Solutions to Problems 2.5 and 3.1
2.5 [10] A particle of mass m is trapped in a potential V x x . Show that
there is only one bound state and find its energy.
Let the energy be E, which must be negative. Schrödinger’s equation then gives
2 d 2
E x x x ,
2m dx 2
Which, away from x = 0, has solutions x e x , where E 2 2 2m . We divide it
into two regions, region I with x 0 and region II with x 0 . To keep the wave
function from diverging, we must pick
I x Ae x and II x Be x .
If we integrate Schrödinger’s equation across the boundary at x = 0, we find,
2 d 2
dx E x dx x x dx ,
2m dx 2
2
II 0 I 0 0 .
2m
Since the derivative of the wave function has a finite discontinuity, the wave function
must be continuous at the boundary, so we have I 0 II 0 , which implies A B .
Then the equation just derived for the discontinuity of the derivative become
m
2
A A A , or 2 .
2m
Substituting this in for the equation for the energy, we find E 2 2 2m m 2 2 2 .
3.1 [5] Prove Schwartz’s inequality, , , , , . You may prove it
however you want; however, here is one way to prove it. Expand out the inner
product of a b with itself, which must be positive, where a and b are
arbitrary complex numbers. Then substitute in a , and b , .
Simplify, and you should have the desired result.
We take the suggestion given, hoping it will not lead us astray. We note that b is
*
real, so b* b , , while a is not, so a* , , .
0 a b , a b
a*a , a*b , b*a , b*b ,
, , , , , , , , , , , ,
, , , , , , .
We now rearrange this and divide by , to give , , , , , the
desired relationship. The only detail that might be unclear is that in the ultimate step, we
divided by , . This is valid, provided , 0 , which is guaranteed for 0 . Of
course, if 0 , then both sides of Schwartz’s inequality are zero, and the result is
trivially true.