Wyoming Clean Water Plant Biosolids Management Final Report Team 7: Blackwards Eyosias Ashenafi Rachel Gaide Andrew Mitchell Katherine Vogel May 2014. Copyright © 2014 Team 7 and Calvin College. All rights reserved. Blackwards Executive Summary This project focuses on designing a progressive biosolids management system for City of Wyoming Clean Water Plant (CWP). Landfills contribute 35% of all methane emissions in the US, and methane gas is 25 times more harmful to the environment than carbon dioxide. Figure A: Schematic of Proposed Sludge Management Process The team selected anaerobic digestion for sludge stabilization. The choice was made over chemical treatment and aerobic digestion on the basis of monetary and non-monetary factors. The primary design specifications of the client were: - Class A biosolids product Progressive technology Nutrient recovery options Anaerobic digestion is a relatively newer technology that enables treatment plant to produce Class A product. The team selected temperature-phase operating condition where three smaller cylindrical tanks operating at thermophillic (65°C) conditions precede two much larger egg shaped digesters operating at mesophillic conditions (35°C). The tank size for each thermophillic tank is 60,000 gallons and hydraulic residence time is 22 hours. The mesophilic tanks have a volume of 1.5 million gallons each and have a hydraulic residence time of 15 days. Proposed digestion system is shown in Figure B. i Blackwards Figure B: Two- stage Anaerobic Digestion system (CB&I) Thickening was then explored in order to decrease sludge volume and therefore decrease digester costs. Thickening options reviewed include centrifuges, rotary drums and belt presses. Centrifuges were determined to be the best alternative because there are currently two units in use that can be utilized in the proposed new process. The new centrifuge can be installed for $588,800 and will be utilized to get the percent solids in waste activated sludge from 0.7% to 4%. Once anaerobic digestion was selected as the stabilization option, the need for dewatering was evaluated. It was decided that for ease of transportation, a dewatering step was necessary. The methods for dewatering were the same as those for thickening, without the benefit of having two on site. Despite this, centrifuges still proved to be the best option for the plant. A building will also need to be put on site for these centrifuges. A 50 x 50 foot steel building is proposed for this purpose and will cost approximately $40,000. The team built a bench scale digester in the spring semester. The system was fed with sludge samples from Wyoming and Grandville CWP. Total and volatile solids test was performed on samples collected daily. The latter test indicates level of biodegradation that occurs during digestion. Figure C below shows results from the final run. Experimental period was 18-days long. Over this period, daily sludge samples were collected, stored at 4 C° and burned weekly. Decrease of volatile solids can be observed in Figure C which imply volatile solids destruction and methane production. ii Blackwards Figure C: Bench Scale Results The team designed a site plan for the proposed biosolids management system which addresses all of the space constraints for the digesters and additional thickening and dewatering units. The site plan also provides details on the constraints of operation throughout the year. Post treatment storage must be able to store all of the biosolids that cannot be land applied due to seasonal constraint. Table A: Project Cost Breakdown Project Cost Digester System Holding Tanks Thickening Dewatering Storage Tanks Cogeneration Biogas Conditioning Gas Storage Contingency Total $15 M $1 M $600 K $1.2 M $3.1 M $1.5 M $507 K $300 K $2.1 M $22.9 M iii Blackwards iv Blackwards Table of Contents Executive Summary .......................................................................................................................... i Table of Contents .............................................................................................................................v Table of Figures ............................................................................................................................. viii Report Tables .................................................................................................................................. ix Abbreviations ...................................................................................................................................x 1. Introduction .............................................................................................................................. 11 1.1 Purpose Statement.............................................................................................................. 11 1.2 The Project .......................................................................................................................... 11 1.3 Overview of Wastewater Treatment .................................................................................. 11 1.4 Overview of Biosolids Classification .................................................................................... 13 2. The Client .................................................................................................................................. 14 2.1 City of Wyoming .................................................................................................................. 14 2.2 Wyoming Clean Water Plant ............................................................................................... 14 2.2.1 Overview ....................................................................................................................... 14 2.2.2 Current Wastewater Treatment Practice ..................................................................... 15 2.2.3 Current Biosolids Management .................................................................................... 16 3. Sludge Thickening Design.......................................................................................................... 18 3.1 Introduction......................................................................................................................... 18 3.2 Evaluation of Thickening Alternatives ................................................................................. 19 3.3 Recommendation ................................................................................................................ 21 3.4 Total Solids Composition for Digestion ............................................................................... 21 3.5 Thickening and Holding Tank Configuration Decision ........................................................ 22 3.6 Cost Information ................................................................................................................. 25 4. Pre-Digestion System: Thermal Hydrolysis ............................................................................... 26 5. Sludge Holding Tank Design ...................................................................................................... 28 5.1 Existing system .................................................................................................................... 28 5.2 Proposed Addition ............................................................................................................... 28 5.3 Mixing Method .................................................................................................................... 29 v Blackwards 5.4 Material of Construction ..................................................................................................... 30 5.5 Gas Elimination .................................................................................................................... 30 5.6 Cost Information ................................................................................................................. 31 6.1 Introduction......................................................................................................................... 32 6.2 Evaluation of Stabilization Alternatives .............................................................................. 32 6.3 Recommendation ................................................................................................................ 34 6.4 Anaerobic Digestion Process Chemistry.............................................................................. 35 6.5 Class A Biosolids Requirement ............................................................................................ 36 6.6 Digestion Temperature ....................................................................................................... 39 6.7 Digester Configuration ........................................................................................................ 41 6.7.1 Tank Design................................................................................................................... 41 6.7.2 Digester Shape .............................................................................................................. 41 7. Digester Biogas Production ....................................................................................................... 46 7.1 Introduction......................................................................................................................... 46 7.2 Potential Methane Production at Wyoming CWP .............................................................. 48 7.3 Operation and Maintenance ............................................................................................... 52 7.4 Case Studies......................................................................................................................... 53 8. Cogeneration ............................................................................................................................. 55 8.1 Cogeneration Implementation ............................................................................................ 55 8.2 Cost Savings ......................................................................................................................... 55 8.3 Biogas Conditioning ............................................................................................................. 57 8.4 Cost Information ................................................................................................................. 58 9. Post-Digestion Dewatering ....................................................................................................... 59 9.1 Dewatering Introduction ..................................................................................................... 59 9.2 Proposed Percent Dewatering ............................................................................................ 59 9.3 Method of Dewatering ........................................................................................................ 60 10. Biosolids Storage Tanks........................................................................................................... 61 10.1 Design Considerations ....................................................................................................... 61 10.2 Current Biosolids Storage Facilities ................................................................................... 61 10.3 Required Biosolids Storage Capital ................................................................................... 62 11. Pumping Station Design .......................................................................................................... 64 vi Blackwards 11.1 Introduction....................................................................................................................... 64 11.2 Pipe Selection .................................................................................................................... 64 11.3 Pipe Diameters .................................................................................................................. 66 11.4 Cleaning Pipes ................................................................................................................... 67 11.5 Cleaning Methods ............................................................................................................. 67 12. Nutrient Removal/Recovery ................................................................................................... 68 13. Site Layout............................................................................................................................... 69 14. Bench Scale Experiments ........................................................................................................ 70 14.1 Digester Construction........................................................................................................ 70 14.2 Operation and Testing ....................................................................................................... 71 14.3 Results and Discussion ...................................................................................................... 72 14.4 Safety ................................................................................................................................. 73 15. Total Cost of Proposed System ............................................................................................... 74 16. Future Work ............................................................................................................................ 74 Acknowledgements....................................................................................................................... 75 References .................................................................................................................................... 76 Appendix I: Team Management ................................................................................................... 79 Appendix II: Mathcad Calculations ............................................................................................... 83 Appendix III: Hydraulic Profile .................................................................................................... 105 Appendix IV: Manual of Laboratory Tests .................................................................................. 107 Appendix V: Formatted Selections from Clean Water Act Part 503 ........................................... 113 Appendix VI: Equipment Info ...................................................................................................... 123 vii Blackwards Table of Figures Figure 1: Layout of a Conventional Wastewater Treatment System ........................................... 12 Figure 2: Projected Biosolids Use and Disposal in the United States (EPA, 1999) ....................... 13 Figure 3: Aerial View of Wyoming CWP ........................................................................................ 15 Figure 4: Current Wastewater Treatment at Wyoming CWP ....................................................... 16 Figure 5: Current Biosolids Management at Wyoming CWP ........................................................ 17 Figure 6: Thickening Room with Andritz Bird Centrifuges ............................................................ 18 Figure 7: Schematic of a typical centrifuge system (EPA, 2000)................................................... 21 Figure 8: Centrifuge Placement Alternatives ................................................................................ 22 Figure 9: Centrisys Model CS26-4 Decanter Centrifuge ............................................................... 25 Figure 10: Sludge Stabilization with CAMBI THP System .............................................................. 27 Figure 11: Sludge Holding Tanks at Wyoming CWP ...................................................................... 28 Figure 12: Jet Mixing System ........................................................................................................ 29 Figure 13: Exponential Cost Curve for Digester Construction ...................................................... 30 Figure 14: Stages of Anaerobic Digestion ..................................................................................... 35 Figure 15: Treatment Processes that achieve Class A Biosolids ................................................... 38 Figure 16: Comparison of Coliform Destruction (Kade, 2004) ..................................................... 40 Figure 17: Two Stage, High-rate Anaerobic Digester .................................................................... 41 Figure 18: Egg Shaped Digester Configuration ............................................................................. 42 Figure 19: Single-stage Cylindrical Digesters ................................................................................ 43 Figure 20: Two- stage Anaerobic Digestion system (CB&I) .......................................................... 45 Figure 21: Effect of Sludge Retention Time (SRT) on VSS Reduction for High-rate System ......... 46 Figure 22: Potential Sources of Biogas for an AD system ............................................................. 48 Figure 23 : Methane Production Prediction for Thermophilic System ......................................... 49 Figure 24 : Methane Production Prediction for TPAD System ..................................................... 50 Figure 25 : Methane Production as a Function of Influent Flow to Plant .................................... 51 Figure 26: Egg-shaped Digester at Grandville CWP ...................................................................... 53 Figure 27: Comparison of Sludge Flow and Associated Gas Production ...................................... 54 Figure 28: Uses for Energy produced from Digestion ................................................................... 56 Figure 29: Hydrogen Sulfide.......................................................................................................... 58 Figure 30: Siloxane Removal System ............................................................................................ 58 Figure 31: Injection Biosolids Land Application Equipment ......................................................... 59 Figure 32: Biosoilds Storage Tanks in the rear .............................................................................. 61 Figure 33: Seasonal Variations in Biosolids Storage in 2013 ........................................................ 62 Figure 34: Pumping Head Needed as a Function of Pipe Diameter ............................................. 66 Figure 35: Suggested Location of Digestion Facility ..................................................................... 69 Figure 36: Bench Scale Anaerobic Digester .................................................................................. 70 Figure 37: Trial Run Spill ............................................................................................................... 71 Figure 38: Results from Trial Run .................................................................................................. 72 viii Blackwards Figure 39: Results from Final Digestion Run ................................................................................. 73 Figure 40: Team Photo .................................................................................................................. 79 Figure 41: Spectronic 20D+ equipment ...................................................................................... 109 Report Tables Table 1: Average Sludge Composition .......................................................................................... 17 Table 2: Thickening Design Matrix ................................................................................................ 20 Table 3 : Comparison of Thickening Placement Alternatives ....................................................... 24 Table 4: Description of Proposed Centrifuge ................................................................................ 25 Table 5: Capital Cost of Holding Tanks.......................................................................................... 31 Table 6: Design Matrix for Sludge Stabilization ............................................................................ 34 Table 7: EPA CWA Pollutant Limits ............................................................................................... 37 Table 8: Digester Operating Temperature Characteristics ........................................................... 40 Table 9: Comparison of cylindrical and egg-shaped digesters ..................................................... 42 Table 10: Configuration of Cylindrical Digesters for Wyoming CWP ............................................ 44 Table 11: Summary of ESD facility plan from CB&I....................................................................... 45 Table 12: Typical Characteristic of Primary and Secondary Solids ............................................... 47 Table 13: Estimated Biogas Production ........................................................................................ 47 Table 14: Information about Wyoming Waste Flow .................................................................... 48 Table 15: VSR Assumption for AD systems ................................................................................... 49 Table 16: Digester Monitoring (WEF, 2007) ................................................................................. 52 Table 17: Digester Gas Composition (by volume)......................................................................... 57 Table 18: Cost Information for Biogas Conditioning .................................................................... 58 Table 19: Comparison of Final Biosolids Percent Solids Composition .......................................... 60 Table 20: Advantages and Disadvantages of Progressive Cavity Pump ....................................... 65 Table 21: Length of New Pipe Needed for Each Section of Route ............................................... 65 Table 22: Comparison of Nutrient Recovery Technologies .......................................................... 68 Table 23: Work Breakdown Structure (Fall 2013) ........................................................................ 80 Table 24: Work Breakdown Structure (Spring 2014) .................................................................... 81 Table 25: Solids Measurement Datasheet .................................................................................. 108 Table 26: COD experiment Datasheet ........................................................................................ 110 ix Blackwards Abbreviations AD BOD °C CHP COD CWA CWP DAF EPA EQ gpm GVRBA HRT kg lb/day m3/day mg mgd MPN NPDES ppb ppm PS SCFAs SRT THP TPAD TS TSS tWAS UV VAR VS VSR WAS WW WWTP WWTPs Anaerobic Digestion Biological Oxygen Demand degrees Celsius Combined Heat and Power Chemical Oxygen Demand Clean Water Act Clean Water Plant Dissolved Air Floatation Environmental Protection Agency Exceptional Quality gallons per minute Grand Valley Regional Biosolids Authority Hydraulic Residence Time kilogram pounds mass per day cubic meters per day milligram million gallons per day Most Probable Number National Pollutant Discharge Elimination System Parts per billion Parts per million Primary Sludge Short-Chained Fatty Acids Sludge Retention Time Thermal Hydrolysis Process Temperature Phase Anaerobic Digestion Total Solids Total Suspended Solids Thickened Waste Activated Sludge Ultraviolet Vector Attraction Reduction Volatile Solids Volatile Solids Reduction Waste Activated Sludge Wastewater Wastewater Treatment Plant Wastewater Treatment Plants x Blackwards 1. Introduction 1.1 Purpose Statement The purpose of this project is to design a modern, efficient and environmentally friendly biosolids management system for the City of Wyoming Clean Water Plant (CWP). This document will elaborate on the design process and future work that need to be completed. 1.2 The Project Calvin College’s Engineering Program includes a year-long senior design project. The design team formed for this class pursued appropriate project alternatives considering the previous educational experience of the team members. Dr. David Wunder, the team’s faculty advisor, suggested that the team approach the City of Wyoming CWP for potential design projects. The City of Wyoming Clean Water Plant was built to handle waste water from Wyoming, Byron Center and surrounding cities. The team met with Myron Erickson, superintendent of the CWP, and with Aaron Vis, Project Manager of GVRBA (Grand Valley Regional Biosolids Authority). During the meeting, the team was informed that GVRBA was currently collecting bids from consulting firms for stabilization alternatives to current practice. Upon further consulting with Myron Erickson, the team decided to design an anaerobic digester for biosolids management for the City of Wyoming CWP. 1.3 Overview of Wastewater Treatment In general, municipal wastewater is collected from residential areas, businesses and industries, and pumped to wastewater treatment plants (WWTPs). Conventional wastewater treatment consists of four major stages (Figure 1). 11 | P a g e Blackwards Figure 1: Layout of a Conventional Wastewater Treatment System I) Preliminary Treatment is the first step in wastewater treatment. Rags and floatables present in influent stream are physically removed using bar screens by size. This stage increases downstream load capacity while preventing damage to pumping equipment. II) Primary Treatment is the second stage which removes sediments by a gravity settling and skimmers. Sludge is allowed to settle inside a primary clarifier. Skimmers remove suspended solids and grease material on the top surface. III) Secondary Treatment is a biological treatment with an aeration and settling stage. It is commonly referred to as activated sludge. During aeration, microbes feed on organic matter inside a tank fitted with air diffusers. After a certain period of time, the waste stream is sent to a secondary clarifier. Sludge settles inside the clarifier. Some portion of the sludge produced is recycled back to the aeration tank to maintain microbial growth while the remaining is sent for further treatment. Management of solids produced from primary and secondary clarifiers is the focus of this project. IV) Tertiary Treatment (Disinfection) is the final step in wastewater treatment before supernatant or treated effluent is sent to water bodies. Common disinfection schemes include chlorination, ozonation, and ultraviolet (UV) radiation. 12 | P a g e Blackwards Several variables are considered in the design and construction of WWTPs including operating capacity and regulations. Population growth and industrial expansion is accounted for in determination of design capacity. Treatment facilities and government agencies assess the quality of supernatant water and by-product sludge to ensure it meets Environmental Protection Agency (EPA) and National Pollutant Discharge Elimination System (NPDES) standards. 1.4 Overview of Biosolids Classification Biosolids are treated residual solids left over after waste water treatment process. Treated biosolids can be classified as either Class A or Class B. Class A Biosolids can also be categorized as “exceptional quality” (EQ) if they satisfy pollutant concentration limits. Biosolids can be applied to land, placed on a surface disposal site, or fired in a sewage sludge incinerator. Figure 2: Projected Biosolids Use and Disposal in the United States (EPA, 1999) shows current biosolids disposal methods in the United States. In land application, treated biosolids are used to moisturize the soil and as fertilizers. “Surface disposal site” is another name for a landfill. From an environmental perspective, land application is the preferred option for final disposal place of treated biosolids. 60% 50% 40% 30% 20% 10% 0% 1998 2000 2005 Land Application Advanced Treatment Other Benficial Use Surface Disposal/ Landfill Incineration Other disposal 2010 Figure 2: Projected Biosolids Use and Disposal in the United States (EPA, 1999) 13 | P a g e Blackwards The end location of the biosolids determines what regulations are applicable from Part 503 of the Clean Water Act (CWA). There are three parts to achieving Class A designation for biosolids. First, the pathogenic content of the sludge must be reduced sufficiently. Second, there must be sufficient Vector Attraction Reduction (VAR). Third, inorganic pollutants must be below certain maximum values. These issues are explained in context more in “Section 6.5 Class A Biosolids Requirement.” Class A Biosolids, with appropriate pollutant loads, can be land applied to agricultural and non-agricultural land, public contact sites, a reclamation site, lawns and/or home gardens. Class A Biosolids can be given away to local farms or it can be sold for its nutrients. Class B Biosolids are restricted as to where and when land application can occur. 2. The Client 2.1 City of Wyoming The city of Wyoming lies within the Grand Rapids Metro area in western Michigan. It occupies an area of 24.9 square miles and serves a population of 73,000 people. The area also includes several major industries including Gordon Food Services, Michigan Turkey Producers and Country Fresh. 2.2 Wyoming Clean Water Plant 2.2.1 Overview Wyoming’s CWP is located on Ivanrest Avenue on the southwestern edge of Wyoming (see Figure 3: Aerial View of Wyoming CWP). The plant treats wastewater from the City of Wyoming, the City of Kentwood, Gaines Township, and Byron Township, and has a design capacity of 24 million gallons per day (mgd). Current average daily flow through the plant is 14.7mgd, 12% of which originates from local industries. Treated water from the plant is discharged into the Grand River. 14 | P a g e Blackwards Figure 3: Aerial View of Wyoming CWP 2.2.2 Current Wastewater Treatment Practice Raw wastewater from the City of Wyoming, the City of Kentwood, Byron Township, and Gaines Township is collected at Wyoming CWP. Bar screens remove large sediments and materials present in incoming wastewater. The flow proceeds to primary clarifiers where large granular molecules are removed by gravity sedimentation. Currently, there are four primary clarifiers with removal rate of 10-40% biological oxygen demand (BOD) and 50-60% total suspended solids (TSS). Clarified effluent from primary treatment proceeds to one of three aeration basins. The basins are equipped with fine bubble diffusers to aerate and provide a conducive environment for microbial growth. Mixed liquor is sent to secondary clarifiers. Flocculated and dense, suspended solids in mixed liquor settle inside the clarifiers. In 2008, a biological phosphorus removal process (anoxic/anaerobic zone) was incorporated into secondary treatment. Waste activated sludge (WAS) is recycled to the aeration basins. Clear low-BOD, lowTSS clarified effluent is chlorinated and de-chlorinated for disinfection before being discharged to the Grand River. An overview of the treatment process is shown in Figure 4. 15 | P a g e Blackwards Figure 4: Current Wastewater Treatment at Wyoming CWP 2.2.3 Current Biosolids Management Biosolids produced by Wyoming and Grand Rapids WWTPs are currently managed by the GVRBA. GVRBA was formed in 2003 to address strict regulatory requirements and manage regionally-produced biosolids efficiently. Sources of biosolids at Wyoming CWP are primary and secondary clarifiers (Figure 5). Based on dry ton basis, approximately 55% thickened waste activated sludge (tWAS) and 45% primary sludge (PS) pumped to sludge holding tanks. Certain volume of WAS from secondary clarifiers is thickened using centrifuges. Thickened WAS is stored in one of three wet wells before it is sent to GVRBA pumping station or storage tanks. Characteristics of PS, un-thickened and thickened WAS are given in Table 1: Average Sludge Composition. To prevent phosphorus release, WAS is thickened to maximum of 2% total solids (TS), and the wet wells are aerated and treated with ferric chloride. 16 | P a g e Blackwards Table 1: Average Sludge Composition1 Parameter Total Solids, %TS Volatile Solids, %VS pH Alkalinity (mg/L) Primary Sludge 4.26 3.72 5.52 922 Un-thickened WAS 0.96 0.8 6.98 216 Thickened WAS 3.53 2.95 6.53 444 Approximately 75% of the year biosolids from Wyoming CWP are stored in three tanks with a combined capacity of 6 million gallons. The biosolids are then lime stabilized and then used for land application. This process is shown in Figure 5. The remaining 25% is pumped to GVRBA storage tanks in Grand Rapids WWTP through two 3-miles long pipelines. Incoming flow is combined with biosolids from the City of Grand Rapids WWTP. The resulting flow is dewatered by centrifuges and stored in a landfill. Figure 5: Current Biosolids Management at Wyoming CWP The team sought out to design a new biosolids management process, focusing on energy and nutrient capture, environmental concerns and government regulations. 1 Data from 12/11/13 to 02/15/14 17 | P a g e Blackwards 3. Sludge Thickening Design 3.1 Introduction Thickening is a mechanical process of altering the solid content of an influent stream. By removing fluid portion of the entering stream, it is used to increase the concentration of solids in sludge. Primarily, a thickening step increases tank detention time, reduces operation costs and lowers tankage capacity downstream in biosolids processing and storage. Currently, thickening at Wyoming CWP is performed with two Andritz Bird centrifuges with a unit capacity of 265 gallons per minute (gpm). The existing thickening system is shown in Figure 6. The centrifuges thicken WAS from 0.5-1%TS on average to 4-5%TS. Mannich and emulsion polymers are added enhance solids capture. The centrate is the clarified supernatant produced from the process and is sent to the head works of the plant. Existing centrifuge units were considered as thickening alternative. Both centrifuges are 24 years old; however one was rebuilt in 2012, and the other was rebuilt in 2013. The plant expects another 10 years of operation from both centrifuges. A rehabilitation of the thickening system is under consideration by the Wyoming CWP. Figure 6: Thickening Room with Andritz Bird Centrifuges 18 | P a g e Blackwards 3.2 Evaluation of Thickening Alternatives Three sludge thickening technologies were considered in the design process. Score of 0% to 100% was assigned on the basis of performance of each alternative under each category. High score corresponds to attractive feature or good performance in the respective category. This leads to values that seem in conflict with categories that describe weaknesses rather than strengths. Decision matrix of thickening alternatives is presented on Table 2. Category Considerations: 1. Sustainability: How much energy is required to operate this technology? What form of energy is used and how is it produced? How much equipment is already owned by the client and can be reused for this project? Does this technology require nonrenewable resources in order to function? How efficient is the technology at completing the required process? 2. Effluent Quality: Does this technology thicken solids adequately? Is it possible to get a uniform solids concentration in effluent consistently? 3. Progressive Technology: Would the novelty of this technology improve public image of the facility? 4. Capital Costs: How much does the equipment cost to obtain? How much will it cost to install? How much time will it take employees to train on using the new equipment? 5. Operating Costs: How much does the technology cost to operate each month? 6. Safety: Is the technology difficult to operate or does the technology utilize conditions that could cause employee injury during machine malfunction? 7. Expandability: Assuming that the future will require increased production can this technology be expanded easily? 19 | P a g e Blackwards Table 2: Thickening Design Matrix Thickening Alternatives Gravity Belt Centrifuge Rotary Drum Press 1 0.6 0.7 0.7 0.7 0.7 Category Weight Sustainability Effluent Quality 13 16 Progressive Technology 10 0.7 0.7 0. Capital Costs Operating Cost Safety Expandability Total Points 19 22 12 8 100 1 0.8 0.9 0.7 84.2 0.7 0.8 0.9 0.7 73.3 0.7 0.6 0.8 0.7 67 Description of Evaluation I. Centrifuge: The centrifuge yields a higher score in capital costs and sustainability because there are already two centrifuges on site that could be used for this project. The centrifuge does not make Class A designation more likely nor does it make it automatically achievable. It does allow for some expansion as the addition of another centrifuge would be possible with the provided space, though it does have higher maintenance and energy costs. II. Rotary Drum: Evaluation of using rotary drums for thickening was very similar to evaluation of centrifuges with one major difference: there are not rotary drums on site currently. There are no rotary drums currently on the site and thus this would make the capital cost for the drum much higher than that of the centrifuge. III. Gravity Belt Press: The operation prices for the belt press are slightly more than that of the centrifuge or the rotary drum. Belt presses have been used in industry for over a century, thus the low score in progressive technology. Other than these slight difference, a belt press also requires more space than the rotary drum or the centrifuges. 20 | P a g e Blackwards 3.3 Recommendation Based on the results from the decision matrix, centrifuges are recommended for thickening purposes. Centrifuges separate solid and fluid content of a sludge via application of centrifugal force. Configuration of a conventional centrifuge is shown in Figure 7. Slurry or influent sludge enters the unit on the right. The bowl drive located at the entrance and bowl rotation provides centrifugal force that will separate the solids and liquid components of influent sludge. The scroll drive provides horizontal rotation to the screw conveyor which moves solids towards the right or the conical section for discharge. Liquid discharge or centrate leaves the unit on the opposite end. Geometry of system components and drive specification determine the efficiency and flow range a unit can handle. Figure 7: Schematic of a typical centrifuge system (EPA, 2000) 3.4 Total Solids Composition for Digestion To achieve optimal feed composition for digestion, the feed could be thickened to 6%. This is not ideal for design however because at that level of solids content, the fluid is approaching a non-Newtonian flow. This would make operation and pumping extremely difficult. To avoid these issues, the team chose to thicken to only 4%2. 2 http://www.lawpca.org/Anaerobic%20Digestion/Conceptual%20Design%20Report.pdf 21 | P a g e Blackwards 3.5 Thickening and Holding Tank Configuration Decision Thickening the solids will decrease the size requirements of system components downstream. The team decided to thicken secondary solids from 0.7% solids to 4% solids. Primary solids is composed of 3.5% percent solids, and therefore could be put into the digester without thickening. However, the team, in acknowledgement that they cannot anticipate all future operating decisions, chose to build the system such that primary solids could be thickened prior to digestion. From this point, the team faced a decision of whether to put thickening upstream or downstream of mixing. The Wyoming CWP already has two centrifuges on site and the team decided that they would like to use these centrifuges for thickening rather than replace them. This resulted in a need to determine the optimal location of thickening within the process between primary/secondary settling and digestion. The team identified three potential alternatives, which are pictorially described in Figure 8. In this figure, blue represents structures that already exist, red represents structures that will need to be built, and green annotations refer to potential expansions or space constraints that are ambiguous. The number under the label “Centrifuges” refer to the number of units currently in place or that would need to be installed. The holding tanks must have mixing mechanisms in order to provide a more consistent feed to the digesters. Figure 8: Centrifuge Placement Alternatives 22 | P a g e Blackwards Alternative 1 involves leaving the current system in place and untouched upstream of the holding tank. The holding tank must be enlarged and a centrifuge building must be installed between the holding tank and digestion. Two centrifuges will be needed. Alternative 2 involves rerouting the flow from secondary settling to the mixing tank and then rerouting flow from the mixing tank to the thickening building. This alternative requires a much larger mixing tank and one new centrifuge with a potential future expansion requiring another new centrifuge. Alternative 3 involves rerouting flow from primary settling to the thickening building and increasing the size of the mixing tank. This alternative needs one new centrifuge with a possible future expansion that would require another new centrifuge. A cost analysis of each alternative was completed and is shown in Table 3 : Comparison of Thickening Placement Alternatives. The holding tank expansion was cost estimated using the assumption that concrete would be the building material and that three days of storage would be needed (see Section 5 for more information on holding/mixing tanks). Piping distances were estimated using satellite imagery in reference to the size of a car parking spot. 23 | P a g e Blackwards Table 3 : Comparison of Thickening Placement Alternatives Major Pipe Rerouting Alternative 1 2 3 Alternative 1 2 3 Pumping Changes Description Cost Description Additional Pipe from Mixing to Second Thickening Building $ 23,800 2 new pumps from Holding to Centrifuge $ 114,000 ~ Replace 6 pumps from Secondary to Holding? ~ Add pumps to handle extra flow from holding to centrifuge ~ Move/replace pumps from (thickening to holding) to (holding to thickening) $ 68,900 ~ Add pumps to handle flow from thickening to holding 2 lines from Secondary To Holding Tank From Holding Tank to Thickening Building From Primary to Holding Tank Holding Tank Expansion Description Yes Yes Largest Volume Needed Yes Smallest Volume Needed New Centrifuge Units Cost Description Cost $ 314,900 2 $ 1,176,000 $ 1,117,000 13 $ 588,000 $ 284,600 14 $ 588,000 New Buildings Description New Thickening Building Cost Cost Negligible compared to other costs Negligible compared to other costs Negligible compared to other costs Total Cost $ 40,000 $ 1,554,700 No New Buildings $0 $ 1,819,000 No New Buildings $0 $ 941,500 3 If the population served by the City of Wyoming Clean Water Plant continues to expand, then an additional unit will be needed. This would require an expansion to the thickening building, as two new units cannot fit into the existing structure 4 Same as 3 24 | P a g e Blackwards 3.6 Cost Information One additional centrifuge is required to meet redundancy needs for future WAS flow condition in the proposed sludge management system. It will be located in Thickening room next to the existing Bird centrifuges. Primary sludge produced at Wyoming CWP has high %TS and does not require thickening. Centrisys decanter centrifuge shown in Figure 9: Centrisys Model CS26-4 Decanter Centrifuge was selected for thickening WAS sludge. The unit’s dimension are 8.25 ft. high by 15.75 ft. wide. Basic technical and cost information of Centrisys decanter centrifuges used in design are summarized in Table 4: Description of Proposed Centrifuge. Gforce in the table represents the horizontal acceleration that the units imparts on feed slurry in comparison to gravitational acceleration. Figure 9: Centrisys Model CS26-4 Decanter Centrifuge5 Table 4: Description of Proposed Centrifuge6 Centrifuge Brand Model Flow Rate (gpm) G-force Motor Horsepower Product Price* Number of Units Total Price Centrisys CS26-4 200-400 3000 125 $588,000 1 $588,000 5 http://centrisys.us/products/decanter-centrifuges/CS26-4/ Cost includes centrifuge, hydraulic backdrive, control panel, stand w/out walkway, hoppers (to collect cake and centrate), piping into plant systems, spare parts kit, service for setup, and shipping. 6 25 | P a g e Blackwards 4. Pre-Digestion System: Thermal Hydrolysis Cambi THP is a thermal hydrolysis process (THP) that solubilizes or disintegrates extracellular substances present in sludge before digestion at high temperature and pressure. Feed sludge is heated at 165°C for 20-30 minutes. Solids content of the feed sludge should be 1617%TS, and thus a prior dewatering stage is required. Advantages of Cambi THP include low digester volume requirement, pathogen reduction, high dewater-ability of biosolids and high biogas generation. Foaming and odor problems are minimized, and the system can enhance stabilization levels post digestion. High quality biosolids can be produced that can be land applied. Schematic of sludge management system with Cambi THP is shown in Figure 10. Cambi THP is an emerging technology from Europe that’s gaining popularity in North America. East Bay Municipal Utility District WWTP in San Francisco and Blue Plains Advanced WWTP in Washington D.C. are two treatment plants in the US that have successfully integrated Cambi THP in their sludge management program. Both plants are designated as Class A solids processing facilities and use cogeneration system to generate heat and electricity from methane production. Cambi THP is an expensive technology to implement and maintain at small or medium scale WWTPs. It requires dewatering equipment. Energy costs associated with dewatering and heating during THP are relatively higher compared to conventional digestion systems. The team considered CAMBI as a pretreatment step. It was not selected in the final design due to high capital and operating cost requirements. 26 | P a g e Blackwards Figure 10: Sludge Stabilization with CAMBI THP System 27 | P a g e Blackwards 5. Sludge Holding Tank Design 5.1 Existing system Two 150,000 gallons tanks are presently used in Wyoming CWP to store the blend of primary sludge and thickened WAS (Figure 11). They are located next to the main administration building. These tanks mix the two streams in order to provide a uniform feed to the digester. They minimize fluctuations in feed sludge composition and loading rate. They serve as equalization basins of thickened primary and secondary sludge before stabilization during normal and higher flow conditions (max month flow). They are also referred to as sludge mixing tanks. Figure 11: Sludge Holding Tanks at Wyoming CWP 5.2 Proposed Addition Based on 2025 projected flow, two additional holding tanks with a combined volume of 300,000 gallons will be required. Three day storage at maximum month sludge production rate was used for determining holding size. More days of storage will lead to sludge quality deterioration. For emergency situations, it is recommended that the CWP either increase thickening to no more than 5%TS (to minimize pumping problems) or direct excess flow to Grand 28 | P a g e Blackwards Rapids WWTP using existing GVRBA facilities. Both holding tanks will be lined with coal tar epoxy and will be located adjacent to existing tanks. 5.3 Mixing Method For the holding tank there were several options of mixing, the most common in industry being the jet mixing system and the other being mechanical agitation. Mechanical agitation consists of propellers attached to a shaft driven by a motor. Mechanical agitation has a capital cost of $15,000 per tank. This system tends to collect rags and other debris on the agitator. The Jet mixing system, as displayed in Figure 12, consists of a chopper pump, several nozzles, and piping. The Jet mixer, $25,000 per tank, has two key advantage over the mechanical agitation. This mixer can be turned on and off as needed which is ideal for the times that the sludge is not being used. Figure 12: Jet Mixing System For a 300,000 to 500,000 gallon tank this system can suspend up to 10% TS in under three hours. This saves municipal plants 30% of the expected operation energy costs7. Secondly, the jet mixers can be turned onto the walls and clean the tank when needed and the maintenance for the jet mixers is minimal. For these reasons the Jet mixer system was implemented. 7 http://www.osti.gov/scitech/servlets/purl/768043 29 | P a g e Blackwards 5.4 Material of Construction Cost curves were constructed using cost data found online for determining appropriate construction material (Figure 13). Steel tank is the cheapest option amongst the different alternatives. For all materials, construction price decreases with increase in tank volume. In other words, it is cost effective to construct a single or few large tanks than several small tanks. The figure also indicates that price difference between the material alternatives narrows down with increase in tankage. Concrete is a conventional and preferred material for tank construction due to its durability, low corrosion property, low maintenance cost and high thermal resistance. $1.60 $1.40 y = 0.65*Cost-0.454 Cost per gallon $1.20 $1.00 y = 0.7*Cost-0.474 $0.80 $0.60 $0.40 y = 0.5*Cost-0.351 $0.20 $0 0.2 0.4 0.6 0.8 1 1.2 Tank Volume (million gallons) Steel Glass lined steel Concrete Figure 13: Exponential Cost Curve for Digester Construction 5.5 Gas Elimination In the event that the sludge holding / mixing tanks must be used in an emergency situation, it is possible that the sludge will naturally produce biogas. A major component of biogas is methane. As biogas is produced, the pressure inside the tank would build up. Both the pressure build up and the composition of the biogas contribute to an explosion risk. 30 | P a g e Blackwards For this reason, a flare will be installed that will automatically bleed gas pressure. The biogas will be burned rather than being simply released because methane is a worse greenhouse gas than carbon dioxide. The flare will cost $21,000 dollars.8 5.6 Cost Information Table 5: Capital Cost of Holding Tanks 8 Item Cost Holding tanks (2) Jet Mixers (2) Flare Total $33,000 $25,000 $21,000 $1,181,000 http://www.epa.gov/gasstar/documents/installflares.pdf 31 | P a g e Blackwards 6. Sludge Stabilization Design 6.1 Introduction Waste solid, commonly referred to as sludge in industry is produced from the physical separation that occurs in primary treatment and biological activity in activated sludge process. Stabilization is the process of decomposing organics and destroying pathogens present in primary and secondary sludge. In most treatment systems, sludge stabilization is incorporated in the treatment scheme to reduce pathogenic content, to control odor problems and to enhance sludge dewatering. 6.2 Evaluation of Stabilization Alternatives Conventional stabilization methods considered during the initial stages were alkaline stabilization, aerobic and anaerobic digestion. I. Alkaline Stabilization: is a conventional sludge stabilization method which uses alkaline substance mainly lime for the destruction of pathogens in sludge. Lime is corrosive in nature which leads to a shorter design compared to other stabilization options. It also presents safety hazards. It is a caustic chemical with severe health risks when in direct contact of the skin. End result of the process has a higher volume due to lime addition. Class A product would not be achieved without operational modifications including increased dosage and contact time. It is difficult to accurately represent on a cost scale as it cost varies depending on location of lime suppliers and seasonal availability. At present, lime stabilization is used at Wyoming CWP. The lime is currently supplied for no cost since it is a byproduct of acetylene production from a local company. II. Aerobic Digestion: is the decomposition of biomass using aerobic bacteria in oxygen-rich environment. About 75% of cell biomass can be oxidized in a series of chemical reactions to produce carbon dioxide, water and nitrogen. Compared to anaerobic digesters, it requires less maintenance and control. Project cost is relatively low, except energy cost associated with oxygen supply. Heating requirements are limited. Satisfactory volatile solids reduction and BOD removal can be obtained with proper design and operation. Effluent stream has low solids 32 | P a g e Blackwards content and consequently higher volume which necessitates frequent trucking and disposal. The process does not recover methane in sludge for energy generation. Sludge retention time for Class B product is 40-60 days and depends upon the digester temperature. This process does not allow for Class A product. III. Anaerobic Digestion (AD): is the biological degradation of organic materials with microorganisms in an oxygen-free environment. Volatile solids in sludge are destructed in sealed tanks, resulting in the production of simple compounds. It is a progressive and proven technology in the municipal waste management industry. It is sustainable system because methane that would otherwise get released to the environment from a land fill site is captured on-site resulting in energy sustainability and reduction of greenhouse gas emissions. Anaerobic digestion can yield Class A biosolids on a uniform basis with proper design and operation. In comparison to other stabilization options, the capital cost of anaerobic systems is high due to tank construction, thickening and dewatering equipment installation and cogeneration system cost. Operational costs are high due to sludge heating and energy requirements for thickening and dewatering equipment. Based on system performance of the different methods, a decision matrix for sludge stabilization was constructed (Table 6). Three of the stabilization alternatives were weighed on a scale of 0% to 100%, with 0% corresponding to poor performance and 100% corresponding to superior performance. Categories in the matrix were given appropriate weight based on client’s needs, adaptability to existing system and future implications. Description of each category is presented below. Category Considerations 1. Capital Costs: How much does the equipment cost to obtain? How much will it cost to install? How much time will it take employees to train on using the new equipment? 2. Operational Costs: How much does the technology cost to operate each month? 3. Progressive Technology: Would the novelty of this technology improve public image of the facility? 33 | P a g e Blackwards 4. Sustainability: How much energy is required to operate this technology? What form of energy is used and how is it produced? How much equipment is already owned by the client and can be reused for this project? Does this technology require nonrenewable energy sources? 5. Reliability: Does this technology depend on operator input for changes in feed flow? Does this technology produce a product that is consistent over time? 6. Design life: How often will this technology need to be replaced? 7. Biosolids Quality: Does this technology make achieving Class A easier or possible? 8. Effect on Plant: If the effluent water is recycled into the plant, will the composition of the stream cause the water treatment process to be less effective? 9. Potential Energy Production: Will this technology result in methane production Table 6: Design Matrix for Sludge Stabilization 14 Alkaline Stabilization 0.9 Anaerobic Digestion 0.8 Aerobic Digestion 0.7 Operational Cost 1 0.7 0.3 0.7 Progressive Technology 9 0.2 0.8 0.6 Sustainability 9 0.2 1 0.7 Reliability 9 0.7 0.8 0.8 Design Life 11 0.6 0.8 0.8 Biosolids Quality 18 0 1 0.2 Effect on Plant 3 1 0.4 1 Potential Energy Production 16 0 1 0 Total Points 100 36.8 60.5 48.8 Category Weight Capital Cost 6.3 Recommendation Based on the design matrix above, anaerobic digestion is the ideal stabilization alternative at Wyoming CWP. The process meets design objectives and regulations. Design objectives of this project include attainment of Class A product and energy recovery. High rate reactors with mixing and uniform loading are recommended. 34 | P a g e Blackwards 6.4 Anaerobic Digestion Process Chemistry Different microorganisms are involved in the decomposition of organic material in anaerobic digestion process. Cellulose, proteins and other organic compounds in sludge are solubilized into fatty acids, alcohol and carbon dioxide by extracellular enzymes. The soluble compounds are further broken down to short-chained fatty acids (SCFAs) such as acetic acid and hydrogen by acidogenic bacteria. The final stage is the formation of biogas from acetate decarboxylation and conversion of carbon dioxide and hydrogen by methanogenic bacteria. The final product, biogas consists of 60% methane and 40% carbon dioxide. Byproducts include hydrogen sulfide, siloxane and ammonia. The activation of different microorganisms depends on the operating temperature of digester, pH and sludge retention time (SRT). Methanogenic bacteria are important microorganisms in the digestion process that regulate the rate of methane formation. Stages of anaerobic digestion are presented in Figure 14. Figure 14: Stages of Anaerobic Digestion 35 | P a g e Blackwards 6.5 Class A Biosolids Requirement In order to obtain Class A designation for the end product of the anaerobic digester, three requirements must be met. First, the biosolids must have satisfactory pathogen content reduction. There are six alternatives for reducing the pathogenic content to below detectable levels. The proposed anaerobic digestion system for Wyoming CWP meets Alternative 1 (Thermally Treated Biosolids). Two basic requirements must be met to achieve Class A status. First, either the biosolids must have a fecal coliform level less than 1000 Most Probable Number (MPN) per gram of total solids or the biosolids must have a salmonella level less than three MPN per four grams of total solids. Research has shown that this level can be achieved using a thermophilic anaerobic digester. Second, the time and temperature of the stabilization must meet one of four options. Influent total solids levels of 4% means that this design will meet option D. The Clean Water Act classifies the sludge by percent solid, temperature, and residence time. The equation shown below describes the relationship between temperature and minimum residence time according to Part 503 of EPA regulation. D= 50,070,000 100.14∗T In this equation, T stands for temperature in degrees Celsius (C) and D is residence time in days. Since a thermophilic digester operates at a temperature of 55°C, this equation shows that our residence time must be at least one day. The residence time chosen was 10 days; therefore this constraint will be met. The second requirement for Class A designation is Vector Attraction Reduction (VAR). In layman’s terms, this means that the biosolids must not have enough energy to support large populations of new microbes. There are 8 alternatives for meeting vector attraction reduction. This design meets option 1, which reads as follows: The mass of volatile solids in the sewage sludge shall be reduced by a minimum of 38 percent. (see calculation procedures in “Environmental Regulations and Technology— 36 | P a g e Blackwards Control of Pathogens and Vector Attraction in Sewage Sludge”, EPA–625/R–92/013, 1992, U.S. Environmental Protection Agency, Cincinnati, Ohio 45268). Research has shown that actual VSS reduction for thermophilic anaerobic digesters is usually between 40 and 60% which meets this requirement. The third requirement for Class A designation is meeting pollutant restrictions. For this requirement, the end location of the biosolids determines what regulation applies. All land applied biosolids must be at or below the values shown in column 1 of Table 7. In addition, any biosolids applied to agricultural land, forest, public contact sites, or reclamation sites must either have a cumulative pollutant loading rate less than column 2 or must have a point concentration less than column 3. Any biosolids sold or given away in a bag or another container for land application must either have concentrations less than the third column or must have a total annual loading rate less than column 4. The four most common treatment configurations that produce Class A biosolids are presented on Figure 15. In this project, option 2 and 4 were investigated. Table 7: EPA CWA Pollutant Limits Pollutant Ceiling Concentration (mg/kg) Arsenic Cadmium Copper Lead Mercury Molybdenum Nickel Selenium Zinc 75 85 4300 840 57 75 420 100 7500 Cumulative Pollutant Loading Rate (kg / hectare) 41 39 1500 300 17 420 100 2800 Monthly Average Concentration (mg/kg) 41 39 1500 300 173 420 100 2800 Annual Pollutant Loading Rate (kg / hectare / 365 day) 2 1.9 75 15 0.85 21 5 140 37 | P a g e Blackwards Figure 15: Treatment Processes that achieve Class A Biosolids9 9 Willis and Schafer, 2006 38 | P a g e Blackwards 6.6 Digestion Temperature Anaerobic digestion can occur at different temperatures. Mesophilic and thermophilic operation correspond to digestion at 35°C and 55°C respectively. Both processes have their own strengths and weaknesses. Important benefits of mesophilic operation include operational simplicity and good pathogen reduction. The mesophilic range does not require nearly as much attention to operating details as the thermophilic range. As a result, most WWTP digestion systems in the US operate at mesophilic temperature. However, volume requirement of mesophilic digesters is almost twice than volume required in thermophilic digesters since average mesophilic HRT is 20 days, approximately twice that of thermophilic HRT. The hydraulic retention time is longer because it takes a long time for the microbes to mature and digest substrate in sludge. The heating costs for mesophilic is not as high as thermophilic due to lower heating temperatures but construction costs are much higher. It is practically not possible to reach Class A pathogen level at mesophilic temperature without additional treatment. The second mode of anaerobic digestion is operation at thermophilic or 55°C. The high temperature requirement is associated with high heating costs. However, the tank volume is nearly half of that required for mesophilic digestion which lowers construction costs considerably. Reaching the thermophilic temperature range also allows the biosolids to reach Class A pathogen level with pre-digestion pasteurization or thermal hydrolysis system. Semibatch operation at thermophilic temperature can achieve Class A status if short-circuiting is avoided. Thermophilic digesters are commonly buried to minimize heat loss from digester walls to the atmosphere. Temperature-phased anaerobic digestion (TPAD) is the thermophilic and mesophilic anaerobic digestion in sequence. Solid residence times (SRT) are varied across two tanks to find appropriate loading rate. TPAD systems have been proven to have better performance in volatile solids (VS) reduction and gas production than single-stage mesophilic or thermophilic digestion (Bolzonella et al). Other benefits include good odor control and no short-circuiting or reinfection which makes Class A designation possible. Previous research work has shown that TPAD system produces fecal coliform less than the regulatory level of 1000MPN or 3-log per gram of total solids 39 | P a g e Blackwards (Figure 16: Comparison of Coliform Destruction (Kade, 2004). A summary of the different digestion temperatures is presented on Table 8. Figure 16: Comparison of Coliform Destruction (Kade, 2004) Table 8: Digester Operating Temperature Characteristics Category Operating Temperature Energy Costs Residence Time Class Mesophilic 35°C Lowest Highest B Thermophilic 55°C Highest Lowest A or B TPAD Both Middle Middle A 40 | P a g e Blackwards 6.7 Digester Configuration 6.7.1 Tank Design The team considered thermophilic digestion and TPAD. First, anaerobic digestion system operating at thermophilic temperature was studied. In particular, sizing requirements and potential gas production were determined for a high rate, single stage thermophilic digesters. Since there is no recycle stream, the solids retention time (SRT) is equal to the hydraulic retention time (HRT). Second, temperature-phased anaerobic digestion (TPAD) system for Wyoming CWP was investigated. Schematic of a two-stage digestion system is shown Figure 17. Figure 17: Two Stage, High-rate Anaerobic Digester10 6.7.2 Digester Shape Commonly used digestion tanks are cylindrical and egg-shaped. Advantages and disadvantages of both configurations are outlined in Table 9. Cylindrical shaped digesters are conventionally used in many WWTP digestion facilities and farming communities for treating animal manure. Common construction material for cylindrical digesters is concrete. A modification of cylindrical tanks, German digesters have cylindrical shape with truncated, conical top and bottom surfaces for efficient mixing and hydraulics. Cylindrical digesters were chosen for the design of thermophilic digestion system. 10 Source: http://water.me.vccs.edu/courses/env108/anaerobic.htm 41 | P a g e Blackwards Table 9: Comparison of cylindrical and egg-shaped digesters11 Cylindrical Digesters Advantage Disadvantage High gas storage Poor mixing Possible use Grit and scum of floating covers accumulation Conventional construction methods Egg-shaped Digesters Advantage Disadvantage Better mixing Complex design (digester, (hydraulic efficiency) foundation and seismic) Low grit accumulation and High construction cost foaming Smaller footprint Limited gas storage capacity Low O&M costs Egg-shaped digesters are gaining popularity in the United States due to their high hydraulic performance. Major benefits include simple operation control, smaller footprint and good mixing. Common construction material is steel due to ease of construction. A local waste water (WW) treatment facility, Grandville Clean Water Plant has an egg-shaped digester. Minimum foaming occurs due to the narrowing near the top. Proposed TPAD system for Wyoming CWP has egg-shaped, mesophilic digesters. Enough land space is available for construction with capacity for future expansion. Figure 18: Egg Shaped Digester Configuration12 11 12 Adapted from Metcalf and Eddy, 2003 Source: http://www.gec.jp/jsim_data/water/water_4/html/doc_282_1.html 42 | P a g e Blackwards 6.7.2.1 Cylindrical, Thermophilic Digesters The anaerobic digestion tank design integrated two key parameters volume and redundancy. After researching common practice, it was decided that the projected 2025 averageannual sludge flow should be shared between two digesters of equal size. There will be a total of three digester of equal size including a redundant digester for max month loads (Figure 19). Figure 19: Single-stage Cylindrical Digesters For peak days, the storage tanks preceding the digesters will contain the exceeding flows so the digesters will not have to continually turn on and off. Also, when the digesters are running at relatively constant volumetric flow rates, the digester offline can be maintained if required. In order to find volume of digestion tanks, appropriate design loads for average month condition as well as hydraulic residence time was designated. The radius and height are equal due to ideal heating conditions as well as ease of burial. All calculations can be found in Appendix II: Mathcad Calculations. Table 10: Configuration of Cylindrical Digesters for Wyoming CWP provides a summary of the results. 43 | P a g e Blackwards Table 10: Configuration of Cylindrical Digesters for Wyoming CWP Parameter Digester volume (per unit) Number of units Material of construction Diameter and height above ground Mixing mechanism Burial Value 1,000,000 gallons13 3 Reinforced concrete 35ft. Typically mechanical agitation or recirculation Fully above ground (water table located 12-15 ft. below ground) Batch or semi batch operation of single- stage thermophilic digestion is required to meet Class A requirements. Continuously fed systems re-infect the digested sludge. Other operational issues include volatile solids (VS) fluctuation, foaming and odor problems. Methane production and cost analysis of this option were performed for comparison with TPAD system and presented in this report. Foam and odor control for this configuration were not investigated. 6.7.2.2 TPAD system with Egg-Shaped Digestion (ESDTM) Temperature-phase anaerobic digestion (TPAD) system is a digestion alternative developed by Richard Dague and co-workers at Iowa State University. The US patent number of the process is 5,746,919 and was given on May 5, 1998. It consists of a short thermophilic digestion followed by a long mesophilic digestion system (Figure 20). Major benefits include good hydrolysis, high volatile solids destruction, significant gas production, odor control and ability to meet Class A requirements. Significant pathogen destruction occurs in the acid/thermophilic stage while high volume of methane is produced from the mesophilic stage. Limited number of WWTPs use TPAD system for sludge stabilization. 13 Grit accumulation, mixing equipment space requirement and gas storage volume included in calculation. 44 | P a g e Blackwards Figure 20: Two- stage Anaerobic Digestion system (CB&I) TPAD system for Wyoming CWP will consist of three thermophilic (acid) reactors followed by two egg-shaped mesophilic digesters. Cleaning of the egg-shaped digesters is minimal since there is only minor scum accumulation in egg-shaped digesters. Summary of proposed system based on 2025 design conditions is presented on Table 11. Table 11: Summary of ESD facility plan from CB&I Parameters Unit volume Number of units Tank shape Height above ground Major diameter Digestion time Mixing system Thermophilic (Acid) Reactors 60,000 gallons Three Cylindrical 76ft. 12ft. 22hr External recirculation pump and integral foam Suppression Mesophilic 1,500,000 gallons Two Sphere- egg shaped 96ft. 72ft. 15 days Jet mix draft tube and integral foam Suppression 45 | P a g e Blackwards 7. Digester Biogas Production 7.1 Introduction The anaerobic biodegradation of organic waste produces biogas and other gaseous compounds such as hydrogen sulfide and siloxane. In particular, biogas production is associated with volatile solids (VS) destruction. Several relationships exist that describe the effect of different parameters on VS reduction. Based on Equation 14-14 from Metcalf & Eddy, VS reduction rate (in percent) as a function of sludge retention time (SRT) is graphed and presented on Figure 21. Higher destruction occurs at long retention times, high temperatures and neutral pH conditions. 70% 65% VSS Reduction % 60% y = 0.137ln(x) + 0.189 55% 50% 45% 40% 35% 30% 25% 20% 0 5 10 15 20 25 30 35 SRT (in days) Figure 21: Effect of Sludge Retention Time (SRT) on VSS Reduction for High-rate System The biological and chemical property of the influent sludge as well as loading rate are important variables that determine the maximum level of gas production possible. Table 12 summarizes the properties of the primary and secondary sludge from wastewater treatment process. Primary and thickened WAS will be digested in proposed system. Pre-digestion storage provides a uniform, homogenous feed to the digester tanks and potentially a stable operation. Parameters such as phosphorous and nitrogen levels in secondary sludge are largely determined by the efficiency of biological treatment. Typically, primary sludge removed from primary 46 | P a g e Blackwards clarifiers contains high percentage of substrate (BOD) and TSS and has high energy production potential via digestion. Furthermore, the configuration of digester and efficiency of mixing mechanism affect the conversion of volatile solids to biogas. Table 12: Typical Characteristic of Primary and Secondary Solids 14 Parameters Total Solids Volatile Solids (% of TS) Grease (% of TS) Phosphorus (% of TS) Nitrogen (% of TS) pH Concentration (dry-weight basis) Primary Sludge Secondary Sludge 2-8 0.4-1.2 60-80 60-85 5-8 5-12 0.8-2.8 1.5-3 1.5-4 2.4-7 5-8 6.5-8 Based on past research and actual operation of AD systems, different mathematical models have been formulated on methane yield. Two widely-used approaches to estimate volume of biogas production are volatile solids reduction and conversion of soluble BOD in sludge. Observed values of biogas volume per mass for both approaches is tabulated in Table 13. Biogas can be produced at different parts of an AD system and can be used to generate heat and electricity (see Figure 22: Potential Sources of Biogas for an AD system). The majority of biogas is produced in the digesters, and biogas from the other sources is normally flared due to its limited amount. Table 13: Estimated Biogas Production15 Parameter Volatile solids reduction Soluble BOD conversion 14 15 Value 0.8-1.1 13-18 0.35 5.61 Unit m3/kg ft3/lb. m3/kg ft3/lb. WEF Task Force, 2010 WEF Task Force, 2010 47 | P a g e Blackwards Sludge Holding Tank Biosolids Storage Tanks Biogas Digesters CHP Figure 22: Potential Sources of Biogas for an AD system 7.2 Potential Methane Production at Wyoming CWP Volatile solids reduction (VSR) approach was used to calculate methane production under different flow conditions. The loads of the influent stream were found and documented on Table 14: Information about Wyoming. Potential VSR using the two AD configurations was computed based on SRT (Table 15). These loads were used in an anaerobic biomass equation to find the pounds of biomass (in terms of TSS and VSS) produced per day. Based on 15 ft3 volume biogas production per lb. VSS destroyed, estimated biogas generation during average annual and maximum month flow conditions were determined. Finally, methane generation was found with the assumption that 60% of biogas by volume is methane. Detailed calculations can be found in the Appendix II: Mathcad Calculations. Table 14: Information about Wyoming Waste Flow Parameter 2014 Annual average flow (mgd) 14.7 TSS loading- annual 29056 average (lb./day) TSS loading- maximum 31630 month (lb./day) VS Loading rate 0.084-0.09 3 (lb./ft /day) 16 2025 2416 47438 51641 0.137-0.149 Represents the plant’s design capacity and expected flow 48 | P a g e Blackwards Table 15: VSR Assumption for AD systems AD Configuration VSR (%) Single-stage, thermophilic Two-stage, TPAD system 51% 57% Methane production is dependent on TSS loading which is proportional to wastewater flow into the plant. It can vary with changes in the number of residential homes and industries that are served by the treatment plant. Furthermore, higher gas generation than theoretical findings may occur with operation of CB&I’s TPAD system due to its high mixing efficiency. Theoretical methane production with thermophilic and TPAD system at Wyoming CWP is presented below in Figure 23 : Methane Production Prediction for Thermophilic System and Figure 24 : Methane Production Prediction for TPAD System respectively. Methane Production (ft3/day) 181000 Thermo 166,000 200000 111000 150000 102000 100000 Max. month 50000 Average annual 0 2014 2025 Figure 23 : Methane Production Prediction for Thermophilic System 49 | P a g e Blackwards Methane Production (ft3/day) 204000 250000 187,000 125000 200000 150000 TPAD 115000 100000 Max. month 50000 Average annual 0 2014 2025 Figure 24 : Methane Production Prediction for TPAD System 50 | P a g e Blackwards Methane Generation Vs. Flow 1,000,000 y = 11535x0.8963 R² = 0.8812 Methane Production (ft3/day) 100,000 10,000 y = 10669x1.0545 R² = 0.8628 1,000 100 10 Wyoming CWP (2014) 1 0.1 1 10 Wyoming CWP (2025) 14.7 24 100 Current Flow to WWTPs in WI (mgd) Figure 25 : Methane Production as a Function of Influent Flow to Plant 51 | P a g e Blackwards 7.3 Operation and Maintenance Several physical and chemical properties of sludge in digester tanks should be monitored frequently for process control. Products of acidogenesis process lower digester pH while methanogenesis products raise pH. Neutral pH is considered the ideal digester pH to support the different stages of digestion process. Fluctuations in pH can have detrimental effect on volatile solids reduction and gas production. Digester parameters that should be monitored daily are presented in Table 16. Alkalinity and volatile acids determine the health of an AD system. Higher alkalinity values are associated with system stability in terms of ability to sustain increased organic loading. Ratio of Volatile acids (VA) and alkalinity give an early indication of pH changes. Table 16: Digester Monitoring (WEF, 2007) Parameter Units Temperature °C pH Alkalinity (mg/L) VA/Alkalinity ratio Total Solids (TS) Volatile Solids (VS) Flow mg/L mg/L % % gal/day ft3/ lb. VS destroyed Gas Production Gas Composition % Target 65- Thermo. 35- Meso. 6.8-7.2 2000-5000 0.1-0.2 (record) (record) (record) Test Method Meter AWWA 2320 Ratio calculation 2540B 2540E Meter 12-16 Meter Low CO2, H2S and NH3 Gas Analyzer/ chromatography Meter 52 | P a g e Blackwards 7.4 Case Studies Digestion systems at three WWTPs were evaluated in light of assessing methane production and benefits from its utilization. A comparison of the plants’ design capacity and gas production is presented on Error! Reference source not found.. Expected gas production at Wyoming CWP is also included. I. Grandville CWP (Grandville, MI) In fall 2012, construction of an egg-shaped anaerobic digester was completed at Grandville CWP (Figure 26). It was the first of its kind in Michigan. The digester has one million gallon volume and operates at mesophilic temperature. Primary sludge is the only feed stream of the system since WAS is co-settled in primary clarifiers. Biosolids produced from the plant has Class B quality and is land applied locally. The plant utilizes methane produced from digestion process using a cogeneration system to meet 90% of its heating and electricity demands. Estimated energy savings is $142,000 per year, and the expected payback period for the digestion system is 8 years. Figure 26: Egg-shaped Digester at Grandville CWP II. Blue Plains Advanced WWTP (Washington D.C.) Blue Plains is one of the largest WW treatment facilities in the world. The plant is located in Washington D.C., and it serves more than 2 million people. Lime stabilization is currently being used to treat waste sludge. A new digestion process train will be completed in 2015 at a cost of 53 | P a g e Blackwards $400 million. A CAMBI THP system, four cylindrical digesters (3.8 million gallon units) and a cogeneration system will be installed. The biosolids from the plant will have Class A quality and can be land applied without space and time limitations. The plants will meet about 30% of its energy needs from methane generated. III. Western Lake Superior Sanitary District (Duluth, MN) The treatment facility serves City of Duluth, Hermantown and neighboring townships in Minnesota. The solids management consists of a dissolved air floatation and two-stage, temperature phased anaerobic digestion (TPAD) system. It was the first, full-scale TPAD system in North America. Prior to 2001, sludge co-incineration with solid waste was used. Sludge is treated in a sealed, cylindrical tank at thermophilic temperature for 5 days in the first stage, followed by mesophilic treatment in three separate, 1.05 million gallon tanks for 15 additional days. Treated biosolids is land applied after dewatering with centrifuges. 600,000 500,000 Sludge Fow (gal./day) 400,000 350,000 400,000 300,000 300,000 250,000 200,000 200,000 150,000 100,000 100,000 Gas Production (ft3/day) 450,000 500,000 50,000 0 0 Grandville CWP Wyoming CWP (Current Capacity) Sludge Flow Wyoming CWP (Design Capacity) Western Lake Superior Gas Production Figure 27: Comparison of Sludge Flow and Associated Gas Production 54 | P a g e Blackwards 8. Cogeneration Digester gas is typically composed of 60% methane and 40% carbon dioxide. Unlike natural gas, digester gas does not contain ethane, propane, butane or other combustible gases, which results in its relatively low heating value. A combined Heat and Power (CHP) system is required to capture the energy in digester gas. Heating sludge pre-digestion will be the primary use of energy from methane production. 8.1 Cogeneration Implementation The cogeneration system that the team recommends for implementation is a CHP system. This system generates energy in the form of both stem for the sludge and the remaining portion as electricity for the rest of the plant. The CHP system uses combustion and steam turbines that use the biogas and create mechanical energy which powers a generator that produces electricity for use. This system will cost $1.5 million dollars according to HESCO. 8.2 Cost Savings Gas production increases with the increase in flow, and thus there is more potential energy produced in 2025 than for the current flow conditions. It was determined the cost to heat the sludge prior to digestion in 2025 will be 10.9MMBTU/year and that the energy produced from digestion will be 15MMBTU/year. The energy used for heating will account for approximately 80% of the energy produced as seen in Figure 28. The remaining energy will be used on site as a subsidiary electricity source. Annual cost savings from this additional energy is estimated at $95,000. 55 | P a g e Blackwards 100% 80% 60% 40% 20% 0% Energy Produced 2014 Energy Produced 2025 Energy for Sludge Heating Remaining Figure 28: Uses for Energy produced from Digestion 56 | P a g e Blackwards 8.3 Biogas Conditioning Digester gas contains trace amounts (<5%) of hydrogen sulfide, siloxane and other gases which cause problems in gas piping and cogeneration system. Several technologies are available in the market to remove these harmful gases. Hydrogen sulfide can be removed or controlled by application of activated carbon, ferric chloride or scrubbing with liquid media. High pH in the digester tanks reduces the rate of hydrogen sulfide formation. Piloting of TPAD system and gas chromatographic tests provide valuable information regarding concentration of this contaminant gases based on system changes such as loading rate and mixing rate. The system provider is Unison Solutions, Inc. A special media, SulfaTreat media is used to remove hydrogen sulfide, inside a vertical vessel. Typical and design maximum concentration for hydrogen sulfide and siloxane are presented on Table 17: Digester Gas Composition (by volume). Rated removal efficiency for particulates above 3 microns is 99%. Recommended removal systems for both gases are shown in Error! Reference source not found. and Error! Reference source not found..The two systems are pivotal for smooth operation and maintaining the design life of cogeneration units. Table 17: Digester Gas Composition (by volume) Parameter Hydrogen Sulfide Siloxane 17 Typical Range in Digester Gas17 200-3500ppm 100-4000ppb Max. Discharge Conc. (Unison) 10ppm 100ppb WEF Task Force, 2010 57 | P a g e Blackwards Figure 29: Hydrogen Sulfide Removal System Figure 30: Siloxane Removal System 8.4 Cost Information The cost of the biogas conditioning systems is outlined in Table 18: Cost Information for Biogas Conditioning. The values are before tax and installation. Cost information was found from Unison Solutions, Inc. Table 18: Cost Information for Biogas Conditioning Removal System Hydrogen Sulfide Siloxane Gas Compression/ Moisture Shipping Commissioning Total Capital Cost $135,000 $85,000 $270,000 $8500 $8500 $507,000 58 | P a g e Blackwards 9. Post-Digestion Dewatering 9.1 Dewatering Introduction Dewatering is an optional mechanical process in biosolids management that increases total solids (TS) concentration in post treatment flow. Major benefits of dewatering include: Reduction in biosolids volume for disposal. No seasonal dependence on disposal method. Wide range of applications for Class A product. Because digestion causes the biodegradation of solids, the post digestion percent solids is expected to be reduced to 2.5%. The calculations used to produce this value can be found in Appendix II: Mathcad Calculations. 9.2 Proposed Percent Dewatering The team considered two potential final biosolids levels: 4% solids and 18-20% solids. Currently, the Wyoming CWP has equipment on site for injection of 3-8% biosolids and an example can be seen in Figure 31. The equipment is managed by a separate company but stored and maintained on site. Currently the Wyoming CWP land applies biosolids at approximately 6% solids. Figure 31: Injection Biosolids Land Application Equipment 59 | P a g e Blackwards The ideal percent solids for pumping is 4% solids because flow is reduced while flow characteristics remain similar to water. A composition at 4% solids would not require the purchase of any additional land application equipment. If total solids of post dewatered sludge is between 18-20%, then the effluent of the process is termed as cake solids. Cake solids do not behave like a fluid and cannot be pumped or injected. An example of cake solids is Milorganite, a commercial fertilizer manufactured by the Milwaukee Metropolitan Sewage District. There is currently little to no market demand for bagged cake biosolids in the Grand Rapids metropolitan area. A comparison of the two options for thickening is summarized in Table 19. After consulting Wyoming CWP, the team decided only to dewater to 4% solids with the option to dewater to a higher percentage during atypical operation. Table 19: Comparison of Final Biosolids Percent Solids Composition Dewatering Final Percent Solids 4% 18-20% Can be Bagged for Residential Application No Yes Hydraulic Capital Needed for Properties of Land Application Water Already Exists on Site Yes Yes No No Volume to be Stored in Winter Large Small 9.3 Method of Dewatering Because dewatering is the same mechanical process as thickening, the options for dewatering are similar. The team looked into three methods for dewatering including centrifuges, rotary drums and gravity thickening equipment. Each of these options could concentrate the solids to 4%. The team selected centrifuged because it was the most effective and versatile method. With centrifuges, the option to increase the amount of dewatering to up to 10% can be done with no additional equipment. This condition provides the CWP with flexibility in the future and also allows for conserving storage during unusual long winters. 60 | P a g e Blackwards 10. Biosolids Storage Tanks 10.1 Design Considerations For the purpose of this project, the system was designed for typical use without GVRBA facilities. For this reason, the Wyoming CWP must be able to store biosolids for approximately 3 months during the year when biosolids cannot be land applied via injection due to frozen ground. 10.2 Current Biosolids Storage Facilities Currently, the Wyoming CWP has two 1.9-million gallon tanks and one 2.1 million gallon tank on site. These tanks handle current biosolids treatment operations such as an equalization basin during upsurges, system shutdown and other emergency situations. These tanks are shown in the distance in Figure 32. Figure 32: Biosoilds Storage Tanks in the rear Based on 2013 GVRBA sludge data, a graph of biosolids entering, leaving and remaining in the storage tanks was created (Figure 33: Seasonal Variations in Biosolids Storage in 2013). The remaining biosolids volume at end-of-month (EOM) is the differential of the flow in and out of the tank plus initial volume in tank from previous month. The dark line represents the total capacity of the existing biosolids storage tanks. According to the graph, approximately half of the tank volume is unused. Also, the values for land application show that the majority of biosolids are stored during summer months. 61 | P a g e Blackwards 7,000,000 Biosolids Volume (gal.) 6,000,000 5,000,000 4,000,000 3,000,000 2,000,000 1,000,000 0 Storage Capacity Sludge in tanks @EOM Addition to storage tanks Land Applied Figure 33: Seasonal Variations in Biosolids Storage in 2013 10.3 Required Biosolids Storage Capital Calculations of the volume of biosolids produced during the winter were completed and can be found in Appendix II: Mathcad Calculations. An additional two cylindrical tanks with volumes of 2 million gallons will be needed for holding typical biosolids production in the winter of 2025. A cost estimate for each was calculated based on an assumed cost per volume for a concrete tank construction. Each tank costs approximately $1.5 million. In the event of a longer winter period than typical, several contingencies for operation exist. First, the biosolids can be dewatered to higher than 4% total solids. Second, biosolids storage at GVRBA could be utilized. However, since the volumetric flow rates used in this calculation are from the year 2025, neither of these options should be needed for some time. While being stored over the winter, the biosolids are at risk of gravity thickening which would make removing the biosolids for land application difficult. For this reason, the tanks need an agitation or mixing system to keep solids suspended. The jet pump mixing system described for the holding tanks was again utilized here. This system is used mainly because the system can be shut off when not needed which is ideal for when the sludge is not needed, but when restarted 62 | P a g e Blackwards can agitate the contents of the tank in under 3 hours. This mixing system will cost $25,000 per tank. During atypical operation, biogas could build up in the biosolids storage tanks. Increasing pressure and gas composition causes a risk for explosion. For this reason a flare will be installed into the facility to relieve pressures. This flare will cost $21,000 to purchase and install.18 Biosolids quantity (dry metric tons) = Sludge Volume (gal. ) ∗ %TS ∗ 8.34 18 lb 1 ton ∗ gal 2000lb (1) http://www.epa.gov/gasstar/documents/installflares.pdf 63 | P a g e Blackwards 11. Pumping Station Design 11.1 Introduction Pumping sludge, a non-Newtonian fluid, presents a unique challenge. The complexity arises from variations in physical and chemical quality of sludge on a seasonal basis. Some factors affecting sludge pumping include viscosity, temperature and flow velocity. Frictional head loss varies with changes in viscosity of sludge at different %TS and temperature. This phenomenon should be considered in sizing pumps and pipes. Worst case operation and maximum viscosity of wastewater strength material should be researched and used as a basis for design. In addition, empirical findings in sludge pumping from previous work should be studied. 11.2 Pipe Selection Redundancy is required in piping and pumps. On the other hand, system components must be regularly cleaned and maintained for extended use (at or above design life) and for good hydraulic performance. As a result, flanges or couplings must be placed at appropriate locations (at bends, before and after a pump etc…) for easy maintenance. In addition, pipe bends should be minimized. In regards to pump selection, information regarding suitable sludge pumps is presented in Table 20: Advantages and Disadvantages of Progressive Cavity Pump. Progressive cavity pumps can be used to transport primary, secondary, thickened and digester sludge. It is a positive displacement pump. Darcy-Weisbach equation was used to calculate head loss in sludge transport. Each component of the system was drawn into the site plan shown in Section 13. Site Layout. Then pipes were drawn into the site plant between each component and the lengths of each section of pipe were combined for each route. Assumed cost of 8 inch inner diameter steel pipe is $4.7 per linear foot. 64 | P a g e Blackwards Table 20: Advantages and Disadvantages of Progressive Cavity Pump Pump Type Description Progressive Cavity Positive Displacement pump Chopper/ grinder Rotary Lobe Centrifugal pump Positive Displacement pump Advantages Accuracy of flow Small turbulence Ideal for fluid with varying viscosity Lower suction head Minimum clogging Reliable at large TS conc. Compact Higher flow rate and efficiency Disadvantages Fixed flow rate Regular stator replacement Large footprint Higher energy cost Not precise No particulates Table 21: Length of New Pipe Needed for Each Section of Route Pipe Route Primary Settling to Thickening Building Secondary Settling to Thickening Building Thickening Building to Sludge Holding Tanks Sludge Holding Tanks to Top of Thermophilic Digesters Bottom of Mesophilic Digesters to Dewatering Building Dewatering Building to Biosolids Storage Total Pipe Length (feet) 420 0 280 770 640 370 Cost $2000 $0 $1350 $3600 $3000 $1750 $11,700 65 | P a g e Blackwards 11.3 Pipe Diameters For each flow route, the head needed from a pump was calculated (See Appendix II: Mathcad Calculations). This included minor frictional losses, major frictional losses, and elevation change. Then all variables were kept constant except pipe diameter and the results graphed in Figure 34: Pumping Head Needed as a Function of Pipe Diameter. In Figure 34: Pumping Head Needed as a Function of Pipe Diameter, Pump 1 Head refers to the head needed from a pump to convey flow from the bottom of the holding/mixing tanks to the top of the thermophilic digesters. Pump 2 Head refers to the head needed from a pump to convey flow from the bottom of the mesophilic digesters to the dewatering building. Pump 3 Head refers to the head needed from a pump to convey flow from the dewatering building to the top of a biosolids storage facility. 80 Pump Head Needed (ft.) 70 60 50 40 Pump 1 Head 30 Pump 3 Head 20 Pump 2 Head 10 0 0 5 10 15 Pipe Diameter (in.) Figure 34: Pumping Head Needed as a Function of Pipe Diameter 66 | P a g e Blackwards 11.4 Cleaning Pipes Transport of solids from primary settling and secondary settling have a few associated problems. These materials are high in grease and tend to adhere to surfaces. As sludge is pumped through pipes, a film coating forms on the inner surface of the pipe. This film increases frictional losses which means the pumps must operate at a higher head in order to send the sludge through the pipe. One method of reducing the work needed from the pump is to periodically clean off this film. 11.5 Cleaning Methods In today’s water and sewage management pigging is a type of plug that is pumped through a water or sewer main to clean out the sludge, slime, or corrosion. The more commonly used type of pigging today is foam pigging which is very effective but has its limitations. The first limitation is the possibility of getting stuck in the pipe which then leads to digging out the main which is highly energy intensive. This system also would need to include pig docking stations where the pig can be added and removed from the piping system. The overall process is quite slow and labor intensive. Another option for pigging is a new and much easier system called ice pigging. This system involves a truck with a slurry of salty ice that will act as a semi-solid mixture that will clean the sides of the pipe as it is passed down. The major perks of a system like this are efficiency, ease of operation, and effectiveness. The efficiency is much better with this system because instead of pigging docks used with the foam pigs, the ice just needs a standard valve that can pass ice through. Another benefit of choosing the ice method is there is no possibility of the ice getting stuck. If the ice ever does get bound up it will quickly melt. Additionally the ice is far more effective in the removal of biofilm and sediment. The current practice is to increase the pressure which is not cleaning the piping system very well. If the ice system is implemented in the pipes it could raise pumping efficiency considerably. The icing option is very clear and it is our recommendation to the city of Wyoming CWP because of many factors but mainly the cost, ease of use, and effectiveness. 67 | P a g e Blackwards 12. Nutrient Removal/Recovery Nutrient removal from wastewater discharges is an increasing challenge for water authorities, as regulatory authorities tighten discharge standards to avoid eutrophication problems in receiving waters. Significant costs are associated with the extra treatment processes required to meet these new discharge standards. The most widely used technologies for nutrient removal include biological nitrification/denitrification for nitrogen removal and polymer flocculation for phosphorus removal. Both approaches result in the nutrient being made unrecoverable for possible use as a fertilizer. An alternative to these conventional technologies which can provide for recovery of the nutrient as a commercial fertilizer could be the production of struvite. Below are listed all of the options currently available for nutrient recovery with the associated benefits and detriments for the overall system. Table 22: Comparison of Nutrient Recovery Technologies Method Phosphorus Recovery Poor High High Nitrogen Recovery None None None Throughput Dewatering Chemical Addition None None High Multiple Screens High Poor Decanting Centrifuge High Good Polymer Flocculation High Good Nitrification / None High Low Poor none De-nitrification Traditional Ammonia None High Low Poor High Stripping DVO Approach Some Some High Poor Some Struvite High High High Average High From the preliminary research into these options, the team would suggest the implementation of the Struvite system in a few years. The system was successful on the pilot plant scale and is starting to be implemented in different waste water treatment plants in conjunction with an anaerobic digester. For the plant that would be similar to CWP with a two stage digestion and 25mgd was estimated at 13 million dollars. In addition to the removal and recovery of Phosphorus and Nitrogen, ammonia is also removed from the system. The team 68 | P a g e Blackwards would suggest waiting until the digester is fully operational and nutrient potential can be analyzed in detail before proceeding with any of the above options 19. 13. Site Layout Figure 35: Suggested Location of Digestion Facility 19 http://www.epa.gov/agstar/documents/conf12/10b_Dvorak-Frear.pdf 69 | P a g e Blackwards 14. Bench Scale Experiments 14.1 Digester Construction The team constructed a bench scale anaerobic digester for experimental purposes. The batch process was used for modeling since the proposed continuous flow method would be too difficult to maintain due to high cost, time, and space requirements. The digester was modeled using a 4.5-gal pressure cooker. The digester was fitted with a motor and two radial impellers that rotate at 5 rpm. To simulate thermophilic conditions, the digester was placed in a water bath at 50°C. A plastic tube directs biogas produced from digestion to an inverted, graduated cylinder. Seed for the digester was obtained from egg-shaped anaerobic digester at Grandville CWP. Raw and thickened WAS were collected from Wyoming CWP. Figure 36: Bench Scale Anaerobic Digester 70 | P a g e Blackwards 14.2 Operation and Testing Once the digester was fed with seed and feed sludge samples, the first test run was commenced on Thursday, February 25, 2014. The team discovered on the second day that almost all of the water has evaporated, and the sludge was cooked inside the digester and eventually spilled. The gas tube was plugged with sludge (see Figure 37: Trial Run Spill). To solve the problem, about two gallons of sludge was removed, and the gas tube was connected near the cover. The team performed COD, total solids and volatile solids experiments to measure system performance based on changes in organic content. COD experiment was not successful because the digester has high solids content. Result of the first experimental run is shown on Error! Reference source not found.. No general trend of TS and VS was observed over the test period. Figure 37: Trial Run Spill 71 | P a g e Blackwards 6% 35% 30% 25% 4% 20% 3% 15% 2% 10% Total Solids 1% 5% Total Volatile Solids 0% 24-Feb % Volatile Solids (avg.) % Total Solids (avg.) 5% 0% 25-Feb 26-Feb 27-Feb 28-Feb 1-Mar 2-Mar 3-Mar 4-Mar Sampling Dates Figure 38: Results from Trial Run For future experiments, the team decided on taking small samples every day, storing in refrigerator and performing solids test weekly. High-range COD vials were purchased for COD tests. The head motor was replaced with a 6rpm motor to solve mixing problems. To standardize sampling method, one team member was assigned to take all remaining daily samples. For the final run, the digester was operated for a total of 18 days. Over this period of time, a daily sample was collected, stored at 4 C° and burned weekly. 14.3 Results and Discussion For the final run, the digester was in operation for a total of 18 days. Over this period of time, sludge samples were collected daily, stored at 4°C and burned weekly. In Figure 39: Results from Final Digestion Run, it is clear that the volatile solids show a general downward progression which imply that solids degradation occurred and methane was produced. The total solids show a similar trend overall but the trend is not as apparent. The team believes that this is the result of the testing method. By burning weekly, the sample had time to degrade slightly in the refrigerator, thus the trend is increasing for some sampling periods, but there is an observable overall decreasing trend. 72 | P a g e Blackwards Figure 39: Results from Final Digestion Run 14.4 Safety To ensure safety of the team and other students working in the lab room, all experiments (except solids testing) were conducted inside a fume hood. Upon entering the lab, safety glasses and goggles were worn. Furthermore, all items in contact with test sludge and in the vicinity were thoroughly washed and disinfected. 73 | P a g e Blackwards 15. Total Cost of Proposed System Project Cost Digester System Holding Tanks Thickening Dewatering Storage Tanks Cogeneration Biogas Conditioning Gas Storage Contingency Total $15 M $1 M $600 K $1.2 M $3.1 M $1.5 M $507 K $300 K $2.1 M $22.9 M 16. Future Work Final design of a full-scale digestion system would include further analysis. The team proposes the following items should be researched: - Piloting (gas production, pollutant concentration in biosolids) - Instrumentation (SCADA system) - HVAC and Plumbing - Architectural and Structural Design - Geotechnical Analysis - Effective Nutrient Recovery 74 | P a g e Blackwards Acknowledgements The team would like to thank Dr. David B. Wunder (Ph.D., P.E.) for serving as the team’s advisor and providing valuable information throughout the semester. Myron Erickson (P.E.), superintendent at City of Wyoming CWP and Aaron Vis, Project Manager of GRVBA have been active participants in our work. The team appreciates their timely response to team requests and showing guidance. Phil Jasperse, manager of Calvin’s metal shop was instrumental in the construction and operation of our bench scale digester. Brain Vu from Grandville CWP has supplemented our bench scale efforts by supplying feed samples from the plant’s egg-shaped digester, and the team appreciates his assistance. Finally, the team is grateful for Jim Flamming (P.E.) and David Filipiak (CHMM) from Fishbeck, Thomson, Carr and Huber, Inc. (FTC&H) for serving us our industrial consultants in the design process and evaluating the team’s decisions. 75 | P a g e Blackwards References "Opportunities for Combined Heat and Power at Wastewater Treatment Facilities: Market Analysis and Lessons from the Field." U.S. Environmental Protection Agency: Combined Heat and Power Partnership (2011). Web. 14 Dec. 2013. <http://www.epa.gov/chp/documents/wwtf_opportunities.pdf>. Abbasi, Tasneem, and Tauseef Abbasi. "Anaerobic Digestion for Global Warming Control and Energy Generation—An Overview." Centre for Pollution Control and Environmental Engineering 16 (2012): 3228-242. Elsevier. Web. Arnett, Clifford, Joseph Farrell, Daniel Hull, Steven Krugel, Billy Turner, Warren Uhte, and John Willis. Biosolids Flow-Through Thermiphilic Treatment Process. Columbus Water Works, assignee. Patent US 2004/0011718 A1. 22 Jan. 2004. Print. Asada, Lucia, Gilberto Sundefeld, Carlos Alvarez, and Sidney Seckler. "Water Treatment Plant Sludge Discharge to Wastewater Treatment Works." Water Environment Research 82.5 (2010): 392-400. Print. Badger Laboratories and Engineering. 2008. Quality Assurance Manual. Bolzonella, David, Francesco Fatone, Silvia Di Fabio, and Franco Cecchi. "Mesophilic, Thermophilic and Temperature Phased Anaerobic Digestion Of Waste Activated Sludge." The Italian Association of Chemical Engineering. Web. 4 May 2014. Camp Dresser & McKee Inc. Charting the Future of Biosolids Management: Final Report. Rep. N.p.: Water Environment Research, 2011. Print. Clean Water Act, Part 503, section (a)(3)(ii)(D), page 20 D, Parry, and Loomis P. "DC Water Biosolids and Energy Process: Blue Plains Advanced Wastewater Treatment Plant." 18th European Biosolids & Organic Resources Conference and Exhibition. Web. 13 Apr. 2014. Day, Doug. "A Good Egg" TPO- Treatment Plant Operator Dec. 2013: 28-33. Web. 13 Apr. 2014. Digestion Systems for Livestock Manures. USDA. Eastern Research Group, Inc. Protocol for Quantifying and Reporting the Performance of Anaerobic Digestion Systems for Livestock Manures. Rep. Lexington: n.p., 2011. U.S. Environmental Protection Agency, 2011. Web. Environmental Research Information Center. Technology Transfer. Sludge Treatment and Disposal. Cincinnati, OH: Environmental Protection Agency, Environmental Research Information Center, Technology Transfer, 1978. Print. EPA "Opportunities for Combined Heat and Power at Wastewater Treatment Facilities: Market Analysis and Lessons from the Field." U.S. Environmental Protection Agency: Combined Heat and Power Partnership (2011). Web. 14 Dec. 2013. <http://www.epa.gov/chp/documents/wwtf_opportunities.pdf>. EPA “Biosolids Generation, Use, and Disposal in the United States.” N.p.: United States Environmental Protection Agency, 1999. Web. 2 Mar. 2014. <http://www.epa.gov/compost/pubs/biosolid.pdf >. Erickson, Ryan J. "Concrete Water Storage Tanks." Sunrise Engineering, n.d. Web. 1 Apr. 2014. <http://deq.state.wy.us/wqd/ 76 | P a g e Blackwards Goldstein, Jerome. "Around the World with Anaerobic Digestion." Biocycle Energy 44.4 (2003): 78-81. Print. Greer, Diane. "Funding Anaerobic Digestion Facilities." BioCycle Energy 52.3 (2011): 70-73. Print. Greer, Diane. "Vermont Builds Anaerobic Digestion Capacity." BioCycle Energy 52.10 (2011): 3841. Print. Informa Economics. National Market Value of Anaerobic Digestor Products. Rep. Innovation Center for US Dairy, Feb. 2013. Web. Kade, Farid. "Enhancing Solids Destruction from Anaerobic Municipal Digesters." M.S. thesis, Marquette University (2004). Web. Khalid, Azeem, Muhammad Arshad, Muzammil Anjum, Tariq Mahmood, and Lorna Dawson. "The Anaerobic Digestion of Solid Organic Waste." Waste Management 31.8 (2011): 1737-744. Print. Kleiven, Harald. Cambi; Recycling Energy. Norway: n.p., 2010. Print. Kopp, Ewert. "New Processes for the Improvement of Sludge Digestion and Sludge Dewatering." Influence of Surface Charge and Exopolysaccharides on the Conditioning Characteristics of Sewage Sludges. Ed. Hamburg Lengede. Vol. 5. N.p.: Springer, 1998. N. pag. Print. Mancl, Karen. Wastewater Treatment Principles and Regulations. Ohio State University, n.d. Web. 13 Nov. 2013. <http://ohioline.osu.edu/aex-fact/0768.html> Martin, J. 2007. A Protocol for Quantifying and Reporting the Performance of Anaerobic Meringa, Joshua. "Grandville's Clean Water Plant: First of its Kind in Michigan." the review Jan. 2013: 27-30. Web. 14 Dec. 2013. <http://www.mml.org/thereview/reviewjanfeb2013/offline/download.pdf>. Metcalf & Eddy., George Tchobanoglous, Franklin L. 1927- Burton, and H. David Stensel. Wastewater Engineering: Treatment and Reuse. 4th ed. Boston: McGraw-Hill, 2003. Panter, Keith, and David Auty. "Thermal Hydrolysis, Anaerobic Digestion and Dewatering of Sewage Sludge as a Best First Step in Sludge Strategy: Full Scale Examples in Large Projects in the UK and Strategic Study including Cost and Carbon Footprint." (n.d.): n. pag. Print. Pauley, Keith. Mid-Atlantic Technology, Research and Innovation Center. Rep. MARTIC Research, 23 Mar. 2010. Web. <http://depts.washington.edu/cpac/Activities/Meetings/Satellite/2010/Thursday/Paule y%20Biomass%20Gasification%20presentation.pdf>. United States. Environmental Monitoring Systems Laboratory. Office of Research and Development. Chemical Oxygen Demand: [test] Method 410.4. By James O'Dell. Cincinnati, OH: U.S. Environmental Protection Agency, 2001. Web. <http://water.epa.gov/scitech/methods/cwa/bioindicators/upload/2007_07_10_metho ds_method_410_4.pdf>. United States. Environmental Protection Agency. Office of Water. U.S. Environmental Protection Agency. By Engineering and Analysis Division. N.p., 2001. Web. <http://water.epa.gov/scitech/methods/cwa/bioindicators/upload/2008_11_25_metho ds_method_biological_1684-bio.pdf>. United States. Massachusetts Department of Environmental Protection. Tapping the Energy Potential of Municipal Wastewater Treatment: Anaerobic Digestion and Combined Heat and Power in Massachusetts. By Shutsu Wong. Massachusetts: n.p., 2011. Print. 77 | P a g e Blackwards United States. Water Environment Federation. Laboratory Evaluation of Thermophilic-Anaerobic Digestion to Produce Class A Biosolids. By Michael Aitken, Glenn Walters, Phillip Crunk, John Willis, Joseph Farrell, Perry Schafer, Cliff Arnett, and Billy Turner. 7th ed. Vol. 77. Stockholm: Water Environment Research, 2005. Print. United States. Water Environment Federation. Laboratory Evaluation of Thermophilic-Anaerobic Digestion to Produce Class A Biosolids. By Michael Aitken, Glenn Walters, Phillip Crunk, John Willis, Joseph Farrell, Perry Schafer, Cliff Arnett, and Billy Turner. 7th ed. Vol. 77. Stockholm: Water Environment Research, 2005. Print. US EPA "Alkaline Stabilization of Biosolids." Biosolids Technology Fact Sheet (2000).http://www.epa.gov/owm/septic/pubs/alkaline_stabilization.pdf. Web. 10 Apr. 2014. US EPA "Centrifuge Thickening and Dewatering." Biosolids Technology Fact Sheet (2000).http://water.epa.gov/scitech/wastetech/upload/2002_06_28_mtb_centrif uge_thickening.pdf. Web. 10 Apr. 2014. Water Environment Federation, Design of Municipal Wastewater Treatment Plants Task Force. Design of municipal wastewater treatment plants. Volume 3: Solids Processing and Management. 5th ed. Alexandria, VA: Water Environment Federation Press, 2010. Print. WEF Manual of Practice No. 11, Operation of Municipal Wastewater Treatment Plants. Alexandria, VA: Water Environment Federation, 2007. Web. 2 May 2014. Wilkinson, Kevin. "Development of On-Farm Anaerobic Digestion." BioCycle Global Jan. 2011: 4950. BioCycle Global. Web. Willis, John, and Perry Schafer. Advances in Thermophilic Anaerobic Digestion. Rep. no. 1114. Rancho Cordova: Brown and Caldwell, n.d. Print. 78 | P a g e Blackwards Appendix I: Team Management Eyosias Ashenafi Eyosias is a senior civil and environmental engineering student from Addis Ababa, Ethiopia. He enjoys playing soccer and studying maps in his free time. He also volunteers regularly with local organizations including Comprenew. He has worked on an environmental research project at Calvin. Two summers ago, he worked with middle school students in Detroit, teaching math and science. His roles in the project included project management and communication. Rachel Gaide Rachel is a senior chemical engineering student from Pueblo, CO. She enjoys baking, playing volleyball and softball, and reading historical fiction in her free time. She has interned at Xcel Energy for a summer and been an engineering Figure 40: Team Photo research assist for a summer. She volunteers as a Sunday school teacher and librarian for Trinity Lutheran Church and school. She is currently seeking full time employment following graduation in May 2014. Andrew Mitchell Andrew is senior civil and environmental engineering student from Iron Mountain, MI. He likes skiing or snowboarding, kayaking, and multiple motorsports. Andrew is captain of the Calvin men’s swim team and enjoys the athletic competition. He spent the last summer in Kenya Africa working with Bridging the Gap Africa building suspended bridges. Katherine Vogel Katherine Vogel grew up in Littleton, CO and is receiving a BSE with a concentration in Civil and Environmental engineering. She volunteers at Madison Square Church as a Sunday school small group leader and as a student representative for two governance committees at Calvin College. Katherine enjoys yoga, watching educational YouTube, reading science fiction, and baking in her free time. She has completed two summers of internship at Knight Piésold Consulting and is currently looking for full time employment in the Denver Metro Area. 79 | P a g e Blackwards Table 23: Work Breakdown Structure (Fall 2013) Task Define Scope and Objectives Background of Project (Introduction) Flows and Loads Tech Memo Determine Operating Capacity Responsible Person Thu 9/26/13 Thu 10/3/13 Thu 10/3/13 Team Thu 9/26/13 Thu 10/17/13 Thu 10/17/13 AM Thu 10/10/13 Fri 11/8/13 Fri 11/8/13 KV Mon Thu 11/7/13 Thu 11/7/13 KV 10/14/13 Fri 10/11/13 Fri 11/29/13 Fri 11/29/13 RG Start Finish Actual Finish Analytical Methods Tech Memo Solids Management Alternatives Tech Thu 9/26/13 Mon 12/2/13 Thu 12/19/13 Memo Stabilization Thu 10/3/13 Mon 12/2/13 Thu 12/19/13 Chemical Thu 10/3/13 Fri 10/11/13 Thu 12/19/13 Wet Chemical Thu 10/3/13 Thu 12/19/13 Thu 12/19/13 Lime Stabilization Thu 10/3/13 Thu 12/19/13 Thu 12/19/13 Time and Temp Thu 10/3/13 Thu 10/17/13 Thu 10/17/13 Biological Thu 10/3/13 Thu 10/24/13 Thu 10/24/13 Aerobic Digestion Thu 10/3/13 Fri 10/11/13 Fri 10/11/13 Anaerobic Thu 10/3/13 Thu 10/24/13 Thu 10/24/13 Wed TPAD Thu 10/3/13 Wed 10/16/13 10/16/13 Wed Thermophilic Thu 10/3/13 Wed 10/16/13 10/16/13 Wed Mesophilic Thu 10/3/13 Wed 10/16/13 10/16/13 Dewatering Thu 9/26/13 Thu 10/17/13 Thu 10/17/13 Thickening Thu 10/3/13 Thu 10/31/13 Thu 10/31/13 Government Regulations Mon 11/4/13 Mon 12/9/13 Mon 12/9/13 Major Components of Digester Thu 10/17/13 Thu 11/14/13 Thu 11/14/13 Wed Mixing method Thu 10/17/13 Wed 10/23/13 10/23/13 Reactor Type Thu 10/17/13 Thu 11/7/13 Thu 11/7/13 Heating Method Thu 10/24/13 Thu 10/31/13 Thu 10/31/13 Complete Process Flow Diagram Thu 10/10/13 Fri 11/29/13 Fri 11/29/13 Optimization of Biodigester Design Fri 11/1/13 Tue 12/3/13 Tue 12/3/13 PPFS 1st Draft Thu 9/26/13 Thu 11/28/13 Thu 11/28/13 PPFS Editing Fri 11/22/13 Sat 12/14/13 Sat 12/14/13 EA AM KV RG AM Team Team AM EA, AM EA, AM EA, AM RG EA KV Team Team Team Team EA RG Team Team 80 | P a g e Blackwards Table 24: Work Breakdown Structure (Spring 2014) Task Due Date Bench Scale Experiments Sampling Testing Every Sat. Data Input & Analysis Every Sat. Final Design Mathcad calculations Final Report UPDATE -2015 &2025 Comparison - Cost analysis - Thickening edit on PPFS -Dewatering edit on PPFS Regulations edit Edit PPFS Research TS coming out of a digester Digester shape and material Mixing for Digester Heat Exchanger Pumping Design Nutrient Recovery P&ID Site Layout Review Project Brief Odor Control Instrumentation Effects to Head Stream Cogeneration Excavation/digester design Team Photo 10Mar EA, AM EA, AM 17- 24Mar Mar KV, RG KV, RG 31Mar Week of 7- 14- 21- 285Apr Apr Apr Apr May ALL-daily KV, RG EA, KV, AM RG KV, RG EA, KV, AM RG EA, AM EA, AM EA, AM EA, AM KV, RG KV, RG EA, AM EA, AM EA ALL EA EA, KV EA RG KV AM AM EA RG RG EA, KV RG KV EA EA KV,AM KV,RG RG EA AM Assigned Tasks 81 | P a g e 12May KV, RG KV, RG Blackwards Engineering Fridays at Calvin Industrial Consultant Meeting Website Update Executive Summary for CEAC Senior Banquet & Projects Night Draft Design Report Final Design Report 14Mar ALL ALL 2Apr 11Apr 10May 25Apr 15May AM/RG ALL ALL ALL 82 | P a g e Blackwards Appendix II: Mathcad Calculations Part A: Sizing of System Components Anaerobic Digestion Calculation for Wyoming CWP Wyoming, MI WWTP Location Design Information - Projected 2025 values for biosolids parameters were used for sizing digester, determining heating requirements and evaluating gas production. Annual Average Flow Maximum Month Flow Primary Sludge (PS) gal QPS.ave 104516 day gal QPS.max 124218 day %Total Solids PS %TSPS.ave 3.5% %TSPS.max 3.5% Waste Activated Sludge (WAS) gal QWAS.ave 422902 day gal QWAS.max 498356 day %Total Solids WAS %TSWAS.ave 0.7% %TSWAS.max 0.7% gal QPS.ave 72.581 min gal QPS.max 86.263 min gal QWAS.ave 293.682 min gal QWAS.max 346.081 min Combined Sludge Production gal Qcombined.ave QPS.ave QWAS.ave 366.263 min Average Annual Flow Maximum Month Flow gal Qcombined.max QPS.max QWAS.max 432.343 min Thickening with Centrifuges Existing System Currently, there are two Andritz Bird centrifuges in the Sludge Thickening Building. Centrifuge capacity per unit gal 5 gal Birdcapacity 265 3.816 10 min day Number of units Birdnumber 2 Proposed Addition (for thickening primary sludge) Number of centrifuge unit Capacity of added centrifuge %Thickening Centrifuge add 1 Centrifuge cap 265gpm %TScentri 4% 83 | P a g e Blackwards Addition of a third centrifuge and a rehab of existing centrifuges is planned to occur in the next 10 years. Qthick.PSave QPS.ave %TSPS.ave Qthick.WAS .ave %TScentri 63.508 QWAS.ave %TSWAS.ave Qthick.PS.maxmonth %TScentri QPS.max %TSPS.max gal min 51.394 75.48 gal min gal %TScentri min QWAS.max %TSWAS.max gal Qthick.WAS.maxmonth 60.564 %TScentri min Combined Flow to Sludge Holding Tanks - Based on Annual Average flow condition (2025 projected) QPS.ave %TSPS.ave QWAS.ave %TSWAS.ave Qholding.ave 0.165mgd %TScentri %TScentri - Based on maximum month condition (2025 projected) QPS.max %TSPS.max QWAS.max %TSWAS.max Qholding.max 0.2 mgd %TScentri %TScentri Sludge Storage at Holding Tanks There are two sludge holding tanks at Wyoming CWP with mixing. Sludge holding tank volume per unit Number of sludge holding tanks at present Calculation for required storage Volhold.present 150000gal Numberhold.present 2 Storagereq 3day Qholding.max 5 Storage req 5.877 10 gal Difference between required tankage and current capacity Vdiff Storagereq Volhold.present Numberhold.present 5 Proposed addition(s) Sludge holding tank volume per unit Number of sludge holding to be added Vdiff 3 10 gal 5 Volhold.new 1.5 10 gal Numberhold.new 2 During emergency flow conditions, GVRBA facilities i.e. flow routing to Grand Rapids WWTP can be utilized. 84 | P a g e Blackwards Design I: Sizing of Cylindrical Digesters Thermophilic Design (55 degrees Celsius) Digestion System Properties -Thermophilic operation (high VS and pathogen destruction) - No recycle stream (HRT=MCRT) - Single-stage, high-rate digester (short HRT) - Steady state operation - Complete mix reactors Operational Temperature Tthermo 55°C HRT 10day Hydraulic Retention Time Feed to digester Qfeed Qholding.ave 6 Total digester volume required Voldigesters.max Qholding.ave HR T 1.65 10 gal Allowance for grit accumulation on top, mixing equipment, gas collection etc... 6 FinalVoldigesters 1.2Voldigesters.max 2 10 gal There will be a total of three digester tanks including a redundant tank of equal size. Numberdigester 2 Number of operational digesters Digester volume per tank FinalVoldigesters UnitVolumedigester Numberdigester UnitVolumedigester 992756.10 gal Designed digester is cylindrical with equal radius and height. 1 Radius/height UnitVolumedigester rdigester Boundary Area of Digester Lateral Surface Area Top/bottom Area of Digester 3 34.8ft A lateral 2 rdigester 2 7.62 10 ft 3 2 A top rdigester 2 3.81 10 ft 3 2 The digesters will be constructed entirely above ground since the water table is located 12-15ft below ground surface. 85 | P a g e Blackwards Part B: Methane Production Volatile Solids Reduction (VSR) Approach Design Information Design VSS/TSS ratio of treatment plant is 0.8 Influent TSS concentration Average annual mg TSScave.annual 237 L Maximum month mg TSScmax.month 258 L TSS removal rate %TSSremo.pri 49% %TSSremo.sec 93% Primary Clarifiers Secondary Clarifiers (assumed) I. Present Condition (2014) Average annual wastewater flow Qann.2014 14.7mgd TSS loading (lb./day) Average annual 4 lb TSSave.2014 Qann.2014 TSScave.annual 2.907 10 day Maximum month 4 lb TSSmax.2014 Qann.2014 TSScmax.month 3.165 10 day Volatile Solids entering digesters Average annual condition VSstart.ave.2014 0.8TSSave.2014%TSSremo.pri 1 %TSSremo.pri TSSave.2014%TSSremo.sec 4 lb VSstart.ave.2014 2.243 10 day Maximum month condition VSstart.max.2014 0.8TSSmax.2014 %TSSremo.pri 1 %TSSremo.pri TSSmax.2014 %TSSremo.sec 4 lb VSstart.max.2014 2.442 10 day Loading rate VSstart.ave.2014 lb loading ave 0.084 2000000gal 3 ft day loading max VSstart.max.2014 2000000gal lb 0.091 Normal loading range= 0.05-0.2 3 ft day lb 3 ft day 86 | P a g e Blackwards % Volatile solids destruction (Empirical formula from Metcalf and Eddy, Page 1513) Design I: Thermophilic digestion (cylindrical) SRTI 10 %VSdes.I 13.7ln SRTI 18.9 % 50.45% Sludge retention time % Volatile solids destruction Higher destruction requires longer SRT and subsequently bigger digester tanks. Since there is enough capacity in sludge holding, the SRT can be varied to increase volatile solids destruction. Based on diminishing returns, a 10-day digestion period gives an optimum VSS reduction. Design II: TPAD digestion (egg shaped mesophilic reactor) SRTII 16 %VSdes.II 13.7ln SRTII 18.9 % 56.88% Sludge retention time % Volatile solids destruction lbm biogas 0.062 3 ft Density of digester gas Biogas production Design I: Thermophilic digestion (cylindrical) 4 lb Mass biogas.ave.I.2014 %VSdes.I VSstart.ave.2014 1.131 10 day 4 lb Mass biogas.max.I.2014 %VSdes.I VSstart.max.2014 1.232 10 day Design I: TPAD digestion (egg shaped mesophilic reactor) 4 lb Mass biogas.ave.II.2014 %VSdes.II VSstart.ave.2014 1.276 10 day 4 lb Mass biogas.max.II.2014 %VSdes.II VSstart.max.2014 1.389 10 vol biogas.ave.14 Mass biogas.ave.II.2014 biogas 5 ft 2.058 10 day 3 day Biogas production (ft3/lb VSS destroyed) biogasVSS 15 ft 3 lb Methane Production Assume 60% of biogas (digester gas) is methane. Design I: Thermophilic digestion (cylindrical) 3 5 ft VCH4.ave.I.2014 0.6Mass biogas.ave.I.2014 biogasVSS 1.02 10 day 3 5 ft VCH4.max.I.2014 0.6Mass biogas.max.I.2014 biogasVSS 1.11 10 day Design II: TPAD digestion (egg shaped mesophilic reactor) 5 ft 3 VCH4.ave.II.2014 0.6Mass biogas.ave.II.2014 biogasVSS 1.15 10 day 3 5 ft VCH4.max.II.2014 0.6Mass biogas.max.II.2014 biogasVSS 1.25 10 day 87 | P a g e Blackwards II. 2025 Design Condition Qann.2025 24mgd Average annual wastewater flow TSS loading (lb/day) Average annual 4 lb TSSave.2025 Qann.2025 TSScave.annual 4.747 10 day Maximum month 4 lb TSSmax.2025 Qann.2025 TSScmax.month 5.167 10 day Volatile Solids entering digesters Average annual condition VSstart.ave.2025 0.8TSSave.2025%TSSremo.pri 1 %TSSremo.pri TSSave.2025%TSSremo.sec 4 lb VSstart.ave.2025 3.662 10 day Maximum month condition VSstart.max.2025 0.8TSSmax.2025 %TSSremo.pri 1 %TSSremo.pri TSSmax.2025 %TSSremo.sec lb 4 VSstart.max.2025 3.986 10 day Loading rate VSstart.ave.2025 lb loading ave.2025 0.137 2000000gal 3 ft day loading max.2025 Normal range= 0.05-0.2 VSstart.max.2025 2000000gal 0.149 lb 3 ft day lb 3 ft day Biogas production Design I: Thermophilic digestion (cylindrical) 4 lb Mass biogas.ave.I.2025 %VSdes.I VSstart.ave.2025 1.847 10 day 4 lb Mass biogas.max.I.2025 %VSdes.I VSstart.max.2025 2.011 10 day Design II: TPAD digestion (egg shaped mesophilic reactor) 4 lb Mass biogas.ave.II.2025 %VSdes.II VSstart.ave.2025 2.083 10 day 4 lb Mass biogas.max.II.2025 %VSdes.II VSstart.max.2025 2.268 10 volbiogas.ave.25 Mass biogas.ave.II.2025 biogas 5 ft 3.36 10 day 3 day 88 | P a g e Blackwards Methane Production Assume 60% of biogas (digester gas) is methane. Design I: Thermophilic digestion (cylindrical) 3 5 ft VCH4.ave.I.2025 0.6Mass biogas.ave.I.2025 biogasVSS 1.66 10 day 5 ft 3 VCH4.max.I.2025 0.6Mass biogas.max.I.2025 biogasVSS 1.81 10 day Design II: TPAD digestion (egg shaped mesophilic reactor) 3 5 ft VCH4.ave.II.2025 0.6Mass biogas.ave.II.2025 biogasVSS 1.87 10 day 3 5 ft VCH4.max.II.2025 0.6Mass biogas.max.II.2025 biogasVSS 2.04 10 day Energy Production from Methane EnergyCH4 650 Energy content of methane gas BT U ft Electric efficiency %effec 38.92% Availability in a year avail 98% 3 *Since it costs more to buy natural gas than sell on a volume basis, it is imperative to utilize biogas produce on-site for heating purposes. Power Generation 2014 Average Flow conditions Design I: Thermophilic digestion (cylindrical) Average annual Powerave.I.2014 %effec EnergyCH4VCH4.ave.I.2014 avail 7 BT U Powerave.I.2014 2.52 10 day Design II: TPAD system Average annual Powerave.II.2014 %effec EnergyCH4VCH4.ave.II.2014 avail 7 BT U Powerave.II.2014 2.85 10 day 89 | P a g e Blackwards 2025 Average Flow conditions Design I: Thermophilic digestion (cylindrical) rated Average annual electrical power of 380kW per unit. There will be a total of two G8-380 model Tech 3 Solutions Turbo Charged cogeneration systems with a Powerave.I.2025 %effec EnergyCH4VCH4.ave.I.2025 avail 7 BT U Powerave.I.2025 4.12 10 day Design II: TPAD system Average annual Powerave.II.2025 %effec EnergyCH4VCH4.ave.II.2025 avail 7 BT U Powerave.II.2025 4.65 10 day Cogeneration System Capacity TPAD system was selected for design after comparing biosolids quality and energy generation potential. The team used maximum methane gas production rate to size cogeneration system. Cogen %effec EnergyCH4VCH4.max.II.2025 5 Cogen 6.305 10 W 90 | P a g e Blackwards Calculation of Storage Space Needed Assuming a month is 31 days month 31day Assuming that we need 3 and a half months storage to get through winter StorageNeeded 3month 93day Flow Rate of sludge leaving the holding/mixing tank for average conditions Qholding 0.16546mgd Percent Total Solids leaving the holding tank TSholding 0.04 Mass fraction Flow Rate of Solids entering digester Assume that density of solids = density of water 3 gal Solidsholding Qholding TSholding 6.618 10 day Percent Total Volatile Solids of Total Solids for flow entering Digester TVS 0.80 Flow Rate of Volatile Solids entering digester Assume that density of volatile solids = density of solids 3 gal VolatileSolidsholding Qholding TSholding TVS 5.295 10 day Flow Rate of Fixed Solids Entering digester 3 gal FixedSolidsholding Qholding TSholding ( 1 TVS) 1.324 10 day Flow Rate of Water Entering Digester 5 gal Water holding Qholding 1 TSholding 1.588 10 day Reduction in Volatile Solids within Digester Reduction 0.5 Flow Rate of Volatile Solids leaving Digester and Entering Dewatering 3 gal VolatileSolidspostDigestion Reduction VolatileSolidsholding 2.647 10 day Flow Rate of Total Solids Percentage leaving digester and entering dewatering 3 gal SolidspostDigestion VolatileSolidspostDigestion FixedSolidsholding 3.971 10 day Flow Rate of Sludge Poste Digestion 5 gal QpostDigestion Water holding SolidspostDigestion 1.628 10 day 91 | P a g e Blackwards Percent Total Solids leaving digester and entering dewatering TSpostDigestion SolidspostDigestion QpostDigestion 0.024 Percent Total Solids leaving dewatering TSpostDewatering 0.04 Flow Rate of Sludge leaving QpostDewatering QpostDigestion TSpostDigestion TSpostDewatering 4 gal 9.928 10 day Current Storage on Site Storagecurrent 6000000gal How Long Current Storage can handle normal flow Storagecurrent TimeCurrentStorage 60.438day QpostDewatering Storage Needed for Winter in No Dewatering Scenario 7 Storagenodewatering QpostDigestion StorageNeeded 1.514 10 gal Ntanks newNoDewatering Storagenodewatering Storagecurrent 2000000gal 4.571 Storage Needed for Winter in Dewatering Scenario 6 Storagedewatering QpostDewatering StorageNeeded 9.233 10 gal NewtanksDewatering Storagedewatering Storagecurrent 2000000gal 1.616 Cost of Tanks VolumeoneTank 2000000gal 0.65 UnitCost gal 6 Cost oneTank VolumeoneTank UnitCost 1.3 10 6 Cost total 2 Cost oneTank 2.6 10 92 | P a g e Blackwards Pumping Station Design Head Needed for Pump that Takes Sludge from Mixing/Holding Tanks to Digestion Tanks Q1 115gpm Average Flow Rate D1 8in Diameter of Pipe Lpipe1 770ft Length of Pipe Actual distance between buildings is 660 ft. Assume an extra 25 ft of pipe inside each 2 D1 building to handle flow between units 2 A cross1 0.349ft Cross Sectional Area of Pipe 4 v 1 Q1 A cross1 0.734 ft s Flow Velocity Major Headloss Due to Friction with Pipe Use Figure 19-4 from Chapter 19 of System Design for Sludge Pumping by Carl N. Anderson and David J. Hanna This figure can be used to get frictional losses within a pipe flowing with sludge from the frictional losses within a pipe flowing with water, the TS percentage, and the velocity within the pipe 93 | P a g e Blackwards factor 1 80 Factor relates headloss for water to headloss for sludge Use Darcy Weisbach formula for head calculation of water flowing within pipe Kinematic Viscosity Use coldest temperature for viscosity (10 deg Celsius) which will be worst case Viscosity Value taken from engineeringtoolbox.com 2 6m H20 1.30710 s v 1 D1 4 ReH201 3.478 10 H20 Calculating Reynold's Number Assume laminar flow 64 3 f1 1.84 10 ReH201 Calculating friction factor 2 h LfH201 f1 Lpipe1 v 1 D1 2g 0.018ft hLf1 hLfH201factor 1 1.424ft Calculating Frictional head loss Relate headloss for water to headloss for sludge Friction Losses due to bends in pipe nbend1 11 Kbend 0.75 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 for a branch flow through a cross fitting or Tee fitting KbendTot1 nbend1 Kbend 8.25 Friction Losses due to in line valves nvalve1 22 Kvalve 2 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-7, pg. 899 for a Rubber flapper check valve with a flow velocity less than 6ft/s KvalveTot1 nvalve1Kvalve 44 Frictional losses due to transition from tank to pipe nentrance1 1 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 for a rounded entrance flush with side of tank Kentrance 0.25 KentranceTot1 nentrance1 Kentrance 0.25 94 | P a g e Blackwards Frictional losses due to transition from pipe to tank nexit1 1 Kexit 1 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 KexitTot1 nexit1Kexit 1 Total Energy Loss Coefficients KSum1 KbendTot1 KvalveTot1 KentranceTot1 KexitTot1 53.5 Total Minor Headloos 2 h Lminor1 KSum1 v 1 2g 0.448ft Use energy equation Relating surface of fluid in mixing/holding tanks to surface of fluid in digester System Description Assume constant pipe diameter (Ai=Af) therefore vi=vf because Qi = Qf vi1 v1 vf1 v1 Althought system is not explosed to atmosphere, the system is not pressured relative to outside system. Therefore pressure at surface level is 1 atmosphere. Pi1 1atm Pf1 1atm Z i refers to the water surface heght within the mixing / holding tank. Conseratively this number was chosen for a tank half full. zi1 640ft Z f refers to the sludge surface height inside digester above sea level. zf1 685ft Fluid Properties 999.7 kg Specific Gravity of water 3 m v 2 v 2 P Pi1 f1 i1 f1 h p1 zf1 zi1 h Lf1 h Lminor1 46.871ft 2g g g 2g 95 | P a g e Blackwards Head Needed for Pump that Takes Sludge from Digestion to Dewatering Q2 115gpm Average Flow Rate D2 8in Diameter of Pipe Lpipe2 640ft Length of Pipe 2 A cross2 v 2 D2 Q2 A cross2 4 0.349ft 0.734 ft s 2 Actual distance between buildings is 660 ft. Assume an extra 25 ft of pipe inside each building to handle flow between units Cross Sectional Area of Pipe Flow Velocity Major Headloss Due to Friction with Pipe Use Figure 19-4 from Chapter 19 of System Design for Sludge Pumping by Carl N. Anderson and David J. Hanna This figure can be used to get frictional losses within a pipe flowing with sludge from the frictional losses within a pipe flowing with water, the TS percentage, and the velocity within the pipe 96 | P a g e Blackwards factor 2 80 Factor relates headloss for water to headloss for sludge Use Darcy Weisbach formula for head calculation of water flowing within pipe Kinematic Viscosity Use coldest temperature for viscosity (10 deg Celsius) which will be worst case Viscosity Value taken from engineeringtoolbox.com 2 6m H20 1.30710 s v 2 D2 4 ReH202 3.478 10 H20 Calculating Reynold's Number Assume laminar flow 64 3 f2 1.84 10 ReH202 Calculating friction factor 2 h LfH202 f2 Lpipe2 v 2 D2 2g 0.015ft hLf2 hLfH202factor 2 1.183ft Calculating Frictional head loss Relate headloss for water to headloss for sludge Friction Losses due to bends in pipe nbend2 6 Kbend 0.75 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 for a branch flow through a cross fitting or Tee fitting KbendTot2 nbend2 Kbend 4.5 Friction Losses due to in line valves nvalve2 12 Kvalve 2 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-7, pg. 899 for a Rubber flapper check valve with a flow velocity less than 6ft/s KvalveTot2 nvalve2Kvalve 24 Frictional losses due to transition from tank to pipe nentrance2 1 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 for a rounded entrance flush with side of tank Kentrance 0.25 KentranceTot2 nentrance2 Kentrance 0.25 97 | P a g e Blackwards Frictional losses due to transition from pipe to tank nexit2 0 Kexit 1 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 KexitTot2 nexit2Kexit 0 Total Energy Loss Coefficients KSum2 KbendTot2 KvalveTot2 KentranceTot2 KexitTot2 28.75 Total Minor Headloos 2 h Lminor2 KSum2 v 2 2g 0.241ft Use energy equation Relating surface of fluid in mixing/holding tanks to surface of fluid in digester System Description Assume constant pipe diameter (A1=A2) therefore v1=v2 because Q1 = Q2 vi2 v2 vf2 v2 Althought system is not explosed to atmosphere, the system is not pressured relative to outside system. Therefore pressure at surface level is 1 atmosphere. Pi2 1atm Pf2 1atm Z 1 refers to the sludge surface heght in the digesters. Conseratively this number was chosen for a tank half full. zi2 590ft Z 2 refers to the height of the dewatering centrifuges above sea level. zf2 600ft Fluid Properties 999.7 kg Specific Gravity of water 3 m v 2 v 2 P Pi2 f2 i2 f2 h p2 zf2 zi2 h Lf2 h Lminor2 11.424ft 2g g g 2g 98 | P a g e Blackwards Head Needed for Pump that Takes Sludge from Dewatering to Storage Tanks Q3 115gpm Average Flow Rate D3 8in Diameter of Pipe Lpipe3 370ft Length of Pipe 2 A cross3 v 3 D3 Q3 A cross3 4 0.349ft 0.734 ft s 2 Actual distance between buildings is 660 ft. Assume an extra 25 ft of pipe inside each building to handle flow between units Cross Sectional Area of Pipe Flow Velocity Major Headloss Due to Friction with Pipe Use Figure 19-4 from Chapter 19 of System Design for Sludge Pumping by Carl N. Anderson and David J. Hanna This figure can be used to get frictional losses within a pipe flowing with sludge from the frictional losses within a pipe flowing with water, the TS percentage, and the velocity within the pipe 99 | P a g e Blackwards factor 3 80 Factor relates headloss for water to headloss for sludge Use Darcy Weisbach formula for head calculation of water flowing within pipe Kinematic Viscosity Use coldest temperature for viscosity (10 deg Celsius) which will be worst case Viscosity Value taken from engineeringtoolbox.com 2 6m H20 1.30710 s v 3 D3 4 ReH203 3.478 10 H20 Calculating Reynold's Number Assume laminar flow 64 3 f3 1.84 10 ReH203 Calculating friction factor 2 h LfH203 f3 Lpipe3 v 3 D3 2g 3 8.55 10 hLf3 hLfH203factor 3 0.684ft ft Calculating Frictional head loss Relate headloss for water to headloss for sludge Friction Losses due to bends in pipe nbend3 2 Kbend 0.75 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 for a branch flow through a cross fitting or Tee fitting KbendTot3 nbend3 Kbend 1.5 Friction Losses due to in line valves nvalve3 9 Kvalve 2 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-7, pg. 899 for a Rubber flapper check valve with a flow velocity less than 6ft/s KvalveTot3 nvalve3Kvalve 18 Frictional losses due to transition from tank to pipe nentrance3 0 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 for a rounded entrance flush with side of tank Kentrance 0.25 KentranceTot3 nentrance3 Kentrance 0 100 | P a g e Blackwards Frictional losses due to transition from pipe to tank nexit3 1 Kexit 1 K value taken from Pumping Station Design edited by Robert L. Sanks Table B-6, pg. 898 KexitTot3 nexit3Kexit 1 Total Energy Loss Coefficients KSum3 KbendTot3 KvalveTot3 KentranceTot3 KexitTot3 20.5 Total Minor Headloos 2 h Lminor3 KSum3 v 3 2g 0.172ft Use energy equation Relating surface of fluid in mixing/holding tanks to surface of fluid in digester System Description Assume constant pipe diameter (A1=A2) therefore v1=v2 because Q1 = Q2 vf3 v3 vi3 v3 Althought system is not explosed to atmosphere, the system is not pressured relative to outside system. Therefore pressure at surface level is 1 atmosphere. Pf3 1atm Pi3 1atm Z 1 refers to the sludge surface heght in the digesters. Conseratively this number was chosen for a tank half full. zi3 600ft Z 2 refers to the height of the dewatering centrifuges above sea level. zf3 640ft Fluid Properties 999.7 kg Specific Gravity of water 3 m v 2 v 2 P Pi3 f3 i3 f3 h p zf3 zi3 h Lf3 h Lminor3 40.856ft 2g g g 2g 101 | P a g e Blackwards Cost Analysis of Holding Tank / Centrifuge Configuration Assume Concrete as Tank Material Costtank 0.65 1 gal Taken from page 6 of "Concrete Water Storage Tanks" by Ryan J. Erickson Assume 3 days of storage (Hydralic Residence Time [HRT]) needed in holding tank HRT 3day Assume max month flow conditions gal QOriginalPrimary 86.3 min TSOriginalPrimary 0.035 gal QOriginalSecondary 346.1 min TSOriginalSecondary 0.007 Assume centrifuge thicken to 4% TSThick 0.04 Volume of holding tanks on site Volexisting 150000gal Calculate New Flow Rates QThickPrimary QOriginalPrimary TSOriginalPrimary TSThick QThickSecondary QOriginalSecondary 75.513 TSOriginalSecondary TSThick gal min 60.568 gal min Calculate Flow into Holding Tank for Each Alternative gal Qalt1 QOriginalPrimary QThickSecondary 146.868 min gal Qalt2 QOriginalPrimary QOriginalSecondary 432.4 min gal Qalt3 QThickPrimary QThickSecondary 136.08 min Calculate Volume of Holding Tank Necessary for Each Alternative 5 Volalt1 HRT Qalt1 6.345 10 gal 6 Volalt2 HR T Qalt2 1.868 10 gal 5 Volalt3 HR T Qalt3 5.879 10 gal 102 | P a g e Blackwards Calculate Volume Still Needed for Each Holding Tank for Each Alternative 5 VolneededAlt1 Volalt1 Volexisting 4.845 10 gal 6 VolneededAlt2 Volalt2 Volexisting 1.718 10 gal 5 VolneededAlt3 Volalt3 Volexisting 4.379 10 gal Calculate Cost of New tanks 5 Cost alt1 VolneededAlt1 Cost tank 3.149 10 6 Cost alt2 VolneededAlt2 Cost tank 1.117 10 5 Cost alt3 VolneededAlt3 Cost tank 2.846 10 Piping Piping distances have been estimated using a satellite photo and using a car parking spot as a reference point. Typical Car Spot is 7.5 ft to 9 ft wide by 16 ft to 20 ft long We'll say a spot is 18 ft long Lengthcar 18ft Cost of piping Assume cast iron, 6" diameter. Number taken from RSMeans Building Construction Cost Data,2009 Costpipe 44 ft Parking lengths between primary settling and thickening PrimaryToThickening 35 LPrimaryToThickening Lengthcar PrimaryToThickening 630ft Parking lengths between secondary settling and thickening SecondaryToThickening 34 LSecondaryToThickening Lengthcar SecondaryToThickening 612ft Parking lengths between primary settling and mixing PrimaryToMixing 27 LPrimaryToMixing Lengthcar PrimaryToMixing 486ft Parking lengths between secondary settling and mixing SecondaryToMixing 55 LSecondaryToMixing Lengthcar SecondaryToMixing 990ft 103 | P a g e Blackwards Parking lengths between mixing and second thickening building MixingToThickening2 15 Parking lengths between mixing and second thickening building ThickeningToMixing 17 LThickeningToMixing Lengthcar ThickeningToMixing 306ft Length of Pipe Needed for Each Alternative Pipealt1 Lengthcar (2MixingToThickening2 ) 540ft 3 Pipealt2 Length car ( 2SecondaryToMixing 2ThickeningT oM ixing) 2.592 10 ft 3 Pipealt3 Length car ( 2PrimaryToThickening ThickeningT oM ixing) 1.566 10 ft Cost of Pipe Needed for Each Alternative 4 Cost pipeAlt1 Cost pipe Pipealt1 2.376 10 5 Cost pipeAlt2 Cost pipe Pipealt2 1.14 10 4 Cost pipeAlt3 Cost pipe Pipealt3 6.89 10 MixingToDigestion 37 LMixingToDigestion Lengthcar MixingToDigestion 666ft DigestionToDewatering 37 LDigestionToDewatering Lengthcar DigestionToDewatering 666ft DewateringToStorage 20 LDewateringToStorage Lengthcar DewateringToStorage 360ft DigestionToCogen 11 LDigestionToCogen Lengthcar DigestionToCogen 198ft HoldingToCogen 51 LHoldingToCogen Lengthcar HoldingToCogen 918ft StorageToCogen 44 LStorageToCogen Lengthcar StorageToCogen 792ft 104 | P a g e Blackwards Appendix III: Hydraulic Profile A Hydraulic Profile was created of the proposed system from information given by the Wyoming CWP. Where information was not available, a conservative estimate was chosen. In the drawing, the Primary and Secondary settling tanks are not shown to scale. Pipe lengths were chosen using the drawing of the site layout in AutoCAD 2012. 105 | P a g e Blackwards 106 | P a g e Blackwards Appendix IV: Manual of Laboratory Tests Solid Concentration Test Purpose The purpose of this experiment is determine the solid concentration present in a sludge sample. Physical and thermal treatment methods are applied to measure suspended and dissolved solids (TSS and TDS) in addition to volatile and fixed solids present in each grouping. Treatment facilities perform solids test for quality control. Since we will not use filters to determine TDS and TSS, total solids can be found by following equation: %𝐓𝐨𝐭𝐚𝐥 𝐒𝐨𝐥𝐢𝐝𝐬 = %𝐅𝐢𝐱𝐞𝐝 𝐒𝐨𝐥𝐢𝐝𝐬 (𝐅𝐒) + %𝐕𝐨𝐥𝐚𝐭𝐢𝐥𝐞 𝐒𝐨𝐥𝐢𝐝𝐬 (𝐕𝐒) TS and VS can be determined by exposing sludge sample to different temperatures for a duration of time. For our purposes, we are interested in TS and VSS levels of sludge samples pre- and postdigestion. VSS is a measure of the organic matter and microbial population of a waste stream and thus serves as an indicator of the methane production potential. In this experiment, three dishes with sludge samples will be tested for repeatability and calculating averages in each test run. Equipment Used 100mL aluminum dishes, muffle furnace (Lucifer), drying oven, analytical balance and thermometer Procedure (Adapted from Method 2540B and 2540E of Standard Methods book, 19 th Edition) 1. Label three clean empty dishes with date. 2. Place the dishes in Lucifer furnace for 1 hour at 550°C (1022°F). 3. Put dishes in the decanter until ready for use. 4. Take out of decanter and weigh the dishes. This is the weight of empty dish. Use table below for recording. 5. Obtain approximately 30mL of slurry sludge (V). 6. Pulverize thoroughly with mortar and pestle. 7. Weigh the dish with sludge. This is the weight of the wet dish. 8. Place samples in furnace for overnight at 103°C (217°F). Only small amount of organic matter is lost at this temperature. 9. Remove from furnace and place in desiccator to cool. 10. Weigh this sample. This is the weight of the dry sample at 103°C. 11. Heat the furnace to 550°C (1022°F), place samples and heat for one hour. 12. Let the samples cool down inside the furnace for 20 minutes with doors open. 13. At the end of the hour, remove samples and let them cool in desiccator. 14. Weigh this sample. This is the weight of the burned sample at 550°C. 15. Perform TS and TVS calculations. 107 | P a g e Blackwards Table 25: Solids Measurement Datasheet Parameter Dish 1 Weight of empty dish, Wdish (mg) Weight of wet dish, Wwet (mg) Weight of dry sample at 103°C, W103 (mg) Weight of burned sample at 550°C, W550c (mg) Calculations 𝑾 Dish 2 Dish 3 −𝑾 %𝑻𝑺 = (𝑾𝟏𝟎𝟑−𝑾𝒅𝒊𝒔𝒉 ) ∗ 𝟏𝟎𝟎 𝒘𝒆𝒕 𝑾 𝒅𝒊𝒔𝒉 −𝑾 %𝑽𝑺 = (𝑾 𝟏𝟎𝟑−𝑾 𝟓𝟓𝟎 ) ∗ 𝟏𝟎𝟎 𝟏𝟎𝟑 𝒅𝒊𝒔𝒉 *Duplicate measurements should agree within 5% of the average (AWWA’s Standard book) 108 | P a g e Blackwards Chemical Oxygen Demand (COD) Test Purpose The purpose of this experiment is to determine the amount of organic matter present in a sample that could be oxidized by a strong reducing agent such as sulfuric acid. It is normally reported in units of mg/L. Previous research has shown that correlation between COD and 5-day BOD could be derived. Standard potassium hydrogen phthalate (KHP) solutions will be used to create calibration curve for COD. A 425 mg/L KHP solution has a theoretical COD value of 500mg/L. Safety Precaution COD vials contain high concentration of sulfuric acid and some mercury sulfate which may cause skin burn and cancer. Thus the experiment should be performed in fume hood. MSDS for the COD vials can be found in the lab binder and team’s folder. Equipment/materials Used Pierce Reacti-Therm digester block, CHEMetrics COD vials, plastic vial rack, Spectronic 20D+ spectrophotometer analytical balance, micropipette, standard KHP solutions, amber bottles and thermometer Procedure (Adapted from CHEMetrics Test Procedure Manual) 1. Obtain 20mL sludge sample using amber bottles and thoroughly mix. 2. Label vials using masking tape and organize on white rack. 3. Heat the digester block to 150°C (7.6 on the scale) inside fume hood. To measure T°, insert thermometer at the small slot on the block. 4. Carefully remove cap from vials avoiding physical contact and gas inhale. 5. Using micropipette, place 2mL of sample into vials. 6. Close cap tightly and invert vials five times for mixing holding the cap. Heat is produced from the mixture of strong acid and sample Figure 41: Spectronic 20D+ (mostly water). equipment 7. Use a damp towel to wipe the surface of the vial carefully. 8. Place samples in the heated digester block for 2hrs and record start time. 9. Prepare vials for another sludge sample, deionized water (reagent blank) and standard KHP solutions as described above, place in digester block and record time. 10. At the end of the 2hr. digestion period, turn off the block. Leave it for the next 15 minutes to cool down. 109 | P a g e Blackwards 11. With care, remove the vials holding the cap and let them cool for at least 30mins in a dark place. 12. Follow instructions on the left to start the spectrophotometer. Select the 600-950nm filter position. 13. Set the absorbance of the device to zero using reagent blank. Clean the outer surface of the vial. 14. Make sure to clean and swipe. 15. Place used COD vials in fume hood. DO NOT drain down the sink. The contents should be transferred to the bottle with labels “Hazardous Waste: COD……” Rinse vials with DI water. 16. Bottles with KHP solutions should be refrigerated for future experiments. 17. Prepare a calibration curve using KHP standard solutions. Experiment Time: 1. Preparation (~ 30min) - Requires supervision 2. Digestion (2hrs) - Does NOT require supervision 3. Cooling (45- 50mins) - Does NOT require supervision 4. Measurement & Data analysis (~15mins) - Requires supervision Table 26: COD experiment Datasheet DI water KHP (mg/L) KHP (mg/L) KHP (mg/L) Sample 1 Sample 2 Start time (hr: min)* End of digestion Absorbance COD** *Start time is the actual time that the vial containing specified liquid is placed in digester block. **Based on calibration curve. References 1. Idris, Azni, and W.A.W.A.K.G Ghani. "Preliminary Study on Biogas Production of Biogas from Municipal Solid Waste (MSW) Leachate." Journal of Engineering Science and Technology 4.4 (2009): 374-80. Web. 23 Feb. 2014. 2. Standard Methods for the Examination of Water and Wastewater. 19th ed. Washington, DC: American Public Health Association, 1995. Print. 110 | P a g e Blackwards Day 1 2 3 4 5 6 7 Start Date 1 2 3 4 5 6 7 8 9 10 11 12 13 Label on Dish Weight of dish (gm) 1.1 1.2 1.3 2.1 2.2 2.3 3.1 3.2 3.3 7.1 7.2 4.1 4.2 5.1 5.2 6.1 6.2 13 14 19 20 1 27 2 3 4 21 22 6 7 11 12 5 28 24 26 10 9 25 34 32 33 30 31 18 17 1.3353 1.337 1.327 1.3284 1.3218 1.3251 1.331 1.324 1.329 1.322 1.3213 1.3215 1.3235 1.319 1.3248 1.32 1.35 1.3378 1.32 1.3257 1.3367 1.3292 1.3157 1.3277 1.329 1.3275 1.3338 1.3406 1.3285 1.333 1.337 1.3315 1.353 1.3291 1.3499 1.3275 1.3252 1.3275 1.3329 1.3212 1.323 1.3308 1.3199 1.3224 1.3299 1.3427 Lab Data For Team 7 Batch Reactor ALL Weights in GRAMS Wet Residue Dry sample sample Weight (gm) weight (gm) (gm) [Post Burn] 3.7936 1.4727 1.3537 12.9505 1.9476 1.4225 24.7171 2.5211 1.5074 6.0106 1.4429 1.3537 9.9672 1.5305 1.3679 7.9889 1.4867 1.3608 21.867 1.6831 1.4072 21.837 1.6672 1.4005 25.178 1.7277 1.4152 13.1531 1.4641 1.3729 23.0265 1.6306 1.4142 8.4604 1.5256 1.3555 9.0242 1.4995 1.3595 6.3348 1.4562 1.3495 8.8766 1.4683 1.3595 13.2671 1.4093 1.3344 13.065 1.4362 1.3661 16.5658 1.5402 1.4034 11.044 1.5246 1.3882 21.5065 2.0201 1.4128 24.5058 2.3271 1.455 16.7377 1.5968 1.3836 9.4627 1.3593 1.3267 9.0305 1.37 1.338 4.801 1.3532 1.334 3.992 1.4051 1.3443 8.4327 1.3681 1.352 6.1142 1.3689 1.3472 5.575 1.3941 1.3432 9.4711 1.3838 1.345 11.1815 1.4063 1.3541 6.2485 1.4028 1.342 7.378 1.3868 1.3599 7.7371 1.3669 1.3384 6.2136 1.3719 1.355 7.6083 1.4326 1.3559 3.2745 1.3382 1.3285 10.539 1.3502 1.3329 8.1502 1.3562 1.3562 7.5372 1.3412 1.3412 10.4089 1.3534 1.3534 10.5184 1.3599 1.3599 5.5514 1.3536 1.3536 2.7 1.3308 1.3308 14.7538 1.3952 1.3952 18.7488 1.4112 1.4112 %TS %TVS 5.59% 5.26% 5.11% 2.45% 2.41% 2.43% 1.71% 1.67% 1.67% 1.20% 1.43% 2.86% 2.29% 2.74% 1.90% 0.75% 0.74% 1.33% 2.10% 3.44% 4.27% 1.7% 0.54% 0.5% 0.7% 2.9% 0.5% 0.6% 1.5% 0.6% 0.7% 1.5% 0.6% 0.6% 0.5% 1.7% 0.67% 0.25% 0.34% 0.32% 0.33% 0.32% 0.80% 0.61% 0.49% 0.39% 13.39% 14.00% 15.11% 22.10% 22.09% 22.09% 21.64% 22.29% 21.62% 35.82% 30.04% 16.66% 20.45% 22.23% 24.18% 16.13% 18.68% 32.41% 33.33% 12.54% 11.94% 79.7% 74.8% 75.7% 79.3% 78.4% 76.7% 77.6% 76.4% 75.3% 85.3% 79.6% 75.4% 76.8% 73.0% 74.6% 76.2% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% AVG. of TS AVG. of TVS 5.32% 14.17% 2.43% 22.09% 1.69% 21.85% 1.31% 32.93% 2.57% 18.56% 2.32% 23.21% 0.74% 17.40% 1.72% 32.87% 3.86% 12.24% 1.70% 79.67% 1.70% 75.21% 1.80% 78.84% 0.54% 76.68% 1.08% 76.98% 1.08% 80.30% 0.58% 77.49% 1.1% 74.90% 0.46% 75.41% 0.33% 0.00% 0.33% 0.00% 0.70% 0.00% 0.44% 0.00% 111 | P a g e Blackwards Day Label on Dish Weight of dish (gm) Wet sample (gm) Dry sample weight (gm) Residue Weight (gm) [Post Burn] %TS %TVS 29 23 16 15 1.3172 1.3258 1.3244 1.3216 10.7777 11.8108 13.3099 6.7823 1.3594 1.4091 1.5057 1.3789 1.3286 1.3437 1.3654 1.336 0.4% 0.8% 1.5% 1.0% 73.0% 78.5% 77.4% 74.9% 8 1.3396 9.6512 1.4258 1.3597 1.0% 76.7% 1 2 1 2 3 4 5 6 7 8 9 10 14 15 16 17 18 19 21 22 23 24 25 26 20 27 28 29 30 1.3241 1.3244 1.3275 1.3254 1.3212 1.3296 1.3247 1.3283 1.3309 1.326 1.3136 1.3319 1.3285 1.3318 1.3249 1.3229 1.3299 1.3257 1.3152 1.3258 1.3247 1.3154 1.3209 1.3163 1.3235 1.3157 1.3304 1.3245 1.3179 5.476 10.9002 9.284 11.3384 12.9161 10.0404 10.2969 7.4655 11.0218 10.6328 14.8563 13.2135 10.9875 8.7546 11.1817 12.9692 10.2797 10.8992 11.1329 9.1113 12.2669 13.3836 10.0873 8.3964 10.5313 15.147 10.4603 15.3836 8.8661 1.3688 1.4392 1.4283 1.4397 1.4485 1.4633 1.442 1.3958 1.4379 1.4255 1.4476 1.4528 1.4122 1.3926 1.3734 1.4021 1.4024 1.4051 1.3999 1.4073 1.4217 1.4194 1.3965 1.3785 1.3861 1.4421 1.3758 1.4349 1.3474 1.3337 1.3515 1.3513 1.3534 1.3539 1.3607 1.3489 1.3448 1.3575 1.3512 1.1% 1.2% 1.3% 1.1% 1.1% 1.5% 1.3% 1.1% 1.1% 1.1% 1.0% 1.0% 0.9% 0.8% 78.5% 76.4% 76.4% 75.5% 74.3% 76.7% 79.4% 75.6% 75.1% 74.7% AVG. of TS AVG. of TVS 0.62% 75.75% 1.28% 76.13% 1.04% 76.68% 1.14% 77.46% 1.20% 75.95% 1.32% 75.53% 1.20% 77.46% 1.09% 74.91% 1.00% 74.61% 0.84% 73.58% 0.68% 73.40% 0.82% 71.13% 0.95% 72.70% 0.87% 72.64% 0.87% 72.62% 0.68% 0.65% 71.41% 69.00% 0.64% 67.48% Start Date 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 1.3626 1.3507 1.3478 1.3379 1.3438 1.3504 1.3491 1.3391 1.3473 1.3512 1.3439 1.342 1.333 1.3414 1.3677 1.3376 1.3788 1.3316 0.7% 0.8% 0.8% 0.9% 1.0% 0.9% 0.9% 0.9% 0.9% 0.7% 0.9% 0.5% 0.8% 0.4% 74.6% 73.5% 73.7% 73.2% 73.6% 71.7% 70.5% 71.8% 73.6% 72.7% 72.6% 72.1% 73.2% 71.4% 58.9% 84.1% 50.8% 53.6% 112 | P a g e Blackwards Appendix V: Formatted Selections from Clean Water Act Part 503 503.13 Pollutant limits. a) Sewage sludge. 1) Bulk sewage sludge or sewage sludge sold or given away in a bag or other container shall not be applied to the land if the concentration of any pollutant in the sewage sludge exceeds the ceiling concentration for the pollutant in Table 1 of 503.13. 2) If bulk sewage sludge is applied to agricultural land, forest, a public contact site, or a reclamation site, either: i. The cumulative loading rate for each pollutant shall not exceed the cumulative pollutant loading rate for the pollutant in Table 2 of 503.13; or ii. The concentration of each pollutant in the sewage sludge shall not exceed the concentration for the pollutant in Table 3 of 503.13. 3) If bulk sewage sludge is applied to a lawn or a home garden, the concentration of each pollutant in the sewage sludge shall not exceed the concentration for the pollutant in Table 3 of 503.13. 4) If sewage sludge is sold or given away in a bag or other container for application to the land, either: i. The concentration of each pollutant in the sewage sludge shall not exceed the concentration for the pollutant in Table 3 of 503.13; or ii. The product of the concentration of each pollutant in the sewage sludge and the annual whole sludge application rate for the sewage sludge shall not cause the annual pollutant loading rate for the pollutant in Table 4 of 503.13 to be exceeded. The procedure used to determine the annual whole sludge application rate is presented in appendix A of this part. 113 | P a g e Blackwards b) Pollutant concentrations and loading rates—sewage sludge. 1) Ceiling concentrations. Table 1 of §503.13 – Ceiling Concentrations Ceiling Concentration (mg/kg)1 75 85 4300 840 57 75 420 100 7500 Pollutant Arsenic Cadmium Copper Lead Mercury Molybdenum Nickel Selenium Zinc 1 Dry weight basis 2) Cumulative pollutant loading rates Table 2 of §503.13 – Cumulative Pollutant Loading Rates Pollutant Arsenic Cadmium Copper Lead Mercury Nickel Selenium Zinc 3) Pollutant concentrations Cumulative pollutant loading rate (kg / hectare) 41 39 1500 300 17 420 100 2800 Table 3 of §503.13 – Pollutant Concentrations Pollutant Arsenic Cadmium Copper Lead Mercury Nickel Monthly average concentration (mg/kg)1 41 39 1500 300 173 420 114 | P a g e Blackwards Selenium Zinc 1 100 2800 Dry weight basis 4) Annual pollutant loading rates Table 4 of §503.13 – Annual Pollutant Loading Rates Annual pollutant loading rate Pollutant (kg / hectare / 365 day period) Arsenic 2 Cadmium 1.9 Copper 75 Lead 15 Mercury 0.85 Nickel 21 Selenium 5 Zinc 140 c) Domestic septage. The annual application rate for domestic septage applied to agricultural land, forest, or a reclamation site shall not exceed the annual application rate calculated using equation (1). 𝐍 𝐀𝐀𝐑 = 𝟎.𝟎𝟎𝟐𝟔 Eq. (1) Where: AAR = Annual Application rate in gallons per acre per 365 day period. N = amount of nitrogen in pounds per acre per 365 day period needed by the crop or vegetation grown on the land. [58 FR 9387, Feb. 19, 1993, as amended at 58 FR 9099, Feb. 25, 1994; 60 FR 54769, Oct. 25, 1995] 503.32 Pathogens. a) Sewage sludge—Class A. 1) The requirement in 503.32(a)(2) and the requirements in either 503.32(a)(3), (a)(4), (a)(5), (a)(6), (a)(7), or (a)(8) shall be met for a sewage sludge to be classified Class A with respect to pathogens. 2) The Class A pathogen requirements in 503.32 (a)(3) through (a)(8) shall be met either prior to meeting or at the same time the vector attraction reduction requirements in 503.33, except the vector attraction reduction requirements in 503.33 (b)(6) through (b)(8), are met. 3) Class A—Alternative 1. i. Either the density of fecal coliform in the sewage sludge shall be less than 1000 Most Probable Number per gram of total solids (dry weight basis), or the density 115 | P a g e Blackwards ii. of Salmonella sp. bacteria in the sewage sludge shall be less than three Most Probable Number per four grams of total solids (dry weight basis) at the time the sewage sludge is used or disposed; at the time the sewage sludge is prepared for sale or give away in a bag or other container for application to the land; or at the time the sewage sludge or material derived from sewage sludge is prepared to meet the requirements in 503.10 (b), (c), (e), or (f). The temperature of the sewage sludge that is used or disposed shall be maintained at a specific value for a period of time. A. When the percent solids of the sewage sludge is seven percent or higher, the temperature of the sewage sludge shall be 50 degrees Celsius or higher; the time period shall be 20 minutes or longer; and the temperature and time period shall be determined using equation (2), except when small particles of sewage sludge are heated by either warmed gases or an immiscible liquid. 𝐃= 𝟏𝟑𝟏,𝟕𝟎𝟎,𝟎𝟎𝟎 𝟏𝟎𝟎.𝟏𝟒𝟎𝟎𝐭 Eq. (2) Where, D=time in days. t=temperature in degrees Celsius. B. When the percent solids of the sewage sludge is seven percent or higher and small particles of sewage sludge are heated by either warmed gases or an immiscible liquid, the temperature of the sewage sludge shall be 50 degrees Celsius or higher; the time period shall be 15 seconds or longer; and the temperature and time period shall be determined using equation (2). C. When the percent solids of the sewage sludge is less than seven percent and the time period is at least 15 seconds, but less than 30 minutes, the temperature and time period shall be determined using equation (2). D. When the percent solids of the sewage sludge is less than seven percent; the temperature of the sewage sludge is 50 degrees Celsius or higher; and the time period is 30 minutes or longer, the temperature and time period shall be determined using equation (3). 𝐃= 𝟓𝟎,𝟎𝟕𝟎,𝟎𝟎𝟎 𝟏𝟎𝟎.𝟏𝟒𝟎𝟎𝐭 Eq. (3) Where, D=time in days. t=temperature in degrees Celsius. 4) Class A—Alternative 2. i. Either the density of fecal coliform in the sewage sludge shall be less than 1000 Most Probable Number per gram of total solids (dry weight basis), or the density of Salmonella sp. bacteria in the sewage sludge shall be less than three Most Probable Number per four grams of total solids (dry weight basis) at the time the sewage sludge is used or disposed; at the time the sewage sludge is prepared for 116 | P a g e Blackwards sale or give away in a bag or other container for application to the land; or at the time the sewage sludge or material derived from sewage sludge is prepared to meet the requirements in 503.10 (b), (c), (e), or (f). ii. A. The pH of the sewage sludge that is used or disposed shall be raised to above 12 and shall remain above 12 for 72 hours. B. The temperature of the sewage sludge shall be above 52 degrees Celsius for 12 hours or longer during the period that the pH of the sewage sludge is above 12. C. At the end of the 72 hour period during which the pH of the sewage sludge is above 12, the sewage sludge shall be air dried to achieve a percent solids in the sewage sludge greater than 50 percent. 5) Class A—Alternative 3. i. Either the density of fecal coliform in the sewage sludge shall be less than 1000 Most Probable Number per gram of total solids (dry weight basis), or the density of Salmonella sp. bacteria in sewage sludge shall be less than three Most Probable Number per four grams of total solids (dry weight basis) at the time the sewage sludge is used or disposed; at the time the sewage sludge is prepared for sale or give away in a bag or other container for application to the land; or at the time the sewage sludge or material derived from sewage sludge is prepared to meet the requirements in 503.10 (b), (c), (e), or (f). ii. A. The sewage sludge shall be analyzed prior to pathogen treatment to determine whether the sewage sludge contains enteric viruses. B. When the density of enteric viruses in the sewage sludge prior to pathogen treatment is less than one Plaque-forming Unit per four grams of total solids (dry weight basis), the sewage sludge is Class A with respect to enteric viruses until the next monitoring episode for the sewage sludge. C. When the density of enteric viruses in the sewage sludge prior to pathogen treatment is equal to or greater than one Plaque-forming Unit per four grams of total solids (dry weight basis), the sewage sludge is Class A with respect to enteric viruses when the density of enteric viruses in the sewage sludge after pathogen treatment is less than one Plaque-forming Unit per four grams of total solids (dry weight basis) and when the values or ranges of values for the operating parameters for the pathogen treatment process that produces the sewage sludge that meets the enteric virus density requirement are documented. D. After the enteric virus reduction in paragraph (a)(5)(ii)(C) of this section is demonstrated for the pathogen treatment process, the sewage sludge continues to be Class A with respect to enteric viruses when the values for the pathogen treatment process operating parameters are consistent with the values or ranges of values documented in paragraph (a)(5)(ii)(C) of this section. iii. 117 | P a g e Blackwards A. The sewage sludge shall be analyzed prior to pathogen treatment to determine whether the sewage sludge contains viable helminth ova. B. When the density of viable helminth ova in the sewage sludge prior to pathogen treatment is less than one per four grams of total solids (dry weight basis), the sewage sludge is Class A with respect to viable helminth ova until the next monitoring episode for the sewage sludge. C. When the density of viable helminth ova in the sewage sludge prior to pathogen treatment is equal to or greater than one per four grams of total solids (dry weight basis), the sewage sludge is Class A with respect to viable helminth ova when the density of viable helminth ova in the sewage sludge after pathogen treatment is less than one per four grams of total solids (dry weight basis) and when the values or ranges of values for the operating parameters for the pathogen treatment process that produces the sewage sludge that meets the viable helminth ova density requirement are documented D. After the viable helminth ova reduction in paragraph (a)(5)(iii)(C) of this section is demonstrated for the pathogen treatment process, the sewage sludge continues to be Class A with respect to viable helminth ova when the values for the pathogen treatment process operating parameters are consistent with the values or ranges of values documented in paragraph (a)(5)(iii)(C) of this section. 6) Class A—Alternative 4. i. Either the density of fecal coliform in the sewage sludge shall be less than 1000 Most Probable Number per gram of total solids (dry weight basis), or the density of Salmonella sp. bacteria in the sewage sludge shall be less than three Most Probable Number per four grams of total solids (dry weight basis) at the time the sewage sludge is used or disposed; at the time the sewage sludge is prepared for sale or give away in a bag or other container for application to the land; or at the time the sewage sludge or material derived from sewage sludge is prepared to meet the requirements in 503.10 (b), (c), (e), or (f). ii. The density of enteric viruses in the sewage sludge shall be less than one Plaqueforming Unit per four grams of total solids (dry weight basis) at the time the sewage sludge is used or disposed; at the time the sewage sludge is prepared for sale or give away in a bag or other container for application to the land; or at the time the sewage sludge or material derived from sewage sludge is prepared to meet the requirements in 503.10 (b), (c), (e), or (f), unless otherwise specified by the permitting authority. iii. The density of viable helminth ova in the sewage sludge shall be less than one per four grams of total solids (dry weight basis) at the time the sewage sludge is used or disposed; at the time the sewage sludge is prepared for sale or give away in a bag or other container for application to the land; or at the time the sewage sludge or material derived from sewage sludge is prepared to meet the requirements in 503.10 (b), (c), (e), or (f), unless otherwise specified by the permitting authority. 7) Class A—Alternative 5. 118 | P a g e Blackwards i. Either the density of fecal coliform in the sewage sludge shall be less than 1000 Most Probable Number per gram of total solids (dry weight basis), or the density of Salmonella, sp. bacteria in the sewage sludge shall be less than three Most Probable Number per four grams of total solids (dry weight basis) at the time the sewage sludge is used or disposed; at the time the sewage sludge is prepared for sale or given away in a bag or other container for application to the land; or at the time the sewage sludge or material derived from sewage sludge is prepared to meet the requirements in 503.10(b), (c), (e), or (f). ii. Sewage sludge that is used or disposed shall be treated in one of the Processes to Further Reduce Pathogens described in appendix B of this part. 8) Class A—Alternative 6. i. Either the density of fecal coliform in the sewage sludge shall be less than 1000 Most Probable Number per gram of total solids (dry weight basis), or the density of Salmonella, sp. bacteria in the sewage sludge shall be less than three Most Probable Number per four grams of total solids (dry weight basis) at the time the sewage sludge is used or disposed; at the time the sewage sludge is prepared for sale or given away in a bag or other container for application to the land; or at the time the sewage sludge or material derived from sewage sludge is prepared to meet the requirements in 503.10(b), (c), (e), or (f). ii. Sewage sludge that is used or disposed shall be treated in a process that is equivalent to a Process to Further Reduce Pathogens, as determined by the permitting authority. b) Sewage sludge—Class B. 1) i. The requirements in either 503.32(b)(2), (b)(3), or (b)(4) shall be met for a sewage sludge to be classified Class B with respect to pathogens. ii. The site restrictions in 503.32(b)(5) shall be met when sewage sludge that meets the Class B pathogen requirements in 503.32(b)(2), (b)(3), or (b)(4) is applied to the land. 2) Class B—Alternative 1. i. Seven representative samples of the sewage sludge that is used or disposed shall be collected. ii. The geometric mean of the density of fecal coliform in the samples collected in paragraph (b)(2)(i) of this section shall be less than either 2,000,000 Most Probable Number per gram of total solids (dry weight basis) or 2,000,000 Colony Forming Units per gram of total solids (dry weight basis). 3) Class B—Alternative 2. Sewage sludge that is used or disposed shall be treated in one of the Processes to Significantly Reduce Pathogens described in appendix B of this part. 4) Class B—Alternative 3. Sewage sludge that is used or disposed shall be treated in a process that is equivalent to a Process to Significantly Reduce Pathogens, as determined by the permitting authority. 5) Site restrictions. 119 | P a g e Blackwards i. Food crops with harvested parts that touch the sewage sludge/soil mixture and are totally above the land surface shall not be harvested for 14 months after application of sewage sludge. ii. Food crops with harvested parts below the surface of the land shall not be harvested for 20 months after application of sewage sludge when the sewage sludge remains on the land surface for four months or longer prior to incorporation into the soil. iii. Food crops with harvested parts below the surface of the land shall not be harvested for 38 months after application of sewage sludge when the sewage sludge remains on the land surface for less than four months prior to incorporation into the soil. iv. Food crops, feed crops, and fiber crops shall not be harvested for 30 days after application of sewage sludge v. Animals shall not be grazed on the land for 30 days after application of sewage sludge. vi. Turf grown on land where sewage sludge is applied shall not be harvested for one year after application of the sewage sludge when the harvested turf is placed on either land with a high potential for public exposure or a lawn, unless otherwise specified by the permitting authority. vii. Public access to land with a high potential for public exposure shall be restricted for one year after application of sewage sludge. viii. Public access to land with a low potential for public exposure shall be restricted for 30 days after application of sewage sludge. c) Domestic septage. 1) The site restrictions in 503.32(b)(5) shall be met when domestic septage is applied to agricultural land, forest, or a reclamation site; or 2) The pH of domestic septage applied to agricultural land, forest, or a reclamation site shall be raised to 12 or higher by alkali addition and, without the addition of more alkali, shall remain at 12 or higher for 30 minutes and the site restrictions in 503.32 (b)(5)(i) through (b)(5)(iv) shall be met. [58 FR 9387, Feb. 19, 1993, as amended at 64 FR 42571, Aug. 4, 1999] 503.33 Vector attraction reduction. 503.33 Vector attraction reduction a) 1) One of the vector attraction reduction requirements in 503.33 (b)(1) through (b)(10) shall be met when bulk sewage sludge is applied to agricultural land, forest, a public contact site, or a reclamation site. 2) One of the vector attraction reduction requirements in 503.33 (b)(1) through (b)(8) shall be met when bulk sewage sludge is applied to a lawn or a home garden. 3) One of the vector attraction reduction requirements in 503.33 (b)(1) through (b)(8) shall be met when sewage sludge is sold or given away in a bag or other container for application to the land. 120 | P a g e Blackwards 4) One of the vector attraction reduction requirements in 503.33 (b)(1) through (b)(11) shall be met when sewage sludge (other than domestic septage) is placed on an active sewage sludge unit. 5) One of the vector attraction reduction requirements in 503.33 (b)(9), (b)(10), or (b)(12) shall be met when domestic septage is applied to agricultural land, forest, or a reclamation site and one of the vector attraction reduction requirements in 503.33 (b)(9) through (b)(12) shall be met when domestic septage is placed on an active sewage sludge unit. b) 1) The mass of volatile solids in the sewage sludge shall be reduced by a minimum of 38 percent (see calculation procedures in “Environmental Regulations and Technology— Control of Pathogens and Vector Attraction in Sewage Sludge”, EPA–625/R–92/013, 1992, U.S. Environmental Protection Agency, Cincinnati, Ohio 45268). 2) When the 38 percent volatile solids reduction requirement in 503.33(b)(1) cannot be met for an anaerobically digested sewage sludge, vector attraction reduction can be demonstrated by digesting a portion of the previously digested sewage sludge anaerobically in the laboratory in a bench-scale unit for 40 additional days at a temperature between 30 and 37 degrees Celsius. When at the end of the 40 days, the volatile solids in the sewage sludge at the beginning of that period is reduced by less than 17 percent, vector attraction reduction is achieved. 3) When the 38 percent volatile solids reduction requirement in 503.33(b)(1) cannot be met for an aerobically digested sewage sludge, vector attraction reduction can be demonstrated by digesting a portion of the previously digested sewage sludge that has a percent solids of two percent or less aerobically in the laboratory in a benchscale unit for 30 additional days at 20 degrees Celsius. When at the end of the 30 days, the volatile solids in the sewage sludge at the beginning of that period is reduced by less than 15 percent, vector attraction reduction is achieved. 4) The specific oxygen uptake rate (SOUR) for sewage sludge treated in an aerobic process shall be equal to or less than 1.5 milligrams of oxygen per hour per gram of total solids (dry weight basis) at a temperature of20 degrees Celsius. 5) Sewage sludge shall be treated in an aerobic process for 14 days or longer. During that time, the temperature of the sewage sludge shall be higher than 40 degrees Celsius and the average temperature of the sewage sludge shall be higher than 45 degrees Celsius. 6) The pH of sewage sludge shall be raised to 12 or higher by alkali addition and, without the addition of more alkali, shall remain at 12 or higher for two hours and then at 11.5 or higher for an additional 22 hours. 7) The percent solids of sewage sludge that does not contain unstabilized solids generated in a primary wastewater treatment process shall be equal to or greater than 75 percent based on the moisture content and total solids prior to mixing with other materials. 8) The percent solids of sewage sludge that contains unstabilized solids generated in a primary wastewater treatment process shall be equal to or greater than 90 percent based on the moisture content and total solids prior to mixing with other materials. 121 | P a g e Blackwards 9) i. ii. iii. Sewage sludge shall be injected below the surface of the land. No significant amount of the sewage sludge shall be present on the land surface within one hour after thesewage sludge is injected. When the sewage sludge that is injected below the surface of the land is Class A with respect to pathogens, the sewage sludge shall be injected below the land surface within eight hours after being discharged from the pathogen treatment process. 10) i. Sewage sludge applied to the land surface or placed on an active sewage sludge unit shall be incorporated into the soil within six hours after application to or placement on the land, unless otherwise specified by the permitting authority. ii. When sewage sludge that is incorporated into the soil is Class A with respect to pathogens, the sewage sludge shall be applied to or placed on the land within eight hours after being discharged from the pathogen treatment process. 11) Sewage sludge placed on an active sewage sludge unit shall be covered with soil or other material at the end of each operating day. 12) The pH of domestic septage shall be raised to 12 or higher by alkali addition and, without the addition of more alkali, shall remain at 12 or higher for 30 minutes. [58 FR 9387, Feb. 19, 1993, as amended at 64 FR 42571, Aug. 4, 1999] 122 | P a g e Blackwards Appendix VI: Equipment Info 123 | P a g e I Biosolids Treatment Wastewater System Solutions A World of Solutions Visit www.CBI.com Egg-shaped digestion systems Thermophilic pretreatment systems CB&I's Egg-Shaped Digesters (ESD'M) comb ine t he optimum shape for anaerobic digestion with patented and prop ri etary design improvements to maximize reliabi lity and minimize operating and mai ntenance costs. CB&l is the leading suppl ier of ESD systems in the Weste rn Hem isphere with a proven track record, having supplied more than 80 stee l ESD vesse ls and related systems since 1989. CB&I's ATP'M 2-stage digestion system reduces pathogens to meet U.S. EPA req uirements fo r Class A biosolids and improves the stabilization process while reducing tota l retention withi n the digestion process. Gas storage Gasholders and spheres round out CB&I's product offering with econom ica l storage of the methane gas generated from anaerobic digestion. ATP 2-STAGE DIGESTION SYSTEM Vent air ....•... : t- Air Aspiration .. ··•· .. : .. j. Air Aspiration Heat ~anger ~ Digested Biosolids Heat Pretreated Sludge Recovery Exchanger Egg-Shaped Digester Facilities CB&I focuses on delivering advanced anaerobic digestion solutions safely, on time and with the highest quality standards. Our advanced EPC approach includes designing and bu ilding projects turnkey, self performing the work from concept to com missioning and providing a lump-sum price for the project. For any project, we can provide: • • • • • • • • Concept definition Design and detai l engineering Specifications and procurement Fabrication Project management Field construction Inspection and testing Startup and training Egg-Shaped Digester (ESD™) Systems Egg-shaped anaerobic digesters have been used throughout North America and Europe for many yea rs. Their optimum shape eliminates dead zones w ith in the vessel to maxim ize soli ds stabilization and minimize so lid s accumulation. CB&I's techn ica l experti se and process improvements enhance the benefits of ESDrM techno logy. The key to the ESD system is the blending of t he optimum egg shape w ith effective and effic ient liquid mixing to enhance digester performance. The double cu rvature sha pe, reduced operating liquid level surface area and effective mixing eliminate scum and grit bu ild-ups, dead zones and the need to take t he egg-shaped digesters out of service for clean ing. Th is contrasts with conventiona l digesters, wh ich, even w ith the use of more co mpl ex and energy intensive mixing systems, must be pe riodically clea ned. High reliability and superior performance • • • Employs lea k-tight, all welded stee l constru ction for long life and durability Maintains full working volu me and consistent residence time Accepts high solids concentrations and reduces digester volume • • • • • Features outsta nding capabil ity to t reat fats, oil and grease Appli es integrated foam supp ress ion system t o co ntrol foaming Uses no internal moving pa rt s w ith in the digester App lies red und ant mechanica l syste ms for reliability Enhances process control fl exibility and minimizes operator atte ntion with automated contro l system Low operating and maintenance costs • • • • • • Cleani ng expenses and downtime are virtually el iminated Simple, easy-to-operate, automated control system permits stand-alone operation Durable, monolithic Automatic Foamed-In-Place (AFIPTM) in su lation system minimizes heat loss and reduces ene rgy input AFIP in sulation protects vessel from atmosp heri c moist ure Patented internal disc harge syste m limits maintenance Patented jet pump mixing system - Eliminates all internal movin g parts - Decreases foam generation and attendant foam con trol problems - Minimizes energy use and maintenance costs Low install ion costs • • • • JET PUMP DUAL ZONE MIXING SYSTEM Sma ll footprint minimizes land requirements and costs High reliablity ca n elimi nate the cost of back-up digesters Large space underneath vessel eli minates the need fo r a sepa rate equ ipment bu ilding Intern al mixing system is simp le and inexpe nsive Stee l composition all ows econom ica l, fast, all-weather const ru ct ion Economical AF IP in sulation is appl ied on site UPPER DRAFT TUBE Good neighbor • • Lea k-t ight, al l-welded steel containment significantly reduces odor em issions Co mpact plant w ith sma ll footprint minimizes comm unity impa ct AF IP insu lation provides attractive appea rance Superior safety and security • • • UPPER ZONE MIXING SYSTEM Includes patented internal d ischarge syste m Removes risk of routine gas relea ses Eli m inates confin ed space work areas HEAT-X SYSTEM ATP Class A System The ATP thermophi li c pret reatment syste m ope rates under nearly anoxic co ndition s resulting in acidified, hydrolyzed and homoge nized slud ge. This thermal co nditi oning, when co mbined w ith anaerobic digestion, provides U.S. EPA ce rtifi ed Class A-pathogen redu ctio n. ATP's no minal Hydraulic Residence Time (HRT) is one day, fol lowed by 12 to 15 days of mesop hilic anaerob ic digestio n. Th e ATP syste m has been used for more than 100 insta ll atio ns throughout No rt h America and Europe. Representative pathogen reduction performance data is provided be low. U.S. 40 CFR PART 503 ATP Salmonella <3 MPN/4 grams < 1 MPBN/4 gram s Helminth Eggs < 1/4grams < 1/4 grams Enterovirus < 1PFU/4 grams <1PFU/4 grams Superior performance • • • • • • • Ce rtifi ed U.S. EPA Class A process Greater so lid s destruction Increased digester ca pacity En hanced gas production Improved dewaterabi lity Minimized odor Demonstrated Nocardia destruction Low operating costs • • • Heat recove ry reduces heating req uirements Digester heatin g system is eliminated Automated co ntrol syst em supports standalone operation High reliability • • • • Minimal moving parts in vessel Fu lly redunda nt mixing syst ems Asp irated ai r injection Atmospheric operat ion Flexible application • • • • • New or existing in sta ll ations Upg rades fo r both convent iona l and egg-s haped d igeste r fac iliti es Batch or co ntinuo us feed optio ns avai lable Singl e vesse l design for small fac ilities Multipl e vesse l design for larg er fac ilit ies L•nd•n Wcuttwcrt•r Trf'llltmf'nt Plont ~C:===:JI~ -~..~-;;: · IJ z l ~~' ~o lliiiiiii I Class A Sludge System ll-1 01 21.on II*IER CtWoleEA """""'~ l--"""""'-'1 1""'"'""""""1 WIUCW. Tuu61y, Wotd'I10, 3X8 2 C3 I lcOUIIIc- w!-- . :: 4 h! I .. Gas Storage Dry seal gas storage Whether the need is for high-p ressure or low-pressure storage, CB&I provides a variety of gasholder so lutions to meet any requirement. • High-pressure gas storage Hortonsphere®pressure vessels provide large volumes of product gas storage in a sma ll area. These vesse ls: • • • Holds more gas in a sma ll er footprint compared with low-pressure storage Al lows for variable discharge pressure for downstream usage Provides lower capita l cost than large-volume, low-pressure gas storage Low-pressure gas storage • • Wet seal gas storage • • • • Two types of low-pressu re gas storage are ava il able, dry seal and wet sea l. Compared with high-pressure storage, these systems provide consistent gas pressure to meet the needs of downstream usage and operate with minimal mechanical operating equipment. Increases gas storage volume compared with a wet seal design for a given tank volume Reduces odor em issions Provides weatherprotected piston and seal Accepts multiple liquids for the wet seal All ows for sludge and gas storage within a single vessel Operates on either constant or variable liquid level Reduces cap ital expend iture due to size and output requirements DRY SEAL GAS HOLDER WET SEAL GASHOLDER LOW POSITION LOW POSITION . ... ...... . Open Top •·· ··· ······Tank Shell ····· Tank Shell ······ ··· Liquid Level • .. . Piston HIGH POS ITION HIGH POSITION •- ······Open Top •- - Tank Shell ..... . Piston Liquid Level A World of Solutions Visit www.CBI.com On ly employees, agents or representatives authorized under and pursuant to written agreem ent with CB&I are authorized to distribute t his brochure to an actual or potential client of CB&I. ©Copyright 2013 by Chicag o Bridge & Iro n Company. All rights reserved. Printed in USA. 08M082013H 2-7 09.27.20 13 108.27 2750.0 224.44 5700.7 Overall Length 186.41 4734.9 Main Frame Length 38.02 965.8 32.39 822.7 Motor Mount Length Main Rotating Assembly Components are Centrifugally Cast Stainless Steel Duplex Vibration Sensor (Optional) 125 H.P. Main Drive Motor 47.37 1203.2 Lifting Lugs Width 27.17 690.0 Rotodiff 55.37 1406.4 Main Frame Width 54.33 1380.0 Motor Mount Width Electrical Junction Box Bearing Temperature Sensors, Typical 2 places (Optional) Shown with Covers Removed 4.31 109.5 26.46 672.2 177.17 4500.0 39.71 1008.7 Liquid End Chamber Inspection & Weir Plate Access Hatch 5.91 150.0 Rotodiff Safety Cover 129.13 3280.0 Main Cover Length Note: Cover Hooks to be used for main Cover Remoaval ONLY. Do NOT use to lift entire unit. 4.94 125.4 17.57 446.3 Main Cover Lifting Lugs 117.32 2980.0 Main Cover & Integrated Housing Pulley Safety Cover 5.91 150.0 Solids End Chamber Inspection Hatch 57.09 1450.0 Clearance needed for Feed Pipe Removal 1.77 R45.0 4.92 125.0 Feed Pipe Offset from Bracket Lifting Lugs Typical 4 Corners of Main Frame 61.46 1561.2 Strap Down Slots 72.44 1840.0 Min. Height Required for Rotating Assembly Removal 2-1/2" NPT Feed Pipe Connection 38.75 984.2 Approx. 33.46 850.0 37.91 962.8 5.91 150.0 Name Plate Rotodiff & Junction Box Chamber Access Plate Strap Down Slots 7.00 177.8 3.91 99.4 4.53 115.0 Typ. Spacing 20.87 530.0 A 1.57 40.0 164.50 4178.3 5.90 149.8 Centrate Discharge See Flange Detail 7.00 177.8 Solids Discharge See Flange Detail 24.50 622.3 B 11.89 302.0 C Weights: 41.73 1060.0 Rotating Assembly 8,054 lbs. Bowl Filling w/S.G. 1.0 1,328 lbs. Complete Centrifuge 18,100 lbs. (with filling) 23.75 603.3 5.22 132.5 Typ. Spacing Static Load Below each point of complete Centrifuge: A = 3,840 lbs. B = 4,060 lbs. C = 1,150 lbs. 9.84 250.0 9.06 230.0 19.69 500.0 18.11 460.0 21.65 550.0 43.31 1100.0 47.50 1206.5 Dynamic Load Below each point of complete Centrifuge: (additional 25% of static load) A = 4,800 lbs. B = 5,075 lbs. C = 1,438 lbs. M10x1.5 Tapped Hole Typ. 24 Places Discharge Flange Dimensions Typical Centrate & Solids End A 10.91 277.2 36.59 929.5 113.54 2884.0 14.36 364.9 B Main Motor Electrical Connection C REVISE ON CAD ONLY 9586 58th Place Kenosha, WI 53144 CENTRIFUGE SYSTEMS Designed by: Drawn by: Chk'd by: Date: D.S. Date: Date: 02/22/08 Tel: (262) 654-6006 Fax: (262) 654-6063 3rd Angle Projection Date: THIS PRINT IS PROVIDED ON A RESTRICTED BASIS AND IS NOT TO BE USED IN ANY WAY DETRIMENTAL TO THE INTERESTS OF CENTRISYS CORP. Title: Cs26-4.01 2-Phase Centrifuge General Arrangement Project: Material(s): NA Estimated weight (lbs): Approved by: Frequency of mounting isolators: 0.83Hz @ max loading of 6,500 lbs. Vibration Isolators Typical 10 Places 18100 Part #: Sht: 14715 Drawing #: 1 OF 1 Scale: 1:20 M-C14715 REV Page 1 of 15 Leaders in Biogas Technology BUDGET PROPOSAL GAS CONDITIONING SYSTEM Date: 4/25/14 Expires: 7/25/14 Glenn Hummel HESCO Proposal Number: PX-214-1742.1 Project Name: GVRBA (Grand Valley Regional Biosolids Authority) Unison Solutions, Inc. is pleased to provide this BUDGET proposal for a Gas Conditioning System for the GVRBA (Grand Valley Regional Biosolids Authority) Project. This BUDGET proposal includes all of the system engineering, CAD design services, technician labor, fabrication and materials to construct a Gas Conditioning System. Thank you for giving Unison Solutions the opportunity to provide you with the enclosed proposal. If you have questions or require additional information, please contact me at your convenience. Sincerely, Tony Schilling Unison Solutions, Inc. Phone: 563-585-0967 Cell: 563-543-6069 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 2 of 15 EQUIPMENT/SUB-SYSTEMS HYDROGEN SULFIDE REMOVAL SYSTEM - Hydrogen Sulfide Inlet Moisture/Particulate Filter - Hydrogen Sulfide Removal Media Vessel - Work Platform and Ladder - Initial Charge of SulfaTreat Media GAS COMPRESSION/MOISTURE REMOVAL SYSTEM - Gas Blower Inlet Moisture/Particulate Filter - Gas Blower - Forced Air to Gas Heat Exchanger - Dual Core Heat Exchanger - Gas Recirculation - Skid Base GLYCOL CHILLER - Glycol Chiller - Initial fill of Propylene Glycol/Water Mixture SILOXANE REMOVAL SYSTEM - Siloxane Removal Media Vessels - Work Platform and Ladder - Initial charge of Siloxane Removal Media - Siloxane Removal Final Particulate Filter CONTROL SYSTEM - Gas Conditioning System Control Panel - Transformer DESIGN CONDITIONS SITE INFORMATION - Minimum Ambient Temperature - Maximum Ambient Temperature - Site Elevation 5°F 86°F 800’ AMSL SYSTEM REQUIREMENTS - Gas Flow 285 scfm 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 3 of 15 ASSUMED INLET GAS CONDITIONS - Inlet Gas Pressure - Inlet Gas Temperature - Relative Humidity - Methane (CH4) - Carbon Dioxide (CO2) - Nitrogen (N2) - Oxygen (O2) - Hydrogen Sulfide (H2S) - Siloxanes (L2, L3, L4, L5, D3, D4, D5, D6) 10”WC 100°F 100% 60% 40% <1% <1% 500 ppmv 1,500 ppbv DISCHARGE GAS CONDITIONS - Discharge Gas Pressure - Discharge Gas Temperature - Dew Point Temperature - Maximum Hydrogen Sulfide - Maximum Siloxane - Particulate Removal 3 psig 80°F 40°F <10 ppmv <100 ppbv 99% removal of >3 micron SITE REQUIREMENTS ELECTRICAL CLASSIFICATION - NEC Class I, Division 1 Group D Areas - Hydrogen Sulfide Removal System - Gas Compression/Moisture Removal System - Siloxane Removal System - Unclassified Electrical Areas - Glycol Chiller - Gas Conditioning System Control Panel EQUIPMENT MOUNTING - Skid Mounted - Gas Compression/Moisture Removal System - Standalone - Hydrogen Sulfide Removal System - Glycol Chiller - Siloxane Removal System - Gas Conditioning System Control Panel 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 4 of 15 EQUIPMENT/SUB-SYSTEM DETAILS HYDROGEN SULFIDE REMOVAL SYSTEM - Hydrogen Sulfide Inlet Moisture/Particulate Filter - Mounted upstream of the Hydrogen Sulfide Removal Media Vessel - 99% removal of 3micron and larger particulates and liquid droplets - Materials of construction shall be 304L stainless steel - 150# ANSI B16.5 side inlet and outlet connections - Cleanable polypropylene structured mesh element - Differential pressure gauge across the filter element - Sight glass for liquid level indication - Level switch above the condensate drain to warn of failure - Bottom drain with strainer, float drain, manual bypass and piping - (1) Hydrogen Sulfide Removal Media Vessel - 12’Ø x 10’ straight side - Rated for 5psig pressure and 1psig vacuum - Materials of construction shall be 304L stainless steel - 150# ANSI B16.5 side inlet and outlet connections - Flanged and dished top and bottom heads - Vessel shall be free-standing on four 304L stainless steel legs - Vessel equipped with a top manway - Vessel equipped with a side manway - Internal supports and grating for media - Pressure relief valves included - Two top vents with stainless steel ball valves - Bottom manual condensate drain with stainless steel ball valves - Work Platform and Ladder - Work platform shall be welded carbon steel construction with satin black powder coat finish - Ladder shall be galvanized steel construction - Initial Charge of SulfaTreat Media - The initial charge of SulfaTreat media for each Hydrogen Sulfide Removal Media Vessel will be provided. - SulfaTreat to be loaded into Hydrogen Sulfide Removal Vessel by INSTALLATION CONTRACTOR GAS COMPRESSION/MOISTURE REMOVAL SYSTEM - Gas Blower Inlet Moisture/Particulate Filter 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 5 of 15 - Mounted upstream of the Gas Blower - 99% removal of 3micron and larger particulates and liquid droplets - Materials of construction shall be 304L stainless steel - 150# ANSI B16.5 side inlet and outlet connections - Cleanable polypropylene structured mesh element - Differential pressure gauge across the filter element - Sight glass for liquid level indication - Level switches above the condensate drains to warn of failure - Bottom drain with strainer, condensate pump, check valve, manual bypass and piping - Gas Blower - One Rotary Lobe Positive Displacement Blower rated for 285scfm - Belt driven 15Hp, 480V/3Ph/60Hz EXP electric motor - Motor speed will be controlled by a VFD - Cast iron casing - Inlet and discharge flex connectors - Discharge silencer - Discharge check valve - Discharge pressure safety valve - Belt guard - Forced Air to Gas Heat Exchanger - Air to Gas plate/fin core - Materials of construction shall be aluminum plate and fins - 480V/3Ph/60Hz EXP electric motor - Motor speed will be controlled by a VFD - Dual Core Heat Exchanger - Stage 1 - Gas to gas plate/fin core - Materials of constructions shall be aluminum plate and fins - Stage 2 - Gas to glycol fin/tube core - Materials of construction shall be aluminum fins on 304L stainless steel tubes - Mounted in single 304 stainless steel housing - 150# ANSI B16.5 inlet and outlet connections - All condensation generated during cooling will be removed inside the heat exchanger housing - Level switch mounted on the housing to warn of drain failure - RTD mounted on the housing to verify the coldest temperature that the gas reaches - Bottom drain with strainer, float drain, manual bypass and piping 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 6 of 15 - Gas Recirculation - Modulating V-port Ball Valve shall be provided to allow excess gas to flow from the discharge of the system back to the inlet. This valve shall be controlled by monitoring the delivery pressure of the system. - V-port Ball Valve - Type 7 explosion proof actuator - 120V weatherproof - Skid Base - Welded carbon steel construction with satin black powder coat finish - All components mounted, piped and wired on skid base - 24V and 120V electrical components wired to one of two junction boxes on edge of skid - INSTALLATION CONTRACTOR to provide conduit and wiring to 480V components - Conduit shall be rigid aluminum - Condensate drains piped to edge of the skid base. Drains to be routed to floor drain by INSTALLATION CONTRACTOR. GLYCOL CHILLER - Glycol Chiller - Sized for the process heat load - Suitable for outdoor installation - Refrigeration System - One refrigeration circuit - One compressor sized for 100% capacity - Chiller capacity: 25% to 100% of rated capacity - EC motor driven condenser fans - Aluminum micro-channel air cooled condensers - 316L stainless steel evaporator - R410a refrigerant. R-410a is an HFC refrigerant with 0 ODP - Refrigeration circuit has sealed core filter drier, liquid line solenoid valve, liquid line shut-off valve, and sight glass/moisture indicator - Electronic expansion valve - Glycol Chiller shall be factory tested and shipped with complete refrigerant charge - Glycol Circulation - One glycol circulation pump sized for 100% capacity - Pump is stainless steel end suction centrifugal - Pump motor is TEFC - Pump isolation valves on inlet and outlet - Pump discharge check valve - Glycol reservoir is a 304 stainless steel closed tank - Glycol piping is copper with anti-corrosion coating 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 7 of 15 - Armaflex insulation - Glycol Chiller to utilize propylene glycol/water mix - Initial fill of Propylene glycol will be provided - Support Structure - G90 galvanized steel member frame - Powder-coated aluminum cover panels - All components mounted, piped and wired on skid - Glycol Chiller Control Panel - UL Type 4 - UL 508A Listed Industrial Control Panel - Painted carbon steel - 480V/3Ph/60Hz feed will be required - 480V disconnect - Microprocessor based controller with full text LCD display - 480VAC to 24VAC transformer SILOXANE REMOVAL SYSTEM - (2) Siloxane Removal Media Vessels - 4’Ø x 8’ straight side - Materials of construction shall be 304L stainless steel - 150# ANSI B16.5 inlet and outlet connections - Flanged and dished top and bottom heads - Vessels shall be free-standing on four 304L stainless steel legs - Elliptical access nozzle on top of each nozzle - Internal septas for even gas distribution through media - Pressure relief valves included - Bottom manual condensate drain with stainless steel ball valves - Test/purge ports with ball valves on the inlet and outlet of each Siloxane Removal Media Vessel - Lead/Lag piping and valves between Siloxane Removal Media Vessels will be provided - Work Platform and Ladder - Work Platform shall be welded carbon steel construction with satin black powder coat finish - Ladder shall be galvanized steel construction - Initial charge of Siloxane Removal Media - The initial charge of siloxane removal media for each Siloxane Removal Media Vessel will be provided. - The media shall be specifically engineered for removal of siloxanes and similar contaminants from landfill and digester gas sources. - Siloxane media to be loaded into the Siloxane Removal Media Vessels by the INSTALLATION CONTRACTOR. 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 8 of 15 - Siloxane Removal Final Particulate Filter - Mounted downstream of the Siloxane Removal Vessels - 99% removal of 3micron and larger particulates and liquid droplets - Materials of construction shall be 304L stainless steel - 150# ANSI B16.5 side inlet and outlet connections - Cleanable polypropylene structured mesh element - Differential pressure gauge across the filter element - Sight glass for liquid level indication - Level switch above the condensate drain to warn of failure - Bottom drain on vessel with manual ball valve CONTROL SYSTEM - Gas Conditioning System Control Panel - Enclosure - UL Type 12 - UL 508A Listed Industrial Control Panel - Painted carbon steel - Indoor location - Thermal Management (as necessary) - Rated for installation in ambient temperatures from 40°F to 104°F - Power Distribution - Fused Disconnect - 480V/3Ph/60Hz feed required - 35kA Short Circuit Current Rating - Over current and branch circuit protection via fuses - 480VAC field wiring to terminate at the component or terminal strips inside control panel - Surge Suppression - 480VAC Transient Voltage Surge Suppressor - 120VAC Surge Filter - Motor Control - (1) 15Hp rated VFD for Gas Blower Motor - (1) 1-1/2Hp rated VFD for Forced Air to Gas Heat Exchanger Motor - (1) 1/2Hp rated Motor Starter Overload for Condensate Pump - Programmable Logic Controller - Allen Bradley - Compact Logix PLC and I/O - Native Allen Bradley Ethernet IP data network - Human Machine Interface - Proface PFXGP4601TAF - TFT Color LCD Display - 12” diagonal - 800 x 600 pixels - Instrument wiring to terminate at terminal strips inside Control Panel - Transformer 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 9 of 15 - 5kVA - 480VAC to 120VAC - NEMA 3R; Painted carbon steel INSTRUMENTATION - All instrumentation provided will be designed for gas service and rated for use in a NEC Class I, Division 1 Group D area. - Hydrogen Sulfide Removal System Instrumentation - Inlet Pressure Transmitter - Inlet Resistive Temperature Detector (RTD) 3 Wire-100Ω - Gas Compression/Moisture Removal System Instrumentation - Level Switches at each Condensate Drain - Level Indicators at each Condensate Drain - RTD’s (3 Wire-100Ω) at each Temperature Change Point - RTD (3 Wire-100Ω) to Monitor Glycol Temperature - Bi-metal Thermometers at each Temperature Change Point - Gas Blower Discharge Pressure Transmitter - Siloxane Removal System Instrumentation - Delivery Pressure Transmitter PIPING - Pipe will be SA-312 TP304/304L Weld Pipe, minimum Schedule 10S. Threaded pipe shall be minimum Schedule 40S. - Flange connections will be ANSI B16.5, SA-182 F304/304L Class 150. - Pipe welding will follow ASME B31.3 Process Piping. Welded pipe will be visually inspected and pressure tested. VALVES - Inlet Electric Actuated Butterfly Valve - Butterfly valve will be lug style, iron body with stainless steel disc and stem and FKM seat. - Type 7 explosion proof actuator - Spring return closed upon power loss - 120V weatherproof - Ball Valves - Stainless steel with PTFE or RTFE seat. - Valves will be full port. - Butterfly Valves - Lug style iron body with stainless steel disc and stem and FKM seat. - Check Valves - Will be one of 2 styles; ball or dual-door. - Ball check valves shall be stainless steel with RTFE ball. - Dual-door check valves shall be wafer style body, material shall be aluminum and/or stainless steel with an FKM seat. - Globe Valves 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 10 of 15 - Stainless steel with PTFE packing FASTENERS - Fasteners shall be F593 304 stainless steel TEMPERATURE CONTROLLED ENCLOSURE (OPTIONAL) - All electrical inside the enclosure is rated Class I Division 1 - Mounted to THE Gas Compression/Moisture Removal Skid - Steel exterior with multiple color options for site esthetics - 3/4” fire rated plywood construction over steel studs - Insulated walls and ceiling - Interior 5/8” green board (mildew resistant drywall) - Lighted interior with two EXP incandescent light fixtures - Thermostatically controlled heater to prevent freezing - LEL inside enclosure for gas detection and warning - Ventilation fan and intake louver to prevent over heating inside enclosure - Double steel entry doors Note: Customer will be required to power the heater, ventilation fan and lights SUBMITTALS - Quantity: (3) copies of 3 ring binders and (1) electronic CD copy - Shop Drawings and Product Data will be provided in sufficient detail to confirm compliance with the requirements for the project. Shop Drawings and Product Data will be provided in a complete submittal package. - Shop Drawings - Installation drawings and specifically prepared technical data, including design capacities will be provided. - Specifically prepared wiring diagrams unless standard wiring diagrams are submitted with product data will be provided. - Written description of operation will be provided. - Product Data - Catalog cuts and product specifications for each product specified will be provided. - Standard wiring diagrams unless wiring diagrams are specifically prepared and submitted with Shop Drawings will be provided. FACTORY TESTING - The System will be tested on ambient air at Unison’s facility prior to shipment. - The CUSTOMER is allowed to witness the testing and Unison will inform the customer (2) weeks prior to anticipated testing date so customer can make travel arrangements. OPERATION & MAINTENANCE MANUALS - Quantity: (6) copies of 3 ring binders and (1) electronic CD copy 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 11 of 15 - After shipment the Gas Conditioning System will be provided with a specifically prepared Operation & Maintenance Manuals. The information provided includes a system overview, operator interface, start-up/shut down procedures, communications, alarms procedures, maintenance overview, mechanical component spec sheets and electrical component spec sheets. OPERATION & MAINTENANCE - Hydrogen Sulfide Removal System - Clean Hydrogen Sulfide Inlet Moisture/Particulate Filter - Replace Hydrogen Sulfide Media - Estimated Cost = $31,460.00 every 205 days** *Labor for change out, disposal and shipping of media not included **No Gas Test data provided at time of proposal. Assumed 500ppmv - Gas Compression/Moisture Removal System - Clean Gas Compressor Inlet Moisture/Particulate Filter - Change Blower Oil - Clean Glycol Chiller Condenser - Test Glycol for Freeze Point - Estimated Cost = $1,500.00 every 365 days - Siloxane Removal System - Replace Siloxane Media - Estimated Cost = $16,830.00 per change out** *Labor for change out, disposal and shipping of media not included **No Gas Test data provided at time of proposal ELECTRICAL PARASITIC - Electrical Parasitic - Condensate Pump = 1 kW - Gas Blower Motor = 12 kW - Forced Air to Gas Heat Exchanger = 1 kW - Glycol Chiller = 18 kW - Controls & Auxiliary Equipment = 4 kW Total = 36 kW (Full Load) Total = 25 kW (Average Run Load) Optional - If Temperature Controlled Enclosure is Included - Enclosure Lighting = 2 kW - Enclosure Heater = 17 kW - Enclosure Ventilation Fan = 2 kW DELIVERY SCHEDULE - Submittals delivered 3 to 4 weeks after order acceptance - Equipment delivery 16 to 18 weeks after submittal approval 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 12 of 15 - Delivery is subject to confirmation at the time of order placement and/or submittal approval PRICING SUMMARY - Price includes all labor and expenses associated with the fabrication of the system. - Prices do not reflect any taxes that may be applicable and are valid for 90 days. - Price is FCA; Factory, Dubuque, IA 52002, per Incoterms 2010. Shipping costs not included, see estimate below - Price does not include Start-up and Commissioning. Costs are shown below BUDGET Hydrogen Sulfide Removal System ...................................................................... $135,000.00 BUDGET Gas Compression/Moisture Removal System ...................................................... $270,000.00 BUDGET Siloxane Removal System ....................................................................................... $85,000.00 Shipping ESTIMATE to Grand Rapids, MI ................................................................................ $7,000.00 Cost is an estimate and is subject to change without notice. It does not include any special packaging or permitting that may be required and is dependent on the final equipment dimensions and weights. Start-up and Commissioning Services ESTIMATE ................................................................... $8,500.00 Price includes Four (4) consecutive, 8 hour days, for one Unison Technician onsite with travel and expenses included. Additional days may be necessary to complete start-up and commissioning, they will be billed to the Buyer/Owner/End User at the cost of $1,200 per day, per technician, plus travel & expenses. Temperature Controlled Enclosure (OPTIONAL) .................................................................. $70,000.00 PAYMENT SCHEDULE - 30% upon order acceptance - 30% at midpoint of construction - 30% upon equipment delivery - 10% upon site acceptance not to exceed 180 days from shipment - Net 30 days on all payments PROVIDED BY OTHERS - VPN connection for remote access to Unison supplied equipment for troubleshooting and remote assistance. PRICE DOES NOT INCLUDE - Shipping of equipment to jobsite - Start-up and commissioning services - Wind or seismic calculations for all equipment - Any maintenance work after start-up 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 13 of 15 - Siloxane or H2S removal media after initial fill - Performance guarantee or service/maintenance contract - Any gas testing or analyses - Permitting for the installation of the equipment or air permits - Freeze protection; including insulation and/or heat trace and heat trace power - Pipe stands for field piping ASSUMPTIONS VESSELS & MEDIA - H2S and VOC’s present in the gas will foul Siloxane media, additional gas testing will be necessary to finalize all vessel and media requirements, budget pricing is dependent on gas data given at the time of the proposal. - No assumption of media life has been given; additional gas testing will be required at the Buyer/Owner/End Users expense. - Any assumption of media life that has been given is an estimate; additional gas testing will be required at the Buyer/Owner/End Users expense. - Vessel sizes are estimates only, gas testing will be necessary to finalize all vessel sizing. MECHANICAL - Flare is supplied by OTHERS - If an existing flare is being used, it is assumed this flare is in good working order, with all safety and control equipment. - Foundations and/or maintenance pads are designed by OTHERS to properly support the equipment. ELECTRICAL - 480V/3Ph/60Hz is available - The following Equipment/Sub-systems will be located in an NEC Class I, Division 1 Group D Area - Hydrogen Sulfide Removal System - Gas Compression/Moisture Removal System - Siloxane Removal System - The following Equipment/Sub-systems will be located in an Unclassified Area - Glycol Chiller - Gas Conditioning System Control Panel INSTALLATION CONTRACTOR RESPONSIBILITIES - Installation responsibilities are broken out below into three categories to outline the work; these responsibilities by no means fall on any single contractor or individual. It is the responsibility of the Buyer/Owner/End User to ensure all these conditions are adhered to, as necessary. It is responsibility of the Buyer/Owner/End User to install all equipment in compliance with local and national codes applicable to the installation site. 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 14 of 15 BUYER/OWNER/END USER RESPONSIBILITIES - All foundations and/or maintenance pads as necessary for equipment - Provide and seal all roof and building penetrations as necessary - Provide all anchor bolts, temporary lift equipment, power, labor, and all other incidentals required for proper installation of the equipment shown on the drawings that will be provided by Unison Solutions, Inc. - All rigging and setting of equipment at job site - Proper storage of the equipment and media prior to installation - Provide installation of Equipment/Sub-systems per the Unison Solutions Installation Guide - Load initial charge of Hydrogen Sulfide Media and Siloxane Media into the vessels MECHANICAL CONTRACTOR RESPONSIBILITIES - Provide all field piping between the Equipment/Sub-systems, including but not limited to: - Hydrogen Sulfide Removal System - Gas Compression/Moisture Removal System - Glycol Chiller - Siloxane Removal System - Provide pipe supports as necessary. Piping shall be self-supporting, and not supported off of the Unison supplied equipment. - Install all field located or shipped loose devices - Provide all Heat Trace and/or Insulation as necessary to provide proper freeze protection as defined by Unison Solutions. ELECTRICAL CONTRACTOR RESPONSIBILITIES - Provide 480V/3Ph/60Hz feed to the Gas Conditioning System Control Panel - Provide all field wiring and conduits between the Equipment/Sub-systems to the Gas Conditioning Control Panel and associated equipment. This includes but not limited to: - Hydrogen Sulfide Removal System - Gas Compression/Moisture Removal System - Glycol Chiller - Siloxane Removal System - Gas Conditioning System Control Panel - Provide local disconnects as necessary - Provide all Hazardous location conduits & wiring systems per Article 500 of the NEC - Provide conduit seals entering and/or leaving the Class I, Division 1 Electrical Area. Conduit seals will need to be filled during Start-up and Commissioning after verification of field wiring by Unison’s Start-up Technician. Conduit seals are to be filled prior to the introduction of gas to the equipment. - Provide heat trace power from local lighting panel, as necessary. 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. Page 15 of 15 WARRANTY - Unison Solutions, Inc. will warrant all workmanship and materials in conformance with the attached Warranty Statement. Warranty is valid for 18 months from the time the equipment is shipped from Unison’s factory or 12 months from the date of startup, whichever occurs first. - This proposal is for equipment only and does not include any system engineering and design services expressed or implied. - Unison Solutions, Inc. will not release the PLC program for this system. This is considered proprietary and the intellectual property of Unison Solutions, Inc. 5451 Chavenelle Road, Dubuque, Iowa 52002 [O] 563.585.0967 www.unisonsolutions.com Design and content included in this document is proprietary and remains the property of Unison Solutions, Inc. WARRANTY STATEMENT Unison Solutions, Inc. (Unison) is committed to providing quality products and services to its customers. As a demonstration of this commitment, Unison offers the following warranty on its products. Grant of Warranty: Unison provides this warranty for its equipment under the terms and conditions which are detailed herein. This warranty is granted to the person, corporation, organization, or legal entity (Owner), which owns the equipment on date of start‐up. This warranty applies to the owner during the warranty period, and is not transferable. Warranty Coverage: Equipment that is determined by Unison to have malfunctioned during the warranty period under normal use solely as a result of defects in manufacturing workmanship or materials shall be repaired or replaced at Unison’s option. Unison’s liability under this warranty to the Owner shall be limited to Unison’s decision to repair or replace, at its factory or in the field, items deemed defective after inspection at the factory or in the field. Warranty Exclusions: All equipment, parts and work not manufactured or performed by Unison carry their own manufacturer’s warranty and are not covered by this warranty. Unison’s warranty does not override, extend, displace or limit those warranties. Unison’s only obligation regarding equipment, parts and work manufactured or performed by others shall be to assign to the Owner whatever warranty Unison receives from the original manufacturer. Unison does not warrant its products from malfunction or failure due to shipping or storage damage, deterioration due to exposure to the elements, vandalism, accidents, power disturbances, or acts of nature or God. This warranty does not cover damage due to misapplication, abuse, neglect, misuse, improper installation, or lack of proper service and/or maintenance, nor does it cover normal wear and tear. This warranty does not apply to modifications not specifically authorized in writing by Unison or to parts and labor for repairs not made by Unison or an authorized warranty service provider. This warranty does not cover incidental or consequential damages or expenses incurred by the Owner or any other party resulting from the order, and/or use of its equipment, whether arising from breach of warranty, non‐conformity to order specifications, delay in delivery, or any loss sustained by the Owner. No agent or employee of Unison has any authority to make verbal representations or warranties of any goods manufactured and sold by Unison without the written authorization signed by an authorized officer of Unison. Unison warrants the equipment designed and fabricated to perform in accordance with the specifications as stated in the proposal for the equipment and while the equipment is properly operated within the site specific design limits for that equipment. Any alterations or repair of Unison’s equipment by personnel other than those directly employed by, or authorized by Unison shall void the warranty unless otherwise stated under specific written guidelines issued by Unison to the Owner. This warranty does not cover corrosion or premature wear or failure of components resulting from the effects caused by siloxanes, hydrogen sulfide or volatile organic compounds in excess of the design limits. All media must be purchased through Unison Solutions or approved in writing by Unison Solutions dur‐ ing warranty period. Media purchased though alternate sources and not approved in writing by Unison shall void the war‐ ranty. The design limit is based on site specific gas data provided by the Owner prior to the proposal for the equipment. Owner shall be responsible for all maintenance service, including, but not limited to, lubricating and cleaning the equipment, replacing expendable parts, media, making minor adjustments and performing operating checks, all in accordance with the procedures outlined in Unison’s maintenance literature. Unison does not warrant the future availabil‐ ity of expendable maintenance items. Warranty Period: This Unison warranty is valid for 18 months from the time the equipment is shipped from Unison’s factory or 12 months from the date of startup, whichever occurs first. Repairs During Warranty Period: All warranty claim requests must be initiated with a Return Material Authorization (RMA) number for processing and tracking purposes. The RMA number shall be issued to the Owner upon claim approval and/or field inspection. When field service is deemed necessary in order to determine a warranty claim, the costs associated with travel, lodging, etc. shall be the responsibility of the Owner except under prior agreement for a field inspection. This warranty does not include reimbursement of any costs for shipping the equipment or parts to Unison or an authorized service establishment, or for labor and/or materials required for removal or reinstallation of equipment or parts in connection with a warranty repair. This warranty covers only those repairs that have been conducted by Unison or by a Unison authorized warranty service provider, or by someone specifically authorized by Unison to perform a particular repair or service activity. All component parts replaced under the terms of this warranty shall become the property of Unison. UNISON ASSUMES NO OTHER WARRANTY FOR ITS EQUIPMENT, EITHER EXPRESS OR IMPLIED, INCLUDING ANY IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR NONINFRINGEMENT, OR LIABILITY FOR ANY INCIDENTAL OR CONSEQUENTIAL DAMAGE. 5451 Chavenelle Road, Dubuque, Iowa 52002 2013 Unison Solutions, Inc. [O] 563.585.0967 [F] 563.585.0970 www.unisonsolutions.com WARRANTY STATEMENT