1 Unit 2 Chemical Reactions Day 1̸ 2 Review chemical equation basics : reactants, products, + sign, arrow, word equations, skeleton equations, symbols for state of matter. State the law of conservation of mass . Balancing equations ( 6 basic steps ), distinguish between subscripts and coefficients. Complete pg 112 (1,2 ) , pg 113 (3,4 ), pg 116 ( 5,6 ), pg 117 ( 7- 9), pg 118 ( 2,4 ). Worksheets Day 3 Types of chemical reactions (5) (pg. 119) Synthesis : metallic oxides versus non-metallic oxides pg 122 ( 10-12 ) ; pg 123 ( 14-16 ) ; Decomposition pg 123 ( 14-16 ) ; combustion ( complete versus incomplete) pg 124 ( 17-20 ) ; pg 125 (1-5 ) Day 4 Lab : Complete and incomplete combustion of Acetylene Day 5 Single Displacement reactions and the activity series ; reactivity of metals in water pg 127 ( 21 ) ; reactivity of metals with metallic ion solutions pg 131 ( 22 ) ; reactivity of non-metallics with nonmetallic ions in solution. Pg 131 ( 23,24 ) Day 6 Inquiry lab : Activity series based on metals reacting with metallic ions in solution pg 128 Day 7-8 Double displacement reactions ; formation of precipitate ; solubility rules ; pg 134 ( 25 ) ; production of a gas pg 135 ( 26 ) ; neutralization reactions pg 135 ( 27,28 ) pg 140 ( 1-4 ) Introduce independent research project Day 9 Lab : Types of Reactions Day 10 Lab : Reactions involving oxygen Day 11 Predicting products of reactions. Complete pg.122 10, 12; pg. 123 (14-16), pg. 124 ( 17 -20 ); pg 125 (1-3) Pg. 127 (21) Day 12-13 Powerpoint Presentations Day 14 Chapter 4 review pg 149 ( 3-12,14-18, 22, 23 ) Day 15 Unit Review pg 156 ( 34,35,41,56 ) Day 16 Unit Test 2 Day 1̸ 2 Review chemical equation basics : reactants, products, + sign, arrow, word equations, skeleton equations, symbols for state of matter. State the law of conservation of mass . Balancing equations ( 6 basic steps ), distinguish between subscripts and coefficients. Complete pg 112 (1,2 ) , pg 113 (3,4 ), pg 116 ( 5,6 ), pg 117 ( 7- 9), pg 118 ( 2,4 ). Worksheets Defintions : Reactants - ____________________________________________________________________ Products - ____________________________________________________________________ + sign - ____________________________________________________________________ arrow - ____________________________________________________________________ state of matter - s _____________ l ____________ law of conservation of mass - g ___________ aq _____________ _________________________________________________________________ word equations - ___________________________________________________________ skeleton Equations - ___________________________________________________________ What about...Rules for Balancing Equations? ( see pg 116 – 6 steps ) 1. Be patient! 2. Check for the 7-diatomic molecules. H2, N2, O2, F2, Cl2, Br2, I2 3. Balance Metals. 4. Balance Nonmetals. Balance polyatomic radicals as a group. 5. Balance Oxygen. 6. Balance Hydrogen. 7. Recount all atoms. 8. If every coefficient will reduce, rewrite it in the simplest whole-number ratio. Watch video : How to balance a chemical reaction – you tube Pg.112 ( Words to balanced equation ) 1a. _________________( ) _____ ______________ b. + _________________( ) => _______________________ ( ) + ______ _____________ => ____ __________________ ______________( ) + ______________( ) => ________________ ( ) + ________________( ) ____ __________ + ____ ___________ => ____ __________ + ____ ___________ c. _______________( ) + ____________( ) + ____________( ) => _____________________( ) 3 ___ ________________ + _____ ___________________ => ____ ___________________________ d. ___________________________( ) => __________________( ) + _________________( ) _____ _______________________ => _____ _________________ + _____ ______________________ 3a. ____________________( ) + _________________( ) => ______________________( ) _____ __________________ + _____ _____________________ => _____ ________________________ b. _________________( ) + ___________________( ) => ____________( ) + ____________( ) ____ __________________ + _____ ________________=> ____ ______________ + ____ _____________ c. __________________( ) + ________________( ) => ________________________( ) ____ ________________________ + _______ __________________ => ____ ______________________ d. ________________( )+ _______________( ) => 4a. ____________________( ) + _________________( ) + ________________( ) _________________( ) => ______________________( ) ____ _____________________ + ____ ____________________ => ___ _____________________ b. ___________________( ) + _________________( ) => ______________________( ) ___ ____________________ + ____ ___________________ => _______ ____________________ c. __________________( ) + ___________________( ) => ________________________( ) ___ ______________ + _____ ________________ => ____ __________________________ pg 116 (5,6) 5a. ____ S + ____ O2 b. ____ P4 + ___ O2 => ____ SO3 => ____ P4O10 c. ____ H2 + ____ Cl2 => ____ HCl d. ____ SO2 + ___ O2 => ____ SO3 6a. _____ Fe b. _______ HgO => ____ Hg + c. _____ H2O2 d. _____ HCl + ____ Na2SO4 + _____ O2 => ____ H2O => ____ Fe2O3 ____ O 2 + ___ O2 => ____ NaCl + ___ H2O BALANCING CHEMICAL EQUATIONS + ____ SO2 4 Balance the following chemical equations: 1 ______Al (s) + ______HCl (aq) => ______AlCl3 (aq) + ______H2 (g) 2 ______K (s) + ______H2O (l) => ______KOH (aq) + ______H2 (g) 3 ______Mg (s) + ______N2 (g) => ______Mg3N2 (s) 4 ______NaNO3 (s) => ______NaNO2 (s) + ______O2 (g) 5 _____Ca(OH)2 (s) + _____H3PO4 (aq) =>_____Ca3(PO4)2 (s) + _____H2O (l) 6 ______C3H8 (g) + ______O2 (g) =>______CO2 (g) + ______H2O (g) 7 ______NH3 (g) + ______O2 (g) => ______NO (g) + ______H2O (g) 8 ____NH3 (g) + ____CuO (s) =>____N2 (g) + ____Cu (s) + ____H2O (g) 9 ______C12H22O11 (s) + ______O2 (g) => ______CO2 (g) + ______H2O (g) 10 ______FeO (s) + ______O2 (g) =>______Fe2O3 (s) 11 ______CS2 (l) + ______NH3 (g) =>______H2S (g) + ______NH4SCN (s) Pg. 118 ( 2,4 ) Pg. 118 (8) 8a. _____ As4S6 + _____ O2 => ____ As4O6 + _____ SO2 5 b. ______ Sc2O3 + ___ H2O c. ____ C2H5OH d. ______ C4H10 + _____ O2 => _____ CO2 + _____H2O 2a. __ __________ + ___ ____________ => ____ _______________________ b. ___ ____________ + ___ ______________ => ___ ______________ + ___ ____________ c. ___ _____________ + ___ ____________ => ___ ___________ + ___ ________ + __ _____ + ____ O2 => ____ Sc(OH)3 => _____ CO2 + _____H2O 4a. b. c. d. e. Balancing Chemical Equations 1 ___ Cu(s) + ___ O2(g) => ___ CuO(s) 6 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Day 3 ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ H2O(l) => ___ H2(g) + ___ O2(g) Fe(s) + ___ H2O(g) => ___ H2(g) + ___ Fe3O4(s) AsCl3(aq) + ___ H2S(aq) =>___ As2S3(s) + ___ HCl(aq) CuSO4•5H2O(s) => ___ CuSO4(s) + ___ H2O(g) Fe2O3(s) + ___ H2(g) => ___ Fe(s) + ___ H2O(l) CaCO3(s) => ___ CaO(s) + ___ CO2(g) Fe(s) + ___ S8(s) => ___ FeS(s) H2S(aq) + ___ KOH(aq) => ___ HOH(l) + ___ K2S(aq) NaCl(l) => ___ Na(l) + ___ Cl2(g) Al(s) + ___ H2SO4(aq) => ___ H2(g) + ___ Al2(SO4)3 H3PO4(aq) + ___ NH4OH(aq) => ___ HOH(l) + ___ (NH4)3PO4(aq) C3H8(g) + ___ O2(g) => ___ CO2(g) + ___ H2O(l) Al(s) + ___ O2(g) =>___ Al2O3(s) CH4(g) + ___ O2(g) => ___ CO2(g) + ___ H2O(l) KNO3 => ___ KNO2 + ___ O2 CaC2 + ___ O2 => ___ Ca + ___ CO2 C5H12 + ___ O2 => ___ CO2 + ___ H2O K2SO4 + ___ BaCl2 =>___ KCl + ___ BaSO4 KOH + ___ H2SO4 => ___ K2SO4 + ___ H2O Ca(OH)2 + ___ NH4Cl =>____ NH4OH + ___ CaCl2 C + ___ SO2 => ___ CS2 + ___ CO Mg3N2 + ___ H2O =>___ Mg(OH)2 + ___ NH3 V2O5 + ___ Ca => ___ CaO + ___ V Na2O2 + ___ H2O => ___ NaOH + ___ O2 Fe3O4 + ___ H2 => ___ Fe + ___ H2O Cu + ___ H2SO4 => ___ CuSO4 + ___ H2O + ___ SO2 Al + ___ H2SO4 => ___ H2 + ___ Al2(SO4)3 Si4H10 + ___ O2 => ___ SiO2 + ___ H2O NH3 + ___ O2 => ___ N2H4 + ___ H2O C15H30 + ___ O2 => ___ CO2 + ___ H2O BN + ___ F2 => ___ BF3 + ___ N2 CaSO4•2H2O + ___ SO3 => ___ CaSO4 + ___ H2SO4 C12H26 + ___ O2 => ___ CO2 + ___ H2O C7H6O3 + ___ O2 => ___ CO2 + ___ H2O Na + ___ ZnI2 => ___ NaI + ___ Zn HBrO3 + ___ HBr =>___ H2O + ___ Br2 Al4C3 + ___ H2O => ___ Al(OH)3 + ___ CH4 Ca(NO3)2•3H2O + ___ LaC2 => ___ Ca(NO3)2 + ___ La(OH)2 + ___ C2H2 CH3NO2 + ___ Cl2 => ___ CCl3NO2 + ___ HCl Ca3(PO4)2 + ___ SiO2 + ___ C => ___ CaSiO3 + ___ CO + ___ P Al2C6 + ___ H2O => ___ Al(OH)3 + ___ C2H2 NaF + ___ CaO + ___ H2O => ___ CaF2 + ___ NaOH LiH + ___ AlCl3 => ___ LiAlH4 + ___ LiCl CaF2 + ___ H2SO4 + ___ SiO2 => ___ CaSO4 + ___ SiF4 + ___ H2O CaSi2 + ___ SbCl3 => ___ Si + ___ Sb + ___ CaCl2 TiO2 + ___ B4C + ___ C =>___ TiB2 + ___ CO NH3 + ___ O2 => ___ NO + ___ H2O SiF4 + ___ NaOH =>__ Na4SiO4 + ___ NaF + ___ H2O NH4Cl + ___ CaO => ___ NH3 + ___ CaCl2 + ___ H2O Watch video . five major chemical reactions on you tube ; Types of chemical reactions (5) (pg. 119) Synthesis : metallic oxides versus non-metallic oxides pg 122 ( 10-12 ) ; pg 123 ( 14-16 ) ; Decomposition pg 123 ( 14-16 ) ; combustion ( complete versus incomplete) pg 124 ( 17-20 ) ; pg 125 (1-5 ) 7 TYPES OF CHEMICAL REACTIONS Most reactions can be classified into one of five categories by examining the types of reactants and products involved in the reaction. Knowing the types of reactions can help a person to predict the products which would be formed in a reaction. 1. SYNTHESIS REACTIONS ( 2 singles to a dance ------> couple + heat ) - two or more elements or compounds combine to form a new substance also called a combination reaction e.g. A + B ----> AB a) element + element ------> compound i) formation of an oxide ii) metal + nonmetal ___ Fe(s) + ___O2 (g) ------> ____ Fe3O2 (s) ___ K (s) + ___Cl2 (g) -------> ___ KCl (s) b) compound + compound -------> larger compound i) formation of an acid (oxide of a nonmetal + water) ___SO3 (g) + ___ H2O (l) ------> _____ _________ (aq) ii) formation of a base (oxide of a metal + water) ___CaO (s) + ___H2O (l) -----> ____ __________ (aq) 2. DECOMPOSITION REACTION ( A couple have a heated argument and break up ) - a compound breaks down into elements and/or other compounds e.g. AB ------> A + B a) simplest type is when compound breaks into its component elements ____ H2O (l) ------> ____ H2 (g) + ____O2 (g) b) carbonates usually decompose into carbon dioxide plus the metal oxide when heated ___CaCO3 (s) -------> ____ CaO (s) + _____ CO2 (g) c) others are more complicated and harder to predict 3. COMBUSTION a) reaction of a compound or element with oxygen to form one or more oxides accompanied by the production of light and heat combustion of any compound containing carbon, hydrogen and water, or of a hydrocarbon (a compound containing only C and H) produces carbon dioxide and water CH4 (g) + _____O2 (g) -------> ____ CO2 (g) + _____ H2O (g) - complete combustion occurs if oxygen supplies are sufficient and above products are obtained - incomplete combustion occurs in absence of sufficient oxygen leading to formation 8 of carbon monoxide along with the carbon dioxide and water (sometimes C formed as well) ___CH4 (g) + ___O2(g) ___CO2(g) + __CO(g) + __ C (s) + __H2O (g) + Energy pg 122 ( 10-12 ) ; pg 123 ( 14-16 ) ; Decomposition pg 123 ( 14-16 ) ; combustion ( complete versus incomplete) pg 124 ( 17-20 ) ; pg 125 (1-5 ) 9 Day 4 Lab : Combustion of Fuels Names _______________________________________ Acetylene gas is a fuel used in welding torches, and it combines with oxygen to produce a very hot flame. Because it is an organic compound, it contains carbon. When it burns in pure oxygen, it should produce carbon dioxide. This gas is the product of complete combustion. If there is not enough oxygen, other products form in what we call incomplete combustion. This activity involves complete and incomplete combustion, and you will compare the products formed by both of these reactions. You will then discuss combustion in car engines and furnaces. Challenge: What is the difference between complete and incomplete combustion of a fuel? Materials - 250 mL beaker - 3 test tubes - Test tube holder - Wooden splint - Calcium carbide - Safety Goggles - Masking tape – mark each test tube Procedure a. Calcium carbide ( CaC2 ) reacts with water to form acetylene. Collect a test tube of acetylene as follows: - Half fill a beaker with water. - Invert a test tube full of water into the beaker. - Use forceps to drop a small piece of calcium carbide into the water. - Place the inverted test tube over the calcium carbide (refer to the figure). - Let the acetylene gas completely fill the test tube. - Lift the test tube from the water, allow the air to replace the water that runs out, and place it mouth down on top of the desk. Repeat these steps two more times, but each time collect less acetylene (for example, collect ½ full test tube, and 1/12 full test tube) b. Put your thumb over the mouth of each tube. Shake it hard for 30 seconds to mix the acetylene and air. Then place each test tube mouth down on top of the desk. c. Holding each test tube horizontally, bring a burning splint to its mouth and wait until each reaction is complete. Record your observations. Observations (5 marks) ____________________________________________________________________________________________ ____________________________________________________________________________________________ ____________________________________________________________________________________________ ____________________________________________________________________________________________ 10 Discussion 1. Which test tube held the most oxygen? The least? Explain. (3 marks) 2. In which test tube did complete combustion occur? What product was formed? (2 marks) 3. In which test tubes did incomplete combustion occur? What products formed? (2 marks) 4. Where did the flame burn in the first test tube completely filled with acetylene? Why? (2 marks) 5. If a car engine is not tuned, incomplete combustion occurs. What product will form in the engine? How might it affect the engine? (2 marks) 6. The burner of a gas or oil furnace must be serviced properly; otherwise incomplete combustion of the fuel occurs. Describe the likely results. Why do you think carbon monoxide detectors are put in house basements? (3 marks) _______________________________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ 7. Write balanced chemical equations for complete and incomplete combustion of C 2H2. Note for incomplete combustion reactions there are many possibilities. 1̸12 filled ________________________________________________________________________ 1̸2 filed ________________________________________________________________________ filled _________________________________________________________________________ 11 Day 5 Single Displacement reactions and the activity series ; reactivity of metals in water pg 127 ( 21 ) ; reactivity of metals with metallic ion solutions pg 131 ( 22 ) ; reactivity of non-metallics with non-metallic ions in solution. Pg 131 ( 23,24 ) Single Displacement ( couple + single new couple + single ) ; single causing breakup can be a metal or non- metal One element replaces (or displaces) another element in a compound because it is more active. A + BC AB + C AC + B AC + B (metal replaces a metal ion in a compound) (usually a halogen replaces an anion in a compound) ____ C ( s) + ____Fe2O3 (s) ______ CO(g) + ______ Fe (s) ____KBr (aq) + ____ Cl2 (g) ____KCl (aq) + ___ Br2 (aq) Note: i) Treat hydrogen as a metal ii) Treat acids (e.g HCl) as ionic compounds ( H+, Cl-) iii) Treat water as ionic (H+ , OH-) iv) Use The Activity Series of the Elements Table : any element will displace another element below it on the series. This is used to predict if a reaction will occur or not. Single Displacement Reactions and the Activity Series (pg 130) It is possible to arrange metals in the order of their chemical reactivities and thereby establish an activity series of metals. • The more metallic elements are located near the top of the activity series. As you go from top to bottom in an activity series the metallic nature of elements decreases. • Reactivity of metals towards other elements decreases as you go down the series. The stability of their compounds also decreases. • Group I metals in the periodic table are the most reactive followed by Group II elements. • A metal will displace from a compound any other metal which is located below it in the activity series. Ex. Zinc will displace copper from copper nitrate but can not displace magnesium from magnesium nitrate. • Metals above hydrogen will react with acids to liberate hydrogen and form salts. This will not occur with elements found below hydrogen in the series. • Elements from cadmium and up liberate hydrogen from hot water or steam • Elements from sodium and up liberate hydrogen from cold water Thus it can be noted that the activity series is useful because it indicates the possibility of reaction of a given metal with water, acids, oxygen, sulphur, halogens and compounds of other metals. It also provides a good indication of the relative stability of compounds of any metal. a) one metal displaces another metal in an ionic compound ____Cu (s) + ____ AgNO3 (aq) -------> ____ Cu(NO3)2 (aq) + ____ Ag (s) b) a metal displaces the hydrogen in an acid Mg (s) + _____HCl (aq) --------> MgCl2 (aq) + H2 (g) c) a metal displaces the hydrogen in water ___Na (s) + ____ H2O (l) -------> ____ NaOH (aq) + ____ H2 (g) d) a non metal displaces another nonmetal in a compound 12 Cl2 (g) + CaBr2 (aq) ------> ____________(aq) + _____________(l) Activity Series Metals : Non-metals : Halogens F2 Cl2 Br2 I2 Pg. 127 21b. _____Zn c. _____ Al d. _____ Cu g. _____ Ba + _____ Pb(NO3)2 + + _____ HCl => ____ _________ + ____ _____________ => _____ AgNO3 + ____ FeCl2 ____ _________ + _____ _____________ => ____ _________ + ____ _____________ => ____ ________ + ____ ______________ Complete pg 131(22-24) below: 22a. _____ Cu + ______ MgSO4 => ____ ___________ + ____ _____________ b. ____ Zn + ______ FeCl2 => ___ _____________ + ____ _____________ c. ____ K + _____ H2O => ____ _____________ + ____ _____________ e. ____ Fe + ____ Al2(SO4)3 => ____ _____________ + ____ ______________ g. ____ Ag + ____ H2SO4 => ____ ______________ + ____ ______________ h. ____ Mg + ____ SnCl2 => ____ ______________ + ____ ______________ 23a. ____ Br2 + ____ KCl => ____ ______________ + ___ ______________ b. ____ Cl2 + ____ NaI => ____ ______________ + ___ ______________ 24a. ____ Pb + ____ HCl b. ____ KI + _____ Br2 => c. ____ KF + _____ Cl2 => ____ ______________ + ___ _____________ d. _____ MgSO4 + _____ Zn => e. ____ Ni + ____ H2SO4 => ____ ______________ + ___ _____________ ____ ______________ + ___ _____________ ____ ___________ + ____ ____________ => ___ ________________ + ____ __________ 13 Day 6 : Lab : Activity Series Names ______________________________________ Introduction In a single displacement reaction, an element replaces a similar element in a compound to create a new element and a new compound. In order for the reaction to take place, the element must be more active, or reactive, than the element in the compound. The activity series of metals lists the elements according to their reactivity, with more reactive elements at the top of the list and less reactive elements at the bottom. The activity series explains why some single displacement reactions work and others don’t. In this lab, you will perform a series of micro-scale experiments to determine the reactivity of several common metals. Then you will create your own activity series of metals based on the results. SAFETY Hydrochloric acid can cause burns to the skin and damage the eyes. Wear goggles at all times. Do not directly inhale any gases produced in this lab. PROCEDURE 1. Arrange the solid metals in the respective wells of the well plate as shown in the data table. Use a small piece or “1/4 of a pea” sized amount of the powdered metals. 2. Add about 6-10 drops of the solutions indicated in the data table to the appropriate wells. Record your observations of any color changes or gas production below. 3. NOTE: Reactions involving very active metals are fast while reactions involving less active elements tend to be very slow. BE PATIENT as you make observations in this lab. Note in each row which metal reacts first and the most readily. Include this information in the observations section below. 4. CLEAN UP: Soak up all remaining solutions and wrap left-over solids in a paper towel and place it in the trashcan. SOLIDS SHOULD NOT BE LEFT IN THE SINK. Rinse the well plate with water and dry it with a paper towel. OBSERVATIONS zinc metal Pb(NO3)2 solution CuSO4 solution AgNO3 solution HCl solution aluminum foil copper metal 14 ANALYSIS Write a balanced equation for each single displacement reaction that took place. Include state symbols for all reactants and products. CONCLUSIONS 1. Which metal element (Zn, Al or Cu) produced the most obvious reactions? ________ Which solution produced the most vigorous reactions? ______________________ 2. Which metal element was largely unreactive? _____________________ Which solution(s) produced the least/smallest reactions? ______________________ 3. Based on the results of your experiment, determine which metal is the more active metal in each pair: HINT: Remember the more active element will cause a reaction. If you saw a reaction with the metal and the solution, the metal element was more active. If you did not see a reaction between the metal and the solution, the element in the solution was more active. Circle the correct answer. Zn vs. Pb Al vs. Pb Cu vs. Pb Zn vs. Cu Al vs. Cu Zn vs. Ag Al vs. Ag Cu vs. Ag Zn vs. H Al vs. H Cu vs. H 4. Based on the results of your experiment, create an activity series of the following metals: Zn, Al, Cu, Pb, Ag, H. (List the most reactive elements first and the least reactive elements last). 15 Day 7 Double displacement reactions ; formation of precipitate ; solubility rules ; pg 134 ( 25,28a ) ; production of a gas pg 135 ( 26 ) ; neutralization reactions pg 135 ( 27,28 ) pg 140 ( 1-4 ) DOUBLE DISPLACEMENT REACTIONS ( couples change partners ) -the exchange of cations between two ionic compounds -usually in aqueous solutions AB + CD ------> AD + CB (A and C are cations, B and D are anions) a) formation of a precipitate -one of the products will be insoluble in water and produce a precipitate -the other product will be soluble -solubility is determined by using a table of solubilities ( see chemistry helper ) ____BaCl2 (aq) + ____ K2SO4 (aq) -------> ___ BaSO4 ( ) + ____ KCl ( ) Solubility is a measure of how a substance dissolves in water at a given temperature and pressure. A substance that does not dissolve well in water is called insoluble . Chalk is a substance that has a low solubility. Substances like sodium chloride, NaCl, that dissolve well in water are called soluble. Look at the Solubility Table pg 666 Predicting The Formation of A Precipitate Follow these steps to correctly determine if a product is an insoluble precipitate. Example 1: Determine the products (if any) when a solution of sodium sulfate is mixed with a solution of lead(II) nitrate. If a reaction occurs, summarize the reaction as a balanced chemical equation. Step What you should write 1 We are starting with two compounds therefore this is a double displacement reaction and the products will be sodium nitrate and lead(II) sulphate 2 sodium sulphate + lead(II) nitrate ------> 3 Anything with nitrate in it is soluble, anything with sodium in it is soluble therefore only lead(II) sulphate is insoluble 4 sodium sulphate(aq) + lead(II) nitrate(aq) ------> sodium nitrate + lead(II) sulphate 5 Na2SO4(aq) + Pb(NO3)2 -----> NaNO3(aq) + 6 Na2SO4(aq) + Pb(NO3)2 -----> _____NaNO3(aq) + sodium nitrate(aq) + lead(II) sulphate(s) PbSO4(s) PbSO4(s) Complete : ___ _____ + _____ ZnCl2 (aq) ____ZnS(s) + ____ NaCl(aq) _____ Na2CO3(aq) + _____ Ca(OH)2(aq) _____ NaOH( ) + _____ CaCO3( ) Complete pg 134 (25,28a) 16 b) formation of a gas Reactions Producing Gas ( double displacement followed by decomposition ) Reactions Producing Gas Summary of Reactions Producing Gas pg 135 ( 26 ) c) Neutralization A special double displacement reaction involving an acid and a base. The reaction always produces a ________ and __________. The acid provides the ____ and the base _________ to make ________________. Acid + HCl(aq) Base + ______________ + _________________ NaOH (aq) _________(aq) + __________(l) H2SO4 (aq) + ___NaOH (aq) _____(aq) + ___ ___________( ) 17 pg 135 ( 27,28 ) pg 140 ( 1-4 ) 18 Day 8 Double Displacement Name _________________ Date __ Period 1. Re-write the reactants with appropriate state symbols (use the solubility chart on the back of the periodic table). 2. Predict the products for each double displacement reaction. 3. Use the solubility rules again to determine the states of each product. Example: 2NaCl(aq) + H2SO4(aq) Na2SO4(s) + 2HCl(aq) 1. FeBr2 + K2CO3 2. Ag2S + CuCl2 3. Pb(NO3)2 4. BaI2 + HI + H2SO4 5. CuBr2 + K2S 6. Na3PO4 7. NaC2H3O2 + MgSO4 + AgNO3 8. FeCl2 + H2S 9. (NH4)2SO3 + Sr(OH)2 10. HCl + NH4OH Complete pg 135 ( 26-28 ) 19 Independent Research Powerpoint Presentations : Computer lab A. Analyse, on the basis of research, chemical reactions used in various industrial processes ( e.g. pulp and paper production, mining and chemical manufacturing ) that can have an impact on the health and safety of local populations. Consider the issue : base metal smelting produces useful metals such as zinc, lead, copper and nickel directly from their ores. However during smelting harmful compounds can be released into the environment, including cadium, arsenic, sulphur dioxide and mercury, all of which can endanger the health and safety of local populations. Answer the questions that follow : 1. What are some chemical reactions used in the manufacture of paper. ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ________________________ 2. How might the reactants or products of the pulp and paper production process affect the health of people living near the plant. ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 3. In what ways might the leaching of chemicals from tailing ponds affect the water quality in a local community. ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 4. In what ways do toxic chemical fires affect local communities. ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 20 B Assess the effectiveness of some applications of chemical reactions that are used to address social and environmental needs and problems. Consider the issue : Scrubber systems are a group of air pollution control devices used by industry to remove or neutralize exhaust gases before they reach the atmosphere. Scrubber technologies help to reduce acid precipitation, but there are many different scrubbing techniques with varying levels of effectiveness in controlling acid gas emissions. Answer the questions that follow : 1. How are chemical reactions used to remediate environments affected by oil spills. ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ 2. How can tailing ponds be rehabitated to lesson the effects of hazardous chemicals on plant populations. ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ 3. What types of chemical reactions can change a toxic chemical into one that is less toxic or non-toxic. ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ 21 Science PowerPoint Rubric Names ____________________________________________________________ Topic __________________________________________________________________ Category Introduction Content Excellent Good Poor or Not Observed 3 points 2 points 1 point 0 points The introduction presents the overall topic and draws the audience into the presentation with compelling questions or by relating to the audience's interests or goals. The introduction is clear and coherent and relates to the topic. The introduction shows some structure but does not create a strong sense of what is to follow. May be overly detailed or incomplete and is somewhat appealing to the audience. The introduction does not orient the audience to what will follow. 10 points 6 points 4 points 0 points The content is written clearly and concisely with a logical progression of ideas and supporting information. The content is written with a logical progression of ideas and supporting information. The content is vague in conveying a point of view and does not create a strong sense of purpose. The content lacks a clear point of view and logical sequence of information. Includes persuasive information from reliable sources. Includes some persuasive information with few facts. The project includes motivating questions and advanced organizers. The project gives the audience a clear sense of the project’s main idea. Some of the information may not seem to fit. Sources used appear unreliable. Information is accurate, current and comes mainly from * primary sources. Text Elements Fair The sequencing is unclear and does not appear interesting or relevant to the audience. Includes little persuasive information and only one or two facts about the topic. Information is incomplete, out of date and/or incorrect. Sequencing of ideas is unclear. 6 points 4 points 2 point 0 points The fonts are easy-toread and point size varies appropriately for headings and text. Sometimes the fonts are easy-to-read, but in a few places the use of fonts, italics, bold, long paragraphs, color or busy background detracts and does not enhance readability. Overall readability is difficult with lengthy paragraphs, too many different fonts, dark or busy background, overuse of bold or lack of appropriate indentations of text. The text is extremely difficult to read with long blocks of text and small point size of fonts, inappropriate contrasting colors, poor use of headings, subheadings, indentations, or bold formatting. Use of italics, bold, and indentations enhances readability. Text is appropriate in length for the target audience and to the point. The background and colors enhance the readability of text. POINTS 22 Layout 6 points 4 points 2 point 0 points The layout is visually pleasing and contributes to the overall message with appropriate use of headings, subheadings and white space. The layout uses horizontal and vertical white space appropriately. The layout shows some structure, but appears cluttered and busy or distracting with large gaps of white space or uses a distracting background. The layout is cluttered, confusing, and does not use spacing, headings and subheadings to enhance the readability. 4 points 2 points 0 points Sources of information are properly cited so that the audience can determine the credibility and authority of the information presented. Most sources of information use proper citation, and sources are documented to make it possible to check on the accuracy of information. Sometimes copyright No way to check validity of guidelines are followed information. 8 points 4 points 2 points 0 points The graphics, sound and/or animation assist in presenting an overall theme and enhance understanding of concept, ideas and relationships. The graphics, sound/and or animation visually depict material and assist the audience in understanding the flow of information or content. Many of the graphics, sounds, and/or animations seem unrelated to the topic/theme and do not enhance the overall concepts. The graphics, sounds, and/or animations are unrelated to the content. Images are created using proper size and resolution, and all images enhance the content. Images are proper size, resolution Most images enhance the content. Scholarly Credits 8 points Graphics, Sound and/or Animation Writing Mechanics Images are too large/small in size. or images are poorly cropped or the color/resolution is fuzzy. Graphics do not enhance understanding of the content, or are distracting decorations that create a busy feeling and detract from the content. Fewer than 3 visuals or sounds are used in the presentation At least 8 visuals are embedded in the PowerPoint There are from 5-7 appropriate visuals or sounds in the presentation.. 3-5 visuals or sounds are appropriate for the presentation 9 points 6 points 3 points 0 points The text is written with no errors in grammar, capitalization, punctuation, and spelling. The text is clearly written with little or no editing required for grammar, punctuation, and spelling. Spelling, punctuation, and grammar errors distract or impair readability. Errors in spelling, capitalization, punctuation, usage and grammar repeatedly distract the reader and major editing and revision is required. (3 or more errors) (more than 5 errors) /50 TOTAL POINTS 23 Day 9 Laboratory Experiment: Types of Chemical Reactions Objectives 1. 2. 3. To observe a variety of chemical reactions. To interpret and explain observations with balanced chemical equations. To classify each reaction as one of the seven main types. Most of the solutions that you will be using in this lab are poisonous, corrosive, or irritants. When handling these solutions be sure to wear your goggles properly. Wash any spills and splashes immediately with plenty of water and inform your teacher of what has been spilled. Materials: Bunsen burner Wood splints Test tubes (6) Crucible Ring clamp Clay triangle Tongs Medicine dropper Steel wool Copper wire Iron nail Copper (II) sulfate pentahydrate solid Mossy zinc Hydrogen peroxide solution (3 %) 0.5 M copper (II) sulphate 0.5 M calcium chloride water 0.5 M sodium carbonate 2 M hydrochloric acid manganese dioxide Procedure: 1. Make observations before, during and after each reaction. Record your observations in a table. 2. Each different reaction is at a different station throughout the room. Travel throughout the room so that all of the 7 reactions are completed. Reaction 1 1. 2. Adjust a burner flame to high heat. Using crucible tongs, hold a 6 cm length of copper wire in the hottest part of the flame, for a few minutes. The hottest part of the flame is the top of the blue cone. Reaction 2 CAUTION: Copper (II) sulphate is poisonous. Do not get any in your mouth; wash any spills or splashes away with plenty of water. 1. 2. 3. Clean an iron nail with a piece of steel wool so that the surface of the nail is shiny. Place the nail in the tube and add copper (II) sulphate solution so that one quarter of the nail is covered. After a few minutes, remove the nail and note any changes in both the nail and the solution. 24 Reaction 3 1. Put about 1 cm of solid copper (II) sulphate pentahydrate in a crucible. 2. Attach the ring clamp to the retort stand, place the clay triangle on the ring clamp and stand the crucible on the clay triangle. 3. Heat the crucible with a Bunsen burner until no further change is observed. 4. Save the contents for Reaction 4. Reaction 4 1. Allow the crucible from Reaction 3 to cool for 5-10 minutes (until the crucible is cool to the touch). 2. Use a medicine dropper to add 2 or 3 drops of water to the crucible. 3. Record your observations (feel the bottom of the crucible). Reaction 5 1. One quarter fill a test tube with calcium chloride solution. One quarter fill the other test tube with sodium carbonate solution. 2. Pour the calcium chloride into the sodium carbonate and observe any changes. 3. Dispose of materials down the drain. Reaction 6 CAUTION: Hydrochloric acid is corrosive to skin, eyes and clothing. When handling hydrochloric acid make sure your goggles are on properly. Wash spills and splashes off your skin and clothing immediately using plenty of water and call your teacher. 1. Place a piece of zinc in the test tube. 2. Carefully add hydrochloric acid to the test tube to cover the piece of zinc. 3. Observe any changes. 4. Stopper the test tube for one minute and test the gas by inserting a flaming splint into the mouth of the test tube. Reaction 7 1. 2. 3. Quarter fill a test tube with hydrogen peroxide solution. Add a small amount of manganese dioxide and quickly stopper the test tube with a stopper. Test the gas evolved by inserting a glowing splint into the mouth of the test tube. Reaction 8 1. Place two spatula tips full of copper (II) carbonate, CuCO3, in a clean test tube. Note the appearance of the sample in your observations. 2. Using a test tube holder, heat the CuCO3 strongly in the burner flame for 2-3 minutes. AIM THE MOUTH OF THE TEST TUBE AWAY FROM YOURSELF AND OTHERS. After heating, another group member should ignite a wood splint and quickly place the burning splint into the test tube to test for the presence of CO2 gas. 25 Observations : Reaction # Observations Post Lab Discussion Write balanced chemical equations for each reaction and state type of reaction : 1. _________________ ________________________________________________________________________ 2. _________________ ________________________________________________________________________ 3. _________________ ________________________________________________________________________ 4. _________________ ________________________________________________________________________ 5. _________________ ________________________________________________________________________ 6. _________________ ________________________________________________________________________ 7. _________________ ________________________________________________________________________ 8. _________________ ________________________________________________________________________ Questions 1. In Reaction 1, with which substance in the air did the copper react? _______________________ 2. In Reaction 2, changes occurred in both the nail and the solution. What do the changes in the solution indicate? _____________________________________________________________________________________ 26 3. What evidence did you see that chemical reactions took place in Reactions 3 and 4? ___________________________________________________________________________________ 4. In reaction 5, one of the products is sodium chloride (table salt), which, as you know, is highly soluble in water. What, therefore, would be the product that would account for the precipitate which formed? _________________________________________________________________________________ 5. 6. What does the glowing splint test suggest about the identity of the gas evolved in Reaction 7? _______________________________________________________________ The formula for hydrogen peroxide is H2O2. Two products are formed in Reaction 7, one of which is a common gas which you know from Question 6 and the other a common liquid. What is the most likely identity of this common liquid? _____________________________________ 7. Compare the solid product produced in in reaction 8 to the product in reaction 1. ___________________ 27 Day 10 Chemical Reactions Involving Oxygen Safety: Caution should be used when burning elements. All burning should be done directly under the fume hood. Goggles should be worn at all times. Finally, avoid looking directly at burning magnesium. Part 1: 1. Your teacher will demonstrate the collection of oxygen and the burning of iron (Fe) & magnesium (Mg). 2. Obtain the following equipment: glass plate, 50 mL beaker, 600 mL beaker, glass jar, “deflagrating spoon”, 2 pieces of red litmus, 2 pieces of blue litmus, pneumatic trough, and a plastic bag with a hose. 3. Use the large beaker to fill the pneumatic trough with tap water; make sure the hose drains into the sink. 4. Put on your goggles. Ensure that the fume hood is in place. Ignite your Bunsen burner. Place the spoon in the flame (directly under the fume hood) for 30 seconds to burn away any residue from previous labs. 5. Place approximately 10 - 20 ml of distilled water in the 50 mL beaker. 6. Fill the jar with oxygen via the downward displacement of water (as demonstrated earlier). 7. Once your deflagrating spoon is cool, get a tiny amount of sulfur from your teacher. Heat the spoon by placing it in the middle of a moderate flame (directly under the fume hood). Lift the spoon out of the flame periodically to check if the sulphur is on fire. When a small flame rises from the sulphur, place the spoon in the jar (directly under the fume hood). Catch as much gas as possible in the jar and seal it with the glass plate. If any sulphur remains, burn it away (directly under the fume hood). 8. At this point, a glass plate should be on top of your jar, trapping an oxide gas inside. Slide the glass plate off to one side so that you can pour in the distilled water from your beaker. Try not to let any gas escape. 9. Ensuring that the mouth of the jar is tightly covered with the plate, shake the jar vigorously. This will allow the water to react with the oxide – forming either an acid or a base. Place one piece of blue litmus and one piece of red litmus in the water. Note whether the water has become acidic or basic. Repeat above using charcoal. 10. Rinse and return all equipment, but keep your fume hood and burner set up for Part 2 below. Observations : Reactants Observation 28 Day 11 Predicting products of reactions. Complete pg.122 10, 12; pg. 123 (14-16), pg. 124 ( 17 -20 ); pg 125 (1-3) Pg. 127 (21) Predicting Products 1. Metals plus oxygen produce metallic oxides ( synthesis reaction ) plus heat 2. 3. 4. Metals plus non-metals produce binary compounds ( synthesis reaction ) plus heat Non-metals plus oxygen produce non-metallic oxides ( binary compounds ) ( synthesis reaction ) 2 non-metals produce binary compound ( see preferred valence of the more electropositive element to predict the mostly product ( synthesis reaction ) Reactive metals plus water produce hydroxides plus hydrogen gas ( single displacement ) Reactive metals plus acids produce salts plus hydrogen gas ( single displacement ) Metallic oxides plus water produce hydroxides ( synthesis reaction ) Non-metallic oxides plus water produce acidic solutions (synthesis reaction) Binary compounds heated produce two elements Carbonates plus heat produce oxides plus carbon dioxide gas ( decomposition ) Halides plus reactive halogen produce a new halide plus a new halogen (single displacement) 2 soluble salts produce precipitate plus new soluble salt ( double displacement ) Carbonate plus acid produce salt plus water plus carbon dioxide ( double displacement followed by decomposition. Acid plus base produce salt + water ( double displacement ) ( neutralization ) Organic compound plus oxygen produce carbon dioxide plus water ( complete combustion ) 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. pg 140 ( 1,2 ) 1a. ___ Li + ___ H2O ___ __________ + ___ ________________ b. ___ Sn + ___ FeCl2 ___ __________ + ___ ________________ c. ___ F2 + ___ KI d. ___ Al + ___ MgSO4 ___ __________ + ___ ________________ e. ___ Zn + ___ CuSO4 ___ __________ + ___ ________________ f. ___ K + ___ H2O ___ __________ + ___ ________________ 2a. ___ NaOH(aq) b. ___ Ca(OH)2 (aq) + ___ HCl(aq) ___ __________(aq) + ___ ________________(l) c. ___ K2CrO4(aq) d. ___ K2CO3(aq) + ___ H2SO4(aq) ___ __________(aq) + ___ ____________(l) + ___ _________(g) ___ __________ + ___ ________________ + ___ Fe(NO3)3 (aq) ___ __________(s) + ___ ________________(aq) + ___ NaCl(aq) ___ __________ + ___ ________________ 29 Types of Reactions Review Worksheet Name______________________ Identify the type of reaction. Predict the products and then write a balanced equation for each reaction. Remember your formulas for the products must be consistent with the charges on common ions. ______________________ 1. ______________________ 2. ___ KClO3(s) ___ ________(s) + ___ ___________(g) ___ KCl (aq) + ___ AgNO3 (aq) ___ ____(s) + ___ _(aq) _______________________3. ___NaIO3 _______________________4. ___ Zn +___ H2SO4 ___ ______(aq) + ___ _________(g) _______________________5. ___BaCl2(aq) + ___ K2SO4(aq) ___ ____(s) + ___ ___(aq) _______________________6. ___ KBr(aq) _______________________7. ___AgNO3(aq) + ___ K2CO3 (aq) ___ ____(s) + ___ __(aq) _______________________8. ___ CaCl2(aq) + __Na3PO4(aq) ___ ____(s) + ___ ____(aq) _______________________9. ___CaCO3 (s) ___ ________(s) + ___ ___________(g) _______________________10. _______________________11. _______________________12. ______________________13. _______________________14. ___ ________(s) + ___ ___________(g) + Cl2 (g) ___ ______(aq) + ___ ________(g) ___N2 ( ) + ___ O2 ( ) ___ ____________ (g) ___ FeCl2 (s) + Cl2 (g ) ___ _____________( ) ___HCl (aq) + ___NaOH ______(aq) + ___ ________(l) ___ CaCl2 (aq)+ ___ Na2CO3(aq) ___ ____(s) + ___ ____(aq) ___Mg(s) + ___ CuBr2 (aq) ___ ____(s) + ___ ____(aq) _______________________15. ___H2 (g) + ___O2(g) ___ ________(g) _______________________16. ___ Al (s) + ___Cl2(g) ___ __________(s) _______________________17. ___BaCl2 (aq) +___ K2CO3 (aq) ___ ____(s) + ___ ____(aq) _______________________18. ___ Mg(s) + _______________________19. ___Zn (s) ______________________ 20. ______________________ 21. ___O2 (g) ___ ___________(s) + ___ CuSO4(aq) ___ ____(s) + ___ ____(aq) ___ Al (s) + ___CuSO4 (aq) ___ ____(s) + ___ ____(aq) ___ C2H2(g) + ___ O2(g) ___ ____(g) + ___ ____(g) ______________________ 22. ___ C2H2(g) + ___ O2(g) ___ ____(g) + ___ ____(g) + ___ C(s) 30 Pg 122 10. 12. a. ____ K + ____ Br2 => ____ ______ ___________________ d. _____ Li + ____ O2 => _____ ______ ____________________ a. _____ K2O + ____ H2O => ____ ________________ _________________ d. _____ SO2 + ____ H2O => ____ ______________ ______________________ 14. _____ HgO => ___ _______ + ___ _________ _______________________ 15. b. ____ Ag2O => _____ ________ + ____ __________ c. ____ AlCl3 => ___ ____________ + ___ ____________ _____________________ 16. a. ____ MgCO3 => ___ ___________ + ____ _____________ ___________________ 17. ____ CH3OH + ____ O2 18. ____ C8H18 19. _____ C3H6O 20. ____ C16H34 + ____ O2 => ____ _________ + ___ _________ ____________________ => ____ _________ + ___ _________ + ____ O2 => ____ _________ + ___ _________ + ____ O2 => ____ _________ + ___ _________ ____________________ __________________ ____________________ ____________________ Pg. 125 1a. _____ Be + ____ O2 => ____ _______________ b. _____ Li + _____ Cl2 => ____ _________________ c. _____ Mg + _____ N2 => ___ __________________ d. ______ Al + ____ Br2 2a. ____ K2O b. ____ CuO => ___ __________ + ____ _______________ d. _____ Ni2O3 => ___ _______________ + ____ ________________ 3a. b. => ____ ___________________ => ___ ____________ + ____ _________________ _____________________________ => __________________ + _________________ __ __________ + ___ ____________ => ____ _______________________ 31 TYPES OF REACTIONS 1.) Predict the products for each of the following ADDITION rxns. a.) Mg(s) + I2(g) b.) CaO(s) + H2O(l) c.) CO2(g) + H2O(l) + d.) Al(s) + O2(g) e.) Na2O(s) + H2O(l) 2.) Predict the products for each of the following DECOMPOSITION rxns a.) MgCl2(s) b.) BeCO2(s) c.) H2CO3(s) + d.) LiHCO3(s) e.) K3N(s) 3.) Predict the products for each of the following SINGLE DISPLACMENT rxns a.) H2(g) + SnO(aq) b.) K(s) + Zn(NO3)2(aq) c.) Cl2(g) + NaBr(aq) + + d.) Ba(s) + H2O(l) e.) Cu(s) + HCl(aq) 4.) Predict the products for each of the following DOUBLE DISPLACEMENT rxns. Show the states. a.) (NH4)2S(aq) + AlCl3(aq) b.) Ba(OH)2(aq) + Li3PO4(aq) c.) Pb(NO3)2(aq) + Na2SO4(aq) + + d.) K2CO3(aq) + MgS(aq) e.) Sr(OH)2(aq) + Rb2SO4(aq) 5.) Predict the products for each of the following COMBUSTION rxns a.) complete combustion: CH4 + O2 b.) complete combusiton: c.) incomplete combusiton: C2H2 + O2 CH3OH + O2 + O2 32 6.) Predict the products for each reaction below and state the type of reaction. All reaction types are represented. a.) Ba(NO3)2(aq) + Na2SO4(aq) Type: ___________________ b.) Cu(s) + O2(g) Type: ___________________ c.) Ni(s) + H2SO4(aq) Type: ___________________ d.) Zn(s) + F2(g) Type: ___________________ e.) LiHCO3(s) Type: ___________________ f.) Ca(s) + H2O(l) Type: ___________________ g.) Al2O3(s) + H2O(l) Type: ___________________ h.) MgO(s) Type: ___________________ i.) Sr(OH)2(aq) + Ca(NO3)2(aq) Type: ___________________ j.) Br2(g) + CaI2(aq) Type: ___________________ k.) Au(s) + H3PO4(aq) Type: ___________________ Day 12-13 Powerpoint Presentations 33 Day 14 Chapter 4 review pg 149 ( 3-12,14-18, 22, 23 ) Day 15 Unit Review pg 156 ( 34,35,41,56 ) Day 16 Unit Test