Name _____________________________ Date ________ Pd____ General Chemistry – Unit 6 Review Chemical Bonding Types of Chemical Bonds, Role of Energy 1. Define a chemical bond. 2. In what terms do we describe the strength of a chemical bond? 3. Bond breaking always (requires/releases) energy; bond formation always (requires/releases) energy. 4. The reaction between methane (CH4) and oxygen gas to form carbon dioxide and water is exothermic. How do you account for this fact in view of your answers to #3? 5. compounds result when a metallic element reacts with a nonmetal. 6. A(n) bond requires the complete transfer of an electron from one atom to another. 7. Name the type of chemical bonding that exists between the atoms in the hydrogen molecule, H2. 8. Name the type of chemical bonding that exists between the atoms in the hydrogen fluoride molecule, HF. Stable Electron Configurations and Charges on Ions 9. In virtually every stable compound, each of the atoms has achieved an electron configuration analogous to that of the elements. 10. Metals form positive ions by (losing/ gaining) enough electrons to achieve the electron configuration of the (previous/next) noble gas. 11. Nonmetals form negative ions by (losing/gaining) enough electrons to achieve the electron configuration of the (previous/next) noble gas. 12. Explain how the atoms in covalent molecules achieve configurations similar to those of the noble gases. How does this differ from the situation in ionic compounds? 13. Define ionization energy. Define atomic radius. What trends to we see in terms of these two things based on the results of our graphing activity? 14. On the basis of their electron configurations, predict the formula of the simple binary ionic compound likely to form when the following pairs of elements react with each other. a. Ca and O b. Sr and F c. Al and S d. Rb and N e. Na and Te Modeling Chemistry 1 U6 gen rev 2011 Ionic Bonding and Structures of Ionic Compounds 15. Why is the formula written for an ionic compound such as NaCl the empirical formula, rather than a molecular formula? 16. Describe, in general terms, the structure of ionic solids such as NaCl. 17. Why are cations always smaller than the atoms from which they are formed? 18. Why are anions always larger than the atoms from which they are formed? Lewis Structures 19. Why are the valence electrons of an atom the only electrons likely to be involved in bonding to other atoms? 20. When elements in the second and third periods occur in compounds, what number of electrons in the valence energy level represents the most stable electron arrangement? Why? 21. Write the Lewis structures. Identify the most stable ion of these elements. a. N b. Br c. Cs d. Al e. Ga f. Xe 22. What is the total number of valence electrons in each of the following molecules? a. H2S b. NI3 c. H2SO4 d. H3PO4 Modeling Chemistry 2 U6 gen rev 2011 23. Write a Lewis structure for each of the following simple molecules. Show all bonding valence electron pairs as lines and all nonbonding valence electron pairs as dots. Also write the name of the compound represented. Are these ionic or molecular compounds? a. PH3 b. SF2 c. HBr d. CCl4 24. Write Lewis structures for the following. Write the name of the compound formed. Are these ionic or molecular compounds? a. H2S b. MgO c. SiH4 d. KCl 25. Explain how atoms in covalent molecules achieve configurations similar to those of the noble gases. How does this differ from the situation in ionic compounds? 26. Write the formulas for the following compounds and identify them as ionic or molecular: a. aluminum oxide _____________________ __________________ b. copper (II) chloride _____________________ __________________ c. barium nitrate _____________________ __________________ d. ammonium chloride _____________________ __________________ e. phosphorus tribromide _____________________ __________________ 27. Write the names of the following compounds and identify them as ionic or molecular: a. Na2SO4 ______________________ _______________________ b. CaCl2 ______________________ _______________________ c. SiO2 ______________________ _______________________ d. FeCl3 ______________________ _______________________ e. Mg(OH)2 ______________________ _______________________ 28. Distinguish between a period and a group or family on the periodic table. How do we use this information in terms of periodic trends we see? 29. Know where the alkali metals, alkali earth metals, transition metals, inner transition metals, halogens and noble gases are on the periodic table. Modeling Chemistry 3 U6 gen rev 2011