Soils for Master Gardeners Patricia Steinhilber, Ph.D. psteinhi@umd.edu Ag Nutrient Management Program University of Maryland College Park Department of Environmental Science and Technology What is Soil? • the ecstatic skin of the Earth (William Logan) • the living skin of the Earth (Ian Pepper) • crucible of terrestrial life (Daniel Hillel, soil physicist) • the pedosphere • the interface between the lithosphere, hydrosphere and atmosphere (ecologists) • a medium for plant growth • phenomena of nature (natural bodies) Department of Environmental Science and Technology mysciencebox.org Agenda • • • • • • • • soil composition soil video soils as natural phenomena hydrologic cycle and soil water plant nutrients & soil testing fertilizers soil acidity and liming soil as biochemical reactors Department of Environmental Science and Technology What are Soils? • reactive, dynamic, three-phase ecosystems composed of solids, liquids and gases topsoil several days after rainfall or irrigation 25% 25% 48% Minerals Air Water Organic Matter 2% Department of Environmental Science and Technology Question 1 • What % of the soil volume would be water-filled after several days of heavy rain? Department of Environmental Science and Technology Question 1 • What % of the soil volume would be water-filled after several days of heavy rain? • 50% Department of Environmental Science and Technology First Things First: Soil Solids • mineral or inorganic solids −often classified based on particle size • organic solids a.k.a. “organic matter” Department of Environmental Science and Technology Major Mineral Classes in a Soil Mineral Class Size of Mineral Particles Feel of Particles sands 0.05 – 2 millimeters (mm) gritty silts 0.002 – 0.05 millimeters (mm) smooth clays less than 0.002 millimeters (mm) sticky when wet Department of Environmental Science and Technology (like flour, cornstarch or talcum powder) Department of of Environmental Environmental Science Department Scienceand andTechnology Technology 60% silt 20% clay 20% sand Department of of Environmental Environmental Science Department Scienceand andTechnology Technology Department of Environmental Science and Technology Effect of Soil Texture on Soil Properties Soil Property Textural Groups coarse-textured medium-textured fine-textured sands, loamy sands, sandy loams, loams, silts loams, silt, sandy clay loams clays, sandy clays, silty clays, silty clay loams, clay loams water-holding capacity low moderate high susceptibility to erosion low high moderate leaching potential high moderate low nutrient retention capacity low moderate high Department of Environmental Science and Technology The Other Soil Solid Material: Organic Matter Humus 75% 10% Biomass 15% Residues & By-Products Department of Environmental Science and Technology Biomass: What It Is • the living component of the soil • consists of a range of creatures − as small as microscopic viruses & bacteria − as large as roots, worms and other creatures that are visible to the unaided eye − and everything between Department of Environmental Science and Technology Source: USDA Department of Environmental Science and Technology Question 2 How many bacteria are there in a handful of soil? A) 10,000 – 50,000 B) 1,000,000 – 10,000,000 C) 300,000,000 – 50 billion Department of Environmental Science and Technology Question 2 How many bacteria are there in a handful of soil? C) 300,000,000 – 50 billion Department of Environmental Science and Technology Biomass: What It Does • participates in nutrient cycling −break down plant and animal materials (residues), using what they need and leaving behind what they don’t • mineralization Department of Environmental Science and Technology Biomass: What It Does (cont.) • creation of biopores −larger organisms move through soil creating channels or pores −channels promote water infiltration and create a healthy balance between large and medium pores Department of Environmental Science and Technology Resources about Soil Organisms http://www.ted.com/talks/bonnie_ bassler_on_how_bacteria_commu nicate.html Soil Biology Primer http://soils.usda.gov/sqi/concepts /soil_biology/biology.html Department of Environmental Science and Technology Residues and By-products: What They Are • dead stuff − crop residues, dead roots and bodies of soil creatures • by-products − materials that plant roots and soil creatures release or exude into the soil Department of Environmental Science and Technology Question 3 • What antibiotic used to treat bacterial infections in humans originates from the by-product of a soil organism? Department of Environmental Science and Technology Question 3 • What antibiotic used to treat bacterial infections in humans originates from the by-product of a soil organism? • Streptomycin −Isolated from Streptomyces by Dr. Selman Waksman of Rutgers University. Led to a Nobel Prize in Medicine in 1952 Department of Environmental Science and Technology Residues and By-products: What They Do • fuel and nutrients for soil organisms − energy and nutrient source for most of the soil creatures • formation and maintenance of soil aggregates (structure or architecture) − sticky and gummy by-products of residue decomposition hold soil particles together in clumps or aggregates Department of Environmental Science and Technology Last But Certainly Not Least: Humus • relatively stable end product of residue decomposition • composes the majority of organic matter • resists further decomposition (1% per year) • it is not a good nutrient or energy source for soil creatures Department of Environmental Science and Technology Humus: What It Does • very small in particle size & high surface area • charged sites at many locations on the surface • effective at holding water and nutrients Department of Environmental Science and Technology The Other Half of Soil: Soil Pores (Void Space) • soil water − adequate (but not too much) quantity − adequate supply of nutrients − minimize runoff and leaching • soil air − source of oxygen for roots and most soil organisms − constantly enriched with carbon dioxide from roots and soil organisms Department of Environmental Science and Technology The Interplay of Air and Water: Soil Aeration • The exchange of O2 and CO2 between the soil pores and the ambient atmosphere Hillel Department of Environmental Science and Technology Comparison of Gasses in the Atmosphere and in Soil Air of Well-Structured Topsoil (several days after rainfall) In Soil Air nitrogen In the Atmosphere 79% oxygen 20.9% 20.6% carbon dioxide 0.035% 0.300% Gas 79% Department of Environmental Science and Technology Balance Between Water and Air • macropores (large pores) − drain quickly after rain or irrigation − allow rapid infiltration of rainfall and replenishment of oxygen in the root zone • mesopores (medium-sized pores) − “storage pores” − hold water in form most plants can use • micropores (very small pores) − water is held too tightly to be use to most plants Department of Environmental Science and Technology Now, a Video Interlude • Dr. Ian Pepper, soil microbiologist, Arizona State University Department of Environmental Science and Technology Department of Environmental Science and Technology Department of Environmental Science and Technology Landscape position Relief 5 soil forming factors physicalgeography.net Department of Environmental Science and Technology 4 soil forming processes • additions • losses • transformations • translocations Department of Environmental Science and Technology From this … … to this. Department of Environmental Science and Technology Let’s talk about the hydrologic cycle and soil water… Department of Environmental Science and Technology Biological Classification of Soil Water • excess or gravitational water − water that drains from soil 1-3 days after a rainfall or irrigation (in macropores) • available − water that is in a form crop plants can use (in mesopores) • unavailable − water that is held to tightly by the soil to be usable by most crop plants (in micropores) Department of Environmental Science and Technology Water and Textural Groups (% water) Coarse- MediumFineTextured Textured Textured 40 50 60 Total Excess 25 15 15 Available 12 27 * 20 3 8 25 Unavailable Department of Environmental Science and Technology Department Environmental Science Technology Department ofofEnvironmental Scienceand and Technology Department of Environmental Science and Technology Soil Solution • keep well supplied with nutrients • minimize adverse conditions for plant growth −acidity −salinity Department of Environmental Science and Technology Soil tests can help identify limiting nutrient factors. Fertilizers can enrich the soil solution when soil tests indicate an insufficiency. Department of Environmental Science and Technology What Elements do Plants Require? Non-Mineral Nutrients carbon oxygen hydrogen Mineral Nutrients macronutrients primary secondary nitrogen phosphorus potassium calcium magnesium sulfur micronutrients iron chlorine zinc boron copper cobalt nickel manganese molybdenum Department of Environmental Science and Technology Forms in Which Nutrients Exist • cation – positively charged ion • anion – negatively charged ion • neutral - uncharged Department of Environmental Science and Technology So Which Nutrients Exist in What Form? • • • • • • • • • • ammonium - NH4+ potassium - K+ calcium - Ca+2 magnesium - Mg+2 iron - Fe+2, Fe+3 zinc - Zn+2 manganese - Mn+2, Mn+4 copper - Cu+2 cobalt - Co+2 nickel - Ni+2 • • • • • nitrate - NO3phosphate - H2PO4-, HPO4-2 sulfate - SO4-2 chlorine - Clborate - H3BO3, H2BO3-, B4O7-2 • molybdate - MoO4-2 Department of Environmental Science and Technology Value of Soil Tests • best pre-plant indicator we have of potential nutritional products • mine them for information! • excellent investment Department of Environmental Science and Technology Soil Tests • best if maintained in the high end of the “optimum” range or the low end of the “excessive” range 0 25 low 50 medium 100 optimum Department of Environmental Science and Technology excessive Soil Test Value and Response to Nutrients Soil Test Category very low and low medium Fertility Index Likelihood of value (FIV) Response 0-25 almost always 26-50 sometimes optimum 51-100 excessive >100 not often almost never Department of Environmental Science and Technology What is a fertilizer? • a compound that contains at least 1 plant nutrient − ammonium nitrate (NH4NO3) − potassium nitrate (KNO3) • no fertilizer materials are 100% of any nutrient! other elements exist with the nutrient in the fertilizer compound • pure N is an inert gas, pure elemental P would ignite when exposed to the atmosphere, pure elemental K burns when it contacts water Department of Environmental Science and Technology Where do N, P and K in fertilizers originate? • N originates from the atmosphere −natural gas is an energy source and a hydrogen source • P originates from rock phosphates • K originates K-bearing minerals, usually chlorides or sulfates Department of Environmental Science and Technology How do we describe the nutrient content of fertilizers? Ag-Gro-Pro 5-10-15 50 lbs. This bag contains: 5% nitrogen--10% phosphate--15% potash or 2.5 lbs. nitrogen (N) 5 lbs. phosphate (P2O5 ) 7.5 lbs. potash (K2O) Department of Environmental Science and Technology The fertilizer guarantee • % nitrogen (total) • % phosphate, P2O5 (citratesoluble) • % potash, K20 (soluble) P2O5 x 0.44 = P K20 x 0.83 = K P x 2.27 = P2O5 K x 1.20 = K20 Department of Environmental Science and Technology Common Commercial N Fertilizers Material ammonia Analysis 82-0-0 ammonium nitrate 34-0-0 urea 46-0-0 ammonium sulfate 21-0-0 UAN (urea+ammonium nitrate) 28-0-0 to 32-0-0 Department of Environmental Science and Technology Less Common Commercial N Fertilizers sulfur-coated urea (SCU) 40-0-0 ureaform 38-0-0 methylene urea 28-0-0 isobutylidene diurea 30-0-0 (IBDU) Department of Environmental Science and Technology Common Commercial P Fertilizers Material superphosphate Analysis 0-18-0 triple superphosphate 0-46-0 monoammonium phosphate (MAP) diammonium phosphate (DAP) ammonium polyphosphate 11-48-0 18-46-0 10-34-0 Department of Environmental Science and Technology Common Commercial K Fertilizers Material muriate of potash sulfate of potash potassiummagnesium sulfate potassium nitrate Analysis 0-0-60 0-0-50 0-0-22-22S-11Mg 13-0-44 Department of Environmental Science and Technology Common Organic Fertilizers • animal manures • composts • by-products of animal harvesting −fish meal, bone meal, blood meal Department of Environmental Science and Technology soil acidity: the adverse condition on humid regions Department of Environmental Science and Technology Adverse Conditions Due to Soil Acidity (Low pH) Adverse Condition Soil Component Affected inadequate supply of some nutrients calcium and magnesium may be present in inadequate amounts in acidic soils excessive or toxic supply of some nutrients or nonessential elements aluminum, iron, zinc, manganese and copper can be present in excessive and even toxic amounts in acidic soils some nutrients bound in unavailable forms phosphorus and molybdenum are so tightly bound to soil clays that they are not available to plants in acidic soils inhospitable environment bacteria, such as those needed for nitrogen fixation, can not thrive in acidic soils Department of Environmental Science and Technology Department of Environmental Science and Technology Soils are Biochemical Reactors • the various components (soil air, soil water, minerals and organic matter) interact • a wide array of chemical and biochemical processes occur Department of Environmental Science and Technology Soil Model biomass organic matter residues & by-products soil solution soil air sand silt clay humus pore space Department of Environmental Science and Technology minerals Clays and Humus • center of chemical reactivity in soil • engine driving chemical transformations in soil geoscienceworld.org fullwiki.org Department of Environmental Science and Technology Solid-Liquid Interface • adsorption of water and nutrients occurs at surfaces • small particles have more surface area than the same weight of large particles • surfaces are often charged; most charge is negative • negatively charged surfaces attract positively charged ions (cations) Department of Environmental Science and Technology Cation exchange is a big deal! • cation exchange capacity (CEC) − a soil’s ability to hold cations on charged surfaces − a measure of the negative charge on the particles − correlated to clay and humus content of soils • exchange phase − those cations held on surfaces of charged particles Department of Environmental Science and Technology Importance of CEC • nutrient cations exist on exchange phase −are protected from leaching −can replenish the soil solution when plant uptake or leaching removes nutrients −the “storehouse” of cationic nutrients Department of Environmental Science and Technology Relationship of Textural Class to Clay Content and CEC Textural Group Range of Clay Content (%) Cation Exchange Capacity (CEC)* 0 - 15 1-5 15 - 20 5 - 10 0 - 25 5 - 15 clay loams, sandy clay loams, silty clay loams 20 - 40 15 - 30 clays, sandy clays, silty clays >49 >30 sand and loamy sands sandy loams loams and silt loams *cmol/kg or centimoles per kilogram, or an older mode of expression, milliequivalent per 100 grams. Department of Environmental Science and Technology Soil: The Most Complex Biomaterial on Earth Department of Environmental Science and Technology Soil – We can’t grow without it. Questions? Smithsonian – Dig it! The Secrets of Soil Hillel, 2008 front cover Department of Environmental Science and Technology