NANO 230 Micro/NanoFabrication Scanning Electron Microscopes 1 Microscopes Light Microscopes • Magnification: 500 X to 1000 X • Resolution: 0.20 µm Electron Microscopes • Magnification: 1,000,000 X • Resolution: <1 nm • down to 0.5 A (TEM) • Limits reached by early 1930s • Use focused beam of electrons instead of light • Color images • “Lenses” are coils, not glass • Sample in air • Sample in vacuum Scanning Electron Microscope (SEM) Transmission Electron Microscope (TEM) Scanning Electron Microscopy (SEM) • Provides information about: – Topography of sample or structure – Chemical composition near the surface of sample • Magnification: ~30X to 500,000X • Resolution – Nanometer scale – Dependent on: 0.612 d n sin • wavelength of electrons () • Numerical aperture of lens system (NA) – Electron gathering ability of the objective – Electron providing ability of the condenser h mv SEM Instrument • Electron beam – Spot size ~5 nm – Energy ~200 - 50,000 eV (electron volts) – Rastered over surface of sample • Emitted electrons collected on a cathode ray tube (CRT) to produce SEM images Sample Prep: • Attach to Al “stub” with conductive carbon tape or paste • Sputter-coat non-conductive samples SEM: How it works 1. Electron beam strikes surface and electrons penetrate surface 2. Interactions occur between electrons and sample 3. Electrons and photons emitted from sample 4. Emitted electrons captured on CRT 5. SEM image made from detected electrons http://www.youtube.com/watch?v=bfSp8r-YRw0&feature=related http://www.youtube.com/watch?v=fToTFjwUc5M&feature=related SEM: Electron Beam Interactions Valence electrons – Inelastic scattering: Energy transferred to atomic electron – If atomic electron has high enough energy can be emitted from sample – “Secondary electron” if energy of emitted electron <50 eV Atomic nuclei – “Backscattered electrons” – Elastic scattering: e- bounce off with same amount of energy – Atoms with high atomic numbers cause more backscattering Core electrons – Core electron ejected from sample; atom becomes excited – To return to ground state, x-ray photon or Auger electron emitted SEM instrumentation Courtesy of the Science Education Resource Center, Carlton College, Carlton, PA Some definitions • Stigmation: – correcting asymmetries in horizontal v. vertical focus – seen as “streakiness” • Collimation: – creation of parallel path particles – typically no control over 8 Improving Images: Spot size Spot size: electron spot radius (rms) • Especially useful to improve focus at high mag • Minimize spot size: – Decrease working distance – Increase current on focusing lens Trade-offs: • Smaller area covered • Lower beam current (worse contrast) 9 Improving Images: Depth of field Depth of field: • How many planes are in focus at once • Related to distance that beam stays narrow • Especially useful to see detail on rough surfaces: • Maximize DOF: • Decrease aperture size • Decrease magnification • Increase working distance Trade-off: • Lower magnification 10 Improving Images: Signal-to-Noise Signal-to-noise ratio: contrast between interacting and non-interacting surfaces • Especially useful to gain more fine detail • Maximize S/N ratio: – High beam current – Slow scan rate Trade-off: • Much larger spot size 11