Heat Transfer Modes T I M Thermal Radiation Convection , Heat Conduction n o e t h l C a T T T g T m r n e a L G /Th ion • Fourier Law © lawlaofr coolingrs• Stefan-Boltzmann • Newton’s t e h o Law for Blackbody dT v g & i S & =thA Q = −kA [W] r ( Q T −oTn ) dx y & = AσT c Q p C e Cross- o r y C Di Convective Stefan-Boltzmann Constant Thermal Sectional g Heat r Conductivity 7 σ=5.67x10 W/m K Area e Transfer Coefficient 7 n 9 9 [W/m-K] [W/m K] 9 9 E • Heat transfer . . Materials Property 2 r 2 cal Flow dependent ) Q& = AF εσ (T − T i o r • HeatF Flux ct • Natural Convection Emissivity of View factor e l dT & E [ ] • Forced Convection F=1 for two two surfaces Fluid Ta y cold hot uy ux x cold hot Tw w 4 a -8 2 4 2 4 hot q = −k dx (= -k∇T) W/m 2 parallel plates 4 cold Thermal Radiation: Planck’s Law T I M , • Intensity: power per unit • Emissive power: power per n earea to solid angle in the direction unit surface h l of propagation C a θdΩ e =g∫ I cosm n er Power a h I = n G T o / i dA dΩdλ r © s t ola = ∫ deϕr∫ I cosθ sin θd θ = πI h v g i S n r dA t o y • Planck’s law c p C e y θ o r i 1 C D rg I (λ ) = 4πc h 7 97 ne λ ⎛ 2πhc ⎞ 9 ⎟⎟ −1 exp⎜⎜ 9 9 E . . l ⎝ k Tλ ⎠ 2 2 a r ric Solid Angle o 4π c h 1 F dA ct e(λ ) = λ ⎛ 2πhc ⎞ e l = sin θdθdϕ dΩ = ⎟⎟ − 1 exp⎜⎜ E λ λ 2π λ 2π π /2 ⊥ λ 0 0 p 2 5 B 2 2 R p 2 5 ⎝ k BTλ ⎠ λ Thermal Radiation: Planck’s Law T I M Q& Wien’s displacement law , n o e t λ T = 2898 Kμmh l C a g rm n e a h G /T ion Total © lar rs t e h o v g i S n r & & t Q = ∫ Q(λ )dλ = AσT o y c p C e o r i y C g D e = σT r 7 97 ne 9 9 9 E . . l Stefan-Boltzmann constant 2 r 2 ca o W/mtrKi σ = 5.67F × 10 c e El 2 EMISSIVE POWER (W/cm μm) max ∞ 4 0 4 b −8 2 10 4 10 3 10 2 10 1 5600 K 2800 K 1500 K 10 0 4 800 K 10 -1 0 2 4 6 WAVELENGTH (μm) 8 10 Universal Blackbody Curve T I M [0,λ] Fraction of Energy between , nBlackbody Function of λT only Relative to Total e o t h l C a e 4π c h 1 g e dλ r m ∫ n = C dλ e a T (λT ) exp ⎛⎜ 2πhc ⎞⎟ − 1 F= =∫ n h G T σT o (λT ) exp ⎛⎜ 2πhc ⎞⎟ − 1 / ⎜ k λT ⎟ i r © s ⎠ ⎝ ⎜ k λT ⎟ a r t l e h ⎝ ⎠ o v g C 1 i S n r = t C d (λT ) 1 o y c (λT ) exp⎛⎜ 2oπp hc ⎞ = C e ∫ ⎟ − 1 r σ (λT ) exp ⎛⎜ 2πhc ⎞ ⎟ − 1 i y C⎜⎝ k λT ⎟⎠D rg ⎜ k λT ⎟ 7 97 ne ⎝ ⎠ 9 9 9 E . . C dx 1 l 2 r 2 ca = = ∫ f (x)dx ∫ σ x i ⎛C ⎞ o r exp ⎜ ⎟ −1 F ct x ⎠ ⎝ e El bλ 5 λ 2 2 bλ 5 λ 0 1 5 4 0 B B λT 1 5 1 5 0 B B λT x 1 5 0 = F(0 - λT) 2 0 T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 λ T9(μmK)l E . . λT (μmK) 2 r 2 ca i o r F ct e l E F(0-λT) f(λT) Universal Function T I M Orbital Earth , n o e t h l C a g rm n e a h G /T i n © la r t e h o v g i S n r o y e p C o r C Di 7 97 n 9 9 9 E . . l 2 r 2 { ca i o r F { ct e l E Image by Robert Simmon (NASA). March equinox Mar 20/21 Sun 1.27 x 107 m 7900 mi 1.39 x 109 m 8.64 x 105 mi Earth 32' Solar constant 2 Gsc Distance is = 1367 W/m = 433 Btu/ft2 hr = 4.92 MJ/m2 hr = 1.495 x 1011 m = 9.3 x 107 mi 1.7% June solstice Jun 21/22 Aphelion July 4 152,100,000 km Sun 147,300,000 km Perihelion January 3 December solstice Dec 21/22 September equinox Sept 22/23 Figure by MIT OpenCourseWare. Figure by MIT OpenCourseWare. Earth Tilt T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C Di rgy 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E Images from Wikimedia Commons, http://commons.wikimedia.org Solar Spectral Outside Atmosphere IT M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r i y C g D r 2 7 7 ne 9 9 .F9 2c.9t al E e l r oE ric Image by Robert A. Rohde/Global Warming Art. http://www.newport.com/images/webclickthru-EN/images/798.gif Solar Going Through Atmosphere T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l Source: E http://marine.rutgers.edu/mrs/education/class/yuri/erb.html Image by NASA. Solar spectra T I M of the path Solar spectra are named by their air mass (AM), which is the, ratio length of air the rays travel through to the shortest possible pathlength (i.e. n directly overhead). Thus the AM0 solar spectrum is e measured above the o t h earth’s atmosphere, AM1 occurs when the sun is directly overhead, and l C a AM1.5 occurs when the sun’s rays travel through 50% more of the g rm atmosphere than when the sun is directlyn overhead. Note 1/cos(48.2°) = 1.5, so AM1.5 occurs when the solar zenith anglee is 48.2°. a h n Gfrom many • AM0 is an average of measured data satellites, the space T o / i shuttle, high-altitude aircraft, sounding rockets, etc. s r © a r t l • AM1.5G and AM1.5 Directh + Circumsolar are calculated values based on e o v atmospheric constituentig and particle concentrations, humidity, ground S n r surface albedo, the y U.S. Standard Atmosphere, and various other t o c parameters. They are defined as follows: p C e o r – AM1.5 Direct + Circumsolar is only y the solar radiation that comes from the sun i C g and the cone of skyD of half-angle 2.5 degrees surrounding the sun. The r reference surface is normal to the sun, with an air mass of 1.5 (solar zenith e 7 7 48.2°). 9 9 (Defined in ASTM n G173-03) 9 9 E accounts for radiation from the sun, the entire sky, and reflections off . l 2–. AM1.5G 2 the ground. The solar zenith is 48.2°, but the panel is tilted at an angle of 37°. a r This results inian angle of incidence of the sun of 11.2°. (ASTM G173-03) c o r – FAM1.5G is t the spectrum used to calibrate solar cells. This spectrum gives higher solar cellc efficiency than AM0, and higher power per square meter than AM1.5 Directle E + Circumsolar. (ASTM E490-00a) Air mass standards IT M , n o e t h l C a g rm n e a h G /T ion r © s a r t 48.1° l e h o v g i S n r t o y c p C e o r C D i rg y AM1.5 e 7 7 n 9 9 9 9 E Earth 2. r 2. cal i o r F ct e l E Air mass standards IT M , n o e t h l C a g rm n e a AM1.5 Direct + Circumsolar AM1.5 Global h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C48.1° Di rgy 7 97 ne 9 9 9 11.1° E . . l 2 r 2 ca i o r F ct Earth Earth e l E T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r i y C g D r 7 e 7 n 9 9 9 9 E 2. r 2. cal i o r F ct Ele Image by Robert A. Rohde/Global Warming Art. Source: http://en.wikipedia.org/wiki/File:Atmospheric_Transmission.png T I M , n o e t h l Here the black body at a 5777 K is C scaled such g that thermtotal power is the n solara constant ateAM0: 1366 W/m . G /Th ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y e 7 7 n 9 9 9 9 E 2. r 2. cal i o r F ct e l E 2 Surface Properties: Emissivity T I M I (Ω ) I (Ω) , Directional-spectral en ε λ (T )to= λ h Iλ l C a g rm n eλ e a h Hemispherical-spectral G /T ioεnλ (T ) = e © lar rs λ t e h o v g i S n r I (Ω ) t o y Diffuse Emitter p c Directional-total ε (T ) = C e o r i ' I y C g ελ = ελ D r 7 97 ne 9 9 E Gray Emitter.9 . l 2 ' r 2' ca Hemispherical-total ε (T ) = e e εFλo= ε ctri e l Diffuse-Gray E Emitter λ ' b b ' b b Surface Properties: Absorptivity T I M Directional-spectral I (Ω) , n o e t absorbed power h l α λ (T ) =C a g rm I λ (Ω )dΩ n e a h G /T i on © lar rs α λ (T ) Hemispherical-spectral t e h o v g i S n r t o y c p C e o r Kirchoff’s rgy α (T ) CLaw Di Directional-total e 7 7 n '9 ' 99 9 E 2.ε λ =r α2λ. cal i o r Hemispherical-total α (T ) F ct e l E λ ' ' Surface Properties: Reflectivity&Transmissivity T I M , I (Ω ) n o I (Ω') Reflectivity: e t h l C I (Ω') a ρ = g Reflectivity Bi-directional m r I (Ω ) n e a h n G T o / i ρ Directional-spectral: r © s t ola er h v g Hemispherical-spectral: i ρ S n r t y ec Co p Directional-total: ρ o r i y C D Hemispherical-total: g ρ r 7 97 ne Diffuse Reflector 9 9 9 E . . l 2Reflector 2 ca Transmissivity: τ ,τ ,τ ,τ ,τ Gray r i o r t F c Diffuse Grayle Reflector ρ + α +τ = 1 Energy Conservation E λ ,i λ ,r λ ,r " λ λ ,i ' λ λ ' " ' λ ' λ λ ' λ ' λ ' λ View Factor T I M , n power reaching dA e o F = t h l dA power leavingadA C g rm cos θ dA n I dA coseθ a G= /Th ioRn © lar πIrsdA θ t e h o v g i S θ cos θ dA cosn r t y ec C = o θ p πR o r i y C D rg 7 97 ne cos θ cos θ 1 9 = ∫∫ dA dA F dA .9 9 E . A πR 2 r 2 ca l i o r t F Assumptions: c Diffuse surface e l E j dAi − dA j j i i i j 2 ij i 2 i j i i j j 2 1 ij i i j Ai − A j 2 i Ai A j i ij Radiation leaving Ai is uniform j View Factor RelationsIT M , n o e t h Reciprocity l C a g rm n FdA − dA dAi = FdA − dA dAGj a FeA − A n Ai = FA − A A j h T o / i r © s a r t l e h o v g i S n r t o y c p C e r Summationo C Di FA −r(gA y+ A ) = FA − A + FA − A e 7 7 n 9 9 9 9 E 2. r 2. cal i o r F ct e l E i j j i i i j k i j j j i k i Sun 1.27 x 107 m 7900 mi Earth-Sun T I Radiation M , n o { e t h Radiation Reaching Earth l { C a g rm n es As Fs −e e a G /Th ion r © s πD Solar Radiation Per Unit a r t π D l e h A = o A = ig Area v Normal to Sun on Earth 4 S n 4 r t Outside Atmosphere o y c p C e o r i y 4 πD / C e AF g D = e F J = F = 7 = 57.67 ×10 er A R n 9 9 9 9 E . . = 5.67 ×10 × (5777 ) × 6.79×10 l 2 πDr 2/ 4 ca i W = 6.79 ×10 F =Fo r t = 1365 R ec m l E 1.39 x 109 m 8.64 x 105 mi Earth 32' Solar constant 2 Gsc Distance is = 1367 W/m = 433 Btu/ft2 hr = 4.92 MJ/m2 hr = 1.495 x 1011 m = 9.3 x 107 mi 1.7% Figure by MIT OpenCourseWare. 2 2 s e s e 2 s −e −9 e 2 s s−e s 8 2 e − s e se e − s s s 4 −5 s 2 se As F s− e = Ae Fe − s 2 Solar Constant: 1366 W/m2 −5 Maximum Efficiency Blackbody At T I Sun’s of a Solar Thermal Engine M Temperature T , n e to Heat Transferred tohAbsorber l C a g rm Blackbody n Q = σ (T h−eT ) a Absorber at T G /T ion © lar rs J t Thermal Efficiencye h o g t S nv i r W y ec Cσo(T − T ) T p Engine o C Dir rgηy = σT = 1 − T 7 97 ne 9 J 9 9 E . . l 2 r 2 ca Carnot Efficiency i r TFo t c Ta e l η = 1− E s h 4 4 4 4 s h 4 s th 4 s c a T 4 s Maximum Efficiency T I of a Solar Thermal Engine M , n o e t h l C a ⎛ T ⎞⎛ T ⎞ g m r n η = η η = ⎜⎜1 − ⎟⎟⎜ 1− ⎟ e a h T T n ⎠ G ⎠⎝ ⎝ T o / i r © s t ola er h g t S nv i r y ec Co p o C Dir rgy Maximum:7 85% @ T=2450K 7 ne 9 9 For T.9 =300 K .9 E l 2 r 2 ca i o r F ct Temperature (K) e El 4 0.9 a 4 s 0.8 0.7 Efficiency th C 0.6 0.5 0.4 0.3 Series8 0.2 0.1 a 0 0 1000 2000 3000 4000 5000 6000 How Hot a Surface Can Get By Solar Radiation? MIT , n e to h l Solar Radiation In Thermal C Emission Out a g rm n Ambient e a h G /T ion T © laαr rs Absorptivity t e h o Emissivity ε v g i S n r t o y c p C Zero Emissivity on This Side e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 Cc∫aα J dλ = ∫ ε [e (T ) − e (T )]dλ i o r F ct e l E Concentration a λ λ ∞ ∞ λ 0 λ λ 0 bλ bλ o Selective surface T I • Black body: emissivity = 1 for all wavelengths M , nsolarospectrum • Selective surface: emissivity is high in the e t and low in the infrared. Ideally the transition would occur h l a . abruptly at the cutoff wavelength λcC g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y e 7 7 n 9 9 9 9 E 2. r 2. cal i o r F ct e l E Approximate the Sun as A Blackbody T I M , One Sun C=1 en to h l C a g rm n e a h (T )]dλ e (T )dG λ = ∫ A[T e (T ) − e n ∫ A F o / i r © s t ola er h g t S nv i r o y ( ) (T ) − e (T )]dλ [ AF e T d λ = A e c p ∫ o ∫ C e C Dir rgy e 7 7 n 9 9 F T ( 0 ) F (0 − λ T ) F (0 − λT ) − λ 9 9 E . . 2 r 2F cσaTl = σT − σT i o r F ct e l E λ λ sun sun− surface bλ bλ sun bλ 0 0 λ λ e − s bλ bλ sun 0 bλ o 0 a s e− s 4 sun 4 4 a o Maximum Temperature AM0 T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E Selective surface T I M , • Fix Temperature, choosing a n e to h l cut-off wavelength C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y e 7 7 n 9 9 9 9 E 2. r 2. cal i o r F ct e l E Efficiency of a Solar Solar Js T I Thermal Engine: M 1 Sun , n • Fix Temperature, choosing a cut-off e o t h l wavelength C a g rm n Selective e a h G /T ion Absorber r © s a r t l J e h o v g i S n r t o y c Wp C e o r i y Engine C g D r 7 97 ne 9 9 E J .9 . l 2 r 2 ca i o r F ct ηth Thermal Efficiency e l E h c Thermal Efficiency for AM1.5G with No Concentration T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E System (Surface x Carnot) Efficiency for AM1.5G with No Concentration T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E System performance T I • Increasing the temperature of the M , hot side of a heat enginenincreases the Carnot efficiency. e o t h • However, increasing the al C g rradiation m temperature increases n e losses, whichadecreases the h n G T amount of heat delivered to the o / i r © s heat engine (surface efficiency). a r t l e h o v g • Example: Sunselect® surface with i S n r t o no concentration: y c p C e o r C D i rg y e 7 7 n 9 9 9 9 E 2. r 2. cal i o r F ct e l E Sunselect absorber T I M , n o e t h l C a g rm n e a h G /T ion © lar rs Optimal t e operation pointh o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E T I M , n o e t h l C a • This same analysis can be performed to find the ideal g m r n absorber for various concentrations and operating e a temperatures. This is the absolute n on G /Thupperiolimit system efficiency. © lar rs t e h So the vSunselect • We can compare iagblackbody, absorber, n r ct and an ideal absorber o y p ire C o C D rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E Blackbody absorber T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E Sunselect absorber T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E Ideal absorber T I M , n o e t h l C a g rm n e a h G /T ion © lar rs t e h o v g i S n r t o y c p C e o r C D i rg y 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E Heat Transfer on A Suspended Surface T I M , nOut o Solar Radiation In Thermal Emission e t h l C a g rm Ambient T n Absorptivity α , Emissivity ε e a G /Th ion © lar rs t Suspension e h o v g i S Emissivity ε n r t o y c p C e o r C D i rg y 7 α 9J7dλ = nε e[e (T ) − e (T )]dλ + T − T 9 9 9 ∫ ∫ E . . R l 2 r 2 ca i o r F ct e l Thermal Resistance by Conduction E λ a λ1 λ2 ∞ ∞ λ 0 λ λ 0 bλ bλ a o th Heat Conduction T I M , n e Heat Conduction Thermal Resistance o R t h l C a & g Heat Current Q m n er T T a h n G T L o / T i T r © s R a r t l e h o 1D, no heat generation v 1 g i S Convection n = R r t o y hA T T T T − − c & p Q = kA = C e y o R ir L C D rg 7 97 ne 9 9 9 E . . l 2 r 2 ca i o r F ct e l E th cold hot hot cold th th hot cold hot cold th = L kA MIT OpenCourseWare http://ocw.mit.edu 2.997 Direct Solar/Thermal to Electrical Energy Conversion Technologies Fall 2009 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms.