MODELS OF THE ATOM Rutherford Rutherford’s early work... • • • • • 1898 - heard about the discovery of radioactivity by Marie and Pierre Curie did his own experiments with radiation and discovered that there were three different types alpha particles - made of matter (bare helium nuclei) with 4 times the mass of a proton and two times the charge of a proton beta particles - made of matter, the mass of an electron and the same negative charge as an electron gamma rays - made of energy with no mass or charge Rutherford’s gold foil experiment • • • • • 1909 - Rutherford did further studies on the atom used alpha particles shot from a chunk of polonium alpha particles were shot at a piece of gold foil expected that most of the alpha particles would pass though the gold foil and strike the fluorescent screen set up behind the foil (why? He assumed that there were fairly large spaces between the atoms) he was surprised to find that some of the alpha particles rebounded from the foil much like a ball would bounce off of a wall Radiation: Beta Particles (-) • Fast moving electrons Gamma Rays • Energy wave Alpha Particles (++) • 4x the mass of a proton Rutherford used radiation and his gold foil experiment to postulate that atoms must contain: - - + ++ + ++ - - A Nucleus - a very positive, dense and massive core An Electron Cloud - a low density, negative envelope around the nucleus Rutherford’s Observations and Conclusions a) Most alpha particles travelled straight through the gold foil without any deflection. Conclusion: most of the atom is empty space b) Some alpha particles were deflected to the side as they travelled through the gold foil. Conclusion: since the alpha particles were positively charged they must have been repelled by a positively charged atom centre. c) Some alpha particles bounced straight back towards the polonium source. Conclusion: there must be a solid, dense core to the atom which these alpha particles collided with head on and were thus bounced back. Rutherford’s Conclusions... • Atoms are mostly EMPTY SPACE with a small, dense, positively charged core which he called the NUCLEUS • the nucleus was surrounded by a clouds of electrons that was very large in volume, but very light in mass compared to the nucleus • this cloud of electrons was negatively charged Rutherford’s Conundrum • Rutherford found that gold atoms have 79 protons in their nuclei, but that this made up less than half of the mass he calculated for their nuclei • thought that the protons could not be alone in the nucleus and that there had to be another type of particle that was uncharged (“neutral”) in the nucleus • these neutral particles would have roughly the same mass as a proton • Rutherford’s inference was confirmed in the 1930’s by James Chadwick’s discovery of the NEUTRON neutrons are important to the structure of the atom because they counteract the repulsive forces between the protons within the nucleus if there were no neutrons, all of the protons in the nucleus would repel each other and the nucleus would fall apart!