Introductory Chemistry (Lecture Note) Chemistry is a science that studies the composition and properties of matter. Matter is anything that takes up space and has mass Mass is a measure of the amount of matter in a sample Chemistry holds a unique place among the sciences because all things are composed of chemicals A knowledge of chemistry will be valuable whatever branch of science you study Characteristics or properties of materials distinguish one type of substance from another Properties can be classified as physical or chemical Physical properties can be observed and measured without changing the chemical identity of the substance, such as melting point, color, density, odor... Chemical properties involve a chemical change and result in different substances, such as flammability EVOLUTION OF CHEMISTRY The earliest concept of science began with ancient Chinese, Egyptian and Greek civilization. The Chinese believed that the universe was created from the interaction of two forces, namely YIN and YANG. Yin, the feminine force, was manifested in darkness, cold and wetness. Yang, the masculine force, was manifested in light, heat and dryness. They believed that these two forces interacted and brought about the material world into existence. The Greek on the other hand, proposed that the AIR, FIRE, EARTH, WATER (Thales, founder of Greek science) were the four elements that make up the universe. EKIBOLAJI Page 1 6/30/2016 These elements were associated with the following properties- hot, cold, wet and dry. The fifth is ether. SCIENTIFIC METHOD Robert Boyle, in one of his books, stated that scientific speculation was worthless unless supported by experimental evidence. This led to the development of scientific method which marked a turning point and the beginning of modern science. What is Science? Science is a method of exploring nature followed by a logical explanation of the observation. The practice of science entails the following: Planning an investigation Carefully recording observation Gathering data Analyzing the results These four steps are the processes involved in an experiment, and this leads us to the definition of experiment. An experiment is exploring nature according to a planned strategy and makes observations under controlled conditions. What is Scientific Method? This is the systematic investigation of nature and requires proposing an explanation for the results of an experiment in the form of a general principle. What is a Hypothesis? Hypothesis is the initial, tentative proposal of a scientific principle. After further experimentation on the hypothesis, it may be Rejected, Modified or elevated to the status of scientific principle. A hypothesis can only become a scientific theory when backed up with sufficient evidence. A scientific theory is not accepted until rigorous testing has established that the hypothesis a valid interpretation of the evidence. A good example is John Dalton that proposed that all matter was composed of small indivisible particles called atoms. EKIBOLAJI Page 2 6/30/2016 However, it took 100 years of gathering additional evidence before his proposal was universally accepted and elevated to the status of the Atomic Theory. What is ‘Theory’ and ‘Natural Law’? A theory is a model that explains behavior nature, while Natural Law states measurable relationship. For example, Law illustrates that heat flows from hotter objects to cooler one, because we can measure experimentally the change in temperature if we drop an ice cube into water. On the other hand, it is a theory that the heat transfer is due to changes in the motion of molecules in the ice and water. We can distinguish between theory and natural law by simply asking the question: Is the proposal measurable? If yes, then it is a Law otherwise, it is a theory. MODERN CHEMISTRY The Arabs introduced the Pseudoscience of Alchemy (pseudo means false). Alchemy is the existence of a magic portion that had miraculous healing powers and could transmute lead into gold. This did not withstand the test time; it preceded the planned, systematic scientific experiments that are the cornerstone of modern chemical research. By now we all know that, CHEMISTRY studies the COMPOSITION of Matter and its PROPERTIES. The advancement in Chemistry led to the division of the subject into various branches and specialties. ORGANIC CHEMISTRY- Is a branch of chemistry that studies substances containing Carbon. INORGANIC CHEMISTRY- Is a branch of chemistry that studies substances that do not contain carbon. BIOCHEMISTRY- Is a branch of chemistry that studies substances derived from plants and animals EKIBOLAJI Page 3 6/30/2016 PHYSICAL CHEMISTRY- Is a specialty that proposes theoretical and mathematical explanation for chemical behavior. ANALYTICAL CHEMISTRY- Is a branch of chemistry that studies Quantitative Analysis (how much of each substance is present) and the Qualitative Analysis (What substance are in a sample). ENVIRONMENTAL CHEMISTRY- Is a branch of chemistry that studies the safe disposal of chemical waste. Chemistry plays important roles in the following fields: Medicine- Pharmaceutical prescription. Agriculture- formulating fertilizers and pesticides. Industries- Automobile, electronic components, Aluminum steel, paper and plastic. Petrochemical- (these are chemicals derived from petroleum and natural gas) these chemicals are used in the making of paints, plastics, rubber, textiles, dyes, detergents, explosives and so on. EKIBOLAJI Page 4 6/30/2016