Lect 4: Intro to Geomorphology 10/5/2015 Goals of Today’s Lecture 1. To answer the question: Where do landscape materials come from? 2. To examine weathering and bedrock erosion processes at Earth’s surface. 3. To consider how these ideas of soil and debris production fit into our generalized continuity equation of the landscape. Change in landscape surface elevation (rate) ∆ dz =U-Edt · qs Bedrock erosion rate (P+W) Uplift rate of the landscape surface All landscapes must obey this fundamental statement about sediment transport! Sediment flux divergence (written in 3D) The whole landscape in one equation! Photo courtesy of Bill Dietrich 1 Lect 4: Intro to Geomorphology ∆ dz =U-Edt 10/5/2015 · qs All landscapes must obey this fundamental statement about sediment transport! Geomorphic transport laws In order to make predictions of landscape change Geomorphologists need to parameterize (E and qs): E includes: • Sediment production by weathering (P) • Bedrock erosion by glaciers, wind, water (W) qs includes erosion and deposition by: • Mass wasting transport processes • Fluvial transport processes The whole landscape in one equation! Photo courtesy of Bill Dietrich ∆ ∂z =U-E∂t · qs All landscapes must obey this fundamental statement about sediment transport! Our discussion today will focus on processes responsible for the production of transportable material in the landscape. There are two components to E: soil production (P) and bedrock wear (W). The whole landscape in one equation! Photo courtesy of Bill Dietrich 2 Lect 4: Intro to Geomorphology 10/5/2015 Where do landscape materials come from? Granite Sand Enchanted Rock State Natural Area of Texas, USA Where do landscape materials come from? There are two processes that are important: 1) Weathering or Soil Production: In situ disintegration or breakdown of rock material 2) Bedrock Wear: Erosion of rock material by water, wind, or ice These are not mutually exclusive processes. Only where rock is covered by soil does weathering operate as the sole process. In many environments, both weathering and bedrock erosion are occurring at the same time. Enchanted Rock State Natural Area of Texas, USA 3 Lect 4: Intro to Geomorphology 10/5/2015 Weathering in the Rock Cycle Weathering in the Source to Sink Framework 4 Lect 4: Intro to Geomorphology 10/5/2015 Types of weathering Physical (Mechanical): Chemical: 1. Pressure release 1. Solution 2. Freeze-thaw 2. Hydration 3. Salt-crystal growth 3. Hydrolysis 4. Thermal expansion 4. Oxidation 5. Biotic 5. Biological Hematite Mechanical Weathering: no change in chemical composition--just disintegration into smaller pieces This increases the total surface area exposed to weathering processes. 5 Lect 4: Intro to Geomorphology 10/5/2015 Chemical Weathering: breakdown as a result of chemical reactions. CaCO3+CO2+H2O ---> Ca2+ + 2HCO3Carbon dioxide Calcium Carbonate Limestone or marble rock Calcium Water Carbonic Acid (H2CO3) Bicarbonate Rock that can be carried in solution! Transformation/decomposition of one mineral into another! Types of weathering Physical (Mechanical): Chemical: 1. Pressure release 1. Solution 2. Freeze-thaw 2. Hydration 3. Salt-crystal growth 3. Hydrolysis 4. Thermal expansion 4. Oxidation 5. Biological 5. Biological 6 Lect 4: Intro to Geomorphology 10/5/2015 Mechanical Weathering: 1. Pressure Release Exfoliation: Rock breaks apart in layers that are parallel to the earth's surface; as rock is uncovered, it expands (due to the lower confining pressure) resulting in exfoliation. Weathering Exfoliation: Formative mechanism 7 Lect 4: Intro to Geomorphology 10/5/2015 Pressure release examples Sheet Joints (Exfoliation) Pressure release examples Half Dome, Yosemite, CA 8 Lect 4: Intro to Geomorphology 10/5/2015 Pressure release examples Stone Mountain, GA Mechanical Weathering: 2. Freeze-thaw Frost Wedging: rock breakdown caused by expansion of ice in cracks and joints 9 Lect 4: Intro to Geomorphology 10/5/2015 Freeze-thaw example Shattered rocks are common in cold and alpine environments where repeated freeze-thaw cycles gradually pry rocks apart. Average number of freezethaw cycles per year in Canada (Fraser 1959) Trenhaile, 2010 10 Lect 4: Intro to Geomorphology 10/5/2015 Mechanical Weathering: Weathering 3. Thermal Expansion Thermal expansion due to the extreme range of temperatures can shatter rocks in desert environments. Repeated swelling and shrinking of minerals with different expansion rates will shatter rocks. Frost shattered rock, Fraser Canyon, 2009 11 Lect 4: Intro to Geomorphology 10/5/2015 Mechanical Weathering: 4. Salt Crystal Growth French Mediterranean coast near St. Tropez F.J.P.M. Kwaad Often thought to be most effective at granular disintegration on exposed rock faces. Can it split rock? 12 Lect 4: Intro to Geomorphology 10/5/2015 Salt weathering process Developing salt crust through evaporation of salt brine in the surf zone. Photos by F.J.P.M. Kwaad Crystallized salt on the rock surface and in rock fissures in granite Rock particles released by salt weathering of granite Tafoni weathering is common in arid coastal areas where brine is abundant and salt crystallization is possible. Yehliu, Taiwan 13 Lect 4: Intro to Geomorphology 10/5/2015 Tafoni Salt Weathering, near San Francisco California Juha Huuskonen (www.juhuu.nu) Honeycombs, Artillery Rocks, Victoria, Australia (Trenhaile, 2010) 14 Lect 4: Intro to Geomorphology 10/5/2015 Mechanical Weathering: 5. Biotic weathering Root Splitting: At large scales, seedlings sprouting in a crevice and plant roots exert physical pressure. Burrowing animals and insects disturb the soil layer adjacent to the bedrock surface, increasing water infiltration and exposure to other processes. Photo courtesy USGS DDS21 Role of Physical Weathering 1) Reduces rock material to smaller fragments that are easier to transport 2) Increases the exposed surface area of rock, making it more vulnerable to further physical and chemical weathering 15 Lect 4: Intro to Geomorphology 10/5/2015 What controls rate of physical weathering? Resistance to weathering: Rock strength, composition, fracture pattern. Joints in a rock are a pathway for water – they can enhance mechanical weathering. The form and density of fractures is controlled by the rock type. What controls rate of physical weathering? Driving force of weathering: 1) Exfoliation requires erosion which requires water 2) Ice crystalization requires water 3) Salt crystalization requires water 4) Biota growth requires water Physical weathering systems are controlled by the availability of water and thus are climatically controlled. More on this later! 16 Lect 4: Intro to Geomorphology 10/5/2015 Chemical Weathering Sandstone found in glacial drift near Angelica, New York Types of weathering Physical (Mechanical): Chemical: 1. Pressure release 1. Solution 2. Freeze-thaw 2. Hydration 3. Salt-crystal growth 3. Hydrolysis 4. Thermal expansion 4. Oxidation 5. Biotic 5. Biotic (?) 17 Lect 4: Intro to Geomorphology 10/5/2015 Chemical Weathering: 1. Solution Solution: process by which rock is dissolved in water H2O + CO2 + CaCO3 Ca+2 + 2HCO3water + carbon dioxide + calcite dissolve into calcium ion + bicarbonate ion Biological activity in soils generates substantial CO2 Bicarbonate is the dominant ion in surface runoff (rivers). Solution Strongly influenced by pH and temperature (as are all chemical reactions) evaporite Rock particularly vulnerable to solution weathering: 1. Calcium carbonate (calcite, limestone) 2. Sodium chloride (salt) 3. Calcium sulfate (gypsum) When water becomes saturated, chemicals may precipitate out forming evaporite deposits. Salt Crystal growth on playa lakes in Death Valley, CA 18 Lect 4: Intro to Geomorphology 10/5/2015 This photo of Lime Sink was taken on 20 July 1932, over a week after the drawdown, which occurred over the night of 9-10 July. ‘Karst’ landforms develop in areas underlain with limestone Chemical Weathering: 2. Hydration Hydration: attachment of water molecules to crystalline structure of a rock, causing expansion and weakness. Hydration of Anhydrite Ca2SO4 + 2H20 Ca2SO4 . 2H20 Anhydrite Water Gypsum But, many of these reactions are reversible! Dehydration of gypsum by heating: Ca2SO4 . 2H20 Ca2SO4 + 2H20 So, is this a chemical weathering process? 19 Lect 4: Intro to Geomorphology 10/5/2015 Chemical Weathering: 3. Hydrolysis Hydrolysis: combination of hydrogen and oxygen in water with rock to form new substances. Carbonation is essentially the same reaction, but with CO2 instead of H+. Feldspar Weathering to Kaolinite: Feldspar Hydrogen Ion Water 2K Al Si3 O8 + 2H+ + 9H2O H4 Al2 Si2 O9 + 4H4 Si O4 + 2K+ Kaolinite Disolved silica (acid) Potassium ion Most common mechanism for clay formation. Chemical Weathering: 4. Oxidation Oxidation: Oxygen dissolved in water oxidizes sulfides, ferrous oxides, native metals Olivine Water Oxygen 2Fe Si O4 + 4H2O + O2 2Fe2 O3 + 4H4 Si O4 Hematite Disolved silica (acid) Hematite 20 Lect 4: Intro to Geomorphology 10/5/2015 Oxidation Weathering? or Aqueous Mineralization? “Blueberries” (hematite spheres) on a rocky outcrop at Eagle Crater. Images from Mars rover Opportunity, NASA Oxidation, Phang Nga Bay, Thailand Trenhaile, 2010 21 Lect 4: Intro to Geomorphology 10/5/2015 Weathering rind formed by oxidation. http://www.marlimillerphoto.com Chemical Weathering: 5. Biotic Plants and animals cause chemical weathering through release of acidic compounds or hydrogen (H+). Thus, biota provide the reactant that causes chemical weathering and may also provide a conduit that feeds water and reactants into fissures and cracks, but does not dissolve rock in any constitutive way. 22 Lect 4: Intro to Geomorphology 10/5/2015 Chemical Weathering Water is the main operator: – Dissolution Many ionic and organic compounds dissolve in water (Silica, K, Na, Mg, Ca, Cl) – Hydration and Hydrolysis both require water – Acid Reactions Require water • Water + carbon dioxide carbonic acid • Water + sulfur sulfuric acid • Water + silica silica acid Typical Chemical Weathering Products Olivine + H2CO3 (acid) Clay 23 Lect 4: Intro to Geomorphology 10/5/2015 Typical Chemical Weathering Products Feldspar + H2CO3 (acid) clay Typical Chemical Weathering Products + anything Quartz Quartz 24 Lect 4: Intro to Geomorphology 10/5/2015 Calcite to ……. Calcite + anything Nothing solid Resistance to Chemical Weathering First to Crystallize Last to Crystallize Crystallization temperature Bowen’s Reaction Series Fast Weathering Goldrich Stability Series Slow Weathering 25 Lect 4: Intro to Geomorphology 10/5/2015 Why is sand so prevalent at Earth’s surface? Mean Lifetime of a 1mm crystal at surface (in years) Quartz Kaolinite Muscovite Microcline (Alk. Feldspar) Albite (Sodium Plagioclase) Sandine (Alk. Feldspar) Enstatite (Pyroxene) Diopside (Pyroxene) Forsterite (Olivine) Nepheline (Amphibole) Anorthite (Calcium Plagioclase) 34,000,000 6,000,000 2,600,000 921,000 575,000 291,000 10,100 6,800 2,300 211 112 It is composed of quartz, a relatively stable mineral! Martian Dunes! 26 Lect 4: Intro to Geomorphology 10/5/2015 Meanwhile…Back in the real world Mechanical and chemical weathering work together to break down the landscape into materials that can be easily transported. – Fracturing, disintegration caused by mechanical weathering exposes more surface area. – Greater surface area, means more places for chemical action to occur. – Disturbances by biota are one of the primary ways in which weathered bedrock is churned up to form soil. Linkage between climate and weathering Boreal Forest Chemical weathering Most effective in areas of warm, moist climates – decaying vegetation creates acids that enhance weathering Least effective in polar regions (water is locked up as ice) and arid regions (little water) Mechanical weathering Enhanced where there are frequent freeze-thaw cycles 27 Lect 4: Intro to Geomorphology 10/5/2015 Yukon Vancouver Amazon Altiplano, Andes How does weathering fit into our generalized continuity equation of the landscape? Bill Dietrich P>Transport Weathering is P Bedrock landscape Detachment or supply-limited P<Transport Capacity dt =U-P- ·∆ dz qs Soil mantled landscape (Transport limited) Bill Dietrich dt =U-P-W- ·∆ dz qs 28 Lect 4: Intro to Geomorphology 10/5/2015 Can we predict rates of soil production (P) from bedrock for inclusion in our generalized continuity equation of the landscape? ∆ dz =U-Edt · qs Some things that we know: 1) Soil profile development varies with climate 2) The production rate can be predicted from observed soil depth Soil Production Function P P0 e H G. K. Gilbert, 1870 P H There is an exponential decay in the soil production rate with soil depth for a given climate and rock type. Heimsath, et al., 1997, Nature. 29 Lect 4: Intro to Geomorphology 10/5/2015 How about the bedrock wear (W) contribution to E? ∆ dz =U-Edt · qs Wear (G.K. Gilbert’s ‘corrasion’) is a function of the imposed stress and the resistance of the bedrock to this stress (Erodibility). Erodibility Resistance to Erosion: There is at least a 5 order of magnitude range in bedrock erodiblity 30 Lect 4: Intro to Geomorphology 10/5/2015 Erosion varies inversely as the square of the rock strength. Driving force: Water Near Banff Springs Hotel, Alberta 31 Lect 4: Intro to Geomorphology 10/5/2015 Driving force: Water J David Rogers Wind sculpted arches? J David Rogers As with water, it is the sediment in the sand that does the work, not the wind itself! Arches National Park near Moab, Utah 32 Lect 4: Intro to Geomorphology 10/5/2015 Yardangs Arizona East of Cameron, Little Colorado River Valley Peru (Coastal), Ica Valley Ica Valley, Cerro Yesera Yardang Field Egypt, Northwest of Bir Tarfawi, Western Desert Photos by USGS, Desert Studies Group Driving force: Wind ~17km Yardangs formed on Mars south of Olympus Mons at 60 N latitude and 220 E longitude, which was probably formed by the action of the wind. 33 Lect 4: Intro to Geomorphology 10/5/2015 Driving force: Ice Glacial grooves caused by the Wisconsin glaciation at Kelleys Island, Ohio Note here too that it is sediment and rock embedded in the ice that actually scours the bedrock Glacial grooves in rock panels, Churchill, Manitoba, Canada. Lassen NP, Northern California. Polished bedrock Yosemite NP http://www.yosemite.ca.us/library/geologic_story_of_yosemite/final_evolution.html photo by Ann Dittmer 2002 34 Lect 4: Intro to Geomorphology 10/5/2015 Driving force: Ice (Avalanche) Driving force: Sediment flow (debris flows) Landslide and debris flow tracks debris flow track 35 Lect 4: Intro to Geomorphology 10/5/2015 Leslie Hsu’s Bedrock Erosion Wheel We will talk more about the stress imposed by sediment flow (mass wasting), water flow, and ice flow in future lectures. ∆ dz =U-Edt · qs All landscapes must obey this fundamental statement about sediment transport! Geomorphic transport laws In order to make predictions of landscape change Geomorphologists need to parameterize (E and qs): E includes: • Sediment production by weathering (P) • Bedrock erosion by glaciers, wind, water (W) qs includes erosion and deposition by: • Mass wasting transport processes • Fluvial transport processes The whole landscape in one equation! Photo courtesy of Bill Dietrich 36