8.5 ACID DEPOSITION INTRODUCTION: - DEFINED Acid deposition (a secondary pollutant) is the process by which acid-forming pollutants are deposited on Earth’s surface. - acid deposition can be _________ (e.g. rain) or ________ (particle or gas) - The most prevalent form of acid deposition is acid ___________. - Acid rain can be considered to be a major _______________ environmental problem. - Other acid deposition forms include __________, ___________ and __________. *CAUSES OF ACID RAIN: - The major pollutants that cause acid rain are sulfur dioxide, SO2 and nitrogen oxides, NO and NO2. *These oxides react with water to form the strong acids: ______________ and _________________ acids. - ____ industrialization/economic development = ____ emissions of sulfur/nitrogen oxides = ____ acid rain -Note that sources of these oxides may also be _________________ in origin. Main Sources of sulfur and nitrogen oxides: NATURAL OCCURANCES HUMAN ACTIVITY - volcanic eruptions - combustion of ______________ fuels (e.g. coal, oil) containing high levels of _______________ impurities - decomposition of vegetation - the internal combustion engine(NOx) - e.g. car and jet engines - emissions from ________________ (SO2) - refining of copper, nickel and other metal ores that contain sulfur *ADVERSE EFFECTS/ IMPACTS OF ACID RAIN / ACID DEPOSITION: - acidification of lakes and river via precipitation and leaching of minerals from soil - deforestation - uptake of toxic minerals/metals from soil/water by plants and marine-life - resulting negative impact on fishing industry (disappearance of fish species such as Atlantic Salmon and Brown Trout) - negative impacts on people’s health - corrosion effects on marble, limestone, metal buildings, bridges and vehicles FORMATION OF ACID RAIN 1. FROM CO2(g) [*Rainwater is naturally acidic (pH 5.6). Acid rain has pH < 5.6.] *2. OXIDES OF SULFUR *3. OXIDES OF NITROGEN The US Environmental Protection Agency and the Acid Deposition Monitoring Network in East Asia: (EANET) http://www.eanet.asia/ Interrelationships of Global Environmental Issues: ACID DEPOSITION Interrelationships of Global Environmental Issues," White Paper on the Environment, 2001. Ministry of the Environment of Japan (2001).