Organic Reactions Page 696 in Text Page 10:41 in Regents Review Book Substitution Definition: replacement of one kid of atom or group by another kind of atom or group in alkanes only Example: Addition Definition: Adding one or more atoms at a double or triple bond in alkenes and alkynes but not in alkanes because there are no multiple bonds Example: Fermentation Glucose is broken down into ethanol and carbon dioxide by enzymes C6H12O6 → C2H5OH + CO2 Glucose Ethanol Carbon Dioxide Esterification The reaction between an acid and an alcohol produce and ester and water Example: ethanoic acid + methanol → methyl ethanoate + water Saponification The reverse of esterification Esters break into acid and alcohol Produces soap Fat + Strong Base → soap + glycerol Salt of an acid Alcohol Combustion Burning a hydrocarbon in the presence of oxygen Produces CO2 + H2O Polymerization Smaller molecules (monomers) join together to form a larger molecule (polymers) Condensation Polymerization – dehydration (remove water) to form a polymer Naturally occuring polymers include starch, protein and cellulose. http://images.google.com/imgres?imgurl=http://www.uwsp.edu/chemistry/tzamis/petpolymeranimate.gif&imgrefurl=http://www.uwsp. edu/chemistry/tzamis/condensationpolymer.html&h=144&w=767&sz=45&hl=en&start=3&um=1&tbnid=ICrvq9jBZmRwJM:&tbnh=27&t bnw=142&prev=/images%3Fq%3Dcondensation%2Bpolymerization%26um%3D1%26hl%3Den%26rls%3Dcom.microsoft:enus%26sa%3DN Polymerization Addition Polymerization Monomers joining together by breaking a double or triple bond to form a polymer Ethene breaking bonds to form polyethylene