To meet these conditions, massive ignimbrite deposits generally form in medial to distal areas from the vent, or where topography reduces velocity and allows ponding of the ignimbrite. Ponding of pyroclastic density currents in low areas can result in a strongly-welded mass with individual flow units that can exceed 100 m in thickness. This is documented in Lower and Upper Bandelier Tuffs that ponded in paleocanyons (Cas and Wright, 1987). Columnar jointing is common in massive ignimbrite deposits that have cooled very slowly. Massive Soldier Meadow Tuff mostly crops out in distal locations, more than 4 km from the southeastern ring fractures. Applying the above models to the Soldier Meadow Tuff suggests that the massive lithofacies formed in relatively low-velocity conditions, where minimal shearing between grains resulted in negligible development of bedding planes. The highly-welded and columnar-jointed characteristics of the massive deposits may suggest localized ponding of the Soldier Meadow Tuff in topographic lows or perhaps low velocity flow over relatively flat ground. It is difficult to determine from the massive deposits alone whether the Soldier Meadow Tuff erupted in multiple pulses, but the strongly-layered, repetitive surge, breccia, and pyroclastic-flow deposits at the High Rock Peak and Ampitheatre measured sections (Plates 2 and 3) demonstrate that the 62 Soldier Meadow Tuff did indeed flow in hundreds or thousands of individual pulses that were closely-spaced in time. An eruptive model for the Soldier Meadow Tuff and post-Soldier Meadow volcanism is illustrated in Figure 15. During collapse of the eruption columns, turbulent, high-velocity flows deposited lag breccias and surge beds near vent. In general, laminated lithofacies formed in proximal locations (less than 4 km) from the southeastern HRC ring fractures. As the pyroclastic density current moved further from the vent, velocity slowed and the massive lithofacies of Soldier Meadow Tuff deposited in distal locations (greater than 4 km) from the vent. Subsequent and multiple column collapses occurred closely in time and resulted in repetition of the lithofacies in stratigraphy. Later effusive volcanism resulted in the extrusion of Soldier Meadow lava along the southeastern HRC ring fractures. Post-Soldier Meadow volcanism included pyroclastic eruptions of andesitic to rhyolitic fall and hydrovolcanic units (Ttp). Explosive eruptions, some phreatomagmatic, ripped up and incorporated accidental blocks of Soldier Meadow Tuff measuring up to 3 m in diameter. The blocks are mostly found near the eastern to southern HRC ring fractures, and suggest that the eruptive vents for Ttp were along the caldera ring fractures. Late feeder-dikes that intruded along the eastern to southern ring fractures resulted in the extrusion of basaltic andesite to dacite lava (Tad). The emplacement of Tad lava, perhaps at roughly 1000º C, fused the upper layers of Ttp and created a welded, resistant marker bed. Fragments of Soldier Meadow Tuff included in the mafic to intermediate magmas were partially melted. 63 Figure 15. Eruptive model for the Soldier Meadow Tuff. Laminated Soldier Meadow Tuff deposits and breccias were deposited in proximal (< 4 km) from the vent. Massive deposits were deposited in distal locations (> 4 km) from the vent. Explosive post-Soldier Meadow eruptions (Ttp) incorporated accidental blocks of the tuff in proximal locations from the vent. Feeder dikes (Td) intruded along the southeastern ring fractures. Effusive volcanism produced capping basaltic andesite to dacite lavas (Tad). 64 GEOCHEMICAL & PETROLOGICAL INTERPRETATIONS It is common for caldera-forming ash-flow sheets to show compositional gradients between early-erupted and later-erupted products (Smith, 1979). The range in major and trace elements concentrations and degree of peralkalinity of Summit Lake Tuff samples and the stratigraphic and geographic chemical variations indicate the 16.33 Ma tuff erupted from a chemically zoned magma chamber. Crystallization and fractionation of anorthoclase in the Summit Lake Tuff magma chamber likely drove the magma toward peralkalinity and lower Eu content. Initial eruptions were from the upper, most evolved and mildly peralkaline part of the chamber and spread mostly to the north. Later eruptions from the less evolved, metaluminous part of the chamber spread mostly to the south. Significant magma differentiation within remnant magma after the Summit Lake Tuff eruption, or from post-Summit Lake Tuff injection of new magma, produced the silica-rich Soldier Meadow Tuff. Linear trends of incompatible elements and REE trends suggest the Soldier Meadow Tuff and related lavas are genetically linked to the Summit Lake Tuff and post-Soldier Meadow units of the HRC volcanic suite. Further differentiation of the magma chamber continued after the caldera-forming eruption of the Summit Lake Tuff to proudce a highly-evolved melt with significant Eu-depletion that later erupted the Soldier Meadow Tuff. The Soldier Meadow Tuff erupted as a peralkaline, high-silica rhyolite along the southeastern ring fractures approximately 16.12 Ma. Early eruptions of the Soldier Meadow Tuff were of highly-differentiated magma that contained relatively high silica 65 content and low concentrations of TiO2, Al2O3, FeO, MgO, CaO, and P2O5. These earlier erupted products, deposited as basal exposures, also have higher concentrations of incompatible elements compared to upper stratigraphic counterparts. Stratified geochemical variation reflects a typical eruptive sequence in which the cooler, lowest density and most-evolved components were concentrated in the uppermost parts of the magma chamber and erupted first, followed by later eruptions of slightly lesser-evolved magma as lower parts of the chamber were tapped. SM-lavas were largely emplaced shortly after the uppermost parts of the Soldier Meadow Tuff (i.e. after BH09HR-49; JS10HR-93; JS10HR-33). However, SM-lava is also found below the Soldier Meadow Tuff at the type-locality. Geochemical data shows that SM-lavas (and Soldier Meadow dike) have a similar chemical variation as the Soldier Meadow Tuff. Later, post-Soldier Meadow eruptions along the eastern to southern ring fractures produced andesitic to rhyolitic bedded pyroclastics (Ttp) and basaltic-andesite to dacite dikes (Td) and lavas (Tad). Linear trends of major element oxides versus silica concentrations are consistent with the more silicic rocks of the HRC volcanic suite forming by fractional crystallization from a lesser-evolved parental magma. The parental magma was likely a continental tholeiite as suggested by the TiO2 – Y/Nb ratio of Td dikes and Tad lavas, the most mafic rocks of the HRC volcanic suite. Ratios of incompatible elements should remain relatively constant through the course of fractional crystallization and may vary only slightly during batch melting (Rollinson, 1993). Variation in ratios of incompatible elements could indicate 66 heterogeneous source magmas, possibly arising from contamination or magma mixing (Bougault et al., 1980). Incompatible element ratios of most rocks of the HRC volcanic suite are relatively constant, suggesting a genetic relationship and possible common magmatic source of the Summit Lake Tuff, Soldier Meadow Tuff, Ttp-bedded pyroclastics and younger Td-dikes and Tad-lavas. This constant ratio slope implies the parental magma was relatively homogeneous and did not undergo significant mixing or contamination processes during evolution of the magmas erupted in the HRC volcanic suite. Summit Lake Tuff, Soldier Meadow Tuff, Ttp bedded pyroclastics, Td dikes and Tad lavas likely evolved from a common parental magma via crystal fractionation processes (with the exception of Soldier Meadow Tuff and SM-lava geochemical outliers that require post-depositional alteration, contamination of analyses from incorporated lithics, or additional petrogenic processes other than simple fractionation). The magma chamber that erupted the Summit Lake Tuff may have been only partly evacuated during the caldera-forming eruption 16.33 Ma. Smith and Shaw (1973; 1975) and Smith (1979) state that a pyroclastic eruption is likely to extrude a maximum of one-tenth the magma chamber volume. Residual magma in the HRC chamber evolved over a 200,000-year to 400,000-year period to produce the Soldier Meadow Tuff and SM-lavas that erupted along HRC ring fractures approximately 15.9 Ma to 16.12 Ma. New magma likely injected into the base of the magma chamber between 16.33 Ma and 16.12 Ma, providing the heat necessary for continued differentiation. However, the new magma may not have materially mixed with the HRC chamber. Post-Soldier Meadow units, including Ttp, Tad lavas, and Td dikes, likely erupted from less-evolved magmas 67 lower in the chamber that were closer in composition to the parent from which the Summit Lake Tuff and Soldier Meadow Tuff magmas evolved. 68 Chapter 5 CONCLUSIONS The HRC formed from the eruption of Summit Lake Tuff approximately 16.33 Ma (Noble et al., 2009). This study suggests the Soldier Meadow Tuff and related lavas erupted along the eastern to southern ring fractures of the HRC approximately 16.12 Ma. Field observations, petrographic data and geochemical analyses were used to determine the HRC as the likely eruptive source of the Soldier Meadow Tuff and SM-lavas, and to characterize the complex eruptive dynamics and depositional facies of the Soldier Meadow Tuff. XRF and ICP-MS geochemical analyses were conducted on the Summit Lake Tuff, Soldier Meadow Tuff, SM-lavas, and an overlying sequence of andesitic to rhyolitic bedded-pyroclastics and basaltic andesite to dacite dikes and lavas. Major oxide concentrations show geographic and stratigraphic compositional zoning in the Summit Lake Tuff, and stratigraphic compositional zoning in the Soldier Meadow Tuff. Overall collinear trends of major-oxides and trace elements vs. silica concentrations, and REE patterns relate the Summit Lake Tuff, Soldier Meadow Tuff, SM-lavas, and post-Soldier Meadow units to a common magmatic source, likely continental tholeitte, that evolved predominantly by typical crystal fractionation processes. Using transport and depositional models of common ash-flow lithofacies (Sparks et al., 1973; Sheridan, 1979; Cas and Wright, 1987; McPhie, et al., 1993; Druitt, 1998; Branney and Kokelaar, 2002), a model of the eruptive sequence of the Soldier Meadow Tuff and post-Soldier Meadow units was illustrated in Figure 15. In the eruptive model, 69 Soldier Meadow Tuff deposits are complex and include fine-grained and coarse-grained thinly-laminated surge layers, breccia, and massive deposits that are distributed along and outboard-of the eastern to southern ring fractures of the HRC. Column collapse resulted in the deposition of low-angle cross-bedded surges as well as deposition of auto-breccia lags in proximal (<4 km) distances from eruption vents. The massive lithofacies deposited in distal (>4 km) locations where velocity slowed and topography allowed ponding or decreased flow velocity. These deposits repeat in stratigraphy, implying the Soldier Meadow Tuff erupted in sequential, closely-spaced pulses from multiple column collapses. Paleocurrent indicators and a widespread distribution suggest that the eruption of Summit Lake Tuff at 16.33 Ma resulted in the initial collapse of the HRC. Paleocurrent indicators and distribution of surge, breccia, and massive lithofacies of the Soldier Meadow Tuff indicate that the Soldier Meadow Tuff and lavas erupted along the southeastern ring fractures of the HRC approximately 16.1 Ma. Further subsidence likely occurred in the southeastern part of the HRC as the Soldier Meadow Tuff erupted. PostSoldier Meadow volcanism endured along the southeastern ring fractures in the form of andesitic to rhyolitic bedded-pyroclastic deposits, rhyolite domes, northeast-aligned basaltic andesite dikes and eruptive centers of basaltic andesite to dacite lavas. 70 APPENDICES Appendix A. Methods Appendix B. Petrography of the High Rock Caldera Volcanic Suite Appendix C. XRF Data: Major Element Oxides of the High Rock Caldera Volcanic Suite Appendix D. XRF Data: Trace Elements of the High Rock Caldera Volcanic Suite Appendix E: ICP-MS Data of the High Rock Caldera Volcanic Suite 71 APPENDIX A Methods Geologic Mapping Previous geologic maps (Korringa, 1973; Ach, 1988a; Ach, 1988b; Ach et al., 1991) covered portions of the Soldier Meadow, Yellow Hills East, Yellow Hills West, and High Rock Lake 7.5’ quadrangles, respectively. Detailed geologic mapping for this project covers portions of these quadrangles and has detailed mapping in areas not previously mapped. Field objectives included mapping the Soldier Meadow Tuff, Soldier Meadow lava, other related volcanics, contacts and faults, ring fractures associated with caldera margins, eruptive vents, and other important features useful for establishing geospatial relationships. Soldier Meadow Tuff crops out in the linear fissure complex (Korringa, 1973) as well as along the eastern to southern margin of HRC. Therefore, detailed mapping was focused near the eastern to southern ring fractures. Although the ring fractures of the HRC are buried, the ring fractures were approximated based on unit distributions, locations of eruptive vents and preferentially-oriented feeder dikes for postSMT lavas. Petrographic Analysis Multiple hand samples of each mapable unit were collected. Collection sites were recorded using a handheld GPS. Petrographic descriptions of both hand specimens and 72 outcrops mapped in the field include mineralogy, modal percentages, colors, and textures from volcanic and depositional processes. Fifty-one standard 30-micron thin-sections were made from collected samples at California State University, Sacramento. Detailed petrographic descriptions of mapped units were recorded from these thin-sections and included phenocryst assemblages, estimated modal percentages of phases, micro-textures of crystals and groundmass, presence of lithic fragments, and other important petrographic features (refer to Appendix B). A thin-section staining method was used for accurate approximations of modal percentages of quartz and sanidine phenocrysts, which are particularly difficult to distinguish from one another in thin-section. Staining procedures were based on revised methods from Rosenblum (1956) and Houghton (1980). Rock surfaces of uncovered thinsections were etched using 50% hydrofluoric acid. Although most staining methods require approximately 30 to 45 seconds for etching, times may vary significantly depending on the strength of the hydrofluoric acid, which changes over time. To obtain a proper etch, thin-sections in this project were etched over acid for approximately 3 minutes. Etched thin-sections were then dipped in a 60-percent saturated solution of sodium cobaltinitrite in distilled water. Again, staining times vary depending on the reactivity of the sodium cobaltinitrite solution. Although procedures suggested staining times of 30 to 45 seconds, successful staining was achieved when thin-sections were dipped in the staining solution for 3 minutes. The resulting effect is that quartz remains unstained, while potassium feldspar retains a light yellow stain. Thin-sections were 73 covered with a glass slip using standard covering procedures. The stain was easily seen in plane polarized light using a petrographic microscope. Geochemical Analysis Samples of ash-flow tuffs, lavas, and dikes representative of igneous activity of the HRC were analyzed by XRF and ICP-MS at Washington State University GeoAnalytical Laboratory using a ThermoARL Advant'XP+ sequential X-ray fluorescence spectrometer. The analyzed samples consisted of 47 whole rocks and 10 single pumices (57 samples total) from the High Rock caldera volcanic suite. Each hand sample was cleaned of weathered surfaces, lichen, dirt and soil, and other factors that may alter the analytical results. Fresh pieces were broken off, and chips of the hand sample were hand-picked. Approximately 30 grams were required for proper analysis of each sample. At the WSU GeoAnalytical Laboratory, XRF analyses for major and trace elements were conducted using a single low dilution Li-tetraborate fusion method (Johnson et al., 1999). Resulting data of major element oxides were reproduced in a spreadsheet, plotted on calibration curves, and normalized to total 100 %; Precision of the data using this fusion method is usually ± 2 ppm (Johnson et al., 1999). For ICP-MS analyses, the GeoAnalytical Laboratory uses an HP (now Agilent) 4500+ ICP-MS quadrupole mass spectrometer with an inductively coupled argon plasma ion source. This mass spectrometer can measure metals and trace elements in liquids from the low part-per-billion (ng/mL) range to tens of parts-per-million (ug/mL) (Knaack et al., 1994). In this routine, 27 elements were analyzed, including 13 trace elements and 14 naturally occurring rare earth elements (REEs) from La through Lu as well as Ba, Rb, 74 Y, Nb, Cs, Hf, Ta, Pb, Th, U, Sr and Zr. Zr is measured as a check for complete dissolution of the sample during the extraction process (Knaack et al., 1994). Personnel at the GeoAnalytical Laboratory prepared samples for analyses based on a hybrid technique of Crock and Lichte (1982) and laboratory experimentation. Samples were ground in an iron bowl, and then two grams of the resulting powder were mixed with two grams of lithium tetraborate flux. The powder was placed in a furnace and fused. The sample preparation used fusion and dilution procedures to ensure complete dissolution of zircons and others phases. Data are imported into a spreadsheet, and oxide- and drift corrections are then applied. Resulting drift-corrected concentrations have a precision typically better than 5% relative standard deviation (RSD) for the REEs and 10% for the remaining trace elements (http://www.sees.wsu.edu/Geolab/note/icpms.html). Ar/Ar Dating Radiometric ages of collected samples were calculated from measured 40Ar/39Ar of sanidine phenocrysts. Sanidine phenocrysts are ideal for radiometric analysis based on the high potassium content, homogeneity of the mineral, and the relative abundance of this phase in these samples. Sample preparation and radiometric analyses were conducted by Christopher Henry at the New Mexico Geochronology Research Laboratory (NMGRL). Individual sanidine or anorthoclase grains were totally fused with a CO2 laser, and the released gas analyzed with a Mass Analyzer Products Limited (MAP) 21550 noble gas mass spectrometer. 75 Before analysis, the rocks were crushed and sieved. The sanidine crystals were separated from other phases using a heavy liquid technique. Residual groundmass was removed by ultrasonically cleaning the grains in 4% hydrofluoric acid solution for 5 minutes (Nomade, 2005). This purified aliquot was used in the irradiation process at NMGRL, where samples were irradiated in a nuclear reactor core. Ar-Ar total fusion is most useful on sanidine crystals due to the high potassium content, and is performed using a laser and measuring the ratios of 40Ar/39Ar. Analytical data were plotted on probability distribution diagrams, or ideograms. Most samples were highly radiogenic so isochron plots were not used. The reported ages are weighted means of the analyzed grains (http://geoinfo.nmt.edu/labs/argon/home.html). 76 APPENDIX B Petrography of the High Rock Caldera Volcanic Suite 77 78 79 80 81 82 83 84 85 86 APPENDIX C Major Element Oxides of the High Rock Caldera Volcanic Suite 87 88 89 90 91 APPENDIX D XRF Data: Trace Elements of the High Rock Caldera Volcanic Suite 92 93 94 95 APPENDIX E ICP-MS Data of the High Rock Caldera Volcanic Suite 96 97 98 99 100 REFERENCES Ach, J.A., 1988a, Geologic Map of the Yellow Hills West Quadrangle, Washoe County, Nevada: U.S. Geological Survey, Miscellaneous Field Studies Map MF-2028. Ach, J.A., 1988b, Geologic Map of the Yellow Hills East Quadrangle, Washoe and Humboldt Counties, Nevada: U.S. Geological Survey, Miscellaneous Field Studies Map MF-2029. Ach, J.A., and Swisher, C.C., 1990, The High Rock Caldera Complex: Nested “failed” calderas in northwestern Nevada: Transactions of the North American Geophysical Union, EOS, v. 71, no. 43, p. 1614. Ach, J.A., Bateson, J.T., Turrin, B.D., Keith, W.J., Noble, D.C., and Swisher, C.C., 1991, Geologic map of the High Rock Lake Quadrangle, Washoe and Humboldt Counties, Nevada: U.S. Geological Survey, Miscellaneous Field Studies Map, MF-2157. Aguirre-Díaz, G.J., and Labarthe-Hernández, G., 2003, Fissure ignimbrites: Fissure-source origin for voluminous ignimbrites of the Sierra Madre Occidental and its relationship with Basin and Range faulting: Geology, v. 31, p. 773-776. Best, M.G., and Christiansen, E.H.,1997, Origin of broken phenocrysts in ash-flow tuffs: Geological Society of America Bulletin, v. 109, p. 63-73. Bonham, H.F., 1969, Geology and mineral deposits of Washoe and Storey Counties, Nevada, with a section on industrial minerals by K.G. Papke: Nevada Bureau of Mines Bulletin, v. 70, 140 p. Bougault, H., Joron, J.L., and Treuil, M., 1980, The primordial chrondritic nature and largescale heterogeneities in the mantle: evidence from high and low partition coefficient elements in oceanic basalts: Philosophical Transactions of the Royal Society of London, Series A, v. 297, p. 203-213. Branney, M.J., and Kokelaar, P., 2002, Pyroclastic density currents and the sedimentation of ignimbrites: Geology Society Memoir no. 27, 143 p. Campbell, I.H., 1985, The difference between oceanic and continental tholeittes: a fluid dynamic explanation: Contributions to Mineralogy and Petrology, v. 91, p. 37-43. Cas, R.A.F., and Wright, J.V., 1987, Volcanic successions: modern & ancient: Chapman and Hall, London, 528 p. Castor, S.B., and Henry, C.D., 2000, Geology, geochemistry, and origin of volcanic rock-hosted uranium deposits in northwestern Nevada and southeastern Oregon, USA: Ore Geology Reviews, v. 16, p. 1-40. 101 Coney, P.J., and Harms, T.A., 1984, Cordilleran metamorphic core complexes: Cenozoic extensional relics of Mesozoic compressions: Geology, v. 12, p. 550-554. Crock, J.G., Lichte, F.E., 1982, Determination of rare earth elements in geologic materials by inductively couple argon plasma/atomic emission spectrometry, Analytical Chemistry, v. 54, p. 1329-1332. Druitt, T.H., 1998, Pyroclastic density currents in Gilbert, J.S., and Sparks, R.S. (Eds.), The Physics of explosive volcanic eruptions: Geological Society Special Publication, No. 145, p. 145-182. Erwin, D.M., H.E. Schorn, R.C. Smith, L.M. Levy, C.I. Millar, R.D., Westfall, J.C. King, and V.S. Moran, 2005, Nevada's buried treasure: the Lund Petrified Forest: Botanical Society of America meeting, Austin, Texas, abstract no. 271. Floyd, P.A. and Winchester, J.A., 1975, Magma-type and tectonic setting discrimination using immobile elements: Earth and Planetary Science Letters, v. 27, pp. 211-218. Gabriel, A., Cox, E.P., 1929, A staining method for the quantitative determination of certain rock minerals, American Mineralogist, v. 14, p. 290-292. Greene, R.C., and Plouff, D., 1981, Location of a caldera source for the Soldier Meadow Tuff, northwestern Nevada, indicated by gravity and aeromagnetic data: Summary: Geological Society of America Bulletin, Part I, v. 92, p. 4-6, Doc. No. S10102. Hildreth, W., 1981, Gradients in silicic magma chambers' implications for lithospheric magmatism: Journal of Geophysical Research, v. 86, no. B11, p. 10153-10192. Hilton, R.P., Hausback, B.P., Bromm, G.E., Schorn, H.E., 2008, Disruption of a mid-Miocene ecosystem associated with incipient “Yellowstone Hotspot” volcanism in northwest Nevada: Geological Society of America Abstracts with Programs, v. 40, no. 1, p. 39. Houghton, H.F., 1980, Refined techniques for staining plagioclase and alkali feldspars in thin section, Journal of Sedimentary Petrology, v. 50, p. 629-631. Howard, K.A., 2010, Caldera collapse: Perspectives from comparing Galápagos volcanoes, nuclear-test sinks, sandbox models, and volcanoes on Mars: GSA Today, v. 20, no. 10, p. 410. Irvine, T.N. and Baragar, W.R.A., 1971, A guide to the chemical classification of the common volcanic rocks: Canadian Journal of Earth Sciences, v. 8, p. 523-548. Johnson, D.M., Hooper, P.R., Conrey, R.M., 1999, XRF Analysis of rocks and minerals for major and trace elements on a singe low dilution Li-tetraborate fused bead, Advances in XRF Analysis, v. 41, p. 843-867. 102 Kamata, H., and Mimura, K., 1983, Flow direction inferred from imbrication in the Handa pyroclastic flow deposit in Japan: Bulletin of Volcanology, v. 46-3, p. 277-282. Knaack, C., Cornelius, S.B., Hooper, P.R., 1994, Trace element analyses of rocks and minerals by ICP-MS, Washington State University GeoAnalytical Laboratory, Technical Notes <http://www.sees.wsu.edu/Geolab/note/icpms.html>. Korringa, M.K., 1972, Vent area of the Soldier Meadow Tuff, an ash-flow sheet in northwestern Nevada: Unpub. Ph.D. thesis, Stanford University, 105 p. Korringa, M.K., 1973, Linear vent area of the Soldier Meadow Tuff, and ash-flow sheet in Northwestern Nevada: Geological Society of America Bulletin, v.84, p. 3849-3866. Korringa, M.K., and Noble, D.C., 1970, Ash-flow eruption from a linear vent area without caldera collapse: Geological Society of America Abstracts with Programs (Cordillera Section), v. 2, pt. 2, p. 108-109. Le Bas, M.J., Le Maitre, R.W., Streckeisen, A., Zanettin, B., and IUGS Subcommission on the Systematics of Igneous Rocks, 1986, A Chemical classification of volcanic vocks based on the Total Alkali-Silica Diagram: Journal of Petrology, v. 27, p. 745-750. Le Maitre, R.W., 1989, A Classification of Igneous Rocks and Glossary of Terms: Recommendations of the International Union of Geological Sciences Subcommission on the Systematics of Igneous Rocks. Blackwell, Oxford, 193 pp. Lerch, D.W., Miller, E., McWilliams, M., and Colgan, J., 2008, Tectonic and magmatic evolution of the northwestern Basin and Range and its transition to unextended volcanic plateaus: Black Rock Range, Nevada: Geological Society of America Bulletin, v. 120, p. 300-311. McDougall, I., and Harrison, T.M., 1999, Geochronology and thermochronology by the 40Ar/39Ar method: New York, Oxford University Press, xii, 269 p. McPhie, J., Doyle, M., Allen, R., 1993, Volcanic textures: A Guide to the interpretation of textures in volcanic rocks: 1993, CODES Key Centre, pp. 197. Merriam, J.C., 1910a, Tertiary Mammal Beds of Virgin Valley and Thousand Creek in northwestern Nevada, Part I, Geologic History: University of California Publications, Bulletin of the Department of Geology, v. 6, no. 2, p. 21-53. Merriam, J.C., 1910b, Tertiary Mammal Beds of Virgin Valley and Thousand Creek in Northwestern Nevada, Part II, Vertebrate Faunas: University of California Publications, Bulletin of the Department of Geology, v. 6, no. 11, p. 199-304. Merriam, J.C., 1911, Tertiary mammal beds of Virgin Valley and Thousand Creek in northwestern Nevada, Pt. II, Vertebrate faunas of California Publications, Bulletin of the Department of Geology, v. 6, p. 199-304. 103 Mimura, K. and MacLeod, N.S., 1978, Source directions of pumice and ash deposits near Bend, Oregon: Geological Society of America Abstracts with Programs (Cordilleran Section), v.10, p. 137. “New Mexico Geochronology Research Laboratory.” Copyright 2007-2008 New Mexico Bureau of Geology & Mineral Resources. <http://geoinfo.nmt.edu/labs/argon/home.html>. Noble, D.C., Henry, C.D., Park, Steven L., Smith, J.A., Hausback, B.P., and Hilton, R.P., 2009, Geologic Framework and Evolution of the High Rock Canyon Volcanic Center, Northwestern Nevada: An Early Caldera-Focused System of the Yellowstone Hotspot Track: Geological Society of America Abstracts with Programs, v. 41, no. 7, p. 57. Noble, D.C., McKee, E.H., Smith, J.G., and Korringa, M.K., 1970, Stratigraphy and geochronology of Miocene volcanic rocks in northwestern Nevada: U.S. Geological Survey Professional Paper 700D, p. D23–D32. Noble, D.C., Plouff, D., Bergquist, J.L., Neumann, T.R., and Close, T.J. 1987, Mineral resources of the High Rock Lake wilderness study area, Washoe and Humboldt Counties, Nevada. U.S. Geological Survey Bulletin 1707A, p. 1-14. Noble, D.C., Rigot, W.L., and Bowman, H.R., 1979, Rare-earth-element content of some highly differentiated ash-flow tuffs and lavas: Geological Society of America Special Paper 180, pp. 77-85. Nomade S., Renne, P.R., Vogel, N., Deino, A.L., Sharp, W.D., Becker, T.A., Jaouni, A.R., Mundil, R., 2005, Alder Creek sanidine (ACs-2): A Quaternary 40Ar/39Ar dating standard tied to the Cobb Mountain geomagnetic event, Chemical Geology, v. 218, p. 315-338. Park, S.L., 1983, Paleomagnetic stratigraphy, geochemistry and source areas of Miocene ash-flow tuffs and lavas of the badger mountain area, northwestern Nevada: Thesis submitted for Master of Sciences in Geology, University of Nevada, Reno. Perkins, M.E., and Nash, B.P., 2002, Explosive silicic volcanism of the Yellowstone hotspot: The ash fall tuff record: Geological Society of America Bulletin, v. 114, no. 3, p. 367-381. Rollinson, H., 1993, Using Geochemical Data: Evaluation, Presentation, Interpretation. UK: Longman Group UK Limited, 352 p. Rosenblum, S., 1956, Improved techniques for staining potash feldspars, American Mineralogist, v. 41, p. 662-664. Schminke, H.U. and Swanson, D.A., 1967, Laminar viscous flowage structures in ash-flow tuffs from Gran Canaria, Canary Islands: Journal of Geology, v. 75, p. 641-664. Shand, S.J., 1947. The Eruptive Rocks, 3rd edition. New York: John Wiley, 444 pp. 104 Sheridan, M.F., 1979, Emplacement of pyroclastic flows: A review in Chapin, C.E., Elston, W.E., 1979, Ash-flow tuffs: Geological Society of America Special Paper 180, p. 125-136. Smith, J.A., Hausback, B.P., Henry, C.D., Noble, D.C., and Hilton, R.P., 2009, The Soldier Meadow Tuff of the High Rock Caldera, Northwestern Nevada: Geological Society of America Abstracts with Programs, v. 41, no. 7, p. 140. Smith, J.A., Hausback, B.P., Henry, C.D., Noble, D.C., 2010, The Soldier Meadow Tuff: Eruptive and depositional processes and relationship to the High Rock Caldera, NW Nevada: American Geophysical Union, Fall Meeting 2010, abstract no. V13A-2338. Smith, R.L., 1979, Ash-flow magmatism: Geological Society of America Special Paper 180, p. 527. Smith, R.L., and Shaw, H.R., 1973, Volcanic rocks as geologic guides to geothermal exploration and evolution: EOS [American Geophysical Union Transactions], v. 54, p. 1213. Smith, R.L., and Shaw, H.R., 1975, Igneous-related geothermal systems, in White, D.E., and Williams, D.L., eds., Assessment of geothermal resources of the United States – 1975: U.S. Geological Survey Circular 726, p. 58-83. Sparks, R.S.J., Self, S., and Walker, G.P.L., 1973, Products of ignimbrite eruptions, Geology, v. 1, p. 115-118. Stirton, R.A., 1939, The Nevada Miocene and Pliocene mammalian faunas as faunal units: Sixth Pacific Science Proceedings, p. 627-638. Sun, S. and McDonough, W.F., 1989, Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes in Saunders, A.D. and Norry, M.J., editors, Magmatism in the ocean basins: Geological Society of London Special Publication, v. 42, p. 313–345. “Trace Element Analyses of Rocks and Minerals by ICP-MS.” Washington State University GeoAnalytical Laboratory Technical Notes. Updated 2011. <http://www.sees.wsu.edu/ Geolab/note/icpms.html>. Wernicke, B.P., England, P.C., Sonder, L.J., and Christiansen, R.L., 1987, Extension in the Basin and Range Province and East Pacific Margin: Tectonomagmatic evolution of Cenozoic extension in the North American Cordillera: Geological Society of London Special Publication, v. 28, p. 203-221. Willden, R., 1964, Geology and mineral deposits of Humboldt County, Nevada: American Association of Petroleum Geologists Bulletin, v. 42, no. 10, p. 2378-2398. Wohletz, K.H., and Sheridan, M.F., 1979, A model of pyroclastic surge: Geological Society of America Special Paper 180, p. 177-194. 105 Zoback, M.L., McKee, E.H., Blakely, R.J., and Thompson, G.A., 1994, The northern Nevada rift: regional tectono-magmatic relations and middle Miocene stress direction: Geological Society of America Bulletin, v. 106, no. 3, p. 371-382.