Ch. 10 Gas Laws Notes Introduction Standard Temperature and Pressure (STP) P= 1 atm = 760 mmHg = 760 Torr = 101.325 kPa = 101,325 Pa T= 0oC = 273.15 K 0 Kelvin is absolute zero Volume units commonly are cm3 = ml dm3 = L 1000 ml = 1 L 1000 ml = 1 dm3 1000 cm3 = 1 L 1000 cm3 = 1 dm3 Pressure units: atm = atmospheres kPa = Kilopascals mmHg = millimeters of Hg Need to convert between all 3 Pressure Units Example: 2.00 atm mmHg Or 2.00 atm kPa Need to convert to Kelvin from Celsius by adding 273.15 Example: 25.0 C + For Gas Law problems 1st conditions Initial conditions Original conditions = Kelvin 2nd conditions Final conditions Next conditions 3rd conditions Combined Gas Law: Because the formula is equal to a constant, it is possible to solve for a change in volume, temperature, or pressure using a proportion: PV/T = P1V1/T1 = P2V2/T2 Combines Boyle’s and Charles’ Laws Temperature must be in Kelvin & Pressure units must match Gas Law Laws Different Laws have different variables held constant If _____Constant, then__________Law T Boyles If _____Constant, then__________Law P Charles If _____Constant, then__________Law V Gay Lussac If temperature is constant, then P * V = k at a specific temperature or P= Or P1V1 = k and P2V2= k, then P1V1 = k = P2V2 Example 1: A sample of gas has a volume of 171 cm3 at 0.999 atm. What is the volume if pressure changes to 1.20 atm? P1= V1= V2= 201 cm3 if P does V and P then P2= V2= V Example 2: A sample of gas has a volume of 250.0 ml at 760.0 mm Hg. What is the pressure if the volume changes to 350.0 ml? Example 3: A sample of gas has a volume of 250.0 ml at 398 K. What is the volume if the temperature changes to 298 K?