Nomenclature: Naming Chemicals PO43phosphate ion HC2H3O2 Acetic Acid C2H3O2acetate ion SAVE PAPER AND INK!!! When you print out the notes on PowerPoint, print "Handouts" instead of "Slides" in the print setup. Also, turn off the backgrounds (Design>Hide background graphics with all slides selected) Before&naming….& ! Some%things%you%MUST% know%to%be%successful….%You% really%need%to%commit%these% things%to%memory% 1 Ions:&A&Refresher& ! Atoms%or%groups%of%atoms%with%a%charge.% ! Cations@%positive%ions%@%get%by%losing% electron(s).% ! Anions@%negative%ions%@%get%by%gaining% electron(s).% ! Ionic%bonding@%held%together%by%the% opposite%charges@%electrostatic%attractions.% ! Ionic%solids%are%called%salts.% ! Salts%are%electrolytes;%they%conduct% electricity%when%dissolved%in%water%(aq.)% " Conductors of heat and electricity " Make cations (lose e to become + charged) " Malleable (made into sheets) " Ductile (made into wire) - 2 " Are a brittle solid or a gas " Make anions (gain e- to become - charged) " Covalently bond to each other • Characteristics of both metals and nonmetals • More metallic as you go down PT 3 Alkali Metals Alkaline Earth Metals 4 Transition metals Inner Transition Metals 5 Halogens Noble Gases 6 +1 Common Ions of Elements +3 +2 +/- 4 -3 -2 -1 0 Variable, always + Predicting Charges on Monatomic Ions KNOW THESE !!!! +1 +2 -3 -2 -1 0 Cd+2 7 Polyatomic&Ions& ! Groups%of%covalently% bonded%atoms%that% have%a%charge.% *%NO3'((:nitrate%ion% *%NO2'((:nitrite%ion% ! Yes,%you%have%to% memorize%them.% ! Listed%in%your% resource%handbook:% memorize(the( required(list!!!!( Pa9erns&for&Polyatomic&Ions& ! @ate%ion% ! chlorate%=%ClO3@% ! @ate%ion%plus%1%O%⇒%same%charge,%per$%prefix% ! perchlorate%=%ClO4@% ! @ate%ion%minus%1%O%⇒%same%charge,%@ite% suffix% ! chlorite%=%ClO2@% ! @ate%ion%minus%2%O%⇒%same%charge,%hypo$% prefix,%@ite%suffix% ! hypochlorite%=%ClO@% 8 Polyatomic%Ions% You can make additional polyatomic ions by adding a H+ to the ion!" ! CO3 -2 is carbonate:" – ! HCO3 is hydrogen carbonate" ! PO43- is phosphate:" ! HPO4 2- is hydrogen phosphate" – ! H2PO4 is dihydrogen phosphate" 2- ! SO4 is sulfate" – ! HSO4 is hydrogen sulfate" The 3 types of Chemical Bonds: Metallic, Ionic and Covalent! ! Electronegativity%and%Bond%Type% ! Bond%type%can%be%determined%by%the%difference% in%electronegativty%between%the%bonds%involved% ! Differences%of:% ! 2%=%ionic% ≥ ! 0.5@1.9%=%polar%covalent% ! %≤%0.4%=%nonpolar%covalent% . ! Metals%bonded%to%other%metals%are%metallically% bonded,%regardless%of%the%difference%in% electronegativity% 9 Metallic bonds& ! The atoms of metals are held together when the atom’s valence electrons float around the nuclei of the metals – the “sea of electrons”" ! Electrostatic forces keep everything together" Ionic&Bonds& " ! Complete transfer of 1 or more electrons from one atom to another (or a polyatomic ion)" ! one loses one or more e-, the other gains those e-s" ! Atoms%involved%are%% ! a%metal%%and%either%a%non@metal%or%a% polyatomic%ion% ! The%cation%and%anion%are%attracted%to% % each%other%by%electrostatic%attraction%% 10 Ionic&compounds&are&neutral& ! Ionic%compounds%are%neutral% ! That%is,%they%have%no%overall%charge% ! This%is%because%the%number%of%electrons%that% are%given%up%by%the%metal%is%the%same%number% of%electrons%that%are%gained%by%the%anion%for% the%formula.% ! Formulas%reflect%this%neutrality@%the% charges%on%the%individual%ions%are%not% written%in%because%they%cancel%out%overall% for%the%compound% COMPOUNDS FORMED FROM IONS& CATION + ANION ---> COMPOUND! Na+%+%Cl@%@@>%NaCl% % %% A neutral compound ! requires! equal number of + ! and - charges.! 11 Covalent&Bonds& " ! 2, 4, or 6 valence electrons that are shared between atoms" ! We are going to name only simple covalent compounds that have 2 elements involved" Most&bonds&are&somewhere&in&between& ionic&and&covalent&(as&you&already&know)& ! Because%not%all%atoms%share%e@%equally% ! The%conventions%of%naming%assume%absolute%difference% in%bond%types% ! Metals%bonded%to%nonmetals%or%polyatomic%ions%are% classified%as%having%ionic%bonds*% ! Materials%made%out%of%all%non@metals%are%classified%as% having%covalent%bonds*% ! *%semimetals%are%not%a%classification%in%naming;%you%need% to%treat%the%elements%that%are%on%the%right%of%the%line%as% non@metals,%and%those%on%the%left%as%metals.%% ! For%more%on%this,%go%back%to%bonding%% 12 Naming&things:& If%there%is%only%one%element%present,%name%it.% & ! Atomic%substances%do%not%require%“special”% naming.% ! For%anything%with%more%than%one%element,% remember%that%there%is%ONE%MAIN%THING%to% look%for:%% ! Is%there%a%metal%first?%% % So…some&general&help&for&naming:& & ! Look%to%see%if%there%is%a%metal%first%in%the% formula% ! Again,%semimetals%are%not%a%classification%in% naming;%you%need%to%treat%the%elements%that%are%on% the%right%of%the%line%as%non@metals,%and%those%on%the% left%as%metals.% ! If%there%are%only%metals,%name%both%metals% ! (metallic%bonding;%nothing%else%need%be%done)% ! If%ONLY%the%first%element%is%a%metal,%then%the% compound%is%an%ionic%compound%% ! Nonmetals%only%signify%a%covalent%compound% ! There%is%a%flow%chart%in%your%handbook%to%help!% % 13 Naming&ionic&compounds:& ! Remember%that%those%are%compounds%that% have%a%metal%first%in%the%formula*,%and%then%a% nonmetal%or%a%polyatomic%ion.%% ! We%can%handle%these%as%simple%types% ! binary%(2%elements)%compounds% ! Ternary(more%than%2%element)%compounds% ! Names%are%always%for%the%smallest%whole% number%ratio%of%the%elements,%the%formula%unit% *Two%exceptions%to%this%rule:% %% ! Compounds%that%start%with%either%ammoniums%(NH4+)%or%hydronium%(H3O+) % General&informaHon&for&naming& ionic&compounds& ! If%the%cation%is%monatomic@%Name% the%metal%(cation).%% ! Use%Roman%Numerals%for%transition% metals%(ONLY)%after%the%metal%% ! If%the%cation%is%polyatomic@%name%it.% ! If%the%anion%is%monatomic@%name%it% but%change%the%ending%to%–ide.% ! %If%the%anion%is%poly%atomic@%just%name%it% 14 Example: CaCl2, or calcium chloride " Name the cation first, then the anion root with an –ide suffix " For CaCl2, the monatomic cation is Ca2+ , calcium, and the monatomic anion is Cl , named chloride. " We use chloride because the root for chlorine is chlor, and we use = root + -ide for the second element in binary compounds " CaCl2 = calcium chloride PracHce&Naming&Binary&Ionic&Compounds& ! (Examples:( ( NaCl(( (( ZnI2 (( (( Al2O3 ( (( 15 Learning&Check&& (Complete(the(names(of(the(following(binary( compounds:( (Na3N ( (( (KBr ( (( (Al2O3 ( (( (MgS ( (( % If&the&Metal&is&a&TransiHon&Metal…& Transition(metals(are(Type(II(Cations,(and(are( elements(that(can(have(more(than(one(possible( charge.((They(MUST(have(a(Roman(Numeral(to( indicate(the(charge(on(the(individual(ion.( (1+(or(2+((((((((((((((2+(or(3+( (( ( Cu+,(Cu2+ ((((((((((((Fe2+,(Fe3+( copper(I)(ion((((((((iron(II)(ion(( (copper((II)(ion((((iron(III)(ion ( ((( (% % 16 Type&II&CaHons& (These(elements(REQUIRE(Roman(Numerals( ( because(they(can(have(more(than(one(possible( charge:( (anything(except(Group(1A,(2A,(Ag,(Zn,(Cd,(and(Al( ( ((You(should(already(know(the(charges(on(these!)( ( Or(another(way(to(say(it(is:(Transition(metals(and(the(metals(in(groups(4A(and( ( (5A((except(Ag,(Zn,(Cd,(and(Al)(require(a(Roman(Numeral.( ( (FeCl3 ((Fe3+)( (iron((III)(chloride (( (CuCl (( (copper((I)(chloride( 4+ ( (SnF4(((((((((( ((Sn ) (tin((IV)(fluoride( 2+ (PbCl2(((((((( ((Pb ) (lead((II)(chloride( 3+ ((((Fe2S3 ((((((((( ((Fe )( (iron((III)(sulfide( ((Cu+()( You(will(appreciate(this(more(when(we(go(from(names(to(formulas!( Type&II&CaHons& Some%Type%II%cations%have%a%name%using%the% “old”%system%as%well%as%the%“new%system”.%%% % The%old%system,%still%widely%used,%adds%to%the% root%or%stem%of%the%Latin%name%of%the%metal% the%suffixes%–ous%and%–ic.%%These%represent% the%lower%and%higher%charges%respectively.%% 17 Examples&of&Older&Names&of&CaHons&formed&from& TransiHon&Metals& (you&do&not&have&to&memorize&these)& Learning&Check&& (Complete(the(names(of(the(following(binary( compounds(with(variable(metal(ions:( (FeBr2 ( (( (CuCl ( (( (SnBr4 ( (( (((Fe2O3 ( (( (Hg2S ( (( ( % 18 WriHng&Formulas&for&Ionic&Compounds&from& Names& Formulas(of(ionic(compounds(are(determined( ( ( from(the(charges(on(the(ions ( ((((((((((((( Na( (+((((F(((("→ (((((((((((((((((((((((( ( ((Na+(((((+(((((F'((("→(((NaF( ((((((((((((((((((((((((( Sodium(atom(+((fluoride(ion(((((((((sodium(fluoride( (((Charge(balance:(((((((((((1+((((((+((((((1'(((((((((((((=((0( ( Remember(that(all(ionic(compounds(have(no(net(charge,( and(that(the(charges(are(not(written(in!(Ever.(Nope.( % Neutral,&you&say?& ! Formulas%are%written%to%make%the% compound%have%a%neutral%charge%overall.%%% ! You%do%NOT%write%the%charges%in%the% formula%because%they%MUST%cross%out%to% accurately%represent%the%compound.%% ! Ex:%NaF2%is%INCORRECT%for%sodium%chloride% because%Na%has%an%oxidation%state%of%+1,%and% F%of%@1.%%There%is%a%one%to%one%ratio%of%Na+%to% F@%to%make%a%neutral%ionic%compound.% 19 WriHng&the&formula…& (Write(the(formula(for(the(barium(chloride,(the( compound(that(will(form(between(Ba2+(and(Cl'.( (Solution:(( 1.(Write(the(cation,(and(then(the(anion( 2.(Balance(charge(with((the(number(of(+(and(–(ions(( ( Ba++ ClThink: (((((( (((((((((((( Cl Why is Cl- written twice? 3.(Write(the(number(of(ions(needed(as(( ((((((((subscripts: (% BaCl2 So&what&if&the&oxidaHon&numbers& aren’t&even?& ! If%the%oxidation%numbers%or%charges%do%not% balance,%you%can%write%the%number%of%ions%of%each% until%you%get%the%same%number%of%each%charge%in% total.% Is#there#an#easier#way?# % ! Yes.%%The%“Criss%Cross”%method.%You%take%the% charge%number%from%the%cation,%and%you%make% it%the%number%of%anions%(subscript)and%take% the%charge%on%the%anion,%and%you%make%that% many%cations%(subscript).%%% 20 CrissTCrossing&in&acHon:& Example:%Lead%(II)%nitrate% % Pb2+%%N3@ % % Pb2+%%N3@%%% %*the%charges%do%not%balance% % % %% %Pb3N2%%%%%%%%%%%% % ! The%2%and%the%3%are%brought%down%to%the% opposite%element,%so%that%there%are%now%3%Pb2+% ions%and%2%N3@%ions% ! This%means%there%were%6e@%transferred%from%the% lead%atoms%to%the%nitrogen%atoms;%the%compound% is%neutral% Learning&Check&& (Write(the(correct(formula(for(the( compounds(containing(the(following( ions:( (1.( (Na+(and((S2'( ((( (a)((NaS ((((b)(Na2S ( (c)(NaS2( (2.((Al3+(and(Cl'( ((( (a)((AlCl3 ((((b)((AlCl( ( (c)(Al3Cl( (3.((Mg2+(and(N3'( ((( (a)((MgN ((((b)(Mg2N3 (c)(Mg3N2( ( 21 Ternary&Ionic&Compounds:& ! Contain(at(least(3(elements( ! There(MUST(be(at(least(one(polyatomic(ion( ( ((it(helps(to(circle(the(ions)( Examples:( (NaNO3 ( (Sodium(nitrate( (K2SO4 ( (Al(HCO3)3 ( ( ( (Potassium(sulfate( (Aluminum(bicarbonate( ((Aluminum(hydrogen(carbonate)( (( ( ( Examples: NaNO3, and Co(NO3)2 " Name the cation first, then polyatomic ion " For NaNO3, the monatomic cation is Na+ , sodium, and the polyatomic anion is NO3 , named nitrate. • NaNO3 is sodium nitrate " For Co(NO3)2, the monatomic cation is Co cobalt (II) and the polyatomic anion is NO3 , named nitrate. +2, • Co(NO3)2 is cobalt (II) nitrate 22 Learning&Check&& Match(each(set(with(the(correct(name:( 1.%%%%% %Na2CO3 ( (a)(((magnesium(sulfite(( ( (MgSO3 ( (b)(((magnesium(sulfate( ( (MgSO4 ( (c)(((sodium(carbonate( (( ( 2(. (Ca(HCO3)2 ( (a)(calcium(carbonate( (((((( (CaCO3 ( (b)((calcium(phosphate( (((((( (Ca3(PO4)2( (c)((calcium(bicarbonate( WriHng&Formulas&for&Ternary&Ionic&Compounds& ! Write%the%cation%first,%then%the%anion.%%% ! Overall%charge%must%equal%zero.% ! If%charges%cancel,%just%write%symbols.% ! If%not,%use%subscripts%to%balance%charges.% ! Use%parentheses(to(show(more(than(one(of(a( particular(polyatomic(ion.% ! Use%Roman(numerals%indicate%the%ion’s%charge%when% needed%(transition%metals)% ! Remember%that%the%final%formula%should%not%have% charges%written%in.% 23 WriHng&Formulas,&cont’d& Example:% Cr2+%%PO43@ %* the%charges%do%not%balance% % Cr2+%%PO43@%%% %Cr3(PO4)2% % The(polyatomic(ions(is(in( parentheses(whenever(a(subscript( is(added.( This(is(so(that(we(know(to(count(a( number(of(those(groups!( Learning&Check&& 1.((aluminum(nitrate(( ( (((a)((AlNO3((((((((((b)(Al(NO)3((((c)((Al(NO3)3( 2.((copper(II)(nitrate( ((((a)(CuNO3 (b)(Cu(NO3)2 (c)((Cu2(NO3) (( 3.((Iron((III)(hydroxide( ((((a)((FeOH (b)((Fe3OH ( 4.((Tin(IV)(hydroxide( ((((a)((Sn(OH)4(((b)((Sn(OH)2((((( (c)((Fe(OH)3( (c)((Sn4(OH)( ( % 24 Ternary&Ionic&Nomenclature:& You(Criss'cross(these,(too.(( ( Sodium(Sulfate( ( ( ( Iron((III)(hydroxide( ( ( ( ( Ammonium(carbonate( Write&the&Formula:& Copper%(II)%chlorate%%%% Calcium%nitride % Aluminum%carbonate Potassium%bromide % Barium%fluoride % Cesium%hydroxide % % % % %% % %% %% %% %% %% 25 General&naming&rules&for& covalent&(molecular)&compounds& ! Names%are%two%words,%with%prefixes.% ! Prefixes%tell%you%how%many.% ! Use%the%first%element’s%whole%name%with% the%appropriate%prefix% ! *********except%mono.% ! NEVER%use%mono%for%the%first%element% ! For%the%second%element,%use%the%root%of% the%name%and%the%@ide%ending%with% appropriate%prefix%for%that%many.% % NEVER% You% criss@cross%charges% with%covalent% compounds.% never& Since%you%are%sharing%electrons,%rather%than%giving% them%away/%picking%them%up,%the%charges%are% not%relevant.% % 26 Covalent&Naming&Prefixes:& PREFIX% %mono@% %di@% %tri@% %tetra@% %penta@% %hexa@% %hepta@% %octa@% %nona@% %deca@% NUMBER% 1% 2% 3% 4% 5% 6% 7% 8% 9% 10% Example: CO2 is carbon dioxide " Name the first element, using a prefix if there is more than one atom of the element present " Name the second element, using the appropriate prefix in all cases " CO2 is carbon dioxide because there is one carbon (no prefix when there is only one atom of the element,) and two oxygens (diprefix) 27 Learning&Check&& 1.( (P2O5 ( (a)((phosphorus(oxide( ( ( ( (b)((phosphorus(pentoxide( ( ( ( (c)((diphosphorus(pentoxide( ( 2.(Cl2O7 (a)((dichlorine((heptoxide( ( ( ( (b)((dichlorine(oxide( ( ( ( (c)((chlorine(heptoxide(( ( ( (( 3.((((( (Cl2 ( (a)((chlorine (( ( ( ( (b)((dichlorine (( ( ( ( (c)((dichloride( Learning&Check&& (Give(the(names(of(following(covalent( compounds:( ( (CO((( ( (( ( (CO2 ( (( ( (PCl3 (( ( (CCl4 ( (( ( (N2O ( (( 28 Covalent&Naming&Examples& " CCl4 " N2O5 " SF6 More&Covalent&Examples& " arsenic trichloride " dinitrogen pentoxide " tetraphosphorus decoxide 29 Hydrates:#Ionic#Compounds7Water# ! Some%salts%trap%water%crystals%when%they% form%crystals.%%% ! Ex:%CuSO4tH2O% ! These%are%hydrates.% ! Both%the%name%and%the%formula%needs%to% indicate%how%many%water%molecules%are% trapped.% ! In%the%name%we%add%the%word%hydrate%with% a%prefix%that%tells%us%how%many%water% molecules.%% ! CuSO4tH2O%is%copper%(II)%sulfate%pentahydrate% Hydrates# ! In%the%formula%you%put%a%dot%and%then%write% the%number%of%molecules.% % ! Calcium%chloride%dihydrate%=%CaCl2•2Η2Ο& & ! Chromium%(III)%nitrate%hexahydrate%=% Cr(NO3)3•%6H2O%% 30 Acid&Nomenclature& ! Acids( ! Compounds(that(form(H+(in(water.( ! Formulas(usually(begin(with(‘H’.( ! In(order(to(be(an(acid(instead(of(a(gaseous(covalent( compound,(it(must(be(aqueous( ! Meaning(dissolved(in(water;(symbolized(by((aq)( ! Ternary(acids(are(ALL(aqueous( ! Two(types:%%% ! Non@oxyacids% ! Oxyacids( Naming&acids:&NonTOxy&acids& If%the%acid%doesn’t%have%oxygen% ! add%the%prefix%“hydro@”% ! change%the%suffix%“–ide”**to%“@ic*acid”* HCl % H2 S % HCN % %Hydrochloric%acid% %Hydrosulfic%acid% %Hydrocyanic%acid% 31 Naming&acids:&Oxy&Acids& If%the%formula%has%oxygen%in%it% ! write%the%name%of%the%anion,%but%change:%% “.ate”*to*“.ic*acid”* ! “.ite”*to%“.ous*acid”* ! ! Watch%out%for%sulfuric%and%sulfurous!% H2CrO4 %% HMnO4%% HNO2%% Chromic%acid% Manganic%acid% Nitrous%acid% Acid&Nomenclature&Flowchart& ACIDS start with 'H' 2 elements 3 elements hydro- prefix -ic ending no hydro- prefix -ate ending becomes -ic ending -ite ending becomes -ous ending 32 Anion Ending Binary # Ternary Acid Name -ide hydro-(stem)-ic acid -ate (stem)-ic acid -ite (stem)-ous acid An easy way to remember which goes with which… “In the cafeteria, you ATE something ICky” Acid&Nomenclature& " HBr (aq) " H2CO3 (aq) " H2SO3 (aq) 33 Acid Name HNO3 HNO2 H2SO4 H2SO3 H3PO4 HC2H3O2 Name&‘Em!& ! HI%(aq)% ! HCl%(aq)% ! H2SO3%(aq)% ! HNO3%(aq)% ! HIO4%(aq)% 34 Formulas&for&acids& ! Backwards%from%names.% ! If%it%has%hydro@%in%the%name%it%has%no% oxygen% ! Anion%ends%in%“.ide”* ! No%hydro,%anion%ends%in%“.ate*or*–ite”* ! Write%anion%and%add%enough%H’s%to% balance%the%charges.% Acid&Nomenclature& " hydrofluoric acid " sulfuric acid " nitrous acid 35 Formulas&for&acids& hydrofluoric%acid% dichromic%acid% carbonic%acid% hydrophosphoric%acid% hypofluorous%acid% perchloric%acid% phosphorous%acid%% Write&the&Formula!& ! Hydrobromic%acid% ! Nitrous%acid% ! Carbonic%acid% ! Phosphoric%acid% ! Hydrotelluric%acid% 36 Common&Names& ! A(lot(of(chemicals(have(common( names(as(well(as(the(proper( IUPAC(name.( ! Chemicals(that(should(always(be( named(by(common(name(and( never(named(by(the(IUPAC( method(are:( ! H2O (water,(not(dihydrogen( monoxide( ! NH3(((ammonia,(not(nitrogen( trihydride( Mixed&PracHce& 1. 2. 3. 4. 5. 6. 7. 8. 9. Dinitrogen%monoxide% Potassium%sulfide% Copper%(II)%nitrate% Dichlorine%heptoxide% Chromium%(III)% sulfate% Iron%(III)%sulfite% Calcium%oxide% Barium%carbonate% Iodine%monochloride% 37 ! Match(each(set(with(the(correct(name:( Na2CO3 MgSO3 MgSO4 ( Ca(HCO3)2 CaCO3 Ca3(PO4)2( ( ( ( (a)(sodium(carbonate( (b)(magnesium(sulfite( (c)(magnesium(sulfate( (( ( ( ( (a)(calcium(bicarbonate( (b)((calcium(carbonate( (c)((calcium(phosphate( Mixed&PracHce!& Name%the%following:% 1. Na2O%% % % 2. CaCO3 %% 3. PbS2 % %% 4. Sn3N2% % %% 5. Cu3PO4% 6. HgF2 % %% %% 38 Mixed&Review&& Name(the(following(compounds:( 1.(( (CaO( ( ( 2.(( ( ( ( 3.(( ( % (a)((calcium(oxide ( (c)((calcium((II)(oxide (b)(calcium(I)(oxide( (d)(calcium(monoxide( (SnCl4( (( (( (a)((tin(tetrachloride (b)(tin(II)(chloride((( (c)((tin(IV)(chloride (( (N2O3( (a)((nitrogen(oxide((( %c)((nitrogen(trioxide (b)(dinitrogen(trioxide( ( % Mixed&PracHce& 1. BaI2% 2. P4S3% 3. Ca(OH)2% 4. FeCO3% 5. Na2Cr2O7% 6. I2O5% 7. Cu(ClO4)2% 8. CS2% 9. B2Cl4% 39 DONE!& Now&it&is&Hme&to&study!& Rainbow&Matrix&Game& ! Link(on(Chemistry(Geek.com(on(Chemistry( I(page( ! http://chemistrygeek.com/rainbow( ( Use([(](to(represent(subscripts(since(you(can’t( enter(subscripts(into(the(computer( So(H2O(would(be(H[2]O( And(Al2(SO4)3(would(be(Al[2](SO[4])[3]( ( Additional(Polyatomic(Ions((you(do(not(have( to(memorize(these,(but(they(are(in(the( game!)( Borate(=(BO3('3((;((Silicate(=(SiO4('4((;( Manganate(=(MnO4('2((permanganate(is('1)( 40